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Low-temperature Synthesis of Carbon Nanofibers/graphite Felt Composites Under Contactless Induction Heating 低温非接触感应加热合成纳米碳纤维/石墨毡复合材料
Q2 Materials Science Pub Date : 2023-08-01 DOI: 10.37358/rc.23.3.8571
Cuong Duong‐Viet, Lai Truong-Phuoc, Thierry Romero, J. Nhut, L. Nguyen-Dinh, L. Vidal, C. Pham‐Huu
In this report induction heating was used for the catalytic chemical vapor decomposition synthesis of carbon nanofibers (CNFs) on Ni-based catalyst. The CNFs were produced with a high yield at a relatively low temperature compared to that observed for conventional heating through convection and conduction. The process also occurred in the absence of secondary toxic organic compounds, formed through side reaction in the high temperature gas-phase or through decomposition on the hot wall of reactor as encountered with traditional Joule heating mode. The improved CNFs yield under induction heating was attributed to the high reaction temperature control thanks to the high temperature regulation rate provided by the induction heating coil. The local heating of the nickel nanoparticles by the electromagnetic field could also contribute to the improvement of the CNFs yield. The results obtained indicate that inductive heating mode could be of great interest for improving the heat transfer in catalytic processes and also to reduce the problem of gradient temperature occurring inside the catalyst bed during the operating of highly exothermic or endothermic processes. It is expected that such electricity-driven heating mode could have contributed in an efficient way toward the electrification of different catalytic processes in order to reduce the associated carbon footprint.
本文采用感应加热技术在镍基催化剂上催化化学气相分解合成了碳纳米纤维。与传统的对流和传导加热相比,CNFs在相对较低的温度下产生了较高的产率。该过程也发生在没有二次有毒有机化合物的情况下,在高温气相中通过副反应形成或在传统焦耳加热方式下在反应器热壁上分解。感应加热下CNFs产率的提高主要归功于感应加热线圈提供的高温度调节速率对反应温度的高控制。电磁场对纳米镍的局部加热也有助于CNFs产率的提高。研究结果表明,感应加热模式对于改善催化过程的传热和减少高放热或吸热过程中催化剂床层内温度梯度问题具有重要意义。预计这种电力驱动的加热模式可以有效地促进不同催化过程的电气化,以减少相关的碳足迹。
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引用次数: 0
Modified Agricultural Waste for Copper Ions Adsorption 改性农业废弃物对铜离子的吸附
Q2 Materials Science Pub Date : 2023-08-01 DOI: 10.37358/rc.23.3.8570
F. Abouzeid, Sultanah Alshammery
The present work represents potential bio-sorbents: Tilia cordata (little leaf linden) and Foeniculum vulgare (fennel). The copper removal was operated in batch procedure. Adsorbent mass, copper ion concentration, pH, time, and temperature considerations were inspected. The highly beneficial provisions for copper adsorption are 10 mg /L as preliminary concentration, 0.2 g as Tilia cordata and Foeniculum vulgare mass and pH 5.5 and 5.23 for Tilia cordata and Foeniculum vulgare. Adsorption statistics follow the Langmuir isotherm with qmax of 29.35 mg/g for Tilia cordata and 32.98 mg/g for Foeniculum vulgare. The removal procedure kinetics was provided perfectly via second-order equations. It was revealed that the copper ion adsorption procedure on mutual bio-sorbents is a spontaneous procedure, and is endothermal for Tilia cordata and Foeniculum vulgare. Characterization of Tilia cordata (little leaf linden) and Foeniculum (vulgare fennel) were inspected with a scanning electron microscope (SEM), Vis-IR Spectroscopy, GC-mass and milling cutter. A distinctive development in the adsorbent surface was exhibited through scanning electron microscope. The removal efficiency reached to 93.34 & 95.4 for Tilia (Tilia cordata) and Fennel (Foeniculum vulgare) respectively at 0.5 M bio-sorbent which indicated that Tilia (Tilia cordata) and Fennel (Foeniculum vulgare) has good renderability and stability.
本研究研究了潜在的生物吸附剂:小叶椴树和小茴香。铜的去除是分批进行的。考察了吸附剂质量、铜离子浓度、pH值、时间和温度等因素。初步浓度为10 mg /L,天麻和小叶质量浓度为0.2 g,天麻和小叶的pH分别为5.5和5.23,对铜的吸附效果非常好。吸附统计符合Langmuir等温线,天麻的qmax为29.35 mg/g,普通小叶的qmax为32.98 mg/g。通过二阶方程可以很好地描述脱除过程动力学。结果表明,铜离子在相互生物吸附剂上的吸附过程是自发的、吸热的。采用扫描电镜(SEM)、可见红外光谱(Vis-IR)、气相色谱质谱(GC-mass)和铣刀对小叶椴树(tila cordata)和小叶茴香(Foeniculum)进行了表征。通过扫描电镜观察,发现吸附剂表面有明显的发育。在0.5 M的生物吸附剂条件下,对天青和茴香的去除率分别达到93.34和95.4,说明天青和茴香具有良好的降解性和稳定性。
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引用次数: 0
Antioxidant Capacity Assays. Chemical and Cellular-based Methods 抗氧化能力测定。基于化学和细胞的方法
Q2 Materials Science Pub Date : 2023-08-01 DOI: 10.37358/rc.23.3.8569
A. Danet, M. Cheregi, S. Lițescu
The article is a continuation of the book chapter entitled Recent Advances in Antioxidant Capacity Assays published by IntechOpen in 2021. The various methods for determining antioxidant capacity in a variety of materials (plant extracts, biological material, foods, etc.) are discussed, with a special emphasis on articles published in recent years and especially on reviews. Both chemical methods for determining antioxidant capacity and cellular antioxidant capacity assays were presented. In addition to the review published in 2021, the following methods for the determination of antioxidant capacity were presented: crocin bleaching assay, Briggs-Rauscher reaction inhibition assay, ferricyanide-Prussian blue assay, cerric reducing antioxidant capacity assay and Anti Oxidant Power 1 (AOP1) assay. Several applications of the cellular antioxidant capacity assay were also presented in tabular form.
这篇文章是IntechOpen于2021年出版的《抗氧化能力测定的最新进展》一书的延续。讨论了测定各种材料(植物提取物、生物材料、食品等)抗氧化能力的各种方法,特别强调了近年来发表的文章,特别是综述。介绍了测定抗氧化能力和细胞抗氧化能力的化学方法。除了在2021年发表的综述外,还提出了以下测定抗氧化能力的方法:藏红花素漂白法、布里格斯-劳舍尔反应抑制法、铁氰化物-普鲁士蓝法、铈还原抗氧化能力法和抗氧化能力1 (AOP1)法。细胞抗氧化能力测定的几种应用也以表格形式提出。
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引用次数: 0
CONTENTS 3 / 2023 目录3 / 2023
Q2 Materials Science Pub Date : 2023-08-01 DOI: 10.37358/rc.23.3.8568
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引用次数: 0
ITSRepeats: Amino Acids Repeats and Composition Differences for Detecting Proteins Causing Bipolar Related Disorder ITSRepeats:用于检测引起双相相关障碍的蛋白质的氨基酸重复序列和组成差异
Q2 Materials Science Pub Date : 2023-01-01 DOI: 10.37358/rc.23.1.8561
M. Muthupandi, Vairamuthu Thangaraj
Bipolar disorder is a threat that needs an efficient solution to detect in earlier times for leading the normal life of human beings. Simple Sequence Editor (SSE) is the tool used to analyze the nucleotide and amino acid sequence that helps in this proposed system to detect the real composition. This paper proposed the algorithm called Intelligent Rule-based Triplet and Single Residue Repeats (ITSRepeats) in proteins to classify the protein sequence which causes bipolar related disorder or not. The hamming distance was used to find the similarity between the protein strings which increase the efficiency initially, the patterns of the proteins are extracted and analyzed from the datasets SwissProt, PDBS25, Surface Residues and DisProt. The performance of the proposed algorithms was evaluated based on the performance among these four datasets for similar residues.
双相情感障碍是一种威胁,为了人类的正常生活,需要尽早发现有效的解决方案。简单序列编辑器(SSE)是用于分析核苷酸和氨基酸序列的工具,有助于在该系统中检测实际组成。本文提出了一种基于智能规则的蛋白质三联体和单残基重复序列(ITSRepeats)算法,用于区分蛋白质序列是否引起双相情感障碍。利用hamming距离寻找蛋白质串之间的相似性,初步提高了效率,并从SwissProt、PDBS25、Surface残基和DisProt数据集中提取蛋白质的模式并进行分析。基于这四个数据集对相似残数的性能评估了所提出算法的性能。
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引用次数: 0
Electrical Analysis of Ceiba Pentandra Oil as a Replacement for Mineral Oil in High Voltage Insulation Application 木棉油替代矿物油在高压绝缘中的电性分析
Q2 Materials Science Pub Date : 2023-01-01 DOI: 10.37358/rc.23.1.8559
Arul Jose Johnsundarsingh, Sree Renga Raja Thangasa
The application of Ceiba Pentandra Oil is introduced as an alternative to the traditional non-biodegradable insulation oil. Through the recent research in vegetable based insulation oil (coconut oil, palm oil, and olive oil), it is identified that the vegetable insulation oil is biodegradable but edible in nature, which leads to the food crisis. To prevent the insufficiency of food, an interesting non-edible oil is extracted from the seeds of Ceiba Pentandra, which has the capability of biodegradation. This work has focused on the utilization of Ceiba Pentandra seeds for the production of vegetable based insulation oil since it is considered as the sustainable energy resource and. A two-step chemical conditioning method and antioxidants are used to produce the Processed Ceiba Pentandra oil (PCPO). Adding to that, the insulation behavior of Processed Ceiba Pentandra oil (PCPO) with and without antioxidant is analyzed. The different concentrations of PCPO and naphthalene based Mineral oil mixtures have been compared as per the ASTM standard. The two-step chemical conditioning method has provided the enhanced behavior of physical properties like Viscosity, Acidity, Flashpoint, Fire points and AC breakdown voltage. While improving the oxidation stability, the electrical property like AC Breakdown voltage has met the dielectric Standards. Thus this Processed Ceiba Pentandra oil (PCPO) has the potential to be an alternative of traditional insulation oil.
介绍了木棉油作为传统非生物降解保温油的替代品的应用。通过最近对植物基绝缘油(椰子油、棕榈油和橄榄油)的研究,发现植物基绝缘油是可生物降解的,但本质上是可食用的,这导致了粮食危机。为了防止食物不足,从Ceiba Pentandra种子中提取了一种有趣的非食用油,这种油具有生物降解能力。本研究重点是利用五角草种子生产植物基保温油,因为它被认为是一种可持续的能源。采用两步化学调理法和抗氧化剂生产加工木棉油(PCPO)。在此基础上,分析了加抗氧剂和不加抗氧剂的加工木棉油(PCPO)的保温性能。根据ASTM标准,对PCPO和萘基矿物油混合物的不同浓度进行了比较。两步化学调理方法提高了粘度、酸度、闪点、燃点和交流击穿电压等物理性能。在提高氧化稳定性的同时,其交流击穿电压等电性能达到了介电标准。因此,这种加工木棉油(PCPO)有可能成为传统保温油的替代品。
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引用次数: 0
Preparation and Modification of Graphite-based and Coal-based Graphene and its Tribological Properties in Lubricants 石墨基和煤基石墨烯的制备、改性及其在润滑油中的摩擦学性能
Q2 Materials Science Pub Date : 2023-01-01 DOI: 10.37358/rc.23.1.8563
Xu-wei Zhao, Kaibinuer Aierken, H. Maimaiti, Lirong Feng, Jianzhao Bao, Jin-yan Sun
Graphite-based graphene oxide (GO) and coal-based graphene oxide (GO/SiO2, which we call graphene oxide/SiO2 because the surface of the resulting coal-based GO is linked with SiO2 from the coal structure) were prepared by the conventional Hummers oxidation method and ultrasound-assisted Hummers oxidation method, respectively, using natural graphite powder and Xinjiang Wucaiwan coal as carbon sources. Furthermore, the structures of the two were studied comparatively. Afterwards, the two lamellar structure products were hydrophilically modified with octadecylamine and dicyclohexylcarbodiimide by a hydrothermal method. And then, added these products (graphite-based GO-ODA and coal-based GO/SiO2-ODA) to No.32 cycloalkyl base oils in order to comparatively investigated their tribological properties as lubricant additives. The results showed that the dispersion stability of coal-based GO/SiO2 in the lubricant was significantly better than that of graphite-based GO; meanwhile, the tribological performance of GO/SiO2-ODA in the lubricant better than that of graphite-based GO-ODA due to the surface linkage of coal-based GO/SiO2 with SiO2 particles. After 1 h - long grinding in a four-ball friction test, the lubricant friction coefficient of 0.03 wt% coal-based GO/SiO2-ODA oil reached a minimum of 0.118, which reduced 58.1% compared to pure base oil and reduced 2.8 times compared to the counterpart using graphite-based GO-ODA under the same experimental conditions.
以天然石墨粉和新疆五菜湾煤为碳源,分别采用常规Hummers氧化法和超声辅助Hummers氧化法制备了石墨基氧化石墨烯(GO)和煤基氧化石墨烯(GO/SiO2,我们称其为氧化石墨烯/SiO2,因为所得煤基氧化石墨烯表面与煤结构中的SiO2相连)。并对两者的结构进行了比较研究。然后用十八胺和双环己基碳二酰亚胺对两种层状结构产物进行水热改性。然后,将石墨基GO- oda和煤基GO/SiO2-ODA加入到32号环烷基基础油中,对比研究了它们作为润滑油添加剂的摩擦学性能。结果表明:煤基氧化石墨烯/二氧化硅在润滑油中的分散稳定性明显优于石墨基氧化石墨烯;同时,由于煤基氧化石墨烯/二氧化硅与SiO2颗粒的表面连接,氧化石墨烯/二氧化硅- oda在润滑油中的摩擦学性能优于石墨基氧化石墨烯- oda。经过1 h的四球磨擦试验,0.03 wt%煤基氧化石墨烯/SiO2-ODA油的润滑摩擦系数最小达到0.118,比纯基础油降低58.1%,比同等实验条件下石墨基氧化石墨烯- oda油降低2.8倍。
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引用次数: 0
Comprehensive Review of Magnetic Polymeric Nanocomposites with Superparamagnetic Iron Oxide Nanoparticles for Oil Removal from Water 超顺磁性氧化铁纳米磁性聚合物复合材料水中除油研究综述
Q2 Materials Science Pub Date : 2023-01-01 DOI: 10.37358/rc.23.1.8562
M. S. Mendes, Lorena Celeste De Souza Coutinho, Ayla Bastos Araujo, M. A. F. S. Neves, M. S. Pedrosa
Several oil spills in aquatic environments have been reported over the last few years, and a great effort has been made to develop new techniques for collecting and removing oil from water on a large scale to prevent environmental pollution by this contaminant. In view of the various problems involving traditional methods, such as the generation of secondary pollution, high costs and complexity of synthesizing material and expenses to transport equipment, among others, new technologies have been developed for removal of oil from water. Among these, the use of magnetic polymeric nano-composites has presented promising results, since they have high oil adsorption efficiency, ease of material removal through an external magnetic field, low cost of synthesis and possibility of reusing the material for several cycles, among others. However, a lack of studies about these promising systems exists regarding this technology and its procedures. Therefore, here we present a brief bibliographic review of the synthesis routes to obtain magnetic polymeric nanocomposites containing superpara-magnetic iron oxide nanoparticles developed for oil removal from water and report future trends and perspectives for progress of this technology.
在过去的几年中,水生环境中发生了几起石油泄漏事件,为了防止这种污染物对环境的污染,人们正在努力开发大规模从水中收集和去除石油的新技术。鉴于传统方法所涉及的各种问题,例如产生二次污染、合成材料的成本高和复杂以及运输设备的费用等,已经开发了从水中除油的新技术。其中,磁性高分子纳米复合材料具有高吸油效率、易于通过外磁场去除材料、合成成本低、材料可多次重复使用等优点,应用前景广阔。然而,缺乏对这些有前途的系统的研究存在关于该技术及其程序。因此,我们在此简要回顾了用于水中除油的磁性聚合物纳米复合材料的合成路线,并报告了该技术的未来发展趋势和前景。
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引用次数: 0
Reclamation of Aged Oil Using Physical-Chemical Method and Analysed Using ANFIS Algorithm 利用物化法回收老化油,并用ANFIS算法进行分析
Q2 Materials Science Pub Date : 2023-01-01 DOI: 10.37358/rc.23.1.8560
Godfrey Bhonz Manoharan, Sree Renga Raja Thangasamy
In this work, the transformer oil reclamation experimental test has been created utilising the physical-chemical reclamation technique and oil lifespan analysis using ANFIS algorithm. The significant of work is that it develops an ANFIS algorithm for estimating transformer life and analyzing transformer oil reliability. Rubber seed oil (mineral oil) is used in transformers to cool the substantial portion of the power transformer and decrease electrical ageing issues. These mineral oils interact chemically with the windings, suffering electrical and mechanical pressure owing to high temperatures over its power balance which leads to moisture and oxidation. In order to improve the performance of ageing oil, a physical and chemical reclamation approach with two primary steps, Coagulation and Adsorption, is used. Breakdown voltage, flash point, viscosity, and fire point are the important dielectric qualities of oil reclamation that will differentiate the performance between before and after reclamation when compared to diverse oil samples. The results of the work revealed that the physical-chemical reclamation process is enhanced the dielectric characteristics of the ageing oil, and the parameters of the reclaimed oil are utilised to predict the projected lifespan of the transformer service.
本文利用物化回收技术和ANFIS算法对变压器油进行寿命分析,建立了变压器油回收实验试验。本文的工作意义在于提出了一种用于变压器寿命估计和变压器油可靠性分析的ANFIS算法。橡胶籽油(矿物油)用于变压器冷却电力变压器的大部分,减少电气老化问题。这些矿物油与绕组发生化学反应,由于高温超过其功率平衡,导致潮湿和氧化,从而承受电气和机械压力。为了改善老化油的性能,采用了包括混凝和吸附两个主要步骤的物理化学回收方法。击穿电压、闪点、粘度和着火点是油料回收的重要介电特性,它将区分不同油样回收前后的性能差异。结果表明,物理化学回收工艺提高了老化油的介电特性,并利用回收油的参数来预测变压器的预计使用寿命。
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引用次数: 0
Transport of Particulate Matter Due to Meteorological Changes Analyzed by HYSPLIT 利用HYSPLIT分析气象变化引起的颗粒物输运
Q2 Materials Science Pub Date : 2022-10-31 DOI: 10.37358/rc.22.4.8542
M. Krishnan, Padmanabhan Krishnaswami, Muthu Ram Pazhani Selvam, Vinnarasi Anthony Dass, Ragu Thangavel, S. Subramanian
The air quality in the urban region varies based on the sources of air pollution from regions near and far. Any pollution produced in the urban region affects the locality near the pollution source and also adjacent distant regions. The study of the interaction between the local weather patterns of a region and the pollutants in the air is needed for air quality management. It is explicit that Chennai city has a high level of air pollution. But the unavailability of the relevant data on the air pollution sources makes the management difficult. If the data on air pollution in the region of Chennai is known, it will be helpful to provide control measures. Between January 2017 and December 2017, the particulate matter below the size of 2.5 micron (PM2.5) was assessed. It was quite concentrated in the metropolitan city of Chennai situated at the shores of the Bay of Bengal. This assessment is to study the transport phenomenon and expansion of the pollutant particles initially emanating from Chennai. This occurs mainly due to the westerly winds originating in the Bay of Bengal. The time duration of the analysis showed an average PM2.5 concentration of 63.524 � 18.942 �g/m3. This far exceeds the regulations of the World Health Organization (WHO). Various regions of the country as affected by different distant sources of pollution in and around Chennai were evaluated by the trajectory modeling. The pollution in the regions of the vicinity is assessed using the Hybrid Single-Particle Lagrangian Integrated Approach (HYSPLIT) software. The method and results are fruitful for similar estimates elsewhere.
城市地区的空气质量因空气污染源远近而异。城市地区产生的任何污染都会影响污染源附近的地区和邻近的遥远地区。空气质量管理需要研究一个地区的当地天气模式与空气中污染物之间的相互作用。很明显,金奈市的空气污染程度很高。但由于缺乏大气污染源的相关数据,给管理工作带来了困难。如果知道金奈地区的空气污染数据,将有助于提供控制措施。2017年1月至12月期间,对2.5微米以下的颗粒物(PM2.5)进行了评估。它相当集中在位于孟加拉湾海岸的大都市金奈。这次评价是为了研究最初从金奈发出的污染物颗粒的传输现象和扩展。这主要是由于源自孟加拉湾的西风。分析期间PM2.5平均浓度为63.524 ~ 18.942 μ g/m3。这远远超出了世界卫生组织(卫生组织)的规定。通过轨迹模型对金奈内外不同污染源对全国不同地区的影响进行了评估。采用混合单粒子拉格朗日积分法(HYSPLIT)软件对周边地区的污染进行了评价。这种方法和结果对其他地方类似的估计是有益的。
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引用次数: 0
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