Pub Date : 2024-03-23DOI: 10.1016/j.sedgeo.2024.106633
Xiaoqing Yuan , Qinhong Hu , Xianglong Fang , Qiming Wang , Yong Ma , Yukio Tachi
Archie's cementation factor, m, is a critical parameter for petrophysical studies, and the value is influenced by several factors such as the shape, type, and size of grains, degrees of diagenesis, and associated pore structure. Using integrated experimental and theoretical approaches, the goal of this study is to obtain the cementation factor of rocks (both reservoir rock and caprock) and assess the impact of diagenetic processes on the values of the cementation factor. Thirteen samples of geologically diverse rocks (six mudstones, four fossiliferous limestones, two marbles, and one sandstone) were selected to achieve these research objectives. Two approaches, the diffusion of gas tracers and the Bosanquet formula calculation using pore-throat sizes from mercury intrusion porosimetry analyses, were used to derive the cementation factors of these rock samples. These rocks were categorized into two groups based on the correlation between average pore-throat diameter and diffusivity, and an exponential-law relationship between the cementation factor and porosity was determined for these sample groups. In addition, thin-section petrography and field emission-scanning electron microscopy observations were utilized to investigate diagenetic processes, with four diagenetic patterns being established: (1) strong compaction, strong cementation, and weak dissolution-diagenesis pattern; (2) weak compaction, medium cementation, and weak dissolution-diagenesis pattern; (3) weak compaction, medium cementation, and strong dissolution-diagenesis pattern; and (4) fracture-matrix pattern. The results indicated that diagenetic processes and microfractures contribute to the variability in the cementation factors of these rock samples.
{"title":"Archie's cementation factors for natural rocks: Measurements and insights from diagenetic perspectives","authors":"Xiaoqing Yuan , Qinhong Hu , Xianglong Fang , Qiming Wang , Yong Ma , Yukio Tachi","doi":"10.1016/j.sedgeo.2024.106633","DOIUrl":"10.1016/j.sedgeo.2024.106633","url":null,"abstract":"<div><p>Archie's cementation factor, <em>m</em>, is a critical parameter for petrophysical studies, and the value is influenced by several factors such as the shape, type, and size of grains, degrees of diagenesis, and associated pore structure. Using integrated experimental and theoretical approaches, the goal of this study is to obtain the cementation factor of rocks (both reservoir rock and caprock) and assess the impact of diagenetic processes on the values of the cementation factor. Thirteen samples of geologically diverse rocks (six mudstones, four fossiliferous limestones, two marbles, and one sandstone) were selected to achieve these research objectives. Two approaches, the diffusion of gas tracers and the Bosanquet formula calculation using pore-throat sizes from mercury intrusion porosimetry analyses, were used to derive the cementation factors of these rock samples. These rocks were categorized into two groups based on the correlation between average pore-throat diameter and diffusivity, and an exponential-law relationship between the cementation factor and porosity was determined for these sample groups. In addition, thin-section petrography and field emission-scanning electron microscopy observations were utilized to investigate diagenetic processes, with four diagenetic patterns being established: (1) strong compaction, strong cementation, and weak dissolution-diagenesis pattern; (2) weak compaction, medium cementation, and weak dissolution-diagenesis pattern; (3) weak compaction, medium cementation, and strong dissolution-diagenesis pattern; and (4) fracture-matrix pattern. The results indicated that diagenetic processes and microfractures contribute to the variability in the cementation factors of these rock samples.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"465 ","pages":"Article 106633"},"PeriodicalIF":2.8,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140273371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-21DOI: 10.1016/j.sedgeo.2024.106632
Juan J. Kasper-Zubillaga , David M. Buchs , Duncan D. Muir , Lizeth Carlos-Delgado , Elsa Arellano-Torres , León Felipe Álvarez-Sánchez
Developing approaches to determine the modes of transport and weathering of mafic detrital minerals in natural sedimentary environments is critical to our understanding of sediment production, dispersal and provenance, as well as carbon capture under natural and enhanced weathering regimes. We integrated the characterisation of morphological and surface textures with the surface composition of recent detrital clinopyroxene grains concentrated in a sandy coastal area from the western North Island of New Zealand and a rocky shore area of Santa Maria Island in the Azores Archipelago. Using the compactness shape descriptor, 341 grains were subdivided into elongated, elongated angular, euhedral, angular and subangular groups, with each group further characterised using morphological and microtextural indicators of abrasion, breakage and dissolution/chemical weathering. In both studied environments, the clinopyroxenes are dominated by elongated to angular shapes with flat cleavage surfaces and conchoidal fractures. This is consistent with dominant subaqueous transport by rivers and longshore currents for New Zealand, and dominant wave action with limited sediment supply by rivers along the rocky shore of Santa Maria. More abundant subabraded and abraded shapes with bulbous and elongated depression microtextures are observed in New Zealand, which indicates additional effects by aeolian transport that are not seen in Santa Maria. Consistent with semi-quantitative EDS spot analyses that document fresh clinopyroxenes surfaces, chemical weathering textures are very rare to absent. In Santa Maria, sampling of recent beach sand was complemented by ∼125 kyr-old palaeobeach clinopyroxenes, but these yielded similar textural results without evidence for chemical weathering. However, the surface of these older clinopyroxenes includes small adhering smectite (typically <50 μm in width and a few μm in thickness) interpreted to reflect incipient cementation with buffering of acidic fluids by more reactive lithic fragments in the deposits. The lack of chemical weathering but pervasive evidence for mechanical breakage of clinopyroxenes indicate that, at the sand size, these minerals break faster than they dissolve due to frequent subaqueous and/or aeolian reworking in the studied high-energy environments and temperate climatic conditions.
{"title":"Physico-chemical alteration of pyroxene in coastal environments: Empirical constraints from New Zealand and the Azores","authors":"Juan J. Kasper-Zubillaga , David M. Buchs , Duncan D. Muir , Lizeth Carlos-Delgado , Elsa Arellano-Torres , León Felipe Álvarez-Sánchez","doi":"10.1016/j.sedgeo.2024.106632","DOIUrl":"10.1016/j.sedgeo.2024.106632","url":null,"abstract":"<div><p>Developing approaches to determine the modes of transport and weathering of mafic detrital minerals in natural sedimentary environments is critical to our understanding of sediment production, dispersal and provenance, as well as carbon capture under natural and enhanced weathering regimes. We integrated the characterisation of morphological and surface textures with the surface composition of recent detrital clinopyroxene grains concentrated in a sandy coastal area from the western North Island of New Zealand and a rocky shore area of Santa Maria Island in the Azores Archipelago. Using the compactness shape descriptor, 341 grains were subdivided into elongated, elongated angular, euhedral, angular and subangular groups, with each group further characterised using morphological and microtextural indicators of abrasion, breakage and dissolution/chemical weathering. In both studied environments, the clinopyroxenes are dominated by elongated to angular shapes with flat cleavage surfaces and conchoidal fractures. This is consistent with dominant subaqueous transport by rivers and longshore currents for New Zealand, and dominant wave action with limited sediment supply by rivers along the rocky shore of Santa Maria. More abundant subabraded and abraded shapes with bulbous and elongated depression microtextures are observed in New Zealand, which indicates additional effects by aeolian transport that are not seen in Santa Maria. Consistent with semi-quantitative EDS spot analyses that document fresh clinopyroxenes surfaces, chemical weathering textures are very rare to absent. In Santa Maria, sampling of recent beach sand was complemented by ∼125 kyr-old palaeobeach clinopyroxenes, but these yielded similar textural results without evidence for chemical weathering. However, the surface of these older clinopyroxenes includes small adhering smectite (typically <50 μm in width and a few μm in thickness) interpreted to reflect incipient cementation with buffering of acidic fluids by more reactive lithic fragments in the deposits. The lack of chemical weathering but pervasive evidence for mechanical breakage of clinopyroxenes indicate that, at the sand size, these minerals break faster than they dissolve due to frequent subaqueous and/or aeolian reworking in the studied high-energy environments and temperate climatic conditions.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"465 ","pages":"Article 106632"},"PeriodicalIF":2.8,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140274469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-20DOI: 10.1016/j.sedgeo.2024.106631
Josep Maria Salvany , Guillem Gisbert , Joan Martínez-Bofill
Thick gypsum‑carbonate sequences were deposited in different periods and basins of Europe during the westward opening of the Tethys Ocean. Although they seem to represent widespread perimarine sulphate-dominated lagoons in shallow epeiric platforms, the sedimentary characteristics and interpretation of these deposits are still poorly constrained. To advance in the knowledge of these deposits, a detailed study is presented of two distinctive sulphate dominated sequences of Late Triassic age located in NE Iberia (Western Europe), which correspond to the Canelles and Espinagosa units, found in the southern Pyrenees and the Catalan Coastal Ranges respectively. These sequences present a diverse suite of carbonate and sulphate lithofacies, which are stacked in several recurring sedimentary cycles. These cycles consistently present a carbonate base that transitions to a sulphate top, and can be correlated along several tens of kilometres. Each of the observed cycles depicts an initial sudden flooding of a tidal-lagoon system by marine water, which led to carbonate-dominated sedimentation. Progressive evaporation under dominant arid climate conditions triggered the shallowing of the lagoon and salinisation of its water. Then, a transition from carbonate to gypsum/anhydrite precipitation and the early dolomitisation of the underlying carbonate sediments by brine reflux occurred. Gypsum precipitated in the water column as cumulate crystals and deposited at the bottom of the lagoon, forming laminations or being incorporated into microbial mats. Anhydrite precipitated as early diagenetic crystals in the different subaqueous and subaerial environments of the tidal-lagoon system, leading to a variated set of lithofacies until now largely undocumented. It mainly formed as displacive lath-shaped crystals randomly oriented within carbonate muds at the bottom of the lagoon, which were mostly reworked at the lagoon margins by wave and tidal currents resulting in aligned fabrics in cross-lamination structures. Anhydrite also formed as pure massive beds by anhydritisation of subaerially exposed gypsum sediments during the main retraction stages of the lagoon, as well as typical nodular (sabkha) lithofacies. Such sulphate lithofacies are not easy recognisable due to the lack of modern analogues to compare and to their current transformation into secondary gypsum in the outcrops. These are aspects to be taken into account in future sedimentological studies on similar evaporitic materials.
{"title":"Lithofacies and cyclicity of sulphate dominated tidal-lagoon deposits of Late Triassic age in Northeast Iberia (western Europe)","authors":"Josep Maria Salvany , Guillem Gisbert , Joan Martínez-Bofill","doi":"10.1016/j.sedgeo.2024.106631","DOIUrl":"10.1016/j.sedgeo.2024.106631","url":null,"abstract":"<div><p>Thick gypsum‑carbonate sequences were deposited in different periods and basins of Europe during the westward opening of the Tethys Ocean. Although they seem to represent widespread perimarine sulphate-dominated lagoons in shallow epeiric platforms, the sedimentary characteristics and interpretation of these deposits are still poorly constrained. To advance in the knowledge of these deposits, a detailed study is presented of two distinctive sulphate dominated sequences of Late Triassic age located in NE Iberia (Western Europe), which correspond to the Canelles and Espinagosa units, found in the southern Pyrenees and the Catalan Coastal Ranges respectively. These sequences present a diverse suite of carbonate and sulphate lithofacies, which are stacked in several recurring sedimentary cycles. These cycles consistently present a carbonate base that transitions to a sulphate top, and can be correlated along several tens of kilometres. Each of the observed cycles depicts an initial sudden flooding of a tidal-lagoon system by marine water, which led to carbonate-dominated sedimentation. Progressive evaporation under dominant arid climate conditions triggered the shallowing of the lagoon and salinisation of its water. Then, a transition from carbonate to gypsum/anhydrite precipitation and the early dolomitisation of the underlying carbonate sediments by brine reflux occurred. Gypsum precipitated in the water column as cumulate crystals and deposited at the bottom of the lagoon, forming laminations or being incorporated into microbial mats. Anhydrite precipitated as early diagenetic crystals in the different subaqueous and subaerial environments of the tidal-lagoon system, leading to a variated set of lithofacies until now largely undocumented. It mainly formed as displacive lath-shaped crystals randomly oriented within carbonate muds at the bottom of the lagoon, which were mostly reworked at the lagoon margins by wave and tidal currents resulting in aligned fabrics in cross-lamination structures. Anhydrite also formed as pure massive beds by anhydritisation of subaerially exposed gypsum sediments during the main retraction stages of the lagoon, as well as typical nodular (sabkha) lithofacies. Such sulphate lithofacies are not easy recognisable due to the lack of modern analogues to compare and to their current transformation into secondary gypsum in the outcrops. These are aspects to be taken into account in future sedimentological studies on similar evaporitic materials.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106631"},"PeriodicalIF":2.8,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140280800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-16DOI: 10.1016/j.sedgeo.2024.106630
Ran Ge , Zheng Gong , Qian Feng , Suna Wang , Chuang Jin , Jiaxin Wei
Biofilm surrounding sediment particles can significantly enhance the stability of coastal sediment. This phenomenon is known as biostabilization. Biofilm mainly consists of extracellular polymeric substances (EPS) and microorganisms. While the role of EPS in biostabilization is well-established, microbial contribution requires further exploration. Herein, an experiment was conducted to compare the stability and morphological characteristics of sediment under the effects of biofilm (with microorganisms) and pure EPS extracted from the biofilm (without microorganisms). The microorganisms used for biofilm culture are composed of diatoms and chlorella. The sediment used is a mixture of well-sorted muddy sand (D50 = 77 μm). Erosion tests showed that in the early stage of biofilm culture (within 17 days), biofilm and pure EPS had a similar ability to stabilize sediment, suggesting that in this stage, biofilm stabilized sediment relying on EPS. However, after 17 days of culture, biofilm showed a stronger ability to stabilize sediment than pure EPS, implying that in this stage, biofilm stabilized sediment by both EPS and microorganisms. These results indicate that microorganisms can also contribute to biostabilization, but during the early stage of culture, microorganisms in biofilm cannot make such contributions. Optical observations found that when the sediment-stabilizing ability of biofilm and pure EPS was comparable, the morphological characteristics of sediment particles under the effects of them were similar, both appearing as scattered single particles. However, when biofilm exhibited a stronger sediment-stabilizing ability, sediment particles with biofilm connected into large-size aggregates, whereas sediment particles with pure EPS remained single and scattered. These results suggest that in the later stage of biofilm culture, microorganisms play a role in the aggregation of sediment particles and hence contribute to biostabilization. Based on these findings, a conceptual framework has been proposed for predicting sediment stability under the effects of biofilm.
{"title":"Particle aggregation induced by microorganisms is a key mechanism for the biostabilization of coastal sediment","authors":"Ran Ge , Zheng Gong , Qian Feng , Suna Wang , Chuang Jin , Jiaxin Wei","doi":"10.1016/j.sedgeo.2024.106630","DOIUrl":"10.1016/j.sedgeo.2024.106630","url":null,"abstract":"<div><p>Biofilm surrounding sediment particles can significantly enhance the stability of coastal sediment. This phenomenon is known as biostabilization. Biofilm mainly consists of extracellular polymeric substances (EPS) and microorganisms. While the role of EPS in biostabilization is well-established, microbial contribution requires further exploration. Herein, an experiment was conducted to compare the stability and morphological characteristics of sediment under the effects of biofilm (with microorganisms) and pure EPS extracted from the biofilm (without microorganisms). The microorganisms used for biofilm culture are composed of diatoms and chlorella. The sediment used is a mixture of well-sorted muddy sand (D<sub>50</sub> = 77 μm). Erosion tests showed that in the early stage of biofilm culture (within 17 days), biofilm and pure EPS had a similar ability to stabilize sediment, suggesting that in this stage, biofilm stabilized sediment relying on EPS. However, after 17 days of culture, biofilm showed a stronger ability to stabilize sediment than pure EPS, implying that in this stage, biofilm stabilized sediment by both EPS and microorganisms. These results indicate that microorganisms can also contribute to biostabilization, but during the early stage of culture, microorganisms in biofilm cannot make such contributions. Optical observations found that when the sediment-stabilizing ability of biofilm and pure EPS was comparable, the morphological characteristics of sediment particles under the effects of them were similar, both appearing as scattered single particles. However, when biofilm exhibited a stronger sediment-stabilizing ability, sediment particles with biofilm connected into large-size aggregates, whereas sediment particles with pure EPS remained single and scattered. These results suggest that in the later stage of biofilm culture, microorganisms play a role in the aggregation of sediment particles and hence contribute to biostabilization. Based on these findings, a conceptual framework has been proposed for predicting sediment stability under the effects of biofilm.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106630"},"PeriodicalIF":2.8,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140203357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-15DOI: 10.1016/j.sedgeo.2024.106628
Wenjun Kang , Shunli Li , Xin Shan , Chengpeng Tan
The formation of vertical sedimentary succession of a delta in the arid and semi-arid basin-margin progradation dramatically depends on the variation of sediment flux and accommodation, but the discontiguous record of signals tends to exist enormously variable, which renders the bulk record of microfacies difficult to quantify from the vertical sedimentary succession. We analyzed the 18 vertical sedimentary successions collected from 18 field trenches of a lake delta by the cusp-catastrophe model, allowing detailed mapping of microfacies. The present detailed study indicates the suitability of cusp-catastrophe theory for explaining vertical sedimentary succession in the BWH (Bawanghe) delta. Three equilibrium states of processes responsible for the deposition of the BWH delta's evolution were established: sandy-dominated upper leaves primarily exhibit the delta plain; sandy/muddy-dominated lower leaves present the delta plain and pro-delta; and sandy-dominated middle leaves which commonly developed the delta front. The result of analysis shows that the reliability of the cusp-catastrophe model to identity mutation of vertical sedimentary succession exceeds 50 %, and to identity microfacies transitions with a precipitation periodicity exceeds 70 %. These cognitions support the previous view that changing precipitation results in an abrupt change in margin progradation. Simultaneously, the study gives new insights into the microfacies quantification of lake deltas and reveals the influence of crest value changes of precipitation on vertical sedimentary succession can be understood from the dependence of microfacies distribution on the change of sediment flux and accommodation.
{"title":"Semi-quantifying vertical sedimentary succession and microfacies characterization from a delta system in a lacustrine basin, Huangqihai Lake, North China","authors":"Wenjun Kang , Shunli Li , Xin Shan , Chengpeng Tan","doi":"10.1016/j.sedgeo.2024.106628","DOIUrl":"10.1016/j.sedgeo.2024.106628","url":null,"abstract":"<div><p>The formation of vertical sedimentary succession of a delta in the arid and semi-arid basin-margin progradation dramatically depends on the variation of sediment flux and accommodation, but the discontiguous record of signals tends to exist enormously variable, which renders the bulk record of microfacies difficult to quantify from the vertical sedimentary succession. We analyzed the 18 vertical sedimentary successions collected from 18 field trenches of a lake delta by the cusp-catastrophe model, allowing detailed mapping of microfacies. The present detailed study indicates the suitability of cusp-catastrophe theory for explaining vertical sedimentary succession in the BWH (Bawanghe) delta. Three equilibrium states of processes responsible for the deposition of the BWH delta's evolution were established: sandy-dominated upper leaves primarily exhibit the delta plain; sandy/muddy-dominated lower leaves present the delta plain and pro-delta; and sandy-dominated middle leaves which commonly developed the delta front. The result of analysis shows that the reliability of the cusp-catastrophe model to identity mutation of vertical sedimentary succession exceeds 50 %, and to identity microfacies transitions with a precipitation periodicity exceeds 70 %. These cognitions support the previous view that changing precipitation results in an abrupt change in margin progradation. Simultaneously, the study gives new insights into the microfacies quantification of lake deltas and reveals the influence of crest value changes of precipitation on vertical sedimentary succession can be understood from the dependence of microfacies distribution on the change of sediment flux and accommodation.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"465 ","pages":"Article 106628"},"PeriodicalIF":2.8,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140203405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-14DOI: 10.1016/j.sedgeo.2024.106629
Lin Wang , Qiqi Lyu , Linhan Li , Jun Liu , Shunshe Luo , Xuehu Sun , Lei Zhang , Xinshou Xu
This study investigates the transport and evolution of fine-grained gravity-flow deposits in lacustrine basins, focusing on the relationship between fine-grained deposits and their respective source–reservoir combinations. Such knowledge is vital for the exploration and development of unconventional oil and gas resources within the source-rock series of continental lake basins in China. We investigated the fine-grained gravity-flow deposits of the Late Triassic Chang73 Sub-member within the Yanchang Formation in the Ordos Basin. Our approach combined core observations, field outcrop evaluations, thin section analysis, scanning electron microscopy, geochemical data, and laboratory measurements. The sedimentary facies, characteristics, controlling factors, and sedimentary model of the fine-grained gravity-flow deposits are investigated. The primary sources of fine-grained sediments are terrestrial clastic and volcanic–hydrothermal fine-grained sediments. These sediments are mainly developed in warm, humid environments with abundant precipitation, favoring a highly reducible hypoxic terrestrial brackish–freshwater environment. Ten lithofacies and eight bed types of fine-grained gravity-flow deposits are categorized. Bed types represent deposits of muddy slide deposits, muddy slump deposits, muddy debris flow deposits, muddy flow deposits, hybrid event beds, fine-grained transitional flow deposits, surge-like turbidity flow deposits, and fine-grained hyperpycnal flow deposits. As a result of paleo-seismicity, volcanic events, and paleogeomorphology, instability and subsequent collapse of the delta front sediments led to the formation of gravity-flow deposits. These deposits formed the “channel–lobe complex” and “sublacustrine fan” sedimentary systems in both the southwestern and northeastern parts of the basin, respectively. Meanwhile, extraordinary flood events formed during the Carnian Pluvial Episode (CPE) played a significant role. It prompted increased fluvial drainage that drove fine-grained hyperpycnal flows through pre-existing valley systems, resulting in the establishment of the “channel–lobe complex” sedimentary system. The Chang 73 Sub-member contains high-quality hydrocarbon source rocks, laying the foundation for shale oil. The introduction of volcanic ash and the influence of hydrothermal activities amplify the enrichment of organic matter within the lacustrine basin. Fine-grained gravity-flow deposits yield siltstone-rich sweet intervals, primarily seen in surge-like turbidity and hyperpycnal flows. The interbedding of sandy and muddy sediments, influenced by hybrid event beds and fine-grained transitional flows, establishes a stratigraphic arrangement in which the upper layer nourishes the underlying reservoir. This structure is particularly beneficial for the development of shale oil and gas sweet intervals.
{"title":"Sedimentary characteristics of mixed source fine-grained gravity-flow and its significance for shale oil exploration in a lacustrine depression basin: A case study of the Chang 73 Sub-member of the Triassic Yanchang Formation in Ordos Basin, NW China","authors":"Lin Wang , Qiqi Lyu , Linhan Li , Jun Liu , Shunshe Luo , Xuehu Sun , Lei Zhang , Xinshou Xu","doi":"10.1016/j.sedgeo.2024.106629","DOIUrl":"10.1016/j.sedgeo.2024.106629","url":null,"abstract":"<div><p>This study investigates the transport and evolution of fine-grained gravity-flow deposits in lacustrine basins, focusing on the relationship between fine-grained deposits and their respective source–reservoir combinations. Such knowledge is vital for the exploration and development of unconventional oil and gas resources within the source-rock series of continental lake basins in China. We investigated the fine-grained gravity-flow deposits of the Late Triassic Chang7<sub>3</sub> Sub-member within the Yanchang Formation in the Ordos Basin. Our approach combined core observations, field outcrop evaluations, thin section analysis, scanning electron microscopy, geochemical data, and laboratory measurements. The sedimentary facies, characteristics, controlling factors, and sedimentary model of the fine-grained gravity-flow deposits are investigated. The primary sources of fine-grained sediments are terrestrial clastic and volcanic–hydrothermal fine-grained sediments. These sediments are mainly developed in warm, humid environments with abundant precipitation, favoring a highly reducible hypoxic terrestrial brackish–freshwater environment. Ten lithofacies and eight bed types of fine-grained gravity-flow deposits are categorized. Bed types represent deposits of muddy slide deposits, muddy slump deposits, muddy debris flow deposits, muddy flow deposits, hybrid event beds, fine-grained transitional flow deposits, surge-like turbidity flow deposits, and fine-grained hyperpycnal flow deposits. As a result of paleo-seismicity, volcanic events, and paleogeomorphology, instability and subsequent collapse of the delta front sediments led to the formation of gravity-flow deposits. These deposits formed the “channel–lobe complex” and “sublacustrine fan” sedimentary systems in both the southwestern and northeastern parts of the basin, respectively. Meanwhile, extraordinary flood events formed during the Carnian Pluvial Episode (CPE) played a significant role. It prompted increased fluvial drainage that drove fine-grained hyperpycnal flows through pre-existing valley systems, resulting in the establishment of the “channel–lobe complex” sedimentary system. The Chang 7<sub>3</sub> Sub-member contains high-quality hydrocarbon source rocks, laying the foundation for shale oil. The introduction of volcanic ash and the influence of hydrothermal activities amplify the enrichment of organic matter within the lacustrine basin. Fine-grained gravity-flow deposits yield siltstone-rich sweet intervals, primarily seen in surge-like turbidity and hyperpycnal flows. The interbedding of sandy and muddy sediments, influenced by hybrid event beds and fine-grained transitional flows, establishes a stratigraphic arrangement in which the upper layer nourishes the underlying reservoir. This structure is particularly beneficial for the development of shale oil and gas sweet intervals.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106629"},"PeriodicalIF":2.8,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-11DOI: 10.1016/j.sedgeo.2024.106620
R. Gastineau , F.S. Anselmetti , S.C. Fabbri , P. Sabatier , P. Roeser , S. Gündüz , M. Şahin , E. Duarte , W. Rapuc , A.C. Gebhardt , S.O. Franz , F. Niessen , J. de Sigoyer
Our study aims to understand the palaeohydrological history of Lake Iznik and unravel the complex interplay between climatic, tectonic, and environmental factors that have shaped this Turkish basin. Through the analysis of seismic stratigraphy and sediment cores, we reveal a significant lowstand, indicating a lake level 60 m lower than today at ∼70 ka BP. Subsequently, a major phase of stepwise transgression is evidenced by 13 buried palaeoshorelines between ∼70 and 45 ka BP. From 45 to ∼10 ka cal BP, strong currents controlled the sedimentation in the lake, as evidenced by the occurrence of contourite drifts. Between ∼14 and 10 ka cal. BP, a major lowstand indicating a drier climate interrupted the current-controlled sedimentation regime. From ∼10 ka cal. BP, the subsequent increase in lake level occurred at the same time as the reconnection between the Mediterranean and Black seas. Archaeological evidence, including submerged structures of a basilica, establishes a link between lake-level changes and human settlement during the last millennium. The level of Lake Iznik has since continued to fluctuate due to climate change, tectonic events, and human activity.
我们的研究旨在了解伊兹尼克湖的古水文历史,并揭示塑造这一土耳其盆地的气候、构造和环境因素之间复杂的相互作用。通过对地震地层学和沉积物岩心的分析,我们发现了一个显著的低洼地带,表明公元前约 70 千年时的湖面比现在低 60 米。随后,在公元前约 70-45 ka 之间,13 条被掩埋的古海岸线证明了一个重要的阶梯式横切阶段。在大约公元前 45 至 10 ka ka 期间,强大的水流控制着湖泊的沉积,等高线漂移的出现就是证明。在约 14-10 ka cal.公元前约 14-10 ka. BP 期间,一个表明气候较干燥的大低潮打断了由水流控制的沉积机制。从约 10 ka cal.公元前约 10 ka. BP 开始,在地中海与黑海重新连接的同时,湖泊水位随之上升。考古证据,包括一座大教堂的水下结构,证明了湖面变化与上一个千年人类定居之间的联系。此后,伊兹尼克湖的水位因气候变化、构造事件和人类活动而持续波动。
{"title":"Seismic stratigraphy and sediment cores reveal lake-level fluctuations in Lake Iznik (NW Turkey) over the past ∼70 ka","authors":"R. Gastineau , F.S. Anselmetti , S.C. Fabbri , P. Sabatier , P. Roeser , S. Gündüz , M. Şahin , E. Duarte , W. Rapuc , A.C. Gebhardt , S.O. Franz , F. Niessen , J. de Sigoyer","doi":"10.1016/j.sedgeo.2024.106620","DOIUrl":"10.1016/j.sedgeo.2024.106620","url":null,"abstract":"<div><p>Our study aims to understand the palaeohydrological history of Lake Iznik and unravel the complex interplay between climatic, tectonic, and environmental factors that have shaped this Turkish basin. Through the analysis of seismic stratigraphy and sediment cores, we reveal a significant lowstand, indicating a lake level 60 m lower than today at ∼70 ka BP. Subsequently, a major phase of stepwise transgression is evidenced by 13 buried palaeoshorelines between ∼70 and 45 ka BP. From 45 to ∼10 ka cal BP, strong currents controlled the sedimentation in the lake, as evidenced by the occurrence of contourite drifts. Between ∼14 and 10 ka cal. BP, a major lowstand indicating a drier climate interrupted the current-controlled sedimentation regime. From ∼10 ka cal. BP, the subsequent increase in lake level occurred at the same time as the reconnection between the Mediterranean and Black seas. Archaeological evidence, including submerged structures of a basilica, establishes a link between lake-level changes and human settlement during the last millennium. The level of Lake Iznik has since continued to fluctuate due to climate change, tectonic events, and human activity.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106620"},"PeriodicalIF":2.8,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0037073824000435/pdfft?md5=6ac13479671ff5964fe62c3180b262b3&pid=1-s2.0-S0037073824000435-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-11DOI: 10.1016/j.sedgeo.2024.106621
Binsong Zheng , Chuanlong Mou , Yuanchong Wang
Redox conditions and primary productivity are proposed to be the major controls of organic matter accumulation in sediments. Studies of the impacts of tectonic processes on organic matter accumulation are still limited. We took the Late Permian-Early Triassic Western Hubei Basin, located in the north of South China, as an example. In black shales in the Dalong Formation, bottom-water redox conditions and surface-water productivity are constrained as shown by the analysis of total organic carbon (TOC) as well as geochemical (enrichment of Mo, U, Ni, Cd and Zn) and mineralogical characteristics. The highest productivity is present in the lower Dalong Formation, and the most intensively anoxic and restricted conditions are found in the middle Dalong Formation. The correlation of the sedimentary successions on the two sides of the basin's boundary fault indicates a subsidence of the basement during the deposition of the lower-middle Dalong Formation, followed by an uplift during the deposition of the upper Dalong Formation. When looked at in conjunction with the tectonic background of the basin, the new data in the present study support that: (1) the collision of the South and North China plates controlled the paleoceanographic and hydrographic evolution of the Western Hubei Basin, as well as organic matter accumulation in sediments; (2) upwelling-induced high productivity and good preservation in an anoxic environment jointly contributed to organic matter enrichment in the lower Dalong Formation, while good preservation in an anoxic environment was the major cause of organic matter enrichment in the middle-upper Dalong Formation. This study indicates that tectonism can act as the ultimate drive mechanism for organic matter accumulation in black shales. Our data also suggest that plate tectonism in related to the assembly of East Asian blocks with the main body of Pangea can also be treated as one of the ultimate drive mechanisms of the end-Permian mass extinction as it created the restricted, anoxic Paleo-Tethys Ocean, which greatly disturbed- global seawater circulation.
{"title":"Organic matter accumulation in response to tectonism: New data from the Upper Permian Dalong Formation black shales in the Western Hubei Basin, South China and its implications for the end-Permian mass extinction","authors":"Binsong Zheng , Chuanlong Mou , Yuanchong Wang","doi":"10.1016/j.sedgeo.2024.106621","DOIUrl":"10.1016/j.sedgeo.2024.106621","url":null,"abstract":"<div><p>Redox conditions and primary productivity are proposed to be the major controls of organic matter accumulation in sediments. Studies of the impacts of tectonic processes on organic matter accumulation are still limited. We took the Late Permian-Early Triassic Western Hubei Basin, located in the north of South China, as an example. In black shales in the Dalong Formation, bottom-water redox conditions and surface-water productivity are constrained as shown by the analysis of total organic carbon (TOC) as well as geochemical (enrichment of Mo, U, Ni, Cd and Zn) and mineralogical characteristics. The highest productivity is present in the lower Dalong Formation, and the most intensively anoxic and restricted conditions are found in the middle Dalong Formation. The correlation of the sedimentary successions on the two sides of the basin's boundary fault indicates a subsidence of the basement during the deposition of the lower-middle Dalong Formation, followed by an uplift during the deposition of the upper Dalong Formation. When looked at in conjunction with the tectonic background of the basin, the new data in the present study support that: (1) the collision of the South and North China plates controlled the paleoceanographic and hydrographic evolution of the Western Hubei Basin, as well as organic matter accumulation in sediments; (2) upwelling-induced high productivity and good preservation in an anoxic environment jointly contributed to organic matter enrichment in the lower Dalong Formation, while good preservation in an anoxic environment was the major cause of organic matter enrichment in the middle-upper Dalong Formation. This study indicates that tectonism can act as the ultimate drive mechanism for organic matter accumulation in black shales. Our data also suggest that plate tectonism in related to the assembly of East Asian blocks with the main body of Pangea can also be treated as one of the ultimate drive mechanisms of the end-Permian mass extinction as it created the restricted, anoxic Paleo-Tethys Ocean, which greatly disturbed- global seawater circulation.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106621"},"PeriodicalIF":2.8,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-08DOI: 10.1016/j.sedgeo.2024.106619
Manuel Martín-Martín , Francesco Guerrera , Juan Carlos Cañaveras , Francisco Javier Alcalá , Francisco Serrano , Alí Maaté , Rachid Hlila , Soufian Maaté , Antonio Sánchez-Navas , Crina Miclăus , José Enrique Tent-Manclús , Manuel Bullejos
The Miocene evolution of the External Rif Zone (NW Africa Plate) was determined through multidisciplinary analysis of fourteen successions. The updated stratigraphic framework shows how Miocene sediments rest on the Cretaceous–Paleogene terrains through unconformity surfaces, whereas it rests with sedimentary continuity in two sectors. After recognition of lithofacies and three unconformities located near the Oligocene–Aquitanian, Aquitanian–Burdigalian and Serravallian–Tortonian boundaries, the Miocene sedimentary record was divided into three stratigraphic intervals representing deep to shallow marine deposits as Aquitanian–Burdigalian, Langhian and Upper Serravallian–Missinian. The two oldest unconformites are restricted to the central sector, while the upper one is generalized and probably related to the nappe tectonics registered in all sectors of the External Rif. Data from analysis of tectofacies, petrology, mineralogy, meaning and implications of unconformities, and subsidence indicate that: (i) mass flow deposits (turbidites, slumps, olistostromes) are common in all successions but more frequent during the Lower Miocene; (ii) petrology of the detrital components of the arenites indicates recycled orogen-derived sediments, with quartz coming from erosion of metamorphic rocks of the Atlas orogen and/or the African craton; (iii) mineralogy of mudstones suggests a complex erosional evolution of local emerged areas derived from a mixture of contributions coming from the erosion of Upper Jurassic to Paleogene suites, and especially from kaolinite-rich Albian–Cenomanian to Paleogene successions with absence of a clear unroofing. The conjunction of all these clues reinforces the idea of a synsedimentary tectonics affecting the margin/basin system during the Miocene. A thickness analysis of the studied sedimentary successions allows proposing the evolution of the orogenic front and main depozones (foredeep, bulges, wedge-top and intramontane sub-basins) integrated in a complex foreland system migrating from north to south with the Atlas-Mesetas area acting as foreland during Miocene. The orogenic front moved from the Internal Intrarif to Mesorif and later to Internal Prerif. The main wedge-top basin also migrated from the Internal Intrarif to External Intrarif. The foredeep migrated from the Mesorif to the Internal Prerif, while the main forebulge was located in the External Prerif and a secondary bulge developed in the External Intrarif. Intramontane basins developed behind the orogenic front in relative extensional conditions moving from the Internal Intrarif to External Intrarif. The reconstructed Miocene evolution was inserted into a 2D paleogeographic-geodynamic evolutionary model using GPlates software, and then compared to those reported in other external margins of the western Tethys (Betic Chain, Tunisian Tell, Sicilian Maghrebids and Apennines), revealing important similarities and local differences.
{"title":"Miocene evolution of the External Rif Zone (Morocco): Comparison with similar and lateral southern Mediterranean Tethyan margins","authors":"Manuel Martín-Martín , Francesco Guerrera , Juan Carlos Cañaveras , Francisco Javier Alcalá , Francisco Serrano , Alí Maaté , Rachid Hlila , Soufian Maaté , Antonio Sánchez-Navas , Crina Miclăus , José Enrique Tent-Manclús , Manuel Bullejos","doi":"10.1016/j.sedgeo.2024.106619","DOIUrl":"10.1016/j.sedgeo.2024.106619","url":null,"abstract":"<div><p>The Miocene evolution of the External Rif Zone (NW Africa Plate) was determined through multidisciplinary analysis of fourteen successions. The updated stratigraphic framework shows how Miocene sediments rest on the Cretaceous–Paleogene terrains through unconformity surfaces, whereas it rests with sedimentary continuity in two sectors. After recognition of lithofacies and three unconformities located near the Oligocene–Aquitanian, Aquitanian–Burdigalian and Serravallian–Tortonian boundaries, the Miocene sedimentary record was divided into three stratigraphic intervals representing deep to shallow marine deposits as Aquitanian–Burdigalian, Langhian and Upper Serravallian–Missinian. The two oldest unconformites are restricted to the central sector, while the upper one is generalized and probably related to the nappe tectonics registered in all sectors of the External Rif. Data from analysis of tectofacies, petrology, mineralogy, meaning and implications of unconformities, and subsidence indicate that: (i) mass flow deposits (turbidites, slumps, olistostromes) are common in all successions but more frequent during the Lower Miocene; (ii) petrology of the detrital components of the arenites indicates recycled orogen-derived sediments, with quartz coming from erosion of metamorphic rocks of the Atlas orogen and/or the African craton; (iii) mineralogy of mudstones suggests a complex erosional evolution of local emerged areas derived from a mixture of contributions coming from the erosion of Upper Jurassic to Paleogene suites, and especially from kaolinite-rich Albian–Cenomanian to Paleogene successions with absence of a clear unroofing. The conjunction of all these clues reinforces the idea of a synsedimentary tectonics affecting the margin/basin system during the Miocene. A thickness analysis of the studied sedimentary successions allows proposing the evolution of the orogenic front and main depozones (foredeep, bulges, wedge-top and intramontane sub-basins) integrated in a complex foreland system migrating from north to south with the Atlas-Mesetas area acting as foreland during Miocene. The orogenic front moved from the Internal Intrarif to Mesorif and later to Internal Prerif. The main wedge-top basin also migrated from the Internal Intrarif to External Intrarif. The foredeep migrated from the Mesorif to the Internal Prerif, while the main forebulge was located in the External Prerif and a secondary bulge developed in the External Intrarif. Intramontane basins developed behind the orogenic front in relative extensional conditions moving from the Internal Intrarif to External Intrarif. The reconstructed Miocene evolution was inserted into a 2D paleogeographic-geodynamic evolutionary model using GPlates software, and then compared to those reported in other external margins of the western Tethys (Betic Chain, Tunisian Tell, Sicilian Maghrebids and Apennines), revealing important similarities and local differences.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106619"},"PeriodicalIF":2.8,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0037073824000423/pdfft?md5=65ab078ed4a2b5355c926450241ad888&pid=1-s2.0-S0037073824000423-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-06DOI: 10.1016/j.sedgeo.2024.106618
Yaxian You , Huaguo Wen , Lianchao Luo , Kathleen A. Campbell , Diego M. Guido , Enrico Capezzuoli , Zhipeng Lu , Lei Du , Yunbao Yang
<div><p>Phanerozoic sinter deposits have been reported globally, with their identification mainly based on sedimentological, petrological, and mineralogical studies. In this study, a detailed geochemical investigation, combined with sedimentological characterization, was conducted on the Wugonglilu siliceous deposit, a Cretaceous (106 Ma) sinter in NE China, to examine its genesis. The deposit is inferred as a siliceous hot spring deposit (sinter) owing to its geological setting in an epithermal gold-mining district, its morphologically variable microbial textures typical of subaerial sinters, and nearly pure silica composition. Three lithofacies were recognized in this study, including laminated to thinly bedded sinter, silica-cemented breccia, and epithermal vein, which represent deposits from three contrasting hydrothermal environments. The <sup>87</sup>Sr/<sup>86</sup>Sr ratios of the sinter are similar to the bedrock through which the geothermal fluids passed, namely the Upper Triassic Dajiahe Formation (T<sub>3</sub>dj), a marine siliceous rock unit, and the Lower Cretaceous Datashanlinchang Formation (K<sub>1</sub>d), a rhyolite unit. Results indicate that both underlying units are possible Sr sources of the silica in the Wugonglilu sinter. The REE + Y (rare-earth elements and yttrium) patterns of the sinter exhibit significant variability, primarily due to terrestrial detrital contamination. Differential REE + Y contamination by terrestrial detritus was striking in the white and dark laminae/beds of the laminated to thinly bedded sinter. The white laminae/beds, generally less contaminated, were probably formed during the dry season, whereas the dark laminae/beds exhibiting greater detrital contamination were likely formed during the wet season. When excluding the samples strongly contaminated by detritus, the sinter exhibits Y anomalies comparable to Post-Archean Australian Shale (PAAS), and to the adjacent underlying K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock samples, indicating that these anomalies were not inherited from rocks dominating the reservoirs. Furthermore, the sinter shows a (Ce/Ce*)<sub>N</sub> range close to that of the underlying marine siliceous rock and rhyolite samples, reflecting that the (Ce/Ce*)<sub>N</sub> of the sinter is largely inherited from the reservoir rock(s). The overall REE + Y patterns of the sinter range from nearly flat to LREE-depleted, similar to some samples of the K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock units. However, most samples of the K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock display (Pr/Tb)<sub>N</sub> and (Pr/Yb)<sub>N</sub> higher than many studied sinter samples. This is likely because of the formation of strong HREE–carbonate complexes during groundwater migration. Based on these results, a generalized formation model of the studied sinter system was constructed. This study suggests that integrated sedimentological and geochemical investig
{"title":"A Cretaceous siliceous sinter in NE China: Sedimentological and geochemical constraints on its genesis","authors":"Yaxian You , Huaguo Wen , Lianchao Luo , Kathleen A. Campbell , Diego M. Guido , Enrico Capezzuoli , Zhipeng Lu , Lei Du , Yunbao Yang","doi":"10.1016/j.sedgeo.2024.106618","DOIUrl":"10.1016/j.sedgeo.2024.106618","url":null,"abstract":"<div><p>Phanerozoic sinter deposits have been reported globally, with their identification mainly based on sedimentological, petrological, and mineralogical studies. In this study, a detailed geochemical investigation, combined with sedimentological characterization, was conducted on the Wugonglilu siliceous deposit, a Cretaceous (106 Ma) sinter in NE China, to examine its genesis. The deposit is inferred as a siliceous hot spring deposit (sinter) owing to its geological setting in an epithermal gold-mining district, its morphologically variable microbial textures typical of subaerial sinters, and nearly pure silica composition. Three lithofacies were recognized in this study, including laminated to thinly bedded sinter, silica-cemented breccia, and epithermal vein, which represent deposits from three contrasting hydrothermal environments. The <sup>87</sup>Sr/<sup>86</sup>Sr ratios of the sinter are similar to the bedrock through which the geothermal fluids passed, namely the Upper Triassic Dajiahe Formation (T<sub>3</sub>dj), a marine siliceous rock unit, and the Lower Cretaceous Datashanlinchang Formation (K<sub>1</sub>d), a rhyolite unit. Results indicate that both underlying units are possible Sr sources of the silica in the Wugonglilu sinter. The REE + Y (rare-earth elements and yttrium) patterns of the sinter exhibit significant variability, primarily due to terrestrial detrital contamination. Differential REE + Y contamination by terrestrial detritus was striking in the white and dark laminae/beds of the laminated to thinly bedded sinter. The white laminae/beds, generally less contaminated, were probably formed during the dry season, whereas the dark laminae/beds exhibiting greater detrital contamination were likely formed during the wet season. When excluding the samples strongly contaminated by detritus, the sinter exhibits Y anomalies comparable to Post-Archean Australian Shale (PAAS), and to the adjacent underlying K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock samples, indicating that these anomalies were not inherited from rocks dominating the reservoirs. Furthermore, the sinter shows a (Ce/Ce*)<sub>N</sub> range close to that of the underlying marine siliceous rock and rhyolite samples, reflecting that the (Ce/Ce*)<sub>N</sub> of the sinter is largely inherited from the reservoir rock(s). The overall REE + Y patterns of the sinter range from nearly flat to LREE-depleted, similar to some samples of the K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock units. However, most samples of the K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock display (Pr/Tb)<sub>N</sub> and (Pr/Yb)<sub>N</sub> higher than many studied sinter samples. This is likely because of the formation of strong HREE–carbonate complexes during groundwater migration. Based on these results, a generalized formation model of the studied sinter system was constructed. This study suggests that integrated sedimentological and geochemical investig","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106618"},"PeriodicalIF":2.8,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140053734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}