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Archie's cementation factors for natural rocks: Measurements and insights from diagenetic perspectives 天然岩石的阿奇胶结系数:成岩学角度的测量和见解
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-23 DOI: 10.1016/j.sedgeo.2024.106633
Xiaoqing Yuan , Qinhong Hu , Xianglong Fang , Qiming Wang , Yong Ma , Yukio Tachi

Archie's cementation factor, m, is a critical parameter for petrophysical studies, and the value is influenced by several factors such as the shape, type, and size of grains, degrees of diagenesis, and associated pore structure. Using integrated experimental and theoretical approaches, the goal of this study is to obtain the cementation factor of rocks (both reservoir rock and caprock) and assess the impact of diagenetic processes on the values of the cementation factor. Thirteen samples of geologically diverse rocks (six mudstones, four fossiliferous limestones, two marbles, and one sandstone) were selected to achieve these research objectives. Two approaches, the diffusion of gas tracers and the Bosanquet formula calculation using pore-throat sizes from mercury intrusion porosimetry analyses, were used to derive the cementation factors of these rock samples. These rocks were categorized into two groups based on the correlation between average pore-throat diameter and diffusivity, and an exponential-law relationship between the cementation factor and porosity was determined for these sample groups. In addition, thin-section petrography and field emission-scanning electron microscopy observations were utilized to investigate diagenetic processes, with four diagenetic patterns being established: (1) strong compaction, strong cementation, and weak dissolution-diagenesis pattern; (2) weak compaction, medium cementation, and weak dissolution-diagenesis pattern; (3) weak compaction, medium cementation, and strong dissolution-diagenesis pattern; and (4) fracture-matrix pattern. The results indicated that diagenetic processes and microfractures contribute to the variability in the cementation factors of these rock samples.

Archie胶结系数m是岩石物理研究的一个关键参数,其值受多种因素影响,如颗粒的形状、类型和大小、成岩程度以及相关的孔隙结构。本研究采用实验和理论相结合的方法,旨在获得岩石(储层岩石和盖层岩石)的胶结因子,并评估成岩过程对胶结因子值的影响。为了实现这些研究目标,我们选择了 13 块地质不同的岩石样本(6 块泥岩、4 块含化石的灰岩、2 块大理岩和 1 块砂岩)。通过气体示踪剂扩散和利用汞侵入孔隙模拟分析得出的孔喉尺寸进行博桑凯公式计算这两种方法,得出了这些岩石样本的胶结系数。根据平均孔喉直径与扩散率之间的相关性,将这些岩石分为两组,并确定了这些样品组的胶结系数与孔隙度之间的指数规律关系。此外,还利用薄片岩相学和场发射扫描电子显微镜观察研究成岩过程,确定了四种成岩模式:(1)强压实、强胶结和弱溶解-成岩模式;(2)弱压实、中等胶结和弱溶解-成岩模式;(3)弱压实、中等胶结和强溶解-成岩模式;以及(4)断裂-基质模式。结果表明,成岩过程和微裂隙导致了这些岩石样本胶结因子的变化。
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引用次数: 0
Physico-chemical alteration of pyroxene in coastal environments: Empirical constraints from New Zealand and the Azores 沿海环境中辉石的物理化学蚀变:新西兰和亚速尔群岛的经验制约因素
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-21 DOI: 10.1016/j.sedgeo.2024.106632
Juan J. Kasper-Zubillaga , David M. Buchs , Duncan D. Muir , Lizeth Carlos-Delgado , Elsa Arellano-Torres , León Felipe Álvarez-Sánchez

Developing approaches to determine the modes of transport and weathering of mafic detrital minerals in natural sedimentary environments is critical to our understanding of sediment production, dispersal and provenance, as well as carbon capture under natural and enhanced weathering regimes. We integrated the characterisation of morphological and surface textures with the surface composition of recent detrital clinopyroxene grains concentrated in a sandy coastal area from the western North Island of New Zealand and a rocky shore area of Santa Maria Island in the Azores Archipelago. Using the compactness shape descriptor, 341 grains were subdivided into elongated, elongated angular, euhedral, angular and subangular groups, with each group further characterised using morphological and microtextural indicators of abrasion, breakage and dissolution/chemical weathering. In both studied environments, the clinopyroxenes are dominated by elongated to angular shapes with flat cleavage surfaces and conchoidal fractures. This is consistent with dominant subaqueous transport by rivers and longshore currents for New Zealand, and dominant wave action with limited sediment supply by rivers along the rocky shore of Santa Maria. More abundant subabraded and abraded shapes with bulbous and elongated depression microtextures are observed in New Zealand, which indicates additional effects by aeolian transport that are not seen in Santa Maria. Consistent with semi-quantitative EDS spot analyses that document fresh clinopyroxenes surfaces, chemical weathering textures are very rare to absent. In Santa Maria, sampling of recent beach sand was complemented by ∼125 kyr-old palaeobeach clinopyroxenes, but these yielded similar textural results without evidence for chemical weathering. However, the surface of these older clinopyroxenes includes small adhering smectite (typically <50 μm in width and a few μm in thickness) interpreted to reflect incipient cementation with buffering of acidic fluids by more reactive lithic fragments in the deposits. The lack of chemical weathering but pervasive evidence for mechanical breakage of clinopyroxenes indicate that, at the sand size, these minerals break faster than they dissolve due to frequent subaqueous and/or aeolian reworking in the studied high-energy environments and temperate climatic conditions.

开发确定自然沉积环境中岩浆岩碎屑矿物迁移和风化模式的方法,对于我们了解沉积物的产生、扩散和来源,以及自然和强化风化机制下的碳捕获至关重要。我们将形态和表面纹理特征与集中在新西兰北岛西部沙质海岸地区和亚速尔群岛圣玛丽亚岛岩石海岸地区的近期霞石颗粒的表面成分相结合。利用致密性形状描述符,将 341 个晶粒细分为细长、细长角形、正八面体、角形和近方形组,并利用磨损、断裂和溶解/化学风化的形态和微纹理指标对每组晶粒进行了进一步表征。在所研究的两种环境中,褐辉石主要呈拉长或棱角状,具有平坦的劈裂面和锥状断裂。这与新西兰主要通过河流和长岸流进行水下搬运,以及圣玛丽亚岩岸主要通过波浪作用和有限的河流沉积物供应相一致。在新西兰观察到了更多的亚磨蚀和磨蚀形状,以及球状和细长的凹陷微观纹理,这表明在圣玛丽亚没有看到风化迁移的额外影响。半定量 EDS 点分析记录了新鲜的辉石表面,与此相一致的是,化学风化纹理非常罕见,甚至不存在。在圣玛丽亚,新近的海滩沙取样得到了 125 千年前的古海滩霞石的补充,但这些霞石也得到了类似的纹理结果,没有化学风化的证据。然而,这些较古老的霞石表面包括小的附着矽卡岩(通常宽度为 50 微米,厚度为几微米),据解释,这反映了沉积物中活性较强的岩石碎片对酸性流体进行缓冲的初期胶结作用。缺乏化学风化作用,但却普遍存在霞石机械破碎的证据,这表明在所研究的高能环境和温带气候条件下,由于水下和/或风化再加工频繁,在砂粒大小的情况下,这些矿物的破碎速度快于其溶解速度。
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引用次数: 0
Lithofacies and cyclicity of sulphate dominated tidal-lagoon deposits of Late Triassic age in Northeast Iberia (western Europe) 伊比利亚东北部(西欧)三叠纪晚期以硫酸盐为主的潮汐-泻湖沉积物的液相和共生现象
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-20 DOI: 10.1016/j.sedgeo.2024.106631
Josep Maria Salvany , Guillem Gisbert , Joan Martínez-Bofill

Thick gypsum‑carbonate sequences were deposited in different periods and basins of Europe during the westward opening of the Tethys Ocean. Although they seem to represent widespread perimarine sulphate-dominated lagoons in shallow epeiric platforms, the sedimentary characteristics and interpretation of these deposits are still poorly constrained. To advance in the knowledge of these deposits, a detailed study is presented of two distinctive sulphate dominated sequences of Late Triassic age located in NE Iberia (Western Europe), which correspond to the Canelles and Espinagosa units, found in the southern Pyrenees and the Catalan Coastal Ranges respectively. These sequences present a diverse suite of carbonate and sulphate lithofacies, which are stacked in several recurring sedimentary cycles. These cycles consistently present a carbonate base that transitions to a sulphate top, and can be correlated along several tens of kilometres. Each of the observed cycles depicts an initial sudden flooding of a tidal-lagoon system by marine water, which led to carbonate-dominated sedimentation. Progressive evaporation under dominant arid climate conditions triggered the shallowing of the lagoon and salinisation of its water. Then, a transition from carbonate to gypsum/anhydrite precipitation and the early dolomitisation of the underlying carbonate sediments by brine reflux occurred. Gypsum precipitated in the water column as cumulate crystals and deposited at the bottom of the lagoon, forming laminations or being incorporated into microbial mats. Anhydrite precipitated as early diagenetic crystals in the different subaqueous and subaerial environments of the tidal-lagoon system, leading to a variated set of lithofacies until now largely undocumented. It mainly formed as displacive lath-shaped crystals randomly oriented within carbonate muds at the bottom of the lagoon, which were mostly reworked at the lagoon margins by wave and tidal currents resulting in aligned fabrics in cross-lamination structures. Anhydrite also formed as pure massive beds by anhydritisation of subaerially exposed gypsum sediments during the main retraction stages of the lagoon, as well as typical nodular (sabkha) lithofacies. Such sulphate lithofacies are not easy recognisable due to the lack of modern analogues to compare and to their current transformation into secondary gypsum in the outcrops. These are aspects to be taken into account in future sedimentological studies on similar evaporitic materials.

在特提斯洋向西开放期间,欧洲不同时期和盆地沉积了厚厚的石膏-碳酸盐序列。虽然这些沉积似乎代表了浅海平原中广泛存在的以硫酸盐为主的近海泻湖,但对这些沉积的沉积特征和解释仍然缺乏深入的研究。为了增进对这些沉积的了解,本文详细研究了位于伊比利亚东北部(西欧)的两个晚三叠世时代以硫酸盐为主的独特序列,它们分别对应于比利牛斯山脉南部和加泰罗尼亚海岸山脉的卡内莱斯单元和埃斯皮纳戈萨单元。这些地层呈现出多种多样的碳酸盐岩和硫酸盐岩相,它们在几个循环往复的沉积周期中层叠。这些循环始终呈现出从碳酸盐岩基底过渡到硫酸盐岩顶的过程,并可沿数十公里的范围相互关联。观察到的每个周期都描述了潮汐-泻湖系统最初被海水突然淹没,导致碳酸盐为主的沉积。在主要干旱气候条件下的逐步蒸发引发了泻湖变浅和湖水盐碱化。随后,碳酸盐沉淀物向石膏/无水石膏沉淀物过渡,盐水回流使底层碳酸盐沉淀物早期白云化。石膏以积聚晶体的形式沉淀在水体中,并沉积在泻湖底部,形成层状或融入微生物垫中。无水石膏在潮汐-泻湖系统的不同水下和水下环境中以早期成岩晶体的形式析出,形成了一系列不同的岩相,直到现在基本上还没有记录。无水石膏主要形成于潟湖底部碳酸盐泥浆中随机定向的置换鳞片状晶体,这些晶体大多在潟湖边缘被波浪和潮汐流重新加工,形成交叉层状结构中的排列结构。在泻湖的主要回缩阶段,暴露在水下的石膏沉积物经过水化作用也形成了纯粹的块状岩床,以及典型的结核(sabkha)岩相。这些硫酸盐岩相不易识别,原因是缺乏可比较的现代类似岩相,以及它们目前在露头处转化为次生石膏。这些都是今后对类似蒸发物质进行沉积学研究时需要考虑的方面。
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引用次数: 0
Particle aggregation induced by microorganisms is a key mechanism for the biostabilization of coastal sediment 微生物诱导的颗粒聚集是沿海沉积物生物稳定的关键机制
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-16 DOI: 10.1016/j.sedgeo.2024.106630
Ran Ge , Zheng Gong , Qian Feng , Suna Wang , Chuang Jin , Jiaxin Wei

Biofilm surrounding sediment particles can significantly enhance the stability of coastal sediment. This phenomenon is known as biostabilization. Biofilm mainly consists of extracellular polymeric substances (EPS) and microorganisms. While the role of EPS in biostabilization is well-established, microbial contribution requires further exploration. Herein, an experiment was conducted to compare the stability and morphological characteristics of sediment under the effects of biofilm (with microorganisms) and pure EPS extracted from the biofilm (without microorganisms). The microorganisms used for biofilm culture are composed of diatoms and chlorella. The sediment used is a mixture of well-sorted muddy sand (D50 = 77 μm). Erosion tests showed that in the early stage of biofilm culture (within 17 days), biofilm and pure EPS had a similar ability to stabilize sediment, suggesting that in this stage, biofilm stabilized sediment relying on EPS. However, after 17 days of culture, biofilm showed a stronger ability to stabilize sediment than pure EPS, implying that in this stage, biofilm stabilized sediment by both EPS and microorganisms. These results indicate that microorganisms can also contribute to biostabilization, but during the early stage of culture, microorganisms in biofilm cannot make such contributions. Optical observations found that when the sediment-stabilizing ability of biofilm and pure EPS was comparable, the morphological characteristics of sediment particles under the effects of them were similar, both appearing as scattered single particles. However, when biofilm exhibited a stronger sediment-stabilizing ability, sediment particles with biofilm connected into large-size aggregates, whereas sediment particles with pure EPS remained single and scattered. These results suggest that in the later stage of biofilm culture, microorganisms play a role in the aggregation of sediment particles and hence contribute to biostabilization. Based on these findings, a conceptual framework has been proposed for predicting sediment stability under the effects of biofilm.

沉积物颗粒周围的生物膜可以大大提高沿岸沉积物的稳定性。这种现象被称为生物稳定。生物膜主要由细胞外高分子物质(EPS)和微生物组成。EPS 在生物稳定中的作用已得到证实,但微生物的作用还需要进一步探讨。在此,我们进行了一项实验,比较生物膜(含微生物)和从生物膜中提取的纯 EPS(不含微生物)作用下沉积物的稳定性和形态特征。用于生物膜培养的微生物由硅藻和小球藻组成。使用的沉积物是分选良好的泥沙混合物(D50 = 77 μm)。侵蚀测试表明,在生物膜培养的早期阶段(17 天内),生物膜和纯 EPS 稳定沉积物的能力相似,表明在这一阶段,生物膜依靠 EPS 稳定沉积物。然而,培养 17 天后,生物膜比纯 EPS 稳定沉积物的能力更强,这意味着在这一阶段,生物膜依靠 EPS 和微生物稳定沉积物。这些结果表明,微生物也能为生物稳定做出贡献,但在培养的早期阶段,生物膜中的微生物无法做出这种贡献。光学观察发现,当生物膜和纯 EPS 的沉积物稳定能力相当时,它们作用下的沉积物颗粒形态特征相似,都表现为分散的单个颗粒。然而,当生物膜表现出更强的沉积物稳定能力时,带有生物膜的沉积物颗粒会连接成大尺寸的聚集体,而带有纯 EPS 的沉积物颗粒仍然是单个和分散的。这些结果表明,在生物膜培养的后期阶段,微生物在沉积物颗粒的聚集过程中发挥作用,从而有助于生物稳定。基于这些发现,我们提出了一个概念框架,用于预测生物膜作用下的沉积物稳定性。
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引用次数: 0
Semi-quantifying vertical sedimentary succession and microfacies characterization from a delta system in a lacustrine basin, Huangqihai Lake, North China 华北黄旗海湖湖沼盆地三角洲系统的半量化垂直沉积演替和微地层特征
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-15 DOI: 10.1016/j.sedgeo.2024.106628
Wenjun Kang , Shunli Li , Xin Shan , Chengpeng Tan

The formation of vertical sedimentary succession of a delta in the arid and semi-arid basin-margin progradation dramatically depends on the variation of sediment flux and accommodation, but the discontiguous record of signals tends to exist enormously variable, which renders the bulk record of microfacies difficult to quantify from the vertical sedimentary succession. We analyzed the 18 vertical sedimentary successions collected from 18 field trenches of a lake delta by the cusp-catastrophe model, allowing detailed mapping of microfacies. The present detailed study indicates the suitability of cusp-catastrophe theory for explaining vertical sedimentary succession in the BWH (Bawanghe) delta. Three equilibrium states of processes responsible for the deposition of the BWH delta's evolution were established: sandy-dominated upper leaves primarily exhibit the delta plain; sandy/muddy-dominated lower leaves present the delta plain and pro-delta; and sandy-dominated middle leaves which commonly developed the delta front. The result of analysis shows that the reliability of the cusp-catastrophe model to identity mutation of vertical sedimentary succession exceeds 50 %, and to identity microfacies transitions with a precipitation periodicity exceeds 70 %. These cognitions support the previous view that changing precipitation results in an abrupt change in margin progradation. Simultaneously, the study gives new insights into the microfacies quantification of lake deltas and reveals the influence of crest value changes of precipitation on vertical sedimentary succession can be understood from the dependence of microfacies distribution on the change of sediment flux and accommodation.

干旱半干旱盆地-边缘渐变中三角洲垂直沉积演替的形成极大地依赖于沉积通量和容纳量的变化,但信号的不连续记录往往存在巨大的变异,这使得微地貌的批量记录难以从垂直沉积演替中量化。我们采用尖顶-灾变模型分析了从湖泊三角洲 18 条野外沟槽中采集的 18 个垂直沉积演替,从而详细绘制了微地貌图。本详细研究表明,尖顶-灾难理论适用于解释 BWH(霸王河)三角洲的垂直沉积演替。研究确定了造成 BWH 三角洲沉积演化过程的三种平衡状态:以砂质为主的上部叶片主要表现为三角洲平原;以砂质/泥质为主的下部叶片表现为三角洲平原和原三角洲;以砂质为主的中部叶片通常发育三角洲前缘。分析结果表明,尖顶-灾变模型识别垂直沉积演替突变的可靠性超过 50%,识别降水周期性微地层转换的可靠性超过 70%。这些认识支持了之前的观点,即降水量的变化会导致边缘渐变的突变。同时,该研究对湖泊三角洲微地貌的量化提出了新的见解,并揭示了降水峰值变化对垂直沉积演替的影响可以从微地貌分布对沉积通量和容纳量变化的依赖性来理解。
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引用次数: 0
Sedimentary characteristics of mixed source fine-grained gravity-flow and its significance for shale oil exploration in a lacustrine depression basin: A case study of the Chang 73 Sub-member of the Triassic Yanchang Formation in Ordos Basin, NW China 混源细粒重力流沉积特征及其对湖相凹陷盆地页岩油勘探的意义:中国西北部鄂尔多斯盆地三叠系延长地层长73亚元案例研究
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-14 DOI: 10.1016/j.sedgeo.2024.106629
Lin Wang , Qiqi Lyu , Linhan Li , Jun Liu , Shunshe Luo , Xuehu Sun , Lei Zhang , Xinshou Xu

This study investigates the transport and evolution of fine-grained gravity-flow deposits in lacustrine basins, focusing on the relationship between fine-grained deposits and their respective source–reservoir combinations. Such knowledge is vital for the exploration and development of unconventional oil and gas resources within the source-rock series of continental lake basins in China. We investigated the fine-grained gravity-flow deposits of the Late Triassic Chang73 Sub-member within the Yanchang Formation in the Ordos Basin. Our approach combined core observations, field outcrop evaluations, thin section analysis, scanning electron microscopy, geochemical data, and laboratory measurements. The sedimentary facies, characteristics, controlling factors, and sedimentary model of the fine-grained gravity-flow deposits are investigated. The primary sources of fine-grained sediments are terrestrial clastic and volcanic–hydrothermal fine-grained sediments. These sediments are mainly developed in warm, humid environments with abundant precipitation, favoring a highly reducible hypoxic terrestrial brackish–freshwater environment. Ten lithofacies and eight bed types of fine-grained gravity-flow deposits are categorized. Bed types represent deposits of muddy slide deposits, muddy slump deposits, muddy debris flow deposits, muddy flow deposits, hybrid event beds, fine-grained transitional flow deposits, surge-like turbidity flow deposits, and fine-grained hyperpycnal flow deposits. As a result of paleo-seismicity, volcanic events, and paleogeomorphology, instability and subsequent collapse of the delta front sediments led to the formation of gravity-flow deposits. These deposits formed the “channel–lobe complex” and “sublacustrine fan” sedimentary systems in both the southwestern and northeastern parts of the basin, respectively. Meanwhile, extraordinary flood events formed during the Carnian Pluvial Episode (CPE) played a significant role. It prompted increased fluvial drainage that drove fine-grained hyperpycnal flows through pre-existing valley systems, resulting in the establishment of the “channel–lobe complex” sedimentary system. The Chang 73 Sub-member contains high-quality hydrocarbon source rocks, laying the foundation for shale oil. The introduction of volcanic ash and the influence of hydrothermal activities amplify the enrichment of organic matter within the lacustrine basin. Fine-grained gravity-flow deposits yield siltstone-rich sweet intervals, primarily seen in surge-like turbidity and hyperpycnal flows. The interbedding of sandy and muddy sediments, influenced by hybrid event beds and fine-grained transitional flows, establishes a stratigraphic arrangement in which the upper layer nourishes the underlying reservoir. This structure is particularly beneficial for the development of shale oil and gas sweet intervals.

本研究探讨了湖相盆地中细粒重力流沉积的运移和演化,重点研究了细粒沉积与其各自的源-储层组合之间的关系。这些知识对于勘探和开发中国大陆湖盆源岩系列中的非常规油气资源至关重要。我们研究了鄂尔多斯盆地延长地层晚三叠世昌7亚元的细粒重力流矿床。我们的研究方法结合了岩心观察、野外露头评价、薄片分析、扫描电子显微镜、地球化学数据和实验室测量。研究了细粒重力流沉积的沉积面、特征、控制因素和沉积模型。细粒沉积物的主要来源是陆相碎屑岩和火山热液细粒沉积物。这些沉积物主要发育在温暖湿润、降水丰富的环境中,有利于形成高还原性缺氧的陆相咸淡水环境。细粒重力流沉积分为 10 个岩相和 8 个床层类型。床层类型包括泥质滑坡沉积、泥质坍塌沉积、泥质碎屑流沉积、泥质流沉积、混合事件床层、细粒过渡流沉积、涌浪状浊流沉积和细粒超浊流沉积。由于古地震、火山事件和古地貌的影响,三角洲前缘沉积物的不稳定性和随后的崩塌导致了重力流沉积的形成。这些沉积分别在盆地的西南部和东北部形成了 "河槽-河湾复合体 "和 "岩下扇 "沉积系统。与此同时,卡尼安冲积事件(CPE)期间形成的特大洪水事件也发挥了重要作用。它促使河道排水量增加,推动细粒超微岩流穿过原有的河谷系统,从而形成了 "河槽-河槽复合 "沉积系统。长 7 亚元含有优质烃源岩,为页岩油奠定了基础。火山灰的引入和热液活动的影响扩大了湖盆内有机质的富集。细粒重力流沉积产生了富含粉砂岩的甜区,主要见于涌动状浊流和超浊流。受混合事件床和细粒过渡流的影响,砂质沉积物和泥质沉积物相互交错,形成了上层滋养下层储层的地层结构。这种结构尤其有利于页岩油气甜区的开发。
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引用次数: 0
Seismic stratigraphy and sediment cores reveal lake-level fluctuations in Lake Iznik (NW Turkey) over the past ∼70 ka 地震地层学和沉积岩芯揭示了伊兹尼克湖(土耳其西北部)过去约 70 ka 年的湖面波动情况
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-11 DOI: 10.1016/j.sedgeo.2024.106620
R. Gastineau , F.S. Anselmetti , S.C. Fabbri , P. Sabatier , P. Roeser , S. Gündüz , M. Şahin , E. Duarte , W. Rapuc , A.C. Gebhardt , S.O. Franz , F. Niessen , J. de Sigoyer

Our study aims to understand the palaeohydrological history of Lake Iznik and unravel the complex interplay between climatic, tectonic, and environmental factors that have shaped this Turkish basin. Through the analysis of seismic stratigraphy and sediment cores, we reveal a significant lowstand, indicating a lake level 60 m lower than today at ∼70 ka BP. Subsequently, a major phase of stepwise transgression is evidenced by 13 buried palaeoshorelines between ∼70 and 45 ka BP. From 45 to ∼10 ka cal BP, strong currents controlled the sedimentation in the lake, as evidenced by the occurrence of contourite drifts. Between ∼14 and 10 ka cal. BP, a major lowstand indicating a drier climate interrupted the current-controlled sedimentation regime. From ∼10 ka cal. BP, the subsequent increase in lake level occurred at the same time as the reconnection between the Mediterranean and Black seas. Archaeological evidence, including submerged structures of a basilica, establishes a link between lake-level changes and human settlement during the last millennium. The level of Lake Iznik has since continued to fluctuate due to climate change, tectonic events, and human activity.

我们的研究旨在了解伊兹尼克湖的古水文历史,并揭示塑造这一土耳其盆地的气候、构造和环境因素之间复杂的相互作用。通过对地震地层学和沉积物岩心的分析,我们发现了一个显著的低洼地带,表明公元前约 70 千年时的湖面比现在低 60 米。随后,在公元前约 70-45 ka 之间,13 条被掩埋的古海岸线证明了一个重要的阶梯式横切阶段。在大约公元前 45 至 10 ka ka 期间,强大的水流控制着湖泊的沉积,等高线漂移的出现就是证明。在约 14-10 ka cal.公元前约 14-10 ka. BP 期间,一个表明气候较干燥的大低潮打断了由水流控制的沉积机制。从约 10 ka cal.公元前约 10 ka. BP 开始,在地中海与黑海重新连接的同时,湖泊水位随之上升。考古证据,包括一座大教堂的水下结构,证明了湖面变化与上一个千年人类定居之间的联系。此后,伊兹尼克湖的水位因气候变化、构造事件和人类活动而持续波动。
{"title":"Seismic stratigraphy and sediment cores reveal lake-level fluctuations in Lake Iznik (NW Turkey) over the past ∼70 ka","authors":"R. Gastineau ,&nbsp;F.S. Anselmetti ,&nbsp;S.C. Fabbri ,&nbsp;P. Sabatier ,&nbsp;P. Roeser ,&nbsp;S. Gündüz ,&nbsp;M. Şahin ,&nbsp;E. Duarte ,&nbsp;W. Rapuc ,&nbsp;A.C. Gebhardt ,&nbsp;S.O. Franz ,&nbsp;F. Niessen ,&nbsp;J. de Sigoyer","doi":"10.1016/j.sedgeo.2024.106620","DOIUrl":"10.1016/j.sedgeo.2024.106620","url":null,"abstract":"<div><p>Our study aims to understand the palaeohydrological history of Lake Iznik and unravel the complex interplay between climatic, tectonic, and environmental factors that have shaped this Turkish basin. Through the analysis of seismic stratigraphy and sediment cores, we reveal a significant lowstand, indicating a lake level 60 m lower than today at ∼70 ka BP. Subsequently, a major phase of stepwise transgression is evidenced by 13 buried palaeoshorelines between ∼70 and 45 ka BP. From 45 to ∼10 ka cal BP, strong currents controlled the sedimentation in the lake, as evidenced by the occurrence of contourite drifts. Between ∼14 and 10 ka cal. BP, a major lowstand indicating a drier climate interrupted the current-controlled sedimentation regime. From ∼10 ka cal. BP, the subsequent increase in lake level occurred at the same time as the reconnection between the Mediterranean and Black seas. Archaeological evidence, including submerged structures of a basilica, establishes a link between lake-level changes and human settlement during the last millennium. The level of Lake Iznik has since continued to fluctuate due to climate change, tectonic events, and human activity.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"464 ","pages":"Article 106620"},"PeriodicalIF":2.8,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0037073824000435/pdfft?md5=6ac13479671ff5964fe62c3180b262b3&pid=1-s2.0-S0037073824000435-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Organic matter accumulation in response to tectonism: New data from the Upper Permian Dalong Formation black shales in the Western Hubei Basin, South China and its implications for the end-Permian mass extinction 有机质积累对构造作用的响应:华南湖北盆地上二叠统大龙层黑色页岩的新数据及其对二叠纪末大灭绝的影响
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-11 DOI: 10.1016/j.sedgeo.2024.106621
Binsong Zheng , Chuanlong Mou , Yuanchong Wang

Redox conditions and primary productivity are proposed to be the major controls of organic matter accumulation in sediments. Studies of the impacts of tectonic processes on organic matter accumulation are still limited. We took the Late Permian-Early Triassic Western Hubei Basin, located in the north of South China, as an example. In black shales in the Dalong Formation, bottom-water redox conditions and surface-water productivity are constrained as shown by the analysis of total organic carbon (TOC) as well as geochemical (enrichment of Mo, U, Ni, Cd and Zn) and mineralogical characteristics. The highest productivity is present in the lower Dalong Formation, and the most intensively anoxic and restricted conditions are found in the middle Dalong Formation. The correlation of the sedimentary successions on the two sides of the basin's boundary fault indicates a subsidence of the basement during the deposition of the lower-middle Dalong Formation, followed by an uplift during the deposition of the upper Dalong Formation. When looked at in conjunction with the tectonic background of the basin, the new data in the present study support that: (1) the collision of the South and North China plates controlled the paleoceanographic and hydrographic evolution of the Western Hubei Basin, as well as organic matter accumulation in sediments; (2) upwelling-induced high productivity and good preservation in an anoxic environment jointly contributed to organic matter enrichment in the lower Dalong Formation, while good preservation in an anoxic environment was the major cause of organic matter enrichment in the middle-upper Dalong Formation. This study indicates that tectonism can act as the ultimate drive mechanism for organic matter accumulation in black shales. Our data also suggest that plate tectonism in related to the assembly of East Asian blocks with the main body of Pangea can also be treated as one of the ultimate drive mechanisms of the end-Permian mass extinction as it created the restricted, anoxic Paleo-Tethys Ocean, which greatly disturbed- global seawater circulation.

氧化还原条件和初级生产力被认为是沉积物中有机物积累的主要控制因素。关于构造过程对其影响的研究还很有限。我们以位于华南北部的晚二叠世-早三叠世湖北西部盆地为例。在大龙层黑色页岩中,根据总有机碳(TOC)、地球化学特征(Mo、U、Ni、Cd 和 Zn 的富集)和矿物学特征的分析,对底层水氧化还原条件和表层水生产力进行了约束。结果表明,下大龙层的生产力最高,而中大龙层的缺氧和受限条件最为严重。位于盆地边界断层两侧的沉积演替的相关性表明,在大龙下-中层沉积过程中基底下沉,随后在大龙上层沉积过程中基底抬升。结合盆地的构造背景,本研究的新数据支持了以下观点:(1)华南板块和华北板块的碰撞控制了湖北西部盆地古海洋学和水文学的演化,也控制了沉积物中有机质的富集;(2)上升流引起的高生产力和缺氧环境中的良好保存共同促进了下大龙层有机质的富集,而缺氧环境中的良好保存是中-上大龙层有机质富集的主要原因。这项研究表明,构造作用是黑色页岩中有机质富集的最终驱动机制。我们的数据还证明,与东亚块体与潘加大陆主体组装相关的板块构造运动也可被视为二叠纪末大灭绝的最终驱动机制之一,因为板块构造运动形成了一个受限缺氧的古特提斯洋,进而对全球海水环流产生了重大干扰。
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引用次数: 0
Miocene evolution of the External Rif Zone (Morocco): Comparison with similar and lateral southern Mediterranean Tethyan margins 外里夫区(摩洛哥)的中新世演化:与类似和横向的地中海南部泰西边缘的比较
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-08 DOI: 10.1016/j.sedgeo.2024.106619
Manuel Martín-Martín , Francesco Guerrera , Juan Carlos Cañaveras , Francisco Javier Alcalá , Francisco Serrano , Alí Maaté , Rachid Hlila , Soufian Maaté , Antonio Sánchez-Navas , Crina Miclăus , José Enrique Tent-Manclús , Manuel Bullejos

The Miocene evolution of the External Rif Zone (NW Africa Plate) was determined through multidisciplinary analysis of fourteen successions. The updated stratigraphic framework shows how Miocene sediments rest on the Cretaceous–Paleogene terrains through unconformity surfaces, whereas it rests with sedimentary continuity in two sectors. After recognition of lithofacies and three unconformities located near the Oligocene–Aquitanian, Aquitanian–Burdigalian and Serravallian–Tortonian boundaries, the Miocene sedimentary record was divided into three stratigraphic intervals representing deep to shallow marine deposits as Aquitanian–Burdigalian, Langhian and Upper Serravallian–Missinian. The two oldest unconformites are restricted to the central sector, while the upper one is generalized and probably related to the nappe tectonics registered in all sectors of the External Rif. Data from analysis of tectofacies, petrology, mineralogy, meaning and implications of unconformities, and subsidence indicate that: (i) mass flow deposits (turbidites, slumps, olistostromes) are common in all successions but more frequent during the Lower Miocene; (ii) petrology of the detrital components of the arenites indicates recycled orogen-derived sediments, with quartz coming from erosion of metamorphic rocks of the Atlas orogen and/or the African craton; (iii) mineralogy of mudstones suggests a complex erosional evolution of local emerged areas derived from a mixture of contributions coming from the erosion of Upper Jurassic to Paleogene suites, and especially from kaolinite-rich Albian–Cenomanian to Paleogene successions with absence of a clear unroofing. The conjunction of all these clues reinforces the idea of a synsedimentary tectonics affecting the margin/basin system during the Miocene. A thickness analysis of the studied sedimentary successions allows proposing the evolution of the orogenic front and main depozones (foredeep, bulges, wedge-top and intramontane sub-basins) integrated in a complex foreland system migrating from north to south with the Atlas-Mesetas area acting as foreland during Miocene. The orogenic front moved from the Internal Intrarif to Mesorif and later to Internal Prerif. The main wedge-top basin also migrated from the Internal Intrarif to External Intrarif. The foredeep migrated from the Mesorif to the Internal Prerif, while the main forebulge was located in the External Prerif and a secondary bulge developed in the External Intrarif. Intramontane basins developed behind the orogenic front in relative extensional conditions moving from the Internal Intrarif to External Intrarif. The reconstructed Miocene evolution was inserted into a 2D paleogeographic-geodynamic evolutionary model using GPlates software, and then compared to those reported in other external margins of the western Tethys (Betic Chain, Tunisian Tell, Sicilian Maghrebids and Apennines), revealing important similarities and local differences.

通过对 14 个续层的多学科分析,确定了外里夫区(西北非洲板块)中新世的演化过程。更新的地层框架显示了中新世沉积物是如何通过不整合地层表面与白垩纪-古近纪地层相衔接的,而在两个区段则与沉积物的连续性相衔接。在确认了岩相和位于渐新世-阿基坦、阿基坦-伯迪加里和塞拉瓦利安-托尔托尼边界附近的三个不整合地层之后,中新世沉积记录被划分为三个地层区间,分别代表深海至浅海沉积,即阿基坦-伯迪加里、朗希安和上塞拉瓦利安-米辛。最古老的两个不整合地层仅限于中部地区,而上部的不整合地层则具有普遍性,可能与外里夫省所有地区的岩层构造有关。对构造成因、岩石学、矿物学、非地层的意义和影响以及沉降的分析数据表明(i) 大量流动沉积物(浊积岩、坍塌岩、鲕粒岩)在所有演替中都很常见,但在下中新世更为频繁;(ii) 磁性砂岩的岩石学表明是造山带的再循环沉积物,其中的石英来自阿特拉斯造山带和/或非洲陨石坑变质岩的侵蚀;(iii) 泥岩的矿物学表明,当地出现的区域侵蚀演化过程复杂,来自上侏罗统至古近纪岩组的侵蚀,特别是来自富含高岭石的阿尔卑斯-仙人掌统至古近纪岩组的侵蚀,没有明显的卸顶。所有这些线索都加强了中新世期间影响边缘/盆地系统的同步沉积构造的观点。通过对所研究的沉积成因进行厚度分析,可以提出中新世时期造山前缘和主要剥蚀带(前深部、隆起、楔顶和山内亚盆地)的演化过程,它们被整合在一个由北向南迁移的复杂前缘系统中,阿特拉斯-梅塞塔斯地区在中新世时期充当了前缘的角色。造山前缘从内特拉里夫(Internal Intrarif)移至梅索里夫(Mesorif),后来又移至内特拉里夫(Internal Prerif)。主要的楔顶盆地也从内幕裂谷向外幕裂谷迁移。前深盆地从中西断裂带迁移到内部前断裂带,而主要的前隆起位于外部前断裂带,外部内部断裂带则发育了第二隆起。在相对伸展的条件下,造山前缘的后方形成了内盆地,从内外侧裂向外内侧裂移动。利用 Gplates 软件将重建的中新世演化插入二维古地理-地球动力学演化模型,然后将其与特提斯西部其他外缘(贝蒂奇链、突尼斯泰勒、西西里马格里布和亚平宁半岛)的演化进行比较,发现了重要的相似之处和局部差异。
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引用次数: 0
A Cretaceous siliceous sinter in NE China: Sedimentological and geochemical constraints on its genesis 中国东北白垩纪硅质烧结矿:沉积学和地球化学对其成因的制约
IF 2.8 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-03-06 DOI: 10.1016/j.sedgeo.2024.106618
Yaxian You , Huaguo Wen , Lianchao Luo , Kathleen A. Campbell , Diego M. Guido , Enrico Capezzuoli , Zhipeng Lu , Lei Du , Yunbao Yang
<div><p>Phanerozoic sinter deposits have been reported globally, with their identification mainly based on sedimentological, petrological, and mineralogical studies. In this study, a detailed geochemical investigation, combined with sedimentological characterization, was conducted on the Wugonglilu siliceous deposit, a Cretaceous (106 Ma) sinter in NE China, to examine its genesis. The deposit is inferred as a siliceous hot spring deposit (sinter) owing to its geological setting in an epithermal gold-mining district, its morphologically variable microbial textures typical of subaerial sinters, and nearly pure silica composition. Three lithofacies were recognized in this study, including laminated to thinly bedded sinter, silica-cemented breccia, and epithermal vein, which represent deposits from three contrasting hydrothermal environments. The <sup>87</sup>Sr/<sup>86</sup>Sr ratios of the sinter are similar to the bedrock through which the geothermal fluids passed, namely the Upper Triassic Dajiahe Formation (T<sub>3</sub>dj), a marine siliceous rock unit, and the Lower Cretaceous Datashanlinchang Formation (K<sub>1</sub>d), a rhyolite unit. Results indicate that both underlying units are possible Sr sources of the silica in the Wugonglilu sinter. The REE + Y (rare-earth elements and yttrium) patterns of the sinter exhibit significant variability, primarily due to terrestrial detrital contamination. Differential REE + Y contamination by terrestrial detritus was striking in the white and dark laminae/beds of the laminated to thinly bedded sinter. The white laminae/beds, generally less contaminated, were probably formed during the dry season, whereas the dark laminae/beds exhibiting greater detrital contamination were likely formed during the wet season. When excluding the samples strongly contaminated by detritus, the sinter exhibits Y anomalies comparable to Post-Archean Australian Shale (PAAS), and to the adjacent underlying K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock samples, indicating that these anomalies were not inherited from rocks dominating the reservoirs. Furthermore, the sinter shows a (Ce/Ce*)<sub>N</sub> range close to that of the underlying marine siliceous rock and rhyolite samples, reflecting that the (Ce/Ce*)<sub>N</sub> of the sinter is largely inherited from the reservoir rock(s). The overall REE + Y patterns of the sinter range from nearly flat to LREE-depleted, similar to some samples of the K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock units. However, most samples of the K<sub>1</sub>d rhyolite and T<sub>3</sub>dj siliceous rock display (Pr/Tb)<sub>N</sub> and (Pr/Yb)<sub>N</sub> higher than many studied sinter samples. This is likely because of the formation of strong HREE–carbonate complexes during groundwater migration. Based on these results, a generalized formation model of the studied sinter system was constructed. This study suggests that integrated sedimentological and geochemical investig
全球各地都有新生代烧结矿床的报道,其识别主要基于沉积学、岩石学和矿物学研究。本研究结合沉积学特征,对中国东北白垩纪(106Ma)烧结矿--武功里路硅质矿床进行了详细的地球化学调查,以研究其成因。该矿床被推断为硅质温泉矿床(烧结矿),因为其地质背景位于热液型金矿区,形态多变的微生物纹理是典型的次生烧结矿,而且硅石成分近乎纯净。本研究确认了三种岩相,包括层状至薄层状烧结矿、硅质胶结角砾岩和热液矿脉,它们代表了三种截然不同的热液环境中的矿床。烧结矿的 Sr/Sr 比值与地热流体流经的基岩相似,即上三叠统大家河地层(Tdj)和下白垩统大山林场地层(Kd),前者为海相硅质岩单元,后者为流纹岩单元。结果表明,这两个下伏单元都可能是武功立路烧结矿二氧化硅的Sr来源。烧结矿的 REE + Y(稀土元素和钇)模式表现出显著的差异性,这主要是由于陆相碎屑污染造成的。在层状至薄层状烧结矿的白色和深色层状/床层中,陆生碎屑对 REE + Y 的不同污染非常明显。白色层状/层床一般污染较少,可能是在旱季形成的,而深色层状/层床的碎屑污染较多,可能是在雨季形成的。如果剔除受碎屑污染较严重的样本,烧结矿的Y异常与后雅典澳大利亚页岩(PAAS)以及邻近的下伏Kd流纹岩和Tdj硅质岩样本相当,表明这些异常不是从储层中的主要岩石继承而来的。此外,烧结矿显示的(Ce/Ce*)范围与下伏海相硅质岩和流纹岩样品的(Ce/Ce*)范围接近,反映出烧结矿的(Ce/Ce*)在很大程度上继承自储层岩石。烧结矿的整体 REE + Y 模式从近乎平缓到 LREE 贫化不等,与 Kd 流纹岩和 Tdj 硅质岩单元的一些样品类似。然而,大多数 Kd 流纹岩和 Tdj 硅质岩样品的 (Pr/Tb) 和 (Pr/Yb) 值都高于许多已研究过的烧结矿样品。这可能是因为在地下水迁移过程中形成了强烈的 HREE-碳酸盐复合物。根据这些结果,构建了所研究烧结矿系统的一般形成模型。这项研究表明,综合沉积学和地球化学调查有助于解释烧结矿床的成因,特别是烧结矿床与相应储层岩石之间的联系。
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Sedimentary Geology
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