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Types and formation mechanisms of authigenic quartz in the Late Paleozoic alkaline lacustrine shales, NW China 晚古生代碱性湖相页岩自生石英类型及形成机制
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-01 Epub Date: 2025-04-04 DOI: 10.1016/j.sedgeo.2025.106880
Changzhi Li , Zhiming Li , Pei Guo , Jian Wang , Wangwei Liu , Baozhen Zhang , Meiyuan Song , Kai Zhong , Jinghong Xu
Authigenic quartz controls the storage and mechanical properties of shales, and has attracted a growing attention in marine and continental shales. The silica solubility in alkaline lakes is high due to the high lake water pH (>9) and thus alkaline lacustrine shales generally contain abundant authigenic quartz. However, the occurrences and formation of authigenic quartz in alkaline lacustrine shales and its impact on shales remain poorly studied. To solve these problems, we systematically studied the Late Paleozoic alkaline lacustrine Fengcheng Formation in the Mahu Sag of the Junggar Basin via optical microscope and scanning electron microscope observations and elemental analyses. Four types of authigenic quartz have been identified in the Fengcheng Formation (shales): chert nodules or bands, matrix-dispersed microquartz, mineral-replacive quartz, and veins-filling quartz. The Fengcheng Formation shales contain excess SiO2 ranging from 11.3 % to 60.4 % based on element calculation and matrix-dispersed microquartz is the dominant type of authigenic quartz, followed by cherts. Cherts and matrix-dispersed microquartz were formed during syndepositional to early diagenetic stage, sourced from pH-driven dissolution of detrital quartz grains and transformation of volcanic materials in highly alkaline water. Both chert and matrix-dispersed microquartz formation can increase the rock strength of shales while matrix-dispersed microquartz can also form massive intercrystalline pores and protect the micropores from compaction. In contrast with marine and non-alkaline lacustrine siliceous shales, alkaline lacustrine shales have a higher abundance and more formation stages of authigenic quartz, and can form high-quality shale reservoirs with high contents of organic matter and authigenic quartz in shallow-water zone.
自生石英控制着页岩的储层和力学性质,在海相和陆相页岩中引起了越来越多的关注。碱性湖泊水体pH值高(>9),硅的溶解度高,因此碱性湖泊页岩一般含有丰富的自生石英。然而,对碱性湖相页岩中自生石英的赋存、形成及其对页岩的影响的研究还很少。为解决这些问题,通过光学显微镜、扫描电镜观察和元素分析,对准噶尔盆地马湖凹陷晚古生代碱性湖泊丰城组进行了系统研究。在丰城组(页岩)中发现了4种自生石英:燧石结核或带状石英、基质分散微石英、矿物替代石英和脉状充填石英。丰城组页岩SiO2含量在11.3% ~ 60.4%之间,自生石英以基质分散微石英为主,其次为燧石;燧石和基质分散微石英形成于同沉积至早期成岩阶段,主要来源于高碱性水体中碎屑石英颗粒的ph驱动溶蚀和火山物质的转化。燧石组和基质分散微石英组均能提高页岩岩石强度,基质分散微石英组还能形成块状晶间孔,保护微孔不被压实。与海相和非碱性湖相硅质页岩相比,碱性湖相页岩自生石英丰度更高,形成期次更多,可形成浅水区有机质和自生石英含量高的优质页岩储层。
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引用次数: 0
Lacustrine sedimentary evidence of cascading mountain hazards at the inner-Alpine Lake Altaussee (Eastern Alps, Austria) during the Late Holocene 晚全新世阿尔卑斯湖内阿尔卑斯湖Altaussee(奥地利东阿尔卑斯)层叠山灾害的湖相沉积证据
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-01 Epub Date: 2025-04-09 DOI: 10.1016/j.sedgeo.2025.106881
Marcel Ortler , Jasper Moernaut , Markus Fiebig , Andrea Franco , Jean Nicolas Haas , Irka Hajdas , Philipp Haeuselmann , Julia Rechenmacher , Lisa-Maria Weber , Erwin Heine
Inner-Alpine or intramountainous lake systems can be formed by glacial, tectonic or landslide processes and typically present complex sediment dynamics that can drastically change over time and can be driven by various natural hazard processes. Their sedimentary archives can therefore provide insights in the past magnitude and frequency of local mountain hazards, which is key for reliable hazard assessment and understanding of mountain landscape evolution. Here we present morphological, seismic-reflection and sedimentary data from Lake Altaussee, a groundwater-fed lake surrounded by steep topography in the Eastern Alps (Austria). The slow organic-rich sedimentation is interrupted by one phase of inflow (by the Augstbach creek), resulting in clastic sediment input between ~1110–1346 cal yr CE. This inflow phase was terminated by an artificial diversion of the creek as documented in historical reports. The combination of large blocks (max. 70 m in diameter), a mass-flow deposit and megaturbidite deposited on deformed basin floor sediments points to multiple terrestrial mass movements with a total volume of ~430,000 m3 that propagated into the lake and which occurred 755–991 cal yr CE. A 3D hydrodynamic model suggests that the potential mass movement at the northern shore induced an impact wave that inundated the western shoreline with flow depth of up to 9 m and reaching up to ca. 210 m inland. Calculated speed of the backflow indicates that coarse shore sediments can be transported into the lake, which can explain the abundance of gravel/coarse sand at the base of the megaturbidite at the periphery of the basin. Moreover, such impact wave would lead to a standing lake water oscillation (seiching), which is further attested by regular lamination and oscillating grain-size parameters at the base of the main silty unit of the megaturbidite. A persistent change in sediment dynamics around a main subaqueous karst spring pit occurred at 165 cal yr BCE–222 cal yr CE when repeated sediment expulsions from the spring pit started to build up a crater rim. This onset of sediment expulsions is directly overlying a soft-sediment deformation structure (micro-faults). A good age correlation of the two major Altaussee events (i: multiple mass movements, ii: onset of sediment expulsions from spring pit) to large mass-transport deposits in the sedimentary record of the nearby Lake Hallstatt let us hypothesize that two large earthquakes took place in the Late Holocene that led to a multitude of morphological and sedimentary responses in the Upper Traun region. Our findings provide the first indication of an impact wave on a natural lake in the Eastern Alps, highlighting the potential for hazard cascades that remain undocumented in historical records, underscoring the need for reassessing natural hazard risks in alpine lake environments.
高山内部或山间湖泊系统可由冰川、构造或滑坡过程形成,通常呈现复杂的沉积动力学,可随时间急剧变化,并可由各种自然灾害过程驱动。因此,它们的沉积档案可以提供当地山地灾害过去的规模和频率的见解,这是可靠的灾害评估和了解山地景观演变的关键。在这里,我们展示了来自阿尔陶湖的形态、地震反射和沉积数据。阿尔陶湖是奥地利东阿尔卑斯山一个被陡峭地形包围的地下水湖泊。缓慢的富有机质沉积被奥格斯特巴赫河(Augstbach creek)的一段流入打断,导致碎屑沉积在约1110-1346 calyr CE之间输入。历史报告中记载,这一流入阶段因人工引流而终止。大块的组合(最大。(直径70 m),在变形的盆地底沉积物上沉积的质量流沉积和巨闪岩表明,发生在公元755-991年的多次陆块运动,总积约43万m3,向湖中扩展。三维水动力模型表明,北岸的潜在质量运动引发了一个冲击波,淹没了西部海岸线,流深达9 m,内陆达约210 m。计算出的回流速度表明,粗岸沉积物可以被带入湖泊,这可以解释盆地外围巨浊岩底部砾石/粗砂丰富的原因。此外,这种冲击波还会引起静湖水振荡(振荡),这一现象在微闪岩主粉质单元底部的层压和粒度参数的振荡中得到了进一步证实。在公元前165年至公元前222年,一个主要的水下岩溶泉坑周围的沉积物动力学发生了持续的变化,当时泉水坑的沉积物不断排出,开始形成火山口边缘。这种沉积物排出的起点直接位于软沉积物变形构造(微断层)之上。在Hallstatt湖附近的沉积记录中,两次主要的Altaussee事件(1:多次物质运动,2:从泉坑开始的沉积物排出)与大型物质搬运沉积的良好年龄相关性使我们假设晚全新世发生了两次大地震,导致了上Traun地区的大量形态和沉积反应。我们的研究结果首次表明,东阿尔卑斯的一个天然湖泊受到了冲击波的影响,强调了历史记录中未记载的危险级联的可能性,强调了重新评估高山湖泊环境中自然灾害风险的必要性。
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引用次数: 0
Depositional environment and redox conditions of the Moncorvo Ironstone – Unveiling the evolution of ironstones under Rheic Ocean influence Moncorvo铁矿沉积环境与氧化还原条件——揭示大洋影响下的铁矿演化
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-01 Epub Date: 2025-04-30 DOI: 10.1016/j.sedgeo.2025.106885
Emilio Evo Magro Correa Urbano , Maria Elisa Preto Gomes , Carlos Augusto Pinto de Meireles , Paulo Roberto Gomes Brandão , João Pedro T.M. Hippertt , Ricardo Scholz , Cristiano Lana
Ironstones, as key archives of past marine environments, provide invaluable insights into Paleozoic history. Their mineralogy may reflect the physical-chemical conditions of the environment and the nature of available sediments. This study focuses on the Moncorvo Ironstone, a Lower-Middle Ordovician deposit formed during the opening of the Rheic Ocean. Here, we use an integrated approach combining sedimentology, petrology, and geochemistry to constrain the depositional settings and the redox landscape associated with the ironstone deposition. The Moncorvo Ironstone present some unusual characteristics, such as the lack of ooids, an uncommon mineralogy, and a stratigraphic thickness that can reach over >45 m, a remarkable feature for an ironstone. Our investigation reveals that this iron-rich sequence is distributed in two distinct marine environments: an inner shelf and a middle to distal shelf. Each environment has a unique mineral assemblage. Despite the influence of metamorphism and deformation, evidence suggests that much of the mineralogy and texture of this deposit still preserve characteristics of the original sediments. Finally, our findings, alongside a careful assessment of the mineralogy of other ironstones of similar age, suggest a strong stratification of the Rheic Ocean throughout the Early and Middle Ordovician.
铁石,作为过去海洋环境的重要档案,提供了对古生代历史的宝贵见解。它们的矿物学可以反映环境的物理化学条件和可用沉积物的性质。Moncorvo铁矿是中奥陶统下第三纪沉积,形成于大洋打开时期。本文采用沉积学、岩石学和地球化学相结合的综合方法来约束与铁矿沉积相关的沉积背景和氧化还原景观。Moncorvo铁矿具有一些不寻常的特征,如缺乏流体,不寻常的矿物学,地层厚度可达45米以上,这是一种铁矿的显著特征。我们的研究表明,这一富铁层序分布在两个不同的海洋环境中:一个内陆架和一个中至远陆架。每种环境都有独特的矿物组合。尽管受到变质作用和变形作用的影响,但有证据表明,该矿床的大部分矿物学和结构仍保留了原始沉积物的特征。最后,我们的发现,加上对其他类似年龄的铁矿的矿物学的仔细评估,表明贯穿早奥陶纪和中奥陶纪的莱西海有很强的分层作用。
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引用次数: 0
Climate forcing of turbidite system on the northern South China Sea margin during the Late Quaternary 晚第四纪南海北部边缘浊积体系的气候强迫
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-01 Epub Date: 2025-04-24 DOI: 10.1016/j.sedgeo.2025.106884
Xuan Zhao , Wei Li , Christopher J. Stevenson , Qiang Zhang , Shuang Li , Lingyun Wu , Zhiyuan Cai , Xiting Liu , Wenhuan Zhan
Turbidites preserved within sedimentary sequences serve as valuable archives of sea-level and climate fluctuations that influence terrigenous sediment supply and depositional processes. However, a comprehensive understanding of how turbidite systems respond to the complex interplay of external forcing on millennial timescales remains limited. Using grain size, geochemical, and chronological data from two sediment cores in different geomorphic settings, we investigate how turbidite system growth responds to sea level, climate and tectonics along the northern South China Sea (SCS) margin. Core QDN-2, located on the northwestern SCS margin, records two turbidites deposited between 43 ka and 12 ka, followed by a cessation of activity during the Holocene. Conversely, core TXN-1 situated on the northeastern SCS margin, documents frequent turbidity currents since 12 ka. These contrasting records demonstrate that turbidite systems on the northern SCS margin can develop at any sea-level. Our findings reveal that while sea level and tectonics play a role, climate emerges as the dominant external forcing on turbidite system development in the northern SCS. Sufficient climate-induced sediment supply compensates for the influence of interception by the wide shelf and high sea level, providing the necessary material basis for the initiation of turbidity currents. The rapid delivery of terrigenous sediments through turbidity currents facilitates the preservation of these climatic signals within the turbidites. This study highlights the crucial role of climate forcing in turbidite depositional patterns, even on the wide continental shelves, and emphasizes the importance of incorporating climate variability into sequence stratigraphic interpretations.
沉积层序中保存的浊积岩是影响陆源沉积物供应和沉积过程的海平面和气候波动的宝贵档案。然而,对浊积系统如何在千年时间尺度上响应外部强迫的复杂相互作用的全面理解仍然有限。利用不同地貌背景下两个沉积物岩心的粒度、地球化学和年代学数据,研究了南海北部边缘浊积岩体系生长对海平面、气候和构造的响应。QDN-2岩芯位于南海西北边缘,记录了两个浊积岩在43ka - 12ka之间沉积,随后在全新世停止活动。相反,位于南海东北部边缘的TXN-1岩芯记录了自12ka以来频繁的浊流。这些对比记录表明,南海北部边缘的浊积体系可以在任何海平面上发育。我们的研究结果表明,尽管海平面和构造作用起作用,但气候成为南海北部浊积体系发展的主要外部强迫。充足的气候引起的泥沙供应补偿了宽大陆架和高海平面截流的影响,为浊流的形成提供了必要的物质基础。陆源沉积物通过浊度流的快速输送有助于在浊积岩中保存这些气候信号。本研究强调了气候强迫在浊积岩沉积模式中的关键作用,甚至在宽大陆架上也是如此,并强调了将气候变率纳入层序地层学解释的重要性。
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引用次数: 0
Environmental and oceanographic evolution in the Southern Qiangtang Basin (eastern Tethys) during the latest Pliensbachian to early Toarcian (Early Jurassic) 羌塘盆地南部(特提斯东部)晚Pliensbachian -早陶瓦良世(早侏罗世)环境与海洋演化
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-01 Epub Date: 2025-04-09 DOI: 10.1016/j.sedgeo.2025.106882
Changjun Ji , Ahmed Mansour , Yun Chen , Zhenhan Wu , Mohamed S. Ahmed , Wolfgang Ruebsam , Guoqing Xia
The late Pliensbachian-early Toarcian (Early Jurassic) interval is marked by significant climatic changes that affected environmental and paleoceanographic conditions, impacting biogeochemical cycles, as well as marine and terrestrial ecosystems. The most profound environmental changes occurred across the Pliensbachian/Toarcian boundary (P/T B) and in the early Toarcian. Both events align with phases of increased greenhouse gas emissions, global warming, sea-level rises, intensified hydrological cycles, and continental weathering. The Toarcian coincides with the expansion of oxygen-deficient conditions in oceanic and at various shelf areas, marking the Toarcian Oceanic Anoxic Event (T-OAE). In this study, we present high-resolution inorganic geochemical data from the Qixiangcuo section of the Southern Qiangtang Basin, which records both the P/T B and early Toarcian events. The section studied reflects a shallow shelf environment in northeastern part of the Tethys Ocean. Element ratios, such as Ti/Al and Zr/Al, interpreted as sediment grain size proxies, reveal characteristic changes that can be linked to the interplay between sea-level changes and shifts in continental weathering and terrigenous sediment influx. Secular trends in these grain-size proxies reflect sea-level dynamics during the late Pliensbachian-early Toarcian, with notable transgressions at the P/T B and early Toarcian. The early Toarcian event further coincides with increased terrigenous material in response to an intensified hydrological cycle, as evidenced by transient increases in grain-size proxies and higher paleo-weathering indices (e.g., ln(Al2O3/Na2O)). Despite the increased nutrient flux to the paleo-shelf sea, enrichment factors (EF) of productivity proxies (ZnEF, CuEF, BaEF, NiEF) do not show increases in organic matter export to the sediments. Thus, organic matter-lean sediments (total organic carbon <0.5 wt%) have accumulated in the Southern Qiangtang Basin during the latest Pliensbachian-early Toarcian. The lack of enrichment in redox-sensitive elements, such as Mo, V, and U in the sedimentary rocks of the Qixiangcuo section, points to a well‑oxygenated environment. Accordingly, although the T-CIE is identified in the study section, the T-OAE did not develop in this paleogeographic area. The new data thereby highlight the role of local-regional paleoenvironmental and paleoceanographic parameters as important factors contributing to the genesis of the T-OAE and the burial of organic carbon in marine sediments.
晚普林恩巴氏—早陶瓦世(早侏罗世)时期,气候发生了重大变化,影响了环境和古海洋条件,影响了生物地球化学循环,影响了海洋和陆地生态系统。最深刻的环境变化发生在Pliensbachian/Toarcian边界(P/T B)和Toarcian早期。这两个事件都与温室气体排放增加、全球变暖、海平面上升、水文循环加剧和大陆风化的阶段相一致。Toarcian ocean Anoxic Event (T-OAE)标志着Toarcian oceanic Anoxic Event (T-OAE)的发生。本文采用高分辨率的无机地球化学资料,记录了羌塘盆地南部七相措剖面的P/T B和早陶瓦世事件。所研究的剖面反映了特提斯洋东北部的浅层陆架环境。元素比率,如Ti/Al和Zr/Al,被解释为沉积物粒度指标,揭示了与海平面变化、大陆风化变化和陆源沉积物流入之间的相互作用有关的特征变化。这些粒度指标的长期趋势反映了pliensbachia晚期- Toarcian早期的海平面动态,在P/T B和Toarcian早期有明显的海侵。早陶拉纪事件进一步与陆源物质的增加相吻合,这是对强化水文循环的响应,这可以通过粒度指标的短暂增加和古风化指数(如ln(Al2O3/Na2O))的升高来证明。尽管向古陆架海的养分通量增加,但生产力指标(ZnEF、CuEF、BaEF、NiEF)的富集因子(EF)并未显示有机质向沉积物输出增加。因此,羌塘盆地南部在晚普林恩巴氏—早陶拉世形成了有机质贫沉积(总有机碳含量为0.5 wt%)。七相错剖面沉积岩中Mo、V、U等氧化还原敏感元素缺乏富集,表明其为富氧环境。因此,虽然在研究区发现了T-CIE,但在该古地理区没有发育T-OAE。因此,这些新数据强调了局部区域古环境和古海洋参数是影响T-OAE成因和海洋沉积物中有机碳埋藏的重要因素。
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引用次数: 0
Effects of drying on biofilm-mediated sediment stability in intertidal mudflats: transition from biostabilization to biodestabilization 干燥对潮间带泥滩生物膜沉积物稳定性的影响:从生物稳定到生物不稳定的过渡
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-01 Epub Date: 2025-04-11 DOI: 10.1016/j.sedgeo.2025.106883
Ran Ge , Yonggang Zhao , Zheng Gong , Suna Wang , Aihong Wei , Mo Peng , Honglei Liu
The presence and growth of biofilms can considerably enhance sediment stability, a phenomenon known as biostabilization. Intertidal mudflats are periodically exposed to air due to tidal cycles. During exposure, they are affected by drying, which may alter the properties of biofilms and then their sediment-stabilizing ability. However, to date, little information is available on this topic. For this, the effects of a biofilm on sediment stability were investigated over a 15-day drying period. The biofilm was obtained by culturing microorganisms isolated from intertidal sediment. Previous studies demonstrate that biofilms enhances sediment stability in two ways. On one hand, biofilms coating on the surface of sediment bed can protect surface sediment from erosion (surface protection), evidenced by an increase in the critical shear stress of sediment. On the other hand, after the detachment of surface biofilms, biofilms growing between sediment particles can hinder the erosion of bottom sediment (hindered erosion), indicated by less amount of sediment eroded following a same erosion event. Results of this study showed that during the drying process, surface protection was initially enhanced but later weakened, while hindered erosion was consistently weakened. By the end of experimental drying trials, the biofilm no longer stabilized sediment; instead, it reduced the stability of surface sediment and promoted the erosion of bottom sediment, leading to biodestabilization. After drying, the structure of the biofilm covering sediment bed became more compact, similar to that of soil crust, whereas the crust-like biofilm was gradually broken towards the end of experimental drying trials. This alteration explains the observed variations in surface protection. The weakened hindered erosion is associated with the loss of adhesion and aggregation of sediment particles as drying progressed. Moreover, many gas bubbles were generated and trapped within dried biofilm and between sediment particles, which possibly increase the buoyancy of biofilm and weaken the inter-particle bonding of sediment particles, thus leading to biodestabilization.
生物膜的存在和生长可以大大提高沉积物的稳定性,这种现象被称为生物稳定。潮间带泥滩由于潮汐循环而周期性地暴露在空气中。在暴露过程中,它们受到干燥的影响,这可能会改变生物膜的特性,进而改变其稳定沉积物的能力。然而,迄今为止,关于这一主题的信息很少。为此,在15天的干燥期内研究了生物膜对沉积物稳定性的影响。生物膜是通过培养从潮间带沉积物中分离的微生物而获得的。先前的研究表明,生物膜通过两种方式增强沉积物的稳定性。一方面,覆盖在沉积物床表面的生物膜可以保护表层沉积物免受侵蚀(表面保护),表现为沉积物临界剪应力的增加。另一方面,表面生物膜分离后,生长在沉积物颗粒之间的生物膜会阻碍底部沉积物的侵蚀(阻碍侵蚀),这表明在相同的侵蚀事件中被侵蚀的沉积物数量较少。研究结果表明,在干燥过程中,表面保护作用先增强后减弱,阻碍侵蚀作用不断减弱。经实验干燥试验结束后,生物膜不再稳定沉淀;相反,它降低了表层沉积物的稳定性,促进了底层沉积物的侵蚀,导致生物不稳定。干燥后,覆盖在沉积物床上的生物膜结构变得更加致密,与土壤结壳结构相似,而在实验干燥试验结束时,类结壳生物膜逐渐破裂。这种变化解释了观察到的表面保护的变化。随着干燥的进行,阻碍侵蚀的减弱与泥沙颗粒的附着力和聚集性的丧失有关。此外,在干燥的生物膜内部和沉积物颗粒之间产生并捕获了许多气泡,这可能会增加生物膜的浮力,削弱沉积物颗粒之间的结合,从而导致生物不稳定。
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引用次数: 0
Arc-continent collision as recorded in modern stream sand from Oecusse (Timor Island) Oecusse(帝汶岛)现代流沙中记录的弧-大陆碰撞
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-01 Epub Date: 2025-03-03 DOI: 10.1016/j.sedgeo.2025.106852
Victor A.S. Vicente , Pedro Dinis , Eduardo Garzanti , Alberto Resentini , Marta Barbarano , Marina Cabral Pinto , João Pratas
The small territory of Oecusse in Timor Island has extremely complex geology, influenced by the collision of the Australian continent with the Banda Arc. In Oecusse, sedimentary, volcanic and metamorphic units associated with the lower plate Australian continental margin, the upper plate Banda Terrane, and synorogenic sedimentary successions are exposed. In this study, geochemistry, petrography, and heavy-mineral data on fluvial bedload sand transported by first- and second-order streams are used to better understand the status of arc-continent collision in Timor and the geological nature of the terranes involved in this tectonic process. The presence of upper mantle outliers in Oecusse is readily revealed by serpentinite grains, a heavy mineral assemblage with enstatite, olivine and Cr-spinel, and by Cr, Fe, Sc, Ti, and V concentrations comparable to the Primitive Mantle standard. Volcanic sources occur both in the Banda Terrane and Australian continental margin. The Manamas Formation (Miocene, Banda Terrane) is the most prominent volcanic source, shedding detritus dominated by mafic volcanic rock fragments, plagioclase, and clinopyroxene, with a geochemical signature similar to the Primitive Mantle. The volcanic units of the Barique Formation (Eocene-Miocene, Banda Terrane) and the Maubisse Formation (Permian, Australian continental margin) comprise compositionally heterogenous suites and are intercalated with sedimentary successions, delivering more felsic material, as indicated by the diversified assemblages of lithic fragments and heavy-minerals. Geochemically, they are characterised by lower contents of most compatible elements, higher contents of Th, Y and REE, steeper REE profiles, and stronger negative Eu anomaly than Manamas-derived detritus. These petrographic and geochemical features locally reveal a major felsic volcanic component in the Barique Formation, which cannot be related to the ongoing orogeny because of its proposed late Eocene to early Miocene age. With the exception of coastal sectors where the Manamas Formation is widely exposed, volcanic, sedimentary and low-rank meta-sedimentary rocks partially derived from the Australian lower plate tend to prevail, confirming that arc-continent collision is still at an early stage in the western part of Timor Island.
由于澳大利亚大陆与班达弧的碰撞,帝汶岛上的奥库斯小领土具有极其复杂的地质情况。在厄库斯,暴露出与下板块澳大利亚大陆边缘、上板块班达地体和同生沉积序列相关的沉积、火山和变质单元。本研究利用一、二级流搬运的河流层载砂的地球化学、岩石学和重矿物资料,更好地了解了帝汶弧-陆碰撞的状态和参与这一构造过程的地体的地质性质。上地幔异常值的存在很容易通过蛇纹岩颗粒(含顽辉石、橄榄石和Cr尖晶石的重矿物组合)以及与原始地幔标准相当的Cr、Fe、Sc、Ti和V浓度来揭示。火山源出现在班达地体和澳大利亚大陆边缘。马纳马斯组(中新世,班达地系)是最突出的火山源,其碎屑以基性火山岩碎屑、斜长石、斜辉石为主,具有与原始地幔相似的地球化学特征。Barique组(始新世-中新世,班达地系)和Maubisse组(二叠纪,澳大利亚大陆边缘)的火山单元组成成分非均质套,并与沉积序列穿插,提供了更多的长英质物质,这可以从岩石碎片和重矿物的多样化组合中看到。地球化学特征为:大部分相容元素含量较低,Th、Y和REE含量较高,REE剖面较陡,Eu负异常较强。这些岩石学和地球化学特征局部揭示了巴里克组主要的长英质火山成分,由于其形成时间为始新世晚期至中新世早期,因此不能与正在进行的造山运动有关。除麦纳麦斯组广泛露出的沿海段外,多为部分来自澳大利亚下板块的火山岩、沉积岩和低阶变质沉积岩,证实了帝汶岛西部弧陆碰撞仍处于早期阶段。
{"title":"Arc-continent collision as recorded in modern stream sand from Oecusse (Timor Island)","authors":"Victor A.S. Vicente ,&nbsp;Pedro Dinis ,&nbsp;Eduardo Garzanti ,&nbsp;Alberto Resentini ,&nbsp;Marta Barbarano ,&nbsp;Marina Cabral Pinto ,&nbsp;João Pratas","doi":"10.1016/j.sedgeo.2025.106852","DOIUrl":"10.1016/j.sedgeo.2025.106852","url":null,"abstract":"<div><div>The small territory of Oecusse in Timor Island has extremely complex geology, influenced by the collision of the Australian continent with the Banda Arc. In Oecusse, sedimentary, volcanic and metamorphic units associated with the lower plate Australian continental margin, the upper plate Banda Terrane, and synorogenic sedimentary successions are exposed. In this study, geochemistry, petrography, and heavy-mineral data on fluvial bedload sand transported by first- and second-order streams are used to better understand the status of arc-continent collision in Timor and the geological nature of the terranes involved in this tectonic process. The presence of upper mantle outliers in Oecusse is readily revealed by serpentinite grains, a heavy mineral assemblage with enstatite, olivine and Cr-spinel, and by Cr, Fe, Sc, Ti, and V concentrations comparable to the Primitive Mantle standard. Volcanic sources occur both in the Banda Terrane and Australian continental margin. The Manamas Formation (Miocene, Banda Terrane) is the most prominent volcanic source, shedding detritus dominated by mafic volcanic rock fragments, plagioclase, and clinopyroxene, with a geochemical signature similar to the Primitive Mantle. The volcanic units of the Barique Formation (Eocene-Miocene, Banda Terrane) and the Maubisse Formation (Permian, Australian continental margin) comprise compositionally heterogenous suites and are intercalated with sedimentary successions, delivering more felsic material, as indicated by the diversified assemblages of lithic fragments and heavy-minerals. Geochemically, they are characterised by lower contents of most compatible elements, higher contents of Th, Y and REE, steeper REE profiles, and stronger negative Eu anomaly than Manamas-derived detritus. These petrographic and geochemical features locally reveal a major felsic volcanic component in the Barique Formation, which cannot be related to the ongoing orogeny because of its proposed late Eocene to early Miocene age. With the exception of coastal sectors where the Manamas Formation is widely exposed, volcanic, sedimentary and low-rank meta-sedimentary rocks partially derived from the Australian lower plate tend to prevail, confirming that arc-continent collision is still at an early stage in the western part of Timor Island.</div></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"481 ","pages":"Article 106852"},"PeriodicalIF":2.7,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143654776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Clay mineral of different lithofacies in a continental shallow water delta: Insights from paleoclimate and diagenesis 大陆浅水三角洲不同岩性的粘土矿物:从古气候和成岩作用中获得的启示
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-01 Epub Date: 2025-03-08 DOI: 10.1016/j.sedgeo.2025.106869
Shaoyun Chen , Yongqiang Yang , Zaixing Jiang , Xiaojuan Wang , Longwei Qiu , Yerejiepu Habulashenmu
Clay minerals in clastic sediments carry important geological information, with their composition and variations reflecting key geological processes. This study investigates the differential clay mineral assemblages among lithofacies within the Middle Jurassic continental shallow-water delta system of the Sichuan Basin, China. Integrated geochemical and XRD analyses demonstrate the significant influence of paleoclimate-driven weathering and diagenetic alteration on clay mineral assemblages. The invariant geochemical characteristics (such as Ti/Al) across different mudstone confirm a uniform provenance, establishing paleoclimate-controlled weathering processes as the principal determinant of clay mineral composition, with negligible provenance influence. Chemical weathering intensity, controlled by the depositional paleoclimate, is a primary factor influencing clay mineral composition in mudstones. In warm, humid climates, abundant rainfall and strong chemical weathering lead to kaolinite enrichment and smectite depletion in black shale facies. Conversely, in cooler, drier climates, physical weathering dominates, resulting in significant illite formation in red mudstone and paleosol facies. In sandstone facies, clay minerals are controlled by diagenetic fluid composition and flux. Chlorite content is related to the primary permeability of the sandstone, while illite content is influenced by K+ concentration in diagenetic fluids, with stronger illite enrichment in areas of intense feldspar dissolution. The smectite-to-illite transformation is common in both sandstone and mudstone facies, with its extent influenced by the openness of the diagenetic system and K+ availability. In humid conditions, feldspar dissolution in an open system leads to K+ advection into sandstone, reducing smectite-to-illite transformation in mudstones. In semi-arid conditions, feldspar dissolution occurs in closed systems during burial, with K+ diffusing into mudstones, promoting greater illitization in mudstones than in sandstones. This study provides insights into how paleoclimate and diagenesis control clay mineral transformations in sedimentary rocks.
碎屑沉积物中的粘土矿物携带着重要的地质信息,其组成和变化反映了关键的地质过程。研究了四川盆地中侏罗统陆相浅水三角洲体系中不同岩相粘土矿物组合的差异性。综合地球化学和XRD分析表明,古气候驱动的风化和成岩蚀变对粘土矿物组合有显著影响。不同泥岩的地球化学特征(如Ti/Al)的不变证实了一个统一的物源,建立了古气候控制的风化过程作为粘土矿物组成的主要决定因素,而物源的影响可以忽略不计。化学风化强度是影响泥岩粘土矿物组成的主要因素,受沉积古气候控制。在温暖湿润的气候条件下,丰富的降雨和强烈的化学风化作用导致黑色页岩相高岭石富集和蒙脱石亏缺。相反,在较凉爽、干燥的气候条件下,物理风化作用占主导地位,导致红泥岩和古土壤相中形成大量伊利石。在砂岩相中,粘土矿物受成岩流体组成和通量的控制。绿泥石含量与砂岩的原生渗透率有关,伊利石含量受成岩流体中K+浓度的影响,在长石溶蚀强烈的地区伊利石富集程度较强。蒙脱石向伊利石转化在砂岩相和泥岩相中都很常见,其程度受成岩系统的开放性和K+有效性的影响。在潮湿条件下,开放体系中的长石溶蚀导致K+平流进入砂岩,减少泥岩中蒙脱石向伊利石的转化。在半干旱条件下,长石在埋藏过程中以封闭体系溶解,K+扩散到泥岩中,泥岩的钝化作用大于砂岩。该研究对古气候和成岩作用如何控制沉积岩中粘土矿物的转化提供了新的认识。
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引用次数: 0
A comprehensive analysis of the Cambrian Drumian carbon isotope excursion (DICE): Insights from paleoclimate, paleoenvironment and global correlations 寒武纪Drumian碳同位素漂移(DICE)的综合分析:来自古气候、古环境和全球相关性的启示
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-01 Epub Date: 2025-03-19 DOI: 10.1016/j.sedgeo.2025.106875
Qiang Gu , Fengcun Xing , Karem Azmy , Xin Jin , Xiaoquan Chen , Chunlin Zhang , Hongshan Qian , Jiao Wen
The Drumian Carbon Isotope Excursion (DICE) has been proposed as a potential marker for the Global Boundary Stratum Section and Point (GSSP) at the base of the Drumian. However, the characteristics of δ13C excursions (i.e., strength, number of subpeaks, and range of the excursion) show significant regional variability, necessitating further verification. Additionally, the paleoenvironmental conditions during the DICE event require deeper investigation to better understand their nature and mechanism. The current study examines carbon-isotope variations across the Qinglongshan section, a representative site within the Miaolingian–Furongian carbonate platform of the Ordos Basin, which spans the DICE event. The δ13C profile of the section documents several key carbon-isotope excursion events: the global Steptoean Positive Isotopic Carbon Excursion (SPICE, ∼2.5 ‰ positive excursion), DICE (∼4.0 ‰ negative excursion 1), and a potential globally negative excursion 2 (NE2, ∼3.5 ‰) which may correlate with the Drumian–Guzhangian boundary. These excursions are linked to major fluctuations in the carbon cycle and significant environmental changes. Sedimentological and geochemical analyses suggest that the DICE event coincided with marine transgression and a shift from warm and arid to more humid climate. The climate transition likely enhanced chemical weathering and increased terrestrial detrital input, leading to reduced salinity and intermittent anoxic conditions. Variations in seawater chemistry driven by sealevel and terrestrial input fluctuations likely contributed to the deposition of alternating red beds and negative excursion of DICE. Minor discrepancies in the stratigraphic position of the global δ13C peak may reflect uncertainties in biostratigraphy or limitations in data resolution. Moreover, terrestrial input is thought to have influenced both the amplitude of the peak negative δ13C values and the overall duration of the DICE event.
Drumian碳同位素偏移(DICE)已被提出作为全球边界地层剖面和点(GSSP)的潜在标志。但δ13C漂移的强度、子峰数和范围等特征表现出明显的区域差异,需要进一步验证。此外,DICE事件期间的古环境条件需要深入研究,以更好地了解其性质和机制。目前的研究考察了青龙山剖面的碳同位素变化,青龙山剖面是鄂尔多斯盆地苗岭—芙蓉期碳酸盐岩台地的一个代表性遗址,跨越了DICE事件。剖面的δ13C剖面记录了几个关键的碳同位素偏移事件:全球阶梯正同位素碳偏移(SPICE, ~ 2.5‰正偏移),DICE(~ 4.0‰负偏移1),以及可能与Drumian-Guzhangian边界相关的潜在全球负偏移2 (NE2, ~ 3.5‰)。这些偏差与碳循环的重大波动和重大环境变化有关。沉积学和地球化学分析表明,DICE事件与海侵同时发生,气候从温暖干旱向湿润气候转变。气候转变可能增强了化学风化作用,增加了陆地碎屑输入,导致盐度降低和间歇性缺氧条件。海平面和陆地输入波动驱动的海水化学变化可能导致交替红层沉积和DICE负偏移。全球δ13C峰值地层位置的微小差异可能反映了生物地层学的不确定性或数据分辨率的局限性。此外,陆地输入被认为影响了峰值负δ13C值的振幅和DICE事件的总持续时间。
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引用次数: 0
Sequence stratigraphy in continental endorheic basins: New contributions from the case of the northern extensional Teruel Basin 陆相内海盆地的层序地层学:来自北伸展特鲁埃尔盆地的新贡献
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-01 Epub Date: 2025-03-14 DOI: 10.1016/j.sedgeo.2025.106868
Lope Ezquerro , Carlos L. Liesa , José L. Simón , Aránzazu Luzón
The tectono-sedimentary analysis is a sequence stratigraphy method particularly useful in continental tectonically active basins far from the influence of sea level changes. It provides a comprehensive study of the sedimentary features and stratigraphic architecture of a basin focusing on the stratigraphical, mainly cyclic, trend of the rock record in order to define genetic (tectono-sedimentary units-TSUs) controlled by allocyclic factors: tectonics and climate. The tectono-sedimentary analysis has been traditionally used in basins related to compressive stress regimes, but their application in extensional basins is less common. In this work the results of the detailed tectono-sedimentary analysis of the northern Teruel Basin rocks are presented. Vertical and lateral distribution of mappable lithofacies associations reveal different depositional systems laterally related and the main paleogeographic changes from the Late Miocene to Early Gelasian (11–1.8 Myr). Five main alluvial progradational-retrogradational cycles integrate six TSUs with chronostratigraphical meaning, bounded by isochronous stratigraphic surfaces (sedimentary breaks) that represent maximum alluvial progradations, and define the basin geodynamic framework. A main challenge, not commonly addressed in this kind of studies, is the discrimination of the effects of tectonic and climate for each unit, which has been based on evidences of synsedimentary tectonism in combination with δ18OPDB isotope data. It is demonstrated that the sedimentary evolution was mainly controlled by the tectonics, with the phases of tectonic activity being consistently recorded as alluvial progradations (correlative lacustrine retractions) and climate only modulating (amplifying or vanishing) the tectonic effects. Certain guidelines are proposed to adequately recognize and characterize genetic units in continental extensional basins. Our results reinforce TSUs as very valuable tools for studying active continental basins far from sea level effects and to discriminate the influence of allogenic controls in sedimentation.
构造-沉积分析是一种层序地层学方法,特别适用于远离海平面变化影响的大陆构造活动盆地。它对盆地的沉积特征和地层构型进行了全面的研究,重点是岩石记录的地层(主要是旋回)趋势,以确定由构造和气候等非旋回因素控制的成因(构造-沉积单元- tsu)。构造-沉积分析传统上用于与压应力有关的盆地,但在伸展盆地中的应用较少。本文介绍了特鲁埃尔盆地北部岩石的详细构造-沉积分析结果。可测岩相组合的垂向和横向分布揭示了晚中新世至早格列世(11-1.8 Myr)不同的沉积体系横向相关和主要的古地理变化。五个主要的冲积进退旋回整合了六个具有年代地层意义的tsu,以代表最大冲积进积的等时地层面(沉积断裂)为界,并定义了盆地的地球动力学格局。基于同沉积构造作用的证据,结合δ18OPDB同位素数据,区分构造和气候对各单元的影响是这类研究中通常未解决的主要挑战。研究表明,沉积演化主要受构造控制,构造活动的阶段一致记录为冲积进积期(相关的湖泊退缩期),而气候只是调节(放大或消失)构造作用。提出了一些准则,以充分认识和表征大陆伸展盆地的成因单元。我们的研究结果表明,tsu是研究远离海平面影响的活动大陆盆地和区分同种异体控制对沉积的影响的非常有价值的工具。
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Sedimentary Geology
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