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Sustainable thermochemical energy storage through eco-friendly zeolites - A characterization study 生态友好型沸石可持续热化学储能的表征研究
4区 工程技术 Q2 Engineering Pub Date : 2023-09-03 DOI: 10.24200/sci.2023.59415.6231
Ankammarao Padamurthy, Jalaiah Nandanavanam, Parameshwaran Rajagopalan
Judicious utilization of natural resources always helps protect the environment from several ill-effects. This paper was aimed at exploring the merits of natural and environment friendly zeolites towards sustainable thermochemical energy storage. Sorption behaviour of selected zeolites were investigated using a differential thermogravimetric analyser. The desorption kinetics was studied by heating the materials from room temperature to 600 °C. The materials lose their water molecules on heating and become anhydrous mostly around 300 °C. The desorption enthalpies due to heating were noted to decrease with increase of heating rate, and found low for Zeolite-Mordenite (334.5 J g-1) and high for Molecular Sieves-4A (1060 J g-1). Materials’ adsorption enthalpies were determined by subjecting them to single cycle tests comprising of heating, cooling and hydration processes in sequence. The desorption and adsorption enthalpies of a single cycle were found to vary with the material and temperature program used. To understand the desorption and adsorption kinetics better, the materials were also tested on X-ray photoelectron spectroscopy, Brunauer–Emmet–Teller, and thermal constants analysers respectively for their elemental composition, structural properties, and thermal conductivity. This paper concludes that many of the naturally available zeolites stand as potential candidates for a sustainable thermochemical energy storage and recovery.
明智地利用自然资源总是有助于保护环境免受一些不良影响。本文旨在探讨天然和环境友好型沸石在可持续热化学储能方面的优点。用差示热重分析仪研究了所选沸石的吸附行为。通过将材料从室温加热到600℃,研究了解吸动力学。这些材料在加热时失去水分子,在300°C左右变得无水。升温解吸焓随升温速率的增加而降低,沸石-丝光沸石的解吸焓较低(334.5 J g-1),分子筛- 4a的解吸焓较高(1060 J g-1)。材料的吸附焓由加热、冷却和水化过程组成的单循环试验确定。发现单循环的解吸和吸附焓随所用材料和温度程序的不同而变化。为了更好地了解脱附和吸附动力学,我们还分别用x射线光电子能谱、brunauer - emet - teller和热常数分析仪对材料进行了元素组成、结构性质和导热系数的测试。本文的结论是,许多天然可用的沸石是可持续热化学能量储存和回收的潜在候选者。
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引用次数: 0
Functionally graded nanobeams subjected to large deflection by considering surface effects 考虑表面效应的功能梯度纳米梁的大挠度
4区 工程技术 Q2 Engineering Pub Date : 2023-09-03 DOI: 10.24200/sci.2023.60997.7113
Yasser Taghipour, Moslem Zeinali
In the current study, structurally graded nanobeams with distributed load are subjected to a large deflection analysis that takes surface effects into account. The nanobeams Young's elasticity modulus changes with thickness under a power-law function. The displacement elements are presented, generalization of the Young-Laplace formula is employed to account for the surface effects, and the total Lagrangian finite element formulation is utilized to get the outcomes by cracking the system of nonlinear differential equations founded on the Timoshenko beams theory. The reliability and correctness of the findings are confirmed by comparison with previously published publications. The investigation is done into how various characteristics, including length-to-thickness ratio, material gradient index, boundary conditions, and surface effects, affect the outcomes. The findings demonstrate that, in the presence of surface effects, residual surface tension plays a significant influence on the deflection of nanobeams. Additionally, a comparison of the power-law and exponential kinds of FG distribution is conducted in this study, and it is discovered that the FG materials with the power-law distribution are more applicable since they are less susceptible to surface effects than the exponential type.
在本研究中,考虑表面效应,对具有分布载荷的结构梯度纳米梁进行了大挠度分析。纳米梁的杨氏弹性模量随厚度呈幂律函数变化。提出了位移单元,推广了Young-Laplace公式来解释表面效应,并利用全拉格朗日有限元公式对建立在Timoshenko梁理论基础上的非线性微分方程组进行求解。通过与先前发表的出版物的比较,证实了研究结果的可靠性和正确性。研究了各种特性,包括长厚比、材料梯度指数、边界条件和表面效应如何影响结果。研究结果表明,在存在表面效应的情况下,残余表面张力对纳米梁的挠度有显著影响。此外,本研究还对幂律型和指数型FG分布进行了比较,发现幂律型FG材料比指数型FG材料更适用,因为它们不容易受到表面效应的影响。
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引用次数: 0
Moving Average Control Charts using Uncertain Information for Various Sampling Schemes 使用不确定信息的各种抽样方案的移动平均控制图
4区 工程技术 Q2 Engineering Pub Date : 2023-09-03 DOI: 10.24200/sci.2023.59210.6111
Muhammad Aslam, Srinivasa Rao Gadde, Nasrullah Khan
Present article proposes the neutrosophic moving average (NMA) control chart under neutrosophic statistics (NS) based on multiple dependent state (MDS), Repetitive and multiple dependent state repetitive (MDSR) sampling schemes. The neutrosophic moving average control chart is useful to monitor the process mean in the industries when the measurements expressed in terms of uncertainty or fuzzy or interval. In this circumstance, the existing monitoring designs could not be useful for the monitoring of mean accident or injury data. In the present investigation neutrosophic moving average control chart is developed under the NS. The chart coefficients of the proposed control chart are obtained using Monte Carlo simulation under NS. A comparative study between the three sampling schemes of neutrosophic moving average control chart under neutrosophic statistics (NS) is given. Two real examples from accident and injury data are taken to investigate the accomplishment of the proposed chart. Based on the simulation study and real data, the proposed chart is out performed over the existing control charts.
提出了基于多依赖状态(MDS)、重复(repeat)和多依赖状态重复(MDSR)采样方案的中性统计(NS)下的中性移动平均(NMA)控制图。中性移动平均控制图用于工业中测量值以不确定性、模糊性或区间表示时的过程均值监测。在这种情况下,现有的监测设计不能用于监测平均事故或伤害数据。在本研究中,在NS下建立了嗜中性移动平均控制图。采用蒙特卡罗仿真方法在NS条件下得到了控制图的图系数。对中性粒细胞统计(NS)下的三种中性粒细胞移动平均控制图抽样方案进行了比较研究。从事故和伤害数据的两个真实的例子来调查所提出的图表的完成。基于仿真研究和实际数据,本文提出的控制图优于现有的控制图。
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引用次数: 0
Development of an Appropriate Model for the Optional Lane-changing Rate in Weaving Segments with Short Lengths 短路段可选变道率模型的建立
4区 工程技术 Q2 Engineering Pub Date : 2023-09-03 DOI: 10.24200/sci.2023.58865.5937
Ali Kashani, Behrooz Shirgir, Shervin Sayyar
In order to compute level of service and density in weaving segments, the Highway Capacity Manual (HCM) defined for the first time in 2010 a relationship based on a lane change rate to assess the density of the weaving segment. It is critical to accurately estimate lane changing rate in these situations, but field observations in weaving segments shorter than 250 meters in Tehran, Iran revealed a significant difference between the HCM2016 model estimate and field data. The traffic and geometric data collected at 87 (15-minute) intervals from six weaving segments in Tehran were used to develop models for estimating lane changing rate in weaving segments. These 87 intervals were then divided into 69 (terrain data) for equations and 18 (test data) for model comparisons. Weaving volume and weaving segment area are introduced as two independent variables in the optional lane changing rate model of weaving vehicles in this study, with R2=0.74. Furthermore, for a lane-changing model of non-weaving vehicles with R2=0.95, two new variables of non-weaving volume and traffic solidity were defined. Finally, based on the 18 intervals used to test the results, it showed the improvement of the developed models results compared to HCM2016 models.
为了计算编织路段的服务水平和密度,公路通行能力手册(HCM)于2010年首次定义了基于变道率的关系来评估编织路段的密度。在这种情况下,准确估计换道率至关重要,但在伊朗德黑兰短于250米的编织段的现场观测显示,HCM2016模型估算值与现场数据存在显著差异。本文利用德黑兰6个编织路段87(15分钟)间隔收集的交通和几何数据,建立了估算编织路段变道率的模型。然后将这87个区间分为69个(地形数据)用于方程,18个(测试数据)用于模型比较。本研究将编织体积和编织段面积作为两个自变量引入编织车辆可选变道率模型,R2=0.74。在R2=0.95的非编织车辆变道模型中,定义了非编织体积和交通固体度两个新变量。最后,利用18个区间对结果进行检验,对比HCM2016模型,表明所开发模型的结果有较好的改善。
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引用次数: 0
On numerical solutions of Telegraph, viscous, and modified Burgers equations via Bernoulli collocation method 用伯努利配置法研究电报方程、粘性方程和修正Burgers方程的数值解
4区 工程技术 Q2 Engineering Pub Date : 2023-09-03 DOI: 10.24200/sci.2023.60051.6569
Waleed Adel, Hadi Rezazadeh, Mustafa Inc
The presented work aims to develop a novel technique for solving a general form of both linear and nonlinear partial differential equations (PDEs). This technique is based on applying a collocation method with the aid of Bernoulli polynomials and the use of such an algorithm to solve different types of PDEs. The method applies the regular finite difference scheme to convert the model equation into a system of a linear or nonlinear algebraic equation and then this system is solved using a novel iterative technique. Then, by solving this system an unknown coefficient is acquired and an approximate solution for the problems is achieved. Some test results of famous equations including the telegraph, viscous Burger, and modified Burger equations are presented to demonstrate the effectiveness of the proposed algorithm along with a comparison with other related techniques. The method proves to provide accurate results in terms of absolute error and through graphical representation of the solution.
提出的工作旨在发展一种新的技术来解决一般形式的线性和非线性偏微分方程(PDEs)。该技术是基于运用伯努利多项式的搭配方法,并利用该算法求解不同类型的偏微分方程。该方法采用正则有限差分格式将模型方程转化为线性或非线性代数方程组,然后采用一种新颖的迭代技术求解该方程组。然后,通过求解该系统得到一个未知系数,得到问题的近似解。通过对电报方程、粘性汉堡方程和修正汉堡方程等著名方程的测试结果,证明了该算法的有效性,并与其他相关技术进行了比较。结果表明,该方法在绝对误差和解的图形表示方面提供了准确的结果。
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引用次数: 0
Exfoliated Poly (styrene-co-urethane) Grafted - Polymethylmethacrylate /Layered Double Hydroxide Nanocomposite Synthesized by Metal Catalyzed Living Radical Polymerization and Solvent Blending Method 金属催化活性自由基聚合和溶剂共混法制备剥离聚苯乙烯-聚氨酯接枝聚甲基丙烯酸甲酯/层状双氢氧化物纳米复合材料
4区 工程技术 Q2 Engineering Pub Date : 2023-09-03 DOI: 10.24200/sci.2023.59942.6507
Mehdi Hosseinzadeh, Saber Ghasemi Karaj-Abad, Mehdi Rasizadeh, Mojtaba Abbasian
In this research, a facile strategy was employed for the synthesis of terpolymer derivatives from polystyrene (PSt), polyurethane (PU), poly (methyl methacrylate) (PMMA), and its organo-modified Zn Al LDH (layered double hydroxide) by in situ ATRP. For this purpose, firstly, LDH nanoparticles were modified with sodium dodecyl sulfonate (SDS) by the anion exchange reaction of Zn-Al-LDH. Secondly, PU macroinitiator was obtained from a solvent composed of 9-decen-1-ol and used in controlled graft copolymerization of styrene to afford PU-co-Pst copolymer. Then, the synthesized PU-co-St was brominated by N-bromosuccinimide (NBS) to obtain a copolymer with the bromine group. In the following, living radical polymerization of MMA was done in the presence of brominated PU-co-St and CuBr /Bpy (2, 2’-bipyridine catalyst to prepare the (PMMA-g-PSt-g-PU) terpolymer. Finally, (PMMA-g-PSt-g-PU)/ ZnAl LDH nanocomposite was successfully synthesized by the solution intercalation method. FE-SEM images showed that surface morphologies of Zn-Al (SDS) and Zn-Al-LDH leads to sheet-like and hexagonal morphology. Investigation of thermal properties using DSC and TGA exhibited that the prepared (PMMA-g-PSt-g-PU) /Zn-Al-LDH nanocomposite has a higher thermal stability compared to neat PU. The synthesized terpolymer and (PMMA-g-PSt-g-PU)/ Zn-Al-LDH nanocomposite can be used as a reinforcing agent for polymeric nanocomposites due to its high LDH properties.
本研究以聚苯乙烯(PSt)、聚氨酯(PU)、聚甲基丙烯酸甲酯(PMMA)及其有机改性Zn Al LDH(层状双氢氧化物)为原料,采用原位ATRP法合成了三元共聚物衍生物。为此,首先通过Zn-Al-LDH的阴离子交换反应,用十二烷基磺酸钠(SDS)修饰LDH纳米颗粒。其次,以9-十二-1-醇为溶剂制备PU宏观引发剂,并将其用于苯乙烯的可控接枝共聚制备PU-co- pst共聚物。然后,将合成的PU-co-St用n -溴代琥珀酰亚胺(NBS)溴化,得到与溴基共聚物。在溴化PU-co-St和CuBr /Bpy(2,2 ' -联吡啶催化剂的存在下,对MMA进行了活性自由基聚合,制备了(pmma -g- st -g- pu)三元共聚物。最后,通过溶液插层法制备了(PMMA-g-PSt-g-PU)/ ZnAl LDH纳米复合材料。FE-SEM图像显示,Zn-Al (SDS)和Zn-Al- ldh的表面形貌为片状和六边形。热性能的DSC和TGA研究表明,制备的(pmma -g- st -g-PU) /Zn-Al-LDH纳米复合材料与纯PU相比具有更高的热稳定性。所合成的三元共聚物和(pmma -g- st -g- pu)/ Zn-Al-LDH纳米复合材料具有较高的LDH性能,可作为高分子纳米复合材料的补强剂。
{"title":"Exfoliated Poly (styrene-co-urethane) Grafted - Polymethylmethacrylate /Layered Double Hydroxide Nanocomposite Synthesized by Metal Catalyzed Living Radical Polymerization and Solvent Blending Method","authors":"Mehdi Hosseinzadeh, Saber Ghasemi Karaj-Abad, Mehdi Rasizadeh, Mojtaba Abbasian","doi":"10.24200/sci.2023.59942.6507","DOIUrl":"https://doi.org/10.24200/sci.2023.59942.6507","url":null,"abstract":"In this research, a facile strategy was employed for the synthesis of terpolymer derivatives from polystyrene (PSt), polyurethane (PU), poly (methyl methacrylate) (PMMA), and its organo-modified Zn Al LDH (layered double hydroxide) by in situ ATRP. For this purpose, firstly, LDH nanoparticles were modified with sodium dodecyl sulfonate (SDS) by the anion exchange reaction of Zn-Al-LDH. Secondly, PU macroinitiator was obtained from a solvent composed of 9-decen-1-ol and used in controlled graft copolymerization of styrene to afford PU-co-Pst copolymer. Then, the synthesized PU-co-St was brominated by N-bromosuccinimide (NBS) to obtain a copolymer with the bromine group. In the following, living radical polymerization of MMA was done in the presence of brominated PU-co-St and CuBr /Bpy (2, 2’-bipyridine catalyst to prepare the (PMMA-g-PSt-g-PU) terpolymer. Finally, (PMMA-g-PSt-g-PU)/ ZnAl LDH nanocomposite was successfully synthesized by the solution intercalation method. FE-SEM images showed that surface morphologies of Zn-Al (SDS) and Zn-Al-LDH leads to sheet-like and hexagonal morphology. Investigation of thermal properties using DSC and TGA exhibited that the prepared (PMMA-g-PSt-g-PU) /Zn-Al-LDH nanocomposite has a higher thermal stability compared to neat PU. The synthesized terpolymer and (PMMA-g-PSt-g-PU)/ Zn-Al-LDH nanocomposite can be used as a reinforcing agent for polymeric nanocomposites due to its high LDH properties.","PeriodicalId":21605,"journal":{"name":"Scientia Iranica","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134948480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Diffraction by a Parallel-Plate Multiport Using the Method of Kobayashi Potentials 小林势法平行板多孔衍射
4区 工程技术 Q2 Engineering Pub Date : 2023-08-30 DOI: 10.24200/sci.2023.62039.7613
Babak Honarbakhsh
Application of Kobayashi potentials (KP) is extended to the electromagnetic (EM) diffraction from the parallel-plate multiport. Standard integral identities are used for problem formulation, without the direct use of Weber-Schafheitlin (WS) integrals. The Fourier function space is exploited for the construction of the governing linear system of equations. A simple strategy is suggested for the evaluation of the required improper integrals. Two-dimensional T- and X-junctions are studied as special cases. Numerical results are validated through convergence test and asymptotic analysis. It is shown that whenever the wave number in the whole problem domain is positive, no real power transfers to the diffracted field in the horizontal section of the aforementioned structures.
将小林势(KP)的应用扩展到平行板多孔口的电磁衍射。标准积分恒等式用于问题表述,而不直接使用韦伯-沙夫海特林(WS)积分。利用傅里叶函数空间来构造控制线性方程组。提出了一种简单的策略来计算所需的反常积分。二维T结点和x结点作为特例进行了研究。通过收敛性检验和渐近分析验证了数值结果。结果表明,当整个问题域中的波数为正时,在上述结构的水平截面上没有实际的功率传递给衍射场。
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引用次数: 0
Structural health monitoring of concrete arch dams using the wavelet transform and modal assurance criterion methods 基于小波变换和模态保证准则的混凝土拱坝结构健康监测
4区 工程技术 Q2 Engineering Pub Date : 2023-08-30 DOI: 10.24200/sci.2023.60688.6938
Amir Meysam Giahi, Jafar Asgari Marnani, Mohammad Sadegh Rohanimanesh, Hassan Ahmadi
Structural health monitoring of dams is a necessary issue in water supply network. Not identifying the local damages in these super structures and their extension could lead to abrupt and total collapse and impose major life or financial losses. This research investigates the effects of damage on the concrete arch dams and the methods for their detection. For this purpose the finite element model of a concrete arch dam was analyzed using the wavelet transform once by static frequency analysis and the second time when it is subjected to dynamic accelerograms. In the wavelet transform method using the static frequency analysis, cracks were formed on the dam body and the obtained results were compared to those obtained from Modal Assurance Criterion (MAC) method. In the wavelet transform method, by applying dynamic loads, different damage scenarios, including 16 damage locations and 3 damage levels (change in the materials properties) were compared to the healthy state of the dam. In order to process the wavelet transforms the displacements obtained from the modal and dynamic analyses were utilized. The results showed that employing wavelet transform method by applying dynamic loads could better detect the damages.
大坝结构健康监测是供水管网建设中必须解决的问题。不确定这些上层结构的局部损伤及其延伸可能导致突然和全面倒塌,并造成重大的生命或经济损失。本文对混凝土拱坝损伤的影响及其检测方法进行了研究。为此,利用小波变换对混凝土拱坝有限元模型进行了静频率分析和动加速度分析。采用静频分析的小波变换方法对坝体进行裂缝分析,并将分析结果与模态保证准则(MAC)方法进行比较。在小波变换方法中,通过施加动荷载,对大坝的16个损伤位置和3个损伤等级(材料性质变化)的不同损伤情景进行对比。为了处理小波变换,利用了模态和动力分析得到的位移。结果表明,采用小波变换方法加动载荷能较好地检测损伤。
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引用次数: 0
Two new numerical approaches for the fractional distribution of the model of a system of lakes via modified hat and quasi-hat functions 用修正帽函数和拟帽函数研究湖泊系统模型分数分布的两种新的数值方法
4区 工程技术 Q2 Engineering Pub Date : 2023-08-30 DOI: 10.24200/sci.2023.60120.6606
Jafar Biazar, hamed Ebrahimi
In this article, two numerical approaches are presented to solve a system of three fractional differential equations that express the pollution of lakes.In our recent study, a new class of hat functions, called quasi-hat functions (QHFs), are constructed.The proposed approaches utilize modified hat functions (MHFs) and quasi-hat functions (QHFs).Fractional-order operational of MHFs and QHFs are used to build algorithms that transform the main problem into a system of six equations with six unknowns and three equations with three unknowns, respectively.Absolute errors of obtained approximate solutions and convergence analysis of the utilized approach will be studied.Finally, three examples are provided to illustrate the capabilities of these algorithms.The pollution monitoring results are reported in some tables and figures for different values of $alpha$.
本文提出了两种数值方法来求解一个由三个分数阶微分方程组成的湖泊污染方程组。在我们最近的研究中,构造了一类新的帽函数,称为准帽函数(qhf)。所提出的方法利用修正帽函数(mhf)和准帽函数(QHFs)。利用mhf和QHFs的分数阶运算来构建算法,分别将主问题转化为六个六未知数方程和三个三未知数方程的系统。本文将研究所得到的近似解的绝对误差和所采用方法的收敛性分析。最后,给出了三个示例来说明这些算法的功能。在不同的$alpha$值下,用一些表格和图表报告了污染监测结果。
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引用次数: 0
Optimization-based Scheduling of Construction Projects with Generalized Precedence Relationships: A Real-Life Case Study 基于广义优先关系的建设项目优化调度:一个现实案例研究
4区 工程技术 Q2 Engineering Pub Date : 2023-08-30 DOI: 10.24200/sci.2023.59493.6275
Saman Aminbakhsh, Ary Ahmed
Concomitant reduction of cost and duration is recognized as one of the main aspects of construction planning. Expedition of project schedule naturally incurs extra costs due to implementation of more productive and/or high-price construction techniques. Meanwhile, a reduction in time is usually plausible only down to a certain limit, below which renders expeditions either technically or financially unviable. Thus, striking a reasonable balance between project cost and duration remains a desirable yet challenging task for which there has been a myriad of advancements and literature. Despite the many studies associated with this problem – referred to as time-cost trade-off problem (TCTP) – it is observed that only a few exercise TCTPs with generalized logical relationships. This observation holds despite the fact that generalized precedence relationships are imperative to introduce parallelism and to secure a realistic overlap among the activities. In this regard, a Simulated Annealing-based Genetic Algorithm as proposed herein, is specifically designed to provide the capability of exerting TCTPs with properly overlapped activities. Efficiency of this algorithm is tested over a wide range of problems and its performance is validated over a large-scale real-case construction project. Results of the hybridized GA indicate fast and robust convergence to high-quality solutions.
同时降低成本和工期被认为是施工规划的主要方面之一。由于实施更高效和/或高价格的施工技术,项目进度的延长自然会产生额外的成本。同时,将时间缩短到一定限度通常是可行的,低于这个限度,探险在技术上或经济上都是不可行的。因此,在项目成本和工期之间取得合理的平衡仍然是一项令人满意但具有挑战性的任务,已经有无数的进步和文献。尽管有许多研究与这个问题相关——被称为时间成本权衡问题(TCTP)——但据观察,只有少数研究将TCTP与广义逻辑关系结合起来。尽管普遍化的优先关系对于引入并行性和确保活动之间的实际重叠是必要的,但这个观察结果仍然成立。在这方面,本文提出了一种基于模拟退火的遗传算法,专门用于提供发挥具有适当重叠活动的TCTPs的能力。在广泛的问题上测试了该算法的效率,并在大规模的实际工程中验证了其性能。结果表明,混合遗传算法收敛速度快,鲁棒性好。
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引用次数: 0
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Scientia Iranica
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