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Investigation of the Water Draining Process Pushed by Gas for U-Type and Z-Type Manifolds 气体推动U型和Z型阀组排水过程的研究
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2022-01-21 DOI: 10.1155/2022/5555759
Weibao Li, Lei Yang, Junling Chen, Jiansheng Hu, B. Guo, Lili Zhu
In the experimental advanced superconducting tokamak (EAST), the cooling channels of plasma-facing components (PFCs) are familiarly connected in parallel through manifolds. According to the drainage performance of the PFCs, the amount of water trapped in the cooling channels is directly correlated with the type of manifolds. To date, manifold types have been well studied with respect to single-phase and mixed multiphase flow characteristics. However, there are few studies on the drainage performance relevant to the type of manifolds. The friction effect and inertia effect in the manifold intake and exhaust are studied through theoretical analysis. In addition, the draining liquid effect in the branches is dependent on the pressure difference and the resistance coefficient. Furthermore, U-type and Z-type manifolds are studied with FLUENT to discuss their drainage capability in this study. The distribution of the water volume fraction, pressure, and flow ratio is obtained to verify that the Z type is more effective than the U type when applied in the drainage process. This is also supported by comparing the experimental value of the two in drainage discharge. This study will provide a theoretical basis for future upgrades of EAST drainage systems.
在实验型先进超导托卡马克(EAST)中,面向等离子体元件(pfc)的冷却通道通常通过流形并联连接。根据PFCs的排水性能,冷却通道中截留水量与歧管的类型直接相关。迄今为止,关于单相和混合多相流动特性的流形已经得到了很好的研究。然而,目前国内外对管汇类型对排水性能的研究较少。通过理论分析,研究了歧管进排气过程中的摩擦效应和惯性效应。此外,分支的排水效果取决于压差和阻力系数。此外,本研究还对u型和z型歧管进行了FLUENT研究,探讨了它们的排水能力。得到了水体积分数、压力和流量比的分布,验证了Z型在排水过程中比U型更有效。比较两者在排水排放中的实验值也支持了这一点。本研究将为今后东岸排水系统的改造提供理论依据。
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引用次数: 4
Cracking Driving Force at the Tip of SCC under Heterogeneous Material Mechanics Model of Safe-End Dissimilar Metal-Welded Joints in PWR 压水堆安全端异种金属焊接接头非均质材料力学模型下SCC尖端裂纹驱动力
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2022-01-13 DOI: 10.1155/2022/6605101
Yuman Sun, H. Xue, K. Zhao, Yubiao Zhang, Y. Zhao, W. Yan, R. Bashir
The complicated driving force at the stress corrosion cracking (SCC) tip of the safe-end dissimilar metal-welded joints (DMWJs) in the pressurized water reactor (PWR) is mainly caused by the heterogeneous material mechanical properties. In this research, to accurately evaluate the crack driving force at the SCC in DMWJs, the stress-strain condition, stress triaxiality, and J-integral of the crack tip at different positions are analyzed based on the heterogeneous material properties model. The results indicate that the larger driving force will be provided for the I-type crack when the crack is in the SA508 zone and the interface between the 316L region and base metal. In addition, the heterogeneous material properties inhibit the J-integral of the crack in the 316L region, which has a promoting effect when the crack is in the SA508 zone and weld metal. It provides a new idea for analyzing driving force at the crack tip and safety evaluation of DMWJs in PWRs.
压水堆安全端异种金属焊接接头(DMWJs)尖端应力腐蚀开裂(SCC)的复杂驱动力主要是由材料力学性能的不均匀性引起的。本研究基于非均质材料特性模型,分析了裂纹尖端不同位置的应力-应变状态、应力三轴性和j积分,以准确评价DMWJs中SCC处的裂纹驱动力。结果表明:当裂纹位于SA508区和316L区与母材交界面处时,对i型裂纹的驱动力较大;此外,非均质材料性能抑制了316L区裂纹的j积分,而当裂纹位于SA508区和焊缝金属时,j积分有促进作用。为压水堆裂纹尖端驱动力分析和安全性评价提供了新的思路。
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引用次数: 0
Mechanical Properties Evaluation and Crack Propagation Behavior in Dissimilar Metal Welded Joints of 304 L Austenitic Stainless Steel and SA508 Low-Alloy Steel 304异种金属焊接接头力学性能评价及裂纹扩展行为 L奥氏体不锈钢和SA508低合金钢
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2022-01-12 DOI: 10.1155/2022/3038397
Yuman Sun, H. Xue, Fu-qiang Yang, Shuai Wang, Shun Zhang, Jinxuan He, R. Bashir
The material mechanical properties and crack propagation behavior of dissimilar metal welded joint (DMWJ) of pressurized water reactor (PWR) was investigated. In this research, the mechanical parameters of the cladding layer materials (304L-SA508) of the DMWJ in PWRs were obtained by the continuous indentation test. Simultaneously, the user-defined (USDFLD) subroutine in ABAQUS was used to establish the heterogeneous materials model of the welded joint. On this basis, the local crack propagation path of DMWJs has been discussed based on the extended finite element method (XFEM). The result indicated that the strength value at the fusion boundary line (FB line) is the largest, and the yield strength reaches 689 MPa. The yield stress values of the cladding metal (304 L) and base metal (SA508) are 371 MPa and 501 MPa, respectively. Affected by the material constraint effect of the DMWJ, the crack will propagate through the FB line when the initial crack is perpendicular to the FB line. And when the initial crack parallels the FB line, the crack will deviate from it. Meanwhile, the crack propagation length is smaller as the initial crack tip is closer to the FB line when the load condition is constant.
对压水堆异种金属焊接接头(DMWJ)的材料力学性能和裂纹扩展行为进行了研究。本研究通过连续压痕试验获得了压水堆中DMWJ包层材料(304L-SA508)的力学参数。同时,利用ABAQUS中的用户自定义(USDFLD)子程序建立焊接接头的非均质材料模型。在此基础上,基于扩展有限元法(XFEM)讨论了DMWJs的局部裂纹扩展路径。结果表明:熔合边界线(FB线)处强度值最大,屈服强度达到689 MPa;包层金属(304 L)和母材(SA508)的屈服应力值分别为371 MPa和501 MPa。受DMWJ材料约束效应的影响,当初始裂纹垂直于FB线时,裂纹将沿FB线扩展。当初始裂纹与FB线平行时,裂纹将偏离FB线。同时,当载荷条件一定时,裂纹扩展长度越小,初始裂纹尖端越靠近FB线。
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引用次数: 4
Control Rod Modeling and Worth Calculation for a Typical 1100 MWe Nuclear Power Plant Using WIMS/D4 and CITATION 基于WIMS/D4和CITATION的典型1100mwe核电站控制棒建模与价值计算
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2022-01-05 DOI: 10.1155/2022/6319628
Izza Shahid, Nadeem Shaukat, Amjad Ali, Meer Bacha, Ammar Ahmad, M. Siddique, R. Khan, Sajjad Tahir, Zeeshan Jamil
A typical 1100 MWe pressurized water reactor (PWR) is a second unit installed at the coastal site of Pakistan. In this paper, verification analysis of reactivity control worth by means of rod cluster control assemblies (RCCAs) for startup and operational conditions of this typical nuclear power plant (CNPP) has been performed. Neutronics analysis of fresh core is carried out at beginning of life (BOL) to determine the effect of grey and black control rod clusters on the core reactivity for startup and operating conditions. The combination of WIMS/D4 and CITATION computer codes equipped with JENDL-3.3 data library is used for the first time for core physics calculations of neutronic safety parameters. The differential and integral worth of control banks is derived from the computed results. The effect of control bank clusters on core radial power distribution is studied precisely. Radial power distribution in the core is evaluated for numerous configurations of control banks fully inserted and withdrawn. The accuracy of computed results is validated against the reference values of Nuclear Design Report (NDR) of 1100 MWe typical CNPP. It has been observed that WIMS-D4/CITATION shows its capability to effectively calculate the reactor physics parameters.
典型的1100兆瓦压水反应堆(PWR)是安装在巴基斯坦沿海地区的第二个机组。本文对该典型核电站(CNPP)在启动和运行条件下利用棒簇控制组件(RCCA)进行反应性控制的价值进行了验证分析。在使用寿命开始时(BOL)对新堆芯进行中子学分析,以确定灰色和黑色控制棒簇对启动和运行条件下堆芯反应性的影响。首次将配备JENDL-3.3数据库的WIMS/D4和CITATION计算机代码组合用于中子安全参数的堆芯物理计算。根据计算结果导出了控制组的微分值和积分值。精确地研究了控制组簇对堆芯径向功率分布的影响。针对完全插入和抽出的控制组的多种配置,评估堆芯中的径向功率分布。计算结果的准确性根据1100 MWe典型CNPP的核设计报告(NDR)的参考值进行了验证。据观察,WIMS-D4/CITATION显示了其有效计算反应堆物理参数的能力。
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引用次数: 1
Study on the Applicability of Neutron Radiation Damage Method Used for High-Temperature Superconducting Tape Based on Geant4 and SRIM 基于Geant4和SRIM的高温超导带中子辐射损伤方法的适用性研究
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-11-24 DOI: 10.1155/2021/2839746
Ying-Ying Zheng, Jinxing Zheng, Xudong Wang
High-temperature superconducting material is a promising candidate to fabricate superconducting magnet for magnetic confinement fusion reactors. The DPA number of the 1 µm thick superconducting layer in a high temperature superconducting tape under neutron irradiation needs to be calculated to predict the property changes. The DPA cross sections, which ignore the spatial distribution of vacancies caused by PKAs, are commonly used to obtain the results of the damage energy and DPA. However, for geometric models with the thickness as small as 1 µm, the energy and angular distribution of PKAs reveal that a significant number of PKAs with relatively high energy tend to scatter forward and cross the boundary of model, so the thickness of model has the potential to affect the number of displaced atoms. In this paper, we developed a method based on Geant4 and SRIM to evaluate the deviation of the traditional analytic method caused by the thickness. Geant4 is used to obtain the location, direction, and energy of PKAs, while SRIM is used to track every PKA and obtain damage energy and the number of displaced atoms. The radiation damage calculation of simple thin plate models with different thicknesses and the tape model are conducted with the neutron energies from 1 to 14 MeV. The results show that PKAs need to be tracked continuously for models with thickness less than 10 µm and the deviation of the analytic formulas increases rapidly with the decrease of thickness. For the superconducting layer composed of four different elements in the tape, the deviation also depends on the proportion of each atomic species and the neutron-atom interaction cross sections under different incident neutron energy.
高温超导材料是制备磁约束聚变堆用超导磁体的一种很有前途的候选材料。需要计算高温超导带中1µm厚超导层在中子辐照下的DPA数,以预测性能变化。DPA截面忽略了由PKAs引起的空位的空间分布,通常用于获得损伤能量和DPA的结果。然而,对于厚度小到1的几何模型 µm,PKA的能量和角度分布表明,大量能量相对较高的PKA倾向于向前散射并穿过模型的边界,因此模型的厚度有可能影响位移原子的数量。在本文中,我们开发了一种基于Geant4和SRIM的方法来评估传统分析方法因厚度引起的偏差。Geant4用于获得PKA的位置、方向和能量,而SRIM用于跟踪每个PKA并获得损伤能量和位移原子的数量。在中子能量为1~14的情况下,对不同厚度的简单薄板模型和带模型进行了辐射损伤计算 MeV。结果表明,对于厚度小于10的模型,需要连续跟踪PKA µm,解析公式的偏差随着厚度的减小而迅速增大。对于带中由四种不同元素组成的超导层,偏差还取决于每个原子种类的比例以及不同入射中子能量下的中子-原子相互作用截面。
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引用次数: 0
Xe Ion Irradiation-Induced Microstructural Evolution and Hardening Effect of Nickel-Base Superalloy Xe离子辐照诱导镍基高温合金组织演变及硬化效应
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-11-19 DOI: 10.1155/2021/5535478
Yu Hou, DeHui Li, Yan-Er Lu, Hefei Huang, WeiGuo Yang, Renduo Liu
The nickel-base superalloy Hastelloy N was irradiated using 1 MeV Xe20+ and 7 MeV Xe26+ ions with displacement damage ranging from 0.5 dPa to 10 dPa at room temperature (RT). The irradiated Ni-based superalloy was characterized with transmission electron microscopy (TEM), XRD, and nanoindenter to determine the changes in microstructural evolution and nanoindentation hardness. The TEM results showed that ion irradiation induced a large number of defects such as black spots and corrugated structures and the second phase was rapidly amorphized after being irradiated to a fluence of 0.5 dPa. The XRD results showed that the Hastelloy N alloy sample did not undergo lattice distortion after ion irradiation. An obvious irradiation hardening phenomenon was observed in this study, and the hardness increased with Xe ion fluence. The pinning effect in which the defects can become obstacles to the free movement of dislocation may be responsible for the irradiation-induced hardening.
采用1mev Xe20+和7mev Xe26+离子辐照镍基高温合金哈氏合金N,室温下位移损伤范围为0.5 ~ 10dpa。采用透射电子显微镜(TEM)、x射线衍射仪(XRD)和纳米压痕仪对辐照后的镍基高温合金进行了表征,以确定其显微组织演变和纳米压痕硬度的变化。TEM结果表明,在0.5 dPa的辐照下,离子辐照引起了大量的黑点和波纹结构等缺陷,第二相迅速非晶化。XRD结果表明,离子辐照后的哈氏合金样品未发生晶格畸变。在本研究中观察到明显的辐照硬化现象,硬度随Xe离子的影响而增大。钉住效应使缺陷成为位错自由运动的障碍,这可能是辐照诱发硬化的原因。
{"title":"Xe Ion Irradiation-Induced Microstructural Evolution and Hardening Effect of Nickel-Base Superalloy","authors":"Yu Hou, DeHui Li, Yan-Er Lu, Hefei Huang, WeiGuo Yang, Renduo Liu","doi":"10.1155/2021/5535478","DOIUrl":"https://doi.org/10.1155/2021/5535478","url":null,"abstract":"The nickel-base superalloy Hastelloy N was irradiated using 1 MeV Xe20+ and 7 MeV Xe26+ ions with displacement damage ranging from 0.5 dPa to 10 dPa at room temperature (RT). The irradiated Ni-based superalloy was characterized with transmission electron microscopy (TEM), XRD, and nanoindenter to determine the changes in microstructural evolution and nanoindentation hardness. The TEM results showed that ion irradiation induced a large number of defects such as black spots and corrugated structures and the second phase was rapidly amorphized after being irradiated to a fluence of 0.5 dPa. The XRD results showed that the Hastelloy N alloy sample did not undergo lattice distortion after ion irradiation. An obvious irradiation hardening phenomenon was observed in this study, and the hardness increased with Xe ion fluence. The pinning effect in which the defects can become obstacles to the free movement of dislocation may be responsible for the irradiation-induced hardening.","PeriodicalId":21629,"journal":{"name":"Science and Technology of Nuclear Installations","volume":" ","pages":""},"PeriodicalIF":1.1,"publicationDate":"2021-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46305549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Technical Options and Cost Estimates for Spent Nuclear Fuel Management at the Barakah Nuclear Power Plants 巴拉卡核电站乏燃料管理的技术选择和成本估算
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-11-12 DOI: 10.1155/2021/3133433
Shadwan M. M. Esmail, J. Cheong
In the planning and management of the interim storage of spent nuclear fuel, the technical and economic parameters that are involved have a significant role in increasing the efficiency of the storage system. Optimal parameters will reduce the total economic costs for countries embarking on nuclear energy, such as the UAE. This study evaluated the design performance and economic feasibility of various structures and schedules, to determine an optimal combination of parameters for the management of spent nuclear fuel. With the introduction of various storage technology arrangements and expected costs per unit for the storage system design, we evaluated eight major scenarios, each with a cost analysis based on technological and economic issues. We executed a number of calculations based on the use of these storage technologies, and considered their investment costs. These calculations, which were aligned with the net present value approach and conducted using MS Project and MATLAB software programs, considered the capacities of the spent fuel pools and the amount of spent nuclear fuel (SNF) that will be transferred to dry storage facilities. As soon as they sufficiently cool, the spent nuclear fuel is to be stored in a pool storage facility. The results show that applying a centralized dry storage (CDS) system strategy is not an economically feasible solution, compared with using a permanent disposal facility (PDF) (unless the variable investment cost is reduced or changed). The optimal strategy involves operating a spent fuel pool island (SFPI) storage after the first 20 years of the start of the permanent shutdown of the reactor. After 20 years, the spent fuel is then transferred to a PDF. This strategy also results in a 20.9% to 26.1% reduction in the total cost compared with those of the other strategies. The total cost of the proposed strategy is approximately 4,307 million USD. The duration of the fuel storage and the investment cost, particularly the variable investment cost, directly affect the choice of facility storage.
在乏核燃料临时储存的规划和管理中,所涉及的技术和经济参数在提高储存系统的效率方面发挥着重要作用。最佳参数将降低阿联酋等核能国家的总经济成本。本研究评估了各种结构和时间表的设计性能和经济可行性,以确定乏核燃料管理的最佳参数组合。随着各种存储技术安排的引入和存储系统设计的单位预期成本,我们评估了八个主要场景,每个场景都基于技术和经济问题进行了成本分析。我们根据这些存储技术的使用情况进行了大量计算,并考虑了它们的投资成本。这些计算与净现值法一致,并使用MS Project和MATLAB软件程序进行,考虑了乏燃料池的容量和将转移到干式储存设施的乏核燃料(SNF)的量。一旦它们充分冷却,乏核燃料将被储存在水池储存设施中。结果表明,与使用永久处置设施(PDF)相比,应用集中干式储存(CDS)系统策略在经济上不是可行的解决方案(除非可变投资成本降低或改变)。最佳策略包括在第一个20 反应堆开始永久停堆的年份。20之后 几年后,乏燃料被转移到PDF中。与其他策略相比,该策略还使总成本降低了20.9%至26.1%。拟议战略的总成本约为43.07亿美元。燃料储存的持续时间和投资成本,特别是可变投资成本,直接影响设施储存的选择。
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引用次数: 0
Benchmark Analysis on Loss-of-Flow-without-Scram Test of FFTF Using Refined SAC-3D Models 基于改进SAC-3D模型的FFTF无断流测试基准分析
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-11-10 DOI: 10.1155/2021/5843910
Si-Chan Lyu, D. Lu, D. Sui
The Fast Flux Test Facility (FFTF) is a liquid sodium-cooled nuclear reactor designed by the Westinghouse Electric Corporation for the U.S. Department of Energy. In July 1986, a series of unprotected transients were performed to demonstrate the passive safety of FFTF. Among these, a total of 13 loss-of-flow-without scram (LOFWOS) tests were conducted to confirm the liquid metal reactor safety margins, provide data for computer code validation, and demonstrate the inherent and passive safety benefits of specific design features. In our preliminary work, we have performed relatively coarse modeling of the FFTF. To better predict the transient behavior of FFTF LOFWOS test #13, we modeled it using a more refined thermal-hydraulics model. In this paper, we simulate FFTF LOFWOS test #13 with the system safety analysis code SAC-3D according to the benchmark specifications provided by Argonne National Laboratory (ANL). The simulation range includes the primary and secondary circuits. The reactor core was modeled by the built-in 3D neutronics calculation module and the parallel-channel thermal-hydraulics calculation module. To better predict the reactivity feedback introduced by coolant level variations within the GEMs, a real-time macro cross-section homogenization processing module was developed. The steady-state power distribution was calculated as the transient simulation initial boundary conditions. In general, both the steady-state calculation results and the whole-plant transient behavior predictions are in good agreement with the measured data. The relatively large deviations in transient simulation occur in the outlet temperature predictions of the PIOTA in row 6. It can be preliminarily explained by the reason for neglecting the heat transfer between channels in this model.
快速通量试验设施(FFTF)是一个由西屋电气公司为美国能源部设计的液态钠冷却核反应堆。1986年7月,进行了一系列无保护瞬态试验,以证明FFTF的被动安全性。其中,共进行了13次无紧急停堆流量损失(LOFWOS)试验,以确认液态金属反应堆安全裕度,为计算机代码验证提供数据,并证明特定设计特征的固有和被动安全优势。在我们的初步工作中,我们对FFTF进行了相对粗略的建模。为了更好地预测FFTF LOFWOS试验#13的瞬态行为,我们使用更精细的热工水力学模型对其进行了建模。在本文中,我们根据阿贡国家实验室(ANL)提供的基准规范,用系统安全分析代码SAC-3D模拟了FFTF LOFWOS测试#13。模拟范围包括初级电路和次级电路。反应堆堆芯由内置的三维中子学计算模块和并联通道热工水力学计算模块建模。为了更好地预测GEM内冷却剂液位变化引入的反应性反馈,开发了一个实时宏观截面均匀化处理模块。稳态功率分布被计算为瞬态模拟的初始边界条件。总的来说,稳态计算结果和整个电厂的瞬态行为预测都与实测数据吻合良好。瞬态模拟中相对较大的偏差出现在第6行PIOTA的出口温度预测中。这可以通过在该模型中忽略通道之间的传热来初步解释。
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引用次数: 3
Dissolution Behavior of Simulated Spent Nuclear Fuel in LiCl-KCl-UCl3 Molten Salt 模拟乏核燃料在LiCl-KCl-UCl3熔盐中的溶解行为
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-11-02 DOI: 10.1155/2021/9048775
Sang‐Kwon Lee, Sung-Wook Kim, Junmyoung Jang, M. Jeon, E. Choi
Considering the necessity of the development of methods to reduce the burden of storage and disposal of high-level radioactive waste, in this study, we propose a nuclide separation technique using molten salt immersion. The dissolution behavior of simulated spent nuclear fuels (SSFs) immersed in a LiCl-KCl-UCl3 (LKU) molten salt at 500°C was investigated using a combination of thermodynamic and experimental studies. Surrogates of transuranic elements (TRUs), that is, rare earth elements (REs), in the SSFs were dissolved into the molten salt without any damage to the UO2 structure of the SSFs. The results suggest that the LKU salt technique can be used to separate REs and, potentially, TRUs from actual spent nuclear fuels (SNFs). It is thought that this technique is advantageous over the conventional TRU recovery techniques because the majority of the SNFs (i.e., UO2) remained stable, thus reducing the process burden. Several SNF treatment process options using this technique were suggested. This study will serve as a guide for future studies on the management of high-level waste discharged from nuclear reactors.
考虑到开发减少高放射性废物储存和处置负担的方法的必要性,在本研究中,我们提出了一种使用熔盐浸渍的核素分离技术。结合热力学和实验研究,研究了500°C下浸入LiCl-KCl-UCl3(LKU)熔盐中的模拟乏核燃料(SSFs)的溶解行为。SSF中超铀元素(TRUs)的替代物,即稀土元素(RE),溶解在熔融盐中,而不对SSF的UO2结构造成任何损害。结果表明,LKU盐技术可用于从实际乏核燃料(SNF)中分离RE,并可能分离TRU。人们认为,与传统的TRU回收技术相比,该技术是有利的,因为大多数SNF(即UO2)保持稳定,从而减少了工艺负担。提出了使用该技术的几种SNF处理工艺选择。这项研究将为未来核反应堆排放的高水平废物管理研究提供指导。
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引用次数: 0
Electrochemical Deposition of U and RE Elements Using the Stirred Liquid Cadmium Cathode in LiCl-KCl Molten Salts 用搅拌液镉阴极在LiCl-KCl熔盐中电化学沉积U和RE元素
IF 1.1 4区 工程技术 Q3 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-10-28 DOI: 10.1155/2021/5788732
Gha-Young Kim, C. Lee, D. Yoon, Junhyuk Jang, Sung-Jai Lee
This study was conducted in an attempt to understand the effect of a stirred liquid cadmium cathode (LCC) on the electrodeposition of U and U/RE on Cd. For this purpose, a series of electrowinning tests were performed using an LCC equipped with a Cd stirrer. Initially, three runs of the U electrodeposition tests were conducted using LiCl-KCl-UCl3 at 500°C under a constant current. From the results obtained from the initial three runs, it was found that the maximum deposited amount of U was 7.4 wt% U/Cd. U dendrite formation on the LCC crucible was not observed across each of the three runs. Three additional runs were conducted using LiCl-KCl-UCl3-RECl3 to determine the extent of U/RE electrodeposition. The maximum number of moles of U + RE metals deposited was 0.07, a value estimated to be 2.14 times higher than the solubility limits exhibited by these metals in Cd. The results of this study show that the use of a Cd stirrer significantly improves the extent of U deposition.
本研究旨在了解搅拌液体镉阴极(LCC)对U和U/RE在Cd上电沉积的影响。为此,使用配备Cd搅拌器的LCC进行了一系列电积试验。最初,使用LiCl-KCl-UCl3在500°C恒流条件下进行了三次U电沉积试验。从前三次运行的结果来看,U的最大沉积量为7.4 wt% U/Cd。LCC坩埚上U枝晶的形成在三次运行中都没有观察到。使用LiCl-KCl-UCl3-RECl3进行了另外三次运行,以确定U/RE电沉积的程度。U + RE金属沉积的最大摩尔数为0.07,估计是这些金属在Cd中的溶解度极限的2.14倍。本研究结果表明,使用Cd搅拌器显著提高了U的沉积程度。
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引用次数: 1
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Science and Technology of Nuclear Installations
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