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Efficient Adsorption of Acid Black 52 from Aqueous Solution by Biochar Prepared from Deoiled Algae Biomass: Process Optimization 脱油藻类制备的生物炭对水溶液中酸性黑52的高效吸附:工艺优化
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4173
P. Nautiyal, Ashok Kumar
The attempt was made to prepare the novel biochar (BC) from deoiled Spirulina platensis algae biomass (DB) which was obtained after single stage oil extraction and transesterification. The adsorption capacity of biochar for acid black 52 dye (AO) removal from individual aqueous solution was investigated. The optimization of process parameters such as effect of initial concentration of AO dye, dosage of adsorbent and the pH of the given solution on the dye adsorption was also examined. The results from the experiments were further compared with those obtained with commercially available activated carbon (AC). The results showed that with the rise in initial concentration of dye from 30 mg/l till 90 mg/l, there was rise in the percentage removal of dye from 86.67% to 89.84%. The percentage dye removal to some extent got improved from 86.60% to 87.80% using biochar while increasing the dosage of adsorbent from 0.2 to 1 g/100 ml. The removal of dye declined from 88.44% to 85.80% using BC while increasing pH from 2 to 10. From the results obtained, it can be concluded that biochar is a potential adsorbent for dye removal, thus supporting the sustainability of biodiesel from algae.
以单段提油和酯交换得到的脱油型螺旋藻(DB)为原料,尝试制备新型生物炭(BC)。研究了生物炭对单个水溶液中酸性黑52染料(AO)的吸附能力。考察了AO染料初始浓度、吸附剂投加量、溶液pH等工艺参数对染料吸附性能的影响。实验结果进一步与市售活性炭(AC)得到的结果进行了比较。结果表明,随着染料初始浓度从30 mg/l增加到90 mg/l,染料去除率由86.67%增加到89.84%。当吸附剂投加量从0.2 g/100 ml增加到1 g/100 ml时,生物炭对染料的去除率从86.60%提高到87.80%,而当pH从2增加到10时,BC对染料的去除率从88.44%下降到85.80%。从得到的结果可以得出结论,生物炭是一种潜在的脱除染料的吸附剂,从而支持藻类生物柴油的可持续性。
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引用次数: 0
Application of Mercaptostyrene Divinyl Benzene Immobilized on Ion-Exchange Polymeric Membrane as Hg(II) Sensor 巯基苯乙烯-二乙烯基苯固定在离子交换膜上作为汞(II)传感器的应用
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4174
Abdellah Hamel, K. Morakchi, A. Bendjama, Hiba Mahfoud, Rochedi Kherrat
Herein, we report the fabrication of electrochemical sensor for the detection of mercury Hg(II) ions using macroporous divinyl benzene immobilized on ion-exchange polymeric ionophore. Impedance spectroscopy was adopted to examine the performance of the fabricated sensor. Various experiments were done to get the optimized experimental conditions of the fabricated sensor. The fabricated sensor demonstrates a linear range of 10–8 to 10–5 M and low detection limit was about 10–4.8 M.
本文报道了用离子交换聚合物离子载体固定化大孔二乙烯基苯制备检测汞汞离子的电化学传感器。采用阻抗谱法对传感器的性能进行了测试。通过各种实验得到了该传感器的最佳实验条件。该传感器的线性范围为10-8 ~ 10-5 M,低检测限约为10-4.8 M。
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引用次数: 0
Design and Analysis of Micro-Opto-Mechanical System Cantilever Integrated with Photonics Waveguide for Pressure Sensing Applications 用于压力传感的光子波导微光机械系统悬臂梁的设计与分析
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4178
Veer Chandra, Rakesh Ranjan
In this work, the pressure sensing approach based on the Micro-Opto-Mechanical System (MOMS) cantilever integrated with waveguide structure has been explored. The MOMS based photonic sensors are drawing attention because of their high sensing capabilities. In the design of MOMS based cantilever pressure sensor, mainly two different waveguide structures, Rib and Slot waveguides have been considered. The deviation in light intensity at the output of the waveguide structure is mainly used to analyze the amount of exerted pressure at the free-end of cantilever. Using the different waveguide parameters such as, effective mode area, light intensity variations, etc., the performance comparison between Rib and Slot waveguides have been done. The relationship between the normalized light intensity at the waveguide output corresponding to the applied pressure has been established from the relationship between the deflection versus pressure and normalized intensity versus deflection. It has been anticipated that the performance of pressure sensor using Slot waveguide is significantly better than the Rib waveguide for some application.
本文研究了基于微光机械系统悬臂梁与波导结构集成的压力传感方法。基于mom的光子传感器以其高传感能力而备受关注。在基于mom的悬臂式压力传感器的设计中,主要考虑了肋波导和槽波导两种不同的波导结构。光强在波导结构输出端的偏差主要用于分析悬臂梁自由端施加的压力。利用不同的波导参数,如有效模面积、光强变化等,对肋波导和槽波导的性能进行了比较。从偏转与压力的关系和归一化强度与偏转的关系,建立了波导输出处对应于施加压力的归一化光强之间的关系。研究表明,在某些应用中,采用槽波导的压力传感器的性能明显优于肋波导。
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引用次数: 0
Numerical Analysis and Optimal Design of All-Optical Fiber Differential Acceleration Sensor 全光纤差分加速度传感器的数值分析与优化设计
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4175
Ya‐Lin Li, Xiaoqian Cui, X. Fang
In order to improve the sensitivity of measurement and realize its miniaturization, an all-optical fiber differential acceleration sensor is studied. This sensor adopts a novel four-port ring fiber coupler, which can realizes the difference of optical signals and the isolation of light source and optical signal. Therefore, the sensitivity of this sensor is doubled compared with that of traditional fiber sensors. The stress–strain relationship simulation results of the sensor probe model show that with the increase of the measured acceleration value, the relative sensitivity, relative resolution, and relative error of the sensor all decrease. In the structural parameters of the probe-sensitive unit, the film thickness has the greatest influence on the performance of the sensor. The radius of the diaphragm 65 μm, a thickness of 2 μm, taking the thickness of the center of mass 20 μm, the mass 20 μm taken radius conditions, sensitivity of this fiber acceleration sensor is not less than 0.0025 m–1 · s2, less than 2% error, the linear measuring range of 0 to 2800 m · s–2. This design combines microelectronics and optical fiber technology, which can more easily realize the miniaturization and multi-function of acceleration sensor.
为了提高测量灵敏度,实现传感器的小型化,对全光纤差分加速度传感器进行了研究。该传感器采用新颖的四端口环形光纤耦合器,实现了光信号的差分以及光源与光信号的隔离。因此,与传统光纤传感器相比,该传感器的灵敏度提高了一倍。传感器探头模型的应力-应变关系仿真结果表明,随着测量加速度值的增大,传感器的相对灵敏度、相对分辨率和相对误差均减小。在探头敏感单元的结构参数中,薄膜厚度对传感器的性能影响最大。膜片的半径为65 μm,厚度为2 μm,取质量中心的厚度为20 μm,取质量中心的半径为20 μm的条件下,该光纤加速度传感器的灵敏度不小于0.0025 m - 1·s2,误差小于2%,线性测量范围为0 ~ 2800 m·s-2。本设计结合了微电子技术和光纤技术,更容易实现加速度传感器的小型化和多功能化。
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引用次数: 0
A Refractive Index Based Micro-Structured Sensor for Blood Components Detection in Terahertz Regime 基于折射率的太赫兹血液成分检测微结构传感器
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4186
Md. Ahasan Habib
In this article, a hexagonal packing photonic crystal fiber based optical sensor is presented and analyzed for different blood components identification using terahertz (THz) signal. The numerical analysis of the proposed sensor is performed by using finite element method based software Comsol V5.0. The proposed fiber is investigated in terahertz frequency spectrum from 1.3 THz to 2.5 THz for higher relative sensitivity and numerical aperture as well as lower absorption loss and confinement loss for better sensing applications. The reported hollow core fiber provide better interaction of light and the analytes, so that high relative sensitivity of 83.45%, 81.20%, 80.78%, 79.60% and 78.80% are obtained for RBCs, Hemoglobin, WBCs, Plasma and Water respectively at a particular geometric condition. Moreover, very low confinement loss and absorption loss with high numerical aperture is offered by the proposed sensor in terahertz spectrum. This optical sensor may be an alternative option to detect blood components present in the blood in a very efficient manner.
本文提出并分析了一种基于六方填料光子晶体光纤的光传感器,利用太赫兹(THz)信号对不同血液成分进行识别。采用基于Comsol V5.0的有限元软件对所设计的传感器进行了数值分析。该光纤在1.3太赫兹到2.5太赫兹的太赫兹频谱范围内进行了研究,以获得更高的相对灵敏度和数值孔径,以及更低的吸收损耗和约束损耗,从而获得更好的传感应用。所报道的空心芯光纤提供了更好的光与被分析物的相互作用,因此在特定几何条件下,对红细胞、血红蛋白、白细胞、血浆和水分别获得了83.45%、81.20%、80.78%、79.60%和78.80%的相对灵敏度。此外,该传感器在太赫兹频谱上具有非常低的约束损耗和高数值孔径的吸收损耗。这种光学传感器可能以一种非常有效的方式检测血液中存在的血液成分的替代选择。
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引用次数: 9
Acoustical Studies on Beryllium Oxide/Silicone Oil Nanofluids 氧化铍/硅油纳米流体的声学研究
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4191
T. M. A. Britto, A. Jeevaraj
Molecular interactions of Silicone oil based Beryllium oxide nanofluids have been studied using ultrasonic parameters at room temperature. BeO nanoparticles synthesized by chemical precipitation method was used to prepare silicone oil based BeO nanofluids. BeO nanofluids were prepared by dispersing synthesized BeO nanoparticles in the Silicone Oil base fluid with the help of sonication. Ultrasonic velocity for particle-fluid mixtures of Silicone oil with BeO has been carried out for different volume fraction (0 to 0.003) at 0.0005 intervals at room temperature. The data experimentally measured has been used to estimate the various acoustical and thermodynamical parameters. The behavior of these parameters in this particle fluid system has been discussed in terms of inter/intramolecular interactions with respect to concentration. The particle base fluid molecular interactions in the nanofluids cause an increment in velocity value of Silicone oil based nanofluids. The propagation of ultrasonic waves causes impedance which increases the intermolecular distance between the molecules. The transmission and reflection modes of sound waves in the nanoparticle and base fluid molecules are noted by the specific acoustic impedance. It is noted that the acoustic impedance value increases with rise in concentration owing to the molecular interaction between BeO and silicone oil fluid molecules affecting the structural arrangement.
在室温下,利用超声参数研究了硅油基氧化铍纳米流体的分子相互作用。利用化学沉淀法合成的BeO纳米颗粒制备硅油基BeO纳米流体。利用超声波将合成的BeO纳米颗粒分散在硅油基液中制备BeO纳米流体。在室温下,对不同体积分数(0 ~ 0.003)的硅油- BeO颗粒-流体混合物在0.0005间隔下的超声速度进行了研究。实验测量的数据被用来估计各种声学和热力学参数。从分子间/分子内相互作用的角度讨论了这些参数在颗粒流体系统中的行为。纳米流体中粒子基流体与分子的相互作用使硅油基纳米流体的流速值增大。超声波的传播引起阻抗,从而增加了分子间的距离。声波在纳米粒子和基流体分子中的传播和反射模式由特定的声阻抗来记录。由于BeO与硅油流体分子之间的分子相互作用影响了结构排列,声阻抗值随浓度的增加而增加。
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引用次数: 1
Enhanced Thermal Conductivity of Carboxyl (–COOH) Functionalized Multi-Walled Carbon Nanotube (MWCNT)-Silicone Oil Based Nanofluids 羧基(-COOH)功能化多壁碳纳米管(MWCNT)-硅油基纳米流体的热导率增强
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4188
M. Premalatha, N. Preetha, S. Padmavathi, A. Jeevaraj
Thermal conductivity and viscosity studies of carboxyl (–COOH) functionalized multi-walled carbon nanotubes-Silicone oil nanofluids were discussed in this work. Carboxyl (–COOH) functionalized MWCNT-Silicone oil nanofluids were prepared in various concentration ranges from 0.001 to 0.005 g of COOH-MWCNT and characterized at a range of temperatures between 303 K to 323 K. The thermal conductivity of carboxyl (–COOH) functionalized MWCNT-Silicone oil nanofluids increases with the raise in concentration of MWCNTs and also with the raise in temperatures. Mechanism for the enhancement of Silicone oil with concentration of MWCNT is due to the percolation of heat through the nanotubes through axial direction than through radial direction. Because of large aspect ratio of nanotubes heat transfer inside MWCNTs is also more. Also, as the temperature increases the viscosity of the (–COOH) functionalized MWCNT-Silicone oil nanofluids decreases, because CNT aggregation kinetics may contribute resulting in enhanced thermal conductivity.
对羧基(-COOH)功能化多壁碳纳米管-硅油纳米流体的导热性和粘度进行了研究。羧基(-COOH)功能化的mwcnt -硅油纳米流体在0.001 ~ 0.005 g COOH-MWCNT的浓度范围内制备,在303 ~ 323 K的温度范围内表征。羧基(-COOH)功能化MWCNTs -硅油纳米流体的导热系数随MWCNTs浓度的升高和温度的升高而增加。硅油随纳米碳管浓度的增加而增强的机理是由于热通过纳米管的轴向渗透而不是径向渗透。由于纳米管宽高比大,纳米碳纳米管内部的传热也更多。此外,随着温度的升高,(-COOH)功能化的mwcnt -硅油纳米流体的粘度降低,因为碳纳米管的聚集动力学可能导致导热性增强。
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引用次数: 1
Improvement of the Vibratory Analysis by Enhancement of Accelerometer Characteristics 通过增强加速度计特性来改进振动分析
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4185
S. Belkhiri, Z. Ghemari, S. Saad, Ghania Boudechiche
In this work, the mathematical model suitable for the operating principle of the piezoelectric accelerometer is extracted then this model which connects the accuracy and the measurement error according of the frequency ration and the damping rate is validated by simulation. The model developed makes it possible to improve the performances of the accelerometer such as precision, sensitivity and reliability as well as to propose a new conception of the latter. A comparative study is made to show the importance of our results compared to literature, these results have showed that a suitable and appropriate choice of damping ratio develops the accelerometer parameters and enhances the vibratory analysis technique.
在此基础上,提出了适用于压电加速度计工作原理的数学模型,并通过仿真验证了该模型根据频率比和阻尼率将精度与测量误差联系起来。该模型的建立为提高加速度计的精度、灵敏度和可靠性等性能提供了可能,并提出了加速度计的新概念。结果表明,阻尼比的选择对加速度计参数的发展和振动分析技术的提高具有重要意义。
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引用次数: 0
Anionic Surfactant Sensing by Optical Properties of Erythrosin B 阴离子表面活性剂对红素B光学性质的传感
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4177
Zainab Saberi
The nonlinear optical properties, absorbance and fluorescence spectra of Erythrosin B (ErB) aqueous solution in different CTAB concentration was studied. Z-scan technique under laser light excitation at 532 nm, was used for study reverse saturable absorption (RSA) of ErB. it was observed that the RSA of solution depend on CTAB concentration. A enhancing of absorbance and quenching of fluorescence is observed with increase of CTAB concentration in solution and the RSA can reduce the fluorescence intensity. It was proposed that the micelle can reduce the dye aggregation is solutions and it can affect on linear and nonlinear optical properties of ErB.
研究了红素B (ErB)水溶液在不同CTAB浓度下的非线性光学性质、吸光度和荧光光谱。采用532 nm激光激发下的z扫描技术,研究了ErB的反饱和吸收(RSA)。观察到溶液的RSA与CTAB浓度有关。随着溶液中CTAB浓度的增加,荧光的吸光度增强和猝灭,RSA可以降低荧光强度。提出胶束可以减少染料在溶液中的聚集,并影响ErB的线性和非线性光学性质。
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引用次数: 0
Tango Binary Search Tree Based Asymmetric Cryptographic Sensor Node Authentication for Secured Communication in Wireless Sensor Networks 基于Tango二叉搜索树的无线传感器网络安全通信非对称加密传感器节点认证
Pub Date : 2020-01-01 DOI: 10.1166/sl.2020.4189
A. Cynthia, V. Saravanan
Wireless sensor network (WSN) comprises the group of sensor nodes distributed to sense and monitor the environments and collects the data. Due to the distributed nature of the sensor nodes, security is a major role to access the confidential data and protect the unauthorized access. In order to improve the secure communication, authentication is essential process in WSN. A Tango Binary Search Tree based Schmidt Cryptographic Sensor Node Authentication (TBST-SCSNA) technique is introduced for secured data communication in WSN with higher authentication accuracy. Initially, the trust values for each sensor nodes are calculated for increasing the security in data communication. The sensor nodes in WSN are arranged in tango binary search tree based on the trust value. The nodes in tree are inserted or removed based on their deployment. After that, the Schmidt-Samoa cryptographic technique is applied for node authentication and secure data communication. The cryptographic technique comprises three processes key generation, encryption and decryption. In key generation phase, the public key (i. e., node_ID) are generated and distributed for the sensor nodes and private key is kept secret using Schmidt-Samoa algorithm. The root node is embedded with a key during the deployment and it is controlled the entire the sensor nodes in the path. A Parent node generates the keys for child node based on the ID of parent node. After the key generation, the sender node encrypts the data packet and transmits to receiver node in the tree with the receiver node ID. After that, the receiver node enters their private key and verifies it with already stored key at the time of key generation. If both keys are same, then the node is said to be authentic node. Otherwise, the sensor node is said to be a malicious node. The authentic node only receives the original data packets. This process gets repeated till all the nodes in the path verify their identities and performs the secure communication. Simulation is carried out with different parameters such as authentication accuracy, authentication time and security level with respect to a number of sensor nodes and a number of data packets. The results observed that the TBST-SCSNA technique efficiently improves the node authentication accuracy, security level with minimum time than the state-of-the-art-methods.
无线传感器网络(WSN)是由一组分布在网络中的传感器节点组成的网络,用于感知和监测环境并收集数据。由于传感器节点的分布式特性,安全是访问机密数据和保护未经授权访问的主要作用。为了提高通信的安全性,认证是无线传感器网络中必不可少的环节。提出了一种基于Tango二叉搜索树的施密特加密传感器节点认证技术(TBST-SCSNA),用于WSN中安全的数据通信,具有较高的认证精度。首先,计算每个传感器节点的信任值,以提高数据通信的安全性。基于信任值的探戈二叉搜索树将WSN中的传感器节点进行排列。根据部署情况插入或删除树中的节点。然后,采用Schmidt-Samoa加密技术进行节点认证和数据安全通信。加密技术包括密钥生成、加密和解密三个过程。在密钥生成阶段,为传感器节点生成并分发公钥(即node_ID),并使用Schmidt-Samoa算法对私钥进行保密。根节点在部署过程中嵌入一个密钥,并由路径中的整个传感器节点控制。父节点根据父节点的ID为子节点生成键。密钥生成后,发送节点对数据包进行加密,发送给接收节点ID所在树中的接收节点。之后,接收方节点输入其私钥,并在生成密钥时使用已存储的密钥进行验证。如果两个密钥相同,则称该节点为可信节点。否则,该传感器节点被认为是恶意节点。被认证节点只接收原始数据包。此过程将重复进行,直到路径中的所有节点验证其身份并执行安全通信。针对多个传感器节点和多个数据包,采用不同的认证精度、认证时间和安全级别等参数进行仿真。结果表明,TBST-SCSNA技术在最短的时间内提高了节点认证的准确性和安全性。
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引用次数: 1
期刊
Sensor Letters
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