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Molten chloride technology pathway to meet the U.S. DOE sunshot initiative with Gen3 CSP 熔融氯化物技术途径,以满足美国能源部sunshot计划与Gen3 CSP
J. Vidal, Noah Klammer
Third-generation (Gen3) concentrating solar power (CSP) technologies require a thermally stable and inexpensive fluid to be used for heat transfer and thermal energy storage. For Gen3 CSP plants, a molten salt composed of MgCl2 – KCl – NaCl is a new candidate, but it is familiar enough to plants with existing molten-salt systems. To determine the best composition for the heat-transfer fluid, we mixed nine different ratios of the salts, dry/purified them following strict protocols, and tested them with a differential scanning calorimeter and a thermogravimetric analyzer. Our results showed that the lowest melting and solidification temperature of 385°C ± 1°C was determined for the eutectic composition 44.7 MgCl2 – 25.8 KCl – 29.4 NaCl (mol.%). We determined that improper handling and preparation of the salt mixture highly affects its thermal properties because of moisture absorption. Preparation standards—particularly the dehydration of hydrous MgCl2—merit further development.
第三代(Gen3)聚光太阳能(CSP)技术需要一种热稳定且廉价的流体用于传热和热能储存。对于第三代CSP装置,由MgCl2 - KCl - NaCl组成的熔盐是一种新的候选盐,但对于现有熔盐系统的装置来说已经足够熟悉了。为了确定传热流体的最佳组成,我们混合了9种不同比例的盐,按照严格的规程进行干燥/纯化,并用差示扫描量热计和热重分析仪进行测试。结果表明,共晶成分为44.7 MgCl2 - 25.8 KCl - 29.4 NaCl (mol.%)时,最低熔融凝固温度为385℃±1℃。我们确定,由于吸湿性,不当的处理和制备盐混合物会严重影响其热性能。制备标准-特别是含水氯化镁的脱水-值得进一步发展。
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引用次数: 37
Advanced measurement techniques to characterize the near-specular reflectance of solar mirrors 太阳反射镜近镜面反射特性的先进测量技术
F. Sutter, A. Fernández-García, A. Heimsath, M. Montecchi, C. Pelayo
The precise measurement of the reflected energy from a solar reflector to the receiver is a challenging task because of its dependency on three different parameters: the wavelength of the incident light, its incidence angle and the acceptance angle of the receiver. Up to today, the commonly employed measurement equipment is not able to fully characterize the mirrors in the required range of parameters which is relevant for CSP. Within this work, four reflectometers were upgraded to overcome the current drawbacks. A Round Robin test among the different characterization methods has been carried out on four reflector materials. The conclusions drawn from the comparison of the measurement results help to improve the current SolarPACES Reflectance Guideline.The precise measurement of the reflected energy from a solar reflector to the receiver is a challenging task because of its dependency on three different parameters: the wavelength of the incident light, its incidence angle and the acceptance angle of the receiver. Up to today, the commonly employed measurement equipment is not able to fully characterize the mirrors in the required range of parameters which is relevant for CSP. Within this work, four reflectometers were upgraded to overcome the current drawbacks. A Round Robin test among the different characterization methods has been carried out on four reflector materials. The conclusions drawn from the comparison of the measurement results help to improve the current SolarPACES Reflectance Guideline.
精确测量从太阳反射器到接收器的反射能量是一项具有挑战性的任务,因为它依赖于三个不同的参数:入射光的波长、入射光的入射角和接收器的接收角。到目前为止,常用的测量设备还不能完全表征与CSP相关的所需参数范围内的反射镜。在这项工作中,对四个反射计进行了升级,以克服目前的缺点。在四种反射材料上进行了不同表征方法的循环测试。从测量结果的比较中得出的结论有助于改进现行的SolarPACES反射率指南。精确测量从太阳反射器到接收器的反射能量是一项具有挑战性的任务,因为它依赖于三个不同的参数:入射光的波长、入射光的入射角和接收器的接收角。到目前为止,常用的测量设备还不能完全表征与CSP相关的所需参数范围内的反射镜。在这项工作中,对四个反射计进行了升级,以克服目前的缺点。在四种反射材料上进行了不同表征方法的循环测试。从测量结果的比较中得出的结论有助于改进现行的SolarPACES反射率指南。
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引用次数: 9
Corrosion testing under inert atmosphere with stainless steel crucibles 不锈钢坩埚在惰性气氛下的腐蚀试验
S. Bell, G. Will, T. Steinberg
Molten salt eutectics have potential applications in Thermal Energy Storage (TES) systems as Phase Change Materials (PCMs), however eutectic salts with melting temperatures above 400°C are highly corrosive under air atmospheres. A method for testing under inert atmosphere is presented and results from testing under isothermal and thermal cycling conditions for two salts (NaCl/Na2CO3 and NaCl/Na2SO4) with melting temperatures of around 630°C are discussed. Chromium oxides were present at the salt/metal interface whilst iron and nickel remained in metal phase.
熔盐共晶作为相变材料(PCMs)在热储能(TES)系统中有潜在的应用,但是熔融温度超过400°C的共晶盐在空气环境下具有很强的腐蚀性。提出了一种惰性气氛下的测试方法,并讨论了在熔点630℃左右的等温和热循环条件下对两种盐(NaCl/Na2CO3和NaCl/Na2SO4)的测试结果。铬氧化物存在于盐/金属界面,而铁和镍则停留在金属相。
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引用次数: 2
A methodology to assess the market potential and identify most promising business cases for small scale CSP plants with thermal energy storage 一种评估市场潜力的方法,并确定具有热能储存的小型CSP工厂最有前途的商业案例
Youssef Benmakhlouf, R. Guédez, Jonas Wallmander, Björn Laumert
This study presents a methodology to quantify the market potential for a novel distributed CSP technology with thermal energy technology. The system in question relies on the Stirling engine for power production, which is fed by heat collected from a heliostat field and stored in an integrated latent heat storage unit. Selected countries in the MENA region are investigated to identify best prospective business cases for such a technology. With a global market potential above 40 GW in the whole MENA, industrial sectors such as mining and cement hold the best prospects in terms of market share. The achievable costs of generation vary depending on the DNI of the sites considered but prove to be lower compared with conventional distributed generation (diesel gensets or PV-BEES). However, several countries in the MENA, although having high DNI resource, still offer low electricity utility prices to industrial customers for distributed CSP to become competitive with on-grid electricity procurement. A scenario analysis coupled with a multi criteria selection of the optimal business case quantifies the amount of subsidies necessary to reach competitiveness.This study presents a methodology to quantify the market potential for a novel distributed CSP technology with thermal energy technology. The system in question relies on the Stirling engine for power production, which is fed by heat collected from a heliostat field and stored in an integrated latent heat storage unit. Selected countries in the MENA region are investigated to identify best prospective business cases for such a technology. With a global market potential above 40 GW in the whole MENA, industrial sectors such as mining and cement hold the best prospects in terms of market share. The achievable costs of generation vary depending on the DNI of the sites considered but prove to be lower compared with conventional distributed generation (diesel gensets or PV-BEES). However, several countries in the MENA, although having high DNI resource, still offer low electricity utility prices to industrial customers for distributed CSP to become competitive with on-grid electricity procurement. A scenario a...
本研究提出了一种量化新型分布式CSP技术与热能技术的市场潜力的方法。该系统依赖于斯特林发动机发电,该发动机由定日镜场收集的热量提供能量,并存储在集成的潜热存储单元中。对中东和北非地区选定的国家进行调查,以确定这种技术的最佳前景商业案例。在整个中东和北非地区,全球市场潜力超过40吉瓦,采矿和水泥等工业部门在市场份额方面拥有最好的前景。可实现的发电成本取决于所考虑的地点的DNI,但与传统的分布式发电(柴油发电机组或PV-BEES)相比,可实现的成本较低。然而,中东和北非地区的一些国家虽然拥有高DNI资源,但仍然向工业客户提供较低的电力公用事业价格,以使分布式CSP与并网电力采购具有竞争力。情景分析与最佳商业案例的多标准选择相结合,量化了达到竞争力所需的补贴金额。本研究提出了一种量化新型分布式CSP技术与热能技术的市场潜力的方法。该系统依赖于斯特林发动机发电,该发动机由定日镜场收集的热量提供能量,并存储在集成的潜热存储单元中。对中东和北非地区选定的国家进行调查,以确定这种技术的最佳前景商业案例。在整个中东和北非地区,全球市场潜力超过40吉瓦,采矿和水泥等工业部门在市场份额方面拥有最好的前景。可实现的发电成本取决于所考虑的地点的DNI,但与传统的分布式发电(柴油发电机组或PV-BEES)相比,可实现的成本较低。然而,中东和北非地区的一些国家虽然拥有高DNI资源,但仍然向工业客户提供较低的电力公用事业价格,以使分布式CSP与并网电力采购具有竞争力。一个场景A…
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引用次数: 1
A thermo-economic assessment of CSP+TES in the north of Chile for current and future grid scenarios 智利北部CSP+TES当前和未来电网情景的热经济评估
F. Gallardo, L. Pratticò, C. Toro
This paper presents a thermo-economic analysis of a hypothesized concentrated solar power (CSP) tower plant with molten salt thermal energy storage (TES) located in the Atacama Desert in Chile with the aim of serving as input for the Solar Committee to better establish public policy programs to increase the competitiveness of CSP in Chile. The study focuses on an optimal plant in terms of size and configuration for expected conditions of the Chilean electricity market in 2018 and 2030. An ideal CSP+TES configuration to complement the electricity pool market from a grid point of view was obtained for each year. An exergetic study was performed for each configuration under assumed annual operation conditions and a thermos-economic analysis was done considering specific costs per component. Thermo-economic indicators were obtained allowing to define a priority hierarchy of specific techno-economical improvements that can be done at plant and component level to maximize the competitiveness of CSP projects in the Chilean market. A sensitivity analysis was performed obtaining the impact of efficiency improvements and capex reductions per component on the Levelized Cost of Energy (LCOE). The maximum allowable trade-off limit for each technical improvement (capex increase or plant factor reduction) was calculated.
本文对位于智利阿塔卡马沙漠的具有熔盐热储能(TES)的集中式太阳能发电(CSP)塔式电厂进行了热经济分析,旨在为太阳能委员会更好地制定公共政策计划提供参考,以提高智利CSP的竞争力。该研究的重点是在2018年和2030年智利电力市场预期条件下的规模和配置方面的最佳工厂。从电网的角度来看,每年都获得了理想的CSP+TES配置,以补充电力池市场。在假定的年度运行条件下,对每种配置进行了热工研究,并考虑了每个组件的具体成本进行了热经济分析。通过获得热经济指标,可以确定具体技术经济改进的优先等级,这些改进可以在工厂和部件级别进行,以最大限度地提高CSP项目在智利市场上的竞争力。进行敏感性分析,获得效率提高和每个组件资本支出减少对能源平准化成本(LCOE)的影响。计算了每项技术改进(资本支出增加或工厂因素减少)的最大允许权衡限制。
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引用次数: 4
Development of high performances solar absorber coatings 高性能太阳能吸收涂层的研制
Ridha Harzallah, M. Larnicol, C. Leclercq, Alexandre Herbein, F. Campana
In order to improve the efficiency of a solar receiver, the operating temperature has to be increased, from 500°C in the 1st generation (direct steam generation solar receivers) to 700°C in the current generation (molten salt solar receivers) and up to more than 800°C in the next generation (higher temperature molten salt solar receivers). This very high operating temperature requires the employment of a solar absorber coating showing high optical performances and good stability at high temperature in order to guarantee the nominal solar receiver performances. The absorber coating currently used exhibits lower performances at such temperatures. For this reason, the development of a new absorber coating having the required high performances at high temperature is sought. The development of high performances (high solar absorbance and high lifetime) solar absorber coatings is one of the developments programs which CMI has been working on for several years in order to increase the performances and reliability of its Solar Receiver and to keep a leadership in the very competitive CSP market. The results of these developments are two new solar absorber coatings: the first one is a high performance “Silicon-based Black Paint”, which will provide high absorptance (97.2% vs 96.2% for current technology) with an increased efficiency of the solar receiver and an increased lifetime (3 years) and the second one is a patented “Plasma Sprayed Coating” that will provide good optical performances (similar absorptance and lower emissivity than current technology) with higher durability (>3 years) useful in the next generation of solar receivers.
为了提高太阳能接收器的效率,必须提高工作温度,从第一代(直接蒸汽产生太阳能接收器)的500°C到当前一代(熔盐太阳能接收器)的700°C,再到下一代(更高温度的熔盐太阳能接收器)的800°C以上。这种非常高的工作温度要求采用具有高光学性能和在高温下良好稳定性的太阳能吸收涂层,以保证标称太阳能接收器的性能。目前使用的吸收剂涂层在这种温度下表现出较低的性能。因此,需要开发一种具有所需的高温高性能的新型吸收剂涂层。开发高性能(高吸收率和高寿命)太阳能吸收器涂层是CMI多年来一直致力于的开发项目之一,以提高其太阳能接收器的性能和可靠性,并在竞争激烈的CSP市场中保持领先地位。这些发展的结果是两种新的太阳能吸收涂层:第一个是高性能的“硅基黑漆”,它将提供高吸收率(97.2%比目前技术的96.2%),提高太阳能接收器的效率和延长寿命(3年),第二个是专利的“等离子喷涂涂层”,将提供良好的光学性能(类似的吸收率和较低的发射率比目前的技术)和更高的耐用性(>3年),在下一代太阳能接收器有用。
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引用次数: 15
The solar thermal treatment of manganese ore pellets using closed-loop forced convection of air 采用空气闭环强制对流法对锰矿球团进行太阳热处理
L. Hockaday, F. Dinter, T. Harms, Q. Reynolds
The incorporation of renewable energy sources in high temperature industrial processes has the potential to reduce energy costs as well as greenhouse gas emissions. The current study forms part of an evaluation of the opportunities to integrate concentrating solar thermal energy into the sintering of manganese ores. The study includes the results of direct irradiation of manganese ore pellets with concentrating solar flux in combination with the closed-loop forced convection of air. The results of this study will be of interest to the fields of high temperature solar thermal process heat and solar thermal materials processing as well as manganese ore sinter production.The incorporation of renewable energy sources in high temperature industrial processes has the potential to reduce energy costs as well as greenhouse gas emissions. The current study forms part of an evaluation of the opportunities to integrate concentrating solar thermal energy into the sintering of manganese ores. The study includes the results of direct irradiation of manganese ore pellets with concentrating solar flux in combination with the closed-loop forced convection of air. The results of this study will be of interest to the fields of high temperature solar thermal process heat and solar thermal materials processing as well as manganese ore sinter production.
在高温工业过程中使用可再生能源有可能降低能源成本以及温室气体排放。目前的研究是对将集中太阳能热能整合到锰矿石烧结中的机会进行评估的一部分。本研究包括集中太阳通量直接照射锰矿球团并结合空气闭环强制对流的结果。该研究结果将对高温太阳热过程热、太阳热材料加工以及锰矿烧结生产等领域产生重要影响。在高温工业过程中使用可再生能源有可能降低能源成本以及温室气体排放。目前的研究是对将集中太阳能热能整合到锰矿石烧结中的机会进行评估的一部分。本研究包括集中太阳通量直接照射锰矿球团并结合空气闭环强制对流的结果。该研究结果将对高温太阳热过程热、太阳热材料加工以及锰矿烧结生产等领域产生重要影响。
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引用次数: 2
Photothermal and thermography techniques applied in the characterization of the thermophysical properties of solar absorbers: A review 光热和热成像技术在太阳能吸收体热物理性质表征中的应用综述
J. Macías, J. Guerra, H. Paredes, C. A. Bulnes, H. V. Vidales, O. Muzio, V. Sánchez, J. J. A. Gil
The efficient generation of renewable energies from solar radiation implies the precise knowledge of the thermophysical properties of the materials and systems involved in such applications, this knowledge is fundamental, since it allows us to evaluate and optimize the performance of materials and methods. One of the great challenges for the efficient use of solar energy is the study of the phenomena involved in the interaction of radiation with matter, and the conversion of energy absorbed into heat. Photothermal and thermographic techniques are ideal methodologies to study these phenomena, since they are non-contact techniques (NCT) and, therefore, can be applied in a wide range of operating temperatures and environments. In general, photothermal techniques consist in illuminating the surface of the sample with a laser light beam modulated or pulsed, therefore the sample is heated and emits infrared radiation IR (among other types of energy). The variations of the IR energy are related to the thermophysical properties of the specimens photothermal techniques are based on the detection of these variations. Some examples of photothermal methodologies are the photothermal radiometry pulsed (PPTR) and modulated (PTR), the photothermal reflectometry (RM) and the thermal wave resonant cavity (TWRC). Infrared thermography is a powerful method of non-contact measurement, using this technique thermal images or thermograms are obtained, which are a representation of the temperature distribution on the surface of an object or a scene. The thermophysical properties of materials they are obtained through the analysis of amplitude and phase signals, as well as thermograms. Reflectance spectroscopy is a powerful tool for characterizing the optical properties (solar absorbance and thermal emittance) of a great diversity of materials applied in solar technology. The analysis can be done in two wavelength ranges of interest: Ultraviolet/visible/near infrared and medium infrared, where solar spectrum radiation wavelengths and infrared emission range are located respectively. The methodologies mentioned have been applied in the characterization of materials at room temperature, however, many processes involved in the new applications of solar energy occur at high temperature. It has also been shown that thermophysical mechanisms related to the conversion of energy that occur at room temperature are not dominant in high temperature regimes therefore, the measurement of the conversion, absorption, emission and energy exchange processes to high temperature, they involve new technological challenges. In this work, we present a summary about the photothermal, thermographic and reflectance spectroscopy techniques, used in the evaluation of the thermophysical properties of solar absorbers applied in low temperature solar systems, as well as high temperature concentrate solar power (CSP) systems.
从太阳辐射中有效地产生可再生能源意味着对此类应用中涉及的材料和系统的热物理特性的精确了解,这些知识是基础的,因为它使我们能够评估和优化材料和方法的性能。有效利用太阳能的巨大挑战之一是研究辐射与物质相互作用的现象,以及将吸收的能量转化为热能。光热技术和热成像技术是研究这些现象的理想方法,因为它们是非接触技术(NCT),因此可以应用于广泛的工作温度和环境。一般来说,光热技术包括用调制或脉冲激光光束照射样品表面,因此样品被加热并发射红外辐射(在其他类型的能量中)。红外能量的变化与样品的热物理性质有关,光热技术是基于对这些变化的检测。光热方法的一些例子是光热辐射测量脉冲(PPTR)和调制(PTR),光热反射(RM)和热波谐振腔(TWRC)。红外热像仪是一种功能强大的非接触式测量方法,利用红外热像仪可以获得物体或场景表面温度分布的热图像或热图。材料的热物理性质是通过分析振幅和相位信号以及热图得到的。反射光谱学是表征太阳能技术中应用的各种材料的光学特性(太阳吸收率和热发射率)的有力工具。分析可以在两个感兴趣的波长范围内进行:紫外/可见/近红外和中红外,其中分别位于太阳光谱辐射波长和红外发射范围。所提到的方法已在室温下应用于材料的表征,然而,在太阳能的新应用中涉及的许多过程发生在高温下。研究还表明,与室温下发生的能量转换相关的热物理机制在高温条件下并不占主导地位,因此,测量高温下的转换、吸收、发射和能量交换过程涉及新的技术挑战。本文综述了光热、热成像和反射光谱技术在评价低温太阳能系统和高温聚光太阳能(CSP)系统中太阳能吸收体热物理性能方面的应用。
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引用次数: 3
High-accuracy real-time monitoring of solar radiation attenuation in commercial solar towers 商用太阳能塔太阳辐射衰减的高精度实时监测
Marcelino Sánchez, C. Fernández-Peruchena, A. Bernardos, C. Heras, R. Chueca, Iñigo Salinas
The main objectives of this work are twofold, the immediate objective is to provide current commercial solar towers with a system able to monitor accurately the solar radiation attenuation, the mid...
这项工作的主要目的有两个,直接目标是为目前的商业太阳能塔提供一个能够准确监测太阳辐射衰减的系统,中间…
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引用次数: 4
CSP in Namibia – Solution to the “duck curve”? 纳米比亚的光热发电——“鸭子曲线”的解决方案?
E. Dall, G. H. Muller, F. Bailey, R. Jagau, Arno R. Pfohl, J. Swart, Juan Manuel Saenz Caballos
Electricity costs from photovoltaics (PV) and wind power generation technologies have fallen greatly in recent years and are still expected to fall into the future. By the year 2020, PV and wind power generation technologies could provide the lowest cost of electricity from any source. A large scale roll-out of PV and wind power plants within conventional electricity grids will create a new operating paradigm to which power utilities and system operators will swiftly need to adapt to. For Namibia, the so-called “duck-curve” best illustrates this paradigm, representing the difference between the future demand and the expected electricity supply from intermittent Renewable Energy Technologies (RETs) (especially PV) into the grid. Through a Namibian case study, this paper investigates the potential role of Concentrating Solar Power (CSP) within the electricity supply mix, given a high penetration of intermittent RETs within the grid. This study suggests that the key role of CSP within the Namibian electricity supply mix, under the set of assumptions considered, would be to provide peaking and mid-merit support to the grid on a seasonal basis.Electricity costs from photovoltaics (PV) and wind power generation technologies have fallen greatly in recent years and are still expected to fall into the future. By the year 2020, PV and wind power generation technologies could provide the lowest cost of electricity from any source. A large scale roll-out of PV and wind power plants within conventional electricity grids will create a new operating paradigm to which power utilities and system operators will swiftly need to adapt to. For Namibia, the so-called “duck-curve” best illustrates this paradigm, representing the difference between the future demand and the expected electricity supply from intermittent Renewable Energy Technologies (RETs) (especially PV) into the grid. Through a Namibian case study, this paper investigates the potential role of Concentrating Solar Power (CSP) within the electricity supply mix, given a high penetration of intermittent RETs within the grid. This study suggests that the key role of CSP within the Namibian electricit...
近年来,光伏发电和风力发电技术的电力成本大幅下降,预计未来仍将下降。到2020年,光伏和风力发电技术可以提供最低成本的电力。在传统电网内大规模推广光伏和风力发电厂将创造一种新的运营模式,电力公司和系统运营商将很快需要适应这种模式。对于纳米比亚来说,所谓的“鸭子曲线”最好地说明了这一范式,代表了未来需求与间歇性可再生能源技术(RETs)(特别是光伏)进入电网的预期电力供应之间的差异。通过纳米比亚的案例研究,本文研究了集中式太阳能发电(CSP)在电力供应结构中的潜在作用,考虑到电网中间歇性ret的高渗透率。这项研究表明,在所考虑的一系列假设下,光热发电在纳米比亚电力供应结构中的关键作用将是在季节性的基础上为电网提供峰值和中等价值的支持。近年来,光伏发电和风力发电技术的电力成本大幅下降,预计未来仍将下降。到2020年,光伏和风力发电技术可以提供最低成本的电力。在传统电网内大规模推广光伏和风力发电厂将创造一种新的运营模式,电力公司和系统运营商将很快需要适应这种模式。对于纳米比亚来说,所谓的“鸭子曲线”最好地说明了这一范式,代表了未来需求与间歇性可再生能源技术(RETs)(特别是光伏)进入电网的预期电力供应之间的差异。通过纳米比亚的案例研究,本文研究了集中式太阳能发电(CSP)在电力供应结构中的潜在作用,考虑到电网中间歇性ret的高渗透率。这项研究表明,光热发电在纳米比亚电力系统中的关键作用是…
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引用次数: 3
期刊
SOLARPACES 2018: International Conference on Concentrating Solar Power and Chemical Energy Systems
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