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Starch‐Based Biodegradable Film from Fruit and Vegetable Waste and Its Standardization Modules Based on Neural Networks and Response Surface Methodology 基于神经网络和响应面方法的淀粉基果蔬垃圾生物降解膜及其标准化模块
Pub Date : 2023-10-25 DOI: 10.1002/star.202300082
Mausumi Sarma, Sourav Chakraborty, Radhakrishnan Kesavan, Kshirod Kumar Dash, Prakash Kumar Nayak
Abstract Fruits and vegetable waste‐based starch has numerous applications for use as a biodegradable film in food packaging materials. This study reviews fruit and vegetable waste‐based non‐commercial starches that can be utilized as an alternatives for commercial starches in biodegradable film growth. Circular economy, sustainable manufacturing goals, recycling waste and by‐products, and new basic concepts drive the hunt for alternative starch sources. Starches from unusual and abandoned fruits and vegetables offer stronger research potential. The characteristics of starch extracted from these sources and their use as a biodegradable film are emerging trends in the field of packaging technology. Further, millet starch, for example, is made from the waste of underused crops or other fruits and vegetables and presents a wealth of new avenues for biodegradable film study. In order to cease throwing away valuable carbohydrates, especially starch, these sources must incorporate into the concept of “circularity” and work toward more sustainable manufacturing practices. Besides, optimizing the biodegradable film composition to improve barrier and shelf life is also crucial. Thus, an additional study may apply response surface‐based hybrid optimization, neural networks, or deep learning‐oriented models to optimize biodegradable film composition and intelligent monitoring of the materials under the packing systems.
果蔬废料淀粉作为一种生物可降解薄膜在食品包装材料中有着广泛的应用。本研究综述了以水果和蔬菜废料为基础的非商业淀粉,这些淀粉可以作为商业淀粉在生物可降解薄膜生长中的替代品。循环经济、可持续制造目标、废物和副产品回收利用以及新的基本概念推动着人们寻找替代淀粉来源。从不常见和废弃的水果和蔬菜中提取的淀粉提供了更大的研究潜力。从这些来源提取的淀粉的特性及其作为可生物降解薄膜的使用是包装技术领域的新兴趋势。此外,以小米淀粉为例,它是由未充分利用的作物或其他水果和蔬菜的废料制成的,为生物可降解薄膜的研究提供了丰富的新途径。为了停止浪费有价值的碳水化合物,特别是淀粉,这些来源必须纳入“循环”的概念,并朝着更可持续的制造实践努力。此外,优化生物可降解膜的组成以提高阻隔性和保质期也是至关重要的。因此,一项额外的研究可能会应用基于响应面的混合优化、神经网络或面向深度学习的模型来优化可生物降解薄膜的组成和包装系统下材料的智能监测。
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引用次数: 0
Preparation, Biological Activities, and Application of Plant Polysaccharide Iron Complexes: A Review 植物多糖铁配合物的制备、生物活性及应用研究进展
Pub Date : 2023-10-23 DOI: 10.1002/star.202300145
Shasha Dai, Zitong Hao, Yuchao Gao, Yumei Sang, Zechao Liu, Hongkun Xue
Abstract Iron is an essential trace element in the human body. Iron deficiency can lead to iron deficiency anemia (IDA) and induce various diseases. Hence, it is urgent to find an iron supplement with minimal side effects and good iron supplementation effect. Natural polysaccharides from plants have various biological activities such as antioxidant, hypoglycemic, immunomodulatory, etc. Increasing research has shown that polysaccharides modified with iron can enhance their biological activities. Among them, polysaccharide iron complex (PIC) has significant anti‐anemia activity. With the powerfully development of PIC, increasing research has found that PIC showed some advantages, including good water solubility, high bioavailability, low gastrointestinal irritation, and high iron content. Therefore, PIC has received widespread attention. Currently, PIC is widely used in various fields such as agriculture, animal husbandry, and clinical treatment. However, there are limited reports on the preparation, biological activities, and applications of PIC. This paper systematically reviews the preparation methods, iron content determination methods, biological activities, and applications of PIC. The results provide important references for the deep development and utilization of PIC.
铁是人体必需的微量元素。缺铁可导致缺铁性贫血(IDA),诱发多种疾病。因此,迫切需要寻找一种副作用小、补铁效果好的补铁剂。天然植物多糖具有抗氧化、降血糖、免疫调节等多种生物活性。越来越多的研究表明,铁修饰多糖可以提高多糖的生物活性。其中,多糖铁复合物(PIC)具有显著的抗贫血活性。随着PIC的大力发展,越来越多的研究发现PIC具有水溶性好、生物利用度高、对胃肠道刺激小、铁含量高等优点。因此,PIC受到了广泛的关注。目前,PIC已广泛应用于农业、畜牧业、临床治疗等各个领域。然而,关于PIC的制备、生物活性和应用的报道有限。本文系统地综述了PIC的制备方法、铁含量测定方法、生物活性及其应用。研究结果为PIC的深入开发利用提供了重要参考。
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引用次数: 0
Gelatin Candies Architected with Active Starch Nanoparticles Containing Phenolic Compounds from Propolis Extract 明胶糖果结构与活性淀粉纳米颗粒含有从蜂胶提取物酚类化合物
Pub Date : 2023-10-23 DOI: 10.1002/star.202300162
Maria Jaízia dos Santos Alves, Wilson Daniel Caicedo Chacon, Alcilene Rodrigues Monteiro, Germán Ayala Valencia
Abstract New trends in the food industry are focused on the development of fortification foods. Gelatin candies are foods widely consumed by the population and they are selected for incorporation with starch nanoparticles (SNPs) obtained by nanoprecipitation and loaded with phenolic compounds from propolis extract (PE). Water activity and total soluble solids result in stable gelatin candies at room temperature and 30% RH (relative humidity) from the microbiological point of view. According to the results, the addition of starch nanoparticles (SNPs) in gelatin candies does not prove to be a factor that influences texture parameters, especially hardness, gumminess, and chewiness. Candies containing SNPs loaded with the phenolic compounds from PE have high total phenolic compounds (324–362 mg of GAE 100 g −1 ) and antioxidant activity (133–136 µmol TROLOX 100 g −1 ). The stability of the starch nanoparticles loaded with the phenolic compounds from propolis extract in the gummy candy is confirmed, exhibiting this food product a yellow color, representing a promising application for these natural additives in the food industry. These results indicate that SNPs loaded with the phenolic compounds from PE can be used for gelatin candies fortification aiming to develop functional foods.
食品工业的新趋势集中在强化食品的发展上。明胶糖果是人们广泛食用的食品,它们被选择与纳米沉淀法获得的淀粉纳米颗粒(snp)结合,并装载蜂胶提取物(PE)中的酚类化合物。从微生物学的角度来看,水活度和总可溶性固体导致室温和30% RH(相对湿度)下稳定的明胶糖果。结果表明,在明胶糖果中添加淀粉纳米颗粒(SNPs)不会影响明胶糖果的质地参数,尤其是硬度、胶性和咀嚼性。含有PE中酚类化合物的snp的糖果具有高的总酚类化合物(324-362 mg GAE 100 g−1)和抗氧化活性(133-136µmol TROLOX 100 g−1)。淀粉纳米颗粒装载了胶糖中蜂胶提取物的酚类化合物,其稳定性得到了证实,表明这种食品呈黄色,代表了这些天然添加剂在食品工业中的应用前景。这些结果表明,负载PE中酚类化合物的snp可以用于明胶糖果的强化,以开发功能食品。
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引用次数: 1
Structural Characterization and Immunomodulatory Effects of Polysaccharide PCP‐1 from Pleurotus citrinopileatus 柑桔侧耳多糖PCP‐1的结构表征及免疫调节作用
Pub Date : 2023-10-22 DOI: 10.1002/star.202300093
Le Shi, Yu Liu, Zhong‐Fei Zhang, Yan‐Xia Li, Yu‐Meng Wu, Yong‐Ming Lu
Abstract The use of fungal polysaccharides as immunomodulators has garnered significant interest. Here, the polysaccharide PCP‐1 is isolated and purified from the fruiting bodies of Pleurotus citrinopileatus . PCP‐1 is identified as a glucan with a molecular weight of 1670 kDa. Methylation analysis reveals that PCP‐1 consists of T‐Glc p , T‐Rha p , 1,3‐Glc p , 1,4‐Glc p , 1,4,6‐Glc p , and 1,3,6‐Glc p . PCP‐1 exhibits exceptional immunomodulatory effects, as it can dose‐dependently stimulate phagocytosis and promote the secretion of nitric oxide and reactive oxygen species in RAW264.7 cells. Additionally, PCP‐1 significantly enhances the secretion of cytokines such as TNF‐ α , IL‐1 β , and IL‐6 at both the protein and mRNA levels, with concentrations ranging from 2.5 to 40 µg mL −1 . At a concentration of 40 µg mL −1 , the immunomodulatory effects are comparable to those of the positive control. Furthermore, PCP‐1 promotes the nuclear translocation of the p65 protein, indicating activation of the NF‐κB signaling pathway. The results demonstrate that PCP‐1 has the potential as a natural immunomodulator, with possible applications in the food, pharmaceutical, and other industries.
真菌多糖作为免疫调节剂的使用已经引起了人们的极大兴趣。本文从杏鲍菇子实体中分离纯化了多糖PCP‐1。PCP‐1被鉴定为分子量为1670 kDa的葡聚糖。甲基化分析表明,PCP‐1由T‐Glc p、T‐Rha p、1,3‐Glc p、1,4‐Glc p、1,4,6‐Glc p和1,3,6‐Glc p组成。PCP‐1表现出特殊的免疫调节作用,因为它可以剂量依赖性地刺激RAW264.7细胞的吞噬作用,促进一氧化氮和活性氧的分泌。此外,PCP‐1在蛋白和mRNA水平上显著增强细胞因子如TNF‐α、IL‐1 β和IL‐6的分泌,浓度范围为2.5至40µg mL−1。在浓度为40µg mL−1时,免疫调节作用与阳性对照相当。此外,PCP‐1促进p65蛋白的核易位,表明NF‐κB信号通路的激活。结果表明,PCP‐1具有作为天然免疫调节剂的潜力,在食品、制药和其他行业有可能应用。
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引用次数: 0
Preparation of Starch‐Fatty acid esters from Agro‐based Raw Materials (Corn Starch, Cassava Starch, Coconut Oil and Castor Seed Oil) 以农产品为原料(玉米淀粉、木薯淀粉、椰子油和蓖麻籽油)制备淀粉脂肪酸酯
Pub Date : 2023-10-04 DOI: 10.1002/star.202200205
Olusegun Amos, Rami Adel Pashameah
Abstract The preparation of starch‐fatty acid esters is investigated for corn starch and cassava starch. The fatty acid contents are obtained from the hydrolysis of coconut oil and castor oil respectively and are characterized by GC/MS techniques. The major fatty acid component of coconut oil is found to be lauric acid (34%) while that of castor oil is ricinoleic acid (84%). Four different starch‐fatty esters are prepared, namely cassava starch‐coconut fatty acid esters (CacoFAE), cassava starch‐castor fatty acid ester (CacaFAE), corn starch‐coconut fatty acid ester (CocoFAE), and corn starch‐castor fatty acid ester (CocaFAE). The starch‐fatty acid esters are analyzed using FT‐IR and liquid chromatography‐mass spectrometer techniques. All the esterified starch‐fatty acid esters contain the C=O absorption peak at 1707 cm −1 which is the peak corresponding to the ester group formed between the starch hydroxyl and fatty acid carboxylic functions. The major fatty acid eluted from LC‐MS for CacoFAE and CocoFAE is lauric (dodecanoic) acid with 67.4% and 74% respectively while ricinoleic acid (58%) is obtained for CacaFAE. The data for CocaFAE are mainly dominated by the ester of the fatty acids.
摘要研究了玉米淀粉和木薯淀粉中淀粉脂肪酸酯的制备工艺。分别由椰子油和蓖麻油水解得到脂肪酸含量,并采用GC/MS技术进行表征。椰子油的主要脂肪酸成分是月桂酸(34%),蓖麻油的主要脂肪酸成分是蓖麻油酸(84%)。制备了四种不同的淀粉-脂肪酯,即木薯淀粉-椰子脂肪酸酯(CacoFAE)、木薯淀粉-蓖麻脂肪酸酯(CacaFAE)、玉米淀粉-椰子脂肪酸酯(CocoFAE)和玉米淀粉-蓖麻脂肪酸酯(cocoae)。采用FT - IR和液相色谱-质谱仪技术对淀粉-脂肪酸酯进行了分析。所有酯化淀粉-脂肪酸酯在1707 cm−1处都有C=O吸收峰,这是淀粉羟基和脂肪酸羧基之间形成的酯基对应的峰。cacoae和CocoFAE的LC - MS洗脱的主要脂肪酸为月桂酸(十二烷酸),洗脱率分别为67.4%和74%,而cacoae的洗脱率为58%。CocaFAE的数据主要以脂肪酸酯为主。
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引用次数: 0
Effect of Soluble Potato Starch on the Pregelatinization Properties of Non‐Conventional Elephant Foot Yam Starch. 可溶性马铃薯淀粉对非常规象脚山药淀粉预糊化性能的影响。
Pub Date : 2023-09-30 DOI: 10.1002/star.202300135
Riya Banerjee, K. Jayaram Kumar
Abstract In recent years, researchers have been exploring alternative sources of starch for drug delivery. Traditional options like corn, potato, and rice starches have been widely used, but sustainability concerns have prompted the investigation of nonconventional starches. Elephant foot yam starch, derived from an agricultural polymer, has gained popularity due to its wide availability. Starches are fundamentally unsuited for the majority of applications; they must be physically and/or chemically altered to maximize their advantages and/or minimize their drawbacks. Due to the chemical toxicity, starch modification is often done using physical techniques that are inexpensive. This study aims to evaluate the impact of elephant foot yam starch on the physicochemical properties and drug delivery of potato starch. Pregelatinization, a crucial process, is found to increase amylose content and improves starch flow properties, as confirmed by Fourier‐transform infrared spectroscopy analysis showing gelatinization in the mixture. Field emission scanning electron microscopy images reveal complete disruption of the starch granular structure after modification. Tablets made with a mixture of pregelatinized starches exhibit a slower drug release compared to those with pregelatinized starch alone. Notably, inclusion of potato starch in the mixture results in a more sustained drug release. Hence, modified starches have diverse applications for enhancing solubility of poorly soluble drugs.
近年来,研究人员一直在探索替代淀粉给药的来源。传统的选择,如玉米、土豆和大米淀粉已被广泛使用,但对可持续性的担忧促使了对非常规淀粉的研究。象脚山药淀粉来源于一种农业聚合物,由于其广泛的可用性而受到欢迎。淀粉从根本上不适合大多数应用;它们必须经过物理和/或化学改变,以最大限度地发挥其优势和/或减少其缺点。由于化学毒性,淀粉改性通常采用廉价的物理技术。本研究旨在评价象脚山药淀粉对马铃薯淀粉理化性质和给药性能的影响。预糊化是一个关键的过程,通过傅里叶变换红外光谱分析证实,预糊化可以增加直链淀粉的含量,改善淀粉的流动特性。场发射扫描电镜图像显示改性后淀粉颗粒结构完全破坏。用预糊化淀粉混合制成的片剂与单独用预糊化淀粉制成的片剂相比,药物释放速度较慢。值得注意的是,在混合物中加入马铃薯淀粉会导致更持久的药物释放。因此,变性淀粉在提高难溶性药物的溶解度方面有多种应用。
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引用次数: 0
Investigation of physicochemical properties of tapioca starch–methyl myristate complexes 木薯淀粉-肉豆蔻酸甲酯配合物理化性质的研究
Pub Date : 2023-09-30 DOI: 10.1002/star.202300043
Santi Anisa, Albert J. J. Woortman, Katja Loos, Rachmawati Rachmawati
Abstract Complexation can be utilized to modify starch properties. In this study, tapioca starch–methyl myristate (SM) complexes are prepared by mixing tapioca starch and methyl myristate (MM) in water at 90 °C. The MM amount is varied at 1%–10% w/w to study its effects on the complexes’ physicochemical properties, which are characterized using spectroscopic, thermal, crystallinity, particle size, and microscopic analyses. The complexes are stable crystalline materials, as iodine cannot replace complexed MM. In water, these complexes aggregate to form two different sizes of 29.5–162.7 nm (23%–58% population) and 711.2–7086.7 nm (42%–77% population), which melt at 90–95 °C. Solid complexes form porous morphologies, which start degrading at 260.3–263.4 °C, indicating high thermal stability. An in vitro digestibility study using α‐amylase shows that the higher the MM amount is, the slower the starch degradation. At 120 min digestion time, the complexes produce 11%–16% lower reducing sugar than native starch (S). This shows that starch complexation with MM complexes can produce starch materials with slower digestibility. For the kinetic analysis, the Weibull model fits better than the exponential model for analyzing the digestion kinetics of SM complexes by the α‐amylase enzyme.
络合可以用来修饰淀粉的性质。本研究将木薯淀粉与肉豆蔻酸甲酯(MM)在90℃的水中混合,制备了木薯淀粉-肉豆蔻酸甲酯(SM)配合物。MM用量在1%-10% w/w范围内变化,以研究其对配合物理化性质的影响,并通过光谱、热、结晶度、粒度和微观分析对配合物的理化性质进行表征。这些配合物在水中聚集形成29.5 ~ 162.7 nm(占23% ~ 58%)和71.2 ~ 7086.7 nm(占42% ~ 77%)两种不同尺寸的配合物,在90 ~ 95℃下熔化。固体配合物形成多孔形态,在260.3-263.4℃开始降解,具有较高的热稳定性。利用α‐淀粉酶进行的体外消化率研究表明,MM含量越高,淀粉降解越慢。在消化时间为120 min时,配合物产生的还原糖比天然淀粉(S)低11% ~ 16%,说明淀粉与MM配合物络合产生的淀粉材料消化率较慢。对于动力学分析,Weibull模型比指数模型更适合于分析SM配合物被α‐淀粉酶消化的动力学。
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引用次数: 0
Effect of Eurotium cristatum on saccharification efficiency, microorganisms in mold culture, and liquor flavor during Wuliangye liquor production 鸡冠孢对五粮液白酒生产中糖化效率、霉菌培养微生物及白酒风味的影响
Pub Date : 2023-09-25 DOI: 10.1002/star.202200236
Yang Qin, Yang Feng‐ying, Zhao Qian‐hui
Abstract Saccharification fermentation is very important technics for Chinese baijiu, which effects its yield and flavor. Eurotium cristatum was been found the ability of saccharification, but has not been applied to the saccharification fermentation in Chinese baijiu. In this study, E. cristatum was added to the mold culture for the co‐fermentation of Wuliangye liquor to verify whether it enhanced the saccharification efficiency. Starch from mold culture was analyzed to infer the effect. Microorganisms in the mold culture and liquor flavor substances were also evaluated. Results showed that reducing sugar in the fermented grains reached the maximum value of 40 g/100 g when 8 mL of E. cristatum suspension was added to 100 g of mold culture. Co‐fermentation using E. cristatum increased the amylose content, decreased the molecular weight, and formed irregular starch particles and an evident crystal structure of starch from the mold culture. These phenomena in starch molecules corresponded to the mechanism by which E. cristatum enhanced saccharification efficiency. What's more, E. cristatum also improved the growth of the original microorganisms in the mold culture, thereby benefitting the flavor of Wuliangye liquor. Therefore, it is scientific and significative for the application of E. cristatum in saccharification fermentation of Wuliangye liquor. This article is protected by copyright. All rights reserved
摘要糖化发酵是白酒生产的重要工艺,直接影响白酒的产量和风味。鸡冠铕具有糖化能力,但尚未应用于白酒的糖化发酵。本研究将鸡冠菌加入到五粮液的共发酵霉菌培养中,验证其是否能提高糖化效率。通过对霉菌培养淀粉的分析来推测其效果。并对霉菌培养微生物和白酒风味物质进行了评价。结果表明,在100 g霉菌培养液中加入8 mL鸡冠菌悬浮液时,发酵谷物中的还原糖达到最大值,为40 g/100 g。利用冠状芽孢杆菌进行共发酵,增加了直链淀粉含量,降低了分子量,形成了不规则的淀粉颗粒,并从霉菌培养物中形成了明显的淀粉晶体结构。淀粉分子中的这些现象与鸡冠菌提高糖化效率的机制相对应。此外,冠状芽孢杆菌还能促进霉菌培养中原始微生物的生长,从而有利于五粮液的风味。因此,将鸡冠菌应用于五粮液酒的糖化发酵具有一定的科学意义。这篇文章受版权保护。版权所有
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引用次数: 0
Structural and Physicochemical Properties of Common Buckwheat Starch in Response to Different Fertilization Levels 不同施肥水平对普通荞麦淀粉结构和理化性质的响应
Pub Date : 2023-09-08 DOI: 10.1002/star.202200235
Xinhui Lei, Chenxi Wan, Jincai Tao, Yixin Wu, Jiale Wang, Qinghua Yang, Baili Feng, Jinfeng Gao
Abstract Buckwheat is a typical medicinal and edible crop with high nutritional value, and the application of appropriate fertilizer can improve the quality of buckwheat starch. The changes of internal structure and physicochemical characteristics of common buckwheat grain starch under low, medium and high fertilization levels were investigated. With increasing fertilizer amount, the volume proportion increased, while the granule size distribution reduced significantly. All of the common buckwheat starch samples showed a typical A‐type pattern in X‐ray diffraction detection. Furthermore, with the increase of fertilization level, the amylose content, retrogradation, and the ratio of 1045/1022 cm −1 certainly reduced and then raised, but the relative crystallinity, the ratio of 1022/995 cm −1 ratio, light transmittance, solubility, and swelling power increased and then decreased. In comparison to other fertilization levels, common buckwheat starch at the medium level had greater pasting temperatures and gelatinization enthalpy but lower pasting viscosities. These results indicated the medium fertilization level of 180 (N), 115.2 (P) and 84.6 (K) kg/hm 2 was more suitable for buckwheat starch quality, which could give information for buckwheat cultivation. This article is protected by copyright. All rights reserved
摘要荞麦是典型的药用和食用作物,具有很高的营养价值,适当施肥可以提高荞麦淀粉的品质。研究了低、中、高施肥水平下普通荞麦籽粒淀粉内部结构和理化特性的变化。随着施肥量的增加,体积比例增大,而粒径分布明显减小。所有普通荞麦淀粉样品在X射线衍射检测中都表现出典型的a型模式。随着施肥水平的增加,直链淀粉含量、退化率和1045/1022 cm−1比值均先降低后升高,但相对结晶度、1022/995 cm−1比值、透光率、溶解度和溶胀力均先升高后降低。与其他施肥水平相比,普通荞麦淀粉在中等施肥水平下具有较高的糊化温度和糊化焓,但糊化粘度较低。结果表明,180 (N)、115.2 (P)和84.6 (K) kg/hm 2的施肥水平对荞麦淀粉品质较为适宜,可为荞麦栽培提供参考。这篇文章受版权保护。版权所有
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引用次数: 0
Masthead: Starch ‐ Stärke 9–10/2023 刊头:Starch - Stärke 9-10/2023
Pub Date : 2023-09-01 DOI: 10.1002/star.202370021
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引用次数: 0
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Starch - Stärke
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