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Nanoparticle-Enhanced Water-Based-Emulsion Fracturing Fluid for Improved Imbibition Recovery in Unconventional Reservoirs: Performance and Mechanism 纳米颗粒增强型水基乳液压裂液用于提高非常规储层的浸润采收率:性能与机理
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.2118/219739-pa
Mengjiao Cao, Ruoyu Wang, Yuchen Li, Caili Dai, Xiang Yan, Liyuan Zhang, Yining Wu
The conventional friction reducer, typically a water-in-oil (W/O) emulsion, used in slickwater, encounters challenges related to poor environmental friendliness, limited stability, and low activity, hindering its widespread applicability. In this study, we synthesized a water-based emulsion through water dispersion polymerization, incorporating nanoparticles (NPs) into the process to enhance the stability and activity of the polymer emulsion. The result is an environmentally friendly, oil-phase-free, instantly dissolution, and highly efficient friction reducer, intended to optimize the utilization efficiency of slickwater. The NP-enhanced water-based emulsion demonstrated a consistent and spherical dispersion, featuring an average particle size of ~10 μm, maintaining stability for more than 6 months. With rapid dissolution in water, achieved within a mere 38 seconds, it facilitated continuous on-the-fly mixing. Slickwater composed of this emulsion exhibited outstanding application performance, yielding a remarkable 76% reduction in pipeline friction. The presence of NPs and specific monomers facilitated the formation of a spatial network structure that maintains high temperature/shear resistance even after prolonged shear. Moreover, the system exhibited an exceptional capacity for imbibition oil production. Indoor spontaneous imbibition experiments showed a final recovery rate of 32.41% in tight oil cores (~10% higher than conventional systems), and imbibition depth reached 40.2 mm (1.2-fold increase compared with traditional systems). Field experiments were conducted in a tight oil reservoir to validate practical applications; the results further validated the effectiveness of the novel system. The treated wells showcased rapid oil production, reaching an average daily production rate of 55.8 t/d and water content as low as ~31%, satisfying the predicted production target.
传统的减摩剂通常是油包水(W/O)乳液,用于浮油水时遇到了环境友好性差、稳定性有限和活性低等挑战,阻碍了其广泛应用。在本研究中,我们通过水分散聚合法合成了一种水基乳液,并在此过程中加入了纳米粒子 (NPs),以提高聚合物乳液的稳定性和活性。其结果是一种环保、无油相、瞬间溶解、高效的减摩剂,旨在优化浮油水的利用效率。经 NP 增强的水基乳液具有稳定的球形分散性,平均粒径约为 10 μm,可在 6 个月内保持稳定。它在水中的溶解速度极快,仅需 38 秒就能完成,有利于连续的即时混合。由这种乳液组成的 Slickwater 具有出色的应用性能,可显著减少 76% 的管道摩擦。NPs 和特定单体的存在促进了空间网络结构的形成,即使在长时间剪切后也能保持较高的耐温/抗剪性能。此外,该系统还表现出卓越的浸润产油能力。室内自发浸润实验显示,致密油岩心的最终采收率为 32.41%(比传统体系高出约 10%),浸润深度达到 40.2 毫米(比传统体系增加了 1.2 倍)。为验证实际应用,在致密油藏中进行了现场实验;结果进一步验证了新型系统的有效性。经过处理的油井显示出快速的石油生产,平均日产量达到 55.8 吨/天,含水率低至 ~31%,达到了预测的生产目标。
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引用次数: 0
Competitive Knowledge Transfer–Enhanced Surrogate-Assisted Search for Production Optimization 用于生产优化的竞争性知识转移--增强型代用辅助搜索
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.2118/219732-pa
Chenming Cao, Xiaoming Xue, Kai Zhang, Linqi Song, Liming Zhang, Xia Yan, Yongfei Yang, Jun Yao, Wensheng Zhou, Chen Liu
Production optimization is a crucial component of closed-loop reservoir management, which typically aims to search for the best development scheme for maximum economic benefit. Over the decades, a large body of algorithms have been proposed to address production optimization problems, among which the surrogate-assisted evolutionary algorithm (SAEA) gained much research popularity due to its problem information-agnostic implementation and strong global search capability. However, existing production optimization methods often optimize individual tasks from scratch in an isolated manner, ignoring the available optimization experience hidden in previously optimized tasks. The incapability of transferring knowledge from possibly related tasks makes these algorithms always require a considerable number of simulation runs to obtain high-quality development schemes, which could be computationally prohibitive. To address this issue, this paper proposes a novel competitive knowledge transfer (CKT) method to leverage the knowledge from previously solved tasks toward enhanced production optimization performance. The proposed method consists of two parts: (1) similarity measurement that uses both reservoir features and optimization data for identifying the most promising previously solved task and (2) CKT that launches a competition between the development schemes of different tasks to decide whether to trigger the knowledge transfer. The efficacy of the proposed method is validated on a number of synthetic benchmark functions as well as two production optimization tasks. The experimental results demonstrate that the proposed method can significantly improve production optimization performance and achieve better optimization results when certain helpful previously optimized tasks are available.
生产优化是闭环油藏管理的重要组成部分,其目的通常是寻找最佳开发方案,以获得最大经济效益。几十年来,人们提出了大量算法来解决生产优化问题,其中代理辅助进化算法(SAEA)因其与问题信息无关的实现方式和强大的全局搜索能力而备受研究青睐。然而,现有的生产优化方法往往以孤立的方式从零开始优化单个任务,忽略了隐藏在先前优化任务中的可用优化经验。由于无法从可能相关的任务中转移知识,这些算法总是需要大量的仿真运行才能获得高质量的开发方案,这在计算上可能是难以承受的。为了解决这个问题,本文提出了一种新颖的竞争性知识转移(CKT)方法,利用以前已解决任务中的知识来提高生产优化性能。该方法由两部分组成:(1) 相似性测量,使用油藏特征和优化数据来识别最有前途的先前已解决任务;(2) CKT,在不同任务的开发方案之间展开竞争,以决定是否触发知识转移。我们在一些合成基准函数和两个生产优化任务上验证了所提方法的有效性。实验结果表明,所提出的方法能显著提高生产优化性能,并在某些有用的先前优化任务可用时取得更好的优化结果。
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引用次数: 0
An Investigation of Gas-Fingering Behavior during CO2 Flooding in Acid Stimulation Formations 酸性地层二氧化碳充注过程中的气体褶皱行为研究
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-03-01 DOI: 10.2118/219486-pa
Longlong Li, Cunqi Jia, Jun Yao, K. Sepehrnoori, A. Abushaikha, Yuewu Liu
CO2 flooding is emerging as a pivotal technique used extensively for carbon capture, utilization, and storage (CCUS) strategies. Acid stimulation is one common technique widely used to improve well-formation connectivity by creating wormholes. This work is motivated to investigate the gas-fingering behavior induced by acid stimulation during CO2 flooding. We present an integrated simulation framework to couple the acid stimulation and CO2 flooding processes, in which the two-scale continuum model is used to model the development of wormhole dissolution patterns. Then, sensitivity case simulations are conducted through the equation of state (EOS)–based compositional model to further analyze the CO2 fingering behavior in acid stimulation formations separately under immiscible and miscible conditions. Results demonstrate that for acid stimulation, the typical dissolution patterns and the optimal acid injection rate corresponding to the minimum acid breakthrough volume observed in the laboratory are prevalent in field-scale simulations. For CO2 flooding simulation, the dissolution patterns trigger CO2 fingering (bypassing due to the high conductivity of wormholes) in the stimulated region, and a lateral boundary effect eliminating fingers exerts its influence over the system through transverse mixing. The optimal acid injection rate varies when the focus of interest changes from the minimum acid breakthrough volume to CO2 flooding performance. The best CO2 flooding performance is always observed in uniform dissolution, and the dissolution patterns have a greater influence on the performance under miscible conditions. This work provides technical and theoretical support for the practical application of acid stimulation and CO2 flooding.
二氧化碳淹没正在成为碳捕集、利用和封存(CCUS)战略中广泛使用的一项关键技术。酸性刺激是一种常用技术,被广泛用于通过创建虫孔来改善成井的连通性。这项工作的目的是研究二氧化碳充注过程中酸性激励引起的气体窜入行为。我们提出了一个综合模拟框架,将酸性刺激和二氧化碳充注过程结合起来,其中使用了双尺度连续模型来模拟虫洞溶解模式的发展。然后,我们通过基于状态方程(EOS)的成分模型进行了敏感性模拟,进一步分析了在不混溶和混溶条件下,酸性激发地层中的二氧化碳指状行为。结果表明,对于酸性激励,实验室观察到的典型溶解模式和与最小酸突破体积相对应的最佳酸注入率在现场规模模拟中普遍存在。在二氧化碳淹没模拟中,溶解模式会触发受激励区域的二氧化碳指接(由于虫洞的高传导性而产生的旁路),而消除指接的横向边界效应会通过横向混合对系统产生影响。当关注点从最小酸突破量转向二氧化碳淹没性能时,最佳酸注入率也会发生变化。最佳的二氧化碳淹没性能总是在均匀溶解的情况下观察到的,而溶解模式对混溶条件下的性能影响更大。这项工作为酸激励和二氧化碳水淹的实际应用提供了技术和理论支持。
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引用次数: 0
Dynamic Scaling Prediction Model and Application in Near-Wellbore Formation of Ultradeep Natural Gas Reservoirs 动态缩放预测模型及在超深层天然气储层近井筒形成中的应用
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-02-28 DOI: 10.2118/219471-pa
Lihu Cao, Hua Yuan, Zhaocai Pan, Zhibin Liu, Bao Zhang, Tao Sun, Jianyi Liu, Hongjun Wu

To address the significant scaling challenges within the near-wellbore formation of ultradeep natural gas reservoirs characterized by high temperature and high salinity, we developed a dynamic scaling prediction model. This model is specifically designed for the prediction of scaling in gas-water two-phase seepage within fractured-matrix dual-porosity reservoirs. It accounts for the concentration effects resulting from the evaporation of water on formation water ions. Our scaling model is discretely solved using the finite volume method. We also conducted on-site dynamic scaling simulations for gas wells, allowing us to precisely predict the distribution of ion concentrations in the reservoir, as well as changes in porosity and permeability properties, and the scaling law dynamics. The simulation results reveal a significant drop in formation pressure, decreasing from 105 MPa to 76.7 MPa after 7.5 years of production. The near-wellbore formation is particularly affected by severe scaling, mainly attributed to the radial pressure drop funneling effect, leading to a reduction in scaling ion concentrations in the vicinity of the wellbore. Calcium carbonate is identified as the predominant scaling component within the reservoir, while calcium sulfate serves as a secondary contributor, together accounting for roughly 85.2% of the total scaling deposits. In contrast, the scaling impact on the matrix system within the reservoir remains minimal. However, the central fracture system exhibits notable damage, with reductions of 71.2% in porosity and 59.8% in permeability. The fracture system within a 5-m radius around the wellbore is recognized as the primary area of scaling damage in the reservoir. The use of the simulation approach proposed in this study can offer valuable support for analyzing the dynamic scaling patterns in gasfield reservoirs and optimizing scaling mitigation processes.

超深层天然气储层具有高温和高盐度的特点,为解决其近井筒地层内的重大缩放难题,我们开发了一种动态缩放预测模型。该模型专门用于预测裂缝基质双孔隙储层中气水两相渗流的缩放情况。它考虑了水蒸发对地层水离子产生的浓度效应。我们的缩放模型采用有限体积法进行离散求解。我们还对气井进行了现场动态缩放模拟,从而可以精确预测储层中离子浓度的分布、孔隙度和渗透率特性的变化以及缩放规律的动态变化。模拟结果显示,地层压力显著下降,在生产 7.5 年后从 105 兆帕下降到 76.7 兆帕。井筒附近地层尤其受到严重缩放的影响,这主要归因于径向压降漏斗效应,导致井筒附近缩放离子浓度降低。碳酸钙被确定为储层中最主要的结垢成分,而硫酸钙则是次要的结垢成分,二者合计约占结垢沉积总量的 85.2%。相比之下,结垢对储层内基质系统的影响仍然很小。然而,中央裂缝系统受到了明显的破坏,孔隙度降低了 71.2%,渗透率降低了 59.8%。井筒周围 5 米半径范围内的裂缝系统被认为是储层中主要的缩放破坏区域。使用本研究提出的模拟方法,可以为分析气田储层的动态缩放模式和优化缩放减缓过程提供有价值的支持。
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引用次数: 0
Virtual Meter with Flow Pattern Recognition Using Deep Learning Neural Networks: Experiments and Analyses 利用深度学习神经网络进行流量模式识别的虚拟仪表:实验与分析
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-02-15 DOI: 10.2118/219465-pa
Renata Mercante, Theodoro Antoun Netto

Operators often require real-time measurement of fluid flow rates in each well of their fields, which allows better control of production. However, petroleum is a complex multiphase mixture composed of water, gas, oil, and other sediments, which makes its flow challenging to measure and monitor. A critical issue is how the liquid component interacts with the gaseous phase, also known as the flow pattern. For example, sometimes liquids can accumulate in the lower part of the pipeline and block the flow completely, causing a gas pressure buildup that can lead to unstable flow regimes or even accidents (blowouts). On the other hand, some flow patterns can also facilitate sediment deposition, leading to obstructions and reduced production. Thus, this work aims to show that deep neural networks can act as a virtual flowmeter (VFM) using only a history of production, pressure, and temperature telemetry, accurately estimating the flow of all fluids in real time. In addition, these networks can also use the same input data to detect and recognize flow patterns that can harm the regular operation of the wells, allowing greater control without requiring additional costs or the installation of any new equipment. To demonstrate the feasibility of this approach and provide data to train the neural networks, a water-air loop was constructed to resemble an oil well. This setup featured inclined and vertical transparent pipes to generate and observe different flow patterns and sensors to record temperature, pressure, and volumetric flow rates. The results show that deep neural networks achieved up to 98% accuracy in flow pattern prediction and 1% mean absolute prediction error (MAPE) in flow rates, highlighting the capability of this technique to provide crucial insights into the behavior of multiphase flow in risers and pipelines.

运营商通常需要实时测量油田每个油井的流体流速,以便更好地控制生产。然而,石油是一种复杂的多相混合物,由水、气体、石油和其他沉积物组成,因此测量和监控其流动具有挑战性。一个关键问题是液相成分如何与气相相互作用,也就是所谓的流动模式。例如,有时液体会积聚在管道下部,完全阻塞流动,造成气体压力积聚,从而导致不稳定的流动状态,甚至发生事故(井喷)。另一方面,某些流动模式也会促进沉积物沉积,导致阻塞和减产。因此,这项工作旨在证明,深度神经网络可以充当虚拟流量计(VFM),只需使用历史产量、压力和温度遥测数据,就能实时准确地估计所有流体的流量。此外,这些网络还可以使用相同的输入数据来检测和识别可能损害油井正常运行的流量模式,从而在不增加成本或安装任何新设备的情况下加强控制。为了证明这种方法的可行性,并提供训练神经网络的数据,我们建造了一个类似油井的水气环路。该装置包括倾斜和垂直的透明管道,用于产生和观察不同的流动模式,以及用于记录温度、压力和容积流量的传感器。结果表明,深度神经网络在流动模式预测方面的准确率高达 98%,在流速方面的平均绝对预测误差 (MAPE) 仅为 1%,这凸显了该技术为立管和管道中的多相流行为提供重要见解的能力。
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引用次数: 0
Injection Temperature Impacts on Reservoir Response during CO2 Storage 二氧化碳封存过程中注入温度对储层响应的影响
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-02-15 DOI: 10.2118/219461-pa
Mahendra Samaroo, Mark McClure, Garrett Fowler, Rick Chalaturnyk, Maurice B. Dusseault, Christopher Hawkes

Sustained injection of industrial-scale volumes of cold CO2 into warmer subsurface rock will result in extensive cooling which can alter rock mass mechanical behavior and fluid migration characteristics. Advanced simulation tools are available to assess and characterize such phenomena; however, the effective use of these tools requires appropriate injection temperatures and rock thermophysical parameters (in addition to geomechanical and hydraulic properties). The primary objective of this study was to demonstrate the sensitivity of injection-induced tensile fracturing and fault reactivation to injection temperature and reservoir thermophysical properties during CO2 injection operations. This was achieved by (1) compiling and reviewing thermophysical parameter data available for formations in the province of Alberta, Canada, and CO2 injection temperature records for CO2 injection projects in western Canada and (2) using a 3D, physics-based, fully integrated hydraulic fracturing and reservoir simulation numerical model to examine the geomechanical response of several potential CO2 reservoirs in the Alberta Basin as a function of injection temperature, thermal conductivity (TC), and coefficient of linear thermal expansion (CLTE) values. The simulation results indicate that reducing the fluid injection temperature from 15°C (assumed in previous work) to 2°C (conservative value selected based on temperature data reviewed in this work) could trigger extensive vertical (20–130 m high, 100–600 m long) tensile fractures with rapid fracture initiation and full vertical growth within short periods (weeks to months) and continued horizontal length increase. When low values for thermophysical properties are used, the results show that thermally-induced tensile fracturing is unlikely, whereas the use of high values results in extensive tensile fracturing in all simulations. A similar conclusion was reached for the thermally-induced reactivation (unclamping) of proximal, critically-stressed faults. Notably, slip is predicted for all simulations where high thermophysical property values are used. This confirms that accurate determination of minimum fluid injection temperature and thermophysical parameters is important for containment risk assessment for commercial-scale CO2 storage projects. Another significant outcome of this work is the observation that most thermophysical parameters in the available data were measured using experimental conditions and/or temperature paths that are not representative of CO2 injection projects. As such, the development and validation of best practice approaches for accurate assessment of these parameters seem necessary.

将工业规模的低温二氧化碳持续注入温度较高的地下岩石会导致大面积冷却,从而改变岩体的机械行为和流体迁移特性。先进的模拟工具可用于评估和描述此类现象;然而,要有效使用这些工具,需要适当的注入温度和岩石热物理参数(以及地质力学和水力特性)。本研究的主要目的是证明在二氧化碳注入过程中,注入诱导的拉伸压裂和断层再活化对注入温度和储层热物理特性的敏感性。具体方法是:(1) 汇编和审查加拿大阿尔伯塔省地层的热物理参数数据,以及加拿大西部二氧化碳注入项目的二氧化碳注入温度记录;(2) 使用基于物理的三维全集成水力压裂和储层模拟数值模型,研究阿尔伯塔盆地几个潜在二氧化碳储层的地质力学响应与注入温度、热导率 (TC) 和线性热膨胀系数 (CLTE) 值的函数关系。模拟结果表明,将流体注入温度从 15°C(以前工作中的假设)降低到 2°C(根据本工作中审查的温度数据选择的保守值)可引发大范围垂直(20-130 米高,100-600 米长)拉伸裂缝,裂缝在短期内(几周到几个月)迅速形成并完全垂直生长,水平长度持续增加。热物理性质数值较低时,结果表明热引起的拉伸断裂不太可能发生,而数值较高时,在所有模拟中都会出现大面积拉伸断裂。对于近端严重受压断层的热诱导重新激活(解闭)也得出了类似的结论。值得注意的是,在使用高热物理特性值的所有模拟中都预测到了滑移。这证明,准确确定最低流体注入温度和热物理参数对于商业规模二氧化碳封存项目的封存风险评估非常重要。这项工作的另一个重要成果是发现,现有数据中的大多数热物理参数都是在不代表二氧化碳注入项目的实验条件和/或温度路径下测量的。因此,似乎有必要开发和验证准确评估这些参数的最佳实践方法。
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引用次数: 0
Adsorption Characteristics of CO2/CH4/H2S Mixtures in Calcite Nanopores with the Implications for CO2 Sequestration 方解石纳米孔中 CO2/CH4/H2S 混合物的吸附特性及其对二氧化碳封存的影响
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-02-15 DOI: 10.2118/219463-pa
Zhenhua Rui, Cheng Qian, Yueliang Liu, Yang Zhao, Huazhou Andy Li, Andrey Afanasyev, Farshid Torabi

Injecting CO2 into reservoirs for storage and enhanced oil recovery (EOR) is a practical and cost-effective strategy for reducing carbon emissions. Commonly, CO2-rich industrial waste gas is used as the CO2 source, whereas contaminants such as H2S may severely impact carbon storage and EOR via competitive adsorption. Hence, the adsorption behavior of CH4, CO2, and H2S in calcite (CaCO3) micropores and the impact of H2S on CO2 sequestration and methane recovery are specifically investigated. The Grand Canonical Monte Carlo (GCMC) simulations were applied to study the adsorption characteristics of pure CO2, CH4, and H2S, and their multicomponent mixtures were also investigated in CaCO3 nanopores to reveal the impact of H2S on CO2 storage. The effects of pressure (0–20 MPa), temperature (293.15–383.15 K), pore width, buried depth, and gas mole fraction on the adsorption behaviors are simulated. Molecular dynamics (MD) simulations were performed to explore the diffusion characteristics of the three gases and their mixes. The amount of adsorbed CH4, CO2, and H2S enhances with rising pressure and declines with rising temperature. The order of adsorption quantity in CaCO3 nanopores is H2S > CO2 > CH4 based on the adsorption isotherm. At 10 MPa and 323.15 K, the interaction energies of CaCO3 with CO2, H2S, and CH4 are −2166.40 kcal/mol, −2076.93 kcal/mol, and −174.57 kcal/mol, respectively, which implies that the order of adsorption strength between the three gases and CaCO3 is CO2 > H2S > CH4. The CH4-CaCO3 and H2S-CaCO3 interaction energies are determined by van der Waals energy, whereas electrostatic energy predominates in the CO2-CaCO3 system. The adsorption loading of CH4 and CO2 are lowered by approximately 59.47% and 24.82% when the mole fraction of H2S is 20% at 323.15 K, reflecting the weakening of CH4 and CO2 adsorption by H2S due to competitive adsorption. The diffusivities of three pure gases in CaCO3 nanopore are listed in the following order: CH4 > H2S ≈ CO2. The presence of H2S in the ternary mixtures will limit diffusion and outflow of the system and each single gas, with CH4 being the gas most affected by H2S. Concerning carbon storage in CaCO3 nanopores, the CO2/CH4 binary mixture is suitable for burial in shallower formations (around 1000 m) to maximize the storage amount, while the CO2/CH4/H2S ternary mixture sho

向储油层注入二氧化碳进行封存和提高石油采收率(EOR)是一种实用且具有成本效益的减少碳排放的策略。通常,富含二氧化碳的工业废气被用作二氧化碳源,而 H2S 等污染物可能会通过竞争性吸附严重影响碳储存和 EOR。因此,本文专门研究了 CH4、CO2 和 H2S 在方解石(CaCO3)微孔中的吸附行为以及 H2S 对 CO2 封存和甲烷回收的影响。应用大卡农蒙特卡罗(GCMC)模拟研究了纯 CO2、CH4 和 H2S 的吸附特性,还研究了它们的多组分混合物在 CaCO3 纳米孔中的吸附特性,以揭示 H2S 对 CO2 封存的影响。模拟了压力(0-20 兆帕)、温度(293.15-383.15 K)、孔隙宽度、埋藏深度和气体摩尔分数对吸附行为的影响。分子动力学(MD)模拟探讨了三种气体及其混合气体的扩散特性。CH4、CO2 和 H2S 的吸附量随压力升高而增加,随温度升高而减少。根据吸附等温线,CaCO3 纳米孔中的吸附量顺序为 H2S > CO2 > CH4。在 10 MPa 和 323.15 K 条件下,CaCO3 与 CO2、H2S 和 CH4 的相互作用能分别为 -2166.40 kcal/mol、-2076.93 kcal/mol 和 -174.57 kcal/mol,这意味着三种气体与 CaCO3 的吸附强度顺序为 CO2 > H2S > CH4。CH4-CaCO3 和 H2S-CaCO3 的相互作用能由范德华能决定,而 CO2-CaCO3 系统中则以静电能为主。在 323.15 K 下,当 H2S 的摩尔分数为 20% 时,CH4 和 CO2 的吸附负荷分别降低了约 59.47% 和 24.82%,这反映了 H2S 由于竞争吸附而削弱了对 CH4 和 CO2 的吸附。三种纯气体在 CaCO3 纳米孔中的扩散率按以下顺序排列:CH4 > H2S ≈ CO2。三元混合物中 H2S 的存在将限制系统和每种单一气体的扩散和流出,而 CH4 是受 H2S 影响最大的气体。关于 CaCO3 纳米孔中的碳封存,CO2/CH4 二元混合物适合埋藏在较浅的地层中(1000 米左右),以获得最大的封存量,而 CO2/CH4/H2S 三元混合物则应尽可能深埋,以减少 H2S 的不利影响。该研究阐明了 H2S 对 CaCO3 纳米孔隙中 CO2 封存和 CH4 回收的影响,为碳酸盐岩层中的 CO2 封存和 EOR 项目提供了理论帮助。
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引用次数: 0
A New Mechanistic Model for Wettability-Altering Surfactant Floods in Carbonates 碳酸盐中润湿性改变表面活性剂泛滥的新机制模型
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-02-14 DOI: 10.2118/219468-pa
Yue Shi, Kishore K. Mohanty, Juliana Y. Leung, Qing You

Surfactants and low-salinity brines have been shown to be effective for enhanced oil recovery in carbonate rocks through wettability alteration (WA). Oil wettability of carbonates is ascribed to the adsorbed organic acid components in oil. The removal of the adsorbed acids leads to WA. Previous experiments with wettability-altering surfactants have shown the following: WA is a slow process; acid removal is irreversible in most cases; surfactants can access the rock surface in water-wet regions and at three-phase contact lines rather than the entire rock surface; surfactant molecules become inactive after interactions with acids. Existing models/simulators do not incorporate the aforementioned observations. In this work, a multiphase, multicomponent, finite-difference reservoir simulator incorporating a new mechanistic model for WA was developed. The model captures the key physicochemical reactions between adsorbed acids and surfactant molecules and honors the four experimental evidences. The model was first tested at the core scale. The simulation results demonstrated that the model can accurately predict waterflood performance in rocks with various wettability. It can also effectively account for the influence of injection rates in surfactant flood experiments. The effectiveness of the surfactant, controlled by an interaction constant in the model, was found to be a dominant factor. The model was also tested for field-scale pilot tests. The results revealed that total quantity of chemicals injected and the injection rate have a more pronounced effect on oil recovery compared to the timing of surfactant treatment and the concentration of surfactant slug.

事实证明,表面活性剂和低盐度盐水可通过润湿性改变(WA)有效提高碳酸盐岩的石油采收率。碳酸盐岩的石油润湿性归因于石油中吸附的有机酸成分。吸附酸的去除会导致润湿性改变。之前使用润湿性改变表面活性剂进行的实验表明了以下几点:WA 是一个缓慢的过程;酸的去除在大多数情况下是不可逆的;表面活性剂可以进入水湿区域和三相接触线处的岩石表面,而不是整个岩石表面;表面活性剂分子在与酸相互作用后会失去活性。现有的模型/模拟器没有将上述观察结果纳入其中。在这项工作中,开发了一种多相、多组分、有限差分储层模拟器,其中包含一个新的 WA 机理模型。该模型捕捉到了吸附酸和表面活性剂分子之间的关键物理化学反应,并尊重了四个实验证据。该模型首先在核心尺度上进行了测试。模拟结果表明,该模型可以准确预测不同润湿性岩石的注水性能。该模型还能有效地解释表面活性剂注水实验中注入率的影响。研究发现,表面活性剂的效果是一个主导因素,由模型中的相互作用常数控制。还对该模型进行了实地规模的试验测试。结果显示,与表面活性剂处理时间和表面活性剂蛞蝓浓度相比,化学品注入总量和注入率对采油率的影响更为明显。
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引用次数: 0
Performance Analysis of the Vortex Cuttings Cleaner: Turbine Hydraulic Drive and Cuttings Transport in Wellbore Annulus 涡流式岩屑清理机的性能分析:涡轮水力驱动与井筒环形空间的岩屑输送
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-02-13 DOI: 10.2118/219462-pa
Yiqun Zhang, Zhaowen Hu, Qi Wang, Haochen Huang, Ya Liu, Wei Wang

In the process of directional and horizontal well drilling, cuttings tend to settle and form a bed at the low side of the annulus due to gravity, which decreases the drilling rate and even causes accidents in severe cases. This paper analyzes the performance of a new tool, the vortex cuttings cleaner, which can be effective without rotation of the drillpipe. Based on the computational fluid dynamics (CFD) approach, together with the discrete phase, Euler, and dynamic mesh models, the vortex cuttings cleaner is investigated with respect to the turbine torque, turbine velocity, pressure drop, and cuttings transport in the annulus. The working mechanism of the vortex cuttings cleaner is clarified. Finally, field tests are conducted on the tool to evaluate its application in terms of service life, wellbore friction, and rate of penetration (ROP). The results show that the turbine can rotate continuously under hydraulic drive. The turbine torque/velocity and the tool’s pressure drop increase with increasing displacement. The cuttings transport in the annulus is jointly affected by factors such as turbine velocity, fluid velocity, and particle size. A too low or high turbine velocity is unfavorable for cuttings transport. Through the analysis of the number of particles and particle concentration, the optimal velocity is determined to be 125 rev/min. The swirling flow intensity in the annulus flow field increases with the increase in turbine velocity. Field applications suggest a service life longer than 200 hours, a notable decrease in wellbore friction, and an average increase in ROP by more than 20%. This study provides a theoretical basis for the research on wellbore cleaning tools.

在定向井和水平井钻井过程中,由于重力作用,切屑容易沉淀并在环空低侧形成床层,从而降低钻井速度,严重时甚至会造成事故。本文分析了一种新工具--涡流式钻屑清理器的性能,该工具无需旋转钻杆即可有效清理钻屑。基于计算流体动力学(CFD)方法,结合离散相位模型、欧拉模型和动态网格模型,研究了涡流式掘进机的涡轮扭矩、涡轮速度、压降和掘进物在环形空间中的输送情况。阐明了涡流式掘进机的工作机理。最后,对该工具进行了现场测试,以评估其在使用寿命、井筒摩擦和穿透率(ROP)方面的应用。结果表明,涡轮可在液压驱动下连续旋转。涡轮扭矩/速度和工具压降随着排量的增加而增加。环空中的切屑输送受到涡轮速度、流体速度和颗粒大小等因素的共同影响。涡轮速度过低或过高都不利于切屑的输送。通过对颗粒数量和颗粒浓度的分析,确定最佳速度为 125 转/分钟。环形流场中的漩涡流强度随着涡轮速度的增加而增加。现场应用表明,涡轮的使用寿命超过 200 小时,井筒摩擦显著降低,ROP 平均提高 20% 以上。这项研究为井筒清洁工具的研究提供了理论依据。
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引用次数: 0
Study on the Shearing Force of Ram and Fracture Characteristics of Drillpipe Under Precutting 预切削下钻杆的柱塞剪切力和断裂特性研究
IF 3.6 3区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2024-02-01 DOI: 10.2118/219482-pa
Shihong Xiao, Maolin Xiang, Jun Guo, Jiakai Cui, Qiulin Tang, Junjie Jiang
The working pressure of the hydraulic system, as well as the volume and weight of the ram blowout preventer (BOP), cannot be increased excessively. This limitation affects the shearing force provided by the hydraulic cylinder of the BOP. When shearing high-strength, large-thickness, and large-diameter drillpipes, it is easy to cause shear failure, making blowout control challenging. Therefore, we proposed a high-pressure water-jet-assisted precutting method to reduce the force required to shear the drillpipe. Based on the numerical model verified by experiments, we compared and analyzed the shearing force variations and drillpipe fracture characteristics under different precutting methods. We also provided recommendations for selecting precutting methods. Furthermore, we identified the weights and grades of drillpipes that affect the shearing force under precutting. The results demonstrate that precutting the drillpipe can reduce shear forces, shorten fracture time, and improve fracture quality. The use of water-jet precutting technology enhances the efficiency of emergency well shut-in operations and subsequent pipe fishing. The presented technology is currently at a prefeasibility stage, and further efforts are needed to implement these ideas in practice.
液压系统的工作压力以及柱塞式防喷器(BOP)的体积和重量不能过度增加。这一限制会影响 BOP 液压缸提供的剪切力。在剪切高强度、大厚度和大直径钻杆时,很容易造成剪切失效,给井喷控制带来挑战。因此,我们提出了一种高压水射流辅助预切割方法,以减少剪切钻杆所需的力。基于实验验证的数值模型,我们对比分析了不同预切割方法下的剪切力变化和钻杆断裂特征。我们还提供了选择预切割方法的建议。此外,我们还确定了影响预切割下剪切力的钻杆重量和等级。结果表明,钻杆预切割可以降低剪切力,缩短压裂时间,提高压裂质量。使用喷水预切割技术可提高紧急关井作业和后续捞管的效率。所介绍的技术目前还处于预可行性阶段,需要进一步努力将这些想法付诸实践。
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引用次数: 0
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