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Adsorption of single and mixed surfactants consisting of cocoamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) onto zinc surface 由椰油酰胺丙基甜菜碱(CAPB)和十二烷基苯磺酸钠(SDBS)组成的单一表面活性剂和混合表面活性剂在锌表面的吸附情况
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-04-18 DOI: 10.1515/tsd-2024-2584
Rami A. Abdel-Rahem, Muayad Esaifan, Abdelmnim Altwaiq, Neela Gayathri Ganesan, Mayyas Al-Remawi
Aqueous solutions of surfactants exhibit remarkable differences in their adsorption properties on metal surfaces. This study evaluates the adsorption of surfactant mixtures on zinc metal surfaces. The adsorption of single surfactants cocamidopropyl betaine (CAPB) and sodium dodecyl benzenesulfonate (SDBS) and their mixtures from aqueous solution at mole fractions of 0.00, 0.25, 0.50, 0.75 and 1.00 on zinc powder at 25 °C was studied. The surface tension of the single and CAPB/SDBS surfactant mixtures was measured in the presence and absence of 2 % zinc powder to determine the adsorption isotherms. The depletion method was employed to carry out the adsorption investigation. The amount of the surfactant adsorbed was also calculated from the shaded area between the surface tension versus concentration curves of these surfactants in the presence and absence of 2 % zinc powder. The highest adsorbed amounts were found to increase with the SDBS content. Furthermore, scanning electron microscope (SEM) images of zinc sheets in solutions containing single or mixed CAPB/SDBS surfactants were taken in the presence and absence of 0.05 M HCl. The micrographs indicated that the CAPB-SDBS surfactant layers formed by precipitation can protect zinc metal from acid corrosion.
表面活性剂水溶液在金属表面上的吸附特性存在显著差异。本研究评估了表面活性剂混合物在锌金属表面的吸附情况。研究了单一表面活性剂椰油酰胺丙基甜菜碱(CAPB)和十二烷基苯磺酸钠(SDBS)以及它们的混合物在 25 °C、0.00、0.25、0.50、0.75 和 1.00 摩尔分数的水溶液中在锌粉上的吸附情况。在 2% 的锌粉存在和不存在的情况下,测量了单一表面活性剂和 CAPB/SDBS 表面活性剂混合物的表面张力,以确定吸附等温线。吸附研究采用了耗竭法。根据这些表面活性剂在有 2% 锌粉和没有 2% 锌粉时的表面张力与浓度曲线之间的阴影面积,还计算出了表面活性剂的吸附量。结果发现,随着 SDBS 含量的增加,吸附量也随之增加。此外,还拍摄了含有单一或混合 CAPB/SDBS 表面活性剂的溶液中锌薄片在 0.05 M HCl 存在和不存在时的扫描电子显微镜(SEM)图像。显微照片显示,沉淀形成的 CAPB-SDBS 表面活性剂层可以保护锌金属免受酸腐蚀。
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引用次数: 0
Micellar extracts obtained from Bistortae rhizoma, Fraxinus excelsior, and Romex crispus as components of hair shampoos 从 Bistortae rhizoma、Fraxinus excelsior 和 Romex crispus 中提取的胶束提取物作为洗发水的成分
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-04-15 DOI: 10.1515/tsd-2024-2587
Małgorzata Zięba, Dominik Czerwonka, Millena Ruszkowska
The aim of the present study was to evaluate the potential applications of micellar extracts derived from Bistortae rhizoma, Fraxinus excelsior, and Romex crispus as components of hair shampoos and to examine the impact of these micellar extracts on the specific properties of the formulated cosmetics. The antioxidant activity, polyphenol content, and vitamin C content of the plant materials selected for the study were assessed. In addition, particle size analysis was performed for the obtained micellar extracts. The shampoos prepared on the basis of original formulations were evaluated for irritation potential, viscosity, foam stability index, and color. The plants evaluated in the study exhibited a high level of antioxidant activity, and the derived extracts were found to contain micellar aggregates. The application of the extracts was shown to reduce the skin irritation potential of the shampoos and reduce their viscosity. In addition, the formulated shampoos were characterized by a high foam stability index. Substantial variations in the color of the cosmetics were observed upon the introduction of the micellar extracts into the formulations.
本研究的目的是评估从 Bistortae rhizoma、Fraxinus excelsior 和 Romex crispus 提取的胶束萃取物作为洗发水成分的潜在应用,并研究这些胶束萃取物对配制化妆品的特定属性的影响。研究对所选植物材料的抗氧化活性、多酚含量和维生素 C 含量进行了评估。此外,还对获得的胶束提取物进行了粒度分析。在原始配方的基础上制备的洗发水在刺激性、粘度、泡沫稳定性指数和颜色方面进行了评估。研究中评估的植物具有很高的抗氧化活性,并发现衍生提取物含有胶束聚集体。研究表明,使用这些提取物可以降低洗发水对皮肤的潜在刺激性,并降低其粘度。此外,配制的洗发水还具有泡沫稳定指数高的特点。在配方中加入胶束提取物后,化妆品的颜色发生了很大变化。
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引用次数: 0
Effect of solubilization with surfactant on the antioxidant activity of ellagic acid 用表面活性剂增溶对鞣花酸抗氧化活性的影响
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-03-14 DOI: 10.1515/tsd-2023-2565
Yulian Tang, Xinyuan Jiang
Ellagic acid (EA) is a natural antioxidant found in many fruits and vegetables. However, its solubility in water is poor, which limits its application. To overcome this limitation, the surfactants Span 20 and Tween 60 are used to increase its solubility in water. FTIR, TEM and laser particle size and zeta potential analysis were used to characterize the morphology and structure of ellagic acid emulsions. The antioxidant activity of surfactant-compatible ellagic acid was determined using various antioxidant evaluation methods such as DPPH and ABTS radical scavenging, reducing power and total antioxidant activity. The results indicate that the solubility of ellagic acid in water was improved by the addition of Span 20 and Tween 60, and ellagic acid formed complex particles in combination with Span 20 and Tween 60. Compared to pure ellagic acid, the antioxidant activity of ellagic acid lotion was significantly enhanced.
鞣花酸(EA)是一种天然抗氧化剂,存在于许多水果和蔬菜中。然而,它在水中的溶解度很低,这限制了它的应用。为了克服这一限制,我们使用了表面活性剂 Span 20 和 Tween 60 来增加其在水中的溶解度。傅立叶变换红外光谱、TEM 和激光粒度及 zeta 电位分析用于表征鞣花酸乳液的形态和结构。采用 DPPH 和 ABTS 自由基清除、还原力和总抗氧化活性等多种抗氧化评价方法测定了与表面活性剂兼容的鞣花酸的抗氧化活性。结果表明,加入司盘 20 和吐温 60 后,鞣花酸在水中的溶解度得到改善,鞣花酸与司盘 20 和吐温 60 结合后形成复合颗粒。与纯鞣花酸相比,鞣花酸乳液的抗氧化活性明显提高。
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引用次数: 0
The impact of detergent performance on sustainable consumer laundry behavior; a socio-technical challenge 洗涤剂性能对消费者可持续洗衣行为的影响;一项社会技术挑战
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-03-08 DOI: 10.1515/tsd-2023-2575
Debora Miranda Cortez, Martin Ter Bekke, Zhiwu Liang, Rainer Stamminger
The laundry process is energy-intensive and an important target for reducing residential environmental impacts. Category life-cycle analysis (LCA) studies show the primary environmental impact is due to the energy consumed during the use phase, mainly for heating water. However, doing the laundry is a complex socio-technical system, where addressing sustainability requires not only technical levers but also an understanding of users’ habits, practices, and belief systems. This study investigates if and how consumers change their laundry habits and product satisfaction when using a technically lower-performing eco-brand detergent compared to a heavy duty high-performance detergent. These represent two distinct sustainable innovation strategies within the detergent industry, i) high-performance detergents formulated to provide excellent cleaning performance at lower wash temperatures and ii) eco-brand detergents optimized for a lower ingredient footprint but reducing cleaning performance. It is hypothesized that consumers may compensate in ways detrimental to the overall sustainability of the laundry lifecycle. The results showed significantly lower consumer satisfaction with the eco-brand performance which led to compensatory behavior including increased detergent dosing and higher wash temperatures. This study confirms the importance of detergent cleaning performance for sustainable consumer habit changes regarding lower wash temperatures.
洗衣过程是能源密集型过程,也是减少住宅环境影响的重要目标。分类生命周期分析(LCA)研究表明,对环境的主要影响来自使用阶段的能源消耗,主要用于加热水。然而,洗衣是一个复杂的社会技术系统,解决可持续性问题不仅需要技术杠杆,还需要了解用户的习惯、做法和信仰体系。本研究调查了消费者在使用技术性能较低的环保品牌洗涤剂与使用重型高性能洗涤剂时,是否以及如何改变他们的洗衣习惯和产品满意度。这代表了洗涤剂行业中两种截然不同的可持续创新战略,即 i) 配制高性能洗涤剂,以便在较低的洗涤温度下提供出色的清洁性能;ii) 优化生态品牌洗涤剂,以减少成分足迹,但降低清洁性能。假设消费者可能会以不利于洗衣生命周期整体可持续性的方式进行补偿。结果显示,消费者对生态品牌性能的满意度明显降低,这导致了补偿行为,包括增加洗涤剂用量和提高洗涤温度。这项研究证实了洗涤剂清洁性能对于消费者改变可持续洗衣习惯、降低洗衣温度的重要性。
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引用次数: 0
Study on an all-in-one foaming agent with corrosion inhibition for air foam flooding 研究一种用于空气泡沫泛滥的具有缓蚀作用的多用途发泡剂
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-03-05 DOI: 10.1515/tsd-2023-2574
Wangjun Chang, Weishou Hu, Xiaojun Wang, Xuefan Gu, Shijun Chen, Gang Chen
Foam has been widely used in drilling, well washing, and oil driving during the development of oil and gas fields. Although air foams have been successfully employed as an enhanced oil medium, the oxygen they contain can seriously corrode piping systems, which can have a negative influence on output. This work used a combination of sodium dodecyl sulfate (SDS), dodecyl aminopropyl betaine (LAB), sodium dodecylbenzene sulfonate (SDBS), and cosurfactants to solve the problem above. The corrosion inhibitor hydrazine hydrate (N₂H₄·H₂O) was added as corrosion inhibitor. The foaming (air)-corrosion inhibitor all-in-one (SLN) was obtained with the formulation of SDS: LAB: N₂H₄·H₂O = 8:2:4. The foam volume of 0.7 % SLN was measured to be 515 mL at room temperature with a half-life of 4.1 min using the stirring method. The initial foam height of this all-in-one agent was measured to be 15.6 cm at 30 °C using the Roche foaming method. The foam height was still maintained at 15.5 cm after 20 min with a foam height retention of 99.2 %. The foam height retention rate was 50.0 % at 70 °C. Moreover, the formulation had good salt resistance to common inorganic salts in oilfield water. It should be emphasized that the SLN all-in-one agent has strong corrosion inhibition performance, and the corrosion inhibition rate can reach up to 96.9 %. The surface tension of this SLN all-in-one agent was reduced to 27.8 mN m−1 at a concentration of 0.1 %. It indicated that the all-in-one agent might increase the stability of the foam by decreasing the surface tension, thus improving the persistence of the foam and the effect of the repelling oil.
在油气田开发过程中,泡沫被广泛用于钻井、洗井和驱油。虽然空气泡沫已被成功用作增油介质,但其所含的氧气会严重腐蚀管道系统,从而对产量产生负面影响。这项工作采用十二烷基硫酸钠(SDS)、十二烷基氨基丙基甜菜碱(LAB)、十二烷基苯磺酸钠(SDBS)和共表面活性剂的组合来解决上述问题。加入缓蚀剂水合肼(N₂H₄-H₂O)作为缓蚀剂。在 SDS:LAB:N₂H₄-H₂O = 8:2:4 的配方下,得到了发泡(空气)-缓蚀剂多合一(SLN)。在室温下,用搅拌法测得 0.7 % SLN 的泡沫体积为 515 mL,半衰期为 4.1 分钟。使用罗氏发泡法,在 30 °C 时测得这种多合一药剂的初始泡沫高度为 15.6 厘米。20 分钟后,泡沫高度仍保持在 15.5 厘米,泡沫高度保持率为 99.2%。在 70 °C 时,泡沫高度保持率为 50.0%。此外,该配方对油田水中常见的无机盐具有良好的耐盐性。需要强调的是,SLN 一体剂具有很强的缓蚀性能,缓蚀率可达 96.9%。浓度为 0.1 % 时,SLN 一体剂的表面张力降至 27.8 mN m-1。这表明多合一助剂可以通过降低表面张力来增加泡沫的稳定性,从而提高泡沫的持久性和驱油效果。
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引用次数: 0
Effect of contaminated water (handwashing detergent) on seed germination traits in wheat, mung bean, and chickpea 污染水(洗手液)对小麦、绿豆和鹰嘴豆种子萌发特性的影响
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-03-05 DOI: 10.1515/tsd-2023-2578
Hassan Heidari, Sahar Karimi
Household detergents are a source of water pollu-tants that adversely affect crops. These pollutants not only reduce plant growth, but also have a negative impact on the environment. To investigate the effect of handwashing liquid on the germination characteristics of wheat, mung bean, and chickpea, a study was conducted using a completely randomized design with three replications. Water contaminated with different concentrations of handwashing liquid ((0, 0.01, 0.1, 1, 10) % of handwashing liquid) was used as treatment. The results showed that with increasing concentration of the contaminant, germination characteristics such as seed germination percentage, caulicle length, radicle length, and seed vigor decreased. Wheat was the most sensitive to detergent concentration compared to the other two plants, with the lowest detergent concentration causing a severe reduction in its germination traits. Therefore, farmers using water contaminated with household detergents need to be aware of its concentration to ensure healthy plant growth.
家用洗涤剂是水污染物的来源之一,会对农作物产生不利影响。这些污染物不仅会降低植物的生长,还会对环境造成负面影响。为了研究洗手液对小麦、绿豆和鹰嘴豆发芽特性的影响,研究采用了完全随机设计,三次重复的方法。使用不同浓度的洗手液((0、0.01、0.1、1、10)%)污染的水作为处理。结果表明,随着污染物浓度的增加,种子发芽率、茎秆长度、胚根长度和种子活力等发芽特性都有所下降。与其他两种植物相比,小麦对洗涤剂浓度最敏感,洗涤剂浓度最低时,小麦的发芽特性严重下降。因此,使用被家用洗涤剂污染的水的农民需要注意洗涤剂的浓度,以确保植物的健康生长。
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引用次数: 0
Synthesis and application feasibility study of cetyltrimethylammonium p-toluenesulfonate 十六烷基三甲基对甲苯磺酸铵的合成及应用可行性研究
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-03-05 DOI: 10.1515/tsd-2023-2570
Rui Zhou, Qiaona Liu, Jianwei Wang, Guibin Liu, Wenyu Ji, Sanbao Dong, Gang Chen
To improve the insufficient performance of anion on cationic surfactants and to further study the influence of anion on the surface properties, a cationic surfactant (cetyltrimethylammonium p-toluenesulfonate, CTATS) was prepared, and the relevant surface properties, including surface tension, critical micelle concentration, foaming ability and stability, corrosion inhibition and oil displacement efficiency were studied. Compared to cetyltrimethylammonium chloride (CTAC), CTATS exhibited higher surface activity, lower foaming volume, higher foam stability, higher corrosion inhibition performance and oil displacement efficiency. The results indicate that the CTATS has better performances as a surfactant type in oil and gas fields.
为了改善阴离子对阳离子表面活性剂性能的不足,进一步研究阴离子对表面性质的影响,制备了一种阳离子表面活性剂(十六烷基三甲基对甲苯磺酸铵,CTATS),并研究了其相关的表面性质,包括表面张力、临界胶束浓度、发泡能力和稳定性、缓蚀性和油置换效率。与十六烷基三甲基氯化铵(CTAC)相比,CTATS 表现出更高的表面活性、更低的发泡量、更高的泡沫稳定性、更高的缓蚀性能和油置换效率。结果表明,CTATS 作为一种表面活性剂在油气田中具有更好的性能。
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引用次数: 0
Investigation of a highly efficient foaming mixture compromising cationic Gemini-zwitterionic-anionic surfactants for gas well deliquification 研究用于气井脱胶的阳离子 Gemini-zwitterionic-anionic 表面活性剂高效发泡混合物
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-03-04 DOI: 10.1515/tsd-2023-2572
Weiwei Han, Hongmiao Lv, Jiabao Fan, Taotao Qiang, Chenwei Liu, Yue Ji, Sanbao Dong
Foamers with high resistance to condensate, salinity and high temperature play a crucial role in gas well deliquification. In this study, we developed an efficient foaming mixture containing a Gemini surfactant (CAGB), a betaine surfactant (CAPB) and sodium lauroyl glutamate (SLG), which exhibited excellent foaming performance (at a molar ratio of 3:3:4 and a dosage of 20 mmol L−1) with a foam volume of 440 mL and a half-life of 11 min. The optimized CAGB/CAPB/SLG mixture showed exceptional liquid unloading and foaming ability under high methanol (up to 40 vol.%) and condensate (up to 50 vol.%) content conditions. Trisodium aminotriacetate (NTA) facilitated the liquid unloading performance at a salinity of 90 g L−1. With 10 vol.% methanol, the liquid unloading rate of CAGB/CAPB/SLG foam at 90 °C could be increased to 90 %. Furthermore, surface tension and morphology analysis confirmed the presence of synergy within the CAGB/CAPB/SLG mixture in foaming, foam stabilizing and liquid unloading ability.
具有高抗凝结水、盐度和高温性能的发泡剂在气井脱液中发挥着至关重要的作用。在这项研究中,我们开发了一种含有双子表面活性剂(CAGB)、甜菜碱表面活性剂(CAPB)和月桂酰谷氨酸钠(SLG)的高效发泡混合物,该混合物表现出优异的发泡性能(摩尔比为 3:3:4,用量为 20 mmol L-1),泡沫体积为 440 mL,半衰期为 11 分钟。优化后的 CAGB/CAPB/SLG 混合物在甲醇(高达 40 Vol.%)和冷凝物(高达 50 Vol.%)含量较高的条件下显示出卓越的液体卸载和发泡能力。当盐度为 90 g L-1 时,氨基三乙酸钠(NTA)可促进液体卸载性能。在 10 Vol.% 甲醇的条件下,CAGB/CAPB/SLG 泡沫在 90 °C 下的液体卸载率可提高到 90%。此外,表面张力和形态分析证实了 CAGB/CAPB/SLG 混合物在发泡、泡沫稳定和液体卸载能力方面的协同作用。
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引用次数: 0
Biosurfactants as determinants of the quality anti-aging products 生物表面活性剂是优质抗衰老产品的决定因素
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-02-28 DOI: 10.1515/tsd-2023-2576
Dobrawa Kwaśniewska
Analysing the possibilities of obtaining biosurfactants and using waste materials as substrates for their production allows us to emphasize that biosurfactants are in line with the ideas of sustainable development and the protection of non-renewable resources. These ideas also apply to the engineering and technology of cosmetic products. For this reason, and because of the multi-functionality of biosurfactants, their role and widespread use in cosmetic formulations is likely to increase. Biosurfactants tend to have good surface properties. Their structural diversity results in differences in biological, antioxidant or biocidal activity. The paper presents the potential of biosurfactants that could be used in the composition of products dedicated to the fight against the problems of ageing skin. Particularly important in the skin ageing process is the fight against radicals and the prevention of collagen loss in the skin. The overall appearance of the skin also depends on the level of hydration and roughness. Biosurfactants also have an effect on the melanogenesis process, controlling hyperpigmentation. A relatively new approach to the fight against skin ageing emphasizes the role of the microbiome, and available research also points to the correlation of biosurfactants with maintaining the correct structure of the microbiome.
通过分析获得生物表面活性剂和使用废料作为生产基质的可能性,我们可以强调,生物表面活性剂符合可持续发展和保护不可再生资源的理念。这些理念也适用于化妆品的工程和技术。因此,由于生物表面活性剂的多功能性,其在化妆品配方中的作用和广泛使用可能会增加。生物表面活性剂往往具有良好的表面特性。其结构的多样性导致了生物、抗氧化或杀菌活性的差异。本文介绍了生物表面活性剂的潜力,这些活性剂可用于抗击皮肤老化问题的产品成分中。在皮肤老化过程中,对抗自由基和防止皮肤胶原蛋白流失尤为重要。皮肤的整体外观也取决于皮肤的水合程度和粗糙度。生物表面活性剂还能影响黑色素生成过程,控制色素沉着。对抗皮肤老化的一种相对较新的方法强调微生物群的作用,现有研究也表明生物表面活性剂与维持微生物群的正确结构有关。
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引用次数: 0
Optimization of kerosene/oleic acid/water mixture for emulsion formation 优化煤油/油酸/水混合物以形成乳状液
IF 1 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2024-02-24 DOI: 10.1515/tsd-2023-2577
Ahmed Yehia, Khaled Ezzat Yassien, Mohsen Farahat
The objective of the research was to investigate the influence of kerosene and oleic acid on emulsion formation. The two solutions were combined to form an emulsion by dispersing the kerosene solution into small droplets within the aqueous phase with the assistance of oleic acid. The surfactant reduced the interfacial tension between the two solutions, facilitating the emulsification process and stabilizing the droplets formed. A comprehensive understanding of the variables that control to the formation and stability of emulsions is essential for their effective development. For this purpose, the stability of oil-in-water emulsions was evaluated by measuring droplet size, turbidity, zeta potential, surface tension, and conductivity. Improved emulsion stability was correlated with smaller droplet size, increased turbidity, and reduced surface tension. The results of this research have significant potential for a variety of industrial applications.
研究的目的是调查煤油和油酸对乳液形成的影响。在油酸的帮助下,将煤油溶液分散成水相中的小液滴,从而将两种溶液混合形成乳液。表面活性剂降低了两种溶液之间的界面张力,促进了乳化过程并稳定了形成的液滴。全面了解控制乳液形成和稳定性的变量对于有效开发乳液至关重要。为此,我们通过测量液滴大小、浊度、zeta 电位、表面张力和电导率来评估水包油乳液的稳定性。乳液稳定性的提高与液滴尺寸变小、浊度增加和表面张力降低有关。这项研究成果在各种工业应用中具有巨大的潜力。
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引用次数: 0
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Tenside Surfactants Detergents
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