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Comprehensive review on performance, reliability, and roadmap of c-Si PV modules in desert climates: A proposal for improved testing standard 全面审查沙漠气候条件下晶体硅光伏组件的性能、可靠性和路线图:关于改进测试标准的建议
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-06-02 DOI: 10.1002/pip.3827
Baloji Adothu, Sagarika Kumar, Jim Joseph John, Gernot Oreski, Gerhard Mathiak, Bengt Jäckel, Vivian Alberts, Jabir Bin Jahangir, Muhammad Ashraful Alam, Ralph Gottschalg

Desert regions have emerged as ideal places for GW utility-scale photovoltaic (PV) module installations because of their ultra-large spaces, abundance of high-irradiance sunshine hours, and clear sky. However, the harsh desert climate presents challenges to the reliability and bankability of PV modules. This review provides an in-depth understanding of the unique desert parameters impact, desert-induced degradation modes, status, and required properties of the bill of materials (BOMs) and suggestions for the development of desert standards. The review reveals that the climatic conditions in the desert are considerably harsher than those in the moderate climate. The main degradation mechanisms caused by the desert are ultraviolet (UV)-induced discoloration, thermomechanical flaws of interconnects, and glass abrasion (because of soiling). The development of desert modules may necessitate the use of new-generation modules with low-temperature coefficients, high efficiency, high bifaciality, stability under UV light, and elevated temperatures. For the desert module application, options include advanced back sheets and encapsulants that are thermally and UV stable, free of acetic acid groups, and have a low water vapor transfer rate. The degradation modes induced by desert climate are not sufficiently addressed by the present environmental and safety standards through accelerated aging tests. As a result, this article provides a summary of current standards and recommends creating a new testing proposal called the “Hot Desert Test Cycle (HDTC)” sequence that is specific to the desert climate. This comprehensive review catalyzes the PV community to explore novel designs and develop desert PV modules while adhering to localized standards.

沙漠地区因其超大的空间、丰富的高辐照度日照时间和晴朗的天空而成为安装全球风能公用事业级光伏(PV)组件的理想之地。然而,恶劣的沙漠气候给光伏组件的可靠性和可储存性带来了挑战。本综述深入介绍了独特的沙漠参数影响、沙漠引起的降解模式、材料清单 (BOM) 的现状和所需属性,以及制定沙漠标准的建议。综述显示,沙漠的气候条件比温和气候条件恶劣得多。沙漠造成的主要降解机制是紫外线(UV)引起的褪色、互连器件的热机械缺陷和玻璃磨损(由于弄脏)。开发沙漠组件可能需要使用具有低温度系数、高效率、高双面性、紫外线照射下的稳定性和高温的新一代组件。在沙漠模块应用中,可供选择的材料包括热稳定性和紫外线稳定性高、不含乙酸基团、水蒸气转移率低的先进背板和封装材料。目前的环境和安全标准并未通过加速老化试验充分解决沙漠气候引起的降解模式。因此,本文对现行标准进行了总结,并建议针对沙漠气候制定新的测试方案,即 "热沙漠测试循环 (HDTC) "序列。这篇全面的综述有助于光伏界探索新颖的设计,并在遵守本地化标准的同时开发沙漠光伏组件。
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引用次数: 0
Impact of string connection and contact defects on electrical current distribution in solar cells and modules: A model validated by magnetic field imaging 电池串连接和接触缺陷对太阳能电池和组件中电流分布的影响:通过磁场成像验证的模型
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-05-28 DOI: 10.1002/pip.3806
Ammar Tummalieh, Max Mittag, Julian Weber, Damla Yucebas, Levin Schäfer, Rüdiger Quay, Christian Reichel, Holger Neuhaus

Modeling of solar modules and their components is essential to quantify geometrical, optical, and electrical losses and to improve the designs and technologies in terms of performance. In most loss analysis models, the current share among the busbars of the solar cell is assumed to be equal since a symmetrical distribution of the metallization is given. The impact of string terminal connection on the current distribution among the ribbons and the resulting changes in ohmic losses has not been studied yet. In this study, a MATLAB model is developed to consider the impact of the string connector terminal position on the current distribution and the ohmic losses in the ribbons and in string connector. The model allows for the analysis of the impact of contact defects scenarios in ribbons and string connectors on the current distribution. Results show that the highest current flows at the closest busbar to the string connector terminal while the current decreases at the busbars farther away from the terminal due to higher ohmic resistance of the current path. The higher the ohmic resistance of the string connector, the more inhomogeneous the current share at busbars. Simulating a 9 busbar M6 half-cell with 1 × 0.08 mm2 string connector, positioning the string connector terminal at the leftmost or rightmost ribbon results in 0.4 W less power compared to center connection configuration, where the string connector terminal is positioned at the center ribbon. Furthermore, simulation results show that inhomogeneity of current causes about 2.1% reduction in module power compared to the case of evenly distributed cell current, considering a 120-haf-cell module with the same string connector. Regarding contact defect analysis, exemplary simulations show the impact of the position of detached ribbons on the power or efficiency loss. Considering left or right connection configuration, detaching the leftmost or rightmost ribbon results in higher power loss compared to other ribbons. Detaching one cell ribbon completely from the string connector results in about 0.2%abs decrease in cell efficiency, while detaching the outer ribbon along all strings of a 120-half-cell module results in power loss of about 0.8%. The developed model is validated by performing magnetic field imaging (MFI) measurements, in which the magnetic flux density induced by the current carried by the ribbons is measured.

太阳能电池组件及其组件的建模对于量化几何、光学和电气损耗以及改进设计和技术性能至关重要。在大多数损耗分析模型中,太阳能电池汇流条之间的电流份额被假定为相等,因为金属化分布是对称的。目前还没有研究过电池串端子连接对电池带之间电流分布的影响以及由此产生的欧姆损耗变化。本研究开发了一个 MATLAB 模型,以考虑串连接器端子位置对色带和串连接器中电流分布和欧姆损耗的影响。通过该模型,可以分析色带和字符串连接器中的接触缺陷对电流分布的影响。结果显示,离串连接器端子最近的母线上的电流最大,而离端子较远的母线上的电流由于电流路径的欧姆电阻较高而减小。组串连接器的欧姆电阻越高,母线上的电流分担越不均匀。模拟带有 1 × 0.08 mm2 串联连接器的 9 母线 M6 半电池,将串联连接器端子置于最左或最右的色带上,与将串联连接器端子置于中心色带上的中心连接配置相比,功率减少了 0.4 W。此外,模拟结果表明,与电池电流均匀分布的情况相比,电流不均匀会导致模块功率降低约 2.1%。在接触缺陷分析方面,示例模拟显示了脱落电池带的位置对功率或效率损失的影响。考虑到左右连接配置,与其他电池带相比,分离最左边或最右边的电池带会导致更高的功率损耗。从电池串连接器上完全拆下一条电池带会导致电池效率降低约 0.2%abs,而拆下 120 个半电池模块所有电池串的外部电池带会导致功率损失约 0.8%。通过磁场成像(MFI)测量验证了所开发的模型,其中测量了电池带所携带的电流引起的磁通密度。
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引用次数: 0
Practical design of an optical filter for thermal management of photovoltaic modules 光伏组件热管理光学滤波器的实用设计
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-05-27 DOI: 10.1002/pip.3813
Juan Camilo Ortiz Lizcano, Ismail Kaaya, Hesan Ziar, Patricia Seoane da Silva, Yilong Zhou, Miro Zeman, Olindo Isabella

This work presents a practical approach to designing an optical filter for thermal management for photovoltaic modules. The approach emphasizes the practicality of manufacturing over optical performance. Simulation work demonstrates that, for an interdigitated back contact solar cell architecture, complete rejection of infrared radiation offers limited thermal benefits requiring highly complex optical filter designs. An alternative approach consists of reducing thermalization losses by providing reflectance at lower wavelength values. An optical filter design that fulfills this requirement is possible using simple structures based on two materials and taking advantage of the harmonics present in quarter wavelength optical thickness designs. The filter is later optimized for angular performance via second-order algorithms, resulting in a device consisting of only 15 thin-film layers. Performance simulations on two locations, Delft (the Netherlands) and Singapore, estimate a temperature reduction of 2.20°C and 2.45°C, respectively. In a single year, the optical loss produced by the filter is not compensated via temperature reduction. However, improvements in the annual degradation rate show that in Singapore, the overall effect of the filter on the lifetime DC energy yield is positive.

这项研究提出了一种实用的方法,用于设计光电模块热管理光学滤波器。该方法强调制造的实用性而非光学性能。模拟工作表明,对于相互咬合的背触式太阳能电池结构,完全阻隔红外辐射所带来的热效益有限,需要高度复杂的光学滤波器设计。另一种方法是通过提供较低波长值的反射率来减少热化损失。利用基于两种材料的简单结构,并利用四分之一波长光学厚度设计中存在的谐波,可以设计出满足这一要求的光学滤波器。随后,通过二阶算法对滤波器的角度性能进行了优化,从而使设备仅由 15 层薄膜组成。在荷兰代尔夫特和新加坡两地进行的性能模拟估计,温度分别降低了 2.20°C 和 2.45°C。在一年中,滤光器产生的光学损耗无法通过降温得到补偿。然而,年降解率的提高表明,在新加坡,滤光器对直流电能产量的总体影响是积极的。
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引用次数: 0
The dynamic of photovoltaic resources on its performance predictability, based on two new approaches 基于两种新方法的光伏资源对其性能可预测性的动态影响
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-05-21 DOI: 10.1002/pip.3801
Yhosvany Soler-Castillo, Manoj Sahni, Ernesto Leon-Castro

The manuscript is a digest, which puts forward findings from previous research papers, combined with new proposals. Approaches comprise two full models' derivation for photovoltaic (PV) systems energy conversion predictability. It brings in several models for key physical observables formulated as functions of the operating conditions. The proposals encompass mean spectral reflectance, coefficient for reflections and spatial geometry, incident angular losses factor, angular losses, and fill factor along with its coefficient of temperature. Applying the superposition principle, these models are integrated into two full approaches for performance predictability. The underlying physics description is mathematically consistent with experimental measurements of the physical observables involved, reported in other studies. To the authors' knowledge, these full models have been reported previously nowhere. Simulation results from the more inaccurate of two full models show good agreement of these findings with the experimental evidence, reported of its performance. The resulting key performance indicators (KPIs), after simulating a grid-connected PV system located in Cuba, yield 1.61%, 13.10%, −1.61%, 2.02%, and 0.81 of MAE, MAPE, MBE, RMSE, and R2, respectively, which they confirm the model's good behavior. Approaches formulations, as functions of solar irradiance and module temperature, its derivations, applications, and model's simulation results are considered the main manuscript novelties.

该手稿是一份文摘,提出了以前研究论文的结论,并结合了新的建议。方法包括两个完整的光伏(PV)系统能量转换可预测性模型推导。它引入了多个关键物理观测指标模型,并将其表述为运行条件的函数。这些建议包括平均光谱反射率、反射系数和空间几何系数、入射角损失系数、角损失、填充系数及其温度系数。应用叠加原理,这些模型被整合成两种完整的性能预测方法。基础物理学描述在数学上与其他研究报告中涉及的物理观测指标的实验测量结果一致。据作者所知,这些完整模型以前从未报道过。两个完整模型中较不精确的一个模型的模拟结果表明,这些结果与实验证据及其性能报告非常吻合。在模拟了位于古巴的并网光伏系统后,得出的关键性能指标(KPI)分别为 MAE、MAPE、MBE、RMSE 和 R2 的 1.61%、13.10%、-1.61%、2.02% 和 0.81,证实了模型的良好性能。作为太阳辐照度和组件温度函数的方法公式、其推导、应用和模型模拟结果被认为是手稿的主要创新点。
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引用次数: 0
Feasibility study on thin-film PV laminates for road integration 道路一体化薄膜光伏层压板可行性研究
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-05-17 DOI: 10.1002/pip.3814
Fallon Colberts, Aldo Kingma, Nicolás Héctor Carreño Gómez, Dorrit Roosen, Serdar Ahmad, Zeger Vroon

Integration of photovoltaics (PV) into the built environment (BIPV) and infrastructure (IIPV) is required to increase the installed capacity of PV worldwide, while still leaving sufficient area for other land uses. Although BIPV applications have proven to play a significant role in the energy transition, road integrated IIPV concepts are less developed and bring challenges in mechanical and electrical stability and safety that still need to be addressed. In this work, the feasibility of integrating thin-film CIGS (Copper Indium Gallium Selenide) modules into road tiles is investigated. PV road stacks were produced by gluing CIGS laminates onto concrete tiles and covering them with epoxy and glass granulates to form impact- and anti-skid layers. IV (current–voltage) characteristics show that, respectively, a thin and thick epoxy layer results in 2% and 6.6% relative loss in power conversion efficiency. Although a thin protective layer would be beneficial to the power conversion efficiency of road modules, raveling tests show increased risk for electrical failure when a thin top layer is used. Pull-off tests showed that the weakest adhesive strength (0.8 N/mm2) is between the thin-film laminate and concrete, offering sufficient adhesive strength to at least withstand light traffic loading. Raveling and wheel tracking tests show no mass loss and only minor deformation of the stack, respectively, indicating no real risk of raveling or rutting. Thermal cycling and damp heat exposure of the PV road tiles show that yellowing of the top layers can significantly reduce performance over longer periods of outdoor operation. Damp heat exposure after mechanical loading shows no indication of moisture ingress on any of the tested configurations, suggesting the proposed CIGS laminate stack is able to withstand light traffic loading. From the measurement results, it can be concluded that thin-film CIGS modules are mechanically and electrically suitable for road integration. Power conversion efficiencies over 12% can be attained with this technology, indicating its potential for renewable energy generation in road infrastructure. Performance stability can especially benefit from alternative top layer materials that maintain high transparency over long lifetimes. Additionally, pilot tests are required to demonstrate the potential of the technology in a controlled outdoor environment.

为了提高全球光伏发电的装机容量,同时为其他土地用途留出足够的面积,需要将光伏发电(PV)集成到建筑环境(BIPV)和基础设施(IIPV)中。尽管 BIPV 应用已被证明在能源转型中发挥了重要作用,但道路集成 IIPV 概念的开发程度较低,在机械、电气稳定性和安全性方面仍面临挑战,需要加以解决。在这项工作中,研究了将薄膜 CIGS(铜铟镓硒)模块集成到路面砖中的可行性。通过将 CIGS 层压板粘贴到混凝土路面砖上,并在其上覆盖环氧树脂和玻璃颗粒以形成抗冲击和防滑层,生产出了光伏路面砖。IV(电流-电压)特性表明,环氧树脂薄层和厚层分别会导致 2% 和 6.6% 的功率转换效率相对损失。虽然薄保护层有利于提高路面模块的功率转换效率,但蹂躏测试表明,使用薄表层会增加电气故障的风险。拉拔测试表明,薄膜层压板与混凝土之间的粘合强度最弱(0.8 牛/平方毫米),但其粘合强度足以至少承受轻微的交通负荷。碎裂和车轮跟踪测试分别表明,叠层没有质量损失,仅有轻微变形,表明没有真正的碎裂或车辙风险。光伏路面砖的热循环和湿热暴露表明,在较长时间的户外运行中,表层的黄化会大大降低其性能。机械加载后的湿热暴露表明,任何测试配置都没有湿气渗入的迹象,这表明所提议的 CIGS 层压材料堆栈能够承受轻微的交通负荷。从测量结果中可以得出结论,薄膜 CIGS 模块在机械和电气方面都适用于道路集成。该技术的功率转换效率超过 12%,表明其在道路基础设施可再生能源发电方面的潜力。性能稳定性尤其得益于可在较长寿命内保持高透明度的替代面层材料。此外,还需要进行试点测试,以证明该技术在受控室外环境中的潜力。
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引用次数: 0
Artificial ground reflector size and position effects on energy yield and economics of single-axis-tracked bifacial photovoltaics 人工地面反射器的尺寸和位置对单轴跟踪双面光伏发电系统的发电量和经济性的影响
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-05-07 DOI: 10.1002/pip.3811
Mandy R. Lewis, Silvana Ovaitt, Byron McDanold, Chris Deline, Karin Hinzer

Artificial ground reflectors improve bifacial energy yield by increasing both front and rear-incident irradiance. Studies have demonstrated an increase in energy yield due to the addition of artificial reflectors; however, they have not addressed the effect of varying reflector dimensions and placement on system performance and the impact of these parameters on the reflectors' financial viability. We studied the effect of high albedo (70% reflective) artificial reflectors on single-axis-tracked bifacial photovoltaic systems through ray-trace modeling and field measurements. In the field, we tested a range of reflector configurations by varying reflector size and placement and demonstrated that reflectors increased daily energy yield up to 6.2% relative to natural albedo for PERC modules. To confirm the accuracy of our model, we compared modeled and measured power and found a root mean square error (RMSE) of 5.4% on an hourly basis. We modeled a typical meteorological year in Golden, Colorado, to demonstrate the effects of artificial reflectors under a wide range of operating conditions. Seventy percent reflective material can increase total incident irradiance by 1.9%–8.6% and total energy yield by 0.9%–4.5% annually after clipping is considered with a DC–AC ratio of 1.2. Clipping has a significant effect on reflector impact and must be included when assessing reflector viability because it reduces reflector energy gain. We calculated a maximum viable cost for these improvements of up to $2.50–4.60/m2, including both material and installation, in Golden. We expanded our analysis to cover a latitude range of 32–48°N and demonstrated that higher-latitude installations with lower energy yield and higher diffuse irradiance content can support higher reflector costs. In both modeling and field tests, and for all locations, the ideal placement of the reflectors was found to be directly underneath the module due to the optimized rear irradiance increase.

人工地面反射器可通过增加前方和后方入射辐照度来提高双面能量产出。研究表明,增加人工反射器可提高发电量;但是,这些研究并未涉及不同反射器尺寸和位置对系统性能的影响,以及这些参数对反射器经济可行性的影响。我们通过光线跟踪建模和实地测量,研究了高反照率(70% 反射率)人工反射器对单轴跟踪双面光伏系统的影响。在现场,我们通过改变反射器的尺寸和位置测试了一系列反射器配置,结果表明,相对于 PERC 模块的自然反照率,反射器可将日发电量提高 6.2%。为了证实我们模型的准确性,我们比较了建模功率和测量功率,发现每小时的均方根误差 (RMSE) 为 5.4%。我们模拟了科罗拉多州戈尔登市的典型气象年,以展示人工反射器在各种运行条件下的效果。考虑到直流-交流比为 1.2 的削波因素后,70% 的反射材料每年可使总入射辐照度增加 1.9%-8.6%,总能量产出增加 0.9%-4.5%。削波对反射器的影响很大,在评估反射器的可行性时必须将其考虑在内,因为它会降低反射器的能量增益。在戈尔登,我们计算出这些改进措施的最大可行成本为 2.50-4.60 美元/平方米,包括材料和安装费用。我们将分析范围扩大到 32-48°N 的纬度范围,结果表明,纬度较高、能量收益较低、漫射辐照度含量较高的设施可以支持较高的反射器成本。在建模和实地测试以及所有地点的测试中,我们都发现,由于后部辐照度的优化增加,理想的反射器位置是在组件的正下方。
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引用次数: 0
Bifacial silicon heterojunction solar cells using transparent-conductive-oxide- and dopant-free electron-selective contacts 使用透明导电氧化物和无掺杂电子选择性接触的双面硅异质结太阳能电池
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-05-01 DOI: 10.1002/pip.3810
Anzhi Xie, Genshun Wang, Yiwei Sun, Haihuai Cai, Xiaoyun Su, Peibang Cao, Zheng Li, Zhexi Chen, Jian He, Pingqi Gao

The development of transparent electron-selective contacts for dopant-free carrier-selective crystalline silicon (c-Si) heterojunction (SHJ) solar cells plays an important role in achieving high short-circuit current density (JSC) and consequently high photoelectric conversion efficiencies (PCEs). This becomes even more important when focusing on the development of bifacial solar cells. In this study, bifacial SHJ solar cells using a transparent-conductive-oxide-free and dopant-free electron-selective passivating contacts are developed, showing a JSC bifaciality of up to 97%. Intrinsic ZnOX layer deposited by atomic layer deposition was used in this structure, which simultaneously provides negligible passivation loss after annealing and enables a low contact resistivity on the electron-selective contact. With both side finger metal electrodes contact, this bifacial solar cell shows an efficiency of 21.2% under front-side irradiation and 20.4% under rear-side irradiation, resulting in an estimated output power density of 24.1 mW/cm2 when considering rear-side irradiance of 0.15 sun.

为无掺杂载流子选择性晶体硅(c-Si)异质结(SHJ)太阳能电池开发透明电子选择性触点,对于实现高短路电流密度(JSC)以及由此产生的高光电转换效率(PCE)具有重要作用。在重点开发双面太阳能电池时,这一点变得更加重要。本研究开发了双面 SHJ 太阳能电池,采用了透明导电氧化物无掺杂电子选择性钝化触点,显示出高达 97% 的 JSC 双面性。在这种结构中使用了通过原子层沉积沉积的本征氧化锌层,退火后的钝化损失可以忽略不计,同时使电子选择性触点的接触电阻率很低。在两侧指状金属电极接触的情况下,这种双面太阳能电池在正面辐照下的效率为 21.2%,在背面辐照下的效率为 20.4%,当考虑到背面辐照度为 0.15 太阳时,估计输出功率密度为 24.1 mW/cm2。
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引用次数: 0
Towards a cutting-edge metallization process for silicon heterojunction solar cells with very low silver laydown 实现硅异质结太阳能电池的尖端金属化工艺,实现极低的银铺设量
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-04-28 DOI: 10.1002/pip.3808
Andreas Lorenz, Timo Wenzel, Sebastian Pingel, Milad Salimi Sabet, Marc Retzlaff, Florian Clement

Within this work, we investigate the potential to optimize the screen-printed front side metallization of silicon heterojunction (SHJ) solar cells. Three iterative experiments are conducted to evaluate the impact of the utilized fine mesh screen configurations and grid layout adaption (finger pitch) for the front side metallization on silver laydown and electrical performance of the solar cells. With respect to the screen configuration, we compare the performance of a fine-mesh knotless screen to a conventionally angled screen demonstrating an additional gain of Δη = +0.1%abs due to reduced shading losses. Additionally, a grid layout is improved by increasing the number of contact fingers from 120 to 156. Furthermore, the current possibility to push the fine-line printing process for low-temperature pastes to the limit is investigated by reducing the nominal finger width wn to 20, 18, and 15 μm. It is shown that even the smallest nominal width of wn = 15 μm can be printed with high quality, leading to an additional efficiency gain of Δη = +0.15%abs as well as a reduction of silver paste laydown by −5 mg. Finally, a batch of champion cells is fabricated by applying the findings of the previous experiments, which results in a maximum efficiency of ηmax = 23.2%. Compared to the reference group without optimization, this corresponds to a gain of Δη = +0.17%abs, which comes along with an additional decrease of the silver paste laydown by approximately −2 mg. This emphasizes the significance of consistent optimization of the screen-printing process in terms of cell performance and resource utilization for SHJ solar cells.

在这项工作中,我们研究了优化硅异质结(SHJ)太阳能电池正面金属化丝网印刷的潜力。我们进行了三项迭代实验,以评估正面金属化所使用的细网丝网配置和网格布局调整(指间距)对太阳能电池的银铺层和电气性能的影响。在滤网配置方面,我们比较了无结细目滤网和传统角度滤网的性能,结果表明,由于遮光损耗减少,额外增益为 Δη = +0.1%abs。此外,通过将触点从 120 个增加到 156 个,栅格布局也得到了改善。此外,通过将标称指宽 wn 减小到 20、18 和 15 μm,研究了目前将低温浆料细线印刷工艺推向极限的可能性。结果表明,即使是最小的标称宽度 wn = 15 μm 也能实现高质量印刷,从而额外提高效率 Δη = +0.15%abs,并减少银浆铺设量 -5 mg。最后,利用之前的实验结果制造了一批冠军电池,其最高效率为 ηmax = 23.2%。与未经优化的参照组相比,这相当于提高了 Δη = +0.17%abs,同时银浆铺设量也减少了约 -2 毫克。这强调了持续优化丝网印刷工艺对 SHJ 太阳能电池的电池性能和资源利用的重要意义。
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引用次数: 0
Interdigitated-back-contacted silicon heterojunction solar cells featuring novel MoOx-based contact stacks 采用基于氧化钼的新型接触叠层的互插背接触硅异质结太阳能电池
IF 8 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-04-25 DOI: 10.1002/pip.3812
Katarina Kovačević, Yifeng Zhao, Paul Procel, Liqi Cao, Luana Mazzarella, Olindo Isabella

The fabrication process of interdigitated-back-contacted silicon heterojunction (IBC-SHJ) solar cells has been significantly simplified with the development of the so-called tunnel-IBC architecture. This architecture utilizes a highly conductive (p)-type nanocrystalline silicon (nc-Si:H) layer deposited over the full substrate area comprising pre-patterned (n)-type nc-Si:H fingers. In this context, the (p)-type nc-Si:H layer is referred to as blanket layer. As both electrodes are connected to the same blanket layer, the high lateral conductivity of (p)nc-Si:H layer can potentially lead to relatively low shunt resistance in the device, thus limiting the performance of such solar cells. To overcome such limitation, we introduce a thin (<2 nm) full-area molybdenum oxide (MoOx) layer as an alternative to the (p)nc-Si:H blanket layer. We demonstrate that the use of such a thin MoOx minimizes the shunting losses thanks to its low lateral conductivity while preserving the simplified fabrication process. In this process, a novel (n)-type nc-Si:H/MoOx electron collection contact stack is implemented within the proposed solar cell architecture. We assess its transport mechanisms via electrical simulations showing that electron transport, unlike in the case of tunnel-IBC, occurs in the conduction band fully. Moreover, the proposed contact stack is evaluated in terms of contact resistivity and integrated into a proof-of-concept front/back-contacted (FBC) SHJ solar cells. Contact resistivity as low as 100 mΩcm2 is achieved, and fabricated FBC-SHJ solar cells obtain a fill factor above 81.5% and open-circuit voltage above 705 mV. Lastly, the IBC-SHJ solar cells featuring the MoOx blanket layer are fabricated, exhibiting efficiencies up to 21.14% with high shunt resistances above 150 kΩcm2. Further optimizations in terms of layer properties and fabrication process are proposed to improve device performance and realize the efficiency potential of our novel IBC-SHJ solar cell architecture.

随着所谓的隧道式 IBC 结构的开发,互插背接触硅异质结 (IBC-SHJ) 太阳能电池的制造工艺得到了显著简化。这种结构利用高导电性(p)型纳米晶硅(nc-Si:H)层沉积在由预图案化(n)型 nc-Si:H 手指组成的整个衬底区域上。在这种情况下,(p)型 nc-Si:H 层被称为空白层。由于两个电极都连接到同一层毯子层,(p)型 nc-Si:H 层的高横向导电性有可能导致器件中的分流电阻相对较低,从而限制了此类太阳能电池的性能。为了克服这种限制,我们引入了一层薄的(2 nm)全面积氧化钼(MoOx)层来替代(p)nc-Si:H 毯状层。我们证明,由于氧化钼的横向导电率较低,使用这种薄氧化钼可以最大限度地减少分流损耗,同时保留简化的制造工艺。在这一过程中,一个新颖的(n)型 nc-Si:H/MoOx 电子收集接触堆栈被应用于所提出的太阳能电池结构中。我们通过电学模拟对其传输机制进行了评估,结果表明,与隧道式 IBC 不同,电子传输完全发生在导带中。此外,我们还从接触电阻率的角度对所提出的接触堆进行了评估,并将其集成到概念验证的前/后接触(FBC)SHJ 太阳能电池中。接触电阻率低至 100 mΩcm2,制造出的 FBC-SHJ 太阳能电池的填充因子超过 81.5%,开路电压超过 705 mV。最后,制造出了具有氧化钼毯层的 IBC-SHJ 太阳能电池,其效率高达 21.14%,并联电阻超过 150 kΩcm2。我们还提出了进一步优化层特性和制造工艺的建议,以提高器件性能,实现新型 IBC-SHJ 太阳能电池结构的效率潜力。
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引用次数: 0
Photovoltaics literature survey (No. 191) 光伏文献调查(第 191 号)
IF 6.7 2区 材料科学 Q1 ENERGY & FUELS Pub Date : 2024-04-24 DOI: 10.1002/pip.3809
Ziv Hameiri
<p>To help readers stay up-to-date in the field, each issue of <i>Progress in Photovoltaics</i> contain a list of recently published journal articles that are most relevant to its aims and scope. This list is drawn from an extremely wide range of journals, including <i>IEEE Journal of Photovoltaics</i>, <i>Solar Energy Materials and Solar Cells</i>, <i>Renewable Energy</i>, <i>Renewable and Sustainable Energy Reviews</i>, <i>Journal of Applied Physics</i>, and <i>Applied Physics Letters</i>. To assist readers, the list is separated into broad categories, but please note that these classifications are by no means strict. Also note that inclusion in the list is not an endorsement of a paper's quality. If you have any suggestions please email Ziv Hameiri at <span>[email protected]</span>.</p><p>Basnet R, Yan D, Kang D, <i>et al</i>. <b>Current status and challenges for hole-selective poly-silicon based passivating contacts.</b> <i>Applied Physics Reviews</i> 2024; <b>11</b>(1): 011311.</p><p>Quirk J, Rothmann M, Li W, <i>et al</i>. <b>Grain boundaries in polycrystalline materials for energy applications: First principles modeling and electron microscopy.</b> <i>Applied Physics Reviews</i> 2024; <b>11</b>(1): 011308.</p><p>Brinkmann KO, Wang P, Lang FL, <i>et al</i>. <b>Perovskite-organic tandem solar cells.</b> <i>Nature Reviews Materials</i> 2024; <b>9</b>(3): 202-217.</p><p>Roose B, Dey K, Fitzsimmons MR, <i>et al</i>. <b>Electrochemical impedance spectroscopy of all-perovskite tandem solar cells.</b> <i>Acs Energy Letters</i> 2024; <b>9</b>(2): 442-453.</p><p>Kumar R, Puranik VE, Gupta R. <b>Application of electroluminescence imaging to distinguish ohmic and non ohmic shunting in inaccessible cells within a PV module.</b> <i>IEEE Journal of Photovoltaics</i> 2024; <b>14</b>(2): 296-304.</p><p>Mahadevan S, Liu T, Pratik SM, <i>et al</i>. <b>Assessing intra- and inter-molecular charge transfer excitations in non-fullerene acceptors using electroabsorption spectroscopy.</b> <i>Nature Communications</i> 2024; <b>15</b>(1): 2393.</p><p>Chojniak D, Steiner M, Reichmuth SK, <i>et al</i>. <b>Outdoor measurements of a full-size bifacial Pero/Si tandem module under different spectral conditions.</b> <i>Progress in Photovoltaics: Research and Applications</i> 2024; <b>32</b>(4): 219-231.</p><p>Ma F-J, Wang S, Yi C, <i>et al</i>. <b>A collaborative framework for unifying typical multidimensional solar cell simulations – Part I. Ten common simulation steps and representing variables.</b> <i>Progress in Photovoltaics: Research and Applications</i> 2024; <b>32</b>(5): 330-345.</p><p>Tahir S, Saeed R, Ashfaq A, <i>et al</i>. <b>Optical modeling and characterization of bifacial SiN</b><sub><b>x</b></sub><b>/AlO</b><sub><b>x</b></sub> <b>dielectric layers for surface passivation and antireflection in PERC.</b> <i>Progress in Photovoltaics: Research and Applications</i> 2024; <b>32</b>(2): 63-72.</p><p>Li B, Hansen CW, Chen X, <i>et al</i>. <b>A robust I–V curve co
Chen X, Zhao Y, Ahmad N, et al. 通过镧铕离子诱导的载流子寿命增强实现高效钾长石太阳能电池的高开路电压 2024; 124: 109448.Chauhan P, Agarwal S, Srivastava V, et al.Chauhan P, Agarwal S, Srivastava V, et al. Ag2S 和 In2Se3 缓冲层与 CuSbS2 背表面场层对 Cu2ZnSnS4 (CZTS) 太阳能电池发电和重组率的影响。光伏技术进展:2024;32(3):Debono A, L'Hostis H, Rebai A, et al.光伏技术进展:Photovoltaics: Research and Applications 2024; 32(3):Zhang C, Ji J, Wang C, et al. 不同气候区碲化镉光伏通风窗与真空玻璃一体化综合性能的年度分析与比较。Renewable Energy 2024; 223: 120029.Agrawal S, De Souza DO, Balasubramanian C, et al. Effect of secondary phases controlled by precursor composition on the efficiency of CZTS thin film solar cell.He Y, Zhao C, Lu Z, et al. Optimizing the window layer for achieving over 10% efficient Cu2ZnSn(S,Se)4 solar cells.太阳能材料与太阳能电池 2024; 269:Kwok CKG, Tangara H, Masuko N, et al.太阳能材料和太阳能电池,2024;269:Liu XL, Abbas A, Togay M, et al. 残余碲化镉层对碲化镉/碲化镉光伏器件性能的影响。Nishinaga J, Kamikawa Y, Sugaya T, et al. 多晶和外延 Cu(In, Ga)Se2 太阳能电池转换效率超过 21% 的比较。太阳能材料和太阳能电池 2024; 269:Phillips AB, Friedl JD, Subedi KK, et al.Tiede DO, Romero-Pérez C, Koch KA, et al.Acs Nano 2024; 18(3):Li C, Yao D, Dong P, et al.Ding XB, Wen X, Kawata Y, et al. In situ synergistic halogen passivation of semiconducting PbS quantum dot inks for efficient photovoltaics.Nanoscale 2024; 16(10):5115-5122.Li ZR, Wu HF, Wang RX.将过氧化物量子点太阳能电池用作光伏屋顶的现实意义和技术前景.太阳能 2024; 269:112359.Xiao G, Wang X, Liang T, et al. Improved charge separation by anatase TiO2 nanorod arrays for efficient solid-state PbS quantum-dot-sensitized solar cells.太阳能材料与太阳能电池,2024;269:Hu ZH, Gao Y, Ji SY, et al. 基于 LSTM 和天气预报数据自我关注的改进型多步超前光伏功率预测模型。Mercier TM, Sabet A, Rahman T. Vision transformer models to measure solar irradiance using sky images in temperate climates.Applied Energy 2024; 362: 122967.Mouhib E, Fernández-Solas A, Pérez-Higueras PJ, et al:在农业光伏系统中整合双面光伏和橄榄树。应用能源 2024; 359: 122660.Varo-Martínez M, Fernández-Ahumada LM, Ramírez-Faz JC, et al. Methodology for the estimation of cultivable space in photovoltaic installations with dual-axis trackers for their reconversion to agrivoltaic plants.Applied Energy 2024; 361: 122952.Vaziri Rad MA, Forootan Fard H, Khazanedari K, et al. A global framework for maximizing sustainable development indexes in agri-photovoltaic-based renewable systems:整合 DEMATEL、ANP 和 MCDM 方法。应用能源 2024》;360: 122715.Zhang K, Wang D, Chen M, et al. 中国 52 个主要城市光伏隔音屏障发电量评估。应用能源 2024; 361: 122839.Sun HJ, Fan SY, Cao SX, et al.边界灰尘对光伏板影响的定量建模与验证:片状单二极管方法。基于I-V曲线转换的光伏阵列快速仿真建模与多PS故障诊断。Ray B, Lasantha D, Beeravalli V, et al. A comprehensive framework for effective long-short term solar yield forecasting.能源转换与管理》:X 2024; 22: 100535.Elamim A, Sarikh S, Hartiti B, et al. 灰尘积累及其对地中海气候下太阳能光伏系统性能影响的实验研究。能源报告 2024; 11: 2346-2359。 Younis A, Rjafallah A, Cotfas PA, et al. 灰尘对光伏电热性能的影响:来自现场和实验室实验的启示。Nedaei A, Eskandari A, Milimonfared J, et al. Fault resistance estimation for line-line fault in photovoltaic arrays using regression-based dense neural network.De SB, Shiradkar N, Kottantharayil A. Improved cleaning event detection
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引用次数: 0
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Progress in Photovoltaics
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