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Application of Accurate Quantification Methods for Determining Emissions from the Acid Gas Removal Process in Natural Gas Processing 精确定量方法在测定天然气加工中酸性气体脱除过程排放中的应用
Pub Date : 2017-12-29 DOI: 10.7569/jnge.2017.692505
Qing Bian, D. Paradine, K. Wreford, Jennifer Eby, Y. Jamin, P. Sriram
Abstract This article presents new methods for accurately determining quantities of acid gas (CO2 and H2S) removed from acid gas removal (AGR) units in natural gas processing plants, and their applications to actual production data, with an emphasis on CO2 quantity determination. Greenhouse gas (GHG) emissions from anthropogenic activities contribute to climate change. The natural gas sector releases significant quantities of GHGs. AGR is a key step in natural gas processing, whereby H2S and CO2 are stripped from raw natural gas. Determining accurate CO2 emission quantities arising from AGR units has been challenging in the context of GHG emission quantification. The US Environmental Protection Agency and the Western Climate Initiative have each developed GHG quantification methods for petroleum and natural gas systems which include the AGR process. However, there is uncertainty about the accuracy of these approaches since not all aspects of the AGR process are taken into consideration. The proposed new methods for AGR GHG quantification are assessed using production data over three years from three natural gas plants. Assuming all other process factors are held constant, quantities of removed acid gas are functions of: •CO2 and H2S content in the inlet and outlet gas streams; and •the gas volume of either the inlet or outlet stream, depending on which quantification method is used. It is revealed that two main factors contribute to inaccurate GHG quantification from AGR units in practice so far: •the use of inlet gas stream volume instead of outlet gas stream volume; and, •failure to account for H2S content in the gas. In this study, inaccurately measured inlet gas stream volume was the primary cause of AGR CO2 quantification error and uncertainty. All calculation methods using inlet gas stream volume overestimated the CO2 quantity removed from an AGR unit by 3–11%. Quantification accuracy using volumes measured by inlet gas meters is limited because there is commonly a loss of gas volume from the inlet stream before it enters an AGR unit, and acid gas corrodes the metals in gas stream meters, which reduces meter accuracy. The H2S content of raw natural gas also has a significant impact on the accuracy of AGR CO2 removal quantification. Results show that methods using outlet gas stream volume without considering H2S content underestimate removed CO2 quantity by a factor of 1.1 times the H2S content in inlet gas stream. The error induced by this method linearly correlates to H2S content in the inlet gas stream. The higher the H2S content in the inlet stream, the larger the error. Calculation using outlet gas stream volume and H2S content in both inlet and outlet gas streams is recommended as a default method for quantifying GHG emissions from AGR units. Meanwhile, quantification methods for removed hydrogen sulfide (H2S) are also presented from the AGR process.
摘要本文介绍了准确测定天然气加工厂酸性气体脱除装置(AGR)中酸性气体(CO2和H2S)脱除量的新方法及其在实际生产数据中的应用,重点介绍了二氧化碳(CO2)量的测定。人为活动产生的温室气体(GHG)排放加剧了气候变化。天然气行业排放了大量的温室气体。AGR是天然气加工的关键步骤,即从原料天然气中剥离H2S和CO2。在温室气体排放量化的背景下,准确确定AGR装置产生的二氧化碳排放量一直是一项挑战。美国环境保护署和西部气候倡议各自开发了包括AGR过程在内的石油和天然气系统的温室气体量化方法。然而,由于没有考虑到AGR过程的所有方面,这些方法的准确性存在不确定性。利用三家天然气厂三年的生产数据,对提出的AGR温室气体量化新方法进行了评估。假设所有其他工艺因素保持不变,去除酸性气体的数量是:•进出口气流中CO2和H2S含量的函数;以及•进口或出口流的气体体积,取决于使用哪种量化方法。结果表明,迄今为止,两个主要因素导致AGR装置的温室气体定量不准确:•使用进口气流体积而不是出口气流体积;•未能考虑到气体中H2S的含量。在本研究中,进口气流体积测量不准确是导致AGR CO2定量误差和不确定性的主要原因。所有使用进口气流体积的计算方法都高估了AGR装置去除的二氧化碳量3-11%。由于进口气流在进入AGR装置之前通常会有气体体积的损失,并且酸性气体会腐蚀气流仪表中的金属,从而降低了仪表的精度,因此使用进口气体仪表测量体积的量化精度受到限制。原料天然气中H2S含量对AGR CO2去除率定量的准确性也有显著影响。结果表明,使用出口气流体积而不考虑H2S含量的方法低估了进口气流中H2S含量的1.1倍的CO2去除量。该方法引起的误差与进口气流中H2S含量呈线性相关。进口流中H2S含量越高,误差越大。建议使用出口气流体积和进出口气流中H2S含量作为量化AGR装置温室气体排放的默认方法。同时,提出了AGR过程中硫化氢(H2S)脱除的定量方法。
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引用次数: 0
Semi Analytical Model for Predicting Screen-out in Hydraulic Fracturing in Vertical Wells 直井水力压裂筛出预测的半解析模型
Pub Date : 2017-06-21 DOI: 10.7569/jnge.2016.692508
Xiao Cai, B. Guo
Abstract The use of hydraulic fracturing has been greatly increased in the petroleum industry over the past few decades. However, the issue of screen-out has remained since proppants were first used in hydraulic fracturing. Due to the serious consequences caused by the screen-out, it is desirable to avoid or delay it where possible in the implementation process of hydraulic fracturing. This paper provides a mathematical method for estimating the screen-out time during hydraulic fracturing in vertical wells. The model result is consistent with field observations. Sensitivity analyses in this paper show that the viscosity of the fracturing fluid, proppant density, injection rate and ratio of proppant volume to fracturing fluid volume significantly affect the screen-out time and characteristics of the proppant pile. This model can be used as a general tool for optimizing fracturing parameters in vertical wells in order to minimize the screen-out effect.
在过去的几十年里,水力压裂在石油工业中的应用大大增加。然而,自支撑剂首次用于水力压裂以来,筛出问题一直存在。由于筛出造成的严重后果,在水力压裂实施过程中尽量避免或延缓筛出。提出了一种估算直井水力压裂筛出时间的数学方法。模型结果与现场观测结果吻合较好。敏感性分析表明,压裂液粘度、支撑剂密度、注入速度、支撑剂体积与压裂液体积之比对支撑剂桩的筛出时间和特性有显著影响。该模型可作为优化直井压裂参数的通用工具,以最大限度地减少筛出效应。
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引用次数: 0
Gas Hydrates Phase Equilibrium with CaBr2 and CaBr2 + MEG at Ultra-High Pressures 超高压下CaBr2和CaBr2 + MEG天然气水合物相平衡研究
Pub Date : 2017-06-21 DOI: 10.7569/jnge.2017.692502
Yue Hu, T. Makogon, P. Karanjkar, Kun-Hong Lee, B. Lee, A. Sum
Abstract We report methane (structure I) and methane/ethane (structure II) hydrate phase equilibrium data with calcium bromide (32 wt%) and a mixture of calcium bromide (20 wt%) + monoethylene glycol (20 wt%) solutions for pressures up to 200 MPa. As expected for thermodynamic hydrate inhibitors, the salt and glycol cause the hydrate phase equilibrium boundary to shift to lower temperatures and higher pressures. These data are the first to be reported for these systems, which are particularly useful as calcium bromide is widely used in drilling fluids and hydrate formation is a growing concern in well completion and workover fluids. The measured experimental data were compared with commonly used hydrate prediction tools to assess their reliability.
我们报告了甲烷(结构I)和甲烷/乙烷(结构II)水合物与溴化钙(32 wt%)和溴化钙(20 wt%) +单乙二醇(20 wt%)溶液的混合物在压力高达200 MPa下的相平衡数据。正如热力学水合物抑制剂所期望的那样,盐和乙二醇导致水合物相平衡边界向较低温度和较高压力转移。这些数据是首次报道这些系统的数据,这些系统特别有用,因为溴化钙广泛应用于钻井液中,水合物地层在完井和修井液中越来越受关注。将实测实验数据与常用水合物预测工具进行了比较,以评估其可靠性。
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引用次数: 13
Flow Impairment by Deposited Sulfur - A Review of 50 Years of Research 沉积硫对流动的损害——50年研究综述
Pub Date : 2017-06-21 DOI: 10.7569/jnge.2017.692504
B. E. Roberts
Abstract Sulfur deposition in the reservoir formation and its impact on well productivity and ultimate recovery has been investigated for close to 50 years. Experimental measurements and numerical modeling studies have focused on the phase behavior of the sulfur-sour gas mixture system and the flow of sulfur and natural gas through the formation. The key results from these investigations are reviewed in this paper. The implementation of the insights gained over these 50 years of research into the field development planning and operation of sour gas fields is described.
近50年来,人们一直在研究储层中的硫沉积及其对油井产能和最终采收率的影响。实验测量和数值模拟研究的重点是硫-酸气体混合系统的相行为以及硫和天然气在地层中的流动。本文对这些研究的主要结果进行了综述。本文描述了在过去50年的研究中获得的见解在油田开发规划和酸性气田运营中的应用。
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引用次数: 7
Modeling of Transient Pressure Response for CO2 Flooding Process by Integrating Convection and Diffusion Driven Mass Transfer 基于对流和扩散传质积分的CO2驱油过程瞬态压力响应建模
Pub Date : 2017-06-21 DOI: 10.7569/jnge.2017.692501
Jianli Li, Gang Zhao
Abstract Traditional well test models for CO2 flooding neglect dynamic mass transfer and over-simplify transient viscosity in a transition zone, making them unable to deal with more complicated and heterogeneous field situations. To eliminate this restriction/limitation, this study proposes a comprehensive transient pressure model that incorporates a convection– diffusion mass transfer process. It actually is an enhanced three-region composite model that includes CO2 bank, transition zone, and oil zone. Type curves are plotted and four flow regimes are identified: early radial flow, transition flow, pseudo-radial flow, and boundary-dominated flow. In addition, it is found that mass transfer mainly leads the transition flow regime to slower slope change, and pseudo radial flow regime with lower straight line compared with a case neglects the mass transfer in a transition zone. Moreover, it shows that a smaller injection rate and a longer injection period are better for viscosity reduction than a larger injection rate and a shorter injection period.
传统的CO2驱试井模型忽略了动态传质,过于简化了过渡层的瞬态粘度,无法处理更复杂、非均质油田的情况。为了消除这一限制,本研究提出了一个包含对流-扩散传质过程的综合瞬态压力模型。它实际上是一个包括CO2库、过渡带和油区在内的增强型三区复合模型。绘制了类型曲线,并确定了四种流动形式:早期径向流动、过渡流动、伪径向流动和边界主导流动。此外,还发现传质主要导致过渡流型的斜率变化较慢,而直线较低的伪径向流型忽略了过渡区的传质。此外,较小的喷射速度和较长的喷射周期比较大的喷射速度和较短的喷射周期对降粘效果更好。
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引用次数: 1
Vitrisol® a 100% selective process for H2S removal in the presence of CO2 Vitrisol®是一种在CO2存在下100%选择性去除H2S的工艺
Pub Date : 2017-05-06 DOI: 10.7569/jnge.2017.692503
W. Wermink, N. Ramachandran, G. Versteeg
Abstract Vitrisol®, a novel desulphurization process that is 100% selective for H2S removal from industrial gases containing CO2, can be described with the following overall reaction equation: H2S+0.5O2→H2O+SO(s) $${H_2}S + 0.5{O_2} to {H_2}O + {S^O}(s)$$ The performance of Vitrisol® is demonstrated for two typical applications in shale gas production by comparing them to a standard amine treating process. The remainder toxic, acid gas produced by the latter technology is compressed for acid gas injection. From the results it can be concluded that significant reductions in utilities can be achieved by using Vitrisol® as depicted in the energy consumptions of the overall process. Contrary to the amine process, Vitrisol® does not require additional treatment of the non-toxic off-gas stream as the H2S is directly converted to crystalline sulphur. This study illustrates clearly that it is advantageous to first remove H2S from a gas stream containing both H2S and CO2 prior to CO2 removal to reduce utilities consumption.
Vitrisol®是一种新型的脱硫工艺% selective for H2S removal from industrial gases containing CO2, can be described with the following overall reaction equation: H2S+0.5O2→H2O+SO(s) $${H_2}S + 0.5{O_2} to {H_2}O + {S^O}(s)$$ The performance of Vitrisol® is demonstrated for two typical applications in shale gas production by comparing them to a standard amine treating process. The remainder toxic, acid gas produced by the latter technology is compressed for acid gas injection. From the results it can be concluded that significant reductions in utilities can be achieved by using Vitrisol® as depicted in the energy consumptions of the overall process. Contrary to the amine process, Vitrisol® does not require additional treatment of the non-toxic off-gas stream as the H2S is directly converted to crystalline sulphur. This study illustrates clearly that it is advantageous to first remove H2S from a gas stream containing both H2S and CO2 prior to CO2 removal to reduce utilities consumption.
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引用次数: 3
Methane Number 甲烷的数量
Pub Date : 2017-01-01 DOI: 10.7569/jnge.2017.692506
G. Palmer
The Methane Number is a measure of the resistance of natural gas to detonation when it is burned as a motor fuel in an engine. Pure Methane is assigned a Methane Number of 100 and pure Hydrogen is assigned a Methane Number of zero. A natural gas having a Methane Number of 80 for example, would have the detonation properties of a mixture consisting of 80 vol% Methane and 20 vol% Hydrogen. The Methane Number concept is similar to the Octane Number for gasoline. Unlike gasoline however, there is not yet a universal standard for testing natural gas Methane Number as there is in the motor test for gasoline. Also, there is no universally accepted method for calculating the Methane Number based on the composition of natural gas.
甲烷数是衡量天然气在发动机中作为发动机燃料燃烧时对爆炸的抵抗力。纯甲烷的甲烷编号为100,纯氢的甲烷编号为0。例如,一种甲烷数为80的天然气,其爆炸特性相当于由80%的甲烷和20%的氢气组成的混合物。甲烷值的概念类似于汽油的辛烷值。然而,与汽油不同的是,天然气甲烷含量的测试还没有一个通用的标准,就像汽油的发动机测试一样。此外,目前还没有普遍接受的基于天然气成分计算甲烷数量的方法。
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引用次数: 4
Helium in Natural Gas - Occurrence and Production 天然气中的氦-赋存与生产
Pub Date : 2016-12-28 DOI: 10.7569/jnge.2016.692506
Eugene W. Grynia, P. J. Griffin
Abstract Helium is produced from natural gas by treatment of vent gas from Nitrogen Rejection Units or LNG plants. There are 16 liquid helium plants in the world, 7 of which are outside of the United States. There are at least six industrial (specialty) gas companies in the world that have direct access to sources of helium: Air Liquide, Air Products, Linde, Matheson, Messer and Praxair. Conventional helium plants use cryogenic distillation to produce crude helium followed by PSA to purify it for liquefaction. There was a period of helium shortage in 2011–2014 which caused more efficient use of helium and helium recycling. The world is now experiencing a period of too much supply of helium, and new helium plants will come online in Qatar and Russia in 2018 and beyond. The global helium demand in 2016 is estimated at 5.9 Bcf, and the supply is around 6.0 Bcf. Helium plays an important role in modern industry and medicine. There are many applications for helium, but the single largest application is in MRI (Magnetic Resonance Imaging), which accounts for around 30% of all helium usage.
摘要氦气是由天然气通过处理排氮装置或液化天然气厂的排气产生的。世界上有16个液氦工厂,其中7个在美国以外。世界上至少有六家工业(特种)气体公司可以直接获得氦气的来源:液化空气集团、空气产品公司、林德、Matheson、梅塞尔和普莱克斯。传统的氦气厂采用深冷蒸馏生产粗氦,然后用PSA对其进行净化液化。2011-2014年有一段时间的氦气短缺,这使得氦气的利用和氦气的回收效率提高。世界正在经历一个氦气供应过剩的时期,新的氦气工厂将于2018年及以后在卡塔尔和俄罗斯投产。2016年全球氦气需求估计为59亿立方英尺,供应量约为60亿立方英尺。氦在现代工业和医学中起着重要作用。氦有很多应用,但最大的应用是MRI(磁共振成像),它占所有氦使用量的30%左右。
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引用次数: 19
The Management System Based on the Dynamic Online Simulation for the CBM Gathering Pipeline System of Northern Fanzhuang 范庄北部煤层气集输管道动态在线仿真管理系统
Pub Date : 2016-12-28 DOI: 10.7569/jnge.2016.692505
Shouxi Wang, Jian Guo, Tingting Zhang, Y. Mei, Jia Wang
Abstract The coal bed methane (CBM) gathering pipeline system of Northern Fanzhuang is in Shanxi province of The People’s Republic of China, near the city of Jincheng. Its features include: low pressure, small throughputs, congestion of the landscape, and undulating terrain. As a result, the management and analysis of the system is very difficult because of the complex structure and the sensitivity to the pressure and to the flow. In response to these problems, a management system was developed using the Pipeline Simulation Network (PNS) pipeline simulation software, integrated with the geographic information system (GIS) and supervisory control and data acquisition (SCADA) system of the CBM gathering system. The management system can automatically generate the required simulation model for the selected systems, pipelines and stations from the GIS geometric information and database. It can perform online simulation with real time data from the SCADA for a quick, direct and precise evaluation of the pipeline system. All the simulation results are stored in the SQL database for history review, and are also sent to the GIS system. According to the simulation results, the status and the flow of the gathering pipeline system are visualized in GIS three-dimensional mode for a quick overall acknowledgement. In addition, more detailed information about the past and current data for each individual component in the gathering system can be searched, sorted and shown in GIS whenever required. The theory and methods for building the management system are discussed in this paper, including the architecture, the simulation model, the self-training of the model, the interaction between the PNS simulation and GIS system, and the three-dimensional search and visualization of the flow status in GIS. Finally, an example was presented to demonstrate the application using better management and regulation of the CBM gathering pipeline system.
范庄北部煤层气集输管道系统位于中华人民共和国山西省晋城市附近。它的特点是:气压低,吞吐量小,景观拥挤,地形起伏。由于系统结构复杂,对压力和流量的敏感性,给系统的管理和分析带来了很大的困难。针对这些问题,利用管道仿真网络(PNS)管道仿真软件,结合煤层气采集系统的地理信息系统(GIS)和监控与数据采集(SCADA)系统,开发了一个管理系统。该管理系统可以根据GIS的几何信息和数据库自动生成所选系统、管道和站的所需仿真模型。它可以利用SCADA提供的实时数据进行在线仿真,从而对管道系统进行快速、直接和精确的评估。所有的仿真结果存储在SQL数据库中进行历史回顾,并发送到GIS系统。根据仿真结果,采用GIS三维模式对集输管道系统的状态和流量进行可视化,以便快速全面确认。此外,收集系统中每个单独组件的过去和当前数据的更详细信息可以随时在GIS中搜索、排序和显示。本文讨论了建立管理系统的理论和方法,包括体系结构、仿真模型、模型的自训练、PNS仿真与GIS系统的交互以及GIS中流态的三维搜索和可视化。最后,通过实例说明了该方法在煤层气集输管道系统管理和调控中的应用。
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引用次数: 0
Research on the New Method of Determining Subsurface Porosity of Unconsolidated Cores 测定松散岩心地下孔隙度新方法研究
Pub Date : 2016-12-28 DOI: 10.7569/jnge.2016.692503
G. Ping, Yuan Zhiwang, Wang Zhouhua, Y. Yiyi
Abstract In this paper, we have derived the transformational relationship between the porosity under triaxial, biaxial stress and uniaxial stress respectively. Moreover, porosity tests under biaxial and triaxial stress for 11 groups of parallel unconsolidated core samples are conducted. Based on the transformational relationship, we have converted the tested porosity under triaxial stress into the porosity under biaxial stress and then compared it with the tested porosity under biaxial stress. The results indicate that the theoretical porosity model is reliable and deformation of unconsolidated cores is approximate elastic deformation of the rock body. Therefore, the porosity under uniaxial stress can be converted from the porosity under biaxial stress, which can simplify the experimental procedure and equipment, and provide a new way of determining subsurface porosity of unconsolidated cores. Besides, the Poisson’s ratio of unconsolidated cores is much larger than that of the normal clastic rock, and the actual conversion factor should be used for the conversion.
摘要本文分别推导了三轴、双轴和单轴应力作用下孔隙度的转换关系。并对11组平行松散岩心进行了双轴和三轴应力下的孔隙度测试。根据转换关系,将三轴应力下的孔隙度测试值转换为双轴应力下的孔隙度测试值,并与双轴应力下的孔隙度测试值进行对比。结果表明,理论孔隙度模型是可靠的,松散岩心的变形近似于岩体的弹性变形。因此,单轴应力作用下的孔隙度可以由双轴应力作用下的孔隙度转换而来,简化了实验程序和设备,为确定松散岩心的地下孔隙度提供了一种新的方法。另外,松散岩心的泊松比远大于正常碎屑岩的泊松比,应采用实际换算系数进行换算。
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引用次数: 0
期刊
The Journal of Natural Gas Engineering
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