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WR21 marine gas turbine thermodynamic simulator for ship propulsion studies 用于船舶推进研究的 WR21 船用燃气轮机热力学模拟器
Pub Date : 2024-03-30 DOI: 10.53294/ijfetr.2024.6.1.0023
U. Campora
An original modular mathematical model, based on physical laws, for steady state and dynamics performance simulation of the WR21 gas turbine is presented in the paper. The model, developed in Matlab-Simulink language, is organized in modular form. Each gas turbine component (i.e. compressor, turbine, combustor, heat exchanger) is modelled in a specific simulator block, that simulates the performance of its pertinent component by means of steady state performance maps and/or correlations, time dependent momentum, energy and mass equations, nonlinear algebraic equations. The great application flexibility of the component simulator modules, allows to modelling any gas turbine layout (i.e. axial or radial flow compressor and turbine, rotating shafts number, heat exchangers). The WR21gas turbine, developed mainly for marine propulsion application, is a three shafts gas turbine with thermal regeneration. It is characterized by a high thermodynamic efficiency, which remains high up to 30% of the design power. The WR21 simulator results are validated by comparison with manufacturer or literature data. The WR21 gas turbine main performances are compared to those of the LM 2500 gas turbine, obtained by a previously author paper. The LM 2500 is the gas turbine currently most used in naval propulsion plants. In the article, a comparison between the steady state working data of the two gas turbines is reported in tabular and graphical form and commented.
本文介绍了一个基于物理定律的原创模块化数学模型,用于 WR21 燃气轮机的稳态和动态性能仿真。该模型采用 Matlab-Simulink 语言开发,以模块化形式组织。每个燃气轮机组件(即压缩机、涡轮机、燃烧器、热交换器)都在一个特定的模拟器模块中建模,该模块通过稳态性能图和/或相关性、与时间相关的动量、能量和质量方程以及非线性代数方程来模拟相关组件的性能。组件模拟器模块具有极大的应用灵活性,可对任何燃气轮机布局(即轴向或径向流压缩机和涡轮机、旋转轴数、热交换器)进行建模。WR21 燃气轮机主要为船舶推进应用而开发,是一种带热再生功能的三轴燃气轮机。它的特点是热动力效率高,在设计功率的 30% 以下仍保持很高的效率。WR21 模拟器的结果通过与制造商或文献数据的比较进行了验证。WR21 燃气轮机的主要性能与 LM 2500 燃气轮机的性能进行了比较,LM 2500 燃气轮机的性能是由作者之前的一篇论文获得的。LM 2500 是目前海军推进装置中使用最多的燃气轮机。文章以表格和图表的形式对两台燃气轮机的稳态工作数据进行了比较,并给出了评论。
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引用次数: 0
Predictive maintenance in oil and gas facilities, leveraging ai for asset integrity management 石油和天然气设施的预测性维护,利用 AI 进行资产完整性管理
Pub Date : 2024-03-30 DOI: 10.53294/ijfetr.2024.6.1.0026
Chuka Anthony Arinze, Izionworu, Vincent Onuegbu, Daniel Isong, Cosmas Dominic Daudu, Adedayo Adefemi
This paper explores the application of AI in predictive maintenance within oil and gas facilities, discussing its benefits, challenges, and future prospects. Through the integration of AI-driven analytics and real-time data monitoring, oil and gas companies can enhance their asset integrity management practices, ultimately driving cost savings and operational excellence. Predictive maintenance has become indispensable in the oil and gas industry, serving as a pivotal strategy to uphold operational efficiency and preserve asset integrity. This paper delves into the profound impact of artificial intelligence (AI) technologies on predictive maintenance, ushering in a new era of proactive equipment management. By harnessing AI capabilities, oil and gas companies can preempt equipment failures, curtail downtime, and refine maintenance protocols, thereby optimizing overall operational performance. The integration of AI in predictive maintenance marks a paradigm shift, offering a proactive approach to asset management. Leveraging AI-driven analytics and real-time data monitoring, oil and gas facilities can fortify their asset integrity management practices. Through predictive algorithms and machine learning models, these technologies empower companies to forecast equipment malfunctions with unprecedented accuracy, allowing for timely interventions and mitigating potential risks the benefits of AI-powered predictive maintenance in the oil and gas sector are multifaceted the future of predictive maintenance in the oil and gas industry is brimming with promise. As AI technologies continue to evolve, we can anticipate further advancements in predictive analytics, fault detection, and decision support systems. By embracing innovation and collaboration, oil and gas companies can harness the full potential of AI-driven predictive maintenance, cementing their position as industry leaders in asset management and operational efficiency.
本文探讨了人工智能在油气设施预测性维护中的应用,讨论了其优势、挑战和未来前景。通过整合人工智能驱动的分析和实时数据监控,石油和天然气公司可以加强其资产完整性管理实践,最终实现成本节约和卓越运营。预测性维护已成为石油和天然气行业不可或缺的一项重要战略,可提高运营效率,维护资产完整性。本文将深入探讨人工智能(AI)技术对预测性维护的深远影响,从而开创一个积极主动的设备管理新时代。通过利用人工智能功能,石油和天然气公司可以预防设备故障、减少停机时间并完善维护协议,从而优化整体运营绩效。人工智能与预测性维护的整合标志着一种模式的转变,为资产管理提供了一种积极主动的方法。利用人工智能驱动的分析和实时数据监控,石油和天然气设施可以强化其资产完整性管理实践。通过预测算法和机器学习模型,这些技术使公司能够以前所未有的准确度预测设备故障,从而及时进行干预并降低潜在风险。随着人工智能技术的不断发展,我们可以预见在预测分析、故障检测和决策支持系统方面将取得进一步的进步。通过创新与合作,石油天然气公司可以充分利用人工智能驱动的预测性维护的潜力,巩固其在资产管理和运营效率方面的行业领导者地位。
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引用次数: 0
Theoretical perspectives on predictive analytics in it service management: Enhancing service quality IT 服务管理中预测分析的理论视角:提高服务质量
Pub Date : 2024-03-30 DOI: 10.53294/ijfetr.2024.6.1.0028
Babajide Tolulope Familoni
This paper explores the theoretical perspectives underpinning the application of predictive analytics in IT service management (ITSM) to enhance service quality. It begins with an introduction to predictive analytics in the context of ITSM and the significance of improving service quality in IT operations. Theoretical frameworks such as Systems Theory, Information Theory, Decision Theory, and Machine Learning Theory are discussed to provide a comprehensive understanding of the underlying principles guiding predictive analytics in ITSM. The paper examines the practical applications, challenges, and benefits of predictive analytics in ITSM, emphasizing its role in anticipatory problem resolution, proactive service improvements, and predictive maintenance. Case studies and examples of successful implementations are presented to illustrate real-world applications and best practices. Additionally, future directions and emerging trends in predictive analytics technology are explored, along with their potential impact on ITSM practices and ethical considerations. Overall, this paper contributes to the theoretical foundation and practical insights for leveraging predictive analytics to enhance service quality in ITSM.
本文探讨了在信息技术服务管理(ITSM)中应用预测分析技术以提高服务质量的理论基础。本文首先介绍了 ITSM 背景下的预测分析以及提高 IT 运营服务质量的意义。本文讨论了系统理论、信息理论、决策理论和机器学习理论等理论框架,以全面了解指导 ITSM 中预测分析的基本原则。论文探讨了预测分析在 ITSM 中的实际应用、挑战和优势,强调了它在预测性问题解决、主动服务改进和预测性维护中的作用。本文介绍了成功实施的案例研究和实例,以说明现实世界中的应用和最佳实践。此外,还探讨了预测分析技术的未来发展方向和新兴趋势,以及它们对 ITSM 实践和道德考量的潜在影响。总之,本文有助于为利用预测分析技术提高 ITSM 服务质量奠定理论基础和提供实践见解。
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引用次数: 0
A Proposal for method of cold nuclear fusion, based on new Axioms and Laws 基于新公理和定律的冷核聚变方法提案
Pub Date : 2024-03-30 DOI: 10.53294/ijfetr.2024.6.1.0027
Valentina Markova
It is known that the Classical field theory is based on 1 basic Axiom set by Maxwell (1864). This basic Axiom describes a field with movement along a closed loop and with constant speed. It is an ideal foundation for describing an Electromagnetic Field, but it is not suitable for other more complex fields with variable speed and different accelerations. The author has proposed a more general Theory of Extended Field which consists of 2 Axioms and 8 Laws. New Axiom1 describes a structure of field with movement along open loop or open vortex with variable speed. New Axiom2 describes two mutual orthogonal structures of fields which work in resonance. This new Theory leads to the following results: movement in a closed loop is replaced with movement in an open loop or vortex; evenly movement is replaced with unevenly movement (decelerated or accelerated) ; during its movement decelerating vortex emits primary free cross vortices, while accelerating vortices suck in of this same primary free cross vortices; movement in 2D is transformed into the movement in 3D; a transverse vortex in 2D generates a longitudinal vortex in 3D through a special transformation and vice versa - a longitudinal vortex in 3D through another special transformation generates the cross vortex in 2D. Now the author proposes to use a longitudinal accelerating vortex for cold fusion. With a force proportional to the positive acceleration, it will suck in both vortices and atoms - in this case the isotope of hydrogen (deuterium). The accelerator vortex sucks in and sticks two of all the deuterium, which will form helium in an exothermic reaction with the release of a lot of heat. A longitudinal acceleration vortex can be generated by applying Law 2. A decelerating transverse vortex in plane 2D (moving outside-inward) generates at its center a longitudinal accelerating vortex in 3D perpendicular to the 2D plane. This perpendicular accelerating vortex at the center pulls the transverse decelerating vortex up (against the Gravitational Force) or has quality of Anti-Gravity Force.
众所周知,经典场论基于麦克斯韦(1864 年)提出的一个基本公理。这个基本公理描述的是沿闭合环路运动且速度恒定的场。它是描述电磁场的理想基础,但并不适用于其他具有变速和不同加速度的更复杂场。作者提出了一种由 2 条公理和 8 条定律组成的更通用的扩展场理论。新公理 1 描述了一种沿开环或开涡运动、速度可变的场结构。新公理 2 描述了两个相互正交的共振场结构。这一新理论产生了以下结果:闭合回路中的运动被开放回路或漩涡中的运动所取代;匀速运动被不均匀运动(减速或加速)所取代;在运动过程中,减速漩涡发出初级自由交叉漩涡,而加速漩涡吸入同样的初级自由交叉漩涡;二维运动转化为三维运动;二维的横向漩涡通过特殊变换产生三维的纵向漩涡,反之亦然--三维的纵向漩涡通过另一种特殊变换产生二维的交叉漩涡。现在,作者提议使用纵向加速涡来进行冷核聚变。在与正加速度成正比的力的作用下,它将同时吸入涡旋和原子--在这种情况下是氢的同位素(氘)。加速器漩涡吸入并粘住所有氘中的两个,在放热反应中形成氦,释放出大量热量。二维平面上的减速横向涡旋(由外向内运动)会在其中心产生一个垂直于二维平面的三维纵向加速涡旋。这个位于中心的垂直加速漩涡将横向减速漩涡向上拉(对抗重力),或者说具有反重力的性质。
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引用次数: 0
Economic and environmental comparison between diesel-electric and mechanical propulsion plants for a small cruise ship 小型游轮柴油-电力推进装置与机械推进装置的经济和环境比较
Pub Date : 2023-12-30 DOI: 10.53294/ijfetr.2023.5.2.0034
Giovanni Benvenuto, Ugo Campora
The paper reports an economic and environmental comparison between diesel-electric and mechanical propulsion plants, employed as an alternative to the other one, to the propulsion of a small cruise ship, also described in a previously authors article. The plants prime mover are two versions of the Rolls-Royce Bergen marine diesel engines, employed one as an alternative to the other in all the considered propulsion plants. The engines are characterized by similar rated power but with different power lint curves and specific fuel contours trend in the operating diagram. The diesel-electric propulsion plants are simulated considering the diesel generators working in both constant and variable speed. The economic and environmental (by EEDI and CII index) comparison results, between the considered ship propulsion plants, are presented in tabular and graphical form and commented.
本文报告了柴油-电力推进装置和机械推进装置在经济和环境方面的比较,这两种推进装置被用作小型游轮推进装置的替代品。设备的原动机是两种型号的劳斯莱斯 Bergen 船用柴油发动机,在所有考虑的推进设备中,一种发动机可替代另一种发动机。这两款发动机的额定功率相似,但在运行图中的功率曲线和比燃料等值线趋势不同。考虑到柴油发电机在恒速和变速状态下工作,对柴油-电力推进装置进行了模拟。所考虑的船舶推进装置之间的经济和环境(通过 EEDI 和 CII 指数)比较结果以表格和图形形式呈现,并进行了评论。
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引用次数: 0
The electric induction like a behavior of electrons is proof of the new theory of new axioms and laws 像电子行为一样的电感应证明了新公理和新定律的新理论
Pub Date : 2023-12-30 DOI: 10.53294/ijfetr.2023.5.2.0035
Valentina Markova
The Theory of new Axioms and Laws contains 2 new Axioms and 8 Laws and it is invented by the same author.The classical axiom (Maxuell 1864) states that the uniform vortex is closed and verifies the Classical Field Theory. In contrast, the first new axiom (Axiom1) asserts that the ununiform vortex is always open and on this basis develops a new Theory of Open vortices.The second new axiom (Axiom2) shows that open vortices in nature (not in technic) are mutually orthogonal. On this basis, the electron is defined as orthogonal to the proton. The Law1, applied to the electron, affirms that a decelerating transverse open vortex generates an accelerating longitudinal vortex in its center. As one of result of the decelerating transverse vortex, the electron becomes a strong eccentric. The center of body moves from Geometric center to a new center, which is the center of Gravity. This means that during its pulsation, this eccentric body emits a transverse electric wave with a greater amplitude from the convex side of eccentric spiral than from its flattened side. As other of result is that the eccentric electron has an open active end of its decelerating transverse vortex. This means that for flowing of Electric wave only 1 axis (coordinate)phasing and ordering is required.Therefore, the electrons arrangement their open ends (tails) towards positive end of a conductor and the movement of theis own Electric wave is also to positive end of the Conductor. But the phenomenon induction of Electric current is connected with phasing of the electrons along the 3 axes. In case of outer hitting of Magnetic lines, electrons arrange themselfs that their own axes are parallel to outer Magnetic lines and to be at minimal distance to them. What's more- the existence of phenomena induction is direct evidence of exactly this structure of the electron. The inner structure of the electron as open decelerating very eccentric vortex is what causes it to react of the external impact from lines of force of external Magnetic field, as a particle possessing some internal intelligence
新公理和定律理论包含 2 条新公理和 8 条定律,由同一作者发明。经典公理(马克苏尔,1864 年)指出均匀涡是封闭的,并验证了经典场论。与此相反,第一个新公理(公理 1)断言,不均匀涡总是开放的,并在此基础上发展了新的开放涡理论。第二个新公理(公理 2)表明,自然界中的开放涡(而非技术中的开放涡)是相互正交的。在此基础上,电子被定义为与质子正交。应用于电子的定律 1 证实,一个减速的横向开放涡旋会在其中心产生一个加速的纵向涡旋。由于横向漩涡减速的结果之一,电子变成了一个强偏心体。身体的中心从几何中心移动到一个新的中心,即重力中心。这意味着在脉动过程中,这个偏心体从偏心螺旋的凸面发出的横向电波比从其扁平面发出的电波振幅更大。另一个结果是,偏心电子减速横向涡旋的活动端是开放的。这意味着电波的流动只需要一个轴(坐标)相位和排序。因此,电子将其开口端(尾部)朝导体的正极排列,其自身的电波也朝导体的正极运动。但感应电流现象与电子沿三条轴线的相位有关。在磁力线外侧撞击的情况下,电子会使自己的轴线与外侧磁力线平行,并与磁力线保持最小距离。更重要的是,感应现象的存在正是电子这种结构的直接证据。电子的内部结构是一个开放的、减速的、非常偏心的漩涡,正是这种结构使它能够对外部磁场力线的冲击做出反应,就像一个拥有内部智慧的粒子一样。
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引用次数: 0
A complete mathematical modelling of robots actuated by epicyclic-gear 用双环齿轮驱动机器人的完整数学模型
Pub Date : 2023-12-30 DOI: 10.53294/ijfetr.2023.5.2.0032
Brahim Fernini
The industrial robots often use planetary gear system to have high joint torques; therefore, the influence of the rotary inertia of the number of the equally spaced planet-gears on the dynamical behavior of the robot is very important. The main objective of this paper is to develop the dynamic modeling of robot actuated by (n) equally spaced planet-gears in the case where the planet-carrier is fixed, no closed solution has been reported for this dynamic modeling, and to compare between the dynamic behavior of robot actuated by (n+1) and (n) equally spaced planet-gears for a same trajectory planning. The authors derive the explicit dynamic model for an elbow down of 2-R manipulator holding an external mass. Finally, the obtained simulation results of the dynamic modeling are verified by modeling the same robot and using an advanced simulation via SolidWorks.
工业机器人通常使用行星齿轮系统来获得高关节扭矩;因此,等间距行星齿轮数量的旋转惯性对机器人动态行为的影响非常重要。本文的主要目的是在行星载体固定的情况下,建立由(n)个等间距行星齿轮驱动的机器人的动态模型,目前还没有关于该动态模型的封闭解的报道,并比较由(n+1)个和(n)个等间距行星齿轮驱动的机器人在相同轨迹规划下的动态行为。作者为手持外部质量的 2-R 机械手的肘部下压推导出了明确的动态模型。最后,通过 SolidWorks 对同一机械手进行建模并使用高级仿真,验证了所获得的动态建模仿真结果。
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引用次数: 0
Cost effective maintenance strategy for centrifugal pumps using reliability centred maintenance 以可靠性为中心的离心泵成本效益维护战略
Pub Date : 2023-11-30 DOI: 10.53294/ijfetr.2023.5.2.0031
A.T. Funmilayo, E. G. Saturday
The aim of this work is to obtain a maintenance strategy that is cost effective for centrifugal pumps using reliability centred maintenance (RCM). The components of the centrifugal pump used for the study are the shaft, impeller, bearing, mechanical seal, coupling, shaft sleeve, wear-ring casing, suction flange and discharge flange. The motor that drives the pump was also considered. Two basic tools of the RCM strategy were applied. These are the failure modes, effects and criticality analysis (FMECA) and logic tree analysis (LTA). Failure data for a period of 10 years about a centrifugal pump was collected and the FMECA was applied to determine the failure modes, the effects of the failure, the criticality of the components, the mean time between failure (MTBF), the failure rate and the mean time to repair (MTTR). The risk priority numbers of all the components were estimated. The LTA was applied to come up with a new maintenance strategy for each of the components of the pump. The maintenance cost consisting of spare part cost and labour cost for the pump components were estimated for the current maintenance practice as well as the new or proposed maintenance practice. The most critical components observed were the motor, shaft, impeller and the mechanical seal. The motor has the highest MTTR value (58 hrs) while the mechanical seal has the highest failure rate (8.06E-04 per hr). The proposed maintenance strategy leads to reduction in spare part cost in a number of components, with the largest reduction of 19.88% occurring in mechanical seal. The proposed strategy also leads to reduction in labour cost in motor, shaft, impeller and the mechanical seal with the values 33%, 25%, 50% and 25% respectively. The methodology could be applied to other devices.
这项工作的目的是利用以可靠性为中心的维护(RCM),为离心泵制定成本效益高的维护策略。研究中使用的离心泵部件包括轴、叶轮、轴承、机械密封、联轴器、轴套、耐磨环外壳、吸入法兰和排出法兰。此外,还考虑了驱动泵的电机。应用了 RCM 策略的两个基本工具。它们是故障模式、影响和临界分析 (FMECA) 和逻辑树分析 (LTA)。收集了离心泵 10 年来的故障数据,并应用 FMECA 确定了故障模式、故障影响、部件关键性、平均故障间隔时间 (MTBF)、故障率和平均修复时间 (MTTR)。对所有组件的风险优先级进行了估算。应用 LTA 为泵的每个组件制定了新的维护策略。估算了当前维护方法以及新的或建议的维护方法的维护成本,包括泵部件的备件成本和人工成本。观察到的最关键部件是电机、轴、叶轮和机械密封。电机的 MTTR 值最高(58 小时),而机械密封的故障率最高(每小时 8.06E-04)。建议的维护策略降低了许多部件的备件成本,其中机械密封的备件成本降低幅度最大,达到 19.88%。建议的策略还能降低电机、轴、叶轮和机械密封的人工成本,分别为 33%、25%、50% 和 25%。该方法可应用于其他设备。
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引用次数: 0
Trend of traffic on inland waterways of Port Harcourt urban coastal environment: a comparative safety imperative for a Ghanaian coastal regional province 哈科特港城市沿海环境内河交通趋势:加纳沿海地区省份的相对安全必要性
Pub Date : 2023-08-30 DOI: 10.53294/ijfetr.2023.5.1.0017
Nnenna Jennifer Nze, Charles Anum Adams, Ibeawuchi Chibueze Nze, Samuel Ato Andam-Akorful
The purpose of the study is to compare mobility and access in Sub- Saharan Africa urban cities of Nigeria and Ghana by analysing trends and accident probabilities on the inland waterways to improve safety standards. Primary data from100 respondents through structured data and interview from boat and ferry operators were used. The responses were ranked on a four-point scale based on the selected routes’ average accident probabilities in percent: Very Safe {0-20}, Fairy Safe {21- 50}, Unsafe {51- 80}, and Very Unsafe {81- 100}. Secondary data from the National Inland Waterways Authority (NIWA) and Ghana Maritime Authority (GMA) and the Volta Lake Transport Company (VLTC) were subjected to probability, percentage and trend analysis. Results indicate that in the Niger delta for every journey there is approximately 59% likelihood of fatal accident; while on the Volta Lake there is a likelihood of 7% fatal accident occurrence. The trend of traffic was high in the Niger delta noticeably in the routes of Akwa- Ibom. Cross Rivers and Rivers State. The Volta Lake recorded high traffic volumes on the routes of Yeji,Tapa Abo and Bidi on market days while on non-market days, Makango. Kwamekrom and Kpechu had high passenger volumes. Estimated annual passenger traffic on the Niger delta routes outweighed that on the Volta Lake routes on a ratio of 4:1. Safety analysis further reveals that the water ways of Port Harcourt in Rivers state were unsafe for travel while the water ways of the Volta Lake were relatively safe as revealed by the average probability ratio of 8:1 in comparative terms. The log linear regression analysis reveals a price elasticity of demand for boat transport of 1.00 and 0.97 for the selected route of Port Harcourt Nigeria and Volta Lake, Ghana respectively. It further supports the fact that more passengers were responsive to travel by waterways in Nigeria than Ghana. The study concludes that waterways of Niger delta basin have high risk indices and likelihood of accident occurrence than the Volta basin; and recommends that VLTC and NIWA should invest optimally and partner with the private sector to enforce and regulate the waterways operations so as to increase safety and mobility of users of the waterways.
该研究的目的是通过分析内陆水道的趋势和事故概率来比较尼日利亚和加纳撒哈拉以南非洲城市的机动性和可达性,以提高安全标准。通过结构化数据和对船只和渡轮运营商的访谈,使用了来自100名受访者的主要数据。根据所选路线的平均事故概率(以百分比为单位),将回答分为四个等级:非常安全{0-20},非常安全{21- 50},不安全{51- 80}和非常不安全{81- 100}。来自国家内河航道管理局(NIWA)、加纳海事管理局(GMA)和沃尔特湖运输公司(VLTC)的二手数据进行了概率、百分比和趋势分析。结果表明,在尼日尔三角洲,每次旅行发生致命事故的可能性约为59%;而在沃尔特湖上,发生致命事故的可能性为7%。在尼日尔三角洲的阿夸-伊博姆路线上,交通的趋势非常明显。跨越河流和河流州。在集市日,在Yeji、Tapa Abo和Bidi路线上的Volta Lake记录了高交通量,而在非集市日,Makango路线上。Kwamekrom和Kpechu的客运量很高。据估计,尼日尔三角洲航线的年客运量与沃尔特湖航线的年客运量之比为4:1。进一步的安全分析表明,河流州的Harcourt港水路是不安全的,而Volta湖的水路是相对安全的,其平均概率比为8:1。对数线性回归分析显示,尼日利亚哈科特港和加纳沃尔塔湖所选航线的船舶运输需求价格弹性分别为1.00和0.97。它进一步支持这样一个事实,即尼日利亚比加纳更多的乘客对水路旅行有反应。研究结果表明,尼日尔三角洲流域的水道风险指数和事故发生可能性高于沃尔特盆地;并建议VLTC和NIWA应进行最佳投资,并与私营部门合作,执行和规范水路运营,以提高水路用户的安全性和机动性。
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引用次数: 0
Effects of process parameters variations and optimization of biodiesel production from orange seed oil using raw and thermal clay as catalyst 原料粘土和热粘土催化橙籽油制备生物柴油的工艺参数变化及优化研究
Pub Date : 2023-08-30 DOI: 10.53294/ijfetr.2023.5.1.0018
Uket Igri, Igri Omini Uket, H. U. Ugwu
In this study, process parameters for the production of biodiesel from orange seed oil using raw and thermal clay as catalyst were analyzed using randomized optimal design. The design was a response surface method (full fractional factorial) which identified the various design points as being numerical and discrete. The process optimization was performed by varying five factors, each at two different levels. The process parameters: methanol to oil molal ratio (mol/mol), catalyst concentration (weight %), reaction time (minutes), temperature (°C) and agitation speed (revolution per minutes, rpm) were the independent variables (input), while the biodiesel yield (vol/vol) was the dependent variable (response) in the optimization process. The designed matrix, 3D (three dimensional) surface plots, contour plots and analysis of variance (ANOVA), was achieved using the Design Expert Software (version 12.0), the optimum biodiesel yield was predicted and experimented to ascertain the interactive effects of parameters. The correlating regression coefficient indicated the satisfactory performance of the model for the raw and thermal clay. The experimental/actual maximum optimal biodiesel yield for the biodiesel production from the orange seed oil using raw and thermal clay as catalyst was 79.53 and 94.58% v/v while the predicted biodiesel yield was 79.55 and 92.98% v/v. The set of conditions that caused these positive effects were established at Time of 150 minutes, Temperature 65 °C, methanol /sample molal ratio of 12:1, catalyst concentration of 3.0 wt. % and agitation speed at 300 rpm respectively. Thisresults shows agreement between the actual and predicted biodiesel yield. It can be concluded that the best biodiesel yield can be achieved using thermally modified clay as catalyst.
采用随机优化设计方法,对以原料和热粘土为催化剂,以橙籽油为原料生产生物柴油的工艺参数进行了分析。设计采用响应面法(全分数阶乘),该方法确定了各个设计点的数值性和离散性。过程优化通过改变五个因素来执行,每个因素在两个不同的水平上。优化过程以甲醇油摩尔比(mol/mol)、催化剂浓度(重量%)、反应时间(min)、温度(℃)和搅拌速度(转/分,rpm)为自变量(输入),以生物柴油产率(vol/vol)为因变量(响应)。利用Design Expert Software (version 12.0)完成设计矩阵、三维曲面图、等高线图和方差分析(ANOVA),并对生物柴油的最佳产率进行了预测和实验,以确定参数的交互效应。相关回归系数表明,该模型对生土和热土具有满意的性能。以原料和热粘土为催化剂,以橙籽油为原料制备生物柴油的实验和实际最优产率分别为79.53和94.58% v/v,预测产率分别为79.55和92.98% v/v。实验条件为:时间150分钟,温度65℃,甲醇/样品摩尔比12:1,催化剂浓度3.0 wt. %,搅拌速度300 rpm。结果表明生物柴油的实际产率与预测产率是一致的。结果表明,以热改性粘土为催化剂制备生物柴油的产率最高。
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International Journal of Frontiers in Engineering and Technology Research
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