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Adsorption of fluoride from water using Al–Mg–Ca ternary metal oxide-coated sand 铝镁钙三元金属氧化物包覆砂对水中氟化物的吸附研究
Pub Date : 2023-10-13 DOI: 10.2166/ws.2023.269
Kiana Modaresahmadi, Amid Khodadoust, James Wescott
Abstract An aluminum–magnesium–calcium-coated sand (AMCCS) sorbent was evaluated as a low-cost ternary metal oxide adsorbent for adsorption and removal of fluoride from water with potential application in flow-through water filtration systems. The AMCCS sorbent coating contained mostly amorphous oxides of aluminum, magnesium, and calcium. The adsorption of fluoride occurred in less than an hour, while fluoride adsorption followed pseudo-second-order kinetics. The favorable adsorption of fluoride onto the AMCCS sorbent occurred according to the Langmuir and Freundlich adsorption equations, whereas the physical adsorption of fluoride onto the AMCCS sorbent occurred based on the Dubinin–Radushkevich adsorption equation. The adsorption of fluoride occurred over a broad pH range from 2 to 10.5 with a decrease in adsorption at pH above 10.5, indicative of the adsorption of fluoride onto the positively charged surface of AMCCS sorbent at pH below the AMCCS sorbent pHPZC of 10.4. The AMCCS sorbent was able to remove fluoride from natural waters with appreciable alkalinity, total hardness and total dissolved solids, indicative of AMCCS sorbent selectivity for fluoride adsorption. The AMCCS sorbent was re-coated and reused after several adsorption cycles, rendering the AMCCS sorbent a recyclable and sustainable adsorbent for effective and rapid removal of fluoride from water.
摘要采用铝镁钙包覆砂(AMCCS)吸附剂作为一种低成本的三元金属氧化物吸附剂,对水中氟化物的吸附和去除进行了研究,并对其在流水过滤系统中的应用前景进行了评价。AMCCS吸附剂涂层主要含有铝、镁和钙的无定形氧化物。氟的吸附在不到1小时的时间内发生,而氟的吸附遵循准二级动力学。根据Langmuir和Freundlich吸附方程,氟在AMCCS吸附剂上发生了良好的吸附,而氟在AMCCS吸附剂上发生了基于Dubinin-Radushkevich吸附方程的物理吸附。在pH值为2 ~ 10.5的较宽范围内,氟化物的吸附发生在pH值大于10.5时,吸附量减少,说明在pH值低于AMCCS吸附剂pHPZC为10.4时,氟化物在AMCCS吸附剂的正电荷表面吸附。AMCCS吸附剂能够去除碱度、总硬度和总溶解固体的天然水体中的氟化物,表明AMCCS吸附剂对氟化物的选择性吸附。经过几个吸附循环后,AMCCS吸附剂被重新涂覆并重复使用,使AMCCS吸附剂成为一种可回收、可持续的吸附剂,可有效、快速地去除水中的氟化物。
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引用次数: 1
Equitable supply in intermittently operated rural water networks in emerging economies 新兴经济体中间歇性运行的农村供水网络的公平供应
Pub Date : 2023-10-13 DOI: 10.2166/ws.2023.268
Varghese Kurian, Prasanna Mohandoss, Srinesh Chandrakesa, Saravanan Chinnusamy, Shankar Narasimhan, Sridharakumar Narasimhan
Abstract Many operators of water distribution networks (WDNs) are unable to meet the increasing demand for water. Utility operators in such situations resort to rationing the supply as a partial solution to this problem; this, in turn, may lead to disproportionate allocation of water or inequity in supply. In this study, we propose a mixed integer non-linear program formulation and an efficient solution approach to minimize the inequity in supply, subject to hydraulic constraints and additional constraints on hours of supply and valve operation. Further, we show that the schedule can be obtained using a data-driven approach based on flow and level measurements, which eliminates the modelling effort and uncertainty associated with the use of hydraulic models. We demonstrate the proposed approaches through simulations of a real WDN, and experiments conducted on a topologically similar laboratory-scale network.
许多供水管网运营商无法满足日益增长的用水需求。在这种情况下,公用事业运营商采取定量供应作为部分解决这一问题的办法;这反过来又可能导致水分配不成比例或供应不平等。在这项研究中,我们提出了一个混合整数非线性规划公式和一个有效的解决方法,以最小化供应不平等,受液压约束和额外的供应时间和阀门操作约束。此外,我们还表明,可以使用基于流量和液位测量的数据驱动方法来获得时间表,这消除了建模工作和与使用水力模型相关的不确定性。我们通过模拟真实的WDN和在拓扑相似的实验室规模网络上进行的实验来证明所提出的方法。
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引用次数: 0
Assessment of forest food–water resources nexus and its utilization efficiency based on the Gaussian model 基于高斯模型的森林食物-水资源关系及其利用效率评价
Pub Date : 2023-10-13 DOI: 10.2166/ws.2023.267
Weiguang Xie, Huaquan Ma
Abstract Forest resources are an important foundation for human survival and development, and their utilization and management are of great significance for sustainable development. Forests are important ecosystems that provide essential ecological services for human survival and development. Based on the Gaussian model, this article evaluates the grain and water resources in forest areas to explore the efficiency of forest resource utilization. By collecting and processing sample data from the forest areas of the Yangtze River Basin from October to December 2021, the food and water resources of the forest areas under different vegetation types and soil moisture content were obtained. The results indicate that the total amount of grain resources varies among different sample areas. The maximum weight is 6,000 kg and the minimum weight is 3,500 kg. The total amount of water resources varies among different sample areas, ranging from 600 to 2,000 m3.
森林资源是人类生存和发展的重要基础,森林资源的利用和管理对可持续发展具有重要意义。森林是重要的生态系统,为人类生存和发展提供必要的生态服务。本文基于高斯模型对林区粮食和水资源进行评价,探讨森林资源利用效率。通过对2021年10 - 12月长江流域林区样本数据的采集和处理,得到了不同植被类型和土壤含水量下林区的粮食和水资源。结果表明,不同样区粮食资源总量存在差异。最大重量为6000公斤,最小重量为3500公斤。不同样区水资源总量差异较大,从600 ~ 2000 m3不等。
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引用次数: 0
New production pathway of musty 2,4,6-tribromoanisole during raw water disinfection processes at a surface water treatment plant 地表水处理厂原水消毒过程中霉性2,4,6-三溴苯甲醚的新生产途径
Pub Date : 2023-10-13 DOI: 10.2166/ws.2023.264
Hunter Adams, Susheera Pochiraju, Keisuke Ikehata, Mark Southard, Sam Reeder, Emily Appleton, Daniel Nix
Abstract The City of Wichita Falls’ Cypress Environmental Laboratory developed a comprehensive taste and odor (T&O) monitoring program to identify T&O compounds, their point of origin, and how to mitigate each T&O event to lessen its impact and maintain consumer confidence. In January 2023, a T&O compound was detected in the water system using sensory analysis with a threshold odor number (TON) of 3, guiding further analytical testing to identify for musty compounds. The unknown was confirmed to be 2,4,6-tribromoanisole (2,4,6-TBA) at a maximum of 9.86 ng/L. Its point of origin for production was tracked to a raw water line using chlorine dioxide as a primary disinfectant. Jar tests were performed to confirm that the mode of production was excess-free chlorine from the generation of chlorine dioxide in the presence of bromide in raw water. The event was mitigated using powdered activated carbon in clarifiers to adsorb and settle out the compound, resulting in a non-detectable level (a TON of 1 and <5.00 ng/L for 2,4,6-TBA). This paper discusses the unique generation pathway within a full-scale treatment plant and how a monitoring and response program can be used to help detect a T&O event at an early stage and aid the mitigation process.
威奇托福尔斯市柏树环境实验室开发了一项全面的味觉和气味(T&O)监测计划,以识别T&O化合物,它们的来源,以及如何减轻每个T&O事件,以减少其影响并保持消费者信心。2023年1月,通过感官分析在水系统中检测到一种T&O化合物,阈值气味数(TON)为3,指导进一步的分析测试以识别霉味化合物。该未知物质为2,4,6-三溴苯甲醚(2,4,6- tba),最大浓度为9.86 ng/L。其生产源头被追踪到一条使用二氧化氯作为主要消毒剂的原水管道。进行了罐子试验,以确认生产方式是在原水中存在溴化物的情况下产生二氧化氯而产生多余的无氯。在澄清剂中使用粉末状活性炭来吸附和沉淀化合物,从而减轻了该事件,导致无法检测到的水平(2,4,6- tba的TON为1和5.00 ng/L)。本文讨论了全规模处理厂内独特的生成途径,以及如何使用监测和响应程序来帮助在早期阶段检测T&O事件并帮助缓解过程。
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引用次数: 0
Projection of monthly surface flows by an optimized SWAT–MLP: a case study 利用优化的SWAT-MLP预测每月地面流量:一个案例研究
Pub Date : 2023-10-13 DOI: 10.2166/ws.2023.265
Gao Furong, Sarmistha Hossain
Abstract Recent investigations have noted that using a hybrid arrangement of Soil and Water Assessment Tool (SWAT) and multi-layer perceptron (MLP) has high efficiency in runoff prediction. In this research, in addition to using the SWAT and MLP models, an optimized algorithm called Mutated SunFlower Optimization (MSFO) algorithm has been proposed to predict better runoff, which improves the results of prediction runoff by decreasing the error percentage in the MLP model. For this purpose, first, runoff modeling is used to assess the efficiency of the SWAT system. The model's verification and calibration have been performed using data from the previous 30 years of statistics. Then, the flow stream simulated by the SWAT method is evaluated with the observational data and applied as the inputs to the MLP model, and finally, runoff is predicted through the MLP model, and MSFO is used in the MLP model to obtain better results for runoff prediction. The results show that the values of statistical indices R2, RMSE, NSE, and RE give satisfying agreement for runoff forecast in the SWAT–MLP/MSFO model with values of 0.83, 1.68, 0.51, and −0.1.
摘要近年来的研究表明,利用土壤和水分评估工具(SWAT)和多层感知器(MLP)的混合配置在径流预测中具有很高的效率。本研究在使用SWAT和MLP模型的基础上,提出了一种优化算法——突变向日葵优化算法(MSFO),通过降低MLP模型的误差百分比,提高了径流预测的效果。为此,首先使用径流模型来评估SWAT系统的效率。利用过去30年的统计数据对模型进行了验证和校正。然后,利用观测数据对SWAT方法模拟的径流进行评价,并将其作为MLP模型的输入,最后通过MLP模型对径流进行预测,并将MSFO应用于MLP模型以获得较好的径流预测结果。结果表明,SWAT-MLP /MSFO模型的统计指标R2、RMSE、NSE和RE的预测值分别为0.83、1.68、0.51和- 0.1,具有较好的一致性。
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引用次数: 0
Water footprint approach in measuring the potential of bioenergy production from agricultural products 用水足迹法衡量农产品生产生物能源的潜力
Pub Date : 2023-10-12 DOI: 10.2166/ws.2023.263
Fangfang Zeng
Abstract Promoting the supply of energy from biomass to reduce the emission of greenhouse gases has resulted in focusing on the production of important products from the perspective of energy and ultimately, increasing water consumption. Therefore, in the present study, an index called water footprint was used to investigate the link between water and bioenergy. For this purpose, information related to grain maize crops was collected in the study plains of Fujian province in eastern China. Based on the calculations, it was found that the water footprint of maize products in the province was equal to 3,728 m3/ton on average, and the water footprint of its biomass was estimated to be 219.6 m3/ton. Moreover, the investigation of the water footprint of maize biomass energy showed that the highest and lowest water footprints per unit of energy are found in Ningde and Zhangzhou, respectively. It was also found that the plains of Zhangzhou, Ningde and Xiamen have little priority for biomass production because the water footprint of their biomass energy is less than 900 MJ/m3. On the other hand, Nanping and Putian plains with bioenergy water footprints between 1,500 and 1,800 MJ/m3 have high priority for using maize biomass for energy production.
促进生物质能源的供应以减少温室气体的排放,导致从能源的角度关注重要产品的生产,最终增加了用水量。因此,在本研究中,用水足迹指数被用来调查水和生物能源之间的联系。为此,收集了福建省研究平原谷物玉米作物的相关信息。计算发现,全省玉米产品的水足迹平均为3728 m3/t,其生物量的水足迹估计为219.6 m3/t。玉米生物质能源的水足迹调查结果显示,单位能源水足迹最高的是宁德市,最低的是漳州市。漳州、宁德和厦门平原生物质能水足迹均小于900 MJ/m3,优先级较低。另一方面,在生物能源水足迹在1500 ~ 1800 MJ/m3之间的南坪平原和莆田平原,玉米生物质能源利用优先度较高。
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引用次数: 0
Experimental study on the performance of the dielectric barrier discharge technique in the treatment of simulated groundwater with high iron and manganese content 介质阻挡放电技术处理高铁、高锰模拟地下水的试验研究
Pub Date : 2023-10-12 DOI: 10.2166/ws.2023.270
Yixin Jin, Xuezhi Li, Lida Ma, Wenjie Tian, Linlin Zhang, Aonan Liu
Abstract Groundwater with high concentrations of iron and manganese is harmful to the human body and modern industries. Conventional methods of treating iron and manganese have the disadvantage of high costs and complex control processes. A dielectric barrier discharge (DBD) water treatment system was built to remove iron and manganese from groundwater in this paper. Single-factor experiments were used to analyze the effect of discharge power, initial iron and manganese concentrations, gas flow rate, liquid flow rate, initial pH, flocculant and capture agent process parameters on iron and manganese removal rates. It was found that Fe2+ removal rates can reach 97.31% and Mn2+ removal rates can reach 81.42% when the initial concentrations of Fe2+ and Mn2+ are 6 and 3 mg/L, respectively. The use of 10 mg/L NaHCO3 or 5 mg/L Ca(OH)2 increased the removal rate of Fe2+ to 99% but had no effect on the removal rate of Mn2+. It was found that the optimum treatment time for Mn2+ was different for different process parameters, mainly in the range of 9–15 min, which needs to be noted in future production applications. This work shows that DBD can effectively remove iron and manganese ions from groundwater and analyzes the removal mechanism.
摘要含高浓度铁、锰的地下水对人体和现代工业都是有害的。传统的铁锰处理方法存在成本高、控制过程复杂等缺点。建立了介质阻挡放电(DBD)水处理系统,以去除地下水中的铁和锰。采用单因素实验分析了放电功率、初始铁锰浓度、气体流速、液体流速、初始pH、絮凝剂和捕集剂工艺参数对铁锰去除率的影响。当Fe2+和Mn2+初始浓度分别为6和3 mg/L时,Fe2+去除率可达97.31%,Mn2+去除率可达81.42%。使用10 mg/L NaHCO3或5 mg/L Ca(OH)2可将Fe2+的去除率提高到99%,但对Mn2+的去除率没有影响。研究发现,不同工艺参数对Mn2+的最佳处理时间不同,主要在9 ~ 15 min范围内,这在今后的生产应用中需要注意。研究表明,DBD能有效去除地下水中的铁和锰离子,并对其去除机理进行了分析。
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引用次数: 0
Water productivity maximization and ecosystem monitoring to estimate tourism economic value 水生产力最大化与生态系统监测估算旅游经济价值
Pub Date : 2023-10-09 DOI: 10.2166/ws.2023.262
Maozheng Fu, Zhenrong Luo, Liying Feng, Xiaoping Que
Abstract Water supply from a common pool resource based on productivity indicators for different uses is one of the goals of planning in dry areas. Productivity indicators are defined based on time, geographical location and hydrological conditions in the form of food security, economic benefits and ecosystem restoration. This study was conducted in order to evaluate the contrast between economic criteria and food security in the exploitation of water resources in Lu'an city in Anhui province of China. Probabilistic modeling based on the prediction of uncertain values using the Latin hypercube technique was used for hydrological variables and water resources. The method of data mining and trend analysis of dependent variables was also simulated to estimate economic values in the water cycle. Statistical information of 32 years from 1991 to 2022 has been collected and used as an annual average per population. The results showed that the economic value of water consumption in the tourism industry has increased compared to agriculture. The total water provided for food security is equal to 6.5 m3 per person, the excess of which can be allocated to other uses through weighting indicators based on ecosystem and quality.
基于不同用途的生产力指标的共同池资源的供水是干旱地区规划的目标之一。生产力指标是根据时间、地理位置和水文条件,以粮食安全、经济效益和生态系统恢复的形式确定的。本研究旨在评价安徽省六安市水资源开发经济指标与粮食安全的对比。利用拉丁超立方体技术对水文变量和水资源进行了基于不确定值预测的概率建模。模拟了数据挖掘和因变量趋势分析的方法来估算水循环中的经济价值。收集1991 - 2022年32年的统计资料,作为人均年平均值。结果表明,与农业相比,旅游业用水量的经济价值有所增加。为粮食安全提供的总水量相当于每人6.5立方米,超过的水量可以通过基于生态系统和质量的加权指标分配给其他用途。
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引用次数: 0
Evaluation energy flow and analysis of energy economy for agricultural yield production in different geographical regions of China 中国不同地理区域农业产量生产能量流评价与能源经济分析
Pub Date : 2023-10-09 DOI: 10.2166/ws.2023.261
Kai Li
Abstract Dry and humid climates have different potentials for providing soil moisture. Agricultural drought is a confirmed criterion for evaluating production potential in agriculture, which is discussed in this research. Therefore, this research aims to investigate drought using meteorological and agricultural drought indicator data in four climatic regions of China (humid, semi-humid, semi-arid and dry). For this purpose, climatic information was collected in the last 20 years, and the values of the standard precipitation index (SPI) and reconnaissance drought index (RDI) were determined. Examining the indicators indicates that the indicators are high in all the years under review in dry areas. In the semi-arid region, there was a significant decrease in the average value of the indices in July and August in the years 2017–2022. Drought indicators did not show a critical situation in humid and semi-humid areas, and there was sufficient moisture for plants throughout the year. The results showed that there was a high correlation between the SPI and the RDI in all the identified areas. In addition to rainfall, the RDI also includes transpiration and is more sensitive, especially in dry areas where transpiration is higher than rainfall.
干燥和潮湿气候对土壤水分的提供具有不同的潜力。农业干旱是评价农业生产潜力的公认标准,本文对此进行了探讨。因此,本研究旨在利用气象和农业干旱指标数据对中国4个气候区(湿润、半湿润、半干旱和干燥)进行干旱调查。为此,收集了近20 a的气候资料,确定了标准降水指数(SPI)和侦察干旱指数(RDI)的数值。对指标的审查表明,在审查的所有年份中,干旱地区的指标都很高。在半干旱区,2017-2022年7月和8月的指数平均值明显下降。湿润和半湿润地区干旱指标不严重,全年植物水分充足。结果表明,在所有鉴定的地区,SPI与RDI之间存在较高的相关性。除降雨外,RDI还包括蒸腾,并且更敏感,特别是在蒸腾高于降雨量的干燥地区。
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引用次数: 0
Corrigendum: Water Supply 1 May 2023; 23 (5): 2197–2209. Evaluation on real-time self-organization algorithm of forest cultivation, tea planting, and tea processing for sustainable ecosystem management of agricultural water resources. Zhenhong Wang, Liyong Zhang, Minfeng Song, Sangjie Luobu, Jiumei, Danzhen, Hong Peng 更正:供水2023年5月1日;23(5): 2197-2209。面向农业水资源生态系统可持续管理的森林种植、茶叶种植和茶叶加工实时自组织算法评价王振红,张立勇,宋敏峰,罗桑杰,九梅,丹珍,彭红
Pub Date : 2023-10-06 DOI: 10.2166/ws.2023.271
{"title":"Corrigendum: <i>Water Supply</i> 1 May 2023; 23 (5): 2197–2209. Evaluation on real-time self-organization algorithm of forest cultivation, tea planting, and tea processing for sustainable ecosystem management of agricultural water resources. Zhenhong Wang, Liyong Zhang, Minfeng Song, Sangjie Luobu, Jiumei, Danzhen, Hong Peng","authors":"","doi":"10.2166/ws.2023.271","DOIUrl":"https://doi.org/10.2166/ws.2023.271","url":null,"abstract":"","PeriodicalId":23573,"journal":{"name":"Water Science & Technology: Water Supply","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135346889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Water Science & Technology: Water Supply
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