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Development and Application of Watershed Regressions for Pesticides (WARP) for Estimating Atrazine Concentration Distributions in Streams 流域回归法估算溪流中莠去津浓度分布的发展与应用
Pub Date : 2004-01-01 DOI: 10.3133/WRI034047
S. Larson, C. G. Crawford, R. Gilliom
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引用次数: 24
Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory : determination of organochlorine pesticides and polychlorinated biphenyls in bottom and suspended sediment by gas chromatography with electron-capture detection 美国地质调查局国家水质实验室的分析方法:用电子捕获检测气相色谱法测定底部和悬浮沉积物中的有机氯农药和多氯联苯
Pub Date : 2004-01-01 DOI: 10.3133/WRI034293
M. C. Noriega, Duane S. Wydoski, W. T. Foreman
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引用次数: 20
Quality of Water from Shallow Wells in Urban Residential and Light Commercial Areas in Lafayette Parish, Louisiana, 2001 through 2002 2001年至2002年路易斯安那州拉斐特教区城市住宅和轻型商业区浅水井水质
Pub Date : 2004-01-01 DOI: 10.3133/wri20034118
R. B. Fendick, R. W. Tollett
In 2001-02, the U.S. Geological Survey installed and sampled 28 shallow wells in urban residential and light commercial areas in Lafayette Parish, Louisiana, for a land-use study in the Acadian-Pontchartrain Study Unit of the National Water-Quality Assessment (NAWQA) Program. The wells were installed in the Chicot aquifer system, the primary source of water for irrigation and public-water supplies in southwestern Louisiana. The purpose of this report is to describe the quality of water from the 28 shallow wells and to relate that water quality to natural factors and to human activities. Ground-water samples were analyzed for general ground-water properties and about 240 water-quality constituents, including dissolved solids, major inorganic ions, trace elements, nutrients, dissolved organic carbon (DOC), radon, chlorofluorocarbons, selected stable isotopes, pesticides, pesticide degradation products, and volatile organic compounds (VOC’s). Dissolved-solids concentrations for two wells exceeded the U.S. Environmental Protection Agency Secondary Maximum Contaminant Level of 500 mg/L (milligrams per liter). Concentrations for major inorganic ions, trace elements, pesticides, degradation products, and VOC’s were less than the Maximum Contaminant Levels for drinking water. Manganese concentrations for 18 wells exceeded the Secondary Maximum Contaminant Level of 50 micrograms per liter. Arsenic concentrations increased with depth and with increased pH, bicarbonate, calcium, and magnesium concentrations. Six pesticides and three degradation products were detected in the ground-water samples. Ten VOC’s also were detected in the ground-water samples. One nutrient concentration (that for nitrite plus nitrate) was greater than 2 mg/L, a level that might indicate contamination from human activities, and was greater than the Maximum Contaminant Level of 10 mg/L. The median DOC concentration was an estimated 0.3 mg/L, which indicated naturallyoccurring DOC conditions in the shallow ground water in Lafayette Parish. Quality-control samples indicated no bias in ground-water data from collection or analysis. Radon concentrations for 19 of 20 wells sampled were greater than the U.S. Environmental Protection Agency Maximum Contaminant Level of 300 picocuries per liter (piC/L). Radon concentrations ranged from 280 to 2,220 piC/L and had a median of 389 piC/L. Radon concentrations were correlated moderately and inversely to the depth to the top of the screened interval. Chlorofluorocarbons indicated the apparent age of the ground water varied with water level and ranged from about 12 to 50 years. The Mann-Whitney rank-sum test was used to compare water-quality data in the Chicot aquifer system between four groups of wells from three NAWQA studies. The means for most constituents were less for the urban wells than for wells in the rice-growing areas. The larger dissolved-solids concentrations, particularly sodium and chloride, for samples from wells in the rice-growin
2001- 2002年,美国地质调查局在路易斯安那州拉斐特教区的城市住宅区和轻型商业区安装了28口浅井,并对其进行了取样,用于国家水质评估(NAWQA)项目阿卡迪亚-庞恰特莱恩研究小组的土地利用研究。这些井安装在奇科含水层系统中,这是路易斯安那州西南部灌溉和公共供水的主要水源。本报告的目的是描述28口浅井的水质,并将水质与自然因素和人类活动联系起来。对地下水样品进行了一般地下水性质和大约240种水质成分的分析,包括溶解固体、主要无机离子、微量元素、营养物质、溶解有机碳(DOC)、氡、氯氟烃、选定的稳定同位素、农药、农药降解产物和挥发性有机化合物(VOC)。两口井的溶解固体浓度超过了美国环境保护局二级最高污染物标准500毫克/升(毫克/升)。主要无机离子、微量元素、农药、降解产物和挥发性有机化合物的浓度低于饮用水的最大污染物水平。18口井的锰浓度超过了每升50微克的二级最高污染物水平。砷浓度随深度和pH值、碳酸氢盐、钙和镁浓度的增加而增加。在地下水样品中检测到6种农药和3种降解产物。地下水样品中还检测到10种挥发性有机化合物。其中一种营养物质浓度(亚硝酸盐加硝酸盐)超过了2毫克/升,这一水平可能表明受到了人类活动的污染,并且超过了10毫克/升的最大污染物水平。DOC的中位数浓度估计为0.3毫克/升,这表明拉斐特教区浅层地下水中存在自然发生的DOC条件。质量控制样本表明,收集或分析的地下水数据没有偏差。取样的20口井中有19口的氡浓度高于美国环境保护署最高污染物水平300皮居里/升(piC/L)。氡浓度范围为280至2220 piC/L,中位数为389 piC/L。氡浓度与筛选层顶深度呈中等和负相关。氯氟烃表明,地下水的表观年龄随水位的变化而变化,从12年到50年不等。Mann-Whitney秩和检验用于比较来自三个NAWQA研究的四组井在Chicot含水层系统中的水质数据。大多数成分的均值城市井小于水稻种植区的井。从水稻种植区的水井中提取的样品中,溶解固体浓度较高,尤其是钠和氯化物,这可能是路易斯安那州西南部大量灌溉的结果,这导致了深层地下水中成分的移动。城市井的大多数成分均值大于奇科特含水层系统露头区的井,而城市井的大多数成分均值小于露头区以南的井。由于溶解固体和其他化学成分的浓度通常会沿着地下水流动路径增加,因此从城市井中提取的许多选定化学成分的浓度预计会比露头地区的井中提取的样品高。与城市井相比,露头区南部井中样品的浓度较高,这可能是类似的解释。露头区南部的井比城市井深,因此增加了水与含水层沉积物发生反应的时间。四组井之间缺乏相关性表明,井的空间分布和到筛选区间顶部的深度影响了路易斯安那州西南部浅层井的水质。
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引用次数: 0
Two-Dimensional Hydrodynamic Simulation of Surface-Water Flow and Transport to Florida Bay through the Southern Inland and Coastal Systems (SICS) 通过南部内陆和海岸系统(SICS)向佛罗里达湾地表水流和输送的二维水动力模拟
Pub Date : 2004-01-01 DOI: 10.3133/WRI034287
E. Swain, Melinda A. Wolfert, J. Bales, C. R. Goodwin
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引用次数: 39
Drought Conditions in Maine, 1999-2002: A Historical Perspective 1999-2002年缅因州的干旱状况:一个历史的视角
Pub Date : 2004-01-01 DOI: 10.3133/WRI034310
P. Lombard
Hydrologic drought can be defined as reduced streamflow, declining ground-water levels, and (or) reductions in lake or reservoir levels. Monthly precipitation totals, annual 7-day low-flow surface-water recurrence intervals, and month-end ground-water levels from drought years 1999-2002 show that 19992002 was the driest period of hydrologic drought in more than 50 years of record in Maine. Record lows were set in all three data sets at select locations in central Maine in April 1999, and in September 2001 and 2002. Although streamflows recovered to normal levels during 2000, ground-water levels in central Maine indicate that the drought carried over through 2000 into 2001 and 2002 in some locations. In 2001, annual 7-day low flows with greater than 100-year recurrence intervals were recorded in central Maine and low flows with up to 75-year recurrence intervals were recorded in coastal areas. In 2002, annual 7-day low flows with greater than 100-year recurrence intervals were recorded at 4 of 14 stations analyzed statewide, placing it as the driest single year of hydrologic drought on record. Month-end groundwater levels at one location in central Maine indicate that the recent hydrologic drought years were the most severe in more than 50 years in that region. The period from 1947 to 1950 may have been the only comparable period of drought to the 1999-2002 period, in Maine. The 1960s drought, although extreme in the far northern and far southern regions of the State, was most exceptional for its duration from 1963 to 1969. INTRODUCTION Drought is among the most complex and least understood of all natural hazards, affecting more people than any other natural hazard (American Meteorological Society, 1997). Although drought typically is not considered a problem in the humid northeastern United States, it is a normal, recurring feature in all climatic regimes. Drought is a temporary aberration, relative to some long-term (tens of years) average condition, as opposed to aridity, which is a permanent feature of some regional climates (American Meteorological Society, 1997). Many questions still remain concerning the physical mechanisms responsible for the onset, persistence, and spatial extent of regional hydrologic drought in the northeast because of hydrologic variability and the inherent complexity of hydrologic systems (Bradbury and others, 2002). Dry conditions were present in Maine from 1999 to 2002, with a severe drought in 2001-2002. Most U.S.Geological Survey (USGS) monitoring wells, and many streamflow-gaging stations, set record lows during this period. An estimated 7 percent, or approximately 17,000 private wells in Maine went dry in the 9 months prior to April 2002 (Maine Emergency Management Agency, 2002). Wells in central Maine were the most likely to have low water levels. Thirtyfive public water supplies, including eight large community systems, were affected severely (Andrews Tolman, Maine Drinking Water Program, written communication
水文干旱可以定义为河流流量减少、地下水位下降和(或)湖泊或水库水位下降。1999-2002年干旱年的月降水总量、年7天低流量地表水重现间隔和月末地下水位表明,1999-2002年是缅因州50多年来水文干旱最干旱的时期。1999年4月、2001年9月和2002年9月,缅因州中部选定地点的所有三个数据集都创下了历史新低。虽然河流流量在2000年恢复到正常水平,但缅因州中部的地下水位表明,在一些地方,干旱持续了2000年至2001年和2002年。2001年,缅因州中部记录到的年7天低流量大于100年的重现间隔,沿海地区记录到的年低流量高达75年的重现间隔。2002年,在全州分析的14个站点中,有4个站点记录了超过100年重复周期的7天低流量,使其成为有记录以来最干旱的水文干旱年。缅因州中部一个地方月末的地下水位表明,最近的水文干旱年份是该地区50多年来最严重的。1947年至1950年可能是缅因州唯一可与1999年至2002年相比的干旱时期。1960年代的干旱虽然在该国最北部和最南部地区极为严重,但在1963年至1969年期间却是最为罕见的。干旱是所有自然灾害中最复杂和最不为人所知的灾害之一,影响的人数比任何其他自然灾害都多(美国气象学会,1997年)。尽管干旱在潮湿的美国东北部通常不被认为是一个问题,但它在所有气候制度中都是一个正常的、反复出现的特征。相对于一些长期(几十年)的平均状况,干旱是一种暂时的失常,而干旱是一些区域气候的永久特征(美国气象学会,1997年)。由于水文变异性和水文系统固有的复杂性,东北地区区域性水文干旱的发生、持续和空间范围的物理机制仍然存在许多问题(Bradbury等,2002)。1999年至2002年,缅因州一直处于干旱状态,2001年至2002年发生了严重干旱。大多数美国地质调查局(USGS)的监测井和许多流量测量站在此期间创下了历史新低。在2002年4月之前的9个月里,缅因州约有7%的私人水井干涸(缅因州紧急事务管理局,2002年)。缅因州中部的水井最有可能出现低水位。35个公共供水系统,包括8个大型社区供水系统,受到严重影响(Andrews Tolman, Maine Drinking water Program, written communication, 2003)。大多数主要地表水水库的放水量低于其调节最小流量,水生生物的溪流流量减少,关键的夏季灌溉受到限制。缅因州农业部的一项用水调查显示,2001年和2002年,缅因州农民的农作物损失超过3200万美元,其中一些野生蓝莓种植者的作物损失高达80%至100%,28%的缅因州农民对此作出了回应(缅因州农业用水管理咨询委员会,2003年)。由于缺乏防备计划,过去全国范围内干旱的影响已经加剧(美国气象学会,1997年)。任何准备计划的一个组成部分将包括基于该地区历史干旱的气象和水文阈值。在1999-2002年期间,水资源专业人士、农民、企业主和其他关注河流流量、储水量或地下水位的人缺乏必要的定量历史信息,无法将1999-2002年干旱的严重程度与历史干旱进行比较,也无法评估干旱对水资源造成压力的潜力。由于未来缅因州将发生干旱,水资源专家将受益于1999年至2002年缅因州水文条件的记录和分析。特别是,缅因州的应急管理人员和公共供水供应商将从这些信息中受益,因为他们可以更好地了解干旱如何在水文系统中移动的复杂性,从而更好地预测干旱的影响。本报告的目的是记录1999年至2002年干旱水文条件的相对区域和历史严重程度,并提供有关缅因州干旱发生和持续的信息。 本报告将1999-2002年的日平均流量、月末地下水位和月总降水量与选定站点的历史统计数据进行了比较。本文还研究了降水、地表水和地下水之间的相互作用,这次干旱期和历史干旱的每年7天地表水低流量重复周期,以及历史干旱的月末地下水水位与地下水统计数据的比较。干旱可以根据多种参数进行测量或定义,包括降水不足、河流流量、地下水位、土壤湿度和经济影响。这些参数的强度、持续时间和时空范围之间的关系定义了许多不同类型的事件,所有这些事件都可以被认为是干旱。例如,该州北部地区没有降雨的生长季节与全州范围内降雨量低于平均水平的多年期的特征不同,但两者都可以被认为是干旱。尽管干旱可以严格地定义为正常降水的百分比,但它更经常被定义为一段时间的水分不足,足以对一个地区的社会或经济活动产生一些不利影响(Changnon, 1980;保尔森等人,1991)。在过去,对自然资源管理人员来说,将多种定义整合到干旱的综合测量中是有问题的。干旱的许多定义使得很难宣布干旱的开始或结束,或在干旱期间评估其严重程度。美国气象学会将干旱分为四种类型,包括气候干旱、农业干旱、水文干旱和社会经济干旱(American Meteorological Society, 1997)。气候干旱通常由降水亏缺阈值或实际降水与正常降水之比来定义。农业干旱将气候干旱与农业效应联系在一起,主要是土壤水分缺乏的结果。水文干旱的定义是河流流量减少、地下水位下降和(或)湖泊或水库水位减少。社会经济干旱将一些经济产品的供给和需求与气候、农业和(或)水文干旱的要素联系在一起(美国气象学会,1997)。这些类型的干旱通常同时发生;然而,水文干旱通常与气候干旱和农业干旱不同步或滞后。气象因素,如温度、风和相对湿度,可以加剧干旱的严重程度和影响(美国气象学会,1997)。尽管这里定义的四种干旱类型的各个方面都发生在1999年至2002年的缅因州,但本报告主要记录了水文干旱的特征以及气候干旱是如何促成它的。以前的研究很少有关于缅因州历史干旱的记录。1991年,美国地质勘探局在美国各州定义了多年的历史干旱,并在一份关于洪水和干旱的国家水资源摘要中计算了它们的复发间隔(Paulson等人,1991)。《缅因州水资源概况》确定的干旱期列于表1 (Maloney和Bartlett, 1991): 2 1999-2002年缅因州的干旱状况:历史视角。由Maloney和Bartlett在1991年的《国家水资源概要》中确定的1938 - 1988年缅因州历史干旱的低流量复发间隔[低流量复发间隔,流量小于特定值的平均时间间隔;表1中干旱的复发间隔是根据与月平均流量的累积偏差计算的。这种方法在《国家水资源概要》(Jordan and Jennings, 1991)中对各州洪水和干旱摘要的介绍部分进行了描述。干旱的强度被考虑在内,但持续时间没有考虑在内;持续时间从1年到6年不等的干旱在相同的尺度上排名。这种方法可能适用于确定多年的干旱期,或在美国西部等依赖水库的系统中为总缺水分配复发间隔,但除了最近似的条件外,它不适用于东部各州。这是因为美国东部的干旱既取决于降水总量,也取决于降水时间。美国东北部的资源管理人员经常使用国家指数来评估区域条件,尽管这些指数可能更适合全国范围的水状况监测(Skaggs, 1975)。 通常,国家指数不能给那些受干旱影响的人或那些制定政策的人提供地方评价和行动的基础(Russell等人,1970年)。甚至一个地区内的不同用户组也可能经历
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引用次数: 11
Water-quality and bottom-material characteristics of Cross Lake, Caddo Parish, Louisiana, 1997-99 路易斯安那州卡多教区克罗斯湖水质和底质特征
Pub Date : 2004-01-01 DOI: 10.3133/WRI034135
B. McGee
Cross Lake is a shallow, monomictic lake that was formed in 1926 by the impoundment of Cross Bayou. The lake is the primary drinking-water supply for the City of Shreveport, Louisiana. In recent years, the lakeshore has become increasingly urbanized. In addition, the land use of the watershed contributing runoff to Cross Lake has changed. Changes in land use and urbanization could affect the water chemistry and biology of the Lake. Water-quality data were collected at 10 sites on Cross Lake from February 1997 to February 1999. Water-column and bottom-material samples were collected. The water-column samples were collected at least four times per year. These samples analyzed included physical and chemical-related properties such as water temperature, dissolved oxygen, pH, and specific conductance; selected major inorganic ions; nutrients; minor elements; organic chemical constituents; and bacteria. Suspended-sediment samples were collected seven times during the sampling period. The bottom-material samples, which were collected once during the sampling period, were analyzed for selected minor elements and inorganic carbon. Aside from the nutrient-enriched condition of Cross Lake, the overall water-quality of Cross Lake is good. No primary Federal or State water-quality criteria were exceeded by any of the water-quality constituents analyzed for this report. Concentrations of major inorganic constituents, except iron and manganese, were low. Water from the lake is a sodium-bicarbonate type and is soft. Minor elements and organic compounds were present in low concentrations, many below detection limits. Nitrogen and phosphorus were the nutrients occurring in the highest concentrations. Nutrients were evenly distributed across the lake with no particular water-quality site indicating consistently higher or lower nutrient concentrations. No water samples analyzed for nitrate exceeded the U.S. Environmental Protection Agency’s Maximum Contaminant Level of 10 milligrams per liter. Based on nitrogen to phosphorus ratios calculated for Cross Lake, median values for all water-quality sites were within the nitrogen-limited range (less than or equal to 5). Historical Trophic State Indexes for Cross Lake classified the lake as eutrophic. Recent (1998-99) Trophic State Indexes classify Cross Lake as mesotrophic-eutrophic, which might indicate a reduction in eutrophication. Sedimentation traps indicate that Cross Lake is filling at an average rate of 0.41 inch per year. Concentrations of fecal-coliform and streptococci bacteria generally were low. Fecal coliform was detected in higher concentrations than fecal streptococci. High bacteria concentrations were measured shortly after rainfall-runoff events, possibly washing bacteria from surrounding areas into the lake.
克罗斯湖是一个浅的、单一的湖泊,是在1926年由克罗斯河口的蓄水形成的。这个湖是路易斯安那州什里夫波特市的主要饮用水来源。近年来,湖岸日益城市化。此外,向克罗斯湖提供径流的流域的土地利用也发生了变化。土地利用和城市化的变化会影响湖泊的水化学和生物。在1997年2月至1999年2月期间,收集了克罗斯湖10个地点的水质数据。采集水柱和底料样品。水柱样本每年至少收集四次。分析的这些样品包括物理和化学相关性质,如水温、溶解氧、pH值和比电导;选定的主要无机离子;营养物质;次要的元素;有机化学成分;和细菌。在采样期间共采集了7次悬浮沉积物样品。取样期间采集一次底料样品,对选定的微量元素和无机碳进行分析。除营养状况良好外,整体水质较好。本报告分析的任何水质成分均未超过联邦或州的主要水质标准。除铁和锰外,主要无机成分浓度较低。湖水是一种碳酸氢钠类型的软水。微量元素和有机化合物的浓度很低,许多低于检测极限。氮和磷是出现在最高浓度的养分。营养物均匀分布在整个湖泊,没有特定的水质点表明营养物浓度持续升高或降低。分析的水样中硝酸盐含量没有超过美国环境保护署规定的每升10毫克的最大污染物水平。根据Cross Lake计算的氮磷比,所有水质点的中位数都在氮限制范围内(小于或等于5)。Cross Lake的历史营养状态指数将湖泊划分为富营养化。最近(1998-99)的营养状态指数将横湖划分为中营养化-富营养化,这可能表明富营养化的减少。沉积圈闭表明克罗斯湖以平均每年0.41英寸的速度填满。粪大肠菌群和链球菌的浓度普遍较低。粪便大肠菌群的检测浓度高于粪便链球菌。在降雨径流事件发生后不久,检测到高浓度的细菌,可能是将周围地区的细菌冲入湖中。
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引用次数: 1
Estimating the magnitude of bankfull flows for streams in Idaho 估算爱达荷州河流的堤岸流量
Pub Date : 2004-01-01 DOI: 10.3133/WRI034261
J. E. Hortness, C. Berenbrock
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引用次数: 8
Environmental setting, water quality, and ecological indicators of surface-water quality in the Mermentau River Basin, southwestern Louisiana, 1998-2001 1998-2001年路易斯安那州西南部Mermentau河流域地表水环境、水质和生态指标
Pub Date : 2004-01-01 DOI: 10.3133/WRI034185
S. C. Skrobialowski, S. Mize, D. K. Demcheck
The U.S. Geological Survey collected data from 29 wells and 24 surface-water sites in the Mermentau River Basin, 1998-2001, to better understand ground-water and surface-water quality; aquatic invertebrate communities; and habitat conditions, in relation to land use. This study was a part of the National Water-Quality Assessment Program, which was designed to assess water quality as it relates to various land uses. Water-quality data were evaluated with criteria established for the protection of drinking water and aquatic life, and bed-sediment data were compared to aquatic-life criteria. Water-quality and ecological data were analyzed statistically in relation to drainage area and agricultural land-use intensity. Concentrations of nutrients and major inorganic ions in ground water and surface water generally were highest in the southeastern part of the study area where soils contain thick loess deposits. Peak concentrations of nutrients in surface water occurred March-May at two sites with high agricultural intensity; the lowest concentrations occurred August-January. The greatest potential for eutrophic conditions in surface water, based on nutrient concentrations, existed March-May, at about the same time or shortly after ricefields were drained. Secondary Maximum Contaminant Levels established by the U.S. Environmental Protection Agency (USEPA) were exceeded for sulfate, chloride, iron, or manganese in samples from 20 wells, and for iron or manganese in samples from all surface-water sites. Fewer pesticides were detected in ground water than in surface water. In 11 of the 29 wells sampled, at least one pesticide or pesticide degradation product was detected. The most frequently detected pesticides or pesticide degradation products in ground water were the herbicides bentazon and atrazine. Concentrations of 4 7 pesticides and degradation products were detected in surface water. At least 3 pesticides were detected in all surface-water samples. In 72 percent of the samples at least 5 hydrophylic pesticides were detected, and in more than 70 percent of the samples at least 3 hydrophobic pesticides were detected. Although atrazine concentrations in three samples collected in the spring exceeded 3 ~giL (micrograms per liter), the USEPA Maximum Contaminant Level of 3 ~giL was not exceeded because it is based on an annual average of quarterly samples. Concentrations larger than 3.0 ~giL were not detected in samples collected during other times of the year. Tebuthiuron was detected at all surface-water sites; the largest concentration (6.33 ~giL) was detected at a site on Bayou des Cannes, and was the only detection that exceeded the criterion (1.6 ~giL) for the protection of aquatic life. Malathion was detected at 16 surface-water sites; the largest concentration (0.113 ~giL) was detected at a site on Bayou Lacassine, and was the only detection that exceeded the criterion (0.1 ~giL) for the protection of aquatic life. Concentrations of fipronil excee
1998-2001年,美国地质调查局收集了Mermentau河流域29口井和24个地表水点的数据,以更好地了解地下水和地表水的质量;水生无脊椎动物群落;以及与土地利用有关的栖息地条件。这项研究是国家水质评估计划的一部分,该计划旨在评估与各种土地利用有关的水质。水质数据以保护饮用水和水生生物的标准进行评价,并将河床沉积物数据与水生生物标准进行比较。水质和生态数据与流域面积和农业土地利用强度的关系进行了统计分析。研究区东南部黄土沉积较厚,地下水和地表水中营养物质和主要无机离子浓度最高。地表水养分浓度峰值出现在农业强度高的2个地点;8 - 1月浓度最低。根据营养物浓度,地表水富营养化条件的最大可能性出现在3月至5月,大约同时或稻田排干后不久。20口井和所有地表水站点的样品中,硫酸盐、氯化物、铁或锰的含量均超过了美国环境保护署(USEPA)规定的二级最大污染物水平。地下水中检测到的农药少于地表水。在29口取样井中,有11口至少检测到一种农药或农药降解产物。地下水中最常检测到的农药或农药降解产物是除草剂苯达松和阿特拉津。在地表水中检测到47种农药及其降解产物的浓度。所有地表水样本均检出至少3种农药。在72%的样品中检测到至少5种亲水性农药,在70%以上的样品中检测到至少3种疏水性农药。虽然春季采集的三个样品中的阿特拉津浓度超过了3 ~giL(微克/升),但由于这是基于季度样本的年平均值,因此没有超过USEPA最大污染物水平3 ~giL。在一年中的其他时间采集的样品中未检测到大于3.0 ~giL的浓度。在所有地表水站点均检测到tebuthuron;在戛纳河的一个地点检测到最大的浓度(6.33 ~giL),是唯一超过水生生物保护标准(1.6 ~giL)的检测值。在16个地表水站点检测到马拉硫磷;拉卡辛河(Bayou Lacassine)的一个地点检测到的浓度最高(0.113 ~giL),是唯一超过水生生物保护标准(0.1 ~giL)的检测值。氟虫腈浓度在3个地点超过急性总最大日负荷(2.3 ~giL),在14个地点超过慢性总最大日负荷(4.6 ~giL)。地表水中农药浓度的最大值通常出现在春季大约同一时间或稻田排干后不久。两个地点的河床沉积物中DDE的浓度超过了保护水生生物的临时淡水沉积物质量准则。在收集河床沉积物样本的所有17个地点均检测到氟虫腈硫化物和脱硫基氟虫腈,但目前(2002年)尚无评估氟虫腈及其降解产物的环境影响的指导方针。采用两种方法对生态数据采集点进行分组:(1)数据采集前(根据研究设计)采用流域面积和农业土地利用强度对采集点进行分组;(2)数据采集后采用典型对应分析(CCA)和聚类分析(聚类分析)技术对采集点进行统计分组。以水生无脊椎动物群落作为地表水水质和生境条件的生态指标。CCA确定了四个重要的环境变量(河流覆盖评分、开放冠层百分比、溶解氧浓度和溶解氟虫腈的最大浓度),这些变量描述了生态数据收集点间水生无脊椎动物群落的分布。CCA的结果用于聚类分析,以确定具有相似水质、栖息地和水生无脊椎动物特征的四个站点组。比较研究设计(抽样前的先验)和cca指定(抽样后的后验)站点组内的环境变量和生物指标。 17个水质变量的中位数在研究区的北部地区最低,那里不到45%的流域面积用于水稻种植。11个水质变量的中位数在研究区东南部的站点最高,该站点用于水稻种植的流域面积百分比不同。浊度、总氨加有机氮、硝酸盐、总磷和溶解氟虫腈浓度的中位数在研究区的中北部地区最高。不同生态数据收集点之间水质差异的可能解释可能是:(1)一般土壤组成和排水特征的差异,以及(2)这些流域用于农业的土地百分比的差异。研究区南北部河流的生境特征包括河道的大小和形态、水的清澈度、开阔的冠层和底物等均存在差异。河流栖息地评级基于10个栖息地参数得分的总和,使用快速生物评估协议栖息地特征。随着栖息地质量的提高,得分也会增加。在19个生态数据收集点中,有16个的评分为次优(102-154)至最佳(155-200)。3个站点被评为边缘(49-101)。河道大小、河岸稳定性和池底的差异可能解释了不同农业强度的立地群之间水生无脊椎动物群落的差异。耐浊度、有机富集和低溶解氧浓度的生物在研究区很常见,并且在水生无脊椎动物群落中占主导地位。农业用地强度立地组和CCA立地组间水生无脊椎动物群落指标在(1)非昆虫比例、(2)蠓类群丰度、(3)取食类群丰度和(4)耐受生物数量方面存在显著差异(p ~ 0.05)。CCA位点组间优势度和多样性指标差异有统计学意义(p ~ 0.05)。在本报告中,溶解氟虫腈的最大浓度是与许多物种(特别是蠓)相对丰度持续下降有关的唯一重要环境变量。本报告中低物种丰度与氟虫腈降解产物浓度低于母体化合物氟虫腈有关。
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引用次数: 9
Relations between total-sediment load and peak discharge for rainstorm runoff on five ephemeral streams in Wyoming 怀俄明州5条河流暴雨径流的总输沙量与峰值流量的关系
Pub Date : 2004-01-01 DOI: 10.3133/WRI024150
J. G. Rankl
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引用次数: 18
Documentation of revisions to the regional aquifer system analysis model of the New Jersey coastal plain 新泽西州沿海平原区域含水层系统分析模型修订文件
Pub Date : 2004-01-01 DOI: 10.3133/WRI034268
L. M. Voronin
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引用次数: 9
期刊
Water-Resources Investigations Report
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