A curtained stormwater storage and treatment facility was constructed in Lake Storsjön (Sweden) to treat urban stormwater runoff discharges. Over two and a half years, sediments were sampled four times across four facility zones (from inlet to outlet) in two depths to inform facility operation and polluted sediment management. Sediments were analysed for particle size distribution, metals, polycyclic aromatic hydrocarbons, and organic matter content to assess the spatial distribution of deposited sediment characteristics. Finer sediments (<0.016 mm) prevailed near the outlet, with a higher presence of fine particles in the deeper layer (10-20 cm). Substantial variations in chemical concentrations were observed, differing by up to three orders of magnitude. Higher concentrations were consistently found in the inlet zone and deeper layers (10-20 cm depth) throughout the sampling program. Combined horizontal and vertical distributions of sediment characteristics indicated a predominance of historical deposits in the sediments collected. Frequent exceedances of Predicted No-Effect Concentrations of chemicals, particularly in the inlet zone, highlighted potential risks to the aquatic environment that would result from dredging activities. This underscores the importance of considering broad mitigation strategies, including the capping of contaminated sediment, to control the environmental impacts of contaminated sediments on the lake ecosystem.
{"title":"Characteristics of sediment deposited in a curtained stormwater storage and treatment facility located in the receiving water.","authors":"Haoyu Wei, Snezana Gavric, Annelie Hedström, Mehwish Taneez, Jiechen Wu, Jiri Marsalek, Maria Viklander","doi":"10.2166/wst.2025.144","DOIUrl":"https://doi.org/10.2166/wst.2025.144","url":null,"abstract":"<p><p>A curtained stormwater storage and treatment facility was constructed in Lake Storsjön (Sweden) to treat urban stormwater runoff discharges. Over two and a half years, sediments were sampled four times across four facility zones (from inlet to outlet) in two depths to inform facility operation and polluted sediment management. Sediments were analysed for particle size distribution, metals, polycyclic aromatic hydrocarbons, and organic matter content to assess the spatial distribution of deposited sediment characteristics. Finer sediments (<0.016 mm) prevailed near the outlet, with a higher presence of fine particles in the deeper layer (10-20 cm). Substantial variations in chemical concentrations were observed, differing by up to three orders of magnitude. Higher concentrations were consistently found in the inlet zone and deeper layers (10-20 cm depth) throughout the sampling program. Combined horizontal and vertical distributions of sediment characteristics indicated a predominance of historical deposits in the sediments collected. Frequent exceedances of Predicted No-Effect Concentrations of chemicals, particularly in the inlet zone, highlighted potential risks to the aquatic environment that would result from dredging activities. This underscores the importance of considering broad mitigation strategies, including the capping of contaminated sediment, to control the environmental impacts of contaminated sediments on the lake ecosystem.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 7","pages":"949-966"},"PeriodicalIF":2.6,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145293760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-01Epub Date: 2025-09-04DOI: 10.2166/wst.2025.131
Anna Cardova, Pavel Jenicek, Martin Srb, Petr Sykora, Jiri Rosicky, Lise Appels
Thermal hydrolysis (THP) combined with thermophilic anaerobic digestion (TAD) offers promising pathways for enhancing sewage sludge treatment. This study is among the first to directly compare THP as both pre- and post-treatment options for TAD. Pre-treatment of waste activated sludge (THP-WAS) and post-treatment of digested sludge (THP-DS) were evaluated on their impacts on process stability, biogas production, and sludge dewaterability. Pilot-scale trials at a wastewater treatment plant (WWTP) in Prague revealed that THP-WAS increased sludge solubilization but faced challenges such as volatile fatty acid accumulation, adversely affecting reactor stability and specific biogas yield. In contrast, THP-DS enhanced biogas production by 10%, improved sludge dewaterability, and achieved superior methane content (73.2%). Further research is needed to optimize THP parameters for reactor stability and to better understand interactions between hydrolyzed WAS and primary sludge.
{"title":"Intensification of thermophilic anaerobic digestion of sewage sludge by thermal hydrolysis.","authors":"Anna Cardova, Pavel Jenicek, Martin Srb, Petr Sykora, Jiri Rosicky, Lise Appels","doi":"10.2166/wst.2025.131","DOIUrl":"https://doi.org/10.2166/wst.2025.131","url":null,"abstract":"<p><p>Thermal hydrolysis (THP) combined with thermophilic anaerobic digestion (TAD) offers promising pathways for enhancing sewage sludge treatment. This study is among the first to directly compare THP as both pre- and post-treatment options for TAD. Pre-treatment of waste activated sludge (THP-WAS) and post-treatment of digested sludge (THP-DS) were evaluated on their impacts on process stability, biogas production, and sludge dewaterability. Pilot-scale trials at a wastewater treatment plant (WWTP) in Prague revealed that THP-WAS increased sludge solubilization but faced challenges such as volatile fatty acid accumulation, adversely affecting reactor stability and specific biogas yield. In contrast, THP-DS enhanced biogas production by 10%, improved sludge dewaterability, and achieved superior methane content (73.2%). Further research is needed to optimize THP parameters for reactor stability and to better understand interactions between hydrolyzed WAS and primary sludge.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 6","pages":"843-855"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145201741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Industrial activities generate significant volumes of wastewater with various heavy metals, suspended solids, oils, tannins, toxic chemicals, organic and inorganic compounds, often with elevated biochemical oxygen demand (BOD) and chemical oxygen demand (COD) levels. This study mainly focuses on providing an in-depth review of the characteristics of effluents, available treatment processes, and regulatory frameworks for managing five common commodity manufacturing industry effluents (textile, pulp and paper, dye, leather, and rice mill). All these manufacturing industries consume large amounts of water and subsequently produce tons of effluents. Direct disposal of these effluents in the open environment poses potential hazards to the environment and human health and requires mitigation before discharge. Different conventional technologies are available to treat these effluents, which are associated with certain merits and demerits and highlighted here. The review also emphasized the most frequently applied process technologies to reduce BOD and COD load from the effluents of particular industries, with their limitations. Therefore, assessing economically viable and sustainable wastewater treatment approaches is crucial. It is concluded that conducting cost-benefit analysis in terms of BOD and COD removal efficiency and life cycle assessment is a must to select the most economical and sustainable solutions for the existence of any technology.
{"title":"Technologies accessible for major commodity manufacturing industries to mitigate effluents: a comprehensive review to emphasize the disparity between efficiency and life cycle of the process.","authors":"Puja Paramanik, Kulbhushan Samal, Swarup Ranjan Debbarma","doi":"10.2166/wst.2025.132","DOIUrl":"https://doi.org/10.2166/wst.2025.132","url":null,"abstract":"<p><p>Industrial activities generate significant volumes of wastewater with various heavy metals, suspended solids, oils, tannins, toxic chemicals, organic and inorganic compounds, often with elevated biochemical oxygen demand (BOD) and chemical oxygen demand (COD) levels. This study mainly focuses on providing an in-depth review of the characteristics of effluents, available treatment processes, and regulatory frameworks for managing five common commodity manufacturing industry effluents (textile, pulp and paper, dye, leather, and rice mill). All these manufacturing industries consume large amounts of water and subsequently produce tons of effluents. Direct disposal of these effluents in the open environment poses potential hazards to the environment and human health and requires mitigation before discharge. Different conventional technologies are available to treat these effluents, which are associated with certain merits and demerits and highlighted here. The review also emphasized the most frequently applied process technologies to reduce BOD and COD load from the effluents of particular industries, with their limitations. Therefore, assessing economically viable and sustainable wastewater treatment approaches is crucial. It is concluded that conducting cost-benefit analysis in terms of BOD and COD removal efficiency and life cycle assessment is a must to select the most economical and sustainable solutions for the existence of any technology.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 6","pages":"856-878"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145201671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-01Epub Date: 2025-09-09DOI: 10.2166/wst.2025.136
Xiao Xu, Thomas Dockhorn, Sören Hornig, Tim Gebhardt
Thermal hydrolysis process (THP) can break down sludge structures and enhance organic solubilization into the liquid fraction. Separately treating liquid and solid fractions could benefit energy and material balances. In this study, five primary sludges (PSs) and seven waste activated sludges (WASs) were treated with thermal alkaline process (TAP) (160 °C, 30 min, pH 9-12), followed by centrifugation for liquid and solid separation. The liquid fractions of PSs after TAP yielded 348 ± 66 L/kg CODadded of biogas. They produced up to 29 ± 7% of the biogas from hydrolysates. In contrast, the liquid fraction of WASs after TAP yielded 395 ± 34 L/kg CODadded of biogas and produced up to 77 ± 4% of the biogas from hydrolysates. Additionally, the dewaterability of WAS increased by about 54%, while the dewaterability of PS decreased by roughly 48% after thermal treatment. With digestion of the liquid fraction and disposal of the solid fraction in WAS treatment with TAP at pH 11, biogas production increased by 4%, and the discharged sludge volume decreased by 10%. Although net electricity generation decreased by 22%, the digester volume could be reduced by 90%, allowing for more capacity for co-substrate digestion in WWTPs.
{"title":"Separate treatment of liquid and solid fractions derived from thermally alkaline-treated sewage sludge: impact on energy and material balance in sludge processing.","authors":"Xiao Xu, Thomas Dockhorn, Sören Hornig, Tim Gebhardt","doi":"10.2166/wst.2025.136","DOIUrl":"https://doi.org/10.2166/wst.2025.136","url":null,"abstract":"<p><p>Thermal hydrolysis process (THP) can break down sludge structures and enhance organic solubilization into the liquid fraction. Separately treating liquid and solid fractions could benefit energy and material balances. In this study, five primary sludges (PSs) and seven waste activated sludges (WASs) were treated with thermal alkaline process (TAP) (160 °C, 30 min, pH 9-12), followed by centrifugation for liquid and solid separation. The liquid fractions of PSs after TAP yielded 348 ± 66 L/kg COD<sub>added</sub> of biogas. They produced up to 29 ± 7% of the biogas from hydrolysates. In contrast, the liquid fraction of WASs after TAP yielded 395 ± 34 L/kg COD<sub>added</sub> of biogas and produced up to 77 ± 4% of the biogas from hydrolysates. Additionally, the dewaterability of WAS increased by about 54%, while the dewaterability of PS decreased by roughly 48% after thermal treatment. With digestion of the liquid fraction and disposal of the solid fraction in WAS treatment with TAP at pH 11, biogas production increased by 4%, and the discharged sludge volume decreased by 10%. Although net electricity generation decreased by 22%, the digester volume could be reduced by 90%, allowing for more capacity for co-substrate digestion in WWTPs.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 6","pages":"903-918"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145201692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-01Epub Date: 2025-09-17DOI: 10.2166/wst.2025.138
Liming Liu, Ping Han, Jin Wang, Sun Xiuqin, Geng Xu, Lin Wang, Ruiting Liu, Xue Shen, Feiyong Chen
With the development of human civilization and the rapid progress of urbanization, the water environment and aquatic ecology need more systematic treatment to support the construction of ecological civilization and sustainable development. Based on a large number of research results and from the four dimensions including governance concept, governance technology, management and control platform and engineering strategy suggestions, this study systematically analysed the cutting-edge concepts such as reverse-driven governance, explored the application of key technologies such as remote sensing in the water environment and water ecological governance, put forward strategic suggestions on building an intelligent analysis and decision-making platform and avoiding great leap forward-style vanity projects in the water environment and aquatic ecology governance. Finally, six cutting-edge governance concepts, four key technologies, two types of governance and control platforms and two engineering strategies were sorted out and formed a governance system covering concept guidance, technical support, platform integration and application, and engineering strategy guarantee. The research enriches the theory of the water environment and aquatic ecology governance, and has important reference value for policy-making and engineering practice of watershed water environment and aquatic ecology governance.
{"title":"Approaches to the water environment and aquatic ecology governance in basin systems.","authors":"Liming Liu, Ping Han, Jin Wang, Sun Xiuqin, Geng Xu, Lin Wang, Ruiting Liu, Xue Shen, Feiyong Chen","doi":"10.2166/wst.2025.138","DOIUrl":"https://doi.org/10.2166/wst.2025.138","url":null,"abstract":"<p><p>With the development of human civilization and the rapid progress of urbanization, the water environment and aquatic ecology need more systematic treatment to support the construction of ecological civilization and sustainable development. Based on a large number of research results and from the four dimensions including governance concept, governance technology, management and control platform and engineering strategy suggestions, this study systematically analysed the cutting-edge concepts such as reverse-driven governance, explored the application of key technologies such as remote sensing in the water environment and water ecological governance, put forward strategic suggestions on building an intelligent analysis and decision-making platform and avoiding great leap forward-style vanity projects in the water environment and aquatic ecology governance. Finally, six cutting-edge governance concepts, four key technologies, two types of governance and control platforms and two engineering strategies were sorted out and formed a governance system covering concept guidance, technical support, platform integration and application, and engineering strategy guarantee. The research enriches the theory of the water environment and aquatic ecology governance, and has important reference value for policy-making and engineering practice of watershed water environment and aquatic ecology governance.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 6","pages":"894-902"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145201755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-01Epub Date: 2025-08-29DOI: 10.2166/wst.2025.130
Allison N Patrick, Kay Bernard, R Andrew Tirpak, Ian M Simpson, Joseph S Smith, Ryan J Winston
Bioretention cells (BRCs) are among the most popular low-impact development techniques in the United States. They effectively mitigate the runoff hydrograph and excessive pollutant loadings affected by widespread urbanization. Overwhelmingly, the literature focuses on the effectiveness of newly constructed BRCs and does not account for the variety of designs found in BRCs installed less recently. The objective of this study was to evaluate the efficacy of a BRC in mitigating runoff quantity, reducing peak flow rate, and improving water quality parameters (i.e., sediment, nutrients, heavy metals, and indicator bacteria) 8 years post-construction. Total runoff volume reduction was substantial (83%), accredited to mature vegetation promoting evapotranspiration, canopy interception, and hydraulic properties of the mature BRC soil. Additionally, the BRC provided similar peak flow mitigation (median 93%) to newly constructed BRCs in the literature. Significant reductions in event mean concentrations and loads of sediments (>88%), particulate-bound nutrients (>60%), and heavy metals (>70%) were observed. In many cases, the BRC had better - or at least similar - pollutant removal efficiencies than younger BRCs. The excellent function of this BRC provides evidence that these systems may improve over time, given proper long-term maintenance.
{"title":"Hydrologic and water quality performance of an 8-year old bioretention cell treating residential runoff.","authors":"Allison N Patrick, Kay Bernard, R Andrew Tirpak, Ian M Simpson, Joseph S Smith, Ryan J Winston","doi":"10.2166/wst.2025.130","DOIUrl":"10.2166/wst.2025.130","url":null,"abstract":"<p><p>Bioretention cells (BRCs) are among the most popular low-impact development techniques in the United States. They effectively mitigate the runoff hydrograph and excessive pollutant loadings affected by widespread urbanization. Overwhelmingly, the literature focuses on the effectiveness of newly constructed BRCs and does not account for the variety of designs found in BRCs installed less recently. The objective of this study was to evaluate the efficacy of a BRC in mitigating runoff quantity, reducing peak flow rate, and improving water quality parameters (i.e., sediment, nutrients, heavy metals, and indicator bacteria) 8 years post-construction. Total runoff volume reduction was substantial (83%), accredited to mature vegetation promoting evapotranspiration, canopy interception, and hydraulic properties of the mature BRC soil. Additionally, the BRC provided similar peak flow mitigation (median 93%) to newly constructed BRCs in the literature. Significant reductions in event mean concentrations and loads of sediments (>88%), particulate-bound nutrients (>60%), and heavy metals (>70%) were observed. In many cases, the BRC had better - or at least similar - pollutant removal efficiencies than younger BRCs. The excellent function of this BRC provides evidence that these systems may improve over time, given proper long-term maintenance.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 5","pages":"752-769"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145064842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-01Epub Date: 2025-08-28DOI: 10.2166/wst.2025.078
Bhavya T R, Ananta Vashisth, P Krishnan, Monika Kundu, Shiv Prasad, Achal Lama
Weather parameters that influence evapotranspiration are air temperature, solar radiation, relative humidity and wind speed. Daily weather data during the wheat-growing period were collected from 1970 to 2018 for the Amritsar district of Punjab state in India. To improve evapotranspiration estimation, a well-defined area of artificial intelligence called machine learning is used. To improve the accuracy of evapotranspiration estimation during the wheat-growing period, a model was developed by random forest (RF), support vector machine (SVM) and artificial neural network (ANN) using different weather input combinations. Based on the evaluation done using various standard statistical criteria during calibration and validation performance of RF was found to be best, followed by SVM and ANN. The model developed by (Tmax, Tmin, RHM, RHE and Rs) weather input combination was ranked first. Two weather input combinations (Rs, Tmax) and (Rs, Tmin) performed excellently by RF and SVM, while the weather input combination (Tmax, Tmin) performed excellently by the ANN. Hence, these input combinations can be used in the estimation of evapotranspiration when the availability of data is limited. From this study, it can be concluded that instead of a large amount of weather data, ET0 estimation can be done with a few data points by the machine learning technique.
{"title":"Estimating reference evapotranspiration using a machine learning approach.","authors":"Bhavya T R, Ananta Vashisth, P Krishnan, Monika Kundu, Shiv Prasad, Achal Lama","doi":"10.2166/wst.2025.078","DOIUrl":"https://doi.org/10.2166/wst.2025.078","url":null,"abstract":"<p><p>Weather parameters that influence evapotranspiration are air temperature, solar radiation, relative humidity and wind speed. Daily weather data during the wheat-growing period were collected from 1970 to 2018 for the Amritsar district of Punjab state in India. To improve evapotranspiration estimation, a well-defined area of artificial intelligence called machine learning is used. To improve the accuracy of evapotranspiration estimation during the wheat-growing period, a model was developed by random forest (RF), support vector machine (SVM) and artificial neural network (ANN) using different weather input combinations. Based on the evaluation done using various standard statistical criteria during calibration and validation performance of RF was found to be best, followed by SVM and ANN. The model developed by (<i>T</i><sub>max</sub>, <i>T</i><sub>min</sub>, RHM, RHE and <i>R</i><sub>s</sub>) weather input combination was ranked first. Two weather input combinations (<i>R</i><sub>s</sub>, <i>T</i><sub>max</sub>) and (<i>R</i><sub>s</sub>, <i>T</i><sub>min</sub>) performed excellently by RF and SVM, while the weather input combination (<i>T</i><sub>max</sub>, <i>T</i><sub>min</sub>) performed excellently by the ANN. Hence, these input combinations can be used in the estimation of evapotranspiration when the availability of data is limited. From this study, it can be concluded that instead of a large amount of weather data, ET<sub>0</sub> estimation can be done with a few data points by the machine learning technique.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 6","pages":"819-842"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145201725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-01Epub Date: 2025-09-11DOI: 10.2166/wst.2025.133
Grace L Wilson, John A Chapman, Jacques C Finlay, Lawrence A Baker
Gross solid materials carried in stormwater runoff can obstruct stormwater systems and transport nutrients and other pollutants to waterways. To characterize key drivers of the mass of gross solid delivered to stormwater systems and the amount of total phosphorus (TP) contributed by these solids, we collected these materials from the inlets of 13 stormwater control measures (SCMs) located in the Minneapolis - St. Paul metropolitan region in Minnesota, USA. Samples were collected from sampler devices during the years 2021-2022. Dry mass and mass organic matter (OM) were measured for all 420 samples collected, and 35% of all samples were analyzed for TP. A regression equation was developed to estimate TP mass for all samples based on measured OM. Additional analysis was performed to determine statistically significant factors that predicted the mass of gross solid material collected at each SCM. Annual dry mass, mass OM, and mass TP of the gross solid materials ranged from 6.1 to 76.9, 1.9 to 45.4, and 0.004 to 0.119 kg yr-1, respectively. The tree canopy area over the street was the best predictor of the annual dry mass, OM mass, and TP mass delivered at the SCMs, with R2 values of 0.44, 0.47, and 0.5, respectively.
雨水径流携带的总固体物质会阻碍雨水系统,并将营养物质和其他污染物输送到水道。为了表征输送到雨水系统的总固体质量和这些固体贡献的总磷(TP)量的关键驱动因素,我们从位于美国明尼苏达州明尼阿波利斯-圣保罗大都会区的13个雨水控制措施(scm)的入水口收集了这些材料。样本采集于2021-2022年间。对采集的420份样品进行干质量和质量有机质(OM)测定,对35%的样品进行TP分析。建立了一个回归方程,根据测量的OM估计所有样品的TP质量。进行了额外的分析,以确定预测在每个SCM收集的总固体物质质量的统计显著因素。总固体物质的年干质量、OM质量和TP质量分别为6.1 ~ 76.9、1.9 ~ 45.4和0.004 ~ 0.119 kg -1。街道上的树冠面积最能预测土壤年干质量、有机质质量和总TP质量,R2分别为0.44、0.47和0.5。
{"title":"Characterization and prediction of gross solids mass, organic matter, and total phosphorus in urban stormwater.","authors":"Grace L Wilson, John A Chapman, Jacques C Finlay, Lawrence A Baker","doi":"10.2166/wst.2025.133","DOIUrl":"https://doi.org/10.2166/wst.2025.133","url":null,"abstract":"<p><p>Gross solid materials carried in stormwater runoff can obstruct stormwater systems and transport nutrients and other pollutants to waterways. To characterize key drivers of the mass of gross solid delivered to stormwater systems and the amount of total phosphorus (TP) contributed by these solids, we collected these materials from the inlets of 13 stormwater control measures (SCMs) located in the Minneapolis - St. Paul metropolitan region in Minnesota, USA. Samples were collected from sampler devices during the years 2021-2022. Dry mass and mass organic matter (OM) were measured for all 420 samples collected, and 35% of all samples were analyzed for TP. A regression equation was developed to estimate TP mass for all samples based on measured OM. Additional analysis was performed to determine statistically significant factors that predicted the mass of gross solid material collected at each SCM. Annual dry mass, mass OM, and mass TP of the gross solid materials ranged from 6.1 to 76.9, 1.9 to 45.4, and 0.004 to 0.119 kg yr<sup>-1</sup>, respectively. The tree canopy area over the street was the best predictor of the annual dry mass, OM mass, and TP mass delivered at the SCMs, with <i>R</i><sup>2</sup> values of 0.44, 0.47, and 0.5, respectively.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 6","pages":"879-893"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145201735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anaerobic co-digestion (AnCoD) presents a promising route for valorizing sludge generated from recycled paper processing. This study explored the co-digestion of primary sludge (PS) and secondary sludge (SS) at various mixing ratios to enhance methane generation and system stability. Batch biochemical methane potential (BMP) assays revealed that the 1:3 PS:SS ratio produced the highest methane yield (918.66 mL CH4/g VS_fed) with a notably short lag phase of 1.59 days. Kinetic assessment using both modified Gompertz and logistic models indicated that the former offered superior fitting accuracy (R2 > 0.986), effectively describing methane production dynamics. A two-stage continuous stirred-tank reactor (CSTR) system operated under this optimal ratio showed distinct functional separation: the acidogenic stage facilitated hydrolysis and volatile fatty acid (VFA) degradation, while the methanogenic stage supported biogas generation with stable pH and low VFA/alkalinity ratios. Microbial analysis confirmed a clear differentiation between fermentative and methanogenic communities, with evidence suggesting enhanced electron transfer pathways. These findings underscore the potential of AnCoD for efficient sludge stabilization and bioenergy recovery in the pulp and paper sector.
厌氧共消化(AnCoD)是一种很有前途的处理废纸污泥的方法。本研究探讨了不同混合比例的一次污泥(PS)和二次污泥(SS)的共消化,以提高甲烷的生成和系统的稳定性。批量生化甲烷势(BMP)测定结果表明,当PS:SS比为1:3时,甲烷产率最高(918.66 mL CH4/g VS_fed),滞后期较短,为1.59 d。采用修正的Gompertz模型和logistic模型进行动力学评价表明,修正的Gompertz模型具有较高的拟合精度(R2 > 0.986),能够有效地描述甲烷生产动态。在此最佳配比下运行的两级连续搅拌槽反应器(CSTR)系统显示出明显的功能分离:产酸阶段促进水解和挥发性脂肪酸(VFA)降解,而产甲烷阶段支持稳定pH和低VFA/碱度比的沼气生成。微生物分析证实了发酵菌群和产甲烷菌群之间的明显差异,有证据表明电子转移途径增强。这些发现强调了AnCoD在纸浆和造纸行业高效污泥稳定和生物能源回收方面的潜力。
{"title":"Feasibility of anaerobic co-digestion for biogas production from recycled paper industry sludge: optimization of mixing ratios and application in two-stage CSTR system design.","authors":"Boonsita Nammana, Patcharin Racho, Siriwan Nawong, Boonchai Wichitsathian, Kraichat Tantrakarnapa","doi":"10.2166/wst.2025.118","DOIUrl":"10.2166/wst.2025.118","url":null,"abstract":"<p><p>Anaerobic co-digestion (AnCoD) presents a promising route for valorizing sludge generated from recycled paper processing. This study explored the co-digestion of primary sludge (PS) and secondary sludge (SS) at various mixing ratios to enhance methane generation and system stability. Batch biochemical methane potential (BMP) assays revealed that the 1:3 PS:SS ratio produced the highest methane yield (918.66 mL CH<sub>4</sub>/g VS_fed) with a notably short lag phase of 1.59 days. Kinetic assessment using both modified Gompertz and logistic models indicated that the former offered superior fitting accuracy (<i>R</i><sup>2</sup> > 0.986), effectively describing methane production dynamics. A two-stage continuous stirred-tank reactor (CSTR) system operated under this optimal ratio showed distinct functional separation: the acidogenic stage facilitated hydrolysis and volatile fatty acid (VFA) degradation, while the methanogenic stage supported biogas generation with stable pH and low VFA/alkalinity ratios. Microbial analysis confirmed a clear differentiation between fermentative and methanogenic communities, with evidence suggesting enhanced electron transfer pathways. These findings underscore the potential of AnCoD for efficient sludge stabilization and bioenergy recovery in the pulp and paper sector.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 5","pages":"683-703"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145065850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-01Epub Date: 2025-08-28DOI: 10.2166/wst.2025.129
Mingda Li, Mengfei Li, Xin Li
The recovery and utilization of phosphorus elements from biogas slurry can effectively prevent secondary pollution caused by biogas slurry application in farmland and eutrophication of water bodies. This study systematically evaluated the adsorption efficiency of soluble P from biogas slurry using biochars (corn straw biochar (CSB), cherry wood biochar (CWB), and cattle manure biochar (CMB)) and biomass power plant residues ash (BPP-ash) and slag (BPP-slag). Physicochemical characterization revealed that BPP-slag exhibited the highest soluble P removal efficiency (92.17%) at 30 g L-1 dosage, attributed to its high metal oxide content (e.g., Ca2+, Mg2+). Kinetic and isotherm analyses indicated that adsorption followed pseudo-second-order kinetics (R2 > 0.96) and Freundlich models (R2 > 0.98), suggesting chemisorption-dominated multilayer adsorption. Mineral precipitation (contributing >70% to total adsorption) was identified as the primary mechanism via XRD and quantitative analysis. This work highlights the potential of biomass power plant residues as cost-effective adsorbents for P capturing, offering a sustainable strategy for waste valorization.
沼液中磷元素的回收利用可以有效防止沼液在农田施用造成的二次污染和水体富营养化。采用生物炭(玉米秸秆生物炭(CSB)、樱桃木生物炭(CWB)、牛粪生物炭(CMB)和生物质电厂残灰(BPP-ash)、炉渣(bpp -渣)对沼液中可溶性磷的吸附效果进行了系统评价。理化性质分析表明,在30 g L-1投加量下,bpp渣中Ca2+、Mg2+等金属氧化物的含量较高,对可溶性磷的去除率最高(92.17%)。动力学和等温线分析表明,吸附符合拟二级动力学(R2 > 0.96)和Freundlich模型(R2 > 0.98),表明化学吸附为主的多层吸附。通过XRD和定量分析,确定矿物沉淀为主要吸附机理,对吸附总量的贡献率为70%。这项工作强调了生物质发电厂残留物作为P捕获的成本效益吸附剂的潜力,为废物增值提供了可持续的策略。
{"title":"Phosphorus capturing from biogas slurry using different adsorbents: adsorption and mechanism.","authors":"Mingda Li, Mengfei Li, Xin Li","doi":"10.2166/wst.2025.129","DOIUrl":"10.2166/wst.2025.129","url":null,"abstract":"<p><p>The recovery and utilization of phosphorus elements from biogas slurry can effectively prevent secondary pollution caused by biogas slurry application in farmland and eutrophication of water bodies. This study systematically evaluated the adsorption efficiency of soluble P from biogas slurry using biochars (corn straw biochar (CSB), cherry wood biochar (CWB), and cattle manure biochar (CMB)) and biomass power plant residues ash (BPP-ash) and slag (BPP-slag). Physicochemical characterization revealed that BPP-slag exhibited the highest soluble P removal efficiency (92.17%) at 30 g L<sup>-1</sup> dosage, attributed to its high metal oxide content (e.g., Ca<sup>2+</sup>, Mg<sup>2+</sup>). Kinetic and isotherm analyses indicated that adsorption followed pseudo-second-order kinetics (<i>R</i><sup>2</sup> > 0.96) and Freundlich models (<i>R</i><sup>2</sup> > 0.98), suggesting chemisorption-dominated multilayer adsorption. Mineral precipitation (contributing >70% to total adsorption) was identified as the primary mechanism via XRD and quantitative analysis. This work highlights the potential of biomass power plant residues as cost-effective adsorbents for P capturing, offering a sustainable strategy for waste valorization.</p>","PeriodicalId":23653,"journal":{"name":"Water Science and Technology","volume":"92 5","pages":"770-784"},"PeriodicalIF":2.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145065387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}