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A review on adsorbent parameters for removal of dye products from industrial wastewater 工业废水中染料产物的吸附剂参数研究进展
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-10-07 DOI: 10.2166/wqrj.2021.023
A. Soltani, M. Faramarzi, Seyed Aboutaleb, Mousavi Parsa
Industrial effluents are usually one of the major industries polluting the environment and surface water. It is estimated that the worldwide production of dyes is about 70 tons/year. To overcome this problem, innovative processes are suggested for the treatment of industrial effluents containing dyes and heavy metals. The goal of the processes is often to reduce the toxicity of these pollutants in order to meet treatment standards. Recently, great attention has been paid to innovative processes for physical and chemical removal techniques such as adsorption on new adsorbents, biomass adsorption, membrane filtration, irradiation, and electrochemical coagulation. In this study, the application of adsorbents in the adsorption process to remove dye pollutants from industrial effluents has been studied. Factors affecting dye adsorption such as pH, temperature, initial dye concentration, and adsorbent amount are also presented. The obtained results revealed that more than 80% of the dye adsorption on the surface of adsorbents are endothermic processes and more than 95% of the processes obey the pseudo-second-order kinetic model.
工业废水通常是污染环境和地表水的主要行业之一。据估计,全球染料产量约为70吨/年。为了克服这个问题,建议采用创新工艺处理含有染料和重金属的工业废水。工艺的目标通常是降低这些污染物的毒性,以达到处理标准。近年来,物理和化学去除技术的创新工艺受到了极大的关注,如新型吸附剂吸附、生物质吸附、膜过滤、辐照和电化学混凝。本研究研究了吸附剂在去除工业废水中染料污染物的吸附过程中的应用。还介绍了影响染料吸附的因素,如pH、温度、染料初始浓度和吸附剂用量。结果表明,吸附剂表面80%以上的染料吸附是吸热过程,95%以上的吸附过程服从拟二阶动力学模型。
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引用次数: 30
Predicting water quality trends resulting from forest cover change in an agriculturally dominated river basin in Eastern Ontario, Canada 加拿大安大略省东部以农业为主的河流流域森林覆盖变化导致的水质趋势预测
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-09-17 DOI: 10.2166/wqrj.2021.010
M. Noteboom, O. Seidou, D. Lapen
Agricultural extensification and forest cover loss can significantly impact aquatic ecosystems. This study considered the conversion of forests to agriculture (and vice versa) in an agriculturally dominated watershed in Eastern Ontario, Canada. A series of de- and reforestation scenarios were developed, and water quantity/quality simulations were executed using the Soil and Water Assessment Tool (SWAT) using 30 years of real-world weather observations. Results indicated that streamflow and sediment loads were not sensitive to forest loss, while continuing the recent rate of deforestation of 0.8% (0.2% of the watershed area) per year would, by 2032, increase annual loads of nitrate by 5.6%, total nitrogen by 1.5%, and total phosphorus by 6.8%. Additionally, the same land-use scenarios were simulated with the inclusion of vegetated filter strips (VFS) and grassed waterways. Some reforestation scenarios were sufficient to reduce total nitrogen concentrations below water quality guidelines, particularly under the combined effect of VFSs along all river reaches. However, meeting water quality guidelines for total phosphorus concentrations requires additional improvements to management practices beyond those simulated here.
农业扩张和森林覆盖的减少会对水生生态系统产生重大影响。这项研究考虑了加拿大安大略省东部一个以农业为主的流域的森林向农业的转变(反之亦然)。开发了一系列的去森林和重新造林情景,并使用土壤和水评估工具(SWAT)使用30年的真实世界天气观测进行了水量/质量模拟。结果表明,径流和泥沙负荷对森林损失不敏感,而到2032年,继续以每年0.8%(流域面积的0.2%)的近期森林砍伐率,硝酸盐的年负荷将增加5.6%,总氮增加1.5%,总磷增加6.8%。此外,模拟了相同的土地利用场景,包括植被过滤带(VFS)和草地水道。一些重新造林的情景足以将总氮浓度降低到水质准则以下,特别是在所有河段的VFS的综合影响下。然而,要达到总磷浓度的水质指南,除了这里模拟的管理实践之外,还需要对管理实践进行额外的改进。
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引用次数: 2
Emerging pollutants and antibiotics removed by conventional activated sludge followed by ultraviolet radiation in a municipal wastewater treatment plant in Mexico 墨西哥城市污水处理厂采用常规活性污泥和紫外线辐射去除新出现的污染物和抗生素
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-08-01 DOI: 10.2166/wqrj.2021.013
Ángeles Martínez-Orgániz, J. E. Bravo, M. Llompart, T. Dagnac, J. Pablo Lamas, Lua Vazquez, L. Sampedro-Rosas
Different groups of emerging pollutants (EPs) were identified (drugs, pesticides, hormones, illicit drugs, and fire retardant), and the removal of four antibiotics was determined (sulfamethoxazole 62.2–94.4%, ciprofloxacin 71–83.1%, norfloxacin 82–89%, and ofloxacin 78–97.9%) in a municipal wastewater treatment plant (WWTP) in Acapulco, Gro. Mexico. The compounds were extracted from influent and effluent samples by solid phase extraction (SPE). The identification of non-target EPs was performed by liquid chromatography coupled with high-resolution mass spectrometry (LC-HRMS). The antibiotic quantification was performed by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). Most of the non-target compounds were detected only in the influent samples. Antibiotics levofloxacin and nalidixic acid, the anticonvulsants carbamazepine and oxycarbamazepine, the local anesthetic lidocaine, and the pesticide tridemorph were the main EPs not removed by the WWTP. In this study, it was shown that the Aguas Blancas WWTP does not manage to remove 100% of the various EPs identified in the effluent, although the elimination degree is high in most cases, despite being one of the model plants in Mexico.
在Gro Acapulco市某城市污水处理厂(WWTP)中,确定了不同类别的新兴污染物(药物、农药、激素、非法药物和阻燃剂),并测定了4种抗生素(磺胺甲恶唑62.2-94.4%、环丙沙星71-83.1%、诺氟沙星82-89%和氧氟沙星78-97.9%)的去除率。墨西哥。采用固相萃取法(SPE)从进水和出水样品中提取化合物。采用液相色谱-高分辨率质谱法(LC-HRMS)对非目标EPs进行鉴定。采用液相色谱-串联质谱法(LC-MS/MS)对抗生素进行定量分析。大多数非目标化合物仅在进水样品中检测到。抗生素左氧氟沙星和钠利地酸、抗惊厥药卡马西平和氧卡马西平、局麻药利多卡因和农药三毒霉是未被污水处理厂去除的主要EPs。在本研究中,研究表明,Aguas Blancas污水处理厂并不能100%去除废水中发现的各种EPs,尽管在大多数情况下消除程度很高,尽管它是墨西哥的模式工厂之一。
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引用次数: 7
Evaluation of Yangon city tap water quality and the efficacy of household treatment 仰光市自来水水质及家庭处理效果评价
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-07-29 DOI: 10.2166/wqrj.2021.006
Shane Htet Ko, H. Sakai
Yangon was one of the first cities in Asia to establish a tap water system. However, the city's water supply infrastructure now lags far behind those of other regions as a consequence of political instability over the last six decades. The installation of disinfection facilities in the tap water system and the enactment of the Myanmar National Drinking Water Quality Standard (MNDWQS) were accomplished only recently during the short period of democratic government. Due to the lack of reliable published information, the suitability of the tap water for drinking remains unclear to city residents. The quality of tap water and bottled water in the central business district was examined to assess compliance with the MNDWQS. The results showed that 95% of tap water delivered to homes was contaminated with Escherichia coli or coliform bacteria. Only 14% of bottled water was free of E. coli and coliform contamination. The efficacy of household treatment devices was tested, and ceramic purifiers (CPs) and reverse osmosis (RO) devices were found to be highly (>99%) effective for E. coli elimination. RO devices performed better in terms of dissolved organic carbon reduction at 60% compared with 43% reduction with CPs.
仰光是亚洲最早建立自来水系统的城市之一。然而,由于过去60年的政治不稳定,该市的供水基础设施现在远远落后于其他地区。在自来水系统中安装消毒设施和颁布缅甸国家饮用水质量标准(MNDWQS)直到最近才在民主政府的短暂时期内完成。由于缺乏可靠的公开信息,城市居民仍然不清楚自来水是否适合饮用。我们检查了中央商务区的自来水和瓶装水的水质,以评估它们是否符合《城市污水质量标准》。结果显示,95%的自来水被大肠杆菌或大肠菌群污染。只有14%的瓶装水没有大肠杆菌和大肠菌群污染。对家用处理装置的效果进行了测试,发现陶瓷净化器(CPs)和反渗透(RO)装置对大肠杆菌的清除效果很高(>99%)。RO装置在溶解有机碳减少方面表现更好,减少60%,而CPs减少43%。
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引用次数: 5
A genetic algorithm-based support vector machine to estimate the transverse mixing coefficient in streams 基于遗传算法的支持向量机估计河流横向混合系数
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-07-09 DOI: 10.2166/wqrj.2021.003
Hosein Nezaratian, J. Zahiri, Mohammad Fatehi Peykani, A. Haghiabi, A. Parsaie
Transverse mixing coefficient (TMC) is known as one of the most effective parameters in the two-dimensional simulation of water pollution, and increasing the accuracy of estimating this coefficient will improve the modeling process. In the present study, genetic algorithm (GA)-based support vector machine (SVM) was used to estimate TMC in streams. There are three principal parameters in SVM which need to be adjusted during the estimating procedure. GA helps SVM and optimizes these three parameters automatically in the best way. The accuracy of the SVM and GA-SVM algorithms along with previous models were discussed in TMC estimation by using a wide range of hydraulic and geometrical data from field and laboratory experiments. According to statistical analysis, the performance of the mentioned models in both straight and meandering streams was more accurate than the regression-based models. Sensitivity analysis showed that the accuracy of the GA-SVM algorithm in TMC estimation significantly correlated with the number of input parameters. Eliminating the uncorrelated parameters and reducing the number of input parameters will reduce the complexity of the problem and improve the TMC estimation by GA-SVM.
横向混合系数(TMC)是水污染二维模拟中最有效的参数之一,提高该系数的估计精度将改善建模过程。在本研究中,使用基于遗传算法的支持向量机(SVM)来估计流中的TMC。SVM中有三个主要参数需要在估计过程中进行调整。GA有助于SVM,并以最佳方式自动优化这三个参数。通过使用来自现场和实验室实验的大量水力和几何数据,讨论了SVM和GA-SVM算法以及以前模型在TMC估计中的准确性。根据统计分析,上述模型在直流和曲流中的性能都比基于回归的模型更准确。敏感性分析表明,GA-SVM算法在TMC估计中的准确性与输入参数的数量显著相关。消除不相关的参数并减少输入参数的数量将降低问题的复杂性,并改进GA-SVM的TMC估计。
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引用次数: 5
Effects of process parameters on the degradation of high salinity industrial wastewater 工艺参数对高盐度工业废水降解的影响
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-02-01 DOI: 10.2166/WQRJ.2021.035
Li Zhishen, Xiaolei Gao, Dongtian Miao, Yang Wanlin, Yuan-yan Xie, Li Ma, Qiu-ping Wei
High salinity wastewater is characterized by high salt content, a large number of organic pollutants and difficulty in biochemical degradation, which has become a major problem in industrial wastewater treatment. In this article, the electrochemical oxidation technology was used to treat high salinity wastewater. The effects of temperature, current density, pH and additives on the removal effect of high salinity wastewater were investigated to optimize the process parameters. The results show that the best degradation effect is when the current density is 21.43 mA cm−2, pH = 2, the temperature is 60 °C, and electric field activates additional persulfate. After purification of high salt wastewater, the evaporated salt can be utilized as a resource. The industrial cost of degradation was estimated, and its economic benefits were calculated. This work will provide a theoretical and experimental basis for treating high salt wastewater by boron-doped diamond (BDD) electrochemical degradation technology.
高盐度废水具有含盐量高、有机污染物多、难以生化降解等特点,已成为工业废水处理中的一大难题。本文采用电化学氧化技术处理高盐度废水。研究了温度、电流密度、pH和添加剂对高盐度废水去除效果的影响,优化了工艺参数。结果表明,当电流密度为21.43 mA cm−2,pH=2,温度为60°C,电场激活额外的过硫酸盐时,降解效果最佳。在高盐废水净化后,蒸发的盐可以用作资源。对退化的工业成本进行了估算,并计算了其经济效益。本工作将为掺硼金刚石(BDD)电化学降解技术处理高盐废水提供理论和实验依据。
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引用次数: 2
Assessment of phytoplankton community structure and water quality in the Hongmen Reservoir 洪门水库浮游植物群落结构与水质评价
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-01-27 DOI: 10.2166/WQRJ.2021.022
Chenwei Liu, Sun Xu, Lianghu Su, Cai Jinbang, Zhang Longjiang, Liyun Guo
To find effective measures to control the water quality of the Hongmen Reservoir, it is necessary to better understand its phytoplankton composition, abundance and spatial and temporal distribution. Samples were collected at three sampling sites in January (dry season), May (wet season) and September (normal season) in 2019. Trophic level and stability status were assessed on the basis of the Shannon diversity index (H), species richness (S) and evenness (J) index. The different relationships between phytoplankton and the concentrations of several physicochemical parameters and the main soluble nutrients were evaluated by statistical tests. The results showed that there were 75 species belonging to seven groups of phytoplankton, including Chlorophyta (44 species), Bacillariophyta (12 species), Cyanophyta (9 species) and others (10 species). The phytoplankton community composition belongs to the Chlorophyta–Bacillariophyta–Cyanobacteria type structure; and Microcystis, Anabaena azotica Ley, Aphanizomenon, Melosira granulata were the main contributors to the dissimilarities in the temporal distributions of their communities. The phytoplankton density ranged from 4.42 × 106 to 8.99 × 106 particles/L, with an average of 6.45 × 106 particles/L, and the biomass was 4.42 × 106 ∼ 8.99 × 106 particles/L, with an average of 6.45 × 106 particles/L. The variation ranges of the Shannon–Wiener index (H′), Margalef index (D) and Pielou evenness index (J) were 2.05 ∼ 2.85, 4.12 ∼ 6.60 and 0.61–0.78, respectively. This research shows that the water in the Hongmen Reservoir is clean and that the pollution level is light. The correlation analysis shows that total phosphorus and dissolved oxygen are the main factors affecting phytoplankton community structure in the Hongmen Reservoir.
为了找到控制洪门水库水质的有效措施,有必要更好地了解洪门水库浮游植物的组成、丰度和时空分布。在2019年1月(旱季)、5月(雨季)和9月(正常季节)的三个采样点采集了样本。根据香农多样性指数(H)、物种丰富度指数(S)和均匀度指数(J)评估营养水平和稳定性。通过统计检验,评价了浮游植物与几种理化参数和主要可溶性营养物质浓度之间的不同关系。结果表明,浮游植物共有75种,隶属于7组,包括绿藻门(44种)、硅藻门(12种)、蓝藻门(9种)和其他门(10种)。浮游植物群落组成属于绿藻门-硅藻门-蓝藻门型结构;微囊藻(Microcystis)、黄颡鱼(Anabaena azotica Ley)、阿芬尼佐米农(Aphanizomenon)、颗粒藻(Melosira granulata)是造成其群落时间分布差异的主要原因。浮游植物密度为4.42×106~8.99×106粒子/L,平均6.45×106粒子/L.生物量为4.42?06~8.99?06粒子/L.平均6.45?06粒子/L。Shannon–Wiener指数(H′)、Margalef指数(D)和Pielou均匀度指数(J)的变化范围分别为2.05~2.85、4.12~6.60和0.61~0.78。研究表明,洪门水库水质清洁,污染程度较轻。相关性分析表明,总磷和溶解氧是影响洪门水库浮游植物群落结构的主要因素。
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引用次数: 7
Stormwater quality assessment and management for the town of Jasper in Alberta, Canada 加拿大阿尔伯塔省Jasper镇的雨水质量评估和管理
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-01-11 DOI: 10.2166/WQRJ.2021.012
Ana Sofijanic, M. Hulley, Daniela Loock, Yves Filion
Stormwater pollutants can have deleterious impacts on the aquatic life of receiving water bodies. This paper presents the findings of a stormwater quality monitoring program performed in the town of Jasper in Alberta, Canada. This is one of the very few studies done on a small urban settlement to identify key pollutants of concern, characterize stormwater and identify unique pollutant sources in the town. A total of 14 stormwater quality parameters were found to be of high concern to aquatic life. The most prominent pollutants were total suspended solids (TSS), metals and phosphorus which compared well with studies conducted in large urban settlements. Tourist influx contributed to high metal and petroleum hydrocarbon loads during the peak season due to high vehicular activity. Elk were found to reside in the town during summer and their fecal droppings resulted in elevated fecal coliform concentrations. It was found that winter road salting was responsible for excessive chloride concentrations observed during the spring melt. TSS concentrations were statistically correlated with various metals as well as phosphorus using Spearman's rank correlation. It was found that the current street sweeping schedule in the town coincided with lower TSS and metal loads in stormwater.
雨水污染物会对受纳水体的水生生物产生有害影响。本文介绍了在加拿大阿尔伯塔省贾斯珀镇进行的雨水质量监测项目的结果。这是为数不多的针对小型城市居民点的研究之一,旨在确定关注的关键污染物,表征雨水,并确定城镇中独特的污染源。共发现14个雨水质量参数是水生生物高度关注的问题。最突出的污染物是总悬浮固体(TSS)、金属和磷,这与在大型城市住区进行的研究相比很好。在旺季,由于车辆活动频繁,游客的涌入导致了金属和石油碳氢化合物的高负荷。麋鹿在夏天被发现居住在该镇,它们的粪便导致粪便大肠菌群浓度升高。研究发现,冬季道路盐渍是春季融化期间观察到的氯化物浓度过高的原因。TSS浓度与各种金属以及磷使用Spearman秩相关进行统计相关。研究发现,该镇目前的街道清扫计划与较低的TSS和雨水中的金属负荷相吻合。
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引用次数: 2
Role of wastewater treatment in COVID-19 control 废水处理在新冠肺炎控制中的作用
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2021-01-06 DOI: 10.2166/WQRJ.2020.025
Chao-Fei Chen, K. Hayward, Stuart J. Khan, B. Örmeci, S. Pillay, J. Rose, J. Thanikal, Tong Zhang
The International Water Association (IWA) initiated a Task Force in April 2020 to serve as a leadership team within IWA whose role is to keep abreast and communicate the emerging science, technology, and applications for understanding the impact and the ability to respond to the COVID-19 pandemic and specifically designed for water professionals and industries. Expertise was nominated across the world with the purpose of collectively providing the water sector with knowledge products for the guidance on the control of COVID-19 and other viruses. This review paper developed by a working group of the IWA Task Force focuses on the control of COVID-19. The purpose of this review paper is to provide an understanding of existing knowledge with regards to COVID-19 and provide the necessary guidance of risk mitigation based on currently available knowledge of viruses in wastewater. This review paper considered various scenarios for both the developed world and the developing world and provided recommendations for managing risk. The review paper serves to pool the knowledge with regards to the pandemic and in relation to other viruses. The IWA Task Team envisage that this review paper provides the necessary guidance to the global response to the ongoing pandemic.
国际水协会(IWA)于2020年4月成立了一个工作组,作为IWA的领导团队,其作用是了解和交流新兴的科学、技术和应用,以了解应对新冠肺炎大流行的影响和能力,并专门为水专业人员和行业设计。世界各地提名了专门知识,目的是共同为水行业提供知识产品,以指导控制新冠肺炎和其他病毒。本审查文件由IWA工作组的一个工作组编写,重点关注新冠肺炎的控制。本综述文件的目的是了解新冠肺炎的现有知识,并根据废水中病毒的现有知识为风险缓解提供必要的指导。这篇综述文件考虑了发达国家和发展中国家的各种情况,并提出了管理风险的建议。该综述文件旨在汇集有关大流行和其他病毒的知识。IWA工作组设想,这份审查文件为全球应对当前的疫情提供了必要的指导。
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引用次数: 14
Removal of nickel through sulfide precipitation and characterization of electroplating wastewater sludge 硫化物沉淀除镍及电镀废水污泥的特性研究
IF 2.3 4区 环境科学与生态学 Q2 WATER RESOURCES Pub Date : 2020-07-28 DOI: 10.2166/wqrj.2020.116
Sarah Jerroumi, Mohammed Amarine, H. Nour, B. Lekhlif, J. Jamal
This work consists of the removal of nickel by sulfide precipitation from industrial electroplating wastewater and characterization of the produced sludge. Tests are carried out in a perfectly stirred batch reactor on electroplating industrial solution and synthetic solution prepared in the laboratory. The aim is to evaluate the impact of complexing agents formed during precipitation of metal ions in the industrial effluent. The concentration of nickel in both solutions is 100 mg/L. The operating conditions for the sulfide precipitation process are optimized: pH, molar ratio [S=]/[Ni2+] and dosage of S= ions. For an initial pH of 5 and an equimolar ratio of [S=]/[Ni2+]:1/1, the results show that the removal efficiency of Ni2+ ions is approaching 91 and 94% for industrial and synthetic solutions, respectively. Otherwise, for the same pH value in supersaturation conditions ([S=]/[Ni2+]:1.5/1), the removal efficiency is approaching 62 and 92% for industrial and synthetic solutions, respectively. For an effective metal removal, the optimal dosage of sulfide ions was evaluated. For 33 mg/L of S=, the removal efficiency of Ni2+ is approximately 90%. The resulting sludge has been characterized by X-ray diffractometry, scanning electron microscopy, infrared spectroscopy and thermal analysis. It consists essentially of millerite and nickel oxide.
本工作包括硫化沉淀法去除工业电镀废水中的镍,并对产生的污泥进行表征。在完全搅拌间歇式反应器中对实验室制备的电镀工业溶液和合成溶液进行了试验。目的是评价在工业废水中金属离子沉淀过程中形成的络合剂的影响。两种溶液中镍的浓度均为100mg /L。优化了硫化物沉淀过程的操作条件:pH、[S=]/[Ni2+]摩尔比和S=离子用量。当初始pH为5,等摩尔比为[S=]/[Ni2+]:1/1时,工业溶液和合成溶液对Ni2+离子的去除率分别接近91%和94%。而在相同pH值的过饱和条件下([S=]/[Ni2+]:1.5/1),工业溶液和合成溶液的去除率分别接近62%和92%。为了有效去除金属,对硫化物离子的最佳用量进行了评价。当S=浓度为33 mg/L时,Ni2+的去除率约为90%。所得污泥已通过x射线衍射、扫描电子显微镜、红外光谱和热分析进行了表征。它主要由千镍石和氧化镍组成。
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引用次数: 11
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