This study investigates the photocatalytic degradation of methylene blue (MB) using an Ag-Pterocarpus santilinoides extract biochar nanocomposites (AgPSBN) followed by characterization and antimicrobial screening of the biogenic photocatalyst. The silver biochar nanocomposite was synthesized by incorporating silver nanoparticles onto the surface of biochar through a facile, biogenic, safe, cost-effective and ecofriendly method. The photosynthesized AgPSBN was porous and spherical with a size of 27 nm range. The UV-spectroscopic analysis indicated spectra band at 648 and 667 nm for biochar and nanocomposite, respectively. The low band gap energy of 2.0 and 1.8 eV for the biochar and nanocomposite, respectively, is an indication that they can be an effective photocatalyst for the degradation of MB and for other energy applications. The percentage removal efficiency of 96.33% indicates high photodegradation ability which remained fairly constant (75%) after five cycle reuse indicating stability of the nanocomposite. The rate constant was evaluated to be 0.008 min−1. The nanocomposite indicated high inhibition zone diameter for Salmonella, E. coli, Klebsiella, and Staphylococcus aureus with inhibition zone diameters of 15, 12, 10, and 8 mm, respectively. The results strongly suggest the nanocomposite to be an effective environmental decontaminant of dyes as well as microbes.
{"title":"Facile fabricated silver Pterocarpus santilinoides biochar-based inorganic–organic hybrid nanocomposite for the photocatalytic decimation of methylene blue and micro-organisms","authors":"F. Nworie, N. Frank, Emelda Asogwa, Oroke Clinton","doi":"10.2166/wqrj.2024.006","DOIUrl":"https://doi.org/10.2166/wqrj.2024.006","url":null,"abstract":"\u0000 \u0000 This study investigates the photocatalytic degradation of methylene blue (MB) using an Ag-Pterocarpus santilinoides extract biochar nanocomposites (AgPSBN) followed by characterization and antimicrobial screening of the biogenic photocatalyst. The silver biochar nanocomposite was synthesized by incorporating silver nanoparticles onto the surface of biochar through a facile, biogenic, safe, cost-effective and ecofriendly method. The photosynthesized AgPSBN was porous and spherical with a size of 27 nm range. The UV-spectroscopic analysis indicated spectra band at 648 and 667 nm for biochar and nanocomposite, respectively. The low band gap energy of 2.0 and 1.8 eV for the biochar and nanocomposite, respectively, is an indication that they can be an effective photocatalyst for the degradation of MB and for other energy applications. The percentage removal efficiency of 96.33% indicates high photodegradation ability which remained fairly constant (75%) after five cycle reuse indicating stability of the nanocomposite. The rate constant was evaluated to be 0.008 min−1. The nanocomposite indicated high inhibition zone diameter for Salmonella, E. coli, Klebsiella, and Staphylococcus aureus with inhibition zone diameters of 15, 12, 10, and 8 mm, respectively. The results strongly suggest the nanocomposite to be an effective environmental decontaminant of dyes as well as microbes.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141655420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Direct current electrocoagulation has various drawbacks, including electrode passivation, heat creation from energy consumption, and high sludge formation. The restrictions limit its usage in tannery wastewater treatment. Therefore, alternating pulse current EC (APC-EC) was developed to solve these obstacles. The study was empirically examined, considering high-frequency (3,000–11,000 Hz), stirring speed (400–1,200 rpm), and reaction time (15–30 min). This research examined how factors affect chemical oxygen demand (COD) removal efficiency, turbidity from trivalent chromium (Cr+3), and energy consumption for perforated aluminum electrodes. The central composite design in the surface response design approach has improved various operational parameters in the APC-EC process for tannery wastewater treatment. The employment of mathematical and statistical methods resulted in optimal removal of COD, Cr+3, and turbidity while reducing energy usage. Using mathematical and statistical methods, we achieved maximum COD, Cr+3 ion, and turbidity reduction while reducing energy use. The investigation found that COD (70.3%), Cr+3 (89.56%), and turbidity (96%) were the most rapidly removed components at 11,000 Hz, 576 rpm, and 30 min. Surface response data explain high-frequency APC-EC dynamics.
{"title":"Development of an electrocoagulation method using alternating pulse current to treat wastewater generated by tanneries","authors":"Hassoun Al Hariri, F. Atallah, Mustafa M. Hathal","doi":"10.2166/wqrj.2024.020","DOIUrl":"https://doi.org/10.2166/wqrj.2024.020","url":null,"abstract":"\u0000 \u0000 Direct current electrocoagulation has various drawbacks, including electrode passivation, heat creation from energy consumption, and high sludge formation. The restrictions limit its usage in tannery wastewater treatment. Therefore, alternating pulse current EC (APC-EC) was developed to solve these obstacles. The study was empirically examined, considering high-frequency (3,000–11,000 Hz), stirring speed (400–1,200 rpm), and reaction time (15–30 min). This research examined how factors affect chemical oxygen demand (COD) removal efficiency, turbidity from trivalent chromium (Cr+3), and energy consumption for perforated aluminum electrodes. The central composite design in the surface response design approach has improved various operational parameters in the APC-EC process for tannery wastewater treatment. The employment of mathematical and statistical methods resulted in optimal removal of COD, Cr+3, and turbidity while reducing energy usage. Using mathematical and statistical methods, we achieved maximum COD, Cr+3 ion, and turbidity reduction while reducing energy use. The investigation found that COD (70.3%), Cr+3 (89.56%), and turbidity (96%) were the most rapidly removed components at 11,000 Hz, 576 rpm, and 30 min. Surface response data explain high-frequency APC-EC dynamics.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141126351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Potato starch-processing wastewater belongs to high-concentration organic wastewater, as direct discharge produce greater pollution to the environment. Flocculation treatment, as the initial process of wastewater purification, can remove large debris in wastewater, reduce energy consumption for subsequent treatment and reduce production costs. In this study, the effects of traditional flocculants and biological flocculants on the treatment of potato starch-processing wastewater under different pH, dosage, stirring rate and settling time were studied. It was found that traditional flocculants and biological flocculants have their own advantages in the purification ability of organic matter, and the removal rates of suspended solids (SS) and total phosphorus (TP) of traditional flocculants are better than biological flocculants for sweet potato starch-processing wastewater, but the flocculation time and settling time are long. Biological flocculants are environmentally friendly, safe and non-polluting, and do not produce secondary pollution when the flocculation treatment of wastewater is conducive to the secondary reuse of wastewater and flocculation sediment resource treatment. According to the flocculation effect and cost, chitosan is the best flocculant for treating sweet potato starch-processing wastewater.
{"title":"Effects of different flocculants and environment on the flocculation effect of potato starch-processing wastewater","authors":"Na Suo, Xiaoqiang Li, Jian Wu","doi":"10.2166/wqrj.2024.026","DOIUrl":"https://doi.org/10.2166/wqrj.2024.026","url":null,"abstract":"\u0000 Potato starch-processing wastewater belongs to high-concentration organic wastewater, as direct discharge produce greater pollution to the environment. Flocculation treatment, as the initial process of wastewater purification, can remove large debris in wastewater, reduce energy consumption for subsequent treatment and reduce production costs. In this study, the effects of traditional flocculants and biological flocculants on the treatment of potato starch-processing wastewater under different pH, dosage, stirring rate and settling time were studied. It was found that traditional flocculants and biological flocculants have their own advantages in the purification ability of organic matter, and the removal rates of suspended solids (SS) and total phosphorus (TP) of traditional flocculants are better than biological flocculants for sweet potato starch-processing wastewater, but the flocculation time and settling time are long. Biological flocculants are environmentally friendly, safe and non-polluting, and do not produce secondary pollution when the flocculation treatment of wastewater is conducive to the secondary reuse of wastewater and flocculation sediment resource treatment. According to the flocculation effect and cost, chitosan is the best flocculant for treating sweet potato starch-processing wastewater.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140968101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sachin Vaidh, Aastha Surana, Viraj Nagariya, Ravindrasinh Rahewar, Harsh Prajapati, Dhaval Patel, Alok Pandya, G. S. Vishwakarma
Worldwide, the harmful ion contamination of water has become a serious problem because of unregulated industry, energy production, and mining, which greatly increase the concentration of pollutants in water. The novel membranes through adsorbent self-assembly, such as protein amyloids, were explored for wastewater treatment. Herein, we report amyloid fibril (AF)-embedded bacterial cellulose nanohybrid membrane for efficient removal of heavy metal from industrial effluent. AFs are synthesized by heat treatment using bovine serum albumin and embedded with bacterial cellulose nanomembrane (BCN). The AF-embedded BCN (AF/BCN) was characterized using microscopy and spectroscopic methods. In addition, the well-ordered multi-layered AF/BCN filtration assembly was fabricated in the commercial cartridge and validated for the removal of heavy metals (Pb2+ and Hg2+) from wastewater and treatment of industrial wastewater sample containing heavy metals. Our multi-layered filtration assembly removed Hg+2 and Pb+2 with efficiency of 95 and 78.34%, respectively. A computational study using molecular docking has also been performed for the identification of metal entrapment sites. Moreover, our AF/BCN filtration assembly showed high regeneration capacity up to four cycles. The isotherm model also revealed a strong fit and good adsorption behaviour. This makes potential filtration assembly for low-cost, high-efficiency for the removal of HM from wastewater.
{"title":"Amyloid fibril–bacterial cellulose nanohybrid membrane cartridge for efficient removal of heavy metal from industrial wastewater","authors":"Sachin Vaidh, Aastha Surana, Viraj Nagariya, Ravindrasinh Rahewar, Harsh Prajapati, Dhaval Patel, Alok Pandya, G. S. Vishwakarma","doi":"10.2166/wqrj.2024.001","DOIUrl":"https://doi.org/10.2166/wqrj.2024.001","url":null,"abstract":"\u0000 \u0000 Worldwide, the harmful ion contamination of water has become a serious problem because of unregulated industry, energy production, and mining, which greatly increase the concentration of pollutants in water. The novel membranes through adsorbent self-assembly, such as protein amyloids, were explored for wastewater treatment. Herein, we report amyloid fibril (AF)-embedded bacterial cellulose nanohybrid membrane for efficient removal of heavy metal from industrial effluent. AFs are synthesized by heat treatment using bovine serum albumin and embedded with bacterial cellulose nanomembrane (BCN). The AF-embedded BCN (AF/BCN) was characterized using microscopy and spectroscopic methods. In addition, the well-ordered multi-layered AF/BCN filtration assembly was fabricated in the commercial cartridge and validated for the removal of heavy metals (Pb2+ and Hg2+) from wastewater and treatment of industrial wastewater sample containing heavy metals. Our multi-layered filtration assembly removed Hg+2 and Pb+2 with efficiency of 95 and 78.34%, respectively. A computational study using molecular docking has also been performed for the identification of metal entrapment sites. Moreover, our AF/BCN filtration assembly showed high regeneration capacity up to four cycles. The isotherm model also revealed a strong fit and good adsorption behaviour. This makes potential filtration assembly for low-cost, high-efficiency for the removal of HM from wastewater.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140968509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Few factors are as important in determining water quality as land use/land cover (LULC). Many land use activities, including agriculture, urban development, mining, and commercial forestry, tend to be sources of diffuse pollution. By contrast, indigenous vegetation can act as a sink, thus providing some protection from diffuse anthropogenic contamination. Notwithstanding the large body of research demonstrating these facts, decision-makers require clear and accessible information to assist them in developing effective management plans that are fully cognisant of the manifold impacts of LULC on water resources. Reviewing the available literature, this article, therefore, offers a critical overview of the typical impacts of LULC on water quality. An important strategy for managing water quality highlighted in this article is the maintenance of a sufficient amount of unfragmented natural vegetation, not only within riparian zones but also across catchment areas. However, knowledge gaps identified in this review indicate that further context-specific research is required to determine not only the types and minimum amount of vegetative cover required to protect water resources from diffuse pollution but also the potential impact of landscape fragmentation on the ability of natural vegetation to protect water resources. A critical discussion of these factors is therefore provided.
{"title":"Impacts of land use/land cover on water quality: a contemporary review for researchers and policymakers","authors":"Kent Anson Locke","doi":"10.2166/wqrj.2024.002","DOIUrl":"https://doi.org/10.2166/wqrj.2024.002","url":null,"abstract":"\u0000 \u0000 Few factors are as important in determining water quality as land use/land cover (LULC). Many land use activities, including agriculture, urban development, mining, and commercial forestry, tend to be sources of diffuse pollution. By contrast, indigenous vegetation can act as a sink, thus providing some protection from diffuse anthropogenic contamination. Notwithstanding the large body of research demonstrating these facts, decision-makers require clear and accessible information to assist them in developing effective management plans that are fully cognisant of the manifold impacts of LULC on water resources. Reviewing the available literature, this article, therefore, offers a critical overview of the typical impacts of LULC on water quality. An important strategy for managing water quality highlighted in this article is the maintenance of a sufficient amount of unfragmented natural vegetation, not only within riparian zones but also across catchment areas. However, knowledge gaps identified in this review indicate that further context-specific research is required to determine not only the types and minimum amount of vegetative cover required to protect water resources from diffuse pollution but also the potential impact of landscape fragmentation on the ability of natural vegetation to protect water resources. A critical discussion of these factors is therefore provided.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140675161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study aims to validate the wastewater treatment technique and compare the effectiveness of applying an ozone mixture and atmospheric oxygen in the presence of a catalyst (manganese dioxide) with various dosages. A total of 540 replicates were performed, corresponding to different levels of manganese dioxide concentrations during oxygen and ozone delivery (270 repetitions for each of the experiments). The research was carried out using an experimental setup developed by the authors. The maximum efficiency of oxidation processes was observed within 15–30 min after the start of the treatment cycle. The decrease in the level of chemical oxygen demand within the first quarter-hour during ozone treatment was significantly greater compared to atmospheric oxygen treatment (p ≤ 0.05). The method's efficiency increased to 53% for ozone and 41% for oxygen after 30 min of purification (p ≤ 0.05). Lower catalyst consumption was observed when using an ozone mixture. The tested technology can be recommended for wastewater treatment with high hydrocarbon concentrations. The findings of the study indicated the potential application of ozone treatment with a manganese catalyst for treating wastewater with high hydrocarbon content, thereby fostering the development of more effective water purification methods in the industrial sector.
{"title":"Comparative study of wastewater treatment efficiency: ozone vs. atmospheric oxygen with a manganese dioxide catalyst","authors":"Sholpan Umbetova, Gulzhan Abylkassova, Dmitriy Spitsov","doi":"10.2166/wqrj.2024.033","DOIUrl":"https://doi.org/10.2166/wqrj.2024.033","url":null,"abstract":"\u0000 \u0000 This study aims to validate the wastewater treatment technique and compare the effectiveness of applying an ozone mixture and atmospheric oxygen in the presence of a catalyst (manganese dioxide) with various dosages. A total of 540 replicates were performed, corresponding to different levels of manganese dioxide concentrations during oxygen and ozone delivery (270 repetitions for each of the experiments). The research was carried out using an experimental setup developed by the authors. The maximum efficiency of oxidation processes was observed within 15–30 min after the start of the treatment cycle. The decrease in the level of chemical oxygen demand within the first quarter-hour during ozone treatment was significantly greater compared to atmospheric oxygen treatment (p ≤ 0.05). The method's efficiency increased to 53% for ozone and 41% for oxygen after 30 min of purification (p ≤ 0.05). Lower catalyst consumption was observed when using an ozone mixture. The tested technology can be recommended for wastewater treatment with high hydrocarbon concentrations. The findings of the study indicated the potential application of ozone treatment with a manganese catalyst for treating wastewater with high hydrocarbon content, thereby fostering the development of more effective water purification methods in the industrial sector.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140384273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reham M. Abu Shmeis, Ibrahim N. Tarawneh, Amneh T. Issa
Phenolic compounds (PCs) are prevalent in olive mill wastewater (OMW), offering numerous health benefits but concurrently posing environmental challenges. This study aims to comprehensively characterize PCs in OMW, both qualitatively and quantitatively. We have successfully developed an accurate, sensitive, and cost-effective method for extracting and quantifying seven PCs in OMW. The extraction procedure was optimized to achieve the highest recovery through the adaptation of a liquid–liquid extraction method. The concentrations of the identified PCs were determined using a high-performance liquid chromatography-diode array detector (HPLC-DAD). Successfully separated on an RP-C8 column within a 23-min runtime, the seven peaks were eluted by employing a gradient mobile phase. The method underwent thorough validation, producing satisfactory results. Subsequently, the developed method was applied to analyze OMW from four olive mills in Jordan. Revealing PC concentrations ranging from 139 to 430 mg/L, tyrosol and hydroxytyrosol were identified as the most abundant compounds. Additionally, gas chromatography–mass spectrometry (GC–MS) was used to separate and identify 40 PCs. The total phenolic content was also quantified and found to be 1,839 mg/L. Moreover, the antioxidant activity was assessed, yielding a maximum value of 95.8%. These results underscore the substantial levels of PCs in OMW, highlighting the importance of economically utilizing this water.
{"title":"Profiling and evaluation of phenolic compounds in olive mill wastewater in Jordan","authors":"Reham M. Abu Shmeis, Ibrahim N. Tarawneh, Amneh T. Issa","doi":"10.2166/wqrj.2024.024","DOIUrl":"https://doi.org/10.2166/wqrj.2024.024","url":null,"abstract":"\u0000 \u0000 Phenolic compounds (PCs) are prevalent in olive mill wastewater (OMW), offering numerous health benefits but concurrently posing environmental challenges. This study aims to comprehensively characterize PCs in OMW, both qualitatively and quantitatively. We have successfully developed an accurate, sensitive, and cost-effective method for extracting and quantifying seven PCs in OMW. The extraction procedure was optimized to achieve the highest recovery through the adaptation of a liquid–liquid extraction method. The concentrations of the identified PCs were determined using a high-performance liquid chromatography-diode array detector (HPLC-DAD). Successfully separated on an RP-C8 column within a 23-min runtime, the seven peaks were eluted by employing a gradient mobile phase. The method underwent thorough validation, producing satisfactory results. Subsequently, the developed method was applied to analyze OMW from four olive mills in Jordan. Revealing PC concentrations ranging from 139 to 430 mg/L, tyrosol and hydroxytyrosol were identified as the most abundant compounds. Additionally, gas chromatography–mass spectrometry (GC–MS) was used to separate and identify 40 PCs. The total phenolic content was also quantified and found to be 1,839 mg/L. Moreover, the antioxidant activity was assessed, yielding a maximum value of 95.8%. These results underscore the substantial levels of PCs in OMW, highlighting the importance of economically utilizing this water.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139613872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Data-driven models for the prediction of lake eutrophication essentially rely on water quality datasets for a longer duration. If such data are not readily available, lake management through data-driven modeling becomes impractical. So, a novel approach is presented here for the prediction of eutrophication indicators, such as dissolved oxygen, Secchi depth, total nitrogen, and total phosphorus, in the waterbodies of Assam, India. These models were developed using water quality datasets collected through laboratory investigation in artificially simulated lake systems. Two artificial prototype lakes were eutrophied in a controlled environment with the gradual application of wastewater. A periodic assessment of water quality was done for model development. Data-driven modeling in the form of multilayer perceptron (MLP), time-delay neural network (TDNN), support vector regression (SVR), and Gaussian process regression (GPR) were utilized. The trained model's accuracy was evaluated based on statistical parameters and a reasonable correlation was observed between targeted and model predicted values. Finally, the trained models were tested against some natural waterbodies in Assam and a satisfactory prediction accuracy was obtained. TDNN and GPR models were found superior compared to other methods. Results of the study indicate feasibility of the adopted modeling approach in predicting lake eutrophication when periodic water quality data are limited for the waterbody under consideration.
{"title":"Examining the effectiveness of artificially replicated lake systems in predicting eutrophication indicators: a comparative data-driven analysis","authors":"Biswajit Bhagowati, K. U. Ahamad","doi":"10.2166/wqrj.2024.014","DOIUrl":"https://doi.org/10.2166/wqrj.2024.014","url":null,"abstract":"\u0000 \u0000 Data-driven models for the prediction of lake eutrophication essentially rely on water quality datasets for a longer duration. If such data are not readily available, lake management through data-driven modeling becomes impractical. So, a novel approach is presented here for the prediction of eutrophication indicators, such as dissolved oxygen, Secchi depth, total nitrogen, and total phosphorus, in the waterbodies of Assam, India. These models were developed using water quality datasets collected through laboratory investigation in artificially simulated lake systems. Two artificial prototype lakes were eutrophied in a controlled environment with the gradual application of wastewater. A periodic assessment of water quality was done for model development. Data-driven modeling in the form of multilayer perceptron (MLP), time-delay neural network (TDNN), support vector regression (SVR), and Gaussian process regression (GPR) were utilized. The trained model's accuracy was evaluated based on statistical parameters and a reasonable correlation was observed between targeted and model predicted values. Finally, the trained models were tested against some natural waterbodies in Assam and a satisfactory prediction accuracy was obtained. TDNN and GPR models were found superior compared to other methods. Results of the study indicate feasibility of the adopted modeling approach in predicting lake eutrophication when periodic water quality data are limited for the waterbody under consideration.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140511666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Tiwari, J. Singh, P. Sahota, N. N. Singh, K. Singh
Low-cost portable water filter having a capacity of 15 l for an average small family size was designed, developed, and fabricated for canal water potability. The volume and thickness of filter media were computed and found to be 4,544 cm3 and 5.6 cm, respectively. The provision for injection of sodium hypochlorite solution was made for the removal of bacterial contaminants and calibrated to be 1.5 mL for 15 l of water to maintain the required level of residual chlorine content (2–5 ppm) which was supplied through the pumping unit. The adsorbed contaminants on the filter media could be removed by placing them in 3 l of boiled water for 2 min. The experiment was conducted to determine the settlement duration of suspended solids in canal water and found to be 8 h, thereafter allowing it for filtration. The performance of the developed filter was evaluated by analyzing water quality parameters of the canal water before and after filtration. The values of BOD, chemical oxygen demand (COD), MPN, TDS, pH, and residual chlorine of filtered water were found to be within the permissible limit. The cost of the developed filter was estimated to be INR 1,300 which is economically viable, technically feasible, and easily portable.
{"title":"Development and evaluation of filter for canal water potability","authors":"V. Tiwari, J. Singh, P. Sahota, N. N. Singh, K. Singh","doi":"10.2166/wqrj.2023.009","DOIUrl":"https://doi.org/10.2166/wqrj.2023.009","url":null,"abstract":"Low-cost portable water filter having a capacity of 15 l for an average small family size was designed, developed, and fabricated for canal water potability. The volume and thickness of filter media were computed and found to be 4,544 cm3 and 5.6 cm, respectively. The provision for injection of sodium hypochlorite solution was made for the removal of bacterial contaminants and calibrated to be 1.5 mL for 15 l of water to maintain the required level of residual chlorine content (2–5 ppm) which was supplied through the pumping unit. The adsorbed contaminants on the filter media could be removed by placing them in 3 l of boiled water for 2 min. The experiment was conducted to determine the settlement duration of suspended solids in canal water and found to be 8 h, thereafter allowing it for filtration. The performance of the developed filter was evaluated by analyzing water quality parameters of the canal water before and after filtration. The values of BOD, chemical oxygen demand (COD), MPN, TDS, pH, and residual chlorine of filtered water were found to be within the permissible limit. The cost of the developed filter was estimated to be INR 1,300 which is economically viable, technically feasible, and easily portable.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139263264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A batch monopolar electrocoagulation system was developed and studied for the removal of phosphorus from anaerobic bioreactor effluent using iron as an electrode material. The study focused on the optimization of the independent variables, such as initial pH, retention time (RT), current density (CD) and inter-electrode distance (IED) using the response surface methodology (RSM) to maximize the removal of total phosphorus (TP). A quadratic model was fitted to the experimental data for TP removal. The optimal parameters were found to be pH of 6.75, RT of 11.06 min, CD of 300 A/m2, and inter-electrode distance of 1.5 cm resulting in 98.05% TP removal and energy consumption of 1.28 kWh/m3. A kinetic study for TP removal revealed that at optimal conditions, removal followed first-order kinetics (K = 0.185 m/min). Phosphorus was recovered from the post-precipitated sludge through combustion at 900 °C followed by acid leaching with sulfuric acid. Acid leaching tests were carried out with sulfuric acid for the post-precipitated sludge obtained at the optimum conditions. It resulted in around 91% of phosphorus recovery at a liquid-to-solid ratio of 100 mL/g.
{"title":"Phosphorus removal and recovery from anaerobic bioreactor effluent using a batch electrocoagulation process","authors":"G. P. Bhoi, Kripa S. Singh, Dennis A. Connor","doi":"10.2166/wqrj.2023.111","DOIUrl":"https://doi.org/10.2166/wqrj.2023.111","url":null,"abstract":"\u0000 \u0000 A batch monopolar electrocoagulation system was developed and studied for the removal of phosphorus from anaerobic bioreactor effluent using iron as an electrode material. The study focused on the optimization of the independent variables, such as initial pH, retention time (RT), current density (CD) and inter-electrode distance (IED) using the response surface methodology (RSM) to maximize the removal of total phosphorus (TP). A quadratic model was fitted to the experimental data for TP removal. The optimal parameters were found to be pH of 6.75, RT of 11.06 min, CD of 300 A/m2, and inter-electrode distance of 1.5 cm resulting in 98.05% TP removal and energy consumption of 1.28 kWh/m3. A kinetic study for TP removal revealed that at optimal conditions, removal followed first-order kinetics (K = 0.185 m/min). Phosphorus was recovered from the post-precipitated sludge through combustion at 900 °C followed by acid leaching with sulfuric acid. Acid leaching tests were carried out with sulfuric acid for the post-precipitated sludge obtained at the optimum conditions. It resulted in around 91% of phosphorus recovery at a liquid-to-solid ratio of 100 mL/g.","PeriodicalId":23720,"journal":{"name":"Water Quality Research Journal","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2023-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41976812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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