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Experimental and theoretical optimization of Chelidonium Majus (Papaveraceae) extract as an environmentally friendly inhibitor for corrosion of a-brass in nitric acid solution 木瓜科菊苣提取物作为环境友好型硝酸溶液中a-黄铜缓蚀剂的实验和理论优化
Pub Date : 2023-01-01 DOI: 10.5937/zasmat2303239f
A. Fouda, Aya Salem, Ahmed Wahba, Samir El-Maksous, Mahmoud El-Haddad
The research paper discusses the study of the inhibition rates of Chelidonium Majus (Papaveraceae) plant extract (CME) on abrass in 1.0 M HNO3 solution. The study was carried out using chemical and electrochemical techniques, which showed results of up to 97% inhibition with 150 ppm at 250C. For the polarization results, CME is a mixed-type inhibitor. The increase in the charge transfer resistance and the decrease in the capacitance of the double layer with increasing concentration were observed by Nyquist diagrams and it was found that the inhibition process follows the Langmuir isotherm which proves the formation of a monolayer on the surface of the abrass. Quantum chemical calculations were performed using the DFT method to determine the active centres of the CME which responsible for adsorption, as well, to their possible interaction mechanism with the brass surface.
本研究探讨了在1.0 M HNO3溶液中,长春花Chelidonium Majus (Papaveraceae)植物提取物(CME)对杂草的抑制率。该研究使用化学和电化学技术进行,结果表明,在250℃下,150ppm的缓蚀效果高达97%。从极化结果来看,CME是一种混合型抑制剂。通过奈奎斯特图观察到,随着浓度的增加,双层的电荷转移电阻增大,电容减小,抑制过程遵循Langmuir等温线,证明在磨砂表面形成单层。量子化学计算使用DFT方法来确定CME的活性中心,这些中心负责吸附,以及它们与黄铜表面可能的相互作用机制。
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引用次数: 0
The capacities of Hedera helix from the Bor region for PAH accumulation in the root and implications for phytostabilization Bor地区Hedera helix在根中积累多环芳烃的能力及其对植物稳定的影响
Pub Date : 2023-01-01 DOI: 10.5937/zasmat2301013p
A. Papludis, S. Alagić, Snežana Milić, Dragana V. Medić, Ivana G. Zlatanović, J. Nikolić, V. Stankov-Jovanović
Polycyclic aromatic hydrocarbons (PAHs) are considered as the pollutants of highest priority, and their remediation is of a global concern. The purpose of this study was to investigate the phytoremediation potential of Hedera helix (Hh) determining the content of 16 priority PAHs in its soil and root samples collected from the rural and industrial zones of the Bor's municipality (Serbia). The content of Ʃ16 PAHs in the soils was: 326.49 mg/kg at the site Borsko jezero to maximal 1937.64 mg/kg at the site Slatinsko naselje. The level of soil pollution (depending on the concentration of S16 PAHs), was high at many tested sites and it was under the significant influence of anthropogenic activities. The concentration for S16 PAHs in the samples of roots ranged from 480.71 mg/kg at the site Krivelj to 1748.32 mg/kg at the site Naselje Sunce. Interestingly, the extremely toxic benzo(a)pyrene, was not detected in the roots of Hh. Bioconcentration factors (BCFs) were applied to determine the capacity of Hh for PAH accumulation in the root, and consequently, for determination of its phytostabilization potential. In most cases, BCF values were higher at the locations from UI zone. The calculated BCFs were higher for LMW PAHs than for HMW PAHs. At the majority of the investigated locations, the tested plant species was especially successful in the root accumulation of the compounds such as acenaphthene, fluorene, anthracene, dibenzo(a,h)anthracene, and the sum of benzo(k)fluoranthene and benzo(b)fluoranthene. These findings showed that Hh can be successfully used in phytostabilization of many PAHs.
多环芳烃(PAHs)被认为是最重要的污染物,其修复是全球关注的问题。本研究的目的是调查Hedera helix (Hh)的植物修复潜力,确定从博尔市(塞尔维亚)的农村和工业区收集的土壤和根样品中16种优先多环芳烃的含量。土壤中Ʃ16多环芳烃含量:Borsko jezero为326.49 mg/kg, Slatinsko naselje为1937.64 mg/kg。土壤污染水平(取决于S16多环芳烃的浓度)在许多试验点都很高,并且受到人为活动的显著影响。根样品中S16多环芳烃的浓度范围从Krivelj位点的480.71 mg/kg到Naselje Sunce位点的1748.32 mg/kg不等。有趣的是,在Hh的根中没有检测到剧毒的苯并(a)芘。利用生物富集因子(BCFs)测定Hh在根中积累多环芳烃的能力,从而确定其植物稳定潜力。在大多数情况下,距离UI区域的位置BCF值较高。低分子量多环芳烃的计算BCFs高于高分子量多环芳烃。在大多数调查地点,测试的植物物种在诸如苊、芴、蒽、二苯并(a、h)蒽以及苯并(k)荧光蒽和苯并(b)荧光蒽等化合物的根积累方面特别成功。这些发现表明Hh可以成功地用于多种多环芳烃的植物稳定。
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引用次数: 0
Physical and mechanical changes in thermal modified wood: A review 热改性木材的物理力学变化研究进展
Pub Date : 2023-01-01 DOI: 10.5937/zasmat2303314h
R. Hasanagić, Leila Fathi, Atif Hodžić, Mohsen Bahmani
In Europe, wood is a crucial construction material that has experienced a surge in use for building applications in recent years. To enhance its dimensional stability and durability, thermal modification is a widely accepted commercial technology. Thermal modification is a popular technique that alters the properties of wood, improving its resistance to decay and increasing its dimensional stability. The process involves heating wood to high temperatures under controlled conditions, leading to chemical reactions that result in various physical and mechanical changes. This paper will discuss the effects of thermal modification on the physical properties of wood, such as density, moisture content, and color, as well as its impact on the mechanical properties, including strength, stiffness, and hardness. Additionally, the review will examine the factors that influence the degree of modification, such as temperature, duration, and wood species. Finally, the paper will conclude with an overview of the current state of research in this field and identify potential avenues for future investigation.
在欧洲,木材是一种重要的建筑材料,近年来在建筑应用中的使用激增。为了提高其尺寸稳定性和耐用性,热改性是一种被广泛接受的商业技术。热改性是一种流行的技术,可以改变木材的性能,提高其抗腐性和增加其尺寸稳定性。该过程包括在受控条件下将木材加热到高温,导致化学反应,从而导致各种物理和机械变化。本文将讨论热改性对木材物理性能的影响,如密度、含水量和颜色,以及它对机械性能的影响,包括强度、刚度和硬度。此外,审查将审查影响改性程度的因素,如温度、持续时间和木材种类。最后,本文将总结在这一领域的研究现状的概述,并确定未来调查的潜在途径。
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引用次数: 0
Concretes based on composite cements with the addition of granulated blast furnace slag and cement dust 掺有粒状高炉矿渣和水泥粉尘的复合水泥基混凝土
Pub Date : 2023-01-01 DOI: 10.5937/zasmat2303262d
L. Dvorkin, V. Zhitkovsky
A set of experimental-statistical models has been obtained that makes it possible to predict the workability and strength of concrete on a composite binder, including the addition of dust from cement clinker kilns and granulated blast-furnace slag, as well as polycarboxylate superplasticizer Sika VC 225. The values of the critical water-cement ratio are determined, which determine the area of constant water demand and take into account the binder normal consistency, as well as the adsorption coefficients of fine and coarse aggregates. Experimental-statistical models of the coefficients that determine the yield of concrete strength per 1 kg of composite cement and Portland cement Cem I contained in it are obtained.
建立了一套实验统计模型,可以预测混凝土在复合粘结剂上的和易性和强度,包括水泥熟料窑粉尘和粒状高炉炉渣的添加,以及聚羧酸酯型高效减水剂西卡vc225。确定了临界水灰比的值,该值确定了恒定需水面积,并考虑了粘结剂的正常稠度以及细、粗骨料的吸附系数。建立了决定复合水泥和硅酸盐水泥每千克混凝土屈服强度系数的实验统计模型。
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引用次数: 0
Synthesis of nanoparticles in dual biodiesel and enchancement in performances and emission characteristics 双生物柴油中纳米颗粒的合成及其性能和排放特性的增强
Pub Date : 2023-01-01 DOI: 10.5937/zasmat2301022j
Casmir Antony, Dhas Ghana, A. Kumar
Biodiesel is being advertised as a realistic alternative fuel. Since it has a lower environmental effect than standard fuel properties, biodiesel has risen in popularity recently, and there has been a lot of study done on it all around the world. Biodiesel is prone to oxidation due to the presence of unsaturated fatty acids in the ester, which has been one of the biggest downsides. When biodiesel comes into contact with oxygen during storage or even with metal impurities, it oxidises. Antioxidants are really helpful in resolving problems with oxidation stability. In this paper, mainly discussed about dual biodiesel (40:60), mixed with TiO2 Nanoparticles at various 25 ppm levels for the blend DBNP20, DBNP40 and DBNP60 respectively. The results implies good performances and emission characteristics with lower SFC and reasonable values are tabulated in the with neat diesel values.
生物柴油被宣传为一种现实的替代燃料。由于生物柴油对环境的影响比标准燃料小,近年来生物柴油越来越受欢迎,世界各地对其进行了大量的研究。由于酯中存在不饱和脂肪酸,生物柴油容易氧化,这是生物柴油最大的缺点之一。当生物柴油在储存过程中与氧气接触,甚至与金属杂质接触时,它就会氧化。抗氧化剂确实有助于解决氧化稳定性问题。本文主要研究了双组分生物柴油(40:60)与不同25 ppm浓度的TiO2纳米粒子混合制备DBNP20、DBNP40和DBNP60。研究结果表明,低SFC和合理的数值在纯柴油值下具有良好的性能和排放特性。
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引用次数: 0
Effect of hybrid SiC/TiO2 nanoparticles on tribological and mechanical performance of polymethylmethacrylate dental base material SiC/TiO2杂化纳米颗粒对聚甲基丙烯酸甲酯牙基材料摩擦学和力学性能的影响
Pub Date : 2023-01-01 DOI: 10.5937/zasmat2301086k
Ameer Kamel, Ahmed Ahmed, A. El-Abd
Many researches dealt with PMMA dental base material and the development of its properties to reach a longer life span for implants and fillings. The current work pay attention to examine the loading amount of hybrid nanoparticles, SiC and TiO2, and find out how it affects the mechanical and tribological properties. Hybrid NPs were dispersed on PMMA resin with filler amount of 0.4%, 0.8%, 1.2%, 1.6%, and 2.0 wt.%, 50/50 between SiC and TiO2 NPs. The mechanical properties were evaluated by determining the hardness, Shore D, compressive strength, and modulus of elasticity. While the tribological performance was assessed via examining the COF, wear rate and scanning the worn surfaces using optical and SEM images. The results can be indicated that the PMMA resin exhibits a good reaction bonding with low loading amount of the hybrid NPs. Moreover, the high loading content had a negative effect on the mechanical and tribological properties. Subsequently, the loading content of 0.8 wt.% of SiC/TiO2 NPs indicates that it has the best performance comparing with the pure PMMA.
许多研究涉及PMMA牙基材料及其性能的发展,以达到更长的种植和填充寿命。本研究的重点是研究SiC和TiO2杂化纳米颗粒的加载量,以及其对材料力学和摩擦学性能的影响。以0.4%、0.8%、1.2%、1.6%、2.0 wt %的填充量分散在PMMA树脂上,SiC和TiO2 NPs的配比为50/50。通过测定硬度、邵氏D值、抗压强度和弹性模量来评估机械性能。同时,通过检查COF、磨损率和使用光学和扫描电镜图像扫描磨损表面来评估摩擦学性能。结果表明,PMMA树脂在低负载量的杂化NPs下具有良好的反应键合性能。此外,高载荷含量对材料的力学性能和摩擦学性能有不利影响。随后,SiC/TiO2 NPs的负载量为0.8 wt.%,表明其与纯PMMA相比具有最佳性能。
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引用次数: 1
Application of artificial neural network in determining the fabric weave pattern 人工神经网络在织物织型确定中的应用
Pub Date : 2022-01-01 DOI: 10.5937/zasmat2203291d
Subrata Das, Keerthana Shanmugaraja
The weave pattern (texture) of woven fabric is considered to be an important factor of the design and production of high-quality fabric. Traditionally, the recognition of woven fabric has a lot of challenges due to its manual visual inspection. The approaches based on early machine learning algorithms directly depend on handcrafted features, which are time-consuming and occurs more errors. Hence, an automated system is needed for classification of woven fabric to improve productivity. Along with the rapid development of computer vision, the automatic and efficient methods for woven fabric classification are desperately needed. The prediction of fabric weave pattern Fabric is done by acquiring the high-quality images of the fabric. Then the acquired images are subjected to weave classification algorithm. The output of the processed image is used as an input to the Artificial Neural Network (ANN) which uses back propagation algorithm to calculate the weighted factors and generates the desired classification of weave patterns as an output. In this review paper discussed about the study on the various neural network that are used for prediction of fabric weave pattern.
机织物的组织花纹(肌理)被认为是设计和生产高质量织物的重要因素。传统的机织物识别由于需要人工目视检测,给识别带来了很大的挑战。基于早期机器学习算法的方法直接依赖于手工制作的特征,这既耗时又容易出错。因此,需要一个自动化系统来分类机织物,以提高生产率。随着计算机视觉技术的飞速发展,迫切需要一种自动、高效的机织物分类方法。织物的织型预测是通过获取织物的高质量图像来实现的。然后对采集到的图像进行编织分类算法。处理后的图像输出作为人工神经网络(ANN)的输入,人工神经网络使用反向传播算法计算加权因子,并生成所需的编织图案分类作为输出。本文综述了用于织物织型预测的各种神经网络的研究进展。
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引用次数: 0
The content of polycyclic aromatic hydrocarbons in soil formed during incineracion of e-waste at the sites of its inadequate disposal and recycling 电子垃圾焚烧过程中形成的土壤中多环芳烃的含量在其处置和回收不足的地点
Pub Date : 2022-01-01 DOI: 10.5937/zasmat2202165p
A. Papludis, Ana T. Simonović, S. Alagić
Electronic and electric (e-) waste is a major environmental problem worldwide. An improper handling, disposal and recycling of e-waste lead to the negative impacts on the environment, especially on soil pollution. It is known that, in the environment, organic pollutants such as polycyclic aromatic hydrocarbons (PAHs), can be formed in several ways, including the pyrolytic processes during the incineration of e-waste. Given that these organic substances are very toxic, even in extremely low concentrations, the main goal of this paper was to present a literature review of PAHs in the soil near the sites for the disposal and recycling of e-waste that are not regulated according to the adequate, positive legislations.
电子电气废弃物是世界范围内的一个主要环境问题。电子垃圾的不当处理、处置和回收会对环境造成负面影响,尤其是对土壤的污染。众所周知,在环境中,多环芳烃(PAHs)等有机污染物可以通过几种方式形成,包括焚烧电子废物期间的热解过程。鉴于这些有机物质是非常有毒的,即使在极低的浓度,本文的主要目标是提出了文献综述在土壤附近的多环芳烃处置和回收的电子废物,不根据适当的,积极的立法监管。
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引用次数: 0
Plant materials as green corrosion inhibitors for select iron alloys: A review 植物材料作为铁合金绿色缓蚀剂的研究进展
Pub Date : 2022-01-01 DOI: 10.5937/zasmat2202183e
I. Ekeke, S. Efe, F. Nwadire
The importance of corrosion studies brings to the forefront economic losses, damage, and safety issues of metals deterioration in the construction industry. Although the choice of a material and use of inhibitors can contribute to its resistance to environmental corrosion behavior, the structural deterioration of metals can be exacerbated under operation conditions. In this review, highlights of research findings published in the past five years on the use of plant materials as corrosion inhibitors for variants of steel: carbon steel, mild steel, stainless steel are provided. It elucidates the meaning of green inhibitors and their types. It also presents the methods employed to ascertain the inhibition efficiencies of the plants/plant parts listed and the parameters considered in the corrosion inhibition analyses. The major gaps or limitations identified in the reported research findings include experimentation at constant temperatures and short immersion periods for the alloys. Due to the fact that, if these extracts were to be deployed for industrial use, they'd be subjected to more hazardous conditions, such as higher temperatures, pressures, etc., this paper proposes that their investigations as potential inhibitors on the laboratory/pilot scale be performed at higher temperatures and longer immersion times which may as such provide more comprehensive knowledge on the environmental/climatic requirements for their application. Additional improvement strategies are also suggested. The list of extracts, however, is not exhaustive.
腐蚀研究的重要性带来了最前沿的经济损失,破坏和安全问题的金属恶化在建筑行业。虽然材料的选择和抑制剂的使用有助于其抗环境腐蚀行为,但在操作条件下,金属的结构恶化可能会加剧。在这篇综述中,重点介绍了过去五年来发表的关于植物材料作为碳钢、低碳钢、不锈钢等钢的缓蚀剂的研究成果。阐述了绿色抑制剂的含义及其类型。还介绍了确定所列植物/植物部件的缓蚀效率的方法和缓蚀分析中考虑的参数。在报告的研究结果中确定的主要差距或限制包括合金在恒温和短浸泡时间下的实验。由于,如果这些提取物用于工业用途,它们将受到更危险的条件,如更高的温度,压力等,本文建议在实验室/中试规模上对其作为潜在抑制剂进行研究,在更高的温度和更长的浸泡时间下进行,这样可以提供更全面的环境/气候要求知识。还提出了其他改进策略。然而,这份摘录的清单并不详尽。
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引用次数: 6
Influence of a paint coating on the corrosion of hull plates made of mild steel in natural seawater 涂料对低碳钢船体板在天然海水中腐蚀的影响
Pub Date : 2022-01-01 DOI: 10.5937/zasmat2203353k
K. Kavipriya, Lavanya Lurdu, Kuppusamy Bhuvaneswari, V. Velkannan, Nilavan Anitha, S. Rajendran, Č. Lačnjevac
The corrosion resistance of mild steel (used to make hull plates in ship technology) in seawater before paint coating (Nippon paint, weatherbond advance) and after paint coating has been measured by electrochemical studies such as Polarisation study and AC impedance spectra. It is observed that after paint coating, the corrosion resistance of mild steel hull plates increases. Polarization study reveals that after paint coating, the linear polarization resistance increases and corrosion current decreases. AC impedance spectra reveal that in the presence of paint coating charge transfer resistance value increases, impedance value increases, phase angle increases and double layer capacitance value decreases.
通过极化研究和交流阻抗谱等电化学研究,测定了低碳钢(在船舶技术中用于制造船体板)在涂漆前(Nippon油漆,weatherbond advance)和涂漆后在海水中的耐腐蚀性。观察到,涂漆后,软钢船体板的耐腐蚀性提高。极化研究表明,涂料涂层后,线极化电阻增大,腐蚀电流减小。交流阻抗谱显示,有涂料存在时,涂层电荷转移电阻值增大,阻抗值增大,相角增大,双层电容值减小。
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引用次数: 1
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Zastita materijala
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