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The quality of circulating water and its impact on the operation of heat exchange equipment at petrochemical enterprises 循环水质量及其对石化企业热交换设备运行的影响
Pub Date : 2024-07-11 DOI: 10.31660/0445-0108-2024-3-148-159
O. Deryugina, E. Skvortsova, A. L. Savhenkov, D. A. Belov
   The correct operation of heat exchange equipment has a direct impact on the quality of the products produced. The study of critical factors impeding the stable operation of equipment at petrochemical enterprises and the elimination of the main ones are of paramount importance. The primary challenge in the operation of heat exchange equipment is the quality of circulating water, which serves as the primary coolant. The analysis of circulating water and scale from an industrial site by the method of atomic emission spectrometry with inductively coupled plasma was performed, which made it possible to identify bottlenecks that impede the operation of the equipment. Scaling and the corrosive effects of water are the most detrimental. Furthermore, a methodology was devised to ascertain the elemental composition of solid deposits derived from heat exchange equipment. The malfunction of heat exchange equipment can give rise to significant issues in production. To prevent emergency production shutdowns, the authors of the article consider a method for improving the quality of circulating water by using the latest reagent, which can reduce the corrosive effect and reduce salt deposition inside heat exchangers. The proposed inhibitor offers a number of advantages, including a reduction in the environmental impact and high work efficiency.
热交换设备的正确运行直接影响到所生产产品的质量。研究阻碍石化企业设备稳定运行的关键因素并消除主要因素至关重要。热交换设备运行的首要挑战是作为主要冷却剂的循环水的质量。采用电感耦合等离子体原子发射光谱法对工业现场的循环水和水垢进行了分析,从而找出了阻碍设备运行的瓶颈。水垢和水的腐蚀作用是最有害的。此外,还设计了一种方法来确定热交换设备产生的固体沉积物的元素组成。热交换设备的故障会给生产带来重大问题。为了防止紧急停产,文章作者考虑了一种使用最新试剂改善循环水质量的方法,这种试剂可以降低腐蚀效果,减少热交换器内的盐沉积。所提出的抑制剂具有许多优点,包括减少对环境的影响和工作效率高。
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引用次数: 0
Study of phase evolution and microstructural features when modeling operating conditions of fuel cells based on lanthanum-strontium ferrite compounds 基于镧锶铁氧体化合物的燃料电池运行条件建模时的相变和微结构特征研究
Pub Date : 2024-07-11 DOI: 10.31660/0445-0108-2024-3-135-147
D. Borgekov, K. B. Kaliyekperova, A. Kozlovskiy, G. Moldabayeva
   Interest in lanthanum-strontium ferrite ceramics having mixed electron and oxygen-ion conductivity as well as good stability is due to the great potential for use as electrode materials for solid oxide fuel cells. The article presents the results of an assessment of alterations in the morphology and phase composition of ceramics based on lanthanum-strontium ferrite compounds obtained by solid-phase synthesis. This was done during simulation of conditions as close as possible to their operating conditions in the mode of elevated temperatures. The primary objective of the research is to alter theratio of the phase composition of ceramics under prolonged thermal exposure, simulating thermal ageing processes, and thus, oxidation processes that occur during long-term cyclic tests. The studies revealed that the presence of the Sr2Fe2O5 phase in the composition of ceramics results in enhanced resistance to corrosive oxidation processes during high-temperature corrosion. The data obtained on the change in the electrochemical characteristics of ceramics depending on the exposure time during the simulation of high-temperature degradation revealed that the most significant decreases were observed after 400-500 hours of consecutive tests at a temperature of 500-600 °C and after 250-300 hours at temperatures above 700 °C. Moreover, the reduction in the specific power is due to the formation of oxide inclusions in ceramics, resulting from the decomposition of the (La0.3Sr0.7)FeO4 phase in the composition of the ceramics. In turn, the presence of the Sr2Fe2O5 phase results in the formation of an oxidation-resistant structure, leading to less pronounced changes in specific power during measurement of parameters of electrochemical characteristics.
镧锶铁氧体陶瓷具有混合电子和氧离子传导性以及良好的稳定性,可用作固体氧化物燃料电池的电极材料,因此备受关注。文章介绍了对通过固相合成获得的基于镧锶铁氧体化合物的陶瓷的形态和相组成变化的评估结果。这项工作是在尽可能接近高温模式下的工作条件下模拟完成的。研究的主要目的是在长期热暴露条件下改变陶瓷相组成的热比率,模拟热老化过程,进而模拟在长期循环测试中发生的氧化过程。研究结果表明,陶瓷成分中含有 Sr2Fe2O5 相,可增强陶瓷在高温腐蚀过程中抵抗腐蚀性氧化过程的能力。在模拟高温降解过程中,陶瓷的电化学特性随暴露时间的变化而变化,所获得的数据显示,在温度为 500-600 °C 的条件下,经过 400-500 小时的连续试验后,以及在温度高于 700 °C 的条件下,经过 250-300 小时的试验后,陶瓷的电化学特性下降最为明显。此外,比功率的降低是由于陶瓷中氧化物夹杂物的形成,而氧化物夹杂物是由陶瓷成分中的(La0.3Sr0.7)FeO4 相分解产生的。反过来,由于 Sr2Fe2O5 相的存在,形成了抗氧化结构,导致在测量电化学特性参数时,比功率的变化不那么明显。
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引用次数: 0
The rationale behind the selection of objects for physical modeling based on geological and statistical data 根据地质和统计数据选择实物模型对象的理由
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-114-124
R. F. Sharafutdinov, A. S. Samoilov, N. Y. Kolotygina
   The intricate structure of the oil rim of oil and gas deposits is a determining factor in the peculiarities of its development. The exploitation of productive formations results in the depletion of oil reserves due to the uncontrolled withdrawal of gas. The application of an unbalanced oil withdrawal and waterflooding process results in a reduction in the oil recovery factor. The article considers the issue of enhancing the efficiency of oil rims exploitation technology, with a particular focus on the research conducted into the displacement process of oil by gas agents. The authors of the article present the applicability criteria of enhanced oil recovery technologies, which serve as a basis for selecting the method of stimulation of the reservoir based on its geological and physical characteristics. Additionally, the results of the technology efficiency assessment for each reservoir are presented, along with a justification for the application of enhanced oil recovery methods. Finally, the article justifies the choice of research objects based on the application of enhanced oil recovery methods for different fields. The results of the ranking led to the identification of the criteria that justified the sites for water-gas impact testing. The following sites were identified as suitable for water-gas impact testing: BU11 2 (Urengoy oil and gas condensate field), BT11 0, BT11 (Zapolyarnoye oil and gas condensate field), BU8-9 3 (Yen-Yakhinskoye oil and gas condensate field), BU9 2 (Pestsovoye oil and gas condensate field), PK1 (Tazovskoye oil and gas condensate field), ACh3 0, ACh3, ACh4, ACh5 (Yamburg oil and gas condensate field).
石油和天然气储藏的油缘结构错综复杂,是其开发特殊性的决定性因素。在开采高产地层时,由于无节制地开采天然气,导致石油储量枯竭。采用不平衡的采油和注水工艺会降低石油采收率。这篇文章探讨了提高油缘开采技术效率的问题,尤其侧重于对气剂置换石油过程的研究。文章作者提出了提高石油采收率技术的适用性标准,作为根据储层的地质和物理特征选择刺激储层方法的依据。此外,文章还介绍了每个油藏的技术效率评估结果,以及应用提高石油采收率方法的理由。最后,文章根据不同油田强化采油方法的应用情况,说明了选择研究对象的理由。根据排序结果,确定了水气影响测试地点的标准。以下地点被确定为适合进行水气影响试验:BU11 2(Urengoy 油气凝析油田)、BT11 0、BT11(Zapolyarnoye 油气凝析油田)、BU8-9 3(Yen-Yakhinskoye 油气凝析油田)、BU9 2(Pestsovoye 油气凝析油田)、PK1(Tazovskoye 油气凝析油田)、ACh3 0、ACh3、ACh4、ACh5(Yamburg 油气凝析油田)。
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引用次数: 0
Problems of studying deposits with cross-border territories: a case study of the Krasnoleninskoye oil and gas condensate field (in the form of a discussion) 跨界矿藏研究问题:克拉斯诺列宁斯阔耶油气凝析油田案例研究(讨论形式)
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-24-32
A. А. Kungurov, L. K. Alimchanova
   The territorial affiliation of one field to different subsurface users gives rise to a number of problems when calculating hydrocarbon reserves and justifying calculation parameters. This is due to the lack of complete information on a cross-border field from one owner of the subsoil.   The aim of the article is to demonstrate the problems of modeling and calculating reserves of cross-border deposits and proposals for their solution. The article briefly describes the history of geological exploration at the Krasnoleninskoye oil and gas condensate field and the history of modeling and calculating reserves.   The difference in the correlation of productive layers is shown. Various methods of delineation of deposits within subsurface use sites are considered. The difficulties of modeling due to the presence of several subsurface users of one cross-border deposit are listed. Specific examples of problems of matching models and calculation of reserves of two subsurface users are given. The problem of combining several fields based on the results of geological exploration is outlined. Conclusions are drawn about the advantages of a single model of cross-border deposits and their benefits for the state. The solution to the problem is the exchange of accumulated geological and commercial information between neighboring subsoil users and an agreement on joint actions to study the field, including work on estimating reserves and on design solutions. Consequently, a unified geological model of the deposit will be established, along with uniform methodologies for classification, mining fund allocation, and the optimal distribution of production. Additionally, the resolution of tax authority-related issues will be facilitated.
在计算油气储量和确定计算参数时,一个油气田隶属于不同的地下用户会产生一些问题。这是由于缺乏来自一个地下所有者的关于跨境油气田的完整信息。 文章旨在说明跨境矿藏储量建模和计算的问题以及解决这些问题的建议。文章简要介绍了 Krasnoleninskoye 油气凝析油田的地质勘探历史以及储量建模和计算历史。 文章显示了生产层相关性的差异。考虑了在地下使用地点内划分矿藏的各种方法。列举了由于一个跨境矿床存在多个地下使用者而造成的建模困难。举例说明了两个地下使用者的模型匹配和储量计算问题。概述了根据地质勘探结果将几个油气田结合起来的问题。就跨境矿藏单一模型的优势及其对国家的益处得出了结论。解决问题的办法是在相邻的底土使用者之间交换积累的地质和商业信息,并就联合行动研究油田(包括储量估算和设计方案)达成协议。因此,将建立一个统一的矿藏地质模型,以及统一的分类、采矿资金分配和生产优化分配方法。此外,还将促进解决与税务部门有关的问题。
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引用次数: 0
An assessment of the potential of polymer flooding at an oil field in Western Siberia 西西伯利亚西部一个油田的聚合物淹没潜力评估
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-73-82
D. N. Zolnikov
   The operational object under study has a high current water-cut and is at the final stage of development.   The aim of the study is to assess the potential for polymer flooding at the object X of the deposit C through hydrodynamic calculations.   Hydrodynamic modeling is performed on a synthetic model cut from a sector model of the reservoir. This model meets the criteria for selecting sites, corresponds to the parameters of a full-scale model. However, it is more detailed, which is why it was chosen to substantiate the effectiveness of polymer flooding. The model specifies the actual well location, which is in the most characteristic zone of the reservoir with the actual development system. The results of the hydrodynamic calculations demonstrated the technological efficiency of polymer flooding at the object X. The increase in the oil recovery factor was 1.85 %. Further plans include further laboratory studies of polymer solution properties, an economic assessment to select the optimal concentration and volume of polymer solution injection, and a decision on conducting pilot work.
所研究的作业对象具有较高的水流断面,处于开发的最后阶段。 研究的目的是通过流体力学计算,评估聚合物淹没矿床 C 的 X 对象的可能性。 水动力建模是在一个从水库扇形模型中切割出来的合成模型上进行的。该模型符合选址标准,与全尺寸模型的参数一致。不过,它更为详细,这也是选择它来证实聚合物淹没的有效性的原因。该模型指定了实际的井位,即实际开发系统中储层最具特征的区域。流体力学计算的结果表明,聚合物注水在 X 对象处的技术效率很高,采油系数提高了 1.85%。进一步的计划包括对聚合物溶液特性进行进一步的实验室研究,进行经济评估以选择最佳的聚合物溶液注入浓度和注入量,以及决定是否进行试点工作。
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引用次数: 0
Simulating the reservoir pressure maintenance strategy by injecting HC and non-HC gases into the Achimov reservoirs 通过向 Achimov 储层注入碳氢化合物和非碳氢化合物气体模拟储层压力维持战略
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-83-99
A. S. Rusanov, A. S. Romanov, E. A. Reitblat, D. N. Glumov
   Prerequisites for the study are selection of the optimal agent to maintain reservoir pressure and setting the optimal conditions under which the maximum condensate recovery factor is achieved.   The aim of the article is to assess the technological efficiency of methods for increasing condensate recovery while maintaining reservoir pressure by injecting hydrocarbon (methane) and non-hydrocarbon (nitrogen, carbon dioxide) gases.   The subject of this study is the Ach3-4 reservoir within the Novo-Urengoyskoye license area of the Urengoy field. The most effective methodology for identifying the stated issue is the outcome of hydrodynamic calculations conducted on a composite hydrodynamic model implemented in ECLIPSE 300 format. In order to model one of the sections of the Ach3-4 reservoir, a development element was selected in which the average parameters corresponded to those of the full-scale model. The efficiency of the selected methods was evaluated by comparing them with the baseline scenario, which represents the conventional approach to the development of the Ach3-4 reservoir on depletion. The injection start was set in a dynamic model after removal of 30, 50 and 85 % of gas initially in-place and at a steady pressure of 18, 37 and 40 MPa, provided that gas recovery factor was achieved on depletion. The technological efficiency of the development options was evaluated by examining the dynamics of the condensate recovery factor in relation to the dynamics of the gas recovery factor. The optimal option was identified based on the maximum value of the condensate recovery factor. The results of the studies conducted to increase condensate recovery from reservoirs indicate the effectiveness of using carbon dioxide as an agent. The condensate recovery factor depends on the ratio of injection and production wells, the time of the start of reservoir pressure maintenance and the number of pore volumes pumped. The efficiency of carbon dioxide injection at late stages of development increases dramatically when the minimum mixing pressure is reached.
研究的先决条件是选择维持储层压力的最佳剂型,并设定实现最大凝析油采收率的最佳条件。 文章旨在评估通过注入碳氢化合物(甲烷)和非碳氢化合物(氮气、二氧化碳)气体在保持储层压力的同时提高凝析油回收率的方法的技术效率。 本研究的对象是乌连可依油田新乌连可依斯克耶许可证区内的 Ach3-4 油藏。确定所述问题的最有效方法是在 ECLIPSE 300 格式的复合流体力学模型上进行流体力学计算的结果。为了模拟 Ach3-4 储油层的一个区段,选择了一个开发要素,其平均参数与全尺寸模型的参数一致。所选方法的效率是通过与基线方案进行比较来评估的,基线方案代表了在枯竭时开发 Ach3-4 储层的常规方法。在动态模型中,注入起始点被设定在去除 30%、50% 和 85%的初始就地天然气之后,稳定压力为 18、37 和 40 兆帕,条件是在耗竭时达到天然气采收率。通过研究凝析油回收率与天然气回收率的动态关系,对开发方案的技术效率进行了评估。根据凝析油回收率的最大值确定了最佳方案。为提高储油层的凝析油回收率而进行的研究结果表明,使用二氧化碳作为添加剂是有效的。凝析油回收系数取决于注入井和生产井的比例、储层压力维持开始的时间以及抽吸孔隙体积的数量。当达到最低混合压力时,开发后期注入二氧化碳的效率会显著提高。
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引用次数: 0
Experience in seismic facies analysis application during prospecting and exploration 在探矿和勘探过程中应用地震剖面分析的经验
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-58-72
A. M. Sheshukova, E. V. Smirnova, S. V. Vasyanina
   Issues of practical application of the results of seismic facies analysis are of concern to subsoil users and specialists from scientific institutes in the oil and gas industry. It is not always evident what contribution this work makes to the outcome of geological modeling and what significance it has when integrating materials from areal seismic studies, geophysical well surveys andcore data. At the same time, interest in this type of work decreases as fields are drilled, although with increasing well data, the reliability of the results of seismic facies analysis increases significantly, and additional opportunities arise to search for promising and undeveloped zones of the deposit.   In this regard, the main objective of the article is to remind the public of the importance of this component of geological modeling, to illustrate the practical applications of seismic facies analysis, and to present various approaches to seismic facies mapping.   The article describes approaches to seismic facies analysis at different stages of exploration of promising areas and fields, taking into account 2D and 3D seismic exploration. It is noted that the use of neural networks for calculating seismic classes makes it possible to work with different input data, including volumetric cubes of digital material and two-dimensional maps constructed from the results of seismic exploration. Attention is a paid to the role of seismic facies analysis in creating geological models and assessing the resource base. An option is a shown for calculating a three-dimensional cube of lithology and reservoir properties taking into account seismic facies analysis and lithofacies analysis with a brief description of modeling algorithms. The impact of seismic facies analysis and lithofacies analysis results on the distribution of reservoirs within the three-dimensional geological model is illustrated through the example of the simulation area. Furthermore, the mapping of zones of probable claying of the productive formation is demonstrated.
地震剖面分析结果的实际应用问题是底土使用者和石油天然气行业科研机构专家所关心的。这项工作对地质建模的结果有什么贡献,在综合全区地震研究、地球物理井调查和岩心数据时有什么意义,这些问题并不总是很明显。同时,虽然随着钻井数据的增加,地震剖面分析结果的可靠性显著提高,并有更多机会寻找有潜力和未开发的矿床带,但随着油田的钻探,对这类工作的兴趣却在下降。 在这方面,文章的主要目的是提醒公众注意地质建模中这一部分的重要性,说明地震剖面分析的实际应用,并介绍地震剖面绘图的各种方法。 文章结合二维和三维地震勘探,介绍了在有前景地区和油气田勘探的不同阶段进行地震剖面分析的方法。文章指出,使用神经网络计算地震类别可以处理不同的输入数据,包括数字材料的体积立方体和根据地震勘探结果绘制的二维地图。地震剖面分析在创建地质模型和评估资源基础方面的作用受到了关注。介绍了计算岩性和储层属性的三维立方体的方法,同时考虑了地震剖面分析和岩性分析,并简要介绍了建模算法。以模拟区为例,说明了地震剖面分析和岩性分析结果对三维地质模型中储层分布的影响。此外,还展示了产层可能的粘土区分布图。
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引用次数: 0
New approaches to the technology of acid treatment of the bottomhole zone without setting up of workover 在不进行修井的情况下对井底区域进行酸处理的新技术方法
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-125-134
A. B. Yumachikov, M. V. Fudashkina, E. N. Malshakov, M. N. Vilkov, I. I. Khakimov, K. V. Solodovnikov
   The article considers the experience of applying bottomhole zone treatment technology without setting up of workover, and reveals the problem of a lack of significant effect of the measures. Proposals for the simplification of technology have been formulated, an instruction for implementation and a register of designs of contactless treatments for solving a wide range of tasks related to bottomhole zone treatment has been developed. Following the selection of candidate wells and the testing of the developed approaches, a benchmarking exercise was conducted at LUKOIL-West Siberia LLC. The work performed led to an increase in the efficiency and economic profitability of contactless treatment.
文章介绍了在不进行修井的情况下应用井底区域处理技术的经验,揭示了措施效果不明显的问题。文章提出了简化技术的建议,制定了实施指南和非接触式处理设计登记册,以解决与井底区域处理有关的各种任务。在选定候选井并对开发的方法进行测试后,在卢克石油西西伯利亚有限责任公司进行了基准测试。这项工作提高了非接触式处理的效率和经济效益。
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引用次数: 0
A forecast of the gas saturation factor in the NB1 layer of Upper Cretaceous deposits within the Nadym-Pur-Taz region of West Siberia 西西伯利亚纳定姆-普尔-塔兹地区上白垩统矿床 NB1 层气体饱和系数预测
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-11-23
T. V. Glukhov
   The investigation of Upper Cretaceous siliceous deposits in West Siberia represents an unconventional problem. The solution to this problem necessitates the utilisation of specialised well logging methods in order to obtain the valuable results. In these circumstances, forecast methods that based on a priori data become important because they allow us to identify high-priority objects for further exploration.   The aim of this research is to make a forecast of the gas saturation factor in the NB1 layer of Upper Cretaceous deposits within the Nadym-Pur-Taz region under conditions of well-data shortage.   The new forecast and mapping method for the volumetric humidity coefficient that based on a priori data is proposed. Consequently, a correlation was identified between the volumetric humidity coefficient and the present depth of deposits. The correlation depends on intensity of silica phase transformation process. The observed dependence is attributed to the tectonic history of the region, specifically the period following the deposition of the NB1 layer siliceous deposits. The gas saturation factor forecast map allows us to identify areas with potential of high gas bearing capacity.
西西伯利亚上白垩统硅质矿床的勘探是一个非常规问题。要解决这个问题,就必须使用专门的测井方法,以获得有价值的结果。在这种情况下,基于先验数据的预测方法变得非常重要,因为这些方法可以让我们确定进一步勘探的优先对象。 本研究的目的是在缺乏油井数据的情况下,预测纳定姆-普尔-塔兹地区上白垩统矿床 NB1 层的天然气饱和系数。 提出了基于先验数据的体积湿度系数预测和绘图新方法。因此,确定了体积湿度系数与目前矿床深度之间的相关性。这种相关性取决于二氧化硅相变过程的强度。观察到的相关性归因于该地区的构造历史,特别是 NB1 层硅质沉积后的时期。通过天然气饱和度系数预测图,我们可以确定具有高含气能力潜力的地区。
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引用次数: 0
Developing neural network analysis technology for the resolution of issues in oil and gas geophysics 开发神经网络分析技术,解决石油和天然气地球物理问题
Pub Date : 2024-07-10 DOI: 10.31660/0445-0108-2024-3-44-57
S. K. Turenko
   Neural network analysis represents a promising avenue for enhancing the efficacy of petroleum geophysics and the oil and gas industry. The analysis of the obtained experience of using the available neural network analysis methods and software packages in solving problems of oil and gas geophysics shows the absence of a significant (breakthrough) effect. In order to achieve a significant effect, it is proposed to move from methods to neural network analysis technologies. The article presents a fundamental framework for neural network analysis technology in the context of oil and gas geophysics. This includes a neural network designer, a subsystem for training geophysicists in the field of neural network analysis, a digital polygon, and a knowledge base comprising tasks, neural network analysis methods, techniques, and experience in solving applied problems. The elements of the proposed technology and their interrelation are discussed in detail. The pilot version of the proposed technology, which includes its principal elements, is initially described in terms of its orientation towards the training of specialists. The results of the pilot version's approval have demonstrated the efficacy of the proposed technology. The scientific and technological priorities of the proposed technology development have been delineated.
神经网络分析是提高石油地球物理和石油天然气工业效率的一条大有可为的途径。对使用现有神经网络分析方法和软件包解决石油和天然气地球物理问题的经验进行的分析表明,没有取得显著的(突破性的)效果。为了取得显著效果,建议从方法转向神经网络分析技术。文章介绍了石油和天然气地球物理学中神经网络分析技术的基本框架。其中包括一个神经网络设计器、一个用于培训神经网络分析领域地球物理学家的子系统、一个数字多边形,以及一个由任务、神经网络分析方法、技术和解决应用问题的经验组成的知识库。详细讨论了拟议技术的要素及其相互关系。首先介绍了拟议技术的试验版本,其中包括其主要元素,该版本面向专家培训。试验版本的批准结果表明了拟议技术的有效性。对拟议技术开发的科学和技术重点进行了界定。
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引用次数: 0
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Oil and Gas Studies
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