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Enhanced catalytic degradation of acetaminophen using magnesium oxide-infused clay with ultrasonic activation of hydrogen peroxide 利用注入氧化镁的粘土和过氧化氢的超声波活化,增强对乙酰氨基酚的催化降解能力
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-06 DOI: 10.1016/j.arabjc.2024.106047
Roshana Rashidi , Seyed Hamed Meraji , Amin Mahmoudi , Ali Mohammad Sanati , Bahman Ramavandi
In this study, clay modified with magnesium oxide (MgO) was used as a catalyst for the degradation of acetaminophen in wastewater, activated by hydrogen peroxide (H2O2) and ultrasonic waves. Characterization of the Clay-MgO catalyst was conducted using TGA, XRD, BET, SEM, FTIR, XRF, and EDX, revealing functional groups capable of activating H2O2. The crystalline catalyst, synthesized at 500 °C, had a surface area of 30 m2/g. Optimal conditions for acetaminophen removal, achieving 75 % efficiency, were pH 8, 3 g/L catalyst, 0.2 mL/100 mL H2O2, and 60 min of contact time. In distilled water, mineralization of acetaminophen was 42 %, while actual wastewater showed 18 %. Hydroxyl radicals played a significant role in the degradation process. The catalyst was tested for reuse up to six times and maintained a high efficiency of over 53 % in five stages. Radical scavenger studies confirmed the importance of hydroxyl radicals in the degradation kinetics, which followed pseudo-first-order (R2 > 0.96) and Langmuir-Hinshelwood (R2 = 0.95) models. The catalyst also demonstrated efficient acetaminophen removal in complex solutions, including seawater. This MgO-modified clay shows promise as an effective catalyst for the degradation of pharmaceutical pollutants through hydrogen peroxide activation, maintaining stability and reusability across multiple cycles.
本研究使用氧化镁(MgO)修饰的粘土作为催化剂,在过氧化氢(H2O2)和超声波的作用下降解废水中的对乙酰氨基酚。使用 TGA、XRD、BET、SEM、傅里叶变换红外光谱、XRF 和 EDX 对粘土-氧化镁催化剂进行了表征,发现了能够活化 H2O2 的官能团。在 500 °C 下合成的结晶催化剂的表面积为 30 m2/g。去除对乙酰氨基酚的最佳条件为 pH 值 8、3 g/L 催化剂、0.2 mL/100 mL H2O2 和 60 分钟的接触时间,去除效率为 75%。在蒸馏水中,对乙酰氨基酚的矿化度为 42%,而实际废水的矿化度为 18%。羟基自由基在降解过程中发挥了重要作用。经测试,该催化剂可重复使用六次,并在五个阶段中保持了 53% 以上的高效率。自由基清除剂研究证实了羟基自由基在降解动力学中的重要性,降解动力学遵循伪一阶(R2 > 0.96)和 Langmuir-Hinshelwood (R2 = 0.95)模型。该催化剂还能在包括海水在内的复杂溶液中高效去除对乙酰氨基酚。这种氧化镁改性粘土有望成为一种有效的催化剂,通过过氧化氢活化降解制药污染物,并在多次循环中保持稳定性和可重复使用性。
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引用次数: 0
Design and research of new virulence factor inhibitors for plant bacterial disease control 设计和研究用于植物细菌病害控制的新型毒力因子抑制剂
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1016/j.arabjc.2024.106042
Wei Zeng, Zhiling Sun, Yi Liu, Qing Zhou, Yufang Zhang, Yujiao Qiu, Hong Fu, Hongqian Zou, Haotao Pu, Wei Xue
In this work, various chalcone derivatives incorporating piperazine-isopropanolamine were elaborately designed and synthesized. The antibacterial efficacy revealed that compound Z6 showed notable biological activity, with a median effective concentration (EC50) of 0.29 mg/L against Xanthomonas oryzae pv. oryzae (Xoo) in vitro, which is around 200 times higher than thiodiazole copper (TC, 91.00 mg/L). Similarly, Z21 exhibited a strong biological response (EC50 = 0.83 mg/L) against Xanthomonas axonopodis pv. citri (Xac), outperforming TC (EC50 = 114.60 mg/L). Results of bioactivity test in vivo demonstrate that Z6 displayed significantly better curative and protective activities (51.5 %, 47.9 %) than TC (47.9 %, 30.5 %) against rice bacterial leaf blight (BLB). Further biochemical studies indicates that Z6 targeted multiple virulence factors and repressed the release of essential nutrients required for bacterial proliferation, thereby disrupting the reduction of cell membrane content of the pathogenic bacteria. According to the research, chalcone derivatives containing piperazine-isopropanolamine have potential to be antibacterial candidates.
本研究精心设计并合成了多种含有哌嗪-异丙醇胺的查尔酮衍生物。抗菌效果显示,化合物 Z6 表现出显著的生物活性,体外对黄单胞菌(Xanthomonas oryzae pv. oryzae,Xoo)的中位有效浓度(EC50)为 0.29 mg/L,比硫二唑铜(TC,91.00 mg/L)高出约 200 倍。同样,Z21 对黄单胞菌(Xanthomonas axonopodis pv. citri,Xac)的生物反应也很强(EC50 = 0.83 mg/L),超过了 TC(EC50 = 114.60 mg/L)。体内生物活性测试结果表明,Z6 对水稻细菌性叶枯病(BLB)的治疗和保护活性(51.5 %、47.9 %)明显优于 TC(47.9 %、30.5 %)。进一步的生化研究表明,Z6 针对多种毒力因子,抑制细菌增殖所需的基本营养物质的释放,从而破坏病原菌细胞膜含量的减少。研究表明,含有哌嗪-异丙醇胺的查尔酮衍生物具有抗菌潜力。
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引用次数: 0
A bone-targeting delivery platform based on mesoporous silica loaded with piR7472 for the treatment of osteoporosis 基于装载 piR7472 的介孔二氧化硅的骨靶向递送平台,用于治疗骨质疏松症
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-02 DOI: 10.1016/j.arabjc.2024.106040
Long Yubin , Ma Yuan , Yang Houzhi , Wang Xiangbin , Fan Jigeng , Li Yong , Tao Bo , Sun Tianwei
Promoting osteogenic differentiation and inhibiting osteoclast formation remain significant challenges in the treatment of osteoporosis. With the growing understanding of osteoporosis, increasing literature has highlighted the regulatory role of m6A methylation in this condition. However, there is currently no reliable method to stably regulate cellular m6A methylation levels. Here, we report a novel approach utilizing alendronate (aln)-modified mesoporous silica nanoparticles (MSNs) to deliver sodium bicarbonate and piR7472, modulating cellular behavior. Our experimental results demonstrate that Aln modification enables the nanoparticles to stably target hydroxyapatite, thereby accumulating in osteoporotic regions. Sodium bicarbonate suppresses osteoclastogenesis, while piR7472 enhances m6A methylation, promoting osteogenic differentiation of bone marrow stromal cells (BMSCs). Computed tomography (CT) and hematoxylin and eosin (HE) staining showed that after 2 weeks of treatment with MSNs-Na@piR7472, cortical bone thickened, trabecular bone density increased, collagen fiber thickness improved, and both the number and staining area of osteoclasts were significantly reduced. These findings indicate a marked improvement in osteoporosis.
促进成骨细胞分化和抑制破骨细胞形成仍然是治疗骨质疏松症的重大挑战。随着人们对骨质疏松症的认识不断加深,越来越多的文献强调了 m6A 甲基化在骨质疏松症中的调节作用。然而,目前还没有稳定调节细胞 m6A 甲基化水平的可靠方法。在此,我们报告了一种利用阿仑膦酸盐(aln)修饰的介孔二氧化硅纳米颗粒(MSNs)来递送碳酸氢钠和 piR7472 并调节细胞行为的新方法。我们的实验结果表明,Aln修饰能使纳米颗粒稳定地靶向羟基磷灰石,从而在骨质疏松区域积聚。碳酸氢钠能抑制破骨细胞的生成,而 piR7472 能增强 m6A 甲基化,促进骨髓基质细胞(BMSCs)的成骨分化。计算机断层扫描(CT)和苏木精及伊红(HE)染色显示,使用 MSNs-Na@piR7472 治疗 2 周后,皮质骨增厚,骨小梁密度增加,胶原纤维厚度改善,破骨细胞的数量和染色面积显著减少。这些发现表明骨质疏松症得到了明显改善。
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引用次数: 0
Reaction mechanism study of calcium carbide residue with graphene oxide in aqueous environment: Adsorption properties and mechanical potentials 电石残渣与氧化石墨烯在水环境中的反应机理研究:吸附特性和机械电位
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1016/j.arabjc.2024.106038
Na Li , Meixin Fan , Ping Jiang , Yingdi Pang , Song Yang , Wei Wang
Graphene Oxide (GO) is widely used, but its hydrophilic properties make it difficult to remove once it enters water and soil environments. In this paper, the adsorption effect of calcium carbide residue (CCR) as adsorbent on GO was investigated through a series of adsorption tests. Adsorption thermodynamics, kinetics, isotherm models, and various characterization techniques were employed to explore the adsorption mechanism. Additionally, the study assessed CCR’s ability to stabilize GO-contaminated soils through unconfined compressive strength tests. The results showed that (1) at T = 303 K, with a pH of 11 and an initial GO concentration of 80 mg/L, CCR demonstrated excellent adsorption performance. (2) The adsorption process followed the Langmuir isotherm and a quasi-second-order kinetic model, indicating chemical adsorption with spontaneous heat adsorption. (3) CCR not only acts as an effective adsorbent for removing GO from wastewater but also has the potential to strengthen GO-contaminated soils. In addition, due to its favorable environmental benefits, this study has a wide range of potential applications in industrial fields such as wastewater treatment, air purification, and energy storage and conversion. This study not only proposes an effective method for removing graphene oxide from aqueous environments, but also provides a new idea for waste resource utilization, which helps to achieve the dual goals of environmental protection and resource reuse.
氧化石墨烯(GO)被广泛应用,但其亲水性使其进入水和土壤环境后难以去除。本文通过一系列吸附试验,研究了电石渣(CCR)作为吸附剂对 GO 的吸附效果。研究采用了吸附热力学、动力学、等温线模型和各种表征技术来探索吸附机理。此外,研究还通过无约束抗压强度测试评估了 CCR 稳定受 GO 污染土壤的能力。结果表明:(1)在 T = 303 K、pH 值为 11、初始 GO 浓度为 80 mg/L 的条件下,CCR 表现出优异的吸附性能。(2)吸附过程遵循 Langmuir 等温线和准二阶动力学模型,表明具有自发吸热的化学吸附作用。(3) CCR 不仅是去除废水中 GO 的有效吸附剂,还具有强化被 GO 污染的土壤的潜力。此外,由于其良好的环境效益,本研究在废水处理、空气净化、能源储存和转换等工业领域也有广泛的潜在应用前景。本研究不仅提出了一种从水环境中去除氧化石墨烯的有效方法,还为废物资源化利用提供了一种新思路,有助于实现环境保护和资源再利用的双重目标。
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引用次数: 0
Identification of Miscanthus floridulus as a promising anti-Alzheimer’s disease and antidiabetic agent through bioactivity evaluations and chemical composition analyses 通过生物活性评估和化学成分分析,确定花叶木属植物是一种很有前景的抗阿尔茨海默病和抗糖尿病药物
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-29 DOI: 10.1016/j.arabjc.2024.106037
Dingping Zhao , Qijun Dai , Yuanyuan Zhang , Hongjian Shen , Yan Mao , Xianxian Zhou , Xiqing Chen , Hanqing pang , Hui Wang , Liang Liu
The Poaceae family, the fifth largest family of angiosperms, has always been an important source of cereal crops, medicinal crops, and industrial crops. However, comprehensive studies on the biological activity and chemical composition of many species are lacking. In the present study, we tested the total flavonoid and total phenol contents and antioxidant, α-glycosidase, α-amylase, acetylcholinesterase (AChE), and butyrylcholinesterase (BChE)-inhibitory activities of five Poaceae plants (Echinochloa crus-galli, Miscanthus floridulus, Sporobolus fertilis, Bromus japonicus, and Eleusine indica). As a result, the 95 % ethanol (EtOH) extract of M. floridulus (EMF) was found to possess strongest abovementioned activities among the extracts of the five different species. The IC50 value of the DPPH radical scavenging activity was 23.18 ± 0.36 μg/mL, and those of the anti-AChE, anti-BChE and anti-α-glycosidase activities were 49.92 ± 1.44, 100.37 ± 2.48, and 50.01 ± 2.15 μg/mL, respectively. Forty-four compounds were identified from the EMF through liquid chromatography–hybrid ion trap-time of flight mass spectrometry (LC–IT–TOF–MS) analysis, and the majority of these compounds were flavonoids and organic acids. In general, the obtained results highlight the medicinal value of the five members of the Poaceae family. More importantly, M. floridulus has potential for the development of multitarget anti-Alzheimer’s disease (AD) and antidiabetic agents in the pharmaceutical industry.
被子植物的第五大家族--禾本科植物一直是谷类作物、药用作物和工业作物的重要来源。然而,对许多物种的生物活性和化学成分缺乏全面的研究。在本研究中,我们测试了五种蒲科植物(Echinochloa crus-galli、Miscanthus floridulus、Sporobolus fertilis、Bromus japonicus 和 Eleusine indica)的总黄酮和总酚含量以及抗氧化、α-糖苷酶、α-淀粉酶、乙酰胆碱酯酶(AChE)和丁酰胆碱酯酶(BChE)抑制活性。结果发现,在这五种不同物种的提取物中,花叶木的 95% 乙醇(EtOH)提取物(EMF)具有最强的上述活性。DPPH自由基清除活性的IC50值为23.18 ± 0.36 μg/mL,抗ACHE、抗BCHE和抗α-糖苷酶活性的IC50值分别为49.92 ± 1.44、100.37 ± 2.48和50.01 ± 2.15 μg/mL。通过液相色谱-混合离子阱飞行时间质谱(LC-IT-TOF-MS)分析,从 EMF 中鉴定出 44 种化合物,其中大部分为黄酮类化合物和有机酸。总体而言,所获得的结果凸显了五种蒲葵科植物的药用价值。更重要的是,M. floridulus 具有开发多靶点抗阿尔茨海默病(AD)和抗糖尿病药物的制药潜力。
{"title":"Identification of Miscanthus floridulus as a promising anti-Alzheimer’s disease and antidiabetic agent through bioactivity evaluations and chemical composition analyses","authors":"Dingping Zhao ,&nbsp;Qijun Dai ,&nbsp;Yuanyuan Zhang ,&nbsp;Hongjian Shen ,&nbsp;Yan Mao ,&nbsp;Xianxian Zhou ,&nbsp;Xiqing Chen ,&nbsp;Hanqing pang ,&nbsp;Hui Wang ,&nbsp;Liang Liu","doi":"10.1016/j.arabjc.2024.106037","DOIUrl":"10.1016/j.arabjc.2024.106037","url":null,"abstract":"<div><div>The Poaceae family, the fifth largest family of angiosperms, has always been an important source of cereal crops, medicinal crops, and industrial crops. However, comprehensive studies on the biological activity and chemical composition of many species are lacking. In the present study, we tested the total flavonoid and total phenol contents and antioxidant, α-glycosidase, α-amylase, acetylcholinesterase (AChE), and butyrylcholinesterase (BChE)-inhibitory activities of five Poaceae plants (<em>Echinochloa<!--> <!-->crus-galli</em>, <em>Miscanthus<!--> <!-->floridulus</em>, <em>Sporobolus<!--> <!-->fertilis</em>, <em>Bromus<!--> <!-->japonicus</em>, and <em>Eleusine<!--> <!-->indica</em>). As a result, the 95 % ethanol (EtOH) extract of <em>M.<!--> <!-->floridulus</em> (EMF) was found to possess strongest abovementioned activities among the extracts of the five different species. The IC<sub>50</sub> value of the DPPH radical scavenging activity was 23.18 ± 0.36 μg/mL, and those of the anti-AChE, anti-BChE and anti-α-glycosidase activities were 49.92 ± 1.44, 100.37 ± 2.48, and 50.01 ± 2.15 μg/mL, respectively. Forty-four compounds were identified from the EMF through liquid chromatography–hybrid ion trap-time of flight mass spectrometry (LC–IT–TOF–MS) analysis, and the majority of these compounds were flavonoids and organic acids. In general, the obtained results highlight the medicinal value of the five members of the Poaceae family. More importantly,<!--> <em>M.<!--> <!-->floridulus</em> has potential for the development of multitarget anti-Alzheimer’s disease (AD) and antidiabetic agents in the pharmaceutical industry.</div></div>","PeriodicalId":249,"journal":{"name":"Arabian Journal of Chemistry","volume":"17 12","pages":"Article 106037"},"PeriodicalIF":5.3,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of modified silica gel supported silver nanoparticles and its evaluation using zone of inhibition for water disinfection 改性硅胶支撑银纳米粒子的制备及其用于水消毒的抑菌区评估
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-28 DOI: 10.1016/j.arabjc.2024.106036
Belete Tessema , Girma Gonfa , Sintayehu Mekuria Hailegiorgis
In this work, preparation of modified silica gel supported silver nanoparticles and its evaluation using zone of inhibition for water disinfection were investigated. The silica contents of the teff straw [TS] and teff straw ash [TSA] are 5.92 and 92.21 %, respectively. The calcinated TS ash at 700 °C was mixed with NaOH solution. The solution is then neutralized with HCl solution and then gel formation using the sol gel method. The silica gel yield was recorded and characterized. The SG with major silica functional group, amorphous structure, high porosity from the morphology, high surface area of 807.163 m2/g, pore volume of 0.34 cm3/g, pore diameter of 1.70 nm and silica gel purity of 99.39 % were achieved at a calcination temperature of 700 °C. It is then; further modified using trimethylchlorosilane (TMCS)/ethanol/hexane at different volumetric ratio and the resulting product is modified silica gel (MSG). MSG has excellent hydrophobic properties that have been required during water treatment. In this method, MSG with a major silica functional group, well ordered structure due to the TMCS modifier, maximum surface area of 510.40 m2/g was achieved at volumetric ratio of 0.25:0.25:1 of TMCS/ethanol/hexane, respectively. Then, MSG supported AgNPs (MSG-AgNPs) was prepared by mixing different concentrations of AgNPs-MSG and characterized. The MSG-AgNPs have shown AgNPs on the surface of MSG from the EDX result, different absorbance, pore from the morphology, with a maximum surface area of 475.0 m2/g was obtained at 1.5 mM of AgNPs concentrations. The performance of MSG-AgNPs was evaluated using zone of inhibition measurement and batch disinfection studies against E. coli and S. aureus. At 1.5 x 108 CFU/mL initial bacterial concentrations, the maximum inhibition zone diameter was 12.80 and 14.30 mm for E. coli and S. aureus, respectively.
在这项工作中,研究了改性硅胶支撑银纳米粒子的制备,并利用抑制区对其进行了水消毒评估。茶秸秆 [TS] 和茶秸秆灰 [TSA] 的二氧化硅含量分别为 5.92 % 和 92.21 %。在 700 °C 下煅烧的 TS 灰与 NaOH 溶液混合。然后用盐酸溶液中和溶液,再用溶胶凝胶法形成凝胶。硅胶产量被记录下来并进行了表征。在 700 °C 的煅烧温度下,硅胶具有主要的二氧化硅官能团、无定形结构、高孔隙率形态、高表面积(807.163 m2/g)、孔体积(0.34 cm3/g)、孔直径(1.70 nm)和纯度(99.39 %)。然后,使用不同体积比的三甲基氯硅烷(TMCS)/乙醇/正己烷对其进行进一步改性,得到改性硅胶(MSG)。MSG 具有水处理过程中所需的优异疏水性能。在该方法中,TMCS 改性剂使 MSG 具有主要的二氧化硅官能团和良好的有序结构,TMCS/乙醇/己烷的体积比分别为 0.25:0.25:1 时,MSG 的最大表面积为 510.40 m2/g。然后,将不同浓度的 AgNPs-MSG 混合,制备出 MSG 支持的 AgNPs(MSG-AgNPs),并对其进行了表征。在 1.5 mM 的 AgNPs 浓度下,MSG-AgNPs 的最大比表面积为 475.0 m2/g。利用抑菌区测量和批量消毒研究评估了味精-AgNPs 对大肠杆菌和金黄色葡萄球菌的性能。在初始细菌浓度为 1.5 x 108 CFU/mL 时,大肠杆菌和金黄色葡萄球菌的最大抑菌区直径分别为 12.80 毫米和 14.30 毫米。
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引用次数: 0
Terbium metal–organic frameworks for the efficient removal of tartrazine food dye from aquatic systems: Thermodynamics, kinetics, isotherm, and box-behnken design optimization 铽金属有机框架用于高效去除水生系统中的酒石酸食品染料:热力学、动力学、等温线和箱式优化设计
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-26 DOI: 10.1016/j.arabjc.2024.106035
Omaymah Alaysuy , Abdullah Ali A. Sari , Albandary Almahri , Kamelah S. Alrashdi , Ibrahim S.S. Alatawi , Meshari M. Aljohani , Ali Sayqal , Nashwa M. El-Metwaly
The elimination and removal of the yellow food coloring tartrazine dye E-102 (TZ) from aqueous solutions was conducted using stacked nanorods made of Terbium metal–organic frameworks (Tb-MOF). The adsorbent was assessed using various methods including FTIR, BET, XRD, XPS, SEM, and TEM. The results showed that the surface area decreased from 1123.07 to 762.8 m2.g−1, the pore volume reduced from 4.02 to 2.6 cc/g, and the pore size decreased from 7.8 to 3.2 nm after adsorption. The reduction in surface area, pore volume, and pore size post-TZ dye adsorption indicates that some of the adsorption mechanisms took place through the pores of the adsorbent. Examined the impact of temperature, pH, initial dye concentration, and contact time on the removal of TZ dye. The adsorption of TZ was found to conform to the Langmuir isotherm and pseudo-second-order kinetic model. The maximum adsorption capacity for TZ was determined to be 817.63 mg/g. The resulting pHzpc value of 5.36 indicates that adsorption of anionic dyes, such as TZ dye, is advantageous at pH levels below 5.36. Moreover, the adsorption process exhibited an adsorption energy of 23.78 kJ/mol, suggesting the presence of a chemisorption mechanism. The thermodynamic parameters calculated indicate that the adsorption processes are both spontaneous and endothermic. It is advisable to utilize the Tb-MOF adsorbent for a total of five cycles, as the adsorbent’s ability to regenerate suggests that treating industrial wastewater can be achieved easily and efficiently. The efficiency of the adsorption process was enhanced through optimization using the Box-Behnken Design (BBD).
利用金属有机铽框架(Tb-MOF)制成的叠层纳米棒,对水溶液中的黄色食用色素酒石酸染料 E-102 (TZ) 进行了消除和去除。采用傅立叶变换红外光谱、BET、XRD、XPS、扫描电镜和 TEM 等多种方法对吸附剂进行了评估。结果表明,吸附后表面积从 1123.07 m2.g-1 减小到 762.8 m2.g-1,孔体积从 4.02 cc/g 减小到 2.6 cc/g,孔径从 7.8 nm 减小到 3.2 nm。TZ染料吸附后表面积、孔体积和孔径的减小表明,部分吸附机理是通过吸附剂的孔隙实现的。研究了温度、pH 值、初始染料浓度和接触时间对去除 TZ 染料的影响。发现 TZ 的吸附符合 Langmuir 等温线和伪秒阶动力学模型。TZ 的最大吸附容量为 817.63 mg/g。得出的 pHzpc 值为 5.36,这表明阴离子染料(如 TZ 染料)在 pH 值低于 5.36 时具有吸附优势。此外,吸附过程的吸附能为 23.78 kJ/mol,表明存在化学吸附机制。计算得出的热力学参数表明,吸附过程既是自发的,又是内热的。由于 Tb-MOF 吸附剂具有再生能力,因此建议使用该吸附剂共进行五个循环,这样可以轻松高效地处理工业废水。通过使用方框-贝肯设计(BBD)进行优化,提高了吸附过程的效率。
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引用次数: 0
Corrigendum to “Discovering common pathogenetic processes between polycystic ovary syndrome and uterine corpus endometrial carcinoma by bioinformatics and experimental approach” [Arab. J. Chem. 17 (2024) 105548] 更正:"通过生物信息学和实验方法发现多囊卵巢综合征和子宫内膜癌的共同发病过程" [Arab. J. Chem. 17 (2024) 105548]
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-24 DOI: 10.1016/j.arabjc.2024.106016
Mingming Wang , Kangyang Diao , Mprah Richard , Lefan Dai , Tao Hu , Huanhuan Ding
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引用次数: 0
Ultra-fine carbon decorated TiO2/C/g-C3N4 hybrid for strong physical adsorption and efficient photodegradation of pollutants 用于强物理吸附和高效光降解污染物的超细碳装饰 TiO2/C/g-C3N4 混合物
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-24 DOI: 10.1016/j.arabjc.2024.106034
Azim Khan , Ruhumuriza Jonathan , Shafiq Ur Rehman , Muhammad Shoaib , Feng Cao , Sajjad Ali , Mohamed Bououdina , Pir Muhammad Ismail , Junwei Wang , Hazem Abu-Farsakh , Yifan Liu , Xian Jian
Enhancement in the visible light absorption and efficient interfacial charge transfer is crucial for optimizing photocatalytic efficiency in the degradation of pollutants such as methyl orange (MO) and formaldehyde. This study focuses on the properties of a TiO2/C/g-C3N4 hybrid efficient photocatalyst, which is developed using an air calcination method to deposit graphitic nitride (g-C3N4) onto a carbon-modified TiO2 surface. The characterization techniques, including high-resolution transmission electron Microscopy (HRTEM), X-ray diffraction (XRD), Raman spectroscopy, thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS), were used to provide a comprehensive understanding of the material’s structural, morphological, thermal, and chemical properties. This hybrid catalyst is specifically engineered for the efficient decomposition of methyl orange (MO) and formaldehyde, demonstrating a significant increase in photocatalytic activity. The TiO2/C/g-C3N4 photocatalyst also exhibits an enhanced specific surface area of 181.2 m2/g, which facilitates increased physical adsorption and photo-catalytic active sites. Experimental results confirm that this catalyst effectively adsorbs MO physically even in the dark without degradation. Combining physical and photo-catalytic functions, this catalyst degrades 94 % of MO within 180 min with the initial concentration 0.2 mol/L of MO, and achieves almost 100 % decolorization of MO under visible light irradiation. Notably, the catalyst retains its high activity after 4 cycles of MO degradation, underscoring its durability and consistent performance. Additionally, the hybrid catalyst features a staggered type-II energy level configuration, which effectively enhances charge separation and boosts photocatalytic efficacy. The incorporation of an ultrafine carbon layer further augments electron mobility towards the surface, crucial for effective catalytic reactions. This study paves the way for future development of highly efficient photocatalytic materials for environmental purification.
在降解甲基橙(MO)和甲醛等污染物时,增强可见光吸收和高效的界面电荷转移对于优化光催化效率至关重要。本研究的重点是 TiO2/C/g-C3N4 混合高效光催化剂的特性,该催化剂采用空气煅烧法在碳修饰的 TiO2 表面沉积氮化石墨(g-C3N4)。表征技术包括高分辨率透射电子显微镜 (HRTEM)、X 射线衍射 (XRD)、拉曼光谱、热重分析 (TGA)、傅立叶变换红外光谱 (FTIR) 和 X 射线光电子能谱 (XPS),用于全面了解材料的结构、形态、热和化学特性。这种混合催化剂专为高效分解甲基橙(MO)和甲醛而设计,光催化活性显著提高。TiO2/C/g-C3N4 光催化剂的比表面积也提高到了 181.2 m2/g,这有利于增加物理吸附和光催化活性位点。实验结果证实,这种催化剂即使在黑暗中也能有效地物理吸附 MO 而不发生降解。该催化剂结合了物理和光催化功能,在初始浓度为 0.2 摩尔/升 MO 的情况下,可在 180 分钟内降解 94% 的 MO,并在可见光照射下实现几乎 100% 的 MO 脱色。值得注意的是,该催化剂在经过 4 次 MO 降解循环后仍能保持较高的活性,这表明它具有耐久性和稳定的性能。此外,该混合催化剂具有交错的 II 型能级配置,可有效增强电荷分离,提高光催化效率。超细碳层的加入进一步增强了电子向表面的流动性,这对有效的催化反应至关重要。这项研究为未来开发用于环境净化的高效光催化材料铺平了道路。
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引用次数: 0
Synthesis and evaluation of an environmentally friendly phosphorus-free and nitrogen-free polymer as a scale and corrosion inhibitor 一种作为阻垢缓蚀剂的环境友好型无磷无氮聚合物的合成与评估
IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-24 DOI: 10.1016/j.arabjc.2024.106033
Xinhua Liu , Yuhua Gao , Baojing Luo , Hongxia Zhang , Xiaoyu Shi , Yuan Zhang , Yongguang Gao , Ying Wang , Zilin Zheng , Nan Ma , Jiarui Du , Linyan Gu
Polyepoxysuccinic acid (PESA) was modified by glycidyl (Gly) to obtain a phosphate-free and nitrogen-free polymer (Gly-PESA), and its scale and corrosion inhibition properties were studied.The effects of Gly-PESA concentration, calcium ion concentration and temperature to scale inhibition performance were studied by static scale inhibition method. The corrosion inhibition performance of Gly-PESA was studied by static weight-loss method. The morphology and structure of calcium scale and steel surface were characterized by spectroscopic and microscopic methods. The scale inhibition efficiency of Gly-PESA for CaCO3 and CaSO4 was 98.06% and 92.6%, respectively. Under the same experimental conditions, the scale inhibition effect of Gly-PESA was obviously better than that of PESA. Gly-PESA could effectively inhibit the growth of CaCO3 and CaSO4 crystals and cause their crystal lattice distortion or crystal dispersion. The corrosion inhibition efficiency of Gly-PESA for carbon steel was 78.17%. The adsorption of Gly-PESA on the surface of the steel test piece followed Langmuir adsorption isotherm, and formed a protective film, which increased the corrosion resistance of the steel test piece, thus effectively protecting the steel test piece. Therefore, Gly-PESA was a green scale and corrosion inhibitor, which solved the problem of environmental pollution.
采用静态阻垢法研究了 Gly-PESA 浓度、钙离子浓度和温度对阻垢性能的影响。采用静态失重法研究了 Gly-PESA 的缓蚀性能。采用光谱法和显微镜法对钙垢和钢表面的形态和结构进行了表征。Gly-PESA 对 CaCO3 和 CaSO4 的阻垢效率分别为 98.06% 和 92.6%。在相同的实验条件下,Gly-PESA 的阻垢效果明显优于 PESA。Gly-PESA 能有效抑制 CaCO3 和 CaSO4 晶体的生长,使其晶格畸变或晶体分散。Gly-PESA 对碳钢的缓蚀效率为 78.17%。Gly-PESA 在钢试件表面的吸附遵循 Langmuir 吸附等温线,并形成一层保护膜,提高了钢试件的耐腐蚀性,从而有效地保护了钢试件。因此,Gly-PESA 是一种绿色阻垢缓蚀剂,解决了环境污染问题。
{"title":"Synthesis and evaluation of an environmentally friendly phosphorus-free and nitrogen-free polymer as a scale and corrosion inhibitor","authors":"Xinhua Liu ,&nbsp;Yuhua Gao ,&nbsp;Baojing Luo ,&nbsp;Hongxia Zhang ,&nbsp;Xiaoyu Shi ,&nbsp;Yuan Zhang ,&nbsp;Yongguang Gao ,&nbsp;Ying Wang ,&nbsp;Zilin Zheng ,&nbsp;Nan Ma ,&nbsp;Jiarui Du ,&nbsp;Linyan Gu","doi":"10.1016/j.arabjc.2024.106033","DOIUrl":"10.1016/j.arabjc.2024.106033","url":null,"abstract":"<div><div>Polyepoxysuccinic acid (PESA) was modified by glycidyl (Gly) to obtain a phosphate-free and nitrogen-free polymer (Gly-PESA), and its scale and corrosion inhibition properties were studied.The effects of Gly-PESA concentration, calcium ion concentration and temperature to scale inhibition performance were studied by static scale inhibition method. The corrosion inhibition performance of Gly-PESA was studied by static weight-loss method. The morphology and structure of calcium scale and steel surface were characterized by spectroscopic and microscopic methods. The scale inhibition efficiency of Gly-PESA for CaCO<sub>3</sub> and CaSO<sub>4</sub> was 98.06% and 92.6%, respectively. Under the same experimental conditions, the scale inhibition effect of Gly-PESA was obviously better than that of PESA. Gly-PESA could effectively inhibit the growth of CaCO<sub>3</sub> and CaSO<sub>4</sub> crystals and cause their crystal lattice distortion or crystal dispersion. The corrosion inhibition efficiency of Gly-PESA for carbon steel was 78.17%. The adsorption of Gly-PESA on the surface of the steel test piece followed Langmuir adsorption isotherm, and formed a protective film, which increased the corrosion resistance of the steel test piece, thus effectively protecting the steel test piece. Therefore, Gly-PESA was a green scale and corrosion inhibitor, which solved the problem of environmental pollution.</div></div>","PeriodicalId":249,"journal":{"name":"Arabian Journal of Chemistry","volume":"17 12","pages":"Article 106033"},"PeriodicalIF":5.3,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Arabian Journal of Chemistry
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