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Self-Assembly Layer of Poly (P-Phenylene Vinylene) Modified With Long Alkyl Chains 长烷基链修饰聚苯乙烯自组装层
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.133
Diana M Bobrowska, K. Wójcik, K. Winkler
Extended Abstract The π-conjugated polymers are particular interest because they are potential materials for several applications such as organic light-emitting diodes (OLEDs) or organic photovoltaic solar cells (OPVs). One of the promising conjugated polymers, but not very popular such as polyaniline or polypyrolle, is poly(phenelene vinylene) (PPV). The main aim of research is synthesis of novel derivatives of p-PPV materials, which could self-assemble on the Indium Tin Oxide (ITO) surface. The new materials should have more ordered structure with higher crystallinity degree, thereby should acquire better electrochemical, spectroscopic and photochemical properties. p-PPV is one of the best donor materials in organic solar cells and it has unique physical properties, such as good conductivity, low cost of production, high mechanical strength and flexibility. PPV is almost insoluble polymer, which hinders its processing. To ensure solubility long alkyl or alkoxy chains could be incorporated into the phenylene ring before polymerization. Also, the significant drawback of polymers is its tendency to aggregation and tendency to "clutter" the polymer chain [1]. It affects the disturbance of its polymer structure and deterioration of conductive properties. The long alkyl side chains are commonly introduced onto polymer backbone to improve its ordered polymer structure. Beside this, the side chains also have significant impact on the morphology of conjugated polymers organized on the surface, and consequently it determines its optical and electrical properties. PPV with long alkyl chains containing 9, 12, 15 and 18 atom of carbons were synthesized using Gilch route with mild polymerization conditions [2]. Understanding the processes leading to the formation of conjugated materials with unusual physico-optical properties, requires multidisciplinary research, combining experimental methods together with the theoretical. For the successful application of these materials, their structure, physicochemical and physico-optical properties after their polymerization and interaction between the different nanostructures have to be well understood. The physicochemical properties of obtained new materials are determined with different optical and electrochemical techniques, such as spectroscopic methods (FTIR with MCT, H NMR, C NMR, Raman), microscopic (AFM and SEM), thermogravimetric (TGA), scanning calorimetric analysis (DSC), electrochemical (CV, DPV, EIS) and optical (UV-Vis-NIR spectrophotometry) methods. The final stage will focused on the construction of OPV solar cell – standard and inverted.
π共轭聚合物在有机发光二极管(oled)和有机光伏太阳能电池(OPVs)等领域具有广阔的应用前景。聚苯胺和聚苯环是一种很有前途但不太流行的共轭聚合物,它是聚苯胺和聚苯环。研究的主要目的是合成可在氧化铟锡(ITO)表面自组装的新型p-PPV材料衍生物。新材料应具有更有序的结构和更高的结晶度,从而获得更好的电化学、光谱和光化学性能。p-PPV是有机太阳能电池中最好的供体材料之一,它具有导电性好、生产成本低、机械强度高、柔韧性好等独特的物理性能。PPV几乎是不溶性聚合物,这阻碍了它的加工。为了保证溶解度,可以在聚合前将长烷基链或烷氧基链掺入苯环中。此外,聚合物的显著缺点是容易聚集,容易使聚合物链“杂乱”[1]。影响其聚合物结构的紊乱和导电性能的恶化。为了改善聚合物的有序结构,通常在聚合物主链上引入长烷基侧链。除此之外,侧链还对表面组织的共轭聚合物的形态产生重大影响,从而决定其光学和电学性质。采用Gilch路线,在温和聚合条件下合成了含有9、12、15和18个碳原子的长烷基链PPV[2]。了解导致具有不同寻常的物理光学性质的共轭材料形成的过程,需要多学科的研究,将实验方法与理论相结合。为了这些材料的成功应用,必须很好地了解它们的结构、聚合后的物理化学和物理光学性质以及不同纳米结构之间的相互作用。通过不同的光学和电化学技术,如光谱方法(FTIR与MCT, H NMR, C NMR, Raman),微观方法(AFM和SEM),热重(TGA),扫描量热分析(DSC),电化学(CV, DPV, EIS)和光学(UV-Vis-NIR分光光度法),来测定所获得的新材料的物理化学性质。最后阶段将重点建设OPV太阳能电池-标准和倒置。
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引用次数: 0
Biomimetic Apply to Waste Recycling 仿生在废物回收中的应用
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.01
J. Chaouki, Jocelyn Doucet
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引用次数: 0
Covalent Modification of Graphene Quantum Dots by Fullerene C60 Derivative 富勒烯C60衍生物对石墨烯量子点的共价修饰
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.132
J. Breczko, Marta Kirmuc, Diana M Bobrowska, V. Kirianchuk, K. Winkler
Extended Abstract Graphene quantum dots (GQDs) are a relatively new class of carbon nanomaterials with a promising potential use. The unique physico-chemical properties of GQDs are intermediate between the features exhibited by nanoparticles, which results from their small size (diameter <30 nm) and features typical for carbon nanostructures with high specific surface area, as the consequence of the fact that GQDs are fragments of a graphene plane [1]. The high reactivity of GQD edges allowing them to be functionalized with oxygen containing groups and to increase their dispersability while good electrochemical properties have been maintained. Presented results are focused on synthesis of a hybrid system between fullerene C60 and GQDs structures based on covalent modification. In the first step, a 1,3-dipolar cycloaddition reaction to obtain the pyrrolidine fullerene derivative was performed. It involved the introduction of fullerene C60 in the toluene solution containing sarcosine and 4hydroxybenzaldehyde and maintaining the mixture at boiling temperature for 12 h, according to the procedure described in the literature [2]. In parallel, the GQDs modified with carboxylic groups were obtained by ultrasonification of graphite flakes in a nitrating mixture under high temperature conditions [3]. The hydrophilic functional groups, formed mainly at the edges of the GQDs, have reacted with the added thionyl chloride and allow to obtain more reactive acid chloride groups. In the final step, fullerene C60 pyrrolidone was covalently bonded to the functionalized GQDs to form hybrid C60-GQDs. Synthesized C60/GQDs material was characterized by microscopic (TEM, SEM) as well as by spectroscopic methods (FTIR, Raman) to confirm each step modifications. According to the combination of GQDs exhibiting large specific capacitance and fullerenes allowing the faradaic processes to occur, obtained hybrid system was expected to act as an interesting charge exchange mediator. Therefore, electrochemical studies were undertaken and the potential of C60/GQDs system as an electrode material of the capacitors was examined.
石墨烯量子点(GQDs)是一类相对较新的碳纳米材料,具有广阔的应用前景。GQDs独特的物理化学性质介于纳米颗粒所表现出的特征之间,这是由于它们的小尺寸(直径<30 nm)和具有高比表面积的碳纳米结构的典型特征,这是由于GQDs是石墨烯平面[1]的片段。GQD边缘的高反应性使其能够与含氧基团进行官能团化,并在保持良好电化学性能的同时增加其分散性。研究结果主要集中在基于共价修饰的富勒烯C60和GQDs结构之间的杂化体系的合成。第一步采用1,3-偶极环加成反应制得吡咯烷类富勒烯衍生物。它包括在含有肌氨酸和4羟基苯甲醛的甲苯溶液中引入富勒烯C60,并根据文献[2]中描述的程序将混合物在沸点下保持12小时。同时,在高温条件下,对石墨薄片在硝化混合物中进行超声波处理,得到了羧基修饰的GQDs。主要在GQDs边缘形成的亲水官能团与添加的亚硫酰氯发生反应,从而得到活性更强的酸性氯基团。最后一步,富勒烯C60吡咯烷酮与功能化的GQDs共价结合,形成杂化的C60-GQDs。对合成的C60/GQDs材料进行了微观表征(TEM, SEM)和光谱表征(FTIR, Raman),以确认每一步的修饰。根据具有大比电容的GQDs和允许法拉第过程发生的富勒烯的组合,所获得的杂化体系有望作为一种有趣的电荷交换介质。因此,对C60/GQDs体系进行了电化学研究,并对其作为电容器电极材料的潜力进行了考察。
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引用次数: 0
Electromagnetic Shielding Woven Fabrics based on Multifilament Silver Coated with PA6,6 and PA6,6-Based Conductive Filament pa6,6和pa6,6导电丝涂覆银复合丝的电磁屏蔽机织织物
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.128
M. J. Toghchi, C. Campagne, C. Loghin, I. Cristian, P. Bruniaux, A. Cayla, Nicolae Lucano, Yan Chen
M. Javadi Toghchi 2, , C. Campagne, C. Loghin, I. Cristian, P.Bruniaux, A. Cayla, Nicolae Lucano and Y. Chen Ecole Nationale Supérieure des Arts et Industries Textiles, GEMTEX Roubaix, France marzieh.javadi-togh@ensait.fr Faculty of Textile, Leather and Industrial Management, Gheorghe Asachi Technical University Iasi, Romania College of Textile and Clothing Engineering, Soochow University Suzhou, China Faculty of Telecommunication Electronics and Information Technology, Gheorghe Asachi Technical University Iasi, Romania
M. Javadi Toghchi 2、C. Campagne、C. Loghin、I. Cristian、P.Bruniaux、A. Cayla、Nicolae Lucano和Y. Chen法国GEMTEX Roubaix国立艺术与工业学院纺织业、皮革与工业管理学院、雅西乔治Asachi工业大学、罗马尼亚纺织与服装工程学院、苏州苏州大学、中国电信电子与信息技术学院、格鲁吉亚Asachi技术大学,罗马尼亚雅西
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引用次数: 0
Effect of Temperature and Graphene Oxide on the Swelling of PAAm-GO Composite Gels 温度和氧化石墨烯对PAAm-GO复合凝胶膨胀的影响
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.146
Büşra Osma, G. Evingür, Ö. Pekcan
Graphene oxide (GO) is a two dimensional carbon material with similar one-atom thickness, and is a light material having extremely high strength and thermal stability [1]. Thus, GO is an efficient filler for the enhancement of the electrical, mechanical and thermal properties of composite materials [2]. We focused on GO as a nanofiller in polyacrylamide hydrogels and PAAm-GO composites to investigate the effect of temperature and graphene oxide on the swelling. Polyacrylamide (PAAm) hydrogels have been proposed for use as promising biomaterials in biomedical and tissue engineering. The composite gels were prepared by free radical crosslinking copolymerization with GO content varying in the range between 8 and 50 μl of GO. The effects of temperature and graphene oxide on the swelling of the composites were studied. The swelling experiment was performed in the distilled water. Decreasing in pyranine (Py) as a fluorescence probe and emission light intensity (Iem) were monitored by steady state fluorescence spectroscopy. Since the increase in Isc corresponds to the increase in turbidity of the swelling composite gel, the corrected fluorescence intensity, I was introduced to analyze the swelling processes. The Stern-Volmer equation combined with Li-Tanaka models was used to explain the behaviour of I during swelling processes. The cooperative diffusion coefficients and time constants were calculated as a function of temperature and GO, respectively.
氧化石墨烯(GO)是一种类似单原子厚度的二维碳材料,是一种具有极高强度和热稳定性的轻质材料[1]。因此,氧化石墨烯是增强复合材料电学、力学和热性能的有效填料[2]。我们重点研究了氧化石墨烯作为纳米填料在聚丙烯酰胺水凝胶和PAAm-GO复合材料中的作用,以研究温度和氧化石墨烯对膨胀的影响。聚丙烯酰胺(PAAm)水凝胶在生物医学和组织工程领域具有广阔的应用前景。采用自由基交联共聚法制备了氧化石墨烯含量在8 ~ 50 μl之间的复合凝胶。研究了温度和氧化石墨烯对复合材料膨胀的影响。在蒸馏水中进行溶胀实验。用稳态荧光光谱法监测荧光探针吡啶(Py)和发射光强(Iem)的下降。由于Isc的增加对应于膨胀复合凝胶浊度的增加,校正后的荧光强度,我被引入来分析膨胀过程。Stern-Volmer方程结合Li-Tanaka模型解释了I在膨胀过程中的行为。计算了协同扩散系数和时间常数分别作为温度和氧化石墨烯的函数。
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引用次数: 1
An Assessment of Operating Conditions for Supercritical Water Gasification and Safety Issues 超临界水气化运行条件评价及安全问题
Pub Date : 2019-08-01 DOI: 10.11159/ICERT19.120
C. Blasio, M. Prestipino, A. Galvagno, Margareta Björklund-Sänkiaho
The research paper presented here describes experimental investigations of Black Liquor Supercritical Water Gasification in a continuous Plug Flow Reactor system. Operating conditions heavily affects the gasification yields within the process. Nevertheless, an important issue in SCWG is the possible deposition of tar, char and inorganic compounds with subsequent plugging of the reactor. Reactions of re-polymerization are taken into account in regards to the results obtained. Important considerations are given here concerning the design and operation of high pressure reactor systems aimed at SCWG of biomass. Operational issues are seldom taken into account in this kind of investigations.
本文介绍了在连续塞流反应器系统中黑液超临界水气化的实验研究。操作条件对气化过程的收率有很大影响。然而,SCWG的一个重要问题是焦油、炭和无机化合物的可能沉积以及随后的反应器堵塞。根据所得结果考虑了再聚合反应。针对生物质超临界水处理的高压反应器系统的设计和运行,本文给出了重要的考虑。在这类调查中很少考虑到业务问题。
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引用次数: 1
Optical Properties of Novel Azo Multi-Functional Dye Thin Films 新型偶氮多功能染料薄膜的光学性质
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.116
A. Stoilova, Y. Trifonova, V. Lilova
Extended Abstract By evaluation the practical applicability of new synthesized compounds, starting point represents the thin film optical properties analysis, which provides rich information about chemical bonding, layer thickness, electronic structure, etc. Here, we present optical properties determination of thin nanocomposite films of three novel N-phthalimide azoazomethine dyes containing OH-group at ortho-position in respect to the -CH=Nchromophore group and designed with different electron donating and electron withdrawing substituents. The structure of these previously synthesized by us dyes is shown below.
通过评价新合成化合物的实用性,以薄膜光学性质分析为出发点,提供了丰富的化学键、层厚、电子结构等信息。本文采用不同的供电子和吸电子取代基设计了三种新型n -邻苯二胺偶氮亚甲基染料的纳米复合薄膜,并对其光学性能进行了测定。这些先前由我们合成的染料的结构如下所示。
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引用次数: 0
Building Physics during the Restoration of the Teatro Nuovo in Spoleto 斯波莱托新剧院修复期间的建筑物理
Pub Date : 2019-08-01 DOI: 10.11159/ICEPR19.182
V. Vodola
The Teatro Nuovo, the theatre where the famous international “Festival of the Two Worlds” is based, after a full restoration work and functional adaptation, has been returned to the city of Spoleto and its audience. The restoration works of the theatre started in 2003 for improving the safety levels and for adapting the operational functionality of the machines on the stage to the current needs of the show, including the acoustic performances. In particular, the Department of Energetic Engineering, Nuclear and Environmental Control of the University of Bologna collaborated with the Teatro Nuovo from the acoustic point of view, In order to monitor the acoustic performance of the concert hall, two campaigns of acoustic measurements, respectively before and after the restoration works, have been conducted, verifying the conservation of its original acoustical characteristics. The measurements were performed through an omnidirectional loudspeaker, a dummy head and a Soundfield probe. The results of the measurements of every campaign are presented in this article.
Nuovo剧院,著名的国际“两个世界的节日”的所在地,经过全面的修复工作和功能调整,已经回到斯波莱托市和它的观众。剧院的修复工程于2003年展开,目的是提高安全水平,并调整舞台上机器的操作功能,以配合演出的需要,包括音响表演。特别值得一提的是,博洛尼亚大学能源工程、核与环境控制系从声学角度与新剧院合作,为了监测音乐厅的声学性能,在修复工程前后分别进行了两次声学测量,验证了其原始声学特性的保存情况。测量是通过一个全向扬声器、一个假头和一个声场探头进行的。本文给出了每个活动的测量结果。
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引用次数: 0
Hydrophobic Ultrafine Hyaluronic Acid Nanofibers 疏水超细玻尿酸纳米纤维
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.151
M. Klicova, L. Voleský, A. Klápšťová, Vaclav Liska Jachym Rosendorf, R. Palek, J. Horáková
Marketa Klicova, Andrea Klapstova, Lukas Volesky, Vaclav Liska, Jachym Rosendorf, Richard Palek and Jana Horakova Technical University of Liberec, Faculty of Textile Engineering, Department of Nonwovens and Nanofibrous Materials Studentska 2, 461 17 Liberec, Czech Republic marketa.klicova@tul.cz Technical University of Liberec, Faculty of Mechanical Engineering, Department of Material Science Studentska 2, 461 17 Liberec, Czech Republic lukas.volesky@tul.cz Charles University, Faculty of Medicine in Pilsen, Biomedical Center alej Svobody 1655/76, 323 00 Plzen, Czech Republic liskav@fnplzen.cz; jachymrosendorf@gmail.com; palekrichard@gmail.com
Marketa Klicova, Andrea Klapstova, Lukas Volesky, Vaclav Liska, Jachym Rosendorf, Richard Palek和Jana Horakova,利贝雷茨工业大学,纺织工程学院,非织造布和纳米纤维材料系,捷克共和国marketa.klicova@tul.cz利贝雷茨工业大学,机械工程学院,材料科学系,捷克共和国lukas.volesky@tul.cz查尔斯大学,皮尔森医学院,生物医学中心alej Svobody 1655/76, 323 00plzen,捷克共和国liskav@fnplzen.cz;jachymrosendorf@gmail.com;palekrichard@gmail.com
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引用次数: 1
Synthesis of Carbon Nanotubes from Polymer Waste 利用高分子废弃物合成碳纳米管
Pub Date : 2019-08-01 DOI: 10.11159/ICNFA19.154
G. Smagulova, N. Yesbolov, B. Kaidar, N. Vassilyeva, N. Prikhodko, Z. Mansurov
The paper represents investigation on the synthesis of carbon nanotubes by chemical vapor deposition. The products of thermal decomposition of polyethylene waste were used as source of carbon. The influence of the decomposition temperature of polyethylene on the carbon nanotubes synthesis was provided. Cenospheres, preliminarily impregnated with aqueous solutions of nickel and cobalt nitrates, were applied as catalysts for carbon nanotubes synthesis. It was determined that in the framework of research, the best results for CNTs production were achieved at polyethylene decomposition temperature of 450 °C with catalyst based on cenospheres impregnated with nickel and cobalt nitrate solutions.
研究了化学气相沉积法合成碳纳米管的方法。利用聚乙烯废弃物热分解产物作为碳源。给出了聚乙烯分解温度对碳纳米管合成的影响。将硝酸镍和硝酸钴水溶液初步浸渍在微球中,作为碳纳米管合成的催化剂。在本研究的框架内,在聚乙烯分解温度为450°C时,以镍和硝酸钴溶液浸渍的微球为催化剂制备碳纳米管的最佳效果。
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引用次数: 3
期刊
Proceedings of the 5th World Congress on New Technologies
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