首页 > 最新文献

2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)最新文献

英文 中文
Mechanical Dicing Challenges and Development on 50um Saw Street with Wafer Backside Coating (WBC) 50um背面涂层锯街机械切割的挑战与发展
Y. Chiew, J. Liong, F. Tan
The continuing package miniaturized on semiconductor industry had driven toward smaller feature sizes and higher density which will raise the hurdle of dicing. This has become a trend to increase the number of potential die per wafer (PDPW) by shrinking the saw street width to have a competitive product cost and strategically maintain the product margin that affected by yearly Average Selling Price (ASP) erosion. Producing a wafer is a fixed cost thus the more die per wafer equates to lower cost per die. Each die is separated from its neighbors by narrow saw street, which are the cut lines for singulating the die. The narrower saw street width, the more dies per wafer and the more challenging the dicing. Generally, the width of the saw streets has been reduced from former industry standard of 85um to 60um and now to latest 50um. The dicing challenges and quality issue become more crucial with the requirement of wafer backside coating (WBC), smaller die size, thinner wafer with passivation stacks on the saw street and existing of process control monitor (PCM) areas which contains the massive test structures. Key dicing quality characteristics focused in this paper are including top side chipping, passivation peeling and die side wall damage. This is most severe issue in dicing process and has induced the quality risk of customer return due to not easy or impossible to screen out at final test for those minor chipped/cracked die. Qualitative analysis will be carried out and high power microscope will be used to check for chipping condition or other defects. This paper reports the challenges faced and the successful development of 50um narrow saw street with conductive and nonconductive wafer backside coating on various thickness of wafers with six sigma process capability dicing performance and passed all the reliability stress test requirements. A comprehensive study was performed in optimizing critical dicing parameter such as blade height, suitable dicing blade and dicing tape.
半导体产业持续的封装小型化,推动著元件的特征尺寸愈来愈小、密度愈来愈高,这也增加了切片的难度。这已经成为一种趋势,通过缩小锯街宽度来增加每片晶圆(PDPW)的潜在芯片数量,以具有竞争力的产品成本,并战略性地保持受年度平均销售价格(ASP)侵蚀影响的产品利润率。生产晶圆片的成本是固定的,因此每片晶圆片的成本越高,每片晶圆片的成本就越低。每个骰子与它的邻居被狭窄的锯街分开,这些锯街是用来分隔骰子的切线。锯街宽度越窄,每片晶片的模数越多,切粒越具有挑战性。一般来说,锯街的宽度已经从以前的85um的行业标准减少到60um,现在到最新的50um。随着晶圆背面涂层的要求、更小的晶圆尺寸、更薄的晶圆和在锯路上的钝化堆以及包含大量测试结构的过程控制监视器(PCM)区域的存在,切割挑战和质量问题变得更加重要。本文重点研究了切削质量的主要特征,包括刃口脱落、钝化剥落和模具侧壁损伤。这是切割过程中最严重的问题,并且由于在最终测试中不容易或不可能筛选出那些轻微的切屑/裂纹模具,导致客户退货的质量风险。将进行定性分析,并使用高倍显微镜检查是否有碎裂或其他缺陷。本文报道了50um窄锯街所面临的挑战和成功开发的导电和不导电的硅片背面涂层,在不同厚度的硅片上具有六西格玛工艺能力,切割性能良好,并通过了所有可靠性应力测试要求。对切刀高度、合适的切刀、切刀胶带等关键切刀参数进行了优化研究。
{"title":"Mechanical Dicing Challenges and Development on 50um Saw Street with Wafer Backside Coating (WBC)","authors":"Y. Chiew, J. Liong, F. Tan","doi":"10.1109/IEMT.2018.8511708","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511708","url":null,"abstract":"The continuing package miniaturized on semiconductor industry had driven toward smaller feature sizes and higher density which will raise the hurdle of dicing. This has become a trend to increase the number of potential die per wafer (PDPW) by shrinking the saw street width to have a competitive product cost and strategically maintain the product margin that affected by yearly Average Selling Price (ASP) erosion. Producing a wafer is a fixed cost thus the more die per wafer equates to lower cost per die. Each die is separated from its neighbors by narrow saw street, which are the cut lines for singulating the die. The narrower saw street width, the more dies per wafer and the more challenging the dicing. Generally, the width of the saw streets has been reduced from former industry standard of 85um to 60um and now to latest 50um. The dicing challenges and quality issue become more crucial with the requirement of wafer backside coating (WBC), smaller die size, thinner wafer with passivation stacks on the saw street and existing of process control monitor (PCM) areas which contains the massive test structures. Key dicing quality characteristics focused in this paper are including top side chipping, passivation peeling and die side wall damage. This is most severe issue in dicing process and has induced the quality risk of customer return due to not easy or impossible to screen out at final test for those minor chipped/cracked die. Qualitative analysis will be carried out and high power microscope will be used to check for chipping condition or other defects. This paper reports the challenges faced and the successful development of 50um narrow saw street with conductive and nonconductive wafer backside coating on various thickness of wafers with six sigma process capability dicing performance and passed all the reliability stress test requirements. A comprehensive study was performed in optimizing critical dicing parameter such as blade height, suitable dicing blade and dicing tape.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116945009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Warpage Studies of Printed Circuit Boards with Shadow Moiré and Simulations 印刷电路板的阴影变形研究与仿真
Sim Jui Oon, K. S. Tan, T. Tou, S. Yap, C. Lau, Y. T. Chin
The demand for lightweight and high functionality devices is always a driving force in development of smaller, lighter and compact electronics circuit. Printed circuit board (PCB) is the most important structure that provides interconnection and supports the components; hence its flatness is always the main concern in SMT manufacturing. In order to ensure product reliability, the monitoring of thermally induced warpage of PCB during high temperature reflow is essential. PCB deformation occurs when there is mismatch of coefficients of thermal expansion between the materials. Thermally induced warpage in PCB can be obtained from the Shadow Moiré measurement, which is a non-contact full-field optical method integrated with a high temperature oven. In this study, a single-sided, small PCB (105 mm X 100 mm X 1.5 mm) and a large, multi-layer PCB (300 mm X 180 mm X 1.6 mm) are measured and analyzed. To reduce the temperature difference between the top and bottom of the PCBs, a heating profile is designed with the use of multiple thermocouples at various positions on the PCB. In addition, finite element analysis is carried out to determine the z-axis deformation of the PCBs. The finite-element simulation is setup to mimic the heating profile in the experiment. The results of simulation are compared to the experimental measurement.
对轻量化和高功能器件的需求一直是推动更小、更轻、更紧凑电子电路发展的动力。印刷电路板(PCB)是提供互连和支持组件的最重要的结构;因此,其平面度一直是SMT制造的主要关注点。为了保证产品的可靠性,对PCB在高温回流过程中的热致翘曲进行监测是十分必要的。当材料之间的热膨胀系数不匹配时,PCB板就会发生变形。阴影莫尔测量是一种与高温烘箱相结合的非接触式全场光学测量方法,可以获得PCB中的热致翘曲。在本研究中,测量和分析了单面小型PCB (105 mm X 100 mm X 1.5 mm)和大型多层PCB (300 mm X 180 mm X 1.6 mm)。为了减少PCB顶部和底部之间的温差,在PCB上的不同位置使用多个热电偶设计了加热剖面。此外,还进行了有限元分析,确定了pcb板的z轴变形。建立了模拟实验中加热剖面的有限元模拟。仿真结果与实验测量结果进行了比较。
{"title":"Warpage Studies of Printed Circuit Boards with Shadow Moiré and Simulations","authors":"Sim Jui Oon, K. S. Tan, T. Tou, S. Yap, C. Lau, Y. T. Chin","doi":"10.1109/IEMT.2018.8511790","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511790","url":null,"abstract":"The demand for lightweight and high functionality devices is always a driving force in development of smaller, lighter and compact electronics circuit. Printed circuit board (PCB) is the most important structure that provides interconnection and supports the components; hence its flatness is always the main concern in SMT manufacturing. In order to ensure product reliability, the monitoring of thermally induced warpage of PCB during high temperature reflow is essential. PCB deformation occurs when there is mismatch of coefficients of thermal expansion between the materials. Thermally induced warpage in PCB can be obtained from the Shadow Moiré measurement, which is a non-contact full-field optical method integrated with a high temperature oven. In this study, a single-sided, small PCB (105 mm X 100 mm X 1.5 mm) and a large, multi-layer PCB (300 mm X 180 mm X 1.6 mm) are measured and analyzed. To reduce the temperature difference between the top and bottom of the PCBs, a heating profile is designed with the use of multiple thermocouples at various positions on the PCB. In addition, finite element analysis is carried out to determine the z-axis deformation of the PCBs. The finite-element simulation is setup to mimic the heating profile in the experiment. The results of simulation are compared to the experimental measurement.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"66 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132792519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Improving Non-Stick on Bond Pad Using High Pre-US (Ultrasonic) Power in Hydroxyl Coated Material 利用高超声功率改善羟基包覆材料粘结垫的不粘着力
E. Corpuz
In wire bonding process, one of the key factors to have a good bonding quality is the cleanliness of the bonding surfaces whether it is bonding pad (Die) or lead (leadframe). Foreign particles, contaminations, discolorations on bonding surfaces are common causes of non-sticking of ball bond. Improving material handling procedures, cleanroom procedures, additional line processes, improvement in process controls, process parameter optimizations, etc. are some of the preventions and improvement actions being carried out by semiconductor companies to minimize or eliminate such bonding surface conditions. In this paper, improvement of Non-Sticking On Pad (NSOP) caused by impurities or contaminations formed after ArH2 plasma cleaning process will be shown. It is detected in the impacted bonding pad surface a thick layer of “O” underneath the “C” layer when undergo depth profiling using X-ray Photoelectron Spectroscopy (XPS) surface analysis. Wirebond 1st bond parameter have been optimized to break through these “O” layer which is believed to be a film of hydroxyl (-OH) where one hydrogen atom combined to one oxygen atom formed after the ArH2 plasma cleaning process. The wirebond parameter (pre-US power) used in this non-sticking on bond pad improvement is not new in the wirebond equipment available today in the market. But with its function, ball bonding was able to break through the thick “O” layer and good bonding is achieved.
在焊丝键合工艺中,无论是焊盘(模具)还是引线(引线架),键合表面的清洁度是保证键合质量的关键因素之一。粘接表面的异物、污染、变色是造成粘接不粘接的常见原因。改进材料处理程序、洁净室程序、附加生产线工艺、改进工艺控制、工艺参数优化等,是半导体公司为减少或消除此类粘接表面状况而采取的一些预防和改进措施。本文将展示ArH2等离子体清洗过程中形成的杂质或污染物对焊盘不粘着(NSOP)的改善。利用x射线光电子能谱(XPS)表面分析进行深度剖面分析,发现在撞击键合垫表面,在“C”层下方有一层厚的“O”层。优化了Wirebond第一键参数,以突破这些“O”层,该“O”层被认为是在ArH2等离子体清洗过程中形成的一个氢原子与一个氧原子结合的羟基(-OH)膜。在目前市场上可用的焊丝焊设备中,用于这种不粘接焊垫改进的焊丝焊参数(pre-US power)并不新鲜。但凭借其功能,球键合可以突破厚的“O”层,达到良好的键合效果。
{"title":"Improving Non-Stick on Bond Pad Using High Pre-US (Ultrasonic) Power in Hydroxyl Coated Material","authors":"E. Corpuz","doi":"10.1109/IEMT.2018.8511766","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511766","url":null,"abstract":"In wire bonding process, one of the key factors to have a good bonding quality is the cleanliness of the bonding surfaces whether it is bonding pad (Die) or lead (leadframe). Foreign particles, contaminations, discolorations on bonding surfaces are common causes of non-sticking of ball bond. Improving material handling procedures, cleanroom procedures, additional line processes, improvement in process controls, process parameter optimizations, etc. are some of the preventions and improvement actions being carried out by semiconductor companies to minimize or eliminate such bonding surface conditions. In this paper, improvement of Non-Sticking On Pad (NSOP) caused by impurities or contaminations formed after ArH2 plasma cleaning process will be shown. It is detected in the impacted bonding pad surface a thick layer of “O” underneath the “C” layer when undergo depth profiling using X-ray Photoelectron Spectroscopy (XPS) surface analysis. Wirebond 1st bond parameter have been optimized to break through these “O” layer which is believed to be a film of hydroxyl (-OH) where one hydrogen atom combined to one oxygen atom formed after the ArH2 plasma cleaning process. The wirebond parameter (pre-US power) used in this non-sticking on bond pad improvement is not new in the wirebond equipment available today in the market. But with its function, ball bonding was able to break through the thick “O” layer and good bonding is achieved.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128553846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Batch Microwave Plasma Cleaning for Robustification of Automotive Devices an Alternative to Strip-Type Radiofrequency Plasma 批量微波等离子体清洗汽车设备的鲁棒性是带状射频等离子体的替代方案
G. J. Abarro, Rod J. Delos Santos, Darwin J. De Lazo, A. Denoyo, Manny S. Ramos
This study attempts to explore Batch-type Microwave (B-MW) plasma cleaning as a potential alternative to the conventional Strip-type Radiofrequency (S-RF) plasma; for application prior molding to improve adhesion along the mold-lead frame interface. Performance of B-MW was evaluated in terms of improvement in surface wettability, quantified via Contact Angle (CA) measurements. Mix of typical industrial plasma gases (Ar, H2 and O2) were assessed. Constant flow pattern was observed to significantly improve surface wettability and uniformity compared to its pulsed counterpart; and also affect the effect of other factors on the over-all cleaning performance of B-MW. Proceeding with constant flow pattern, surface wetting was found to improve with increasing power and cleaning time. The combination of O2and H2 plasma was found to be more effective compared to utilizing them separately. Both cleaning time and flow rate increased the amount of reactive species that come in contact with the contaminants. With optimized parameters, both techniques are effective in addressing delamination; but B-MW was confirmed to be a more efficient method than S-RF i.e. better uniformity, 12% more effective in and improving surface wettability and at least 28% higher throughput.
本研究试图探索间歇式微波(B-MW)等离子体清洁作为传统条形射频(S-RF)等离子体的潜在替代方案;用于成型前应用,以提高沿模具-引线框架界面的附着力。通过接触角(CA)测量对B-MW的表面润湿性进行了量化评估。对典型工业等离子体气体(Ar, H2和O2)的混合进行了评估。与脉冲流动模式相比,恒定流动模式显著改善了表面润湿性和均匀性;也会影响其他因素对B-MW整体清洗性能的影响。在恒流模式下,表面润湿性随着功率和清洗时间的增加而改善。o2和H2结合使用比单独使用更有效。清洗时间和流速都增加了与污染物接触的活性物质的数量。通过优化参数,两种技术都能有效地解决分层问题;但B-MW被证实是比S-RF更有效的方法,即均匀性更好,表面润湿性提高12%,吞吐量至少提高28%。
{"title":"Batch Microwave Plasma Cleaning for Robustification of Automotive Devices an Alternative to Strip-Type Radiofrequency Plasma","authors":"G. J. Abarro, Rod J. Delos Santos, Darwin J. De Lazo, A. Denoyo, Manny S. Ramos","doi":"10.1109/IEMT.2018.8511627","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511627","url":null,"abstract":"This study attempts to explore Batch-type Microwave (B-MW) plasma cleaning as a potential alternative to the conventional Strip-type Radiofrequency (S-RF) plasma; for application prior molding to improve adhesion along the mold-lead frame interface. Performance of B-MW was evaluated in terms of improvement in surface wettability, quantified via Contact Angle (CA) measurements. Mix of typical industrial plasma gases (Ar, H2 and O2) were assessed. Constant flow pattern was observed to significantly improve surface wettability and uniformity compared to its pulsed counterpart; and also affect the effect of other factors on the over-all cleaning performance of B-MW. Proceeding with constant flow pattern, surface wetting was found to improve with increasing power and cleaning time. The combination of O2and H2 plasma was found to be more effective compared to utilizing them separately. Both cleaning time and flow rate increased the amount of reactive species that come in contact with the contaminants. With optimized parameters, both techniques are effective in addressing delamination; but B-MW was confirmed to be a more efficient method than S-RF i.e. better uniformity, 12% more effective in and improving surface wettability and at least 28% higher throughput.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121718402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling of Molded Electronic Package Warpage Characteristic with Cure Induced Shrinkage and Viscoelasticity Properties 基于固化收缩和粘弹性特性的模制电子封装翘曲特性建模
W. K. Loh, R. Kulterman, Chih Chung Hsu, H. Fu
One of the challenges for developing an electronic package is to understand the dynamic warpage behavior of the package even before having the real physical sample. Hence, industry relies on the use of simulation tools, be it the finite element model and analytical equations, to refine the design options to obtain a high confidence warpage prediction. However, this is never consistently predictable because of the underlying assumptions where the actual assembly process is a lot more complex. In this paper, the comparison of assembly process steps and modeling method is discussed coupled with a demonstration of the use of Moldex3D to predict the mold flow pattern and warpage prediction by leveraging the mold cure kinetics, PVTC (Pressure Volume Temperature Cure) and viscoelasticity material properties of the mold. Effect of mesh detail, mold shrinkage percentage and glass transition temperature were considered to provide some general trend of these parameters impacting the package warpage prediction. The use of analytical equation in managing the material properties transition from uncured to cured mold was demonstrated. Even with existing modeling capabilities, there is no one common modeling method and capability to capture all the potential package assembly process interaction. Hence, this is the motivation for further development.
开发电子封装的挑战之一是在获得真正的物理样品之前就了解封装的动态翘曲行为。因此,行业依赖于模拟工具的使用,无论是有限元模型还是分析方程,来完善设计方案,以获得高置信度的翘曲预测。然而,由于潜在的假设,实际的装配过程要复杂得多,这永远无法始终预测。在本文中,讨论了装配过程步骤和建模方法的比较,并演示了使用Moldex3D通过利用模具固化动力学,PVTC(压力体积温度固化)和模具的粘弹性材料特性来预测模具流动模式和翘曲预测。考虑了网格细部、模具收缩率和玻璃化转变温度对包装翘曲预测的影响,给出了这些参数的总体趋势。分析方程的使用在管理从未固化到固化模具的材料性能转变。即使有了现有的建模功能,也没有一种通用的建模方法和功能来捕获所有潜在的包组装过程交互。因此,这是进一步发展的动力。
{"title":"Modeling of Molded Electronic Package Warpage Characteristic with Cure Induced Shrinkage and Viscoelasticity Properties","authors":"W. K. Loh, R. Kulterman, Chih Chung Hsu, H. Fu","doi":"10.1109/IEMT.2018.8511686","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511686","url":null,"abstract":"One of the challenges for developing an electronic package is to understand the dynamic warpage behavior of the package even before having the real physical sample. Hence, industry relies on the use of simulation tools, be it the finite element model and analytical equations, to refine the design options to obtain a high confidence warpage prediction. However, this is never consistently predictable because of the underlying assumptions where the actual assembly process is a lot more complex. In this paper, the comparison of assembly process steps and modeling method is discussed coupled with a demonstration of the use of Moldex3D to predict the mold flow pattern and warpage prediction by leveraging the mold cure kinetics, PVTC (Pressure Volume Temperature Cure) and viscoelasticity material properties of the mold. Effect of mesh detail, mold shrinkage percentage and glass transition temperature were considered to provide some general trend of these parameters impacting the package warpage prediction. The use of analytical equation in managing the material properties transition from uncured to cured mold was demonstrated. Even with existing modeling capabilities, there is no one common modeling method and capability to capture all the potential package assembly process interaction. Hence, this is the motivation for further development.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"98 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124174731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Wire Sweep Improvement for Tuning Wires in RF Power TO288 Packages 射频功率TO288封装中调谐导线的导线扫描改进
Navaretnasinggam Arivindran, Derus Rozazmi, T. Ming
RF Power packages have complex bonding diagram (BD) with high loop and long length of tuning wires which are very critical to achieve the resonance frequency of the device. The high loop and long length of tuning wires are very sensitive to wire sweep occurrence after molding process. Lately, the RF Power devices are becoming more complex with additional tuning wires and ground wires [1]. The height of tuning wires plays a critical role to ensure proper efficiency of the device at the same time prone to wire sweep at molding process. During initial startup of the RF Power devices, pre sway was implemented at wire bond (WB) process. The tuning wires are swayed 3° so that after molding the wires will be sweep by the mold compound flow into the package and eventually the wires will be become straight after molding [2]. However, the latest RF Power TO288 package has longer tuning wires up to 180mils and tuning wire height up to 60mils [1]. The pre sway at wire bond cannot be applied as wire bonders do not have the capability to perform pre-sway for such a long and high loop wires. Due to limitation at WB, mold process has to find strategies to minimize the wire sweep occurrence. This particular paper discusses how molding process have optimized their molding parameters to minimize the wire sweep occurrence. This paper will give a complete summary of wire sweep improvements done for RF Power TO288 package in terms of process optimization and mold gate location. The learnings of RF TO288 wire sweep study was implemented to upcoming RF packages.
射频电源封装具有复杂的键合图(BD),具有高回路和长调谐线,这对于实现器件的谐振频率至关重要。调弦线圈高、长度长,对成型后的扫丝现象非常敏感。最近,RF功率器件变得越来越复杂,有额外的调谐线和地线[1]。调丝高度对保证设备的合理效率起着至关重要的作用,同时在成型过程中也容易产生扫丝现象。在射频功率器件的初始启动过程中,在线键(WB)过程中实现预摇摆。调弦摆动3°,使调弦成型后被模具复合气流扫入包内,最终调弦成型后变直[2]。然而,最新的RF Power TO288封装具有更长的调谐线,最高可达180mils,调谐线高度可达60mils[1]。对于如此长且高的环线,由于焊线机没有能力进行预摇,因此不能采用焊线预摇。由于在WB上的限制,模具工艺必须找到最小化钢丝扫线发生的策略。本文讨论了如何优化成型工艺参数,以减少钢丝扫线的发生。本文将在工艺优化和模口位置方面对RF Power TO288封装的线扫描改进进行完整的总结。在即将推出的RF封装中实现了对RF TO288线扫描的学习。
{"title":"Wire Sweep Improvement for Tuning Wires in RF Power TO288 Packages","authors":"Navaretnasinggam Arivindran, Derus Rozazmi, T. Ming","doi":"10.1109/iemt.2018.8511755","DOIUrl":"https://doi.org/10.1109/iemt.2018.8511755","url":null,"abstract":"RF Power packages have complex bonding diagram (BD) with high loop and long length of tuning wires which are very critical to achieve the resonance frequency of the device. The high loop and long length of tuning wires are very sensitive to wire sweep occurrence after molding process. Lately, the RF Power devices are becoming more complex with additional tuning wires and ground wires [1]. The height of tuning wires plays a critical role to ensure proper efficiency of the device at the same time prone to wire sweep at molding process. During initial startup of the RF Power devices, pre sway was implemented at wire bond (WB) process. The tuning wires are swayed 3° so that after molding the wires will be sweep by the mold compound flow into the package and eventually the wires will be become straight after molding [2]. However, the latest RF Power TO288 package has longer tuning wires up to 180mils and tuning wire height up to 60mils [1]. The pre sway at wire bond cannot be applied as wire bonders do not have the capability to perform pre-sway for such a long and high loop wires. Due to limitation at WB, mold process has to find strategies to minimize the wire sweep occurrence. This particular paper discusses how molding process have optimized their molding parameters to minimize the wire sweep occurrence. This paper will give a complete summary of wire sweep improvements done for RF Power TO288 package in terms of process optimization and mold gate location. The learnings of RF TO288 wire sweep study was implemented to upcoming RF packages.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"16 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115351658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Materials for MEMS Packaging: MEMS Die Attach and ASIC Die Coating and Encapsulation MEMS封装新材料:MEMS封装和ASIC封装
M. Schindler
In a lot of MEMS-based devices, stress decoupling is of highest importance in order to avoid temperature-induced stress, i.e. on the membranes of pressure sensors or microphones. DELO's latest generation of MEMS die attach (DA) adhesives reaches Young's moduli lower than e.g. those of silicones at room temperature. The patented mCD chemistry also allows for an optional light pre-fixation of the dispensed adhesive in order to avoid unwanted spreading or bleeding during placement of the MEMS chip and/or the final heat curing step (b-stage process). In addition, DELO has developed new materials for ASIC die coating and ASIC encapsulation. Exposing the ASIC die to e.g. IR radiation leads to unwanted signal noise, especially in MEMS microphones. The bare ASIC die is exposed to the back volume ambience on all five sides. Hence, all five surfaces of the die need to be shielded (five face coating) against IR. DELO has developed materials with tailored dispensing and flow properties for this application. These adhesives are optimized for jet dispensing, still leaving the freedom to adjust the layer thickness to the needs of the application. The coating covers all five surfaces very well while minimizing the spread on the substrate, keeping the footprint small. This paper describes the new possibilities for MEMS packaging arising from MEMS DA adhesives based on DELO's patented mCD chemistry featuring a Young's modulus of < 1MPa at room temperature, which is lower than that of silicones. A further benefit of this class of adhesives is its screen- or stencil-printability for a fast and precise production process. Bondlines of about 50 µm are achievable, improving stress decoupling significantly.
在许多基于mems的器件中,应力去耦是最重要的,以避免温度引起的应力,即在压力传感器或麦克风的膜上。DELO最新一代的MEMS贴片(DA)胶粘剂在室温下的杨氏模量低于硅树脂等。专利的mCD化学还允许可选的光预固定点胶,以避免在放置MEMS芯片和/或最后的热固化步骤(b阶段过程)期间不必要的扩散或出血。此外,DELO还开发了ASIC模具涂层和ASIC封装的新材料。将ASIC芯片暴露在例如红外辐射下会导致不必要的信号噪声,特别是在MEMS麦克风中。裸露的ASIC芯片暴露在所有五个侧面的背面体积环境中。因此,模具的所有五个表面都需要屏蔽(五面涂层)以防止IR。DELO为这一应用开发了量身定制的点胶和流动特性材料。这些粘合剂针对喷射点胶进行了优化,仍然可以根据应用的需要自由调整层厚度。涂层可以很好地覆盖所有五个表面,同时最大限度地减少基底上的扩散,保持占地面积小。本文描述了基于DELO专利mCD化学的MEMS DA粘合剂带来的MEMS封装的新可能性,该粘合剂在室温下的杨氏模量< 1MPa,低于有机硅。这类胶粘剂的另一个优点是它的丝网或模板印刷能力,用于快速和精确的生产过程。可以实现约50 μ m的键合线,显著改善应力解耦。
{"title":"Novel Materials for MEMS Packaging: MEMS Die Attach and ASIC Die Coating and Encapsulation","authors":"M. Schindler","doi":"10.1109/IEMT.2018.8511787","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511787","url":null,"abstract":"In a lot of MEMS-based devices, stress decoupling is of highest importance in order to avoid temperature-induced stress, i.e. on the membranes of pressure sensors or microphones. DELO's latest generation of MEMS die attach (DA) adhesives reaches Young's moduli lower than e.g. those of silicones at room temperature. The patented mCD chemistry also allows for an optional light pre-fixation of the dispensed adhesive in order to avoid unwanted spreading or bleeding during placement of the MEMS chip and/or the final heat curing step (b-stage process). In addition, DELO has developed new materials for ASIC die coating and ASIC encapsulation. Exposing the ASIC die to e.g. IR radiation leads to unwanted signal noise, especially in MEMS microphones. The bare ASIC die is exposed to the back volume ambience on all five sides. Hence, all five surfaces of the die need to be shielded (five face coating) against IR. DELO has developed materials with tailored dispensing and flow properties for this application. These adhesives are optimized for jet dispensing, still leaving the freedom to adjust the layer thickness to the needs of the application. The coating covers all five surfaces very well while minimizing the spread on the substrate, keeping the footprint small. This paper describes the new possibilities for MEMS packaging arising from MEMS DA adhesives based on DELO's patented mCD chemistry featuring a Young's modulus of < 1MPa at room temperature, which is lower than that of silicones. A further benefit of this class of adhesives is its screen- or stencil-printability for a fast and precise production process. Bondlines of about 50 µm are achievable, improving stress decoupling significantly.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130948265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Electronic Packaging Moisture Interaction Study 电子封装水分相互作用研究
Yung Hsiang Lee, I. Chin, W. K. Loh
Reliability defects associated with thermal humidity environments are not new to the electronics packaging industry, yet to this day it remains a key concern even for our latest technologies. Moisture absorbed into electronic packaging can impact package warpage, cause corrosion, underfill crack and interfacial delamination. Fundamental studies are needed to better understand the effect of moisture interaction with different package designs. This paper summarizes the lab experiments and Finite Element Analysis (FEA) that have been performed to study package moisture absorption-desorption, room temperature (RT) warpage and dynamic warpage, on packages post exposure to thermal humidity environment. This has yielded good fundamental learning and identified areas for future work.
与热湿度环境相关的可靠性缺陷对电子封装行业来说并不新鲜,但直到今天,它仍然是一个关键问题,即使是我们最新的技术。电子封装中吸收的水分会影响封装翘曲,引起腐蚀、衬底裂缝和界面分层。为了更好地了解不同包装设计对水分相互作用的影响,需要进行基础研究。本文综述了热湿环境下包装吸湿-解吸、室温翘曲和动态翘曲的室内实验和有限元分析。这产生了良好的基础学习,并确定了今后工作的领域。
{"title":"Electronic Packaging Moisture Interaction Study","authors":"Yung Hsiang Lee, I. Chin, W. K. Loh","doi":"10.1109/IEMT.2018.8511674","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511674","url":null,"abstract":"Reliability defects associated with thermal humidity environments are not new to the electronics packaging industry, yet to this day it remains a key concern even for our latest technologies. Moisture absorbed into electronic packaging can impact package warpage, cause corrosion, underfill crack and interfacial delamination. Fundamental studies are needed to better understand the effect of moisture interaction with different package designs. This paper summarizes the lab experiments and Finite Element Analysis (FEA) that have been performed to study package moisture absorption-desorption, room temperature (RT) warpage and dynamic warpage, on packages post exposure to thermal humidity environment. This has yielded good fundamental learning and identified areas for future work.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"130 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124245075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Verification of Delamination Observed in SAM Transmission Mode (Thru-Scan) Using Reflection Mode (C-SAM Bottom Scan) 利用反射模式(C-SAM底部扫描)验证SAM传输模式(透扫)中观察到的分层现象
Kunjapat Mugunan, L. Ying, C. C. Fei
Analysis of semiconductor packages with stacked dies poses a great challenge when assessing the die attach integrity of the different dies. With multiple interfaces already existing within the package it becomes even more difficult if the individual dies are bonded using different die attach material e.g. solder for the Base Chip and glue for the Top Chip. Typically the non-destructive test employed by most of the failure analysis labs to detect delamination for such kind of packages is by using Scanning Acoustic Microscopy in Transmission Mode (Thru-Scan). This non-invasive technique transmits ultrasound through the sample and reveals delamination at all interfaces in a single scan. However with this mode there is no way to determine which interface is delaminated. Furthermore the degree of spatial resolution for this mode is also rather poor. Verification of the Thru-Scan results is normally carried out by performing a mechanical cross-section across the delaminated region to identify the affected interface. The work presented in this paper focuses on an alternative non-destructive method using the Reflection Mode (C-SAM) to verify the delamination detected by the Transmission Mode Thru-Scan by progressively scanning from the bottom of the package across each of the interfaces within the package to identify the exact location of the defect. Various destructive tests were subsequently performed to validate this alternative method. The results show not only the effectiveness of this method in determining the correct interface that was affected but the Reflective Mode scanning also proves that it can reveal defects which are not able to be detected by the Transmission Mode Thru-Scan.
在分析具有堆叠芯片的半导体封装时,评估不同芯片的贴片完整性是一个很大的挑战。由于封装中已经存在多个接口,如果单个模具使用不同的模具附加材料进行粘合,例如用于基础芯片的焊料和用于顶部芯片的胶水,则变得更加困难。大多数失效分析实验室通常采用无损检测来检测这类封装的分层,使用透射模式扫描声学显微镜(through - scan)。这种非侵入性技术通过超声波传输样品,并在一次扫描中显示所有界面的分层。然而,在这种模式下,没有办法确定哪个接口是分层的。此外,该模式的空间分辨率也很差。通过对分层区域进行机械横截面来验证透扫结果,以确定受影响的界面。本文提出的工作重点是一种非破坏性的替代方法,使用反射模式(C-SAM)来验证传输模式全扫描检测到的分层,该方法从封装的底部开始逐步扫描,穿过封装内的每个接口,以确定缺陷的确切位置。随后进行了各种破坏性试验,以验证这种替代方法。结果表明,该方法不仅在确定受影响的正确接口方面是有效的,而且反射模式扫描也证明了它可以发现传输模式穿透扫描无法检测到的缺陷。
{"title":"Verification of Delamination Observed in SAM Transmission Mode (Thru-Scan) Using Reflection Mode (C-SAM Bottom Scan)","authors":"Kunjapat Mugunan, L. Ying, C. C. Fei","doi":"10.1109/IEMT.2018.8511783","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511783","url":null,"abstract":"Analysis of semiconductor packages with stacked dies poses a great challenge when assessing the die attach integrity of the different dies. With multiple interfaces already existing within the package it becomes even more difficult if the individual dies are bonded using different die attach material e.g. solder for the Base Chip and glue for the Top Chip. Typically the non-destructive test employed by most of the failure analysis labs to detect delamination for such kind of packages is by using Scanning Acoustic Microscopy in Transmission Mode (Thru-Scan). This non-invasive technique transmits ultrasound through the sample and reveals delamination at all interfaces in a single scan. However with this mode there is no way to determine which interface is delaminated. Furthermore the degree of spatial resolution for this mode is also rather poor. Verification of the Thru-Scan results is normally carried out by performing a mechanical cross-section across the delaminated region to identify the affected interface. The work presented in this paper focuses on an alternative non-destructive method using the Reflection Mode (C-SAM) to verify the delamination detected by the Transmission Mode Thru-Scan by progressively scanning from the bottom of the package across each of the interfaces within the package to identify the exact location of the defect. Various destructive tests were subsequently performed to validate this alternative method. The results show not only the effectiveness of this method in determining the correct interface that was affected but the Reflective Mode scanning also proves that it can reveal defects which are not able to be detected by the Transmission Mode Thru-Scan.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"23 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124806884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization of Silicon Die Strength with Different Die Backside Unevenness Location 不同模后不均匀位置下硅模强度的表征
L. Chia, L. B. Huat, C. M. Wan, Mohamad Som Siti Robiatun, Jessie Liong Shih Man
Development of mircoelectronic packages are always moving towards smaller and thinner. This is in conjunction of consumers need for mobile and wearable electronic gadgets. In order to achieve this, beside improvements in packaging technologies silicon die had to be smaller and thinner too. However thinner packages increase the challenges of package stress and thinner silicon chip becomes more susceptible to process related weakness especially at the front-end processes. Silicon die strength is an important parameter to ensure the packing reliability under stringent conditions. The strength of silicon wafer is heavily influenced by the die thickness and wafer the backside surface preparation prior to metal deposition. Stresses induced in the silicon die throughout the process of wafer processing, packaging and die assembly. Small flaws such as small micro cracks or uneveness can occur during backside processes causing the strength of the Silicon die to decrease and cause failure at early stage of packaging process or even reliability concern. This paper investigated the effect of die strength to the surface morphology using 3 point bending test and 3D Laser Measuring Microscope. The die strength was characterized using 3 point bending test while surface morphology was characterized using 3D Laser Measuring Microscope. The evaluation was performed with silicon die singulated from wafers of unevenness at wafer backside. The silicon die was then categorized into 4 different types by unevenness location, 1) unevenness through complete die in x-direction, 2) unevenness through complete die in y-direction 3) unevenness at the middle of die, 4) unevenness at the edge of die. Silicon die strength of 4 different type of location of unevenness was being measured using 3 point bending test. The result showed that the depth of unevenness was not the main factor of low die strength. Unevenness location at the die is the main factor of low die strength. Die strength with unevenness at the edge of die having the lowest strength.
微电子封装的发展一直朝着更小、更薄的方向发展。这与消费者对移动和可穿戴电子产品的需求相结合。为了实现这一目标,除了封装技术的改进外,硅晶片也必须更小更薄。然而,更薄的封装增加了封装应力的挑战,更薄的硅芯片变得更容易受到工艺相关弱点的影响,特别是在前端工艺。硅模强度是保证在苛刻条件下封装可靠性的重要参数。硅片的强度很大程度上受硅片模具厚度和硅片金属沉积前的背面制备的影响。硅片加工、封装和组装过程中硅晶片所产生的应力。在背面加工过程中,可能会出现微小的裂纹或不均匀等小缺陷,导致硅晶片的强度降低,导致封装过程早期失效甚至可靠性问题。采用三点弯曲试验和三维激光测量显微镜研究了模具强度对表面形貌的影响。采用三点弯曲试验对模具强度进行了表征,采用三维激光显微镜对模具表面形貌进行了表征。采用硅片背面不均匀的硅片模拟硅片模进行评价。然后根据不均匀位置将硅模分为4种不同类型:1)x方向全模不均匀,2)y方向全模不均匀,3)模具中部不均匀,4)模具边缘不均匀。采用三点弯曲试验测量了4种不同不均匀位置的硅模强度。结果表明,不均匀深度不是导致模具强度低的主要因素。模具位置不均匀是造成模具强度低的主要原因。在模具边缘不均匀的模具强度最低。
{"title":"Characterization of Silicon Die Strength with Different Die Backside Unevenness Location","authors":"L. Chia, L. B. Huat, C. M. Wan, Mohamad Som Siti Robiatun, Jessie Liong Shih Man","doi":"10.1109/IEMT.2018.8511673","DOIUrl":"https://doi.org/10.1109/IEMT.2018.8511673","url":null,"abstract":"Development of mircoelectronic packages are always moving towards smaller and thinner. This is in conjunction of consumers need for mobile and wearable electronic gadgets. In order to achieve this, beside improvements in packaging technologies silicon die had to be smaller and thinner too. However thinner packages increase the challenges of package stress and thinner silicon chip becomes more susceptible to process related weakness especially at the front-end processes. Silicon die strength is an important parameter to ensure the packing reliability under stringent conditions. The strength of silicon wafer is heavily influenced by the die thickness and wafer the backside surface preparation prior to metal deposition. Stresses induced in the silicon die throughout the process of wafer processing, packaging and die assembly. Small flaws such as small micro cracks or uneveness can occur during backside processes causing the strength of the Silicon die to decrease and cause failure at early stage of packaging process or even reliability concern. This paper investigated the effect of die strength to the surface morphology using 3 point bending test and 3D Laser Measuring Microscope. The die strength was characterized using 3 point bending test while surface morphology was characterized using 3D Laser Measuring Microscope. The evaluation was performed with silicon die singulated from wafers of unevenness at wafer backside. The silicon die was then categorized into 4 different types by unevenness location, 1) unevenness through complete die in x-direction, 2) unevenness through complete die in y-direction 3) unevenness at the middle of die, 4) unevenness at the edge of die. Silicon die strength of 4 different type of location of unevenness was being measured using 3 point bending test. The result showed that the depth of unevenness was not the main factor of low die strength. Unevenness location at the die is the main factor of low die strength. Die strength with unevenness at the edge of die having the lowest strength.","PeriodicalId":292144,"journal":{"name":"2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)","volume":"17 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122303721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
2018 IEEE 38th International Electronics Manufacturing Technology Conference (IEMT)
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1