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10th MATBUD’2023 Scientific-Technical Conference最新文献

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Increasing the Pozzolanic Reactivity of Recovered CDW Cement Stone by Mechanical Activation 机械活化法提高再生CDW水泥石的火山灰反应性
Pub Date : 2023-02-15 DOI: 10.3390/materproc2023013027
R. Szabó, M. Szűcs, M. Ambrus, G. Mucsi
: The study focuses on enhancing the reactivity of the fine size fraction of construction and demolition waste (CDW) by mechanical activation in a stirred media mill. Systematic measurements were carried out to monitor the change in cement stone reactivity. The fine size fraction of CDW (<200 µ m) was milled in a stirred media mill for 1, 3, 5
研究了在搅拌介质磨机中采用机械活化法提高建筑垃圾(CDW)细粒组分的反应性。对水泥石反应性的变化进行了系统的测量。将CDW(<200µm)的细粒级分在搅拌介质磨机中研磨1、3、5
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引用次数: 2
The Use of Calcined Diatomite as an Additive to Geopolymeric Materials 煅烧硅藻土作为地聚合物添加剂的应用
Pub Date : 2023-02-15 DOI: 10.3390/materproc2023013028
K. Pławecka, Agnieszka Bąk, M. Hebdowska-Krupa, M. Łach
: Diatomites are mineral resources formed from diatoms. They are widely used in sorption processes, medicine, cosmetology, and in protecting animals from parasites. Attempts are being made to incorporate them into concretes and construction binders to improve various performance properties. This paper presents the results of analyses (particle size analysis, XRD, and SEM) of a fine fraction of non-calcined and calcined diatomite as an additive to geopolymers made from fly ash from lignite combustion. The fly ash was also analyzed in the same way. Diatomite was introduced in its calcined and non-calcined form at 10%, 15%, and 30% by weight, replacing parts of the filler sand. The geopolymer mixtures were activated with 10 and 14 M aqueous sodium hydroxide solution with sodium water glass. As a result, it was found that it was possible to obtain geopolymers with diatomite additives with a compressive strength of about 34 MPa. In addition, after the strength tests, the microstructure of the obtained geopolymers was analyzed by scanning electron microscopy.
硅藻土是由硅藻形成的矿产资源。它们广泛用于吸附过程、医药、美容和保护动物免受寄生虫侵害。人们正在尝试将它们掺入混凝土和建筑粘合剂中,以改善各种性能。本文介绍了以褐煤燃烧后的粉煤灰为原料制备地聚合物,并对未煅烧硅藻土和煅烧硅藻土的细组分进行了粒度分析、XRD和SEM分析。对粉煤灰也进行了同样的分析。硅藻土以10%、15%和30%的重量以煅烧和未煅烧的形式引入,取代部分填料砂。用10 M和14 M氢氧化钠水溶液和水玻璃钠活化地聚合物混合物。结果发现,添加硅藻土可以获得抗压强度约为34 MPa的地聚合物。此外,在强度测试后,用扫描电镜对所得地聚合物的微观结构进行了分析。
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引用次数: 0
Sulfate Resistance in Carbonated Low-Calcium Silicate Cement Pastes 碳酸化低钙硅酸盐水泥浆的抗硫酸盐性能
Pub Date : 2023-02-15 DOI: 10.3390/materproc2023013022
R. Tokpatayeva, J. Olek, S. Sahu
: This paper focuses on the evaluation of sulfate resistance in carbonated pastes prepared from low-lime calcium silicates (CCS). The chemical interaction between the sulfate solution and paste powders was assessed by monitoring the leaching of the Ca and Si species, reduction in the content of carbonates and formation of gypsum. The analytical techniques used in the study included TGA, ICP-OES and IC. The results of the study revealed that the level of the resistance to the chemical effect of the sulfates depends on the type of the calcium silicate, degree of crystallinity of calcium carbonate, and the type of cation present in the sulfate solution.
本文主要研究了低石灰硅酸钙(CCS)制备的碳酸糊的抗硫酸盐性能。通过监测钙和硅的浸出、碳酸盐含量的减少和石膏的形成来评估硫酸盐溶液与膏体粉末之间的化学相互作用。研究中使用的分析技术包括TGA、ICP-OES和IC。研究结果表明,对硫酸盐化学作用的抵抗程度取决于硅酸钙的类型、碳酸钙的结晶度和硫酸盐溶液中存在的阳离子类型。
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引用次数: 0
Investigation of the Electrical Properties of Graphene-Reinforced Geopolymer Composites 石墨烯增强地聚合物复合材料的电性能研究
Pub Date : 2023-02-15 DOI: 10.3390/materproc2023013034
R. Krishna, Suman Saha, K. Korniejenko, T. Qureshi, S. Mustakim
Geopolymer composites provide an environmentally friendly alternative to cement-based composites in the construction industry. Due to their distinctive material composition, geopolymers also exhibit electrically conductive properties, which permit their application as a functional material. The current work aims to study the distinctive electrical properties of fly-ash-based geopolymer composites. Varying dosages of graphene oxide (i.e., 0, 0.1, 0.2, 0.3, 0.4% (by wt. of binder)) were introduced into the geopolymer matrix to enhance electrical conductivity. While GO (graphene oxide) is typically less conductive, the interaction of GO sheets with the alkaline solution during geopolymerisation reduced the functional groups and produced cross-linked rGO (reduced graphene oxide) sheets with increased mechanical and electrical conductivity properties. Solid-state impedance spectroscopy was used to characterize the electrical properties of geopolymer composites in terms of several parameters, such as impedance, electrical conductivity and dielectric properties, within the frequency ranging from 101 to 105 Hz. The relationship between the electrical properties and graphene oxide reinforcement can effectively establish geopolymer composite development as smart materials with desirable functionality. The results suggest an effective enhancement in electrical conductivity of up to 7.72 × 10−13 Ω·mm−1 and the dielectric response performance of graphene-reinforced fly-ash-based geopolymer composites.
地聚合物复合材料为建筑行业提供了水泥基复合材料的环保替代品。由于其独特的材料组成,地聚合物也表现出导电特性,这使得它们可以作为功能材料应用。目前的工作旨在研究粉煤灰基地聚合物复合材料的独特电学性能。不同剂量的氧化石墨烯(即0、0.1、0.2、0.3、0.4%(按粘结剂的重量))被引入地聚合物基体以增强导电性。虽然氧化石墨烯(氧化石墨烯)的导电性通常较差,但在地聚合过程中,氧化石墨烯片与碱性溶液的相互作用减少了官能团,并产生了交联的氧化石墨烯(还原氧化石墨烯)片,具有更高的机械和导电性。在101 ~ 105 Hz的频率范围内,采用固态阻抗谱法对地聚合物复合材料的电性能进行了表征,包括阻抗、电导率和介电性能等参数。电性能与氧化石墨烯增强之间的关系可以有效地建立地聚合物复合材料作为具有理想功能的智能材料的发展。结果表明,石墨烯增强粉煤灰基地聚合物复合材料的电导率可有效提高到7.72 × 10−13 Ω·mm−1,并提高了介电响应性能。
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引用次数: 1
Properties of the Cement, Slag and Fly Ash Mixture Composition Corresponding to CEM II/C-M and CEM VI CEMⅱ/C-M和CEMⅵ对应水泥、矿渣和粉煤灰混合料的性能
Pub Date : 2023-02-14 DOI: 10.3390/materproc2023013011
E. Tkaczewska, G. Malata
: In the study, cement mixtures containing granulated blast furnace slag (GBFS) and siliceous fly ash (SFA) were tested, including those corresponding to special cements according to the PN-B-19707: 2013 standard. Measurements included the period of development of standard strength (up to 28 days) and concerned the compressive strength, linear changes and phase composition of cement mixtures. Furthermore, an evaluation of the microstructure of cement mortar was carried out by SEM. The mixture of composition CEM II/C-M (S-V) satisfies the requirements of the 32.5R or 32.5N strength class, whereas that of CEM VI (S-V) is of the 32.5N strength class
本研究测试了含有粒状高炉矿渣(GBFS)和硅质粉煤灰(SFA)的水泥混合料,包括符合PN-B-19707: 2013标准的特种水泥。测量包括标准强度的发展周期(长达28天),并关注水泥混合物的抗压强度,线性变化和相组成。此外,利用扫描电镜对水泥砂浆的微观结构进行了评价。CEM II/C-M (S-V)混合物的强度等级为32.5R或32.5N, CEM VI (S-V)混合物的强度等级为32.5N
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引用次数: 0
Study on the Blending Characteristics of Ternary Cementless Materials 三元无水泥材料共混特性研究
Pub Date : 2023-02-14 DOI: 10.3390/materproc2023013009
Yi-Hua Chang, L. Fiala, M. Záleská, D. Koňáková, W. Lin, A. Cheng
: In this study, three industrial by-products (ultrafine fly ash, ground granulated blast-furnace slag (ggbs) and circulating fluidized bed co-fired fly ash) were used to produce ternary cementless composites without using alkali activators. The finenesses of ultrafine fly ash, ggbs and co-fired fly ash were 33,800, 5830 and 5130 cm 2 /g, respectively. The composite material was developed by mixing supplementary cementing materials of different particle sizes and exploiting the high-alkaline properties of the co-fired fly ash to develop a substantial hardening property like cement. The test specimens were made in the form of pastes and the water-to-cementitious-material ratio for the test was fixed at 0.55. The test results show that the flowability of the six different mixtures could be up to 120% and the setting time could be controlled within 24 h. At 60% of the ggbs proportion, the setting time could be held for 8 h. The compressive strength of each proportion reached 7 MPa at 7 days and 14 MPa at 28 days. The water-cured specimens exhibited better strength behavior than the air-cured specimens. Scanning electron microscopy found the main components of strength growth of the specimens to be hydrated reactants of C-A-S-H or ettringite. The results of the XRF analysis show that the specimens responded to higher compressive strengths as the Ca/Si and Ca/Al ratios increased.
本研究以三种工业副产品(超细粉煤灰、磨粒高炉渣和循环流化床共烧粉煤灰)为原料,在不使用碱活化剂的情况下制备三元无水泥复合材料。超细粉煤灰、矿渣和共烧粉煤灰的细度分别为33,800、5830和5130 cm 2 /g。该复合材料是通过混合不同粒径的补充胶凝材料,并利用共烧粉煤灰的高碱性来获得类似水泥的实质性硬化性能。试件以膏体形式制作,试验水胶料比固定为0.55。试验结果表明,6种混合料的流动性可达120%,凝结时间可控制在24 h以内,在ggbs比例为60%时,凝结时间可保持8 h, 7天抗压强度可达7 MPa, 28天抗压强度可达14 MPa。水固化试件的强度表现优于风干试件。扫描电镜发现试样强度增长的主要成分是C-A-S-H或钙矾石的水合反应物。XRF分析结果表明,随着Ca/Si和Ca/Al比的增大,试样的抗压强度增大。
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引用次数: 0
Feasibility Study of Waste Gypsum as a Full Replacement for Fine Aggregates of Controlled Low-Strength Material 废石膏全面替代可控低强度细集料的可行性研究
Pub Date : 2023-02-14 DOI: 10.3390/materproc2023013019
W. Lin, K. Korniejenko, D. Mierzwiński, M. Łach, A. Cheng, Kae‐Long Lin
: The waste gypsum used in this study was a by-product of petroleum coke burning by petrochemical companies which has been treated with hydration. The waste gypsum has been stored in the atmosphere for over ten years and can be considered an inert filler. Its main chemical components were calcium sulfate dihydrate (47.90%), calcium hydroxide (21.64%) and calcium carbonate (14.80%). In this study, Portland cement and fly ash were used as cementitious materials, and waste gypsum of the particle size from 9.53 mm to 0.149 mm was selected as the fine aggregate to produce a controlled low-strength material (CLSM) and to verify the suitability of reusing waste gypsum. The water to binder ratio of 0.65 was used for the specimen. The test results showed that the CLSM specimen with a high amount of waste gypsum had air-hardening properties. The placement of the specimen in water caused abnormalities, such as cracking and disintegration of the specimens. The compressive strength of atmospherically maintained specimens increased with age, with 4.71 MPa and 6.08 MPa at 28 and 56 days, respectively. No significant changes in weight or volume were measured after the specimens had been left for 56 days and then immersed in seawater and water for 28 days. As specimens were immersed in seawater for up to 100 days, needle-shaped ettringite and C-S-H colloids filled the interface between the pores and the colloids. In accordance with the concept of eco-engineering, special consideration should be given to avoid long-term contact with water and to ensure the safety and durability of waste gypsum reuse through the design of multiple protective layers.
本研究使用的废石膏是石油化工企业燃烧石油焦后的副产物,经水化处理后得到。废石膏在大气中存放了十多年,可以认为是一种惰性填料。其主要化学成分为二水硫酸钙(47.90%)、氢氧化钙(21.64%)和碳酸钙(14.80%)。本研究以波特兰水泥和粉煤灰为胶凝材料,选取粒径为9.53 mm ~ 0.149 mm的废石膏作为细骨料,制备可控低强度材料(CLSM),验证废石膏再利用的适宜性。试样的水胶比为0.65。试验结果表明,高废石膏掺量的CLSM试样具有良好的空气硬化性能。将标本置于水中会引起异常,如试样开裂和解体。大气保持试样的抗压强度随龄期的增加而增加,28和56 d时分别为4.71 MPa和6.08 MPa。放置56天后,在海水和水中浸泡28天后,样品的重量和体积均无明显变化。试样在海水中浸泡100天,针状钙矾石和C-S-H胶体填充了孔隙与胶体的界面。按照生态工程的理念,应特别考虑避免与水长期接触,并通过多层保护层的设计,确保废石膏回用的安全性和耐久性。
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引用次数: 1
Numerical Modelling of Structural Behaviour of Curved Insulating Glass Units 弯曲中空玻璃构件结构性能的数值模拟
Pub Date : 2023-02-14 DOI: 10.3390/materproc2023013012
M. Kozłowski, Kinga Zemła
: The application of curved Insulating Glass Units (IGUs) in facades has emerged as a novel solution to meet aesthetic and energy performance objectives. Due to improved stiffness, curved IGUs cannot equalise internal and atmospheric pressure changes by pillowing, as flat IGUs do. Thus, the climatic loads in curved IGUs may be several times higher than those in flat units. This paper deals with experiments and numerical simulations of cylindrically curved IGUs. It presents the results of an experimental campaign designed to collect data that validate the numerical model of a curved IGU developed within this study. The model is sequentially used to analyse a case study that compares the resulting internal pressure, displacement, and stress in glass in a flat and curved IGU subjected to the characteristic climatic actions given by DIN18008-1.
弯曲中空玻璃单元(igu)在立面上的应用已经成为一种满足美学和能源性能目标的新解决方案。由于刚度的提高,弯曲的igu不能像扁平的igu那样通过枕动来平衡内部和大气压力的变化。因此,弯曲igu中的气候负荷可能比平坦igu中的气候负荷高几倍。本文对圆柱弯曲igu进行了实验和数值模拟。它提出了一项实验活动的结果,旨在收集数据,以验证本研究中开发的弯曲IGU的数值模型。该模型随后用于分析一个案例研究,该案例研究比较了在DIN18008-1给出的特征气候作用下,平面和弯曲IGU中玻璃的内部压力、位移和应力。
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引用次数: 1
The Influence of the Ageing Process on the Mechanical Properties of Cement Mortars with Nano-SiO2 Admixture Initially Subjected to Thermal Treatment † 老化过程对纳米sio2水泥砂浆初始热处理力学性能的影响
Pub Date : 2023-02-14 DOI: 10.3390/materproc2023013020
E. Horszczaruk, P. Łukowski
: The research aimed to evaluate the effect of nano-silica (NS) on the strength recovery of the previously heated cement mortars. One hundred twenty cement mortar specimens were prepared with 1% to 5% of NS. The specimens were heated at temperatures ranging from 200 ◦ C to 800 ◦ C. Half of the samples, after heating and cooling, were mechanically tested. The other half of the specimens were stored for 24 months in 90% relative humidity. The presence of NS fostered partial recovery of the compressive strength of the heated mortars. The cement mortars regained more than 40% of their compressive strength after heating at 400 ◦ C and about 25% after heating at 600 ◦ C. The strength recovery phenomenon faded away at 800 ◦ C.
本研究旨在评价纳米二氧化硅(NS)对加热后水泥砂浆强度恢复的影响。以1% ~ 5%的NS配制120个水泥砂浆试件。样品在200°C至800°C的温度范围内加热,加热和冷却后的一半样品进行机械测试。另一半标本在90%的相对湿度下保存24个月。NS的存在促进了受热砂浆抗压强度的部分恢复。400℃加热后水泥砂浆抗压强度恢复40%以上,600℃加热后水泥砂浆抗压强度恢复25%左右,800℃时强度恢复现象逐渐消失。
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引用次数: 0
Characterization of a Coal Shale from Marcel Mining as Raw Material for Geopolymer Manufacturing 马塞尔矿煤页岩制备地聚合物原料的表征
Pub Date : 2023-02-14 DOI: 10.3390/materproc2023013021
K. Korniejenko, B. Figiela, K. Pławecka, A. Bulut, B. Şahin, G. Azizağaoğlu, M. Łach
: Implementing the idea of a circular economy is one way to reduce carbon emissions and, at the same time, the consumption of natural resources. The use of mining waste as a raw material helps meet the growing demand for construction materials with a smaller carbon footprint. The article shows the possibility of using a coal shale from Marcel mining to create new eco-friendly materials, geopolymers. The main aim of the presented research includes characteristics of raw material and synthesis of geopolymers based on mining waste (coal shale from Marcel mining) and next, investigations of the obtained materials. Geopolymer was prepared using a sodium activator plus milled and calcinated precursor materials. In this study, the following research methods were used: particle size analysis, XRD analysis, mechanical properties tests (compressive and bonding strength), and microstructure analysis—scanning electron microscopy. The results show potential for the extraction of waste from the Marcel company to obtain material for advanced applications in the geopolymerization process. The material had a compressive strength of 12.7 MPa and a bending strength of 3.4 MPa, which makes it possible for use in construction applications such as various types of foundations, walls, columns, lintels, terraces, stairs, ceilings, small building elements, and small architecture. The proposed process could be a promising alternative to current methods of managing waste rock, in particular hard coal mining.
实施循环经济的理念是减少碳排放,同时减少自然资源消耗的一种方式。使用采矿废料作为原材料有助于满足对建筑材料日益增长的需求,同时减少碳足迹。这篇文章展示了利用马塞尔煤矿的煤页岩来制造新的环保材料——地聚合物的可能性。本研究的主要目的是研究以马塞尔煤矿的煤页岩为原料合成地聚合物的原料特性,并对所得材料进行研究。以钠为活化剂,再加上粉碎和煅烧的前驱体材料制备地聚合物。本研究采用了以下研究方法:粒度分析、XRD分析、力学性能测试(抗压和结合强度)、微观结构分析-扫描电镜。结果表明,从马塞尔公司提取的废物有潜力获得在地聚合过程中先进应用的材料。该材料的抗压强度为12.7 MPa,抗弯强度为3.4 MPa,这使得它可以用于建筑应用,如各种类型的基础,墙壁,柱子,门楣,露台,楼梯,天花板,小型建筑元素和小型建筑。拟议的过程可能是目前管理废石,特别是硬煤开采方法的一个有希望的替代方法。
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引用次数: 0
期刊
10th MATBUD&amp;rsquo;2023 Scientific-Technical Conference
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