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Polietileno de baja densidad funcionalizado con un poliéster poliol altamente ramificado maleinizado 低密度聚乙烯功能化与高度支链马来化聚酯多元醇
Pub Date : 2016-02-22 DOI: 10.17230/INGCIENCIA.12.23.7
Carlos A. Ararat, Edwin A. Murillo
Abstract In this work, low density polyethylene (LDPE) was modified in the melt state with a maleinized hyperbranched polyester polyol (HBPAM), using several proportions of dicumyl peroxide (0.5, 1.0, 1.5 and 2.0 %). Infrared analysis showed the signals of OH, C=O, -COOR and -C=C- groups of the HBPAM in the spectra of the functionalized samples (LDPE-g-HBPAM). Grafting degree (GD) was between 9.14 and 9.82 %. Melt flow index of the samples LDPE-g-HBPAM was lower than that of the LDPE, and it did not exhibit dependency on the dicumyl peroxide content and GI. Except for the sample obtained with a 2.0 % of dicumyl peroxide, all melting temperatures of the samples of LDPE-g-HBPAM were similar to that of the LDPE. The melting enthalpy of the samples LDPE-g-HBPAM decreased with the concentration of dicumyl peroxide and GD. The tensile modulus of these samples was higher than that of LDPE, but the elongation at break was lower
在本研究中,低密度聚乙烯(LDPE)在熔融状态下被马来化超支化聚酯多元醇(HBPAM)改性,使用不同比例的过氧化二氨基(0.5,1.0,1.5和2.0%)。红外分析表明,在功能化样品(LDPE-g-HBPAM)的光谱中存在OH、C=O、- coor和-C=C-基团的信号。嫁接度(GD)在9.14% ~ 9.82%之间。LDPE-g- hbpam样品的熔体流动指数低于LDPE,且不依赖于过氧化二氨基含量和GI。除了添加2.0%过氧化二umyl得到的样品外,LDPE-g- hbpam样品的所有熔融温度都与LDPE相似。LDPE-g-HBPAM样品的熔融焓随过氧化二氨基和GD浓度的增加而降低。这些样品的拉伸模量高于LDPE,但断裂伸长率较低
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引用次数: 7
Criterios para el procesamiento y evaluación de datos experimentales para un motor de encendido provocado de alta relación de compresión 高压缩比触发点火发动机实验数据处理与评价标准
Pub Date : 2016-02-22 DOI: 10.17230/INGCIENCIA.12.23.6
Edisson S. Castaño Mesa, Sebastián H. Quintana, Iván D. Bedoya, Andrés Adolfo Amell Arrieta
This article presents the evaluation of some of these methodologies applied to a high compression ratio-spark ignition engine, which was achieved through modification of a commercial Diesel engine. The accuracy on calculation of equivalence ratio from exhaust gas analysis and the start of combustion from mass fraction burned has been tested. The effect of trapped mass on the in-cylinder energy balance was determined. The results suggest that the tested methodologies for calculation of equivalence ratio, start of combustion, and trapped are reliable tools for evaluation of quality of data and studying spark ignition engines with high compression ratios.
本文提出了一些这些方法的评估应用于高压缩比火花点火发动机,这是通过商用柴油发动机的修改实现的。通过尾气分析计算当量比和燃烧质量分数启动燃烧的准确性进行了检验。确定了捕获质量对缸内能量平衡的影响。结果表明,当量比计算、燃烧启动和俘获的测试方法是评估数据质量和研究高压缩比火花点火发动机的可靠工具。
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引用次数: 0
Influence of Si Atoms Insertion on the Formation of the Ti-Si-N Composite by DFT Simulation Si原子插入对Ti-Si-N复合材料形成的影响
Pub Date : 2016-02-22 DOI: 10.17230/INGCIENCIA.12.23.1
J. González, J. Restrepo, C. Portilla, A. R. Muñoz, Federico Sequeda Osorio
Using Density Functional Theory (DFT) SiN and TiN structures were simulated, in order to study the influence of the silicon atoms insertion in the TiN lattice placed on interstitial and substitutional positions in a face centered cubic (FCC) crystalline lattice. Results showed that the SiN FCC structure is pseudo-stable; meanwhile the tetragonal structure is stable with ceramic behavior. The TiN FCC structure is stable with ceramic behavior similar to SiN Tetragonal. 21% silicon atoms insertion in interstitial positions showed high induced deformation, high polarization and Si N bond formation, indication an amorphous transition that could lead to the production of a material composed from TiN grains or nano-grains embedded in a Si N amorphous matrix. When
利用密度泛函理论(DFT)模拟了TiN和SiN的结构,研究了TiN晶格中硅原子的插入对面心立方(FCC)晶格中间隙和取代位置的影响。结果表明,SiN FCC结构是准稳定的;同时,四边形结构稳定,具有良好的陶瓷性能。TiN FCC结构稳定,具有类似于Si四方晶的陶瓷行为,21%的硅原子插入到间隙位置,表现出高诱导变形、高极化和Si - N键的形成,表明非晶过渡可能导致由嵌入Si - N非晶基体的TiN晶粒或纳米晶粒组成的材料。当
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引用次数: 0
Modelo lineal para la programación de clases en una institución educativa 教育机构班级规划的线性模型
Pub Date : 2016-02-22 DOI: 10.17230/INGCIENCIA.12.23.3
J. Ángel, P. Duque
Abstract This paper presents a mathematical programing model that supports the design of timetables of classes in primary and secondary educational institutions, allowing the decision maker to take into account the constraints and variables that are commonly associated to this problem. Our model differs from most of those in the literature as the objective function aims at maximizing the number of blocks, two consecutive hours of lecture devoted to the same subject, which favors the learning process, optimizes teachers' agendas by reducing idle times and reduces cost and contractual difficulties. The model is validated using a real instance of a middle size institution for which the current timetable is considerably improved. Additionally, computational experiments with larger instances were carried on in order to test the capacity of the model for which promising results were obtained
摘要本文提出了一个数学规划模型,该模型支持中小学教育机构课程表的设计,使决策者能够考虑到通常与此问题相关的约束和变量。我们的模型与大多数文献中的模型不同,因为目标函数旨在最大化块的数量,连续两个小时的讲座专门用于同一主题,这有利于学习过程,通过减少空闲时间优化教师的议程,降低成本和合同困难。该模型使用一个中等规模机构的实际实例进行了验证,该机构目前的时间表得到了很大的改进。此外,为了测试模型的能力,还进行了更大实例的计算实验,并获得了令人满意的结果
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引用次数: 3
Algoritmo memético con operadores de inteligencia artificial para el CARP con inicio y fin no determinado y bi-objetivo 带有人工智能操作符的模因算法,用于不确定的开始和结束和双目标鲤鱼
Pub Date : 2016-02-22 DOI: 10.17230/INGCIENCIA.12.23.2
B. Macias, C. Amaya
Abstract The arc routing problem with a variable starting/ending position (Open Capacitated Arc Routing Problem - OCARP), in its classic version, pursues the best strategy to serve a set of customers located in the network arcs using vehicles. Compared to the Capacitated Arc Routing Problem (CARP), the OCARP lacks of constrains that guarantee that each vehicle ought to start and end the tour at a given vertex (also known as a depot). The aim of this paper is to propose a heuristic to find an efficient frontier for the main objective functions: minimize the number of vehicles and the total cost. Additionally, a hybrid algorithm that complements the genetic algorithm with artificial intelligence operator is proposed.
具有可变起始/结束位置的圆弧路由问题(Open Capacitated arc routing problem - OCARP)的经典版本追求的是利用车辆为位于网络圆弧中的一组客户提供服务的最佳策略。与有能力弧线路由问题(CARP)相比,OCARP缺乏保证每辆车应该在给定顶点(也称为仓库)开始和结束巡回的约束。本文的目的是提出一种启发式方法来寻找主要目标函数的有效边界:最小化车辆数量和总成本。此外,提出了一种将遗传算法与人工智能算子相结合的混合算法。
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引用次数: 0
Prediction of Multiphase Flow in Pipelines: Literature Review 管道中多相流的预测:文献综述
Pub Date : 2015-08-14 DOI: 10.17230/INGCIENCIA.11.22.10
M. Jerez-Carrizales, J. E. Jaramillo, D. Fuentes
In this work a review about the most relevant methods found in the literature to model the multiphase flow in pipelines is presented. It includes the traditional simplified and mechanistic models, moreover, principles of the drift flux model and the two fluid model are explained. Even though, it is possible to find several models in the literature, no one is able to reproduce all flow conditions presented in the oil industry. Therefore, some issues reported by different authors related to model validation are here also discussed.
在这项工作中,回顾了文献中发现的最相关的方法来模拟管道中的多相流。它包括传统的简化模型和机械模型,并解释了漂移通量模型和两种流体模型的原理。尽管有可能在文献中找到几个模型,但没有人能够重现石油工业中出现的所有流动条件。因此,本文还讨论了不同作者报告的与模型验证相关的一些问题。
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引用次数: 10
Diffraction Efficiency Adjustment to Record High Quality Color Holograms 调整衍射效率以记录高质量的彩色全息图
Pub Date : 2015-08-06 DOI: 10.17230/INGCIENCIA.11.22.1
D. Velasquez, L. M. Giraldo
In this article, we report the experimental values of required exposure to obtain the maximum diffraction efficiencies in PFG-03C Slavich film on independent recordings and RGB multiplexed recordings. Also, color adjustments by modifying wavelength channels contribution on reflection diffraction gratings, and color composition changes on Denisyuk holograms observed by using different spectral compositions light sources were studied and presented.
在本文中,我们报告了PFG-03C Slavich薄膜在独立记录和RGB多路记录下获得最大衍射效率所需的曝光实验值。此外,还研究并介绍了通过改变反射衍射光栅的波长通道贡献来调整颜色,以及使用不同光谱组成光源观察到的Denisyuk全息图的颜色组成变化。
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引用次数: 1
Effect of the Recycled Rubber on the Properties of Recycled Rubber/Recycled Polypropylene Blends 再生橡胶对再生橡胶/再生聚丙烯共混物性能的影响
Pub Date : 2015-08-04 DOI: 10.17230/INGCIENCIA.11.22.8
E. Ciro, J. Parra, M. Zapata, E. Murillo
This study evaluates the influence of recycled rubber (RR) with a specific particle size in the properties of blends, blended recycled polypropylene/polyethylene (RPP) and RR (RPP/RR). The proportions of RPP/RR employed to obtain the blends were as follows: 90/10 (PP90), 75/25 (PP75), 60/40 (PP60) and 45/55 (PP45). The particle size of the RR employed was 850 µm . The properties of the blends were evaluated by rheometric, thermogravimetric (TGA), differential scanning calorimetric (DSC), scanning electronic microscopy (SEM), density, melt flow index and tensile analysis. The maximum torque increased with the RPP content. By DSC analysis, it was observed that the RPP exhibited two melting temperatures, the first corresponded to low density polyethylene (LDPE) and the second to polypropylene (PP). Furthermore, the RR affected the crystallinity of the RPP. By using SEM and TGA analyses, it was determined that the RPP as well as RR contained fillers. The blend densities were higher than those of RPP. The melt flow index exhibited a trend with the amount of RR.PACS: 61.25.hk, 83.80.Va, 81.05.Lg
本研究考察了特定粒径的再生橡胶(RR)对共混物、共混再生聚丙烯/聚乙烯(RPP)和再生聚乙烯(RPP/RR)性能的影响。共混物的RPP/RR比例分别为90/10 (PP90)、75/25 (PP75)、60/40 (PP60)和45/55 (PP45)。所采用的RR粒径为850µm。通过流变学、热重法(TGA)、差示扫描量热法(DSC)、扫描电镜(SEM)、密度、熔体流动指数和拉伸分析对共混物的性能进行了评价。最大转矩随RPP含量的增加而增大。通过DSC分析发现,RPP呈现出两个熔融温度,第一个对应于低密度聚乙烯(LDPE),第二个对应于聚丙烯(PP)。此外,RR对RPP的结晶度也有影响。通过SEM和TGA分析,确定RPP和RR均含有填料。共混密度高于RPP。熔体流动指数随RR量的增加呈一定的趋势。pac: 61.25。, 83.80港元。弗吉尼亚州,81.05.Lg
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引用次数: 10
El valor de shapley como estrategia de optimización de recursos sobre Power Line Communication (PLC) shapley作为电力线通信(PLC)资源优化策略的价值
Pub Date : 2015-08-04 DOI: 10.17230/INGCIENCIA.11.22.9
J.C.V.N.A Ferreira, G. Acuña, Javier Emilio Sierra Carrillo
En este articulo se propone el uso de la teoria de juegos cooperativos, apoyados en el uso del juego de la bancarrota y el valor de Shapley, como estrategia para optimizar la asignacion de recursos en cada nodo, acorde con la demanda en el servicio, el numero de estaciones y las condiciones del canal PLC. El articulo plantea un escenario bajo condiciones de trafico saturado, con el fin de evaluar el grado de optimizacion que el valor de Shapley puede realizar ante condiciones de trafico y de canal claramente establecidas. Se concluye que el uso de la teoria juegos cooperativos, soportado en el valor de Shapley, puede considerarse como una excelente alternativa a la hora de realizar procesos de optimizacion de recursos en un canal PLC y con la posibilidad de ser implementado en sistemas embebidos de bajo costo, debido a que no requiere de operaciones complejas para su estimacion.  MSC: 91A12,90C26 | PACS: 02.50.Le, 84.40.Ua, 02.50.Le
在这篇拟使用理论合作游戏,在游戏的时候使用并且Shapley值,作为优化资源asignacion策略在每个节点,按照需求服务,数量的季节以及频道PLC的条件。本文提出了一种饱和交通条件下的情景,以评估Shapley值在明确建立的交通和通道条件下所能实现的优化程度。由此断定理论游戏合作,担当Shapley值,可以认为是一个不错的选择过程进行时optimizacion PLC和渠道资源和可能性是实施低成本系统中,由于不需要复杂行动的estimacion。MSC: 91A12,90C26 - PACS: 02.50。他,84.40。非盟02.50.Le
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引用次数: 5
Efecto de datos influyentes en el análisis de diseños factoriales de efectos fijos 3 ω 影响数据对固定效应因子设计分析的影响3 ω
Pub Date : 2015-08-04 DOI: 10.17230/INGCIENCIA.11.22.6
Ó. Melo, Carlos A. Falla, J. A. Jiménez-Moscoso
This paper provides a methodology alternative for the detection of in- fluential observations in factorial design of fixed effects 3 ω . Our proposal is developed through the approach of the test statistic (Fq), and the characterization of the impact of such observations on the analysis, the sums of squares and the estimators of the model that describes the experimental design.MSC: 62K15, 62E15, 62-07, 62J20
本文提供了一种在固定效应3 ω的析因设计中检测非影响观测值的替代方法。我们的建议是通过检验统计量(Fq)的方法,以及这些观察对分析、平方和和描述实验设计的模型的估计量的影响的表征来发展的。Msc: 62k15, 62e15, 62-07, 62j20
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引用次数: 0
期刊
Ingenieria y Ciencia
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