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2008 16th IEEE International Conference on Advanced Thermal Processing of Semiconductors最新文献

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Ellipsometry on ion implantation induced damage 椭圆偏振法研究离子注入损伤
P. Petrik, T. Lohner, O. Polgár, M. Fried
The optical properties of semiconductors largely depend on the disorder in the crystal structure, especially in the photon energy range near the direct interband transition energies. The E1 and E2 critical point (CP) energies in silicon are about 3.4 eV (∼365 nm) and 4.2 eV (∼295 nm), respectively. These transitions are located in a photon energy range that is available in most commercial spectroscopic ellipsometers, which makes ellipsometry a powerful technique for the characterization of ion implantation-caused damage. Due to the absorption peaks at the CP energies the optical penetration depth is small. For example, in silicon it is about 10 nm and 5 nm at photon energies corresponding to the E1 and E2 CP energies, respectively. It means that current trends towards shallower junctions and lower ion implantation energies make ellipsometry even more sensitive to the near-surface crystal structure, and the sensitivity of depth profiles can further be increased preparing special samples for the measurements using wedge masks. Ellipsometry measures the complex reflectance ratio of the sample in form of a pair of ellipsometric angles (ψ,Δ) that can accurately be measured using commercial ellipsometers. It is more and more important to use proper optical models to evaluate the measured spectra. There are two key points when evaluating ellipsometric spectra measured on ion implanted semiconductors: (i) the parameterization of the dielectric function of disordered material and (ii) the parameterization of the damage depth profile. The dielectric function can be characterized using numerous methods including the generalized critical point model, the standard critical point model, and the model dielectric function. The depth profile can be described using coupled half-Gaussian profiles or error functions. Because ellipsometry is a non-invasive and non-destructive method, it is capable of the measurement of decreasing disorder in situ, during annealing in a vacuum chamber or a furnace. It has also been demonstrated that ellipsometry is a powerful tool for a quick and non-destructive mapping of large surfaces using special optical arrangements and proper optical models. Using this tool, it is possible to map the lateral homogeneity of the dose, to map the thickness of thin surface layers and any other near-surface properties that can be described by proper optical models.
半导体的光学性质在很大程度上取决于晶体结构的无序性,特别是在接近直接带间跃迁能的光子能量范围内。硅中的E1和E2临界点(CP)能量分别约为3.4 eV (~ 365 nm)和4.2 eV (~ 295 nm)。这些跃迁位于大多数商用光谱椭偏仪可获得的光子能量范围内,这使得椭偏仪成为表征离子注入引起的损伤的强大技术。由于在CP能量处存在吸收峰,因此光学穿透深度较小。例如,在硅中,对应于E1和E2 CP能量的光子能量分别约为10 nm和5 nm。这意味着当前的趋势是更浅的结和更低的离子注入能量使椭圆偏振对近表面晶体结构更加敏感,并且可以进一步提高深度剖面的灵敏度,为楔形掩模的测量准备特殊的样品。椭偏仪以一对椭偏角(ψ,Δ)的形式测量样品的复反射率,这可以用商用椭偏仪精确测量。使用合适的光学模型对测量光谱进行评估变得越来越重要。在评价离子注入半导体的椭偏光谱时,有两个关键点:(1)无序材料介电函数的参数化;(2)损伤深度剖面的参数化。电介质函数可以用多种方法来表征,包括广义临界点模型、标准临界点模型和模型电介质函数。深度分布可以用耦合半高斯分布或误差函数来描述。由于椭偏仪是一种非侵入性和非破坏性的方法,它能够在真空室或炉中原位测量退火过程中减少无序。利用特殊的光学排列和合适的光学模型,椭偏仪是快速、无损地绘制大型表面的有力工具。使用该工具,可以绘制剂量的横向均匀性,绘制薄表面层的厚度和任何其他可以通过适当的光学模型描述的近表面性质。
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引用次数: 3
Impact of multiple sub-melt laser scans on the activation and diffusion of shallow Boron junctions 多次亚熔体激光扫描对浅硼结活化和扩散的影响
E. Rosseel, W. Vandervorst, T. Clarysse, J. Goossens, A. Moussa, R. Lin, D. H. Petersen, P. Nielsen, O. Hansen, N. Bennett, N. Cowern
Sub-melt laser annealing is a promising technique to achieve the required sheet resistance and junction depth specifications for the 32 nm technology node and beyond. In order to obtain a production worthy process with minimal sheet resistance variation at a macroscopic and microscopic level, careful process optimization is required. While macroscopic variations can easily be addressed using the proper spatial power compensation it is more difficult to completely eliminate the micro scale non-uniformity which is intimately linked to the laser beam profile, the amount of overlaps and the scan pitch. In this work, we will present micro scale sheet resistance uniformity measurements for shallow 0.5 keV B junctions and zoom in on the underlying effect of multiple subsequent laser scans. A variety of characterization techniques are used to extract the relevant junction parameters and the role of different implantation and anneal parameters will be explored. It turns out that the observed sheet resistance decrease with increasing number of laser scans is caused on one hand by a temperature dependent increase of the activation level, and on the other hand, by a non-negligible temperature and concentration dependent diffusion component.
亚熔体激光退火是一种很有前途的技术,可以达到32nm及以上技术节点所需的片电阻和结深度规格。为了在宏观和微观水平上获得具有最小片材阻力变化的生产价值的工艺,需要仔细的工艺优化。使用适当的空间功率补偿可以很容易地解决宏观变化,但很难完全消除与激光束轮廓,重叠量和扫描间距密切相关的微观尺度非均匀性。在这项工作中,我们将展示0.5 keV B浅结的微尺度薄片电阻均匀性测量,并放大多次后续激光扫描的潜在影响。使用多种表征技术提取相关结参数,并探讨不同注入和退火参数的作用。结果表明,随着激光扫描次数的增加,所观察到的薄片电阻下降一方面是由温度依赖性的激活水平增加引起的,另一方面是由不可忽略的温度和浓度依赖性扩散成分引起的。
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引用次数: 5
Plasma doping control by mass metrology 等离子体兴奋剂质量计量控制
J. Everaert, G. Zschatzsch, G. Vecchio, W. Vandervorst, L. Cunnane
We show that accurate mass metrology can determine how dopants are added or material is removed during the plasma doping process. In case of erosion, information of mass reduction rate and selectivity can be obtained. Although deposition and erosion can occur simultaneous with implantation, a method is presented how to distinguish these basic reactions. Mass monitoring before and after anneal, reveals that As is very volatile. In the search for a solution we present a post treatment which reduces this loss, hence achieving lower sheet resistance.
我们表明,精确的质量计量可以确定在等离子体掺杂过程中如何添加掺杂剂或去除材料。在腐蚀情况下,可以得到质量还原速率和选择性的信息。虽然沉积和侵蚀可能与注入同时发生,但提出了一种如何区分这些基本反应的方法。退火前后的大量监测表明,砷具有很强的挥发性。在寻找解决方案时,我们提出了一种减少这种损失的后处理方法,从而实现更低的片材电阻。
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引用次数: 0
High mobility and advanced channels materials 高流动性和先进的渠道材料
Jungwoo Oh, P. Majhi, R. Jammy
• Ge based channels appear promising for high mobility pMOSFETs - Need for module level (epi, gate stack, junctions, contacts) optimization as demonstrated • Demonstrated additivity of strain (uniaxial) to the mobility of Ge based channels • Several challenges remain but exciting opportunities for focused research (academic and industry collaboration)
•基于Ge的通道有望用于高迁移率的pmosfet -需要模块级(epi,栅极堆栈,结,触点)优化,证明了应变(单轴)对基于Ge的通道迁移率的可加性•仍然存在一些挑战,但令人兴奋的机会是重点研究(学术和行业合作)
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引用次数: 0
Thermal and non-thermal kinetics of defects and dopant in Si Si中缺陷和掺杂物的热动力学和非热动力学
A. La Magna, G. Fisicaro, G. Mannino, V. Privitera, G. Piccitto, L. Vines, B. Svensson
A modeling approach is formalized and implemented to investigate the kinetics of the defects-dopant system in the extremely far-from-the equilibrium conditions induced by laser irradiation of Si. The master equations for the evolution of the defect-impurity system is rigorously obtained starting from the Boltzmann’s formalism. The formalism allows to simulate beyond the hypothesis of instantaneous equilibration of the local system energy to the lattice thermal field. Comparisons between simulations and experimental analysis of the processes are discussed. These results indicate the general reliability of the Si self-interstitial clusters energetic derived using conventional thermal processes. The impact of the formalism for other non-conventional annealing techniques is discussed.
建立并实现了一种模型方法,用于研究激光辐照硅诱导缺陷掺杂体系在远离平衡条件下的动力学。从玻尔兹曼的形式出发,严格推导出缺陷-杂质体系演化的主方程。这种形式允许对晶格热场的局部系统能量的瞬时平衡进行超越假设的模拟。讨论了模拟过程与实验分析过程的比较。这些结果表明,用常规热过程推导出的Si自间隙团簇能量的总体可靠性。讨论了形式化对其他非常规退火技术的影响。
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引用次数: 0
Temperature measurement in RTP: Past and future RTP中的温度测量:过去和未来
B. Adams
RTP emerged as a mainstream technology during the last two decades in part by solving a difficult technical challenge, that of reliable temperature measurement using optical thermometry. Current thermal processing chambers are capable of controlling temperatures which change at hundreds of degrees celsius per second with repeatability of less than one degree with uniformity on the order of a degree. This is accomplished in a radiatively heated environment where the optical properties of the substrate may vary arbitrarily and contact with it is not acceptable or even feasible. This high degree of thermal stability has enabled the production of the current generation of integrated circuits. Processing requirements are pushing the limits of traditional lamp based technology, and new techniques for sub-second anneals are starting to emerge. With the development of the sub-second anneal, temperature heating and cooling rates may exceed millions of degrees per second, and temperature control may become the limiting factor as it was in the early days of the evolution of the industry.
RTP在过去二十年中成为主流技术,部分原因是解决了一个困难的技术挑战,即使用光学测温技术进行可靠的温度测量。目前的热处理室能够控制以每秒数百摄氏度的速度变化的温度,可重复性小于1度,均匀性为1度。这是在辐射加热的环境中完成的,在这种环境中基材的光学特性可能任意变化,与基材接触是不可接受的,甚至是不可行的。这种高度的热稳定性使当前一代集成电路的生产成为可能。加工要求正在推动传统的基于灯的技术的极限,亚秒退火的新技术开始出现。随着亚秒退火技术的发展,温度加热和冷却速度可能超过每秒数百万度,温度控制可能成为行业发展初期的限制因素。
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引用次数: 3
Parasitic resistance and leakage reduction by raised source / drain extention fabricated with cluster ion implantation and millisecond annealing 簇离子注入和毫秒退火制备的源/漏凸起延伸的寄生电阻和泄漏降低
K. Yako, Toyoji Yamamoto, K. Uejima, T. Ikezawa, M. Hane
We designed and fabricated sub-30 nm gate length pMOSFETs developing the raised source/drain extension (RSDext) process. Our process features usages of cluster-ion (B18H22) implantation and high-temperature millisecond annealing processes and a facet-structure-control of the RSDext of less than 10 nm thickness for suppressing a fringe capacitance increase for the “effective” ultra-shallower junction formation. As the results, experimentally obtained our pMOSFETs with raised source/drain extension show almost the same LMIN, 1/2 times lower parasitic resistance and lower junction leakage.
我们设计并制造了sub- 30nm栅极长度的pmosfet,开发了升高源极/漏极扩展(RSDext)工艺。我们的工艺采用了簇离子(B18H22)注入和高温毫秒退火工艺,并对厚度小于10 nm的RSDext进行了面结构控制,以抑制“有效”超浅结形成的条纹电容增加。实验结果表明,我们的pmosfet具有提高源极/漏极扩展,具有几乎相同的LMIN,寄生电阻降低1/2倍,结漏更低。
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引用次数: 1
Free form microlens sysems enable new laser beam profiles for RTP 自由形式微透镜系统为RTP提供了新的激光束轮廓
D. Hauschild, P. Harten, L. Aschke, V. Lissotschenko
The use of laser technologies for the well defined selective heating of wafers and thin film semiconductors for melt and non-melt RTP processes is an alternative way to fulfil the design goals of next generation semiconductor devices for data processing or photovoltaic. A variety of efficient and reliable laser sources are available from UV to IR that can match the absorption characteristics of nearly any material. To make technical and economical use of these advantages the laser power has to be focussed on the surface with a well defined beam geometry and intensity profile. For a fast processing of 300mm wafers or Gen 8 LCD or solar panels a beam with line or rectangular geometry is needed. In addition to the beam geometry, the intensity distribution in scanning direction is an essential parameter for a controlled temporal heating and cooling profile of the materials. These beam profiles control the vertical thermal penetration depth and reduce the thermal load of the semiconductor layers and substrates by faster scanning speed and μs- and ns-illumination regime.
使用激光技术对晶圆和薄膜半导体进行明确的选择性加热,用于熔体和非熔体RTP工艺,是实现下一代数据处理或光伏半导体器件设计目标的另一种方法。从紫外到红外,各种高效可靠的激光源可以匹配几乎任何材料的吸收特性。为了在技术和经济上利用这些优势,激光功率必须集中在具有良好定义的光束几何形状和强度分布的表面上。为了快速处理300mm晶圆或第8代LCD或太阳能电池板,需要具有直线或矩形几何形状的光束。除了光束的几何形状外,扫描方向上的强度分布是控制材料的时间加热和冷却剖面的重要参数。这些光束轮廓控制了垂直热穿透深度,并通过更快的扫描速度和μs和ns照明模式降低了半导体层和衬底的热负荷。
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引用次数: 1
Emission feedback control system for sub-millisecond laser spike anneal 亚毫秒激光脉冲退火发射反馈控制系统
J. Mcwhirter, D. Gaines, P. Zambon
For the successful implementation of any advanced annealing system in a production environment, real-time measurement and control of wafer peak temperature is critical. For sub-millisecond laser anneal (SMA), the uniformity and repeatability of wafer peak temperature is limited by a variety of local and global effects. Two examples are variations in substrate temperature, and optical power fluctuations which are primarily caused by changes in the transmittance of the beam delivery system. We report on characterization and temperature uniformity performance of a laser spike anneal (LSA) system utilizing a closed loop feedback control system based on thermal emission from the local anneal site. We also report on the results of a characterization of a silicon wafer’s thermal response to temporal variations in incident optical power. Finally, we show that a properly designed measurement and control system enables the achievement of uniform and repeatable peak anneal temperatures.
为了在生产环境中成功实施任何先进的退火系统,晶圆峰值温度的实时测量和控制至关重要。对于亚毫秒激光退火(SMA),晶圆峰值温度的均匀性和可重复性受到各种局部和全局效应的限制。两个例子是衬底温度的变化,以及主要由光束传输系统的透射率变化引起的光功率波动。本文报道了利用基于局部退火点热辐射的闭环反馈控制系统对激光脉冲退火(LSA)系统的表征和温度均匀性。我们还报告了对入射光功率随时间变化的硅晶圆热响应的表征结果。最后,我们证明了一个适当设计的测量和控制系统可以实现均匀和可重复的峰值退火温度。
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引用次数: 2
Wavelength and polarization dependent absorbtion effects in millisecond annealing of metal gate structures 金属栅结构毫秒退火中波长和极化相关的吸收效应
D. Ceperley, A. Neureuther, A. Hawryluk, Xiaoru Wang, M. Shen, Yun Wang
Finite difference time domain simulation of the electromagnetic coupling in millisecond radiation heating is used to explore how the energy couples, where it goes in the device structure, and wavelength dependencies. Millisecond annealing is advantageous for improving IC device characteristics; however, the application of short time scale annealing requires very careful control over the localized heating that can be pattern, device structure, and material dependent. The presence of metal gate structure introduces extra complexity. This paper considers the case of tungsten gates on poly-silicon pedestals with or without silicon nitride caps. Rigorous finite difference time domain techniques are used to compute the fields throughout the device structure as a function of polarization, angle of incidence, wavelength, CD, and pitch. One of the dominant effects is that a grating formed by a metal gate array acts like a polarizer. Thus the coupling changes with grating orientation. The coupling is the strongest when the incident plane is perpendicular to the gate and the electric field is p-polarized. In the case of laser light with a 10 μm wavelength incident near silicon’s Brewster angle, the absorptivity approaches 100% just as if the tungsten metal gates do not exist. Data from similar studies at shorter wavelengths is also presented as well as a comparison with experimental measurements.
利用时域有限差分方法对毫秒辐射加热中的电磁耦合进行了仿真,探讨了能量如何耦合、在器件结构中的去向以及波长依赖关系。毫秒退火有利于改善IC器件的特性;然而,短时间尺度退火的应用需要非常仔细地控制局部加热,这可能是模式,器件结构和材料相关的。金属闸门结构的存在带来了额外的复杂性。本文考虑了在多晶硅基座上钨栅极有或没有氮化硅盖的情况。严格的时域有限差分技术用于计算整个器件结构的场,作为偏振,入射角,波长,CD和螺距的函数。其中一个主要的效应是由金属栅阵列形成的光栅就像一个偏振器。因此,耦合随光栅的取向而变化。当入射平面垂直于栅极且电场为p极化时,耦合最强。当波长为10 μm的激光入射到硅的布鲁斯特角附近时,吸收率接近100%,就像钨金属栅极不存在一样。本文还介绍了短波长的类似研究的数据,并与实验测量结果进行了比较。
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引用次数: 4
期刊
2008 16th IEEE International Conference on Advanced Thermal Processing of Semiconductors
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