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High magnesium isotope ratios in subglacial icelandic waters: impacts of carbonate precipitation and implications for CO2 sequestration 冰岛冰下水域的高镁同位素比率:碳酸盐降水的影响及其对CO2封存的影响
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-13 DOI: 10.1016/j.gca.2025.12.017
Philip A.E. Pogge von Strandmann, Xianyi Liu, Chun-Yao Liu, Sigurður R. Gíslason, Kevin W. Burton
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引用次数: 0
Underplating of H2O-rich magmas in post-collisional tectonic settings 碰撞后构造环境下富氢岩浆的下覆
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-13 DOI: 10.1016/j.gca.2025.12.018
Davide Mariani, Riccardo Tribuzio, Tong Liu, Fu-Yuan Wu, Alberto Zanetti
The Southern Alps expose the Permian Mafic Complex, an 8 km thick gabbro-diorite intrusion formed during the post-collisional phase of the Variscan orogeny. The lower sector of the Mafic Complex mainly consists of amphibole-rich gabbros, thereby suggesting the emplacement of H2O-rich magmas in deep levels of the extending continental crust. To ascertain the nature of these magmas and the processes driving to their chemical differentiation, we have carried out a petrological-geochemical study of a 2.5 km thick section from the Lower Mafic Complex. The amphibole gabbros display a widespread foliation developed under hyper-solidus conditions and locally include concordant layers consisting of: (i) amphibole-free norites enclosing granulite-facies metasedimentary lenses, and (ii) amphibole-rich ultramafic rocks. The amphibole gabbros display Mg# [molar Mg/(Mg + Fe2+tot) × 100] ranging from 48 to 68, associated with nearly homogeneous incompatible trace element signature and Nd-Sr-O isotopic compositions. The Mg# variations therefore record a magmatic differentiation process with no substantial assimilation of crustal material. In detail, the amphibole gabbros have an enriched Nd-Sr isotopic signature (i.e., initial εNd ca. −3.3, initial 87Sr/86Sr ca. 0.7071) that is coupled with a moderate O isotopic enrichment (δ18OWR = +6.3 ‰ to +6.5 ‰, δ18OPx = +6.4 ‰ to +6.9 ‰). The norites typically have an evolved chemical signature and slightly enriched Nd-Sr-O isotopic compositions compared to the amphibole gabbros, indicating that the two rock-types were cogenetically related through a process of crustal contamination. Assimilation of crustal material was driven by anhydrous melts released from basement granulite-facies metasediments and was promoted by extensional deformation. We estimated that 15 % crustal component inhibited the crystallization of Ca-rich mafic silicates (i.e., amphibole and clinopyroxene) and triggered the orthopyroxene saturation in the melt. The ultramafic rocks interlayered with the amphibole gabbros provide evidence for involvement of chemically distinct magma pulses and record reaction processes with melts derived from the adjacent crystallizing gabbros. The primary magmas forming the studied section of the Lower Mafic Complex were most likely generated from a H2O-rich mantle source of subcontinental lithospheric origin undergoing different extents of partial melting. The building of the whole Mafic Complex involved primary magmas derived from mantle sources having markedly heterogeneous compositions.
南阿尔卑斯山暴露了二叠纪基性杂岩,这是一个8 公里厚的辉长闪长岩侵入物,形成于瓦里斯坎造山运动的后碰撞阶段。基底杂岩下部主要为富含角闪岩的辉长岩,表明在伸展的大陆地壳深部有富氢岩浆侵位。为了确定这些岩浆的性质和推动其化学分化的过程,我们对下基底杂岩2.5 km厚的剖面进行了岩石地球化学研究。角闪洞辉长岩在超固相条件下发育广泛的片理,局部包括和谐层,由(i)包裹麻粒岩相变质沉积透镜体的无角闪岩和(ii)富含角闪岩的超基性岩组成。闪孔辉长岩的Mg#[摩尔Mg/(Mg + Fe2+tot) × 100]值在48 ~ 68之间,具有几乎均匀的不相容微量元素特征和Nd-Sr-O同位素组成。因此,镁#的变化记录了一个岩浆分异过程,没有大量的地壳物质同化。角闪洞辉长岩具有富集的Nd-Sr同位素特征(初始εNd ca.−3.3,初始87Sr/86Sr ca. 0.7071),并具有中等富集的O同位素特征(δ18OWR = +6.3 ‰~ +6.5 ‰,δ18OPx = +6.4 ‰~ +6.9 ‰)。与角闪洞辉长岩相比,黑长岩具有演化的化学特征和略富的Nd-Sr-O同位素组成,表明这两种岩石类型通过地壳污染过程具有共成关系。基底麻粒岩相变质沉积物释放的无水熔体推动了地壳物质的同化作用,伸展变形促进了地壳物质的同化作用。15 %的地壳成分抑制了富钙基性硅酸盐(即角闪孔和斜辉石)的结晶,并引发了熔体中正辉石的饱和。超镁铁质岩与角闪洞辉长岩互层提供了化学上不同的岩浆脉冲参与的证据,并记录了与邻近辉长岩结晶产生的熔体的反应过程。形成下基性杂岩研究剖面的原生岩浆极有可能是由源自次大陆岩石圈的富氢地幔源经过不同程度的部分熔融形成的。整个镁铁质杂岩的形成涉及来自地幔源的原始岩浆,它们的成分明显不均匀。
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引用次数: 0
Average trace element composition of the upper continental crust derived from an integrated study of sedimentary and igneous rocks 由沉积岩和火成岩综合研究得出的上大陆地壳的平均微量元素组成
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-12 DOI: 10.1016/j.gca.2025.11.044
Kang Chen, Pengyuan Han, Roberta L. Rudnick, Jingliang Guo, Zhaochu Hu
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引用次数: 0
Constraining the maximum temperature of atmospheric entry heating of dust particles and the effects of flash heating on He and Ne 尘粒进入大气加热的最高温度约束及闪热对He和Ne的影响
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-12 DOI: 10.1016/j.gca.2025.12.016
My E.I. Riebe, Nicola M. Allen, Colin Maden
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引用次数: 0
Whole-rock Fe isotope compositions as mantle source and process tracers across the Hawaiian archipelago 夏威夷群岛全岩铁同位素组成作为地幔源和过程示踪剂
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-10 DOI: 10.1016/j.gca.2025.12.009
Nicole M.B. Williamson, Laura D. Bilenker, Dominique Weis
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引用次数: 0
Global K cycle revisited: The role of arc hydrothermal systems 全球钾循环重访:弧热液系统的作用
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-10 DOI: 10.1016/j.gca.2025.12.011
Cheng Cao, Weiqiang Li, Tianyu Chen, Jun Chen, Yuanfeng Cai
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引用次数: 0
An I-Xe age 8 Myr after solar system formation in a Hayabusa2 sample records alteration on the parent planetesimal of asteroid Ryugu 隼鸟2号样品在太阳系形成后的8 Myr的I-Xe年龄记录了龙宫小行星母星的变化
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-10 DOI: 10.1016/j.gca.2025.12.008
S.A. Crowther, J.S. Cowpe, L. Fawcett, J.D. Gilmour, R. Okazaki, F. Kitajima, T. Yada, S. Tachibana, K. Yogata, K. Sakamoto, H. Yurimoto, T. Nakamura, T. Noguchi, H. Naraoka, H. Yabuta, S. Watanabe, Y. Tsuda, M. Nishimura, A. Nakato, A. Miyazaki, M. Abe, T. Okada, T. Usui, M. Yoshikawa, T. Saiki, S. Tanaka, F. Terui, S. Nakazawa, H. Busemann, K. Hashizume, B. Marty, A. Meshik, M.E.I. Riebe, D. Krietsch, C. Maden, A. Ishida, P. Clay, T. Lawton, M.W. Broadley, D.J. Byrne, E. Füri, L. Zimmermann, O. Pravdivtseva, Y.N. Miura, J. Park, K. Bajo, Y. Takano, K. Yamada, S. Kawagucci, Y. Matsui, M. Yamamoto, K. Righter, S. Sakai, N. Iwata, N. Shirai, M. Inagaki, M. Ebihara, K. Nishiizumi, K. Nagao, J.I. Lee, A. Kano, M.W. Caffee, R. Uemura
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引用次数: 0
Formation of glauconite with co-occurring apatite traces marine rare earth element behavior: evidence from US Atlantic continental margin sediments 海绿石与共生磷灰石的形成表明海洋稀土元素行为:来自美国大西洋大陆边缘沉积物的证据
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-09 DOI: 10.1016/j.gca.2025.12.010
Caroline H. Koschik, Xiao-Ming Liu
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引用次数: 0
Evaluating shallow-water carbonates as archives for seawater zinc isotope compositions: implications for palaeoceanographic studies 评价作为海水锌同位素组成档案的浅水碳酸盐:对古海洋学研究的意义
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-09 DOI: 10.1016/j.gca.2025.12.012
Chengyu Zhang, Mengchun Cao, Na Li
Zinc (Zn) is an essential micronutrient for marine phytoplankton and exhibits a strong linear correlation with the major nutrient silicon in modern oceans. In recent years, Zn isotopes (δ66Zn) in marine carbonates have been increasingly used as proxies for reconstructing past marine productivity. However, improved understanding of the modern marine Zn cycle suggests that this potential link may be obscured by multiple biotic and abiotic factors. Additionally, the diverse mineralogical types and broad δ66Zn ranges reported for carbonate archives have raised ongoing debates about the reliability of marine carbonates in recording seawater zinc isotopic composition. Here, we present new δ66Zn data from 39 bulk carbonate sediment samples collected from two shallow-water push cores (Jiuzhang Atoll) in the South China Sea. The samples yield relatively consistent δ66Zn values across depth profiles, averaging +0.28 ± 0.11 ‰ (2SD), suggesting that shallow-water carbonates may serve as promising archives for palaeoceanographic reconstructions. However, comprehensive comparison with other recent carbonates—considering both Zn isotopic compositions and concentrations—suggests that the original seawater δ66Zn signatures recorded in ancient carbonate rocks were likely modified by depositional and diagenetic processes. These processes include mixing between inorganic primary calcite and biogenic carbonates, and the redox conditions of pore waters during deposition. Furthermore, the low Zn concentrations in modern primary carbonates—only about 3 % of those in ancient carbonate rocks—highlight their high susceptibility to diagenetic alteration. In addition, the wide spatial variability of modern surface seawater δ66Zn complicates the establishment of a consistent isotopic offset for calibrating ancient carbonates. Together, our findings call for caution when employing carbonate-hosted Zn isotopes as proxies for past ocean productivity, particularly given the unresolved uncertainties regarding the relationship between seawater δ66Zn and marine primary production.
锌(Zn)是海洋浮游植物必需的微量营养元素,与现代海洋中主要营养元素硅呈较强的线性相关。近年来,海洋碳酸盐岩中的Zn同位素(δ66Zn)越来越多地被用作重建过去海洋生产力的指标。然而,对现代海洋锌循环的进一步了解表明,这种潜在的联系可能被多种生物和非生物因素所掩盖。此外,碳酸盐档案中不同的矿物类型和广泛的δ66Zn范围引起了关于海相碳酸盐记录海水锌同位素组成可靠性的争论。本文对南海两个浅水推动岩心(九章环礁)的39个大块碳酸盐沉积物样品进行了新的δ66Zn数据分析。样品的δ66Zn值在各深度剖面上相对一致,平均为+0.28±0.11‰(2SD),表明浅水碳酸盐岩可以作为古海洋重建的有前景的档案。然而,综合对比其他近代碳酸盐岩,考虑Zn同位素组成和浓度,认为古碳酸盐岩中记录的原始海水δ66Zn特征可能受到沉积和成岩作用的改变。这些过程包括无机原生方解石与生物碳酸盐的混合,以及沉积过程中孔隙水的氧化还原条件。此外,现代原生碳酸盐岩锌含量较低,仅为古碳酸盐岩锌含量的3%左右,表明其易受成岩蚀变的影响。此外,现代表层海水δ66Zn的广泛空间变异性使得建立一致的同位素偏移以校准古代碳酸盐变得复杂。总之,我们的研究结果呼吁在使用碳酸盐承载的Zn同位素作为过去海洋生产力的代理时要谨慎,特别是考虑到关于海水δ66Zn与海洋初级生产之间关系的未解决的不确定性。
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引用次数: 0
The behaviour of Ni and its isotopes during early diagenesis of Mn oxide-rich abyssal sediments 富氧化锰深海沉积物早期成岩过程中镍及其同位素的行为
IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-07 DOI: 10.1016/j.gca.2025.12.007
Sarah Fleischmann, Jianghui Du, Brian Haley, James McManus, Mingzhao Sun, Derek Vance
The use of nickel (Ni) and its isotope system as biogeochemical tracers of past ocean environments requires a sound understanding of the oceanic mass balance and the sinks that control output fluxes. Recent efforts have focused in particular on quantifying and understanding the size and Ni isotope composition of the most complicated and largest sink of Ni from the dissolved oceanic pool, the output to oxic Mn-rich sediments. The precise processes controlling Ni and its isotopes during early diagenesis in oxic sediments are not yet fully understood, but could impact estimates of the net oxic sink used in oceanic mass balance calculations. To address this issue, we present Ni concentration and isotope data from fully oxic Mn-rich sediments and corresponding porewater samples from 3 stations in the Equatorial North Pacific, south of Hawai’i.
使用镍(Ni)及其同位素系统作为过去海洋环境的生物地球化学示踪剂,需要对海洋质量平衡和控制输出通量的汇有充分的了解。最近的工作主要集中在量化和理解溶解海洋池中最复杂和最大的Ni汇的大小和Ni同位素组成,输出到富锰的富氧沉积物。在含氧沉积物早期成岩过程中控制镍及其同位素的精确过程尚未完全了解,但可能影响用于海洋质量平衡计算的净氧汇的估计。为了解决这一问题,我们提供了来自夏威夷以南赤道北太平洋3个站点的全氧富锰沉积物和相应孔隙水样品的Ni浓度和同位素数据。
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引用次数: 0
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Geochimica et Cosmochimica Acta
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