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Investigations on Different Sol-gel Incorporation Methods of Green Synthesized AgNPs in Textiles for Antibacterial Activity 绿色合成AgNPs在纺织品中不同溶胶-凝胶掺入方式的抗菌活性研究
Pub Date : 2023-09-12 DOI: 10.31881/tlr.2023.088
Toufique Ahmed, R. Tugrul Ogulata, Osman Gülnaz
Sol-gel is an excellent antibacterial agent carrier. Different researchers incorporated various antibacterial substances, including silver nitrate (AgNO3), quarternary ammonium chloride (QAC), and titanium dioxide (TiO2) in sol-gel. However, there is limited study on the influence of pH and acid hydrolysis time (ageing) to form sol-gel. Besides, few investigations have been made on the influence of fabric structure and silver nanoparticles (AgNPs) incorporation into fabrics by the sol-gel method. This study also compared the light and heavy fabrics in terms of sol-gel application and the advantages of sol-gel over other AgNPs incorporation methods. The sol-gel-AgNPs incorporated fabric samples were characterized by Ultra Violet Spectroscopy (UV-VIS), X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersion spectroscopy (EDS). For AgNPs synthesis in a green way, we used Calendula arvensis, a Mediterranean weed. This study found, that for sol-gel formation the minimum acid hydrolysis time was 5.30 hours, 6.30 hours, and 8.00 hours at 60 ºC, 25 ºC, and 3 ºC, respectively. After ageing, a minuscule amount of alkaline was needed for gelation. Seven different methods for incorporating AgNPs through sol-gel have been illustrated. The lower molarity of AgNO3, having a more significant portion in the sol-gel solution, had excellent antibacterial activity and wash fastness. Besides, the ex-situ method was better than the in-situ method. Among different types of cotton fabric, lightweight knit fabric showed much better antibacterial activity than heavier twill fabric.
溶胶-凝胶是一种优良的抗菌剂载体。不同的研究人员在溶胶-凝胶中加入了各种抗菌物质,包括硝酸银(AgNO3)、氯化铵(QAC)和二氧化钛(TiO2)。然而,关于pH和酸水解时间(老化)对形成溶胶-凝胶的影响的研究有限。此外,溶胶-凝胶法对织物结构和银纳米粒子(AgNPs)掺入织物的影响研究较少。本研究还比较了轻质和重型织物在溶胶-凝胶应用方面的差异,以及溶胶-凝胶与其他AgNPs掺入方法相比的优势。采用紫外光谱(UV-VIS)、x射线衍射(XRD)、扫描电镜(SEM)和能谱仪(EDS)对溶胶-凝胶- agnps织物样品进行了表征。对于AgNPs的绿色合成,我们使用了金盏菊,一种地中海杂草。本研究发现,在60ºC、25ºC和3ºC条件下,形成溶胶-凝胶的最短酸水解时间分别为5.30小时、6.30小时和8.00小时。老化后,凝胶化需要少量的碱性物质。本文介绍了通过溶胶-凝胶结合AgNPs的七种不同方法。AgNO3的摩尔浓度较低,在溶胶-凝胶溶液中占有更大的比例,具有良好的抗菌活性和洗涤牢度。此外,非原位法优于原位法。在不同类型的棉织物中,轻质针织物的抗菌活性明显优于较重的斜纹织物。
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引用次数: 0
Optimization Rubbing Fastness in Lyocell and Silk Fabric Dyeing with Tinospora cordifolia using Box-Behnken Design and Citrus limon Extract with Potassium Aluminium Sulfate Mordants 用Box-Behnken设计和柑桔柠檬提取物与硫酸铝钾介质优化对莱cell和真丝织物染色的摩擦牢度
Pub Date : 2023-09-12 DOI: 10.31881/tlr.2023.105
Ramratan Guru, Jyoti Rani
The demand for environmentally friendly natural dyes has risen significantly. This study currently aims to assess the rub-fastness properties of silk and lyocell fabrics that have been dyed using Tinospora cordifolia stem extracts. This dyeing process involves the utilization of both Citrus limon and potassium aluminium sulfate as mordants. To achieve this objective, we have employed the Box-Behnken experimental research design for sample preparation. Our investigation delves into the influence of various processing factors, encompassing dye concentration, time duration, and temperature, on the rubbing fastness attributes of lyocell and silk fabrics treated with Citrus limon extract and alum mordant. The dye, sourced through an aqueous extraction method from Tinospora cordifolia stems, is subsequently employed in dyeing silk and lyocell fabrics, followed by mordanting using the meta-mordanting technique. The assessment of rubbing fastness quality is conducted using the standard test method AATCC 8 for both fabric types. Our experimental findings unveil a notable similarity in rubbing properties between lyocell and silk fabrics dyed with Citrus limon and those treated with potassium aluminium sulfate mordant. Intriguingly, fabric samples treated with Citrus limon mordants exhibit marginally enhanced rubbing (2 to 3 G to 5 G) results when juxtaposed with their counterparts treated with potassium aluminium sulfate mordant. Throughout the experimental course, it becomes evident that both temperature (35 °C, 50 °C, 65 °C) and time (40, 55 and 70 min) exert a significant influence on the wet and dry rubbing fastness characteristics of both silk and lyocell fabrics. Notably, as dyeing time and temperature increase, there is a corresponding rise in fabric dye uptake.
对环保天然染料的需求显著上升。本研究目前的目的是评估用Tinospora cordifolia茎提取物染色的丝绸和莱赛尔织物的耐摩擦性能。这种染色方法包括使用柑橘柠檬和硫酸铝钾作为媒染剂。为了实现这一目标,我们采用Box-Behnken实验研究设计进行样品制备。本文研究了染料浓度、时间、温度等不同处理因素对柠檬酸柠檬提取物和明矾媒染剂对莱赛布和真丝织物摩擦牢度的影响。染料通过水萃取法从Tinospora cordifolia茎中提取,随后用于对丝绸和lyocell织物进行染色,然后使用超媒染法进行媒染法。摩擦牢度质量的评定采用AATCC 8标准测试方法对两种织物进行。我们的实验结果揭示了用柑橘酸橙染色和硫酸铝钾介质处理的莱赛尔织物和真丝织物在摩擦性能上的显著相似性。有趣的是,与硫酸铝钾媒染剂处理的织物样品相比,柑橘柠檬媒染剂处理的织物样品表现出轻微增强的摩擦(2到3g到5g)结果。在整个实验过程中,温度(35°C、50°C、65°C)和时间(40、55和70 min)对真丝和莱赛尔织物的干湿摩擦牢度特性都有显著影响。值得注意的是,随着染色时间和温度的增加,织物的染料吸收率也相应增加。
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引用次数: 0
Application of Coriander to Medical Cotton Bandage for the Development of Antimicrobial and Wound- Healing Properties 芫荽在医用棉绷带中的应用及其抗菌和伤口愈合性能的发展
Pub Date : 2023-09-09 DOI: 10.31881/tlr.2023.113
Joyjit Ghosh, Nishat Sarmin Rupanty, Shohag Chandra Das
The aim of the research is to create a medical bandage utilizing an eco-friendly herb extract that is both antibacterial and wound-healing without the use of external dressing materials. The goal was accomplished by solvent extraction of the coriander herb (Coriandrum sativum). Ten layers of extracted solution were combined with one cotton bandage to create it using the pad-dry-cure technique. Following the same process, a second sample was created with a single layer using a ten-fold more concentrated coriander extraction solution. The K/S value measurement, SEM analysis, ATR analysis, and antimicrobial test were performed on treated materials. Implementations of the samples were made on a rabbit's wound site to demonstrate their ability to recover. The second sample's K/S value was remarkably similar to that of the first sample's tenth layer which was 0.89. The second sample's SEM picture showed that a significant amount of coriander extract had been deposited on the fibre surface. The presence of coriander extract's phytochemicals in the treated sample was confirmed by ATR analysis. Samples that had been padded with coriander extract had zones of inhibition (ZOI) against Grampositive and Gram-negative bacteria that were 14 mm and 12 mm, respectively, in terms of antibacterial activity. Healing of the wound showed good results when the bandages were removed after seven days. The wound had fully recovered. Environmentally friendly products are in high demand in the medical industry. Therefore, these modified samples are marketable for use as medical bandages.
这项研究的目的是创造一种医用绷带,利用一种环保的草药提取物,既能抗菌,又能愈合伤口,不需要使用外部敷料。目的是通过溶剂提取芫荽草(Coriandrum sativum)。将提取的十层溶液与一个棉质绷带结合使用垫干固化技术制成。按照同样的过程,第二个样品是用十倍浓度的香菜提取溶液制作的单层样品。对处理后的材料进行K/S值测定、SEM分析、ATR分析和抗菌试验。样品的实施是在兔子的伤口部位进行的,以证明它们的恢复能力。第二个样品的K/S值与第一个样品的第10层的K/S值非常相似,为0.89。第二个样品的扫描电镜图片显示,大量的香菜提取物已经沉积在纤维表面。经ATR分析证实香菜提取物中存在植物化学物质。用香菜提取物填充的样品对革兰氏阳性菌和革兰氏阴性菌的抑菌区(ZOI)分别为14 mm和12 mm。7天后取下绷带,伤口愈合效果良好。伤口已完全愈合。医疗行业对环保产品的需求量很大。因此,这些改性样品可作为医用绷带销售。
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引用次数: 0
Re/Assembling the Imaginary: Counter-Narratives of Haiti’s Transnational Textile Industry 重新组装想象:海地跨国纺织工业的反叙述
Pub Date : 2023-08-24 DOI: 10.1080/14759756.2023.2242118
C. Hammond
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引用次数: 0
Investigating the Influence on the Electro-Conductive Properties of Leather as a Result of Natural Aging 自然老化对皮革导电性能影响的研究
Pub Date : 2023-08-24 DOI: 10.31881/tlr.2023.086
Majlinda Hylli, Aulon Shabani, Ilda Kazani, Genti Guxho
Conductive leather and its use in smart products have found a lot of interest. Leather behaves as a good insulator, so it was treated with electrically conducting polypyrrole using a chemical polymerization technique to give it conductive characteristics. The electro-conductive properties are obtained by using the double in–situ oxidative polymerization of pyrrole. The electrical properties of conductive samples are studied using the Van Der Pauw method as a measuring method. The conductive leather transformation process was carried out during the 2018-2020 period, and the conductive leather samples were preserved in room conditions until the year 2023. The effect of natural ageing on the electro-conductive properties of conductive leather is the focus of this research. The results show that environmental factors influence polymer breakdown and stability, by causing an increase in electrical resistance. The changes in electrical surface resistance, as the effect of the ageing factor, vary from 39.8% to 129.9%. Those changes in electrical resistance indicate that ageing is one of the major concerns in the electrical properties and stability of conductive leather samples, so the performed measurements have importance in providing information for the researchers and designers regarding the conductivity changes over time as a result of natural ageing, which would like to work with conductive leather on smart products.
导电皮革及其在智能产品中的应用引起了人们的极大兴趣。皮革是一种很好的绝缘体,所以用化学聚合技术对皮革进行了导电聚吡咯处理,使其具有导电特性。采用双原位氧化聚合法制备了吡咯的导电性能。采用Van Der Pauw法对导电样品的电性能进行了研究。导电皮革的转化过程在2018-2020年期间进行,导电皮革样品在室内条件下保存到2023年。自然老化对导电皮革导电性能的影响是本研究的重点。结果表明,环境因素通过引起电阻的增加来影响聚合物的击穿和稳定性。由于老化因素的影响,电表面电阻的变化从39.8%到129.9%不等。这些电阻的变化表明,老化是导电皮革样品电性能和稳定性的主要问题之一,因此所进行的测量对于为研究人员和设计师提供有关自然老化导致的电导率随时间变化的信息具有重要意义,这希望在智能产品上使用导电皮革。
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引用次数: 0
Braiding the Identity of the Zenú People: Territory and Nature-Culture Relationships in the Crafting of the Vueltiao Hat 编织的身份Zenú人:领土和自然文化的关系,在制作韦尔提奥帽
Pub Date : 2023-08-24 DOI: 10.1080/14759756.2023.2233178
Sandra Milena Babativa Chirivi, Rosa Inés Babilonia Ballesteros, Darío Pérez
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引用次数: 0
Protecting “Paradise”: Anti-Nuclear Textiles in New Zealand 保护“天堂”:新西兰的反核纺织品
Pub Date : 2023-08-24 DOI: 10.1080/14759756.2023.2239563
Jane Groufsky
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引用次数: 0
Stormy Weather: Textile Art, Water and Climate Emergency 暴风雨天气:纺织艺术、水和气候紧急情况
Pub Date : 2023-08-24 DOI: 10.1080/14759756.2023.2239568
Fionna Barber, J. Gilson
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引用次数: 0
Investigating the Influence on the Electro-Conductive Properties of Leather as a Result of Natural Aging 自然老化对皮革导电性能影响的研究
Pub Date : 2023-08-24 DOI: 10.31881/tlr.2032.086
Majlinda Hylli, Aulon Shabani, Ilda Kazani, Genti Guxho
Conductive leather and its use in smart products have found a lot of interest. Leather behaves as a good insulator, so it was treated with electrically conducting polypyrrole using a chemical polymerization technique to give it conductive characteristics. The electro-conductive properties are obtained by using the double in–situ oxidative polymerization of pyrrole. The electrical properties of conductive samples are studied using the Van Der Pauw method as a measuring method. The conductive leather transformation process was carried out during the 2018-2020 period, and the conductive leather samples were preserved in room conditions until the year 2023. The effect of natural ageing on the electro-conductive properties of conductive leather is the focus of this research. The results show that environmental factors influence polymer breakdown and stability, by causing an increase in electrical resistance. The changes in electrical surface resistance, as the effect of the ageing factor, vary from 39.8% to 129.9%. Those changes in electrical resistance indicate that ageing is one of the major concerns in the electrical properties and stability of conductive leather samples, so the performed measurements have importance in providing information for the researchers and designers regarding the conductivity changes over time as a result of natural ageing, which would like to work with conductive leather on smart products.
导电皮革及其在智能产品中的应用引起了人们的极大兴趣。皮革是一种很好的绝缘体,所以用化学聚合技术对皮革进行了导电聚吡咯处理,使其具有导电特性。采用双原位氧化聚合法制备了吡咯的导电性能。采用Van Der Pauw法对导电样品的电性能进行了研究。导电皮革的转化过程在2018-2020年期间进行,导电皮革样品在室内条件下保存到2023年。自然老化对导电皮革导电性能的影响是本研究的重点。结果表明,环境因素通过引起电阻的增加来影响聚合物的击穿和稳定性。由于老化因素的影响,电表面电阻的变化从39.8%到129.9%不等。这些电阻的变化表明,老化是导电皮革样品电性能和稳定性的主要问题之一,因此所进行的测量对于为研究人员和设计师提供有关自然老化导致的电导率随时间变化的信息具有重要意义,这希望在智能产品上使用导电皮革。
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引用次数: 0
Maker to Wearer: A Transfer of Intention 制造者到穿戴者:意向转移
Pub Date : 2023-08-24 DOI: 10.1080/14759756.2023.2242122
H. Kim
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引用次数: 0
期刊
Textile Leather Review
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