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UNJUK KERJA NaOH DALAM MEREDUKSI LOGAM BERAT PADA LIMBAH ABU BOILER NaOH 在减少锅炉废渣中重金属方面的应用
Pub Date : 2024-06-10 DOI: 10.51544/kimia.v8i1.4950
Maria Peratenta Sembiring, Rozanna Sri Irianty, Zulfansyah, Chairul
Proses pembakaran batu bara menghasilkan emisi berupa gas SO2, NO2, CO, CO2, volatile hydrocarbon (VHC), suspended particulate matter (SPM), serta residu padat berupa abu boiler. Abu boiler mengandung berbagai logam berat beracun, diantaranya tembaga (Cu), kobalt (Co), kromium (Cr), cadmium (Cd) dan timbal (Pb). Penelitian ini bertujuan untuk menentukan efisiensi reduksi logam berat Cu, Co, Cr, Pb, dan total dengan melakukan ekstraksi menggunakan pelarut kimia NaOH dan mengubah logam transisi menjadi kompleks dengan Ethylene diamine tetraacetic acid (EDTA) pada rasio EDTA: abu boiler sebesar 1:2, 1:1, 2:1; durasi pengadukan sebesar 2 dan 4 jam; serta suhu ekstraksi sebesar 25 dan 60 oC. Analisis Inductively Coupled Plasma (ICP) dilakukan untuk mengetahui penurunan kadar logam berat dari ekstrak abu boiler. Hasil penelitian menunjukkan bahwa kondisi ekstraksi berupa rasio EDTA: abu boiler sebesar 2:1, durasi pengadukan sebesar 4 jam, dan suhu ekstraksi sebesar 60 oC dapat menghasilkan persentase penurunan kadar logam berat total tertinggi yang mencapai 77,2% dengan persentase penurunan kadar Co, Cr, Cu, dan Pb secara berturut-turut sebesar 75,4%, 77,9%, 74,5%, dan 81,9%. Penelitian ini diharapkan dapat menjadi rekomendasi bagi penelitian selanjutnya dalam mengeksplor potensi pemanfaatan abu boiler yaitu sebagai bahan campuran aspal, pembuatan batako, dan sebagainya.
燃煤过程会产生二氧化硫、二氧化氮、一氧化碳、二氧化碳、挥发性碳氢化合物 (VHC)、悬浮颗粒物 (SPM) 以及锅炉灰渣形式的固体残留物。锅炉灰含有多种有毒重金属,包括铜 (Cu)、钴 (Co)、铬 (Cr)、镉 (Cd) 和铅 (Pb)。本研究旨在确定铜、钴、铬、铅和总重金属的还原效率,方法是使用 NaOH 化学溶剂萃取,并将过渡金属转化为乙二胺四乙酸(EDTA)络合物,EDTA:锅炉灰的比例分别为 1:2、1:1、2:1;搅拌时间分别为 2 小时和 4 小时;萃取温度分别为 25 摄氏度和 60 摄氏度。为确定锅炉灰提取物中重金属含量的下降情况,进行了电感耦合等离子体(ICP)分析。结果表明,乙二胺四乙酸与锅炉灰比例为 2:1、搅拌时间为 4 小时、萃取温度为 60 摄氏度的萃取条件下,重金属总含量的降低率最高,达到 77.2%,钴、铬、铜和铅的降低率分别为 75.4%、77.9%、74.5% 和 81.9%。这项研究有望为进一步探索锅炉灰的潜在利用价值(即作为沥青混合材料、制砖等)提供建议。
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引用次数: 0
PROCESSING OF SAWDOW WASTE OF MAHONI AND JATI WOOD AS A MATERIAL GYPSUM CEILING FILLERS WITH POLIVINYL ADHESIVE ALCOHOL 加工马霍尼和贾提木锯废作为石膏吊顶填料的材料用聚乙烯醇胶粘剂
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3986
Liver Zai, Estetika Niat Iman Halawa, Malemta Tarigan, Erdiana Gultom, V. Purwandari, Ong Amanda Jiamin
Along with the increase in population, the need for building materials, namely wood, will increase, thus triggering rampant illegal logging, which will cause floods, landslides, and global warming. One of the efforts made to reduce the use of wood is to make gypsum composite boards. This study aims to utilize mahogany wood waste and jati wood powder as gypsum board fillers. Research has been carried out on processing waste sawdust from mahogany and jati wood as a filling material for making gypsum ceilings with polyvinyl alcohol adhesive by mixing and compacting using a hot compressor at 70o C. Good quality with a density value of 0.82 g /cm3 and absorption capacity of 38.4% complied with SNI 03-2105-2006. Mechanical properties with variations in impact strength (95:5:10) of 19.014 J/m2, flexural strength of variation (95:5) of 395, 446 N/m2, and fracture strength of variation (95:5:5) of 1.7758 N/m2. A Gypsum board was obtained, which did not meet SNI 03-6384-2000 on the gypsum board specification for the results of testing for flexural strength and fracture strength.
随着人口的增加,对建筑材料,即木材的需求将会增加,从而引发猖獗的非法采伐,这将导致洪水,山体滑坡和全球变暖。为减少木材的使用所做的努力之一是制作石膏复合板。本研究的目的是利用红木废料和贾提木粉作为石膏板填料。研究了将红木、皂角木废锯末作为聚乙烯醇胶粘剂制作石膏顶棚的填充材料,在70℃高温下进行混合压实处理。质量优良,密度值为0.82 g /cm3,吸收量为38.4%,符合SNI 03-2105-2006标准。力学性能:冲击强度(95:5:10)变化为19.014 J/m2,弯曲强度(95:5)变化为395,446 N/m2,断裂强度(95:5:5)变化为1.7758 N/m2。所制石膏板的抗折强度和断裂强度试验结果不符合石膏板规范SNI 03-6384-2000的要求。
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引用次数: 1
PEMBUATAN NANOKARBON DARI LIMBAH PADAT KELAPA SAWIT MENGGUNAKAN METODE HIDROTERMAL 利用热液方法从棕榈油固体废物中提取纳米碳
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3906
Nelson Silitonga, Nurliana Tarigan, Gimelliya Saragih, Vivi Purwandari, Ahmad Zukhruf Akbari
Meningkatnya kesadaran tentang polusi telah menyebabkan pengembangan solusi untuk masalah lingkungan dengan memaksimalkan pemanfaatan biomassa yang berlimpah untuk pembuatan nanokarbon. Penelitian ini bertujuan untuk memanfaatkan limbah padat kelapa sawit menjadi material yang memiliki nilai guna dan nilai ekonomis menjadi nanokarbon dan material yang berteknologi tinggi. nanokarbon yang berasal dari pelepah dan cangkang sawit yang dibuat melalui metode hidrotermal dengan 180oC selama 2 jam dengan pelarut air dan dilakukan metode ultrasonikasi selama 15 menit. Nanokarbon yang didapat  dikarakterisasi menggunakan Fourier Tranform Infrared (FTIR), X-Ray Difraktometer (XRD), dan Particle Size Analyzer (PSA). Dari hasil analisa gugus fungsi menggunakan FTIR telah menunjukan gugus fungsi nanokarbon dan ditemukan perubahan ukuran partikel yang sangat signifikan dari proses sebelum dan sesudah proses hidrotermal, yaitu 895,2 nm menjadi 334,2 nm. Peningkatan volume pori dan luas permukaan partikel masing-masing sebesar 3,5% dan 63% setelah proses hidrotermal.
越来越多的污染意识导致了环境问题的解决方案,通过最大限度地利用大量的生物量来制造纳米碳。这项研究的目的是将一种有价值的、经济价值的棕榈油废物转化为碳和高科技材料。纳米碳是由氢气和棕榈油制成的,通过水冷介质使用180oC 2小时,用水溶剂进行了15分钟的超声波处理。通过FTIR、x光仪和粒子分析仪(PSA)对纳米碳进行了分类。利用FTIR进行的函数星团分析发现了纳米碳星团,热液工艺前后的颗粒大小发生了显著变化,即895.2 nm至334.2 nm。热液处理后,每一个孔体积和表面积增加3.5%和63%。
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引用次数: 0
PENGARUH UKURAN PARTIKEL TANDAN KOSONG KELAPA SAWIT (TKKS) DAN CANGKANG SAWIT DALAM PEMBUATAN PAPAN PARTIKEL MENGGUNAKAN POLIETILENA (PE) DAN POLIVINIL ALKOHOL (PVA)
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3867
Donda Donda, E. Salim, Darni Paranita, Yosua Francisco
Telah dilakukan penelitian terhadap besar ukuran Tandan Kosong Kelapa Sawit (TKKS) terhadap beberapa bahan polimer  yaitu LDPE (Low Density Polietilena), HDPE (High Density Polietilena, dan PVA (Polivinil Alkohol) diperoleh hasil terhadap daya serap air sangat dipengaruhi terhadap ukuran TKKS  dimana semakin besar ukuran bahan (10 mesh) pada bahan LDPE semakin besar daya serap air = 9,47 %, sedangkan pada HDPE semakin besar ukuran TKKS (10 mesh) semakin besar daya serap = 2,34 %, dan untuk bahan PVA untuk TKKS (10 mesh) semakin besar kadar air semakin kecil =7,39%,  kerapatan partikel pada bahan LDPE semakin kecil ukuran TKKS (60 mesh) kerapatan semakin besar = 1,39 g/ml, pada bahan HDPE semakin kecil ukuran TKKS (40 mesh) maka nilai kerapan makin tinggi =1,80 g/ml, sedang pada bahan PVA semakin besar ukuran TKKS akan lebih besar nilai kerapatannya untuk ukuran TKKS (20 mesh ) =1,09 g/ml. Keteguhan patah (MOR)  untuk bahan LDPE semakin besar ukuran TKKS (10 mesh)  semakin semakin besar = 0,70  x 102 kgf/cm2, untuk bahan HDPE semakin besar ukuran TKKS maka keteguhan patah (MOR) semakin besar untuk TKKS  (10 mesh) = 0,81 x 102 kgf/cm2 dan untuk bahan PVA semakin kecil ukuran TKKS maka semakin besar nilai keteguhan patah (MOR) untuk   TKKS ukuran bahan (60 mesh) = 0,70x 102 kgf/cm2
研究对大尺寸做了空串(TKKS)对一些棕榈油LDPE(低密度Polietilena),聚合物材料HDPE的高密度Polietilena, PVA (Polivinil酒精)获得的结果对水渗透性深受对TKKS大小尺寸越大(10网)材料在哪里LDPE材料吸收水= 9.47 %功率越大,而对HDPE TKKS尺寸越大(10网)渗透性= 234 %越大,和为TKKS PVA材料(10网)= 7,39%越小,水分越大LDPE TKKS尺寸越小的粒子密度材料(60网)= 1,39 g / ml越大,密度对HDPE材料TKKS尺寸越小(40网)那么kerapan价值=大约g / ml越高,在PVA材料层TKKS会更大尺寸越大价值对于TKKS(20网)= 1.09 g / ml。莫尔(骨折)来坚定LDPE TKKS尺寸越大,材料(10 x网)= 0.70越大越102 kgf / cm2, HDPE材料TKKS尺寸越大那么决心断了(MOR)为TKKS越大(10网)= x 0,81 102 kgf / cm2和PVA材料为TKKS尺寸越小就越坚定的价值大断了莫尔()来TKKS大小(60网材料)= 0,70x 102 kgf / cm2
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引用次数: 0
PENENTUAN DISOLUSI PADA OBAT SENYAWA KETOPROFEN SECARA SPEKTROFOTOMETRI 光谱测定化合物KETOPROFEN的解药
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3868
Renny Futeri, Pevi Riani
Research on dissolution determination of Ketoprofen compounds by Spectrophotometry. Ketoprofen is a non-steroidal anti-inflammatory drug compound (NSAID) that works as an anti-inflammatory. Anti-inflammatory here is a group of drugs used to reduce inflammation and relieve pain. The dissolution test is a method used to determine the content of active compounds that dissolve in drugs, where the time, temperature and media are set according to the human stomach and intestines, and can find out how much the content of active compounds dissolves in the human intestines and stomach. This dissolution test, then the ketoprofen drug is read by spectrophotometry. Test the dissolution by spectrophotometer at a wavelength of 260 nm using HCl 0.1 N and buffer pH 7.4. The results of the determination of the dissolution test of the active substance on ketoprofen at the acid stage obtained an average of 0.009% and at the pH 7.4 buffer stage obtained an average content of 86.4155%. It can be concluded that the determination of the ketoprofen dissolution test in the sample meets the requirements (MS), in accordance with the specifications of the Internal Standard of PT Novell Pharmaceutical Laboratories, namely at the acid stage not more than 10% of ketoprofen dissolved in 2 hours, and at the pH 7.4 buffer stage it has a requirement of 75%. ketoprofen dissolved in 45 minutes. In the dissolution of acidic media, 0.1 N HCl is used because its condition resembles that of the stomach.
分光光度法测定酮洛芬类化合物溶出度的研究。酮洛芬是一种非甾体抗炎药化合物(NSAID),具有抗炎作用。消炎在这里是指一组用于减少炎症和缓解疼痛的药物。溶出度试验是测定药物中溶解的活性化合物含量的一种方法,根据人体的肠胃设定时间、温度和介质,可以得知活性化合物的含量在人体的肠胃中溶解了多少。溶出度试验,然后用分光光度法读出酮洛芬药物。用盐酸0.1 N,缓冲液pH 7.4,分光光度计在260 nm波长下测定溶出度。酮洛芬在酸性阶段的活性物质溶出度测定结果平均为0.009%,pH 7.4缓冲阶段的平均含量为86.4155%。可以得出,样品中酮洛芬溶出度试验的测定符合要求(MS),按照PT Novell制药实验室内部标准的规定,即在酸阶段,酮洛芬在2小时内溶出量不超过10%,在pH 7.4缓冲阶段,酮洛芬溶出量要求为75%。酮洛芬在45分钟内就溶解了。在酸性介质的溶解中,使用0.1盐酸,因为它的情况类似于胃的情况。
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引用次数: 0
PEMBUATAN PENYERAP GAS BUANG KENDARAAN BERMOTOR BERBASIS LIMBAH PADAT KELAPA SAWIT 生产一种以棕榈油固体废物为基础的机动车废气捕获物
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3904
Abdillah Abdillah, Gimelliya Saragih, Muhammad Zaim Akbari, Vivi Purwandari
Polusi udara merupakan masalah yang dihadapi di masa sekarang, kendaraan bermotor menyumbang 70% Polusi udara yang ada di Indonesia. Membran Keramik sebagai penyerap emisi karbon dengan nanokarbon sebagai filler digunakan untuk menyerap gas buang yang dihasilkan oleh kendaraan bermotor. Penelitian ini bertujuan untuk membantu pemerintah dalam mengatasi polusi udara dengan memanfaatkan limbah padat kelapa sawit. Tanah liat sebagai matriks di aktivasi menggunakan KOH, serbuk pelepah sawit sebagai pembentuk pori dan menggunakan nanokarbon sebagai filler yang berasal dari cangkang sawit yang dibuat melalui metode hidrotermal dengan 180oC selama 6 jam dengan pelarut air dengan perbandingan 80:15:5. Campuran di hotpress dengan suhu 120oC dilanjutkan dengan proses furnance dengan suhu 600oC selama 1 jam. menghasilkan kekuatan tarik sebesar 6.475 Mpa. Hasil analisa FTIR membran keramik berpori menunjukan adanya gugus fungsi bahan baku pembentuk membran keramik dan dari hasil analisa DSC membran keramik menunjukan bahwa kemampuan termal penggunaan membran keramik dapat digunakan dibawah temperatur 470oC. Hasil uji data filtrasi (emisi gas buang) pada keramik berpori yang dihasilkan dapat di lihat CO terserap 3,20%, CO2 terserap 5.6% dan HC terserap 418 ppm.
空气污染是当今面临的一个问题,汽车占印尼空气污染的70%。陶瓷膜作为碳排放和纳米碳作为过滤器被用来吸收机动车产生的废气。本研究旨在通过利用茂密的棕榈油废物,帮助政府解决空气污染问题。粘土作为激活矩阵,使用KOH,棕榈油凝血粉作为孔隙,使用纳米碳作为过滤器,从棕榈油壳中提取,通过热液方法用180oC和水溶剂进行6小时的比较,使用80:5。混合热压,温度为120oC,然后加热过程为600摄氏度,温度为1小时。引起6475 Mpa的吸引力。孔隙膜FTIR分析表明,陶制膜的原料组和DSC膜分析表明,使用陶瓷膜的热性能可以在470摄氏度下使用。由此产生的陶瓷孔过滤数据测试结果可以看到CO吸收3.20%,二氧化碳吸收5.6%和HC吸收418 ppm。
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引用次数: 0
MECHANICAL PROPERTIES OF CELLULOSE-BASED EXTRACTED FROM NATA DE COCO 从椰子树中提取纤维素的机械性能
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3884
Sherlyna Pertiwi, Malemta Tarigan, M. Harahap, Adiansyah
Paper production is currently important for various community needs due to the use in daily life. The aim of this study is to produce paper cellulose-based extracted from Nata de Coco with the addition of polyvinyl alcohol (PVA) as an adhesive. The paper was produced by using pulp method followed by ultrasonication with variation of ultrasonication from 10 min, 20 min, to 30 min. The sample was characterized in terms of functional groups and mechanical properties. The results showed that the longer the ultrasonication time, the lower the mechanical value. The highest tensile test was obtained at 10 min of ultrasonication with the value of 5.036 MPa.
由于日常生活中的使用,纸张生产目前对各种社区需求非常重要。本研究的目的是用聚乙烯醇(PVA)作为粘合剂,从椰子树中提取纸纤维素。采用纸浆法制备纸,超声处理10 min、20 min、30 min,对样品的官能团和力学性能进行表征。结果表明,超声时间越长,其力学值越低。超声作用10 min时拉伸试验值最高,为5.036 MPa。
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引用次数: 1
PENENTUAN KADAR RESIDU PESTISIDA PROFENOFOS PADA TANAMAN TOMAT GAFHA DENGAN METODE GAS CHROMATOGRAPHY 用色素法测定GAFHA西红柿的原酚农药残留水平
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3869
Renny Futeri
Research on determination of Profenofos Pesticide Residue Levels on Agafha Tomatoes Using Gas Chromatography Method has been carried out. The purpose of conducting research on samples of tomatoes that are often consumed by the community is to find out whether the tomato plants are suitable for consumption by the community or whether they have a negative impact if consumed frequently and to find out whether the tomato samples reach the maximum residue limit that has been set. After analyzing the Agaftha tomato samples in the pesticide laboratory, data was obtained that the Agaftha tomatoes contained prefenofos pesticide residues with a concentration of 0.0805 mg/kg, and the results of this test stated that the Agaftha tomato samples could be consumed properly because the concentration did not exceed the maximum residue limit. Prefenofos residue is regulated in the Regulation of the Minister of Agriculture of the Republic of Indonesia Number 55/PERMENTAN/KR.040/11/2015. The maximum residue limit (BMR) for the active ingredient profenofos is 10 mg/Kg. Hence, it can be concluded that the Agaftha tomato sample is suitable for consumption because the concentration of residue levels in the Agaftha tomato sample is lower than the BMR which has been regulated in the Regulation of the Minister of Agriculture of the Republic of Indonesia.
研究了气相色谱法测定阿加法番茄中丙诺福农药残留量的方法。对市民经常食用的番茄样本进行研究的目的,是要了解这些番茄是否适合市民食用,或经常食用会否对市民产生负面影响,以及番茄样本是否达到规定的最高残留限量。经农药实验室对Agaftha番茄样品进行分析,数据显示Agaftha番茄中农药残留浓度为0.0805 mg/kg,本次检测结果表明Agaftha番茄样品未超过最大残留限量,可正常食用。印度尼西亚共和国农业部长法规第55/PERMENTAN/KR.040/11/2015号规定了对苯甲胺磷残留的监管。活性成分丙酚的最大残留限量(BMR)为10 mg/Kg。因此,可以得出结论,Agaftha番茄样品适合消费,因为Agaftha番茄样品中的残留浓度水平低于印度尼西亚共和国农业部长条例规定的BMR。
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引用次数: 0
PENENTUAN JENIS MEDIA TERHADAP EFEKTIVITAS PERTUMBUHAN JAMUR TRICHODERMA HARZIANUM 确定一种介质对哈兹亚南菌生长有效性的影响
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3909
Pevi Riani, Renny Futeri
This study aims to determine a suitable medium for the growth Trichoderma harzianum. The treatments tested were rice media (M1), bran media (M2), corn media (M3), potato media (M4), and rice husk mixed media (M5). The parameters observed in this study were the quality test of conidia density using a microscope and haemacytometer, macroscopic observation of the media for 7 days and microscopic observation of the media to evaluate the media that had the best effectiveness as a medium for propagation of Trichoderma harzianum. The initial isolate of Trichoderma harzianum used had a conidia density of 2,9x109conidia/ml. The results showed that the propagation of Trichoderma harzianum in various media affected the macroscopic, microscopic and conidia density changes of Trichoderma harzianum. Trichoderma harzianum can grow on all treatment media. The bran media is the medium with the highest conidia density compared to other media.
本研究旨在确定适宜哈茨木霉生长的培养基。试验处理为水稻培养基(M1)、麸皮培养基(M2)、玉米培养基(M3)、马铃薯培养基(M4)和稻壳混合培养基(M5)。本研究观察的参数为显微镜和血细胞计对分生孢子密度进行质量检测,对培养基进行宏观观察7天,对培养基进行微观观察,评价最适合哈茨木霉繁殖的培养基。最初使用的哈茨木霉分离物的分生孢子密度为2.9 x109个/ml。结果表明,哈茨木霉在不同培养基中的繁殖对哈茨木霉的宏观、微观及分生孢子密度变化均有影响。哈茨木霉可以在所有处理培养基上生长。与其他培养基相比,麸皮培养基是分生孢子密度最高的培养基。
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引用次数: 0
IDENTIFIKASI ANALISIS KADAR KARBOHIDRAT DAN KADAR GULA REDUKSI METODE LUFF SCHOORL DARI HIDROLISIS SELULOSA LIMBAH MENGKUDU (Morinda citrifolia L.) 分析碳水化合物和糖还原法的姜黄水溶方法(Morinda citrifolia)。
Pub Date : 2023-06-14 DOI: 10.51544/kimia.v7i1.3942
N. Sari
Dalam penentuan uji kadar karbohidrat , pada sampel limbah buah mengkudu dilakukan analisis, yaitu analisis secara kuantitatif dan kualitatif. Uji analisis yang sudah dilakukan dalam analisis hidrolisis selulosa limbah buah mengkudu secara kualitatif yaitu menggunakan uji benedict sehingga menghasilkan endapan merah bata dan secara kuantitatif menggunakan metode Nelson-Somogyi  menghasilkan kadar gula reduksi sebsar 11.87%. Secara berkelanjutan dilakukan uji penentuan kadar karbohidrat dari hasil hidrolisis  yaitu analisis karbohidrat total dan analisis  gula reduksi  dengan  metode Luff Schoorl.  Akhir penelitian yang sudah dilakukan dari hidrolisis selulosa limbah buah mengkudu, menunjukkan bahwa hasil rata-rata total kadar karbohidrat  yaitu 51. 83% dan hasil gula reduksi rata-rata menurut metode Luff Schoorl adalah 16.52%. Karbohidrat berperan sebagai pemberi rasa manis, penentuan kadar karbohidrat dilakukan dengan mengukur jumlah gula reduksi yang dikandungnya. Rasa manis ini dikarenakan adanya gula reduksi.
在确定碳水化合物水平的过程中,对水果废水样本进行了定量和定性分析。用本尼迪克特试验产生红砖沉积物,用氧化脱氧核糖核酸(Nelson-Somogyi)的定量方法进行分析,以定性的方式进行分析。通过Luff Schoorl方法,持续测试水溶结果、全碳水化合物分析和糖还原分析的碳水化合物水平。一项从水果的纤维素水解系统中得出的研究表明,平均含水率为51。根据Luff Schoorl法,平均转导糖产量为16.52%。碳水化合物起甜味的作用,通过测量它们的含糖量来确定碳水化合物的含量。这种甜味是由于低糖的作用。
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JURNAL KIMIA SAINTEK DAN PENDIDIKAN
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