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PENGOLAHAN LIMBAH KULIT KAKAO DAN KEMIRI PADA PEMBUATAN BIOPELET SEBAGAI BAHAN BAKAR ALTERNATIF 可可生树皮废物处理厂和炼生生物丸为替代燃料
Pub Date : 2022-12-20 DOI: 10.51544/kimia.v6i2.3492
Vivi Purwandari, M. Harahap, L. Zai, Muhammad Arya Mubarakh
The amount of fuel reserves were getting depleted and has created problems with the occurrence of a fuel crisis, which has resulted in higher prices and the economy of the community has been down. Biomass is a renewable alternative fuel source but still has weaknesses, like high water content, low calorific value and low density and the combustion process requires high temperatures. To overcome this problem, biomass can be processed into biopellets with the aim of increasing its density and increasing the quality of combustion. The research was about the processing of cocoa and candlenut shell waste as an alternative fuel in the manufacture of biopellets using tapioca adhesive. The stages of this research include the preparation of raw materials for cocoa shells and candlenut shells ground to a size of 60 mesh and then added with various adhesives of 5%, 10% and 15%, then printed manually and dried in an oven with a temperature of 60oC for ±3 hours. Furthermore, the biopellets were characterized based on the provisions of SNI 8021:2014 which included density, moisture content, ash content, volatile matter, fixed carbon, calorific value with the most optimum values, respectively, 1.02 g/cm3, 3.14%, 6 ,25%, 64.56%, 26.05% and 4145.6 cal/g. Biopellets were also tested for effectiveness such as fracture strength and combustion rates with values of 0.14% and 0.11 g/min, respectively. Biopellet with the best quality was found in the type of biopellet with a mixture of raw materials 2:1 and using 10% tapioca adhesive.
燃料储备的数量正在耗尽,造成了燃料危机的问题,导致价格上涨,社区的经济一直在下降。生物质是一种可再生的替代燃料,但仍存在含水量高、热值低、密度低、燃烧过程需要高温等缺点。为了克服这个问题,生物质可以加工成生物电池,目的是增加其密度和提高燃烧质量。这项研究是关于可可豆和核桃壳废料的加工,作为使用木薯胶制造生物细胞的替代燃料。本研究的阶段包括可可豆壳和烛壳的原料制备,磨成60目大小,然后加入5%,10%和15%的各种粘合剂,然后手工打印,在60℃的烤箱中干燥±3小时。根据SNI 8021:2014的规定,对生物电池的密度、含水量、灰分、挥发物、固定碳和热值进行了表征,其中最优值分别为1.02 g/cm3、3.14%、6、25%、64.56%、26.05%和4145.6 cal/g。此外,还测试了生物电池的有效性,如断裂强度和燃烧速率,分别为0.14%和0.11 g/min。以2:1的原料配比和10%的木薯淀粉胶粘剂制备的生物颗粒质量最好。
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引用次数: 0
MODIFIKASI JERAMI PADI/BATANG PISANG/PP/PP-g-MAH APLIKASI PAPAN PARTIKEL (PARTICLE BOARD)
Pub Date : 2022-12-20 DOI: 10.51544/kimia.v6i2.3729
Adiansyah, Salomo Sijabat, Hotromasari Dabukke, Putri Aulia
Telah dilakukan penelitian optimasi pencampuran jerami padi/batang pisang/Polipropilena/polipropilena-grafthing-maleat anhidrat aplikasi papan partikel (particle board) dalam pencampuran tersebut menggunakan PP-g-Mah sebagai bahan perekat dari hasil yang diperoleh ditemukan permukaan yang lebih homogen pada variasi yang optimum (70:40:10:30) dengan berbagai variasi konsentrasi. Permukaan yang lebih homogen memberikan gambaran hasil yang lebih baik dan berbanding lurus dengan peningkatan sifat mekanik yang diperoleh hasil tersebut juga dapat dilihat pada munculnya puncak (C-H bending)  pada panjang gelombang (1453,7 cm).
研究了麦麸/香蕉棒/聚丙烯/聚丙烯-石墨试剂/聚丙烯-石墨试剂更均匀的表面呈现出更直接、更直接的结果,其结果的机械性能的增加也可以在波长(1453.7厘米)的峰值(C-H弯曲)出现时看到。
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引用次数: 0
MAKANAN TAMBAHAN IBU HAMIL UNTUK MENCEGAH STUNTING DALAM UPAYA MENINGKATKAN KUALITAS SDM BAGI PERTAHANAN NEGARA 孕妇额外的食物,以防止发育迟缓,以提高国家国防资源的质量
Pub Date : 2022-12-20 DOI: 10.51544/kimia.v6i2.3494
Arfiyanti, Dita Ariyanti
Anak dengan stunting memiliki kemampuan verbal dan IQ rendah, disabilitas kognitif, penurunan kemampuan motorik dan gangguan fungsi imunitas. Perlu pemberian makanan tambahan (PMT) sebagai pendamping program suplementasi pemerintah pada ibu hamil untuk meningkatkan status gizi ibu hamil dan mencegah stunting dalam upaya meningkatkan kualitas SDM bagi pertahanan negara.  Mendapatkan formulasi fortifikasi cookies yang sesuai kebutuhan ibu hamil untuk mencegah stunting. Formulasi cookies berawal dari  pembuatan tepung (tempe, kacang hijau, ikan tuna, pisang), dilanjutkan dengan formulasi tepung  komposit. Rancangan metode optimasi tepung komposit RSM mixture design D-optimal, menggunakan software Design Expert 7.0 trial (DX 7 trial). Kandungan zat gizi bahan pangan yang digunakan lalu dibandingkan dengan jumlah zat gizi yang ingin ditambahkan. Formula tepung komposit dipilih berdasarkan kandungan gizi dan rasa. Substitusi tepung beras dengan tepung komposit terpilih pada resep  standar. Cookies berbentuk bulat, aroma, rasa, warna, kenampakan sesuai SNI01-2891-1992, BUTIR1.2. Kandungan protein, energi, vitamin A, B12, calsium, pospor, iodium, asam folat memenuhi AKG ibu hamil trimester II dan persyaratan BPOM. 70% ibu hamil trimester II menyukai cookies. Cookies ikan tuna dapat digunakan sebagai PMT ibu hamil pendamping program suplementasi pemerintah untuk mencegah stunting 180 HPK.
发育不良的儿童有语言能力和智商低,认知功能障碍,运动能力下降和免疫功能障碍。需要额外的食物(PMT)作为政府孕妇补充计划的支持,以提高孕妇的营养状况,防止发育迟缓,以提高国家国防的资源质量。获得适合准妈妈服用的多糖配方,以防止晕眩。这些饼干的配方始于面粉(tempe,青豆,金枪鱼,香蕉),然后是复合面粉配方。采用设计设计的RSM混合d -最佳设计方法,采用设计专家7.0试用软件(DX 7试用)。所使用的食品营养成分的含量,然后与所补充的营养物质的数量进行比较。基于营养和风味的复合面粉配方进行选择。标准食谱中选择的混合面粉替换米粉。它是圆的,气味,味道,颜色,配上SNI01-2891-1992年的不毛。蛋白质、能量、维生素A、B12、钙离子、磷、碘、叶酸与妊娠妊娠g和BPOM需求相匹配。怀孕70%的孕妇喜欢饼干。金枪鱼饼干可作为PMT准妈妈辅助政府补充计划,以防止180 HPK的特技表演。
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引用次数: 0
PRODUCTION OF CELLULOSE ACETATE MEMBRANE FROM COCOA (THEOBROMA CACAO L) SHELL MODIFIED POLYETHYLENE GLICOL FOR PB METAL ION FILTRATION 以可可壳改性聚二甘醇为原料制备醋酸纤维素膜,用于铅金属离子过滤
Pub Date : 2022-12-20 DOI: 10.51544/kimia.v6i2.3521
Pevi Riani, Syafrinal, Muhammad Ikhlas Armin
In this study, a modified polyethylene glycol modified cellulose acetate membrane was made. Cellulose acetate was synthesized from cocoa husk waste (Theobroma cacao L) with several steps, namely isolation of alpha cellulose from cocoa husk waste, synthesis of cellulose acetate from alpha cellulose, preparation of 10% cellulose acetate membrane with the addition of polyethylene glycol 0, 5, 10, 15, 20 & 25% . From the results of the research, it was found that the FT-IR analysis of -cellulose from cocoa shells showed an absorption peak at wave numbers between 3400 – 3500 cm-1 which indicated the presence of O-H stretch groups. At wave numbers 2800-2900 cm-1 indicates C-H stretching, then it can be seen at wave numbers 1160 cm-1 indicates C-O-C stretching, and at 1035-1060 cm-1 indicates C-O stretching. In the fingerprint area, we found absorption peaks at wave numbers around 1300 cm-1 which indicated the presence of C-H bending and around 1400 cm-1 indicating the presence of CH2 bending. The cellulose acetate obtained is white and smooth compared to alpha cellulose. At the membrane preparation stage, the results of the insoluble cellulose acetate & PEG using acetone as a solvent. So it is necessary to do a solubility test and find a suitable solvent to form polyethylene glycol modified cellulose acetate membrane for Pb metal ion filtration.
本研究制备了一种改性聚乙二醇改性醋酸纤维素膜。以可可壳渣(Theobroma cacao L)为原料,通过从可可壳渣中分离α -纤维素、α -纤维素合成乙酸纤维素、添加0、5、10、15、20、25%聚乙二醇制备10%醋酸纤维素膜等步骤合成乙酸纤维素。从研究结果中发现,对可可壳-纤维素进行FT-IR分析,发现在3400 ~ 3500 cm-1的波数处有一个吸收峰,表明存在O-H拉伸基团。在波数2800 ~ 2900 cm-1处为C-H拉伸,在波数1160 cm-1处为C-O- c拉伸,在波数1035 ~ 1060 cm-1处为C-O拉伸。在指纹区,我们发现1300 cm-1左右的吸收峰表明存在碳氢弯曲,1400 cm-1左右的吸收峰表明存在CH2弯曲。与α纤维素相比,得到的醋酸纤维素是白色和光滑的。在膜制备阶段,以丙酮为溶剂对不溶性醋酸纤维素和聚乙二醇的结果进行了研究。因此有必要进行溶解度试验,寻找合适的溶剂形成聚乙二醇改性醋酸纤维素膜过滤铅金属离子。
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引用次数: 0
PENGGUNAAN PESTISIDA DAN KADAR CHOLINESTRASE PADA PETANI PENYEMPROT 喷洒农药和CHOLINESTRASE水平
Pub Date : 2022-12-20 DOI: 10.51544/kimia.v6i2.3515
Vierto Irennius Girsang, Apriani Novaria Barus, Johansen Hutajulu, L. Siregar
Using pesticides can decrease the population of organisms in plants. A pesticide which the work of cholinesterase enzyme in the body is oregano phosphate; it also has a side effect on the decrease in cholinesterase content. The research used a cross-sectional design which was aimed to find out the influence of using pesticides on the decrease in blood cholinesterase content in farmers who spray their plants with pesticides at Desa Cikaok, Kecamatan Sitellu Talli Urang Julu, Kabupaten Pakpak Bharat. The samples were farmers who sprayed their plants with pesticides. Chi Square statistic test was used to find out the variables which probably decrease in cholinesterase content at p,0,05. It was found that 26,7% of the respondents underwent a normal decrease in cholinesterase content, and 73,3% of the respondents underwent an abnormal decrease. Statistically, there was a significant correlation between the length of spraying pesticides with the decrease in cholinesterase content in the blood of farmers who sprayed their plants with pesticides at Desa Cikaok at p-value = 0,678. It is recommended that the farmers lessen the duration of spraying in order to reduce the risk of exposure to pesticides and use personal protective devices such as gloves, hats masks, glasses, uniforms, and shoes. The regional government should provide protection, counseling, and training about the procedure of using pesticides in order to forestall the incidence of illness in the farmers who sprayed their plants with pesticides.
使用杀虫剂可以减少植物中生物的数量。一种体内胆碱酯酶作用为牛至磷酸盐的农药;对胆碱酯酶含量的降低也有副作用。本研究采用横断设计,目的是找出使用农药对在Desa Cikaok、Kecamatan Sitellu Talli Urang Julu、Kabupaten Pakpak Bharat喷洒农药的农民血液胆碱酯酶含量降低的影响。这些样本是给他们的植物喷洒杀虫剂的农民。采用x方统计检验找出可能降低胆碱酯酶含量的变量,p < 0.05。结果发现,26.7%的应答者胆碱酯酶含量正常下降,73.3%的应答者胆碱酯酶含量异常下降。在统计上,施药时间的长短与施药农民血液中胆碱酯酶含量的下降有显著的相关性,p值= 0.678。建议农民缩短喷洒时间,以减少接触农药的风险,并使用个人防护设备,如手套、帽子、口罩、眼镜、制服和鞋子。地方政府应该提供保护、咨询和关于使用杀虫剂程序的培训,以防止给他们的植物喷洒杀虫剂的农民生病。
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引用次数: 0
EKSTRAKSI UNSUR FERRUM DARI LIMBAH PADAT PABRIK PULP DAN KERTAS 从纸浆厂的高密度废弃物中提取FERRUM的元素
Pub Date : 2022-07-24 DOI: 10.51544/kimia.v6i1.3012
Maria Peratenta Sembiring, Desi Heltina, Chairul Chairul, Zulfansyah Zulfansyah
Functioning industrial waste as raw material or as a product is an achievement that will continue to be optimized, especially in industries where the amount of waste is significant. Pulp and paper mills produce  waste in the form of solid, sludge, liquid and gas. The objective of this research is to extract the element ferrum contained in one of the solid wastes in pulp and paper mills. By using two fatty amine extractor, lauryl amine and stearyl amine with ethanol and n-hexane as solvents. The results showed that the use of stearyl amine as an extractor and n-hexane as a solvent with operating conditions of 4 hours and a dose of 5 grams gave the best results with an extraction yield of 10,964 mg/kg.
将工业废物作为原材料或产品使用是一项将继续优化的成就,特别是在废物量很大的工业中。纸浆和造纸厂以固体、污泥、液体和气体的形式产生废物。本研究的目的是提取纸浆和造纸厂的一种固体废物中所含的铁元素。采用十二烷基胺和硬脂酰胺两种脂肪胺萃取剂,以乙醇和正己烷为溶剂。结果表明,以硬脂酰胺为萃取剂,正己烷为溶剂,操作时间为4小时,萃取量为5 g,萃取效果最佳,萃取率为10964 mg/kg。
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引用次数: 0
PRODUKSI DAN KARAKTERISASI NANOSERAT SELULOSA ASETAT DENGAN METODE ELEKTROSPINING 醋酸盐纳米纤维素的生产和分类方法与电旋法
Pub Date : 2022-07-24 DOI: 10.51544/kimia.v6i1.2978
M. Harahap, L. Zai
In this research, cellulose acetate fiber was produced by electrospinning method. Cellulose acetate was dissolved with acetone solvent and then putin to a cooling system torestrain the rate of evaporation of cellulose acetate. The conductivity and evaporation rate of the cellulose acetate solution were tested, and the cellulose acetate fiber sproduced were tested using scanning electron microscopy (SEM). The conductivity of the cellulose acetate solutionwas 3.45 S/cm at 15oC and almost doubled at 22oC. The cooling system test was ableto maintain the temperature of the cellulose acetate solution at 15 oC for approximately 2 minutes. In addition, bead fibers are produced due to their low conductivity.
本研究采用静电纺丝法制备醋酸纤维素纤维。用丙酮溶剂溶解醋酸纤维素,然后放入冷却系统以抑制醋酸纤维素的蒸发速率。测试了醋酸纤维素溶液的电导率和蒸发速率,并用扫描电镜(SEM)对制备的醋酸纤维素纤维进行了测试。醋酸纤维素溶液的电导率在15℃时为3.45 S/cm,在22℃时几乎翻倍。冷却系统测试能够将醋酸纤维素溶液的温度保持在15℃约2分钟。此外,珠状纤维由于其低导电性而产生。
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引用次数: 0
PENGARUH KADAR SILIKA DARI FLY ASH BATU BARA SEBAGAI BAHAN PENGISI HIDROGEL BERBAHAN DASAR SELULOSA BAKTERI (HSB)
Pub Date : 2022-07-24 DOI: 10.51544/kimia.v6i1.2975
Indra Surya, Vivi Purwandari, Ani Khodijah
In one coal combustion process, about 80% of fly ash is produced and the rest is bottom ash, which is around 20%. The main components of coal fly ash originating from power plants are silica (SiO2), alumina (Al2O3), and iron oxide (Fe2O3), the rest are carbon, calcium, magnesium, and sulfur. Silica is one of the most dominant components of fly ash. Hydrogels obtained without fillers still have a Swelling capacity that is not maximized, it is necessary to process hydrogels with high absorption capabilities. One of the methods used to increase the absorption of hydrogels is to add silica as a voice filler. This study aims to determine the effect of 10, 20, 30, and 40% silica content from coal fly ash as a filler for bacterial cellulose-based hydrogels. Silica was obtained by extracting sodium silicate solution from fly ash followed by the manufacture of silica gel using 3N H2SO4. The resulting silica gel is added to the hydrogel manufacturing process. Hydrogel with silica as a filler which produces water absorption, FTIR, and SEM. The test results show that the silica content of 20% has the highest water absorption capacity of 1290%. With the concentration used, silica precipitation will produce a sharper silica peak in the FTIR results. SEM analysis with the addition of silica with bacterial cellulose produces pores on the HSB surface which can absorb air more quickly. The pores on the surface of the HSB affect the water absorption capacity (hydrophilicity) to increase. The addition of silica precipitated from fly ash waste as a filler in Bacterial Cellulose Hydrogel (HSB) was able to increase the Swelling capacity of HSB
在一次煤燃烧过程中,产生的飞灰约占80%,其余为底灰,约占20%。电厂煤飞灰的主要成分是二氧化硅(SiO2)、氧化铝(Al2O3)和氧化铁(Fe2O3),其余为碳、钙、镁和硫。二氧化硅是粉煤灰的主要成分之一。没有填料得到的水凝胶仍然有膨胀能力,没有最大化,有必要加工具有高吸收能力的水凝胶。增加水凝胶吸收量的方法之一是加入二氧化硅作为声音填充物。本研究旨在确定10%、20%、30%和40%粉煤灰二氧化硅含量作为细菌纤维素基水凝胶填料的效果。从粉煤灰中提取水玻璃溶液得到二氧化硅,然后用3N H2SO4制备硅胶。所得到的硅胶被添加到水凝胶制造过程中。水凝胶与二氧化硅作为填料,产生吸水,FTIR和SEM。试验结果表明,二氧化硅含量为20%时,吸水性最高可达1290%。随着浓度的增加,二氧化硅沉淀将在FTIR结果中产生一个更尖锐的二氧化硅峰。SEM分析表明,在细菌纤维素中加入二氧化硅会在HSB表面产生气孔,从而更快地吸收空气。HSB表面的孔隙影响其吸水能力(亲水性)的增加。在细菌纤维素水凝胶(HSB)中加入粉煤灰沉淀二氧化硅作为填料,可以提高HSB的溶胀能力
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引用次数: 0
IDENTIFIKASI AMPHETAMINE, METHAMPETAMINE DALAM URINE SISWA SMA “X” METODE STRIP STICK 在高中生的尿液中发现安非他命,甲烷佩他命X带条方法
Pub Date : 2022-07-24 DOI: 10.51544/kimia.v6i1.2973
Dyna Grace Romatua Aruan, M. Siahaan
Amphetamines called alpha-methyl-phenethylamine, beta-phenyl-isopropylamine, or benzedrine are a class of simulants used to treat hyperactivity disorder due to inattention in adults and children. Methamphetamine is a drug that belongs to the amphetamine class. It works the same way as amphetamine can increase alertness, concentration, and when taken at high doses can cause euphoria. In general, marijuana is used through cigarettes, including the hallucinogenic drug group and class 1 drugs. The harmful impact of drugs on adolescents and especially for students is that drug use can cause negative effects that will cause mental and behavioral disturbances in a person, resulting in disruption of the neuro-transmitter system in the brain. nerves in the brain. Amphetamine and methampetamine levels were lowest in stems, roots and seeds, while the highest levels were found in flowers, sap and leaves. The type of research carried out is a qualitative analysis with the method of examining samples using ICT (Imunochromatography Test) with amphetamine and methamphetamine strips/sticks. The population in this study were 15 students of class XI SMA "X". The research conducted, took all the urine of class XI students. The urine collection process was carried out at the "X" School and then examined directly at the Science Laboratory in March 2022. The results of the overall urine sample examination were negative for amphetamine and methampetamine.
安非他命被称为-甲基-苯乙胺、-苯基-异丙胺或苯丙胺,是一类用于治疗成人和儿童因注意力不集中而引起的多动障碍的模拟药物。甲基苯丙胺是一种属于安非他明类的药物。它的作用方式和安非他明一样,可以提高警觉性和注意力,当服用大剂量时可以引起欣快感。一般来说,大麻是通过香烟使用的,包括致幻药物和1类药物。毒品对青少年的有害影响,特别是对学生的有害影响是,吸毒会造成负面影响,导致一个人的精神和行为紊乱,导致大脑中神经递质系统的破坏。大脑中的神经。安非他明和甲基苯丙胺含量在茎、根和种子中最低,而在花、树液和叶子中含量最高。所进行的研究类型是定性分析,使用免疫层析试验(ICT)用安非他明和甲基苯丙胺条/棒检查样品的方法。在进行这项研究时,采集了十一班所有学生的尿液。尿液收集过程在“X”学校进行,然后在2022年3月直接在科学实验室进行检查。整体尿样检查结果为安非他命和甲基苯丙胺阴性。
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引用次数: 1
PENERAPAN LKS BERBASIS CTL PADA PERUBAHAN MATERI UNTUK MENINGKATKAN MOTIVASI BELAJAR SISWA PAKET B DI MASA COVID – 19 PADA SPNF KOTA BANDA ACEH 基于CTL的LKS应用于物质变化,以提高学生B包的学习动力在svid - 19班达亚齐市
Pub Date : 2022-07-24 DOI: 10.51544/kimia.v6i1.2976
Aulia Prasetia, Sri Ismulyati, Rizki Damayanti
A research has been carried out with the theme "Implementation of CTL-Based Worksheets on Material Changes to Increase Student Learning Motivation in Package B during the Covid-19 Period at SPNF Banda Aceh City". This study aims to determine the effectiveness of the application of Contextual Teaching and Learning (CTL)-based LKS on material changes used in SPNF SKB Banda Aceh and to determine student responses to the application of Contextual Teaching And Learning (CTL)-based LKS on material changes in SPNF SKB. Banda Aceh City. The benefits of this research are for students, the LKS Module can be used as a learning resource, so that it can increase interest in learning chemistry, and can relate the material to the surrounding environment; For teachers, the LKS Module can be used as teaching materials to assist teachers in creating interesting and interactive learning situations; For schools, this research is expected to contribute to improving the conditions of chemistry learning so that it can create a better quality of education in the future. In this research, the method of observation, test (pre-test and post-test) and questionnaire. The results of this study indicate a positive response as evidenced by the data generated.
在班达亚齐市SPNF开展了一项主题为“在2019冠状病毒病期间实施基于ctl的材料变化工作表,以提高B包学生的学习动机”的研究。本研究旨在确定基于情境教学(CTL)的LKS在班达亚齐SPNF SKB中材料变化应用的有效性,并确定学生对基于情境教学(CTL)的LKS在SPNF SKB中材料变化应用的反应。班达亚齐市。这项研究的好处是,对于学生来说,LKS模块可以作为一种学习资源,这样可以增加学习化学的兴趣,并且可以将材料与周围环境联系起来;对于教师来说,LKS模块可以作为教材,帮助教师创造有趣和互动的学习情境;对于学校而言,本研究可望有助于改善化学学习的条件,从而在未来创造更优质的教育。本研究采用观察法、测试法(前测法和后测法)和问卷调查法。本研究的结果表明,正如所产生的数据所证明的那样,这是一个积极的反应。
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引用次数: 0
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JURNAL KIMIA SAINTEK DAN PENDIDIKAN
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