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Revealing the Sodium Storage Behavior of Biomass-Derived Hard Carbon by Using Pure Lignin and Cellulose as Model Precursors 以纯木质素和纤维素为模型前体揭示生物质衍生硬碳的钠储存行为
Pub Date : 2022-03-01 DOI: 10.2139/ssrn.3885509
Xi-Shuo Wu, Xiao-Ling Dong, Bohao Wang, Jiabing Xia, Wen‐Cui Li
Lignin and cellulose are dominant components in biomass and hold the key for preparing hard carbons. Identifying the sodium storage behaviors of sole lignin/ cellulose-derived hard carbons is significant for choosing optimal biomass precursors. Herein, milled-wood lignin and microcrystalline cellulose are used as model precursors to prepare hard carbons and the corresponding sodium storage performances are investigated to understand the contribution of each biomass component. Compared with lignin-derived carbon, cellulose-derived carbon enables a larger initial coulombic efficiency of 87.1 %, a higher reversible capacity of 343.3 mA h g-1 at 0.02 A g-1 and a good rate capability of 49.2 mA h g-1 at 1 A g-1. That’s attributed to large La, IG/ID values and high sp2C, C=O contents, which enhance the conductivity, plateau capacity, and the rapid diffusion of sodium ions. The excellent performance of cellulose-derived carbon provides guidance on the choice of biomass precursors for high-performance sodium-ion battery.
木质素和纤维素是生物质的主要成分,是制备硬碳的关键。确定单一木质素/纤维素衍生硬碳的钠储存行为对选择最佳生物质前驱体具有重要意义。本文以木质素和微晶纤维素为模型前驱体制备硬碳,并研究了相应的钠储存性能,以了解每种生物质组分的贡献。与木质素衍生的碳相比,纤维素衍生的碳具有更高的初始库仑效率(87.1%),在0.02 a g-1时具有更高的可逆容量(343.3 mA h g-1),在1 a g-1时具有49.2 mA h g-1的良好速率能力。这是由于大的La, IG/ID值和高的sp2C, C=O含量,提高了电导率,平台容量和钠离子的快速扩散。纤维素衍生碳的优异性能为高性能钠离子电池生物质前驱体的选择提供了指导。
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引用次数: 15
Lithium-Ionic Control of Magnetism Through Spin Capacitance and Conversion 锂离子通过自旋电容和转换控制磁性
Pub Date : 2021-02-18 DOI: 10.2139/ssrn.3788469
Feng-jun Zhang, Zhaohui Li, Q. Xia, Qinghua Zhang, C. Ge, Yanxue Chen, Xiangkun Li, Leqing Zhang, Kai Wang, Hongsen Li, Shandong Li, Y. Long, L. Gu, Shishen Yan, G. Miao, Qiang Li
Magnetoelectric (ME) coupling has gradually developed into one of the core means of advancing ultralow-power memory, logic and sensor technologies. Among various strategies, magneto-ionic control of magnetism based on mechanism such as redox, intercalation/deintercalation, and charge accumulation can be achieved in ion battery or capacitor systems. In this work, we demonstrate a ME effect originating from the spin capacitance, combining the advantages of intercalation batteries and supercapacitors. A giant, fast and reversible modulation on the saturation magnetization of ferromagnetic Fe is achieved by lithium ions motion across the Fe/Li2O interface at no more than 1 V. Furthermore, the magnetic evolution driven by the conversion reaction between FeO and Fe over a larger voltage range demonstrates ferromagnetic ordering of the FeO surface. These findings not only open new perspectives for developing high-performance magneto-ionic devices, but also are crucial to designing spintronic devices composed of iron and oxide multilayer structures.
磁电耦合已逐渐发展成为推进超低功耗存储、逻辑和传感器技术的核心手段之一。在各种策略中,基于氧化还原、嵌入/脱嵌和电荷积累等机制的磁离子控制可以在离子电池或电容器系统中实现。在这项工作中,我们展示了一种源自自旋电容的ME效应,结合了插层电池和超级电容器的优点。通过在Fe/Li2O界面上不超过1v的锂离子运动,实现了铁磁性Fe饱和磁化的巨大、快速和可逆调制。此外,FeO和Fe之间的转换反应在较大电压范围内驱动的磁性演化表明FeO表面具有铁磁性有序。这些发现不仅为开发高性能磁离子器件开辟了新的前景,而且对设计由铁和氧化物多层结构组成的自旋电子器件具有重要意义。
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引用次数: 0
Promoting Renewable Energy: How Fares the Philippines? 推广可再生能源:菲律宾进展如何?
Pub Date : 2020-12-09 DOI: 10.2139/ssrn.3745492
Josef T. Yap, Joyce Marie Lagac
Sustainability is a key component of energy security. To help achieve the global long-term goal of zero-carbon emissions by 2050, the Philippine government has implemented laws, policies, and programs to increase the share of renewable energy (RE). An important example is the feed-in-tariff (FiT) scheme. The share of RE in electricity generation, however, has fallen from 45.4% in 1990 to 21% in 2019, a clear indication that the interventions have not been effective. Main constraints to the expansion of RE are formidable, which include market-based factors, technology inertia, market failure, and political economy issues. Even if policies are designed to overcome these constraints, there has been a delay in the implementation of some of them; but more importantly, many of the interventions do not adhere to the principles underlying sound industrial policy. In particular, policies should abide by the principle of embeddedness, which refers to the coordination between the public sector and private firms that allows the former to be aware of the constraints and opportunities of the latter. To address this problem, policymakers must incorporate said principles and streamline future interventions by anchoring them to three aspects: the moratorium on greenfield coal plants, the study on Competitive Renewable Energy Zones (CREZ), and the serious consideration of incorporating nuclear power in the energy mix. Meanwhile, the COVID-19 pandemic has provided an opportunity to “build back better”. Studies have shown that some “green” fiscal recovery measures have strong multiplier effects and, at the same time, promote sustainability. An example is retrofitting buildings to enhance energy efficiency. The experience of other Southeast Asian countries in designing interventions can be useful but policymakers should acknowledge that one size does not fit all.
可持续性是能源安全的关键组成部分。为了帮助实现到2050年零碳排放的全球长期目标,菲律宾政府实施了法律、政策和计划,以增加可再生能源(RE)的份额。一个重要的例子是上网电价(FiT)计划。然而,可再生能源在发电中的份额从1990年的45.4%下降到2019年的21%,这清楚地表明干预措施并未奏效。制约可再生能源发展的主要因素包括市场因素、技术惯性、市场失灵和政治经济问题。即使制定的政策是为了克服这些限制,其中一些限制的执行也有延误;但更重要的是,许多干预措施并不遵循健全产业政策的基本原则。特别是,政策应遵循嵌入性原则,即公共部门和私营企业之间的协调,使前者能够意识到后者的限制和机会。为了解决这一问题,政策制定者必须将上述原则纳入其中,并通过将其固定在三个方面来简化未来的干预措施:暂停新建燃煤电厂,研究竞争性可再生能源区(CREZ),以及认真考虑将核电纳入能源结构。同时,新冠肺炎疫情为“更好地重建”提供了契机。研究表明,一些“绿色”财政复苏措施具有很强的乘数效应,同时还能促进可持续性。一个例子是改造建筑物以提高能源效率。其他东南亚国家在设计干预措施方面的经验可能是有用的,但政策制定者应该承认,一种模式并不适用于所有国家。
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引用次数: 3
Development of Energy Harvesting With Water Droplet Continuous Flow Over Nanohollow and Nanostalagmite of Taro Leaf Surface 水滴在芋头叶片表面纳米空心和纳米石笋上连续流动的能量收集研究进展
Pub Date : 2020-10-31 DOI: 10.15587/1729-4061.2020.214263
K. M. T. Negara, N. Hamidi, D. Widhiyanuriyawan, I. Wardana
Electrical energy is generated by harvesting the induced charge in metal electrodes and by connecting the surface of the taro leaf , coated with the electrodes underneath , to the bridge rectifier and capacitor. This discussion was supported by a Scanning Electron Microscope analysis on the surface of taro leaves. The electrical energy was measured using a bridge rectifier at various water droplet rate in contact with leaf, and at various slope of the taro leaves . The results showed that the slope of the leaf surface contact area with water droplets and taro leaf increase s the generation of electric voltage. The greater the tilt angle of the taro leaf surface causing more electrons to jump out of orbit. The surface of taro leaves made by a cluster of nanostalagmites with other nanostalagmites separated by nano scale hollow s that tend to repel water droplets. The r esults from the repulsion of nanostalagmites at a very small radius of the nanostalagmite structure were v ery high surface tension or surface energy. The electron jump is mainly generated due to the high surface tension energy of the nan o stalagmite structure that when it comes into contact with ionized H + and OH - in the water droplet , it produce s hydrogen (H 2 ). H 2 is trapped in the nanohollows between the nan o stalagmites. Due to the dense morphology of nanostalagmite, H 2 will tend to be pushed upwards to force the water droplet. As a result, the surface tension will be higher and the surface will be more superhydropobic thereby increasing the electrical voltage . T he morphology and the tilt angle have an important role in generating electrical energy. Thus , it is necessary to do further research on superhidrophobic characteristics as a solution in the future to overcome the problem of electrical energy
电能的产生是通过收集金属电极中的感应电荷,并将芋头叶子的表面(下面涂有电极)连接到桥式整流器和电容器。对芋头叶片表面的扫描电镜分析支持了这一讨论。用桥式整流器测量了不同水滴与叶片接触速率和不同叶片坡度下芋头的电能。结果表明:叶片表面水滴与芋头叶片接触面积的坡度增大了电压的产生;芋头叶片表面的倾斜角越大,导致更多的电子跳出轨道。由一簇纳米石笋和其他纳米石笋组成的芋头叶片表面,这些纳米石笋被纳米级的空心分隔开,这些空心可以排斥水滴。在纳米石笋结构的很小半径处,纳米石笋的排斥力产生很高的表面张力或表面能。电子跳变主要是由于石笋结构的高表面张力能,当它与水滴中电离的H +和OH -接触时,产生s氢(h2)。氢被困在石笋和石笋之间的纳米空洞中。由于纳米石笋的致密形态,h2会倾向于被向上推动,以迫使水滴。因此,表面张力会更高,表面会更疏水,从而增加了电压。电极的形态和倾角对产生电能有重要作用。因此,有必要进一步研究超疏水特性,作为未来克服电能问题的解决方案
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引用次数: 0
Influence of Large Molecular Guest Species on the Formation of CH 4 and CO 2 Hydrates 大分子客体物质对甲烷和二氧化碳水合物形成的影响
Pub Date : 2020-10-09 DOI: 10.2139/ssrn.3691244
Asheesh Kumar, Nagu Daraboina, Praveen Linga, R. Kumar
Methane hydrates in nature are considered as a future energy resource for natural gas due to their abundance in nature. The presence of all three structures of clathrate hydrates in the nature have been reported. Structural transition in clathrate hydrates in particular with regards to sH hydrates and the influence of large guest molecules is still not well understood. In the current work, we synthesize mixed hydrate of CO2 & CH4 mixture in presence of sH formers, neo-hexane (NH) and tert-butylmethylether (TBME). High-pressure in-situ differential scanning calorimetry was employed to investigate the phase transformation between soild-liquid-gas. We confirmed that CO2 lean mixture (24% CO2 & 76% CH4) forms structure H (sH) hydrate, while CO2 rich mixture (76% CO2 & 24% CH4) forms structure I (sI) hydrate. This study presents new insights to understand the dynamic preference of methane and carbon dioxide in three different types of cages in sH hydrate.
自然界中的甲烷水合物储量丰富,被认为是天然气的未来能源。这三种结构的笼形水合物在自然界中都有报道。包合物水合物的结构转变,特别是sH水合物和大客分子的影响,仍然没有很好地理解。本研究在sH生成物、新己烷(NH)和叔丁基甲基醚(TBME)存在下,合成了CO2和CH4混合物的混合水合物。采用高压原位差示扫描量热法对固液气相变进行了研究。结果表明,CO2贫混合物(24% CO2 + 76% CH4)形成H (sH)型水合物,而CO2富混合物(76% CO2 + 24% CH4)形成I (sI)型水合物。本研究为了解甲烷和二氧化碳在水合物中三种不同笼型中的动态偏好提供了新的见解。
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引用次数: 0
One-Pot Synthesis of High Density Aviation Fuel with Cyclohexanol 环己醇一锅法合成高密度航空燃料
Pub Date : 2020-09-28 DOI: 10.2139/ssrn.3701196
Dr. Vaishali R. Umrigar, Darshak Panchani, Ajay Maiwala, A. Khandelwal, N. Patel, Jenish Bhanderi
Due to exhaustion of fossil fuels, there is a keen need for the alternative solution to fuel reliance. Globally, jet fuels account for 12% of current used liquid transportation fuels. Production of branched decalins, one of the most advanced jet fuel is in research with high density, low freezing point and high thermal stability. Decalins being most thermally stable component of jet fuels due to the unique bicyclic structure with hydrogen-detonating capability are in demand for synthesis. In the present study, the reaction is carried out in a single reactor using H2SO4 as catalyst with N2 as an inert. The experiment comprises of three steps in single reactor by managing addition and speed of mixing of reactant and catalyst. 1) Oligomerisation in N2 atmosphere 2) Neutralisation with NaOH 3) Separation and drying New and simple routes for branched decalins from cyclic alcohols and cyclic alkanes through alkylation and hydride transfer in a one-pot process have been presented. The reaction mass is analysed by GC and GCMS for quantification of the products. Further operating parameters such as temperature, concentration and feed addition time and stirring speed are studied in detailed.
由于化石燃料的枯竭,迫切需要替代燃料依赖的解决方案。在全球范围内,喷气燃料占目前使用的液体运输燃料的12%。具有高密度、低凝固点、高热稳定性的最先进的航空燃料之一——支链十烷基醇的生产正在研究中。十碳林由于其独特的双环结构,具有爆氢能力,是喷气燃料中热稳定性最好的成分,是目前急需的合成材料。在本研究中,反应是在单反应器中进行的,以H2SO4为催化剂,N2为惰性气体。该实验通过控制反应物和催化剂的加入量和混合速度,在单个反应器中分为三个步骤。1) N2气氛下的低聚化2)NaOH中和3)分离干燥提出了一锅烷基化和氢化物转移从环醇和环烷烃中提取支链癸烯的简单新途径。用气相色谱和气相质谱分析反应质量,定量测定产物。对温度、浓度、加料时间、搅拌速度等操作参数进行了详细的研究。
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引用次数: 1
Thermo-Structural Analysis of Carbon Fibre-Ni Based Super Alloy Composite Employed in Gas Turbines 燃气轮机用碳纤维-镍基超级合金复合材料的热结构分析
Pub Date : 2020-09-07 DOI: 10.2139/ssrn.3696518
Ankit Dhoka
A computational analysis was carried out on two different materials of turbine blades, namely Inconel MA754 and Nimonic 80A, in order to determine their structural and thermal properties at elevated temperatures. Long carbon fibers of uniform length were used and deposited at varying thicknesses ranging from 1 mm to 4 mm, on the top surface of turbine blades and then analyzed for its performance. It is seen that the carbon fibers (IM10) embedded in the super alloys drastically improve the load bearing parameters of the configurations being analyzed. The improvement in structural load carrying ability is a result of higher Young's modulus primarily. Subsequent analysis with higher volume fraction of the fibers indicated saturation of performance at about 70% volume fraction for 4 mm fibers and significant improvement beyond it for the 1 mm fibers. With improvement in the load bearing characteristics the blade with fibers embedded into a tube like structure at 3 sections were configured and A thermal analysis of the same underscores the effectiveness of the 4 mm fibers in undergoing much reduced principal strains than other configurations. This is seen to be a result of insulation of the top surface from increase in temperature, which significantly reduces the thermal expansion, especially at the free end. This is in contrast to other configurations, where the low volume fraction of fibers resulted in high principal strain.
为了确定两种不同材料的涡轮叶片(Inconel MA754和Nimonic 80A)在高温下的结构和热性能,对其进行了计算分析。采用长度均匀的长碳纤维,在涡轮叶片顶表面沉积厚度从1 mm到4 mm不等的碳纤维,并对其性能进行了分析。结果表明,碳纤维(IM10)的加入大大提高了合金结构的承载性能。结构承载能力的提高主要是杨氏模量提高的结果。随后的分析表明,当纤维的体积分数较高时,4mm纤维的性能在70%左右达到饱和,1mm纤维的性能在70%以上有显著提高。随着承载特性的改善,在叶片的3个截面上配置了嵌入纤维的管状结构,热分析强调了4mm纤维的有效性,其承受的主应变比其他配置要小得多。这可以看作是由于顶部表面的绝缘温度升高,这大大减少了热膨胀,特别是在自由端。这与其他配置相反,其中纤维的低体积分数导致高主应变。
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引用次数: 0
A Different Theoretical View on The Modified Black-Body Radiation Setup Using Anisotropic Medium 各向异性介质修正黑体辐射设置的不同理论观点
Pub Date : 2020-09-01 DOI: 10.2139/ssrn.3693284
Jalal Gholinejad
Various points of view help us to have a better cognition. In this article, the main goals is to propose a possible technique for analyzing the sorts of energy based anisotropic crystal in the modified theoretical black-body radiation setup. Here, a structure is introduced to test the energy radiated from black-body, and this may lead to achieve the behavior of negative energy, associated with dark matter.
不同的观点帮助我们有更好的认知。在本文中,主要目的是提出一种在改进的理论黑体辐射设置中分析基于能量的各向异性晶体种类的可能技术。在这里,我们引入了一种结构来测试黑体辐射的能量,这可能会导致实现与暗物质相关的负能量行为。
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引用次数: 0
Design and Implementation of an Intelligent Gas Cylinder Valve Regulating System Using Solenoid 基于电磁阀的智能气瓶阀门调节系统的设计与实现
Pub Date : 2020-08-31 DOI: 10.5121/ijcsea.2020.10402
Ebenezer Narh Odonkor
Developed and developing nations like Ghana frequently experience fire outbreaks which area major problem across the globe. Some causes of such fire outbreaks are due to Leakage gas, electrical fault. Some attendant problems are accidents, loss of life and damage to properties. National fire service stations may be the answer to these conditions in Ghana but few stations are built in some specific places in Ghana. This paper proposed a design and implementation of an intelligent gas stove valve regulating system using Solenoid Valve. Temperature sensor, gas sensor and 555 Timer were used. The proposed system will detect time setting for cooking and cut off gas flow automatically to the stove when food is cooked, gas leakage is detected and when surround temperature is above the threshold. Proteus software is used for designing and simulating of the circuit. Programming was done using the Arduino software. Microcontroller ATMEGA 328 serves as the heart of the design. A Liquid Crystal Display (LCD) is used to show the condition of the stove. In addition, a buzzer is used to sound an alarm when food is cooked. The system has facilities to shut-off gas stove regulator automatically when food is cooked, gas leakage is detected or when a high temperature is detected.
像加纳这样的发达国家和发展中国家经常发生火灾,这是全球的一个主要问题。这类火灾发生的一些原因是由于漏气、电气故障。随之而来的一些问题是事故、生命损失和财产损失。在加纳,国家消防站可能是解决这些问题的答案,但在加纳的一些特定地方,很少有消防站。本文提出了一种基于电磁阀的智能煤气炉阀门调节系统的设计与实现。采用温度传感器、气体传感器和555定时器。该系统将检测烹饪时间设置,并在食物煮熟、检测到气体泄漏以及周围温度高于阈值时自动切断炉膛的燃气流量。采用Proteus软件对电路进行设计和仿真。编程使用Arduino软件完成。微控制器atmega328是设计的核心。液晶显示器(LCD)用于显示炉子的状况。此外,一个蜂鸣器用来在食物煮熟时发出警报。该系统具有在食物煮熟、检测到气体泄漏或检测到高温时自动关闭煤气灶调节器的功能。
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引用次数: 0
An Experimental Analysis of DC Magnetic Blowout High-Speed Circuit Breakers’ Parameters 直流磁爆高速断路器参数的实验分析
Pub Date : 2020-08-31 DOI: 10.15587/1729-4061.2020.210232
A. Rojek
High-speed circuit breakers (HSCB) used in DC circuits are one of the basic elements of overload, short-circuit and electric shock protection. Such breakers are used in transport (trams, trolleybuses, subways and railways) in electric power supply facilities and in vehicles. The performance and capability of limiting the current depend on the HSCB design and solutions applied in it. The circuit parameters, particularly its inductance also affect the performance. Additionally, each DC breaking in the RL circuit is accompanied by overvoltages whose level depends on the circuit parameters and breaker design. The paper discussed the process of direct current breaking by magnetic blowout high-speed circuit breakers and factors that affect the HSCB performance, i. e. opening time and arcing time. The influence of the circuit parameters and HSCB design on the value of arc voltage is outlined. The results of laboratory tests of 4 types of high-speed circuit breakers produced in Europe are presented. The test results were used to analyze the effect of current changes in the short circuit on the time of current breaking and the value of switching overvoltages – arc voltage. The results of simulation of the short-circuit breaking in the RL DC circuit made at the rate-of-rise of current in the circuit are presented. Based on the tests and simulations, the current breaking times, values of arc voltage generated in this process and arc energy that is acquired and dissipated by the arc chamber are determined. The objective of the tests and simulations was to answer the question whether it is possible to turn off direct current quickly without generating high arc voltage values – overvoltages in the circuit and how di/dt changes should be formed by a high-speed circuit breaker to achieve the shortest possible time with the lowest possible arc voltage and its lowest energy
高速断路器(HSCB)是直流电路中过载、短路和触电保护的基本元件之一。这种断路器用于运输(电车、无轨电车、地铁和铁路)、电力供应设施和车辆。限制电流的性能和能力取决于HSCB的设计和所采用的解决方案。电路参数,特别是其电感也会影响其性能。此外,RL电路中的每次直流开断都伴随着过电压,其水平取决于电路参数和断路器设计。本文讨论了磁吹断高速断路器的直流分断过程,以及影响高速断路器性能的因素,即开断时间和起弧时间。概述了电路参数和HSCB设计对电弧电压值的影响。介绍了欧洲生产的4种高速断路器的实验室试验结果。利用试验结果分析了短路时电流变化对电流分断时间和开关过电压-弧电压值的影响。给出了在电流上升速率下RL直流电路短路分断的仿真结果。在试验和仿真的基础上,确定了断电流次数、断电流过程中产生的电弧电压值以及电弧室获取和耗散的电弧能量。测试和模拟的目的是回答以下问题:是否有可能在不产生高电弧电压值的情况下快速关闭直流电-电路中的过电压,以及高速断路器应如何形成di/dt变化,以实现尽可能短的时间,尽可能低的电弧电压和最低的能量
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引用次数: 0
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EngRN: Materials in Energy (Topic)
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