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Internal cracks in rods, structured in a steam microwave environment 棒的内部裂纹,结构在蒸汽微波环境中
Pub Date : 2021-07-08 DOI: 10.15407/steelcast2021.02.052
L. Solonenko, S. Repyakh
The aim of the study is to elucidate the mechanism of the occurrence of internal cracks in casting molds and rods, structured by the process of steam-microwave hardening (SMH), with sand clad with water glass. The studies used quartz sand of grade 1K 1 O 1 02, which was clad with soda sodium water glass with a silicate modulus of 2.9 and a specific density of 1440 kg/m 3 at 20 ° C. Dilatometric measurements were carried out in a chamber of a specially adapted microwave oven with a magnetron power of 700 W and a frequency of 2.45 GHz. The linear change in the height of the sand in the container was recorded by video recording of the readings of the dial indicator in time. The sands were tested in both microwave and steam-microwave radiation with the previous sifting of dry clad sand through a sieve with a mesh of 0.4 mm and 0.63 mm. The article presents the results of dilatometric studies of changes in the size of samples from pure sand and sand clad with liquid glass, during their processing by microwave radiation in air and in a water vapor environment. It is shown that the reason for the appearance of internal cracks in casting molds and cores, which are made by the SMH-process, is the temporary cessation of microwave action on the mixture during its structuring. As a result, due to the difference in the nature and magnitude of the change in the size of the structured and unstructured mixture in the flask (core box), a layer with a weak mechanical bond between adjacent grains of sand appears at the structuring front, and, as a result, an internal crack. The scientific novelty of the work lies in the elucidation of the causes and mechanism of the occurrence of internal cracks in casting molds and rods, structured by the SMH-process with sand clad with liquid glass.
本研究的目的是阐明通过蒸汽微波硬化(SMH)工艺构造的铸模和棒材中出现内部裂纹的机制,其中砂包水玻璃。研究使用的是1K 1 O 1 02级石英砂,该石英砂覆有钠钠水玻璃,硅酸盐模量为2.9,比密度为1440 kg/m 3,温度为20°C。在磁控管功率为700 W、频率为2.45 GHz的特制微波炉的室内进行膨胀测量。容器中沙子高度的线性变化是通过实时千分表读数的视频记录来记录的。在微波和蒸汽微波辐射下对沙子进行了测试,之前用0.4 mm和0.63 mm筛网对干包层沙子进行了筛分。本文介绍了在空气和水蒸气环境中通过微波辐射处理纯沙子和包层液体玻璃的沙子样品时,其尺寸变化的膨胀测量研究结果。结果表明,在SMH工艺制造的铸模和型芯中出现内部裂纹的原因是在混合物结构化过程中微波作用暂时停止。因此,由于烧瓶(芯盒)中结构化和非结构化混合物尺寸变化的性质和幅度不同,在结构前沿出现了相邻砂粒之间具有弱机械结合的层,因此出现了内部裂纹。这项工作的科学新颖性在于阐明了铸造模具和棒材内部裂纹发生的原因和机制,这些模具和棒材是通过SMH工艺用液态玻璃包砂制成的。
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引用次数: 0
The current state and the prospects for the development of high-plasticity ultrastrong Fe-Mn-Al-C steels 高塑性超强Fe-Mn-Al-C钢的发展现状及前景
Pub Date : 2021-07-08 DOI: 10.15407/steelcast2021.02.101
O. Verzilov, M. Voron, A. Semenko, V. Shemet
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引用次数: 2
General classification and system approach to the development of roll press structures 辊压机结构发展的一般分类和系统方法
Pub Date : 2021-07-08 DOI: 10.15407/steelcast2021.02.090
K. Baiul, I. Muraviova, S. Vashchenko, O. Khudyakov, N. Solodka
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引用次数: 0
Analysis and development of modern concepts on the rhomboidity formation nature for continuously cast billets. Part 1 连铸方坯菱形形成性质现代概念的分析与发展。第1部分
Pub Date : 2021-07-08 DOI: 10.15407/steelcast2021.02.031
S.M. Pisarskyi, O. Smirnov
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引用次数: 1
Oxidation resistance of aluminum chromium steels in agressive environments 铝铬钢在腐蚀性环境中的抗氧化性能
Pub Date : 2021-01-01 DOI: 10.15407/STEELCAST2021.01.032
M. Yamshynskyi, Georgy Fedorov
The analyzes of operating conditions of high-temperature parts of fuel-burning devices of boiler units at thermoelectric power stations (TPS) has revealed that their operating temperature reaches 1100–1250 ° C. Since the nozzles of such devices are subjected to intense abrasive actions of coal dust and other fuel components and wear out quickly as a result of erosion processes, then Cr-Al steels with an optimal carbon content can also be used. From the economic point of view, it should be noted that nickel, the content of which in some types of steel reaches 20 %, belongs to expensive and scarce metals. Thus, its use in such quantities for alloying heat-resistant steels is unjustified and impractical, and it becomes possible to replace expensive heat-resistant chromium-nickel steels with cheap casting materials, for example, iron-based alloys with a high chromium content. The choice of an alloy with high oxidation resistance is necessary but insufficient criterion to ensure the reliability and durability of its operation. This is due to the fact that in the process of operation, the products are subjected to periodic heating and cool-ing, that means thermal cycles. In this case, an unequal temperature field arises in the volume of the metal, which contributes to the accumulation of thermal tension. Such tensions can exceed the permissible norms under these conditions, as a result plastic deformation develops in the metal, which subsequently leads to its destruction. To achieve the goal, the work investigated the effect of alloying elements of chromium and aluminum on the heat resistance of iron-based alloys in superheated air with the addition of water vapor and carbon dioxide. The main chemical element in steels of this class is carbon, which has a negative effect on oxidation resistance; therefore, this fact must be taken into account when choosing a heat-resistant steel to manufacture products operating at high temperatures and aggressive environments. A decrease in the rate of oxidation of alloys at high temperatures is achieved due to the formation of a dense protective oxide layer on their surfaces, in which the processes of diffusion transfer of metal and oxygen ions are significantly complicated. This is obtained by adding appropriate amounts of chromium and aluminum to the steel. When the content of aluminum is more than 4 %, the rate of its burnout is practically constant, and the average content of aluminum in steel at any moment of the test time submits to linear relationship.
对热电站锅炉机组燃料燃烧装置高温部件的运行条件分析表明,这些部件的运行温度达到1100–1250°C。由于这些装置的喷嘴受到煤尘和其他燃料成分的强烈磨蚀作用,并因侵蚀过程而迅速磨损,那么也可以使用具有最佳碳含量的Cr-Al钢。从经济角度来看,应该注意的是,镍在某些类型的钢中的含量达到20%,属于昂贵和稀缺的金属。因此,将其如此大量地用于耐热钢的合金化是不合理和不切实际的,并且可以用廉价的铸造材料,例如具有高铬含量的铁基合金来代替昂贵的耐热铬镍钢。选择具有高抗氧化性的合金是必要的,但不足以确保其操作的可靠性和耐久性。这是因为在操作过程中,产品会受到周期性的加热和冷却,即热循环。在这种情况下,在金属的体积中出现不相等的温度场,这有助于热张力的积累。在这些条件下,这种张力可能超过允许的标准,因此金属会发生塑性变形,随后导致其破坏。为了实现这一目标,研究了铬和铝合金元素对铁基合金在添加水蒸气和二氧化碳的过热空气中耐热性的影响。这类钢中的主要化学元素是碳,碳对抗氧化性有负面影响;因此,在选择耐热钢来制造在高温和侵蚀性环境下运行的产品时,必须考虑到这一事实。合金在高温下的氧化速率的降低是由于在其表面上形成了致密的保护性氧化物层,其中金属和氧离子的扩散转移过程非常复杂。这是通过向钢中加入适量的铬和铝来实现的。当铝含量超过4%时,其燃尽率实际上是恒定的,并且在试验时间的任何时刻钢中铝的平均含量服从线性关系。
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引用次数: 0
Forced heat exchange and cooling rate of drops at producing metal powders by melt water atomizatio 熔融水雾化法制备金属粉末时液滴的强制换热和冷却速率
Pub Date : 2021-01-01 DOI: 10.15407/STEELCAST2021.01.026
Yu. F. Ternovyi, A. Prigunova, V. Panova
of the technological process for the production of metal products using the powder metallurgy method. Among the wide variety of methods for making powders, in terms of efficiency and productivity, the spraying of melts with high-pressure water is favorably distinguished, in which the geometric shape and microstructure of particles significantly depend on the cooling rate, which is associated with the peculiarities of heat transfer in the melt drop – water – gas phase system. However, experimental confirmation of one or another mode of heat transfer is not possible, which is associated with the small size of particles, the number of which in 1 cm 3 of the spray zone is about 10 7 . The influence of the thermal physics of the sputtering process on the solidification rate of metal droplets is analyzed. Based on the analysis of the known regularities and phenomena of heat and mass transfer, the heat transfer coef-ficients, the heat flux density for various heat transfer modes, as well as the contribution of the conductive, convective and radiation components of heat transfer are estimated. It is shown that the fraction of heat transfer by radiation is no more than 0.1 %. It has been theoretically proven that droplets are cooled in the bubble mode of water boiling. For tool steel, the particle cooling rate calculated on the basis of the heat transfer coefficient in the developed bubble mode is about 10 6 K/s. Such a cooling rate during bubble or pseudobubble boiling is provided when the resulting vapor film is "torn off" by the water flow, simulating "pseudobubble" cooling. The formation of a cellular structure of powders, which is observed in practice during spraying with water under pressure, confirms the correctness of the theoretical calculations. The results of the work can be used to substantiate the thermal regimes for obtaining powders with various structures, including amorphous ones.
介绍了采用粉末冶金法生产金属制品的工艺流程。在各种各样的粉末制造方法中,就效率和生产率而言,高压水喷射熔体是很好的区分,其中颗粒的几何形状和微观结构显著依赖于冷却速度,这与熔体滴-水-气相系统中传热的特性有关。然而,实验无法证实一种或另一种传热模式,这与颗粒尺寸小有关,在1 cm 3的喷雾区中颗粒的数量约为10 7。分析了溅射过程的热物理特性对金属液滴凝固速率的影响。在分析已知的传热传质规律和现象的基础上,估计了各种传热方式的传热系数、热流密度以及传热中传导、对流和辐射分量的贡献。结果表明,辐射传热的比例不大于0.1%。从理论上证明了液滴是在水沸腾的气泡模式下冷却的。对于工具钢,根据发达气泡模式下的传热系数计算出的颗粒冷却速率约为10.6 K/s。当产生的蒸汽膜被水流“撕裂”,模拟“假气泡”冷却时,在气泡或假气泡沸腾期间提供这样的冷却速率。在加压喷水过程中观察到粉末的胞状结构形成,证实了理论计算的正确性。这项工作的结果可以用来证实获得具有各种结构的粉末的热状态,包括非晶结构。
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引用次数: 0
Current aspects of hydrogen and oxygen content in aluminum alloys 铝合金中氢和氧含量的现状
Pub Date : 2021-01-01 DOI: 10.15407/STEELCAST2021.01.054
V. Gnatush, M. Voron
The analysis of the scientific researches devoted to questions of influence of the content of hydrogen and oxide inclusions in aluminum alloys in the context of these impurities interaction of with various components of material is presented. Based on the published results of experiments in scientific works, aluminum alloys depending on their hydrogen content can be divided into the following four groups: aluminum alloys with nominal hydrogen content; aluminum alloys containing hydride-forming additives; aluminum alloys with high hydrogen content; aluminum alloys with excess hydrogen content (gas). Information on single- and multistage methods of aluminum melt refining, as well as classification of quality control methods for aluminum alloy refining is presented. Some features of properties of aluminum alloys which contain hydride-forming additives are con-sidered. The results of the study of high hydrogen content on the mechanical characteristics of aluminum alloys are traced. Features of technologies of creation of aluminum alloys with ultrahigh content of gases (foam aluminum) are considered. Information on the content of non-metallic inclusions in aluminum and aluminum alloys and methods for determining their content in the melt is presented. Based on the review and analysis, the need for comprehensive studies of the system hydrogen – oxide – alloying/modifying metals in aluminum alloys is shown to clarify the mechanisms of physicochemical and metal- lophysical processes that are realized in the crystallization of aluminum melts. There is a need to use experimental planning to build mathematical models of the relationship between hydrogen/oxide content, process parameters and properties of samples and products made of aluminum alloys. Aluminum alloys, hydrogen, oxides, refining, modification, non-metallic inclusions.
本文对铝合金中氢和氧化物夹杂物含量与材料各组分相互作用的影响进行了分析。根据科学著作中发表的实验结果,铝合金根据其含氢量可分为以下四类:标称含氢量铝合金;含氢化物形成添加剂的铝合金;高含氢铝合金;含有过量氢(气体)的铝合金。介绍了铝熔体单阶段精炼法和多阶段精炼法,以及铝合金精炼质量控制方法的分类。讨论了含氢化物形成添加剂的铝合金的一些性能特点。介绍了高氢含量对铝合金力学特性影响的研究结果。分析了超高气体含量铝合金(泡沫铝)生产工艺的特点。介绍了铝和铝合金中非金属夹杂物的含量及其测定方法。在综述和分析的基础上,指出有必要对铝合金中氢氧合金/改性金属体系进行全面研究,以阐明铝熔体结晶过程中实现的物理化学和金属物理过程的机理。有必要利用实验计划来建立铝合金样品和产品的氢/氧化物含量、工艺参数和性能之间关系的数学模型。铝合金、氢、氧化物、精炼、改性、非金属夹杂物。
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引用次数: 0
Manufacture of foundry forms by steam-microwave hardening by models from frozen sand-water mixtures 用冷冻砂-水混合物模型进行蒸汽-微波硬化的铸造成形
Pub Date : 2021-01-01 DOI: 10.15407/steelcast2021.01.038
Solonenko L.I., Repyakh S.I.
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引用次数: 0
Investigation of the microstructure and hardness of experimental rail steels in the cast state, after hot plastic deformation and heat treatment 试验钢轨钢在铸态、热塑性变形和热处理后的显微组织和硬度研究
Pub Date : 2021-01-01 DOI: 10.15407/STEELCAST2021.01.081
O. Babachenko, G. Kononenko, R. Podolskyi, O. Safronova
The mechanical properties of railroad rails depend on the chemical composition, the elaboration of the cast structure by metal pressure treatment, as well as the heat treatment of the finished rails. The aim of this work is to study the effect of hot plastic deformation (hereinafter HPD) and heat treatment (hereinafter HT) on the change in the structure of the cast state in relation to its initial chemical heterogeneity. The general theoretical conclusions of this work were obtained on the basis of an analysis of literary sources, as well as many years of research on wheel products. These results complement the existing understanding of structural heredity in metals and alloys. The chemical composition of experimental steels for railroad rails has been developed and ingots weighing up to 10 kg have been smelted under laboratory conditions. The study of the micro- structure was carried out and the hardness of the experimental steel was determined on samples of 70x70x80 mm in size, cut from ingots of laboratory rail heats. It was processed in laboratory conditions in two modes: 1 – HPD with a sediment of 50 % after heating to 1250 ± 10 ° С; 2 – normalization (austenitization at 900 ± 10 ° C, air cooling at a rate of 5.1 ° C/s) after HPD. In the study of the cast state of experimental rail steels (RST), it was found that it is austenite dendrites enriched with impurity elements. The effect of hot plastic deformation and heat treatment on the structure and properties of a cast test steel for railroad rails has been studied. The positive effect of deformation and subsequent heat treatment on the mechanical properties of experimental steels was established: after hot plastic deformation, in comparison with the cast state, the increase in hardness was ≈ 14.1 %; after hot plastic deformation with subsequent heat treatment, the increase in hardness was ≈ 39.4 %. The influence of the primary dendritic structure of the investigated steel on its final pearlite structure in the cast state has been established.
铁路轨道的机械性能取决于化学成分、金属压力处理对铸件结构的细化以及成品轨道的热处理。本工作的目的是研究热塑性变形(以下简称HPD)和热处理(以下简称HT)对铸态组织变化的影响及其初始化学非均质性。这项工作的一般理论结论是在分析文献资料的基础上得出的,以及多年来对车轮产品的研究。这些结果补充了对金属和合金结构遗传的现有认识。研制了铁路用试验用钢的化学成分,并在实验室条件下冶炼了重达10公斤的钢锭。以实验室钢锭为试样,切取尺寸为70x70x80mm的试样,进行了显微组织研究,并测定了实验钢的硬度。在实验室条件下以两种模式进行处理:1 - HPD,加热至1250±10°С后沉淀50%;2 - HPD后正火(900±10°C时奥氏体化,5.1°C/s空冷)。在对实验钢轨钢(RST)铸态的研究中,发现其为富含杂质元素的奥氏体枝晶。研究了热塑性变形和热处理对铁路钢轨铸造试验钢组织和性能的影响。变形及后续热处理对实验钢力学性能的积极影响是确定的:热塑性变形后,与铸态相比,硬度提高了≈14.1%;热塑性变形后再进行热处理,硬度提高约39.4%。确定了钢的初生枝晶组织对铸态最终珠光体组织的影响。
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引用次数: 0
Physical modeling of traffic behavior and formation of stagnant zones in a single-line tundish during casting in the conditions of a metallurgical micro-mill 冶金微磨机条件下单线中间包浇注过程中流动行为和滞流区形成的物理模型
Pub Date : 2021-01-01 DOI: 10.15407/STEELCAST2021.01.020
O. Smirnov, O. Verzilov, A. Kravchenko, Yu.O. Smirnov, A. Semenko, D.I. Hoida
моделювання поведінки розплаву формування застійних зон в однострумковому проміжному ковші умовах металургійного The research presented in this paper is aimed at choosing the optimal geometric shape of the tundish box, which must meet the conditions of work in a single-flow tundish with continuous or semi-continuous casting of high-grade or bloom billets in small metallurgical micro-mills. The experiments based on the establishment of a hydrodynamic pattern of metal leakage in the tundish, performed on a physical cold model, were based on the following options: without tundish box (№ 1), asymmetric tundish box with low side, deployed towards the dispenser glass (№ 2), asymmetric tundish box with a low side, deployed in the direction of the nearest narrow wall (№ 3), asymmetric tundish box without side, also deployed in the direction of a narrow wall (№ 4). The best results were shown by broom tundish box deployed towards the nearest narrow wall. But it should be noted that the impact of convec-tive and circulating flows on the lining in this area needs further research. An volume tundish tundish, beaker. was first the narrow tundish. tundish seconds, tundish box design 2 seconds; 3 seconds; a stagnant the tundish box and the tundish nozzle 35–60
моделювання поведінки розплаву формування застійних зон однострумковому проміжному ковші умовах металургійного本文的研究目的是选择中间包箱的最佳几何形状,该形状必须满足小型冶金微轧机连续或半连续铸造高档或坯坯的单流中间包的工作条件。在建立中间包金属泄漏流体动力模式的基础上,在物理冷模型上进行的实验基于以下选项:无中间包箱(№1),低边的不对称中间包箱,向分配器玻璃方向部署(№2),低边的不对称中间包箱,向最近的窄壁方向部署(№3),无边的不对称中间包箱,也向窄壁方向部署(№4)。向最近的窄壁部署的扫帚中间包箱显示出最好的效果。但需要注意的是,对流流动和循环流动对该地区衬板的影响还需要进一步研究。中间包,中间包,烧杯。首先是狭窄的中间包。中间包秒,中间包箱设计秒2;3秒;中间包箱与中间包喷嘴之间有35-60的停滞
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引用次数: 0
期刊
Metall i lit''e Ukrainy
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