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Re-utilization of Stone Industry Waste Materials for Stabilization of Expansive Soil 石料废弃物在膨胀土稳定中的再利用研究
Pub Date : 2022-01-31 DOI: 10.24949/njes.v14i2.670
Umar Zada, K. Haleem, Asim Abbas
This research paper depicts the experimental investigation of the impact of stone dust as an admixture on the geotechnical characteristics of expansive soils that shrink and swell during the wet and dry seasons. As a result, expansive soil causes the differential settlement of structures. Thus the stabilization of expansive soil is important to overcome potential pavement failure. For this purpose research studies were carried out on the reuse of stone industry wastage for the improvement of expansive soil. Also, this research is beneficial to utilize the stone dust waste for strengthening the soil and making the environment pollution-free. Stone dust was used to stabilize the geotechnical characteristics of the weak soil such as shear strength, unconfined compressive strength (UCS), index properties, maximum dry density (MDD), optimum moisture content (OMC), and California bearing ratio (CBR). The percentages of stone dust employed in the studies were 0%, 7%, 14%, 21%, and 28% by dry weight of soil, which substantially reduced the soil's swelling properties. The results show significant improvements in the desirable geotechnical characteristics of the expansive soil. The optimal quantity of stone dust was concluded based on the findings for treating the subgrade of weaker expansive soil.
这篇研究论文描述了石粉作为外加剂对膨胀土在湿季和旱季收缩和膨胀的岩土力学特性的影响的实验研究。因此,膨胀土会引起结构的差异沉降。因此,膨胀土的稳定对于克服潜在的路面破坏具有重要意义。为此,开展了石料工业废弃物回用改良膨胀土的研究。同时,本研究也有利于利用石粉废弃物加固土壤,实现环境无公害。采用石粉对软弱土的抗剪强度、无侧限抗压强度(UCS)、指标特性、最大干密度(MDD)、最佳含水率(OMC)、加州承载比(CBR)等岩土力学特性进行了稳定。研究中使用的石粉的百分比分别为土壤干重的0%、7%、14%、21%和28%,这大大降低了土壤的膨胀特性。结果表明,膨胀土的理想岩土特性得到了显著改善。根据对软弱膨胀土路基的处理结果,得出石粉的最佳用量。
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引用次数: 2
Electrochemical Water Splitting Using NiO-NiFe2O4/MWCNTs Nanocomposite as Electrocatalyst 以NiO-NiFe2O4/MWCNTs纳米复合材料为电催化剂的电化学水分解
Pub Date : 2022-01-31 DOI: 10.24949/njes.v14i2.660
Rida Noor, M. Shahid, F. Khan, M. Umer
Escalating energy demands, scarcity of conventional energy resources and environmental concerns are the key to fuel production through water splitting. Various electrocatalysts have been reported, considering the cost effectiveness, stability and OER (oxygen evolution reaction) activity. In the same context, porous hybrid NiO-NiFe2O4/MWCNTs based nanocomposite as an OER electrocatalyst, has been investigated in the current study. The synthesis has been accomplished via co-precipitation using Tween as a surfactant. Characterization and electrochemical study for water electrolysis using synthesized electrocatalyst deposited glassy Carbon (GC) electrode as anode was carried out using relevant tools. Iron-doped Nickel oxide nanoparticles were synthesized recognizing excellent oxygen evolution activity of NiO and its increase in conductivity with Fe incorporation due to its higher electropositivity. Nanocomposites were synthesized by incorporating upto 20% weight percent MWCNT (Multiwall carbon nanotubes). High surface to volume ratios, stability and excellent conductivity of MWCNTs furthermore, reduction of crystallite sized due to their incorporation enhanced the performance of the electrocatalyst significantly. Hybrid formation of NiO and NiFe2O4 at a certain calcination temperature was also found to be the reason for enhanced OER activity due to the increased grain boundaries. Porous NiO-NiFe2O4/MWCNTs with 10% MWCNTs concentration outperformed with 35mA/cm2 of current density at 1.8V in alkaline media.
不断上升的能源需求、传统能源的稀缺和环境问题是通过水分解生产燃料的关键。考虑到成本效益、稳定性和OER(析氧反应)活性,已经报道了各种各样的电催化剂。在同样的背景下,基于NiO-NiFe2O4/MWCNTs的多孔杂化纳米复合材料作为OER电催化剂也被研究。以吐温为表面活性剂,通过共沉淀法合成。利用相关工具对合成电催化剂沉积玻碳(GC)电极作为阳极的电解水进行了表征和电化学研究。合成了铁掺杂的氧化镍纳米颗粒,发现NiO具有优异的析氧活性,并且由于其较高的电正性,铁掺杂使其电导率提高。纳米复合材料是通过掺入重量高达20%的MWCNT(多壁碳纳米管)合成的。MWCNTs具有高的表面体积比、稳定性和优异的导电性,并且由于它们的掺入而减小了晶体尺寸,从而显著提高了电催化剂的性能。在一定的煅烧温度下,NiO和NiFe2O4的杂化形成也是OER活性增强的原因,因为晶界增加。多孔NiO-NiFe2O4/MWCNTs浓度为10%时,在碱性介质中1.8V电流密度为35mA/cm2时表现更好。
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引用次数: 0
Thermal Transport Properties of Bi2O2Se-Ag2Se Hybrid Structures Bi2O2Se-Ag2Se杂化结构的热输运性质
Pub Date : 2021-09-19 DOI: 10.24949/njes.v14i2.662
M. U. Farooq, Sumayya, M. Umer Iqbal, Ishrat Asghar, Mujtaba Ikram, Sajid Butt
The series of Bi2O2Se-Ag2Se composites were synthesized by two step solid state reaction followed by Spark plasma sintering. To optimize their thermal transport properties, different weight percent (wt. %) of silver i-e, 10%, 15% and 20%, was added. The room temperature X-ray diffraction (XRD) and high temperature XRD was used to investigate the crystalline phases,  whereas the morphological study was conducted through FESEM. The thermal transport properties were evaluated from 323 K to 773 K, to study the effect of silver addition on thermal conductivity of all the composite samples. The reduced thermal conductivity of the composite with decreasing Ag contents is might be attributed to increase of the Ag2Se and Bi2O3 nano-inclusions in Bi2O2Se multi-phase-system that increased the phonon scattering regions and reduced the overall thermal conductivity significantly, up to 54 % for BA15SO as compared to that of BA20CO at 473 K.
采用两步固相反应和放电等离子烧结法制备了Bi2O2Se-Ag2Se系列复合材料。为了优化它们的热输运性能,添加不同重量百分比(wt. %)的银i-e, 10%, 15%和20%。采用室温x射线衍射(XRD)和高温x射线衍射(XRD)对其进行了晶相分析,并用FESEM对其形貌进行了研究。在323 K ~ 773 K范围内考察了复合材料的热输运性能,研究了银的加入对复合材料导热性能的影响。随着Ag含量的降低,复合材料的导热系数降低可能是由于Bi2O2Se多相体系中Ag2Se和Bi2O3纳米夹杂物的增加,增加了声子散射区域,显著降低了总导热系数,在473 K时,BA15SO的导热系数比BA20CO降低了54%。
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引用次数: 0
Impact of Riveting Parameters on Mechanical Properties of Aluminum Alloy (LY-12) Sealant Applied Lap Joint of an Aircraft 铆接参数对飞机搭接铝合金(LY-12)密封胶力学性能的影响
Pub Date : 2021-06-01 DOI: 10.24949/NJES.V14I1.649
A. A. Qureshi
 The assembling process includes various techniques, out of which riveting has been employed most successfully in fields like construction of enormous structures, auto-motives, and most notably in the aerospace industry. This process includes marking, drilling followed by riveting. Furthermore, being a successful process, most of the aircraft structure is assembled using rivets. However, various factors contribute to the result. Therefore, the effect of riveting process parameters such as Sheet Thickness, Rivet Diameter, Rivet Type, and Riveting Sequence have been studied on responses, i.e., Deformation and Joint Load Capacity of lap joint composed of Aluminum Alloy sheets (LY-12) at T0 condition by sandwiching aerospace-grade sealant (XM-22B). Each of these parameters is studied on three levels and the experimental setup is designed using Response Surface Methodology (RSM). The main objective of this work is to demonstrate the effect of riveting parameters on lap joints with sealant and analyze the effect through careful measurement of deformation and joint load capacity of the test specimen. Finally, a variance analysis (ANOVA) is performed to identify significant factors influencing response parameters using Design Expert Software V-12.
装配过程包括各种各样的技术,其中铆接技术最成功地应用于大型结构建筑、汽车制造以及最著名的航空航天工业等领域。这个过程包括打标、钻孔和铆接。此外,作为一个成功的过程,大多数飞机结构是用铆钉组装的。然而,各种因素促成了这一结果。为此,研究了板材厚度、铆钉直径、铆钉类型、铆接顺序等铆接工艺参数对夹带航空级密封胶(XM-22B)铝合金板材(LY-12)在T0工况下搭接接头的变形响应和接头承载能力的影响。在三个层面上对这些参数进行了研究,并利用响应面法设计了实验装置。本工作的主要目的是论证铆接参数对密封胶搭接接头的影响,并通过仔细测量试件的变形和接头承载能力来分析这种影响。最后,使用Design Expert Software V-12进行方差分析(ANOVA)以确定影响响应参数的显著因素。
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引用次数: 0
Water quality assessment of Raw and Chlorinated drinking water of a Residential University 某住宿大学原水及氯化饮用水水质评价
Pub Date : 2021-06-01 DOI: 10.24949/NJES.V14I1.633
Huda M. Kamal, I. Hashmi
 The safety of water is essential for life on earth. Drinking contaminated water can give rise to many health issues. Tohighlight the major causes of contamination in water, this study was carried out to determine the physicochemical andbacteriological quality of raw and chlorinated water. Raw and chlorinated water samples were obtained from three locations (zones) of a residential university (National University of Sciences and Technology, NUST). Ten physicochemicalparameters were analyzed (pH, Electrical conductivity, Turbidity, Dissolved oxygen, Hardness, Alkalinity, Total suspendedsolids, Total dissolved solids, Total organic carbon, and Chlorine (free & total)). Bacteriological analysis was performedthrough the MPN technique. The results showed that all the physicochemical parameters were found within the permissible limits set by WHO and PSDWQ for raw and chlorinated water, except TSS and Chlorine (free & total). The TSS of raw and chlorinated water ranged from 3.3-14.3mg/L and 8.7-12.7mg/L, greater than the permissible limits. The free Chlorine for both raw and chlorinated water ranged from 0.04-0.09mg/L and 0.06-0.07mg/L and total Chlorine for both raw and chlorinated water in the range 0.10-0.09mg/L and 0.22-0.24mg/L, respectively, which were far below the recommended limit required for water disinfection. The MPN index for raw and chlorinated water ranged from 23 to >23MPN/100ml and 16 to >23MPN/100ml, exceeding the permissible limits. The results concluded that the water, whether raw or chlorinated, was not fit for drinking purposes. Proper dosages of Chlorine and filtration techniques are required to make the water fit for consumption.
水的安全对地球上的生命至关重要。饮用受污染的水会引起许多健康问题。为了突出水污染的主要原因,本研究进行了确定原水和氯化水的物理化学和细菌质量。从一所住宿大学(国立科技大学,NUST)的三个地点(区)获得了原水和氯化水样。分析了10个理化参数(pH、电导率、浊度、溶解氧、硬度、碱度、总悬浮固体、总溶解固体、总有机碳和氯(游离和总))。通过MPN技术进行细菌学分析。结果表明,除TSS和氯(游离氯和总氯)外,其余理化参数均在WHO和PSDWQ规定的原水和氯化水允许范围内。原水和氯化水的TSS分别为3.3 ~ 14.3mg/L和8.7 ~ 12.7mg/L,均高于允许限值。原水和氯化水的游离氯含量分别为0.04 ~ 0.09mg/L和0.06 ~ 0.07mg/L,总氯含量分别为0.10 ~ 0.09mg/L和0.22 ~ 0.24mg/L,均远低于水消毒推荐限量。原水和氯化水的MPN指数分别为23 ~ >23MPN/100ml和16 ~ >23MPN/100ml,均超过允许限值。结果表明,无论是生水还是氯化水,都不适合饮用。需要适当剂量的氯和过滤技术,使水适合饮用。
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引用次数: 0
Condition Monitoring of Outdoor High Voltage Insulators, Online and Offline Techniques: A review 室外高压绝缘子状态监测:在线与离线技术综述
Pub Date : 2021-06-01 DOI: 10.24949/NJES.V14I1.627
Haseeb Faisal, A. Ali, M. Riaz
 Outdoor insulator plays a vital role in high voltage transmission and distribution system. The performance and properties of outdoor insulator may severely affect due to various types of pollutants. The failure of insulation in high voltage system results in loss of supply and a huge loss of electrical energy to distribution utilities. In order to reduce power losses and provide a reliable power transmission, selection and design of insulators is very important. To monitor the condition and performance of outdoor insulator in contaminated conditions an appropriate diagnostic technique is required. In this paper various online and offline techniques for conditioning monitoring of outdoor insulators are reviewed under different contaminated conditions. To maintain the healthy environment, the condition monitoring of power line insulators is an important requirement. There are number of techniques that have been introduced to fulfil this requirement. Each technique used at different contaminated condition have their own pros and cons. The findings indicate that the most important effect on the surface of the insulators based on the contamination on the surface leakage current and the flashover voltage. This paper will help in the selection and design of condition monitoring techniques for high voltage outdoor insulator.
室外绝缘子在高压输配电系统中起着至关重要的作用。室外绝缘子的性能和性能会受到各种污染物的严重影响。高压系统的绝缘失效会造成供电损失,给配电设施造成巨大的电能损失。为了减少电力损耗,提供可靠的电力传输,绝缘子的选择和设计是非常重要的。为了监测室外绝缘子在污染条件下的状态和性能,需要一种适当的诊断技术。本文综述了不同污染条件下室外绝缘子状态监测的各种在线和离线技术。为了维护健康的运行环境,对电力线绝缘子进行状态监测是一项重要的要求。已经引入了许多技术来满足这一要求。在不同污染条件下使用的每一种技术都有各自的优缺点。研究结果表明,对绝缘子表面影响最大的是污染对表面泄漏电流和闪络电压的影响。本文将有助于高压室外绝缘子状态监测技术的选择和设计。
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引用次数: 0
Synthesis of Rubidium-doped Calcium Hydroxyapatite Nanoparticles for Biomedical Applications 生物医学用掺铷羟基磷灰石纳米颗粒的合成
Pub Date : 2021-06-01 DOI: 10.24949/NJES.V14I1.644
A. Nisar, S. Iqbal, M. Anjum, M. Shafique
 Due to high biocompatibility, bioactivity, and natural occurrence in bones and teeth, synthetic calcium hydroxyapatite (CaHAp) is a widely applied biomaterial in tissue engineering, including orthopedic surgery and dentistry. However, the brittle nature and low strength reduce its durability, which can be improved by doping metal ions. Rubidium (Rb) is an essential trace element that works as an antibacterial agent in the human body; therefore, it can be doped in synthetic Ca-HAp to promote its durability. In this work, Rb-doped calcium hydroxyapatite (Rb-HAp) nanoparticles are synthesized by the coprecipitation method at low temperatures. Phase purity, crystallinity, doping level, and mechanical properties are investigated by X-ray diffraction (XRD), inductively coupled plasma optical emission spectroscopy (ICP-OES), and micro-hardness tester. It is observed that a minute quantity (≈ 0.02%) of Rb remained in the apatite structure when 5% of Rb+ is doped via in situ method. Moreover, small dopant concentration did not affect the crystal structure and the tensile strength of HAp.
合成羟基磷灰石钙(CaHAp)由于具有较高的生物相容性和生物活性,且在骨骼和牙齿中天然存在,是一种广泛应用于组织工程的生物材料,包括骨科和牙科。然而,其脆性和低强度降低了其耐久性,可以通过掺杂金属离子来提高其耐久性。铷(Rb)是人体必需的微量元素,具有抗菌作用;因此,它可以在合成掺杂Ca-HAp促进其耐久性。本文采用共沉淀法在低温下合成了rb掺杂的羟基磷灰石(Rb-HAp)纳米颗粒。采用x射线衍射(XRD)、电感耦合等离子体发射光谱(ICP-OES)和显微硬度仪研究了相纯度、结晶度、掺杂水平和力学性能。当原位法掺杂5%的Rb+时,在磷灰石结构中仍有微量的Rb(≈0.02%)残留。此外,小掺杂浓度对HAp的晶体结构和抗拉强度没有影响。
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引用次数: 0
Variation in Mechanical Properties of SAE 1006 Interstitial Free (IF) Steel Sheets During Cold Rolling SAE 1006无间隙(IF)钢板在冷轧过程中力学性能的变化
Pub Date : 2020-12-01 DOI: 10.24949/NJES.V13I2.623
A. Chandio, A. Shah, I. A. Channa, S. Abro, Y. Raza, M. Rizwan, M. Ali, K. Iqbal, M. Ansari, W. Salman
This research aims to study the variation in properties of hot-rolled SAE 1006 IF steel sheets during cold rolling to reveal the factors causing the decrease in formability of SPCG steel sheets during deep drawing. Results have shown that pickling does not affect the mechanical properties; however, cold rolling results in an increase in hardness, tensile strength and yield strength. Stress relieve annealing results in coarsening and homogenizing of grains which reduces brittleness and impart ductility. Temper rolling causes an increment in mechanical parameters again, improve surface hardness and flatness. By analyzing the microstructure and comparing it with the HESCO sample, it is revealed that there are still some elongated grains found along with coarse grains after annealing. Soaking time is not sufficient for the growth of homogenized structure, resulting in decreased ductility and formability during deep drawing.
本研究旨在研究热轧sae1006 IF钢板在冷轧过程中的性能变化,揭示导致SPCG钢板在深拉深成形性能下降的因素。结果表明:酸洗对材料的力学性能没有影响;然而,冷轧导致硬度,抗拉强度和屈服强度的增加。应力消除退火导致晶粒粗化和均匀化,从而降低脆性并赋予延展性。回火轧制使机械参数再次增加,提高了表面硬度和平整度。通过组织分析,并与HESCO试样进行比较,发现退火后除了晶粒粗大外,还存在一些拉长的晶粒。浸渍时间不足以形成均匀化组织,导致拉深成形时延展性和成形性下降。
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引用次数: 1
Development of Cost-Effective Fertilizer-Based Media for the Microalgae Cultivation Aimed at Effective Biomass Production 以高效生物质生产为目标的低成本肥料微藻培养培养基的开发
Pub Date : 2020-12-01 DOI: 10.24949/NJES.V13I2.628
Muneeb Qayyum, A. H. Khoja, S. Naqvi, Haider Ejaz, Azra Nawar, Abeera A. Ansari
In the diversification of the world's energy portfolio, microalgae biofuels have gained particular attention as a means of providing carbon-neutral hydrocarbon-based fuels. The progress on this front has been hindered because of expensive and unreliable microalgae cultivation systems, where the preparation of synthetic culture media poses a monetary strain. This study aims to investigate a new microalgae growth media that is readily available and cost-effective. The new microalgae fertilizerbased media (FBM) were designed and compared with Bold Basal media (BBM) in terms of growth parameters, production of lipid and value-added algal by-products (carotenoid and phycobiliprotein). The growth parameters such as cell count and specific growth rate were investigated for FBM and BBM. FBM showed a significant growth rate of 7 million/mL-per day as compared to 2 million/ml per day. A similar growth trend was observed for chlorophyll (a), (b) and carotenes which increased to the values of 5microgram/gram formula weight (µg/gfw), 3 µg/gfw and 2 µg/gfw for FBM. On the other hand, lipid and phycobiliprotein showed a decrease of 18.75 % and 16.66 %, respectively, compared to BBM. Even though some growth parameters are negatively affected by fertilizer-based media, the cost reduction is substantial to allow this drawback to be overlooked. The medium's cost is reduced by a factor of 7 and provides ground for the use of the FBM in the large-scale cultivation of algae for biomass production.
在世界能源组合多样化的过程中,微藻生物燃料作为一种提供碳中性烃基燃料的手段受到了特别的关注。由于昂贵和不可靠的微藻培养系统,这方面的进展受到阻碍,其中合成培养基的制备造成了资金紧张。本研究旨在探索一种易于获得且具有成本效益的新型微藻生长培养基。设计了新型微藻肥基培养基(FBM),并与Bold基础培养基(BBM)进行了生长参数、脂质产量和增值藻类副产物(类胡萝卜素和藻胆蛋白)的比较。研究了FBM和BBM的生长参数,如细胞计数和特定生长速率。与每天200万/毫升相比,FBM显示出700万/毫升/天的显著增长率。FBM的叶绿素(A)、(b)和胡萝卜素也有类似的增长趋势,分别增加到5微克/克配方重(µg/gfw)、3微克/gfw和2微克/gfw。脂质和藻胆蛋白含量分别比BBM降低18.75%和16.66%。尽管一些生长参数受到以肥料为基础的介质的负面影响,但成本的大幅降低使这一缺点被忽视。该培养基的成本降低了1 / 7,并为FBM在大规模种植用于生物质生产的藻类中使用提供了基础。
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引用次数: 1
Nano Particles Effect on Transformation Behavior and Mechanical Properties on Commercial Steel Used for Automobile Parts 纳米颗粒对汽车零部件用钢相变行为和力学性能的影响
Pub Date : 2020-12-01 DOI: 10.24949/NJES.V13I2.622
S. Abro, Mohammed N. Alghamdi, H. Moria
A scientific study has been performed in this research work on the basis of experimental results and ramification to divulge the advancement of second phase particles and its influence on ferrite and austenite phase transformation in less carbon-manganese added steel. Two steels have been engaged in this competition with and without aluminum addition along with nitrogen. To fade out the already present particles, as received steel under investigation was solution heat treated at 1200°C and then both the steel samples were heat treated at 750°C and 810°C for 15, 20, 35, and 70 sec incubation time in the cyanide added liquid bath furnace and were rapidly cooled from elevated temperature at room temperature in ordinary water. Metallography was performed after etching technique in two etchant solutions microstructural features with advanced Olympus optical microscope with polarized light. To further enlarge the important microstructure SEM was used to capture the micrographs. It was concluded that aluminum combine with nitrogen stimulate the fine aluminum nitride (AlN) particles and these particles were the major source to hinder the grain boundary mobility and consequently phase transformation was interrupted in aluminum added steel and it lowers the critical temperatures. Surprisingly there was no such attitude was observed in without aluminum added steel.
本研究在实验结果和实验结果的基础上进行了科学的研究,揭示了低碳锰钢中第二相颗粒的进步及其对铁素体和奥氏体相变的影响。两种钢在加铝和不加氮的情况下进行了竞争。为了淡化已经存在的颗粒,接受调查的钢在1200°C进行固溶热处理,然后在添加氰化物的液浴炉中分别在750°C和810°C进行15、20、35和70秒的培养时间,然后在室温下的普通水中从高温快速冷却。采用先进的奥林巴斯偏振光光学显微镜,在两种蚀刻液中蚀刻工艺后进行金相分析。为了进一步放大重要的微观结构,采用扫描电镜捕捉显微图像。结果表明,铝与氮的结合激发了细小的氮化铝(AlN)颗粒,这些颗粒是阻碍晶界迁移的主要来源,从而中断了加铝钢的相变,降低了临界温度。令人惊讶的是,在没有添加铝的钢中没有观察到这种态度。
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引用次数: 1
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