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ADSORPSI Pb(II) DARI AIR DENGAN KARBON AKTIF DARI KULIT SALAK PONDOH : KINETIKA DAN ISOTERM ADSORBSI
Pub Date : 2021-08-10 DOI: 10.20885/ijcr.vol6.iss1.art1
M. Anugrahwati, Febi Indah Fajarwati, Rika Awalin Safitri
In this research, salacca edulis peel was synthesized into activated carbon as Pb2+ ion adsorbent. This conversion process involved an affordable method of carbonization and activation using KOH. The adsorbent material obtained was then characterized by FTIR and used in the study of kinetics and adsorption isotherms in solutions containing Pb2+. The characterization results indicated functional groups that may be involved in adsorption such as O-H. In the adsorption application, the determination of the concentration of Pb2+ was analyzed using Atomic Absorption Spectrophotometry (AAS). The optimum adsorption time condition in this study was 15 minutes with adsorption capacity reaching 90% where the adsorption kinetics followed pseudo second order while the adsorption isotherm was in accordance with the Langmuir isotherm equation
本研究以黄芩皮为原料,制备活性炭作为Pb2+离子吸附剂。该转化过程涉及一种经济实惠的碳化和KOH活化方法。然后用FTIR对所得的吸附材料进行了表征,并将其用于含Pb2+溶液的动力学和吸附等温线的研究。表征结果显示了可能参与吸附的官能团,如O-H。在吸附应用中,采用原子吸收分光光度法(AAS)测定Pb2+的浓度。本研究的最佳吸附时间为15分钟,吸附量达到90%,吸附动力学为准二级,吸附等温线符合Langmuir等温线方程
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引用次数: 0
Analisis Kadar Padatan Tersuspensi Total (TSS) Dan Logam Krom Total (Cr) Pada Limbah Tekstil Di Dinas Lingkungan Hidup Sukoharjo 分析了Sukoharjo环境服务处纺织品的总死水和总铬合金的分析
Pub Date : 2021-08-10 DOI: 10.20885/ijcr.vol6.iss1.art4
Agil Lestari, Sigit Samsunar
Textile waste is one of the most common liquid wastes and has the potential to pollute the environment. This is due to the high level of water pollution and the degree of water contamination indicating the presence of TSS solids which increase the density of waste and textile waste water also contains very complex pollutants such as metal Chrome (Cr). Based on the Regulation of the Minister of Environment and Forestry of the Republic of Indonesia Quality standards for wastewater for businesses and / or activities of the textile industry for total suspended solids (TSS) parameters of 50mg / L and for total chromium (Cr) metal parameters of 1.0 mg / L To overcome this problem, it is necessary to analyze TSS levels and total chromium metal whether it is in accordance with the textile industry wastewater quality standards. Analysis of TSS levels can be done using gravimetric methods and analysis of total chromium metal levels using the AAS instrument. From the analysis, it was found that the total TSS and chromium metal levels in the waste were still below the standard threshold for wastewater quality, namely 20 mg / L for TSS levels and total chromium metal at 0.112 mg / L.
纺织废物是最常见的液体废物之一,具有污染环境的潜力。这是由于水污染程度高,水污染程度表明TSS固体的存在增加了废物的密度,纺织废水也含有非常复杂的污染物,如金属铬(Cr)。根据印度尼西亚共和国环境和林业部长条例,纺织工业企业和/或活动废水的质量标准,总悬浮固体(TSS)参数为50mg / L,总金属铬(Cr)参数为1.0 mg / L。为了克服这一问题,有必要分析TSS水平和总金属铬是否符合纺织工业废水质量标准。TSS含量的分析可以用重量法进行,总铬金属含量的分析可以用原子吸收光谱法进行。分析发现,废水中总TSS和总金属铬含量仍低于废水水质标准阈值,即TSS含量为20 mg / L,总金属铬含量为0.112 mg / L。
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引用次数: 0
STUDY OF THE EFFECT OF SOLVENT AND QUANTITY OF CATALYST ON ARICRYL POLYMERIZATION AT PT. ARISTEK HIGHPOLYMER BEKASI 溶剂和催化剂用量对羊尾草高聚物聚合的影响研究
Pub Date : 2020-11-05 DOI: 10.20885/ijcr.vol5.iss2.art2
N. H. Airun, Zukhrufi Zukhrufi, F. I. Fajarwati
Aricryl synthesis was carried out by feeding technique. The monomers used were styrene, isobutyl acrylate, 2-HEMA and acrylamide powder. The catalysts used were AIBN (Azobisisobutyronitrile) and Perbutyl O98. The synthesis results were then devided by 2 for resin batch G-0915 A was diluted in > 63% mixture of n-butanol and methanol, while for G-0915 B was carried out dilution in > 63% toluene. the results obtained were compared based on the influence of the solvent using the parameters of viscosity, NV/total solid, AV (Acid Value), color and OH value. It was found that the best solvent according to specifications is toluene solvent with a viscosity of Z2-15. The Aricryl batch G-0915 was compared with Aricryl batch G-0903 based on the influence of the quantity of catalyst. The results showed that the increasing quantity of catalyst affects the aging process. Aging duration for Aricryl batch G-0903 was 11 hours, while for Arycril batch G-0915 was 8 hours.
采用进料法合成芳基。所使用的单体有苯乙烯、丙烯酸异丁酯、2-HEMA和丙烯酰胺粉末。催化剂为AIBN(偶氮二异丁腈)和过丁基O98。树脂批G-0915 A在> 63%的正丁醇和甲醇混合物中稀释,G-0915 B在> 63%的甲苯中稀释,合成结果除以2。通过粘度、NV/total solid、AV (Acid Value)、颜色、OH值等参数,比较了溶剂对所得结果的影响。结果表明,符合规格要求的最佳溶剂为粘度为Z2-15的甲苯溶剂。根据催化剂用量的影响,对G-0915和G-0903两批aricyl进行了比较。结果表明,催化剂用量的增加会影响其老化过程。芳烯醇G-0903批次的老化时间为11小时,而芳烯醇G-0915批次的老化时间为8小时。
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引用次数: 0
EFFECT OF SOLVENTS ON ARICRYL POLYMERIZATION AND APPLICATION IN WOOD COATINGS 溶剂对芳基聚合的影响及其在木器涂料中的应用
Pub Date : 2020-11-05 DOI: 10.20885/ijcr.vol5.iss2.art1
Desi Nasriyanti, Zukhrufi Zukhrufi, F. I. Fajarwati
Aricryl polymerization is made in three stages according to the addition polymerization scheme, namely initiation, termination and propagation. The processed aricryl polymerization was batch G-0903, G-0915A and G-0915B. The difference in each batch is the use of solvents for dilution. Dilution for resin batch G-0905 was carried out in >63% n-butanol and toluene. Dilution for resin carried out in >63% toluene. Based on data on the application of wood coatings, the best results were in batch G-0905 with a hardness value of 97, a glass value of 97 and a drying time of 0.05. The resin obtained has a total solid specification of 59.66%, a viscosity of Z2-Z3, an acid number of 0.45 mg KOH/g, a colorless than I and the resulting resin is clear and clean.
根据加成聚合方案,芳基聚合分起始、终止和增殖三个阶段进行。所处理的芳基聚合批次为G-0903、G-0915A和G-0915B。每批的不同之处在于使用溶剂进行稀释。用大于63%的正丁醇和甲苯稀释G-0905树脂批。在大于63%的甲苯中稀释树脂。根据木器涂料的应用数据,G-0905批次的效果最好,硬度值为97,玻璃值为97,干燥时间为0.05。所得树脂的总固含量为59.66%,粘度为Z2-Z3,酸数为0.45 mg KOH/g,无色小于1,树脂清澈干净。
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引用次数: 0
Adsorption Kinetics Study of Cu(II) and Pb(II) Using Biosorbent from Nephelium Fruit Peel Extract Polymers 枸杞果皮萃取物聚合物生物吸附剂吸附Cu(II)和Pb(II)的动力学研究
Pub Date : 2020-07-29 DOI: 10.20885/ijcr.vol5.iss1.art1
W. Winata, I. Yanti
Recovery of Cu(II) and Pb(II) which are mostly contained in industrial liquid waste, both large and home industries, have been carried out, one of them is by the adsorption process. This research was carried out kinetics study of adsorption of Cu(II) and Pb(II) in liquid waste to determine the effectiveness of biosorbents from Nephelium fruit peel extracts against liquid wastes containing Cu(II) and Pb(II). Determination of Cu(II) and Pb(II) adsorption kinetics by using biosorbent from rambutan fruit peel extract was done through several kinetic models namely the Langmuir-Hinshelwood, Santosa, Lagergreen and Ho kinetics models. The Cu(II) and Pb(II) adsorption kinetics all follow the Ho kinetics model, which is the  kinetics mechanism of pseudo-second order.
铜(II)和铅(II)主要存在于大型和家庭工业废液中,对其进行了回收,其中一种方法是吸附法。通过对废液中Cu(II)和Pb(II)的吸附动力学研究,确定枸橼果皮提取物生物吸附剂对含Cu(II)和Pb(II)废液的吸附效果。采用Langmuir-Hinshelwood、Santosa、Lagergreen和Ho动力学模型,研究了红毛丹果皮提取物对Cu(II)和Pb(II)的吸附动力学。Cu(II)和Pb(II)的吸附动力学均遵循Ho动力学模型,为准二级动力学机制。
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引用次数: 0
Synthesis of TiO2/Vulcanic Ash as Photocatalyst for Batik Wastewater Treatment in Household Scale TiO2/火山灰光催化剂的合成及其在蜡染废水处理中的应用
Pub Date : 2020-06-19 DOI: 10.20885/ijcr.vol5.iss1.art5
Rico Nurillahi, I. Fatimah, Dwi Halimah, G. D. Apriliani
The TiO2/Vulcanic ash as a photocatalyst for batik waste treatment has been conducted in this study. thas been synthesized in this study. Titanium precursor has been dispersed into volcanic ash powder suspension followed by drying and calcination. Characterization of material was conducted by using X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF), Fourier Transform InfraRed (FT-IR) and spectrophotometer UV-Visible. The material was applied in batik’s waste water photooxidation at varied treatment of the addition of H2O2 and potassium peroxodisulphate as oxidant. In this research, from varied treatment is concluded that with addition of potassium peroxodisulphate have better effectivity than using H2O2. TiO2/Vulcanic Ash is a potential material that can be developed for batik’s wastewater treatment under photooxidation mechanism with low-cost treatment and friendly for environmental.
以二氧化钛/火山灰为光催化剂,对蜡染废渣进行了处理。本研究已合成。将钛前驱体分散到火山灰粉末悬浮液中,然后进行干燥和煅烧。采用x射线衍射(XRD)、x射线荧光(XRF)、傅里叶变换红外(FT-IR)和紫外可见分光光度计对材料进行了表征。以过氧化氢和过氧二硫酸钾为氧化剂,对蜡染废水进行了光氧化处理。本研究从不同的处理方法得出,添加过氧二硫酸钾比使用H2O2有更好的效果。二氧化钛/火山灰是一种具有光氧化处理成本低、环境友好的蜡染废水处理材料。
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引用次数: 0
Biochar From Sawdust Modified Mahogany Magnetite (Fe3O4) to Reduce Chromium Metal Levels in Batik 木屑改性红木磁铁矿(Fe3O4)生物炭降低蜡染中铬金属含量
Pub Date : 2020-06-19 DOI: 10.20885/ijcr.vol5.iss1.art4
Nova Restu Nur Ardiyanto, Try Nur Arisky, Baiq Milla Fadilla
This study will highlight the potency of Mahogany wood biochar as an adsorbent for Cr (VI) in Batik wastewater. Adsorption is a good method for the treatment of certain types of waste. One promising adsorbent is activated carbon. Activated carbon can be prepared from materials that contain high carbon-based organic compounds such as cellulose and hemiscellulose. Mahogany wood contains a lot of content such as cellulose, holocellulose, hemicellulose and lignin respectively 47.26, 74.63, 23.37 and 25.82 in percent. The organic compounds contained rich Carbon are good raw material for biochar preparation. Biochar is a porous wood charcoal substance (porous). Biochar magnetic was remarkable material to reduce metal Cr (VI) from Batik wastewater. This study was concluded that Mahogany wood characteristics that are almost the same as other wood could potentially be used as raw materials for biochar for adsorption Cr (VI) from batik waste.
本研究将突出红木生物炭作为蜡染废水中Cr (VI)吸附剂的效力。吸附法是处理某些类型废物的好方法。活性炭是一种很有前途的吸附剂。活性炭可以由含有高碳基有机化合物如纤维素和半纤维素的材料制备。红木中纤维素、全纤维素、半纤维素和木质素的含量分别为47.26%、74.63%、23.37%和25.82%。富含碳的有机化合物是制备生物炭的良好原料。生物炭是一种多孔木炭物质(多孔)。生物炭磁性材料对蜡染废水中金属Cr (VI)的还原效果显著。本研究认为,红木具有与其他木材几乎相同的特性,可以作为生物炭吸附蜡染废弃物中铬(VI)的原料。
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引用次数: 1
Comparison of the essential oil of fresh cananga (Cananga odorata) flowers and wilted cananga 鲜香加楠花精油与枯萎香加楠花精油之比较
Pub Date : 2020-06-18 DOI: 10.20885/ijcr.vol5.iss1.art3
Danna Amelia, D. Rubiyanto
The isolation and identification of physico-chemical properties of fresh and wilted cananga (Cananga odorata) essential oil were conducted. Essential oil of cananga flower was isolated by steam distillation method. The chemical components of the two conditions of the cananga flower were analyzed using the GCMS instrument. Several physical parameters including color, odor, specific gravity and refractive index were carried out in this study. The analysis showed that the yield of essential oil on fresh and wilted cananga flowers was 0.325  and 0.276 respectively.
对鲜香加楠精油和枯萎香加楠精油的理化性质进行了分离鉴定。采用水蒸气蒸馏法分离了甘南花精油。采用气相色谱法(GCMS)分析了两种条件下甘南花的化学成分。本文研究了几种物理参数,包括颜色、气味、比重和折射率。分析结果表明,鲜花叶挥发油得率为0.325,枯花叶挥发油得率为0.276。
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引用次数: 0
Analysis of pH, Total Dissolved Solid (TDS), and Mn levels in Well Water in Cirebon Regency 炭摄政区井水pH、总溶解固形物(TDS)和Mn含量分析
Pub Date : 2020-06-17 DOI: 10.20885/ijcr.vol5.iss1.art2
Wanda Hamidah, Cintia Cindramawa
This study has been conducted to determine the levels of pH, Total Dissolved Solid (TDS), and manganese (Mn) from a well water in Cirebon (A), well water from Laboratorium Perumda Tirta Giri Nata Kota Cirebon (B), dan air Perumda Tirta Giri Nata Kota Cirebon (C). Sampling using a simple random sampling method. Analysis of pH and TDS using a conductometer ADWA AD8000. Concentration of Mn has been analyzed using HACH DR1900 spectrophotometer. The results show that the pH value of sample of A, B and C are 6.53, 7.00 and 6.78. The result of TDS are 381 mg/L, 421 mg/L and 176 mg/L for A, B and C sample respectively. Whilst, the concentration of Mn are 0.680 mg/L, 0.128 mg/L and 0.012 mg/L for A, B and C. Analysis of pH and TDS on all samples showed that they were within safe limits for clean water and drinking water.
本研究旨在测定Cirebon井水(a)、Perumda Tirta Giri Nata Kota Cirebon实验室的井水(B)和Perumda Tirta Giri Nata Kota Cirebon实验室的井水(C)的pH值、总溶解固体(TDS)和锰(Mn)水平。采用简单的随机抽样方法进行采样。用ADWA AD8000电导仪分析pH和TDS。用HACH DR1900分光光度计分析了锰的浓度。结果表明,A、B和C样品的pH值分别为6.53、7.00和6.78。A、B、C样品的TDS分别为381 mg/L、421 mg/L、176 mg/L。A、B和c的Mn浓度分别为0.680 mg/L、0.128 mg/L和0.012 mg/L。对所有样品的pH和TDS分析表明,它们在清洁水和饮用水的安全范围内。
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引用次数: 0
Essential oils from Alpinia purpurata (Zingiberaceae): Chemical composition and Formulation of antiacne cream 紫姜科紫荆精油:抗痘霜的化学成分及配方
Pub Date : 2019-07-16 DOI: 10.20885/IJCR.VOL4.ISS1.ART3
Farah Khilma Yustica, N. Widiastuti, Nava Sapitri, D. Fitriastuti
Jerawat merupakan penyakit radang yang terjadi di kulit wajah, leher, dada dan punggung yang salah satunya disebabkan oleh bakteri. Salah satu bahan yang memiliki aktivitas antibakteri yaitu minyak lengkuas merah. Minyak atsiri diperoleh dengan cara distilasi uap-air. Penelitian ini bertujuan untuk mengetahui kandungan kimia minyak atsiri lengkuas merah Alpinia purpurata (Zingiberaceae) dan formulasi krim dari minyak atsiri lengkuas merah sebagai krim anti jerawat. Sediaan krim dipilih karena merupakan sistem emulsi yang mudah dioleskan dengan tekstur yang lembut dan dapat digunakan pada bagian kulit yang luas dan berfungsi sebagai pelindung yang baik bagi kulit. Minyak atsiri diformulasikan dalam sediaan krim dengan perbandingan konsentrasi minyak atsiri F1(0 persen), F2 (2,5persen), F3 (5persen), F4 (10persen). Minyak atsiri lengkuas merah diuji sifat fisik meliputi warna, bau, rendemen, berat jenis, indeks bias serta dianalisis menggunakan GC-MS. Berdasarkan hasil GC-MS minyak lengkuas merah didominasi oleh senyawa Beta-sesquiphellandrene dan Beta-bisabolene yang merupakan golongan terpenoid. Evaluasi sediaan krim meliputi pemeriksaan organoleptis seperti bau, warna, bentuk serta pengujian daya sebar, daya serap, homogenitas, pH, dan antibakteri. Hasil evaluasi sediaan krim menunjukkan sediaan homogen, pH sesuai dengan pH kulit, daya sebar yaitu meningkat untuk setiap penambahan beban. Kata kunci: Alpinia purpurata, minyak atsiri, formulasi, krim anti jerawat
痤疮是一种由细菌引起的面部、颈部、胸部和背部皮肤炎症性疾病。抗菌活性的一种成分是红姜黄油。蒸馏油是通过蒸馏的方式获得的。这项研究的目的是确定洋甘菊回避油(Zingiberaceae)的化学成分,以及一种抗痤疮油的奶油配方。选择剂型霜是因为它是一种易于涂抹于软组织中的乳液系统,可以用于皮肤的宽阔区域,可以作为皮肤的良好保护。atsiri油在剂型中通过比较atsiri油浓度(0.0%)、F2(2,5%)、F3(5%)、F4(10%)等来确定。红色挥发油测试了物理性质,包括颜色、气味、修饰性、密度、偏振光指数和GC-MS分析。根据gc剂型评估包括气味、颜色、形状和测试散热、吸收能力、同质、pH和抗菌等有机缺陷。剂型评价结果显示,同质性上皮pH值对应于皮肤pH值,即每次增加负荷的释放力增加。关键词:苹果籽油、止疼药油、配方、止疼药霜
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引用次数: 4
期刊
Indonesian Journal of Chemical Research
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