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Arc-Welding: Lithium-Containing Aluminum Alloys 电弧焊:含锂铝合金
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000442
V. Ryazantsev, V. Fedoseev
The development of structures in the aerospace industry is associated mainly with the application of advanced methods and new technologies. Promising metals include alloys containing lithium (the lightest metal, its density is 543 kg/m3). The use of these alloys in welded structures reduces the weight by 20–25% in comparison with structures produced using conventional aluminium alloys such as D16, V95, etc. This article shows that alloys of aluminium with lithium of all alloying systems have metallurgical and technological special features which must be taken into account when producing welded sections by fusion welding.
航空航天工业中结构的发展主要与先进方法和新技术的应用有关。有前途的金属包括含锂的合金(最轻的金属,其密度为543千克/立方米)。在焊接结构中使用这些合金,与使用传统铝合金(如D16、V95等)生产的结构相比,重量减轻了20-25%。本文指出,所有合金体系的铝锂合金都有冶金和工艺上的特点,在采用熔焊生产焊接断面时必须考虑到这些特点。
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引用次数: 0
Graphene-Reinforced Aluminum Matrix Nanocomposites: Structure and Properties 石墨烯增强铝基纳米复合材料:结构与性能
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000218
Shaojiu Yan, Xiang Chen, Q. Hong, Nan Wang, Xiuhui Li, Shuang-Hui Zhao, Wenzhen Nan, Xiaoyan Zhang, S. Dai, Z. Lin
Graphene materials with excellent mechanical and physical properties as well as two-dimensional flexible morphology are attractive reinforcement nanofillers for aluminum matrix nanocomposites. Rapid progress in graphene materials and nanocomposites fabricating technology promotes the development of advanced graphene-reinforced aluminum matrix nanocomposites for structural and functional applications. Nevertheless, the dispersion of graphene nanofillers within aluminum matrix and the interfacial controlling between them remain long-standing challenges in the fabrication of graphene-reinforced aluminum matrix nanocomposites. This article focuses on the recent development of the fabrication and characterization of graphene-reinforced aluminum matrix nanocomposites, including the dispersion and consolidation technology of graphene-reinforced aluminum matrix nanocomposites as well as their structural characters and mechanical behaviors.
石墨烯材料具有优异的力学和物理性能以及二维柔性形态,是铝基纳米复合材料中极具吸引力的增强纳米填料。石墨烯材料和纳米复合材料制造技术的快速发展促进了先进的石墨烯增强铝基纳米复合材料的结构和功能应用。然而,石墨烯纳米填料在铝基内的分散和它们之间的界面控制仍然是石墨烯增强铝基纳米复合材料制备中的长期挑战。本文重点介绍了石墨烯增强铝基纳米复合材料的制备和表征的最新进展,包括石墨烯增强铝基纳米复合材料的分散和固结技术以及其结构特性和力学行为。
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引用次数: 0
Heat-Treatable Aluminum Alloys: Three-Point Bending 热处理铝合金:三点弯曲
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000225
I. Westermann, G. Gruben
In many applications within the automotive industry, the formability of sheets or extruded material is of great importance. The formability is strongly influenced by the chemical composition and the thermomechanical treatment prior to deformation. Grain size and morphology as well as texture and the presence of constituent particles make the material heavily anisotropic and the properties direction dependent. In all cases, shear band formation leads to surface topography during bending, and fracture initiates from the grooves. The crack propagation after initiation is, however, dependent on the grain size and the number and distribution of particles.
在汽车工业的许多应用中,板材或挤压材料的成形性非常重要。成形性受化学成分和变形前热处理的强烈影响。晶粒尺寸和形貌以及织构和组成颗粒的存在使材料具有很强的各向异性和性能方向依赖性。在所有情况下,在弯曲过程中,剪切带的形成导致了表面形貌,裂缝从沟槽开始。裂纹萌生后的扩展与晶粒尺寸、颗粒的数量和分布有关。
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引用次数: 0
Microstructural Evolution During Solution Treatment of ADC12 (A383) Alloy Die Castings ADC12 (A383)合金压铸件固溶处理过程中的组织演变
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000322
Gil-Yong Yeom, Ghasem Eisaabadi Bozchaloei, H. Lim, S. K. Kim, Y. Yoon, S. Hyun, N. Netto, M. Tiryakioğlu
High-pressure die casting (HPDC) components are known to be not heat treatable due to the formation of unacceptable surface blisters, dimensional instability, and poor mechanical properties during conventional solution treatment, such as at 540°C for 8 h. In the present study, the possibility of solution treating a recycled ALDC12 HPDC alloy at temperatures less than 500°C and with shorter solution treatment times was investigated. HPDCs with thickness of 2 and 3 mm were solution treated at 490°C for various times ranging from 15 to 180 min. Microstructural evolution during solution treatment was examined by various techniques, including metallography, energy dispersive spectrometry, electrical conductivity, and X-ray diffraction. Results indicated that almost all of the Al2Cu intermetallics were dissolved within 90 min of solution treatment. The coarsening of eutectic Si particles was found to follow the Lifshitz–Slyozov–Wagner theory with two distinct regimes. Furthermore, measurements of Cu concentration within α-Al dendrites revealed that the diffusion of Cu atoms in α-Al phase is not the primary limiting factor for homogenization of the alloy. Most importantly, no blisters were observed at the surface of the castings. Therefore, this heat treatment can be used for HPDC components from ALDC12 alloy at a reasonable time.
众所周知,高压压铸(HPDC)部件在常规固溶处理(如540°C固溶8小时)过程中会形成不可接受的表面水泡、尺寸不稳定以及机械性能差,因此无法热处理。在本研究中,研究了在低于500°C的温度下,用更短的固溶处理时间对再生ALDC12 HPDC合金进行固溶处理的可能性。厚度为2和3mm的HPDCs在490°C下固溶处理15至180分钟。通过各种技术,包括金相、能量色散光谱、电导率和x射线衍射,研究了固溶处理过程中的微观结构演变。结果表明,在固溶处理90 min内,Al2Cu金属间化合物几乎全部溶解。发现共晶Si颗粒的粗化遵循Lifshitz-Slyozov-Wagner理论,具有两种不同的机制。此外,α-Al枝晶内Cu浓度的测定表明,Cu原子在α-Al相中的扩散并不是合金均匀化的主要限制因素。最重要的是,在铸件表面没有观察到水泡。因此,可以在合理的时间对ALDC12合金的HPDC部件进行这种热处理。
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引用次数: 0
Corrosion and Wear Protection through Micro Arc Oxidation Coatings in Aluminum and Its Alloys 铝及其合金微弧氧化涂层的腐蚀和磨损保护
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000207
L. Krishna, G. Sundararajan
This article presents the brief overview of fairly recent and eco-friendly micro arc oxidation (MAO) coating technology. The weight-cost-performance benefits in general raised the interest to utilize lightweight materials, especially the aluminum and its alloys. Despite numerous engineering advantages, the aluminum alloys themselves do not possess suitable tribology and corrosion resistance. Therefore, improvements in surface properties are essential to enable developing potential industrial applications. For improving wear and corrosion resistance of Al alloys, the most demanding surface properties are high hardness and chemical inertness. The technical and technological limitations associated with traditional anodizing and hard anodizing processes have been the strongest driving force behind the development of new MAO technology. While presenting the key technological elements associated with the MAO process, the basic mechanism of coating formation and its phase gradient nature is presented. Influence of various process parameters including the electrolyte composition has been discussed. The typical microstructural features and distribution of α- and γ-Al2O3 phases across the coating thickness as a key strategy to form dense coatings with required mechanical, tribological, and corrosion properties which are vital to meet potential application demands are briefly illustrated.
总体而言,重量-成本-性能的好处引起了人们对使用轻质材料的兴趣,特别是铝及其合金。尽管有许多工程上的优势,铝合金本身不具备适当的摩擦学和耐腐蚀性。因此,改善表面性能对于开发潜在的工业应用至关重要。为了提高铝合金的耐磨性和耐腐蚀性,对其表面性能要求最高的是高硬度和化学惰性。与传统阳极氧化和硬阳极氧化工艺相关的技术和工艺限制一直是新阳极氧化技术发展背后的最强大推动力。讨论了电解液组成等工艺参数的影响。简要说明了α-和γ-Al2O3相在涂层厚度上的典型微观结构特征和分布,这是形成具有所需机械、摩擦学和腐蚀性能的致密涂层的关键策略,对满足潜在的应用需求至关重要。
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引用次数: 0
Steel: Aluminum Coatings 钢:铝涂层
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000391
A. Bahadur
Aluminum coated steel possesses excellent oxidation and corrosion resistance in sulfur and marine: environments and can substitute for expensive alloy of steels. Hot dip aluminizing (HDA) and pack cementation calorizing (CAL) are dealt with in detail. IN HDA coats, some alloying action takes place, when the substrate is dipped in molten Al at 973 K for 1–2 minutes. The coat consists of an outer pure Al layer, followed by a hard intermetallic layer consisting of FeAl3 and Fe2Al5, forming a serrated interface with the base. Isothermal holding of such samples at 773–933 K for 10 minutes leads to further diffusion and phase changes. This improves resistance to thermal shock and bending. In CAL coats, the process parameters (1173–1223 K/2–4 h and pack composition), were optimized, resulting in appreciable alloying. The surface layer consists of Fe3Al and FeAl, which is comparable to the inner alloy layer of HDA coats. The structure/ property correlation is carried out for both coatings and the results compared.
铝包覆钢在硫和海洋环境中具有优良的抗氧化和耐腐蚀性能,可以代替昂贵的合金钢。详细讨论了热浸渗铝(HDA)和填料胶结加热(CAL)。在HDA涂层中,当衬底在973 K的熔融Al中浸泡1-2分钟时,会发生一些合金化作用。涂层外层为纯Al层,其次是由FeAl3和Fe2Al5组成的硬金属间层,与基体形成锯齿状界面。在773-933 K下等温保温10分钟会导致进一步的扩散和相变。这提高了对热冲击和弯曲的抵抗力。在CAL涂层中,优化了工艺参数(1173-1223 K/ 2-4 h和包料成分),得到了明显的合金化效果。表层由Fe3Al和FeAl组成,与HDA涂层的内合金层相当。对两种涂层进行了结构/性能对比,并对结果进行了比较。
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引用次数: 0
Corrosion Protective Coatings: Fabrication of Sputtered CeO2-La2O3 and La2O3-CeO2 Bilayers 防腐蚀涂层:溅射CeO2-La2O3和La2O3-CeO2双层膜的制备
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000216
Domínguez-Crespo Miguel Antonio, Brachetti-Sibaja Silvia, Torres-Huerta Aidé, Onofre Edgar, L. Ana, Rodil Sandra
This entry provides a comparative study on the corrosion protection efficiency of Ce, La films as well as Ce/La- and La/Ce-bilayered coatings deposited onto AA7075 and AA6061 substrates by the radio frequency magnetron sputtering technique. The coating thickness ranged from ~12 to 835 nm, which changed with the deposition parameters and substrate composition. The relationship between microstructure, roughness, and electrochemical performance is examined. The reactivity and crystallinity of rare earth (RE) films can be tailored by adjusting the sputtering parameters. Sputtered La films with a thickness of ~390 nm and an average roughness of 66 nm showed the best corrosion protection properties in chloride medium as determined by potentiodynamic curves and electrochemical impedance spectroscopy. The method to obtain RE-bilayered coatings, i.e., La/Ce or Ce/La as well as the substrate composition and applied power, conditioned their inhibition properties. The RE-bilayered coatings displayed better barrier properties than Ce films, which were worser than those featured by La films.
本文对比研究了采用射频磁控溅射技术在AA7075和AA6061基体上沉积Ce、La膜以及Ce/La-和La/Ce双层涂层的防腐效果。涂层厚度随沉积参数和衬底成分的变化而变化,范围为~12 ~ 835 nm。研究了微结构、粗糙度和电化学性能之间的关系。通过调整溅射参数,可以调整稀土薄膜的反应性和结晶度。电势动力学曲线和电化学阻抗谱分析表明,厚度为~390 nm、平均粗糙度为66 nm的溅射La膜在氯离子介质中的防腐性能最好。获得re双层涂层的方法,即La/Ce或Ce/La,以及衬底成分和施加功率,决定了它们的缓蚀性能。re -双层膜的阻隔性能优于Ce膜,而La膜的阻隔性能较差。
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引用次数: 0
Tube Bending Forming Technologies: Advances and Trends 管材弯曲成形技术:进展与趋势
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000210
Li Heng, Yang He, M. jun.
Bent tube parts have been widely used, as one kind of key components with enormous quantities and diversities, to satisfy the increasing demands for lightweight and high-performance products in broad industries such as aerospace, marine, automobile, energy, and health care. Tube bending is one of the key technologies used for manufacturing these lightweight products. The recent advances in tube bending are critically reviewed from four fundamental issues in tube bending, viz. characterization of tubular materials, prediction of multiple defects, bending formability, and innovative optimization design. Advantages and limitations of some recently developed innovative bending approaches are reviewed. Finally, considering the urgent requirements of more lightweight and high-performance bent tubes with hard-to-deform materials with complex structures, the development trends and corresponding challenges are thereafter presented for realizing the precision and high-efficiency tube bending.
弯管件作为一种数量庞大、种类繁多的关键零部件,在航空航天、船舶、汽车、能源、医疗等广泛的行业中得到了广泛的应用,以满足日益增长的产品轻量化和高性能的需求。弯管是制造这些轻量化产品的关键技术之一。从管材弯曲的四个基本问题,即管状材料的表征、多缺陷预测、弯曲成形性和创新优化设计等方面综述了管材弯曲的最新进展。综述了近年来发展起来的一些新型弯曲方法的优点和局限性。最后,针对材料难变形、结构复杂的弯管对轻量化、高性能的迫切要求,提出了实现精密、高效弯管的发展趋势和挑战。
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引用次数: 1
Porosity in Aluminum Welds 铝焊件中的孔隙率
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000429
M. Mazur
Porosity constitutes the main defect in aluminium welds. It is generally assumed that the basic reason for its formation is the presence of hydrogen. Hydrogen can originate from a variety of sources. Major sources of hydrogen are surface contamination of both the parent and deposited metals in the form of hydroxides, hydrocarbons or oxides with adsorbed moisture. Another source of hydrogen can be impurity of the gas shield associated with either moisture or air sucked into the arc atmosphere if an incorrect welding procedure is adopted. It has been found that even 2 ppm of hydrogen in the molten metal, or 250 ppm of hydrogen in the gas shield can be sufficient to produce porosity in aluminium welds.
气孔是铝焊缝的主要缺陷。一般认为它形成的基本原因是氢的存在。氢的来源多种多样。氢的主要来源是母体和沉积金属的表面污染,其形式是氢氧化物、碳氢化合物或具有吸附水分的氧化物。如果采用不正确的焊接工艺,氢气的另一个来源可能是与吸进电弧气氛的湿气或空气有关的气体保护的杂质。已经发现,即使在熔融金属中含有2ppm的氢,或在气体保护中含有250ppm的氢,也足以在铝焊缝中产生气孔。
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引用次数: 2
Electron Backscatter Diffraction 电子背散射衍射
Pub Date : 2018-11-16 DOI: 10.1201/9781351045636-140000410
D. Field, Mukul Kumar
Electron backscatter diffraction (EBSD) is a scanning electron microscope (SEM) based technique that is used to obtain local information on the crystallographic character of bulk crystalline and polycrystalline materials. Topics discussed in this article include: EBSD system overview, multiphase analysis, and application to aluminum integrated circuit interconnects, dislocation structure analysis, analysis of grain boundary networks, and application to friction stir welding of aluminum alloys.
电子背散射衍射(EBSD)是一种基于扫描电子显微镜(SEM)的技术,用于获得块状晶体和多晶材料的晶体学特征的局部信息。本文讨论的主题包括:EBSD系统概述、多相分析及其在铝集成电路互连中的应用、位错结构分析、晶界网络分析以及在铝合金搅拌摩擦焊接中的应用。
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引用次数: 12
期刊
Encyclopedia of Aluminum and Its Alloys
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