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Superconducting Bi(2223) thick film on Ba2HoNbO6: a new perovskite ceramic substrate Ba2HoNbO6上的超导Bi(2223)厚膜:一种新的钙钛矿陶瓷衬底
Pub Date : 2003-08-01 DOI: 10.1179/096797803225004945
S. Nair, P. Warriar, J. Koshy
Abstract Barium holmium niobate Ba2HoNbO6 (BHNO) has been developed as a new substrate for (Bi,Pb)2Sr2Ca2Cu3Ox (Bi(2223)) superconductor film. Ba2HoNbO6 has a cubic perovskite structure with lattice constant a = 8·26 Å. The dielectric constant and loss factor of this material are in a range suitable for its use as a substrate for microwave applications. The Bi(2223) superconductor shows no detectable chemical reaction with BHNO, even under extreme processing conditions. Dip coated Bi(2223) thick film on Ba2HoNbO6 substrate had T c(0) of 109 K and current density of around 4 × 103 A cm - 2 at 77 K and in zero magnetic field.
摘要:研究了铌酸钡(Ba2HoNbO6, BHNO)作为(Bi,Pb)2Sr2Ca2Cu3Ox (Bi(2223))超导体薄膜的新型衬底材料。Ba2HoNbO6具有立方钙钛矿结构,晶格常数a = 8·26 Å。这种材料的介电常数和损耗系数在一个范围内,适合作为微波应用的衬底。即使在极端的加工条件下,Bi(2223)超导体也不会与BHNO发生可检测到的化学反应。在Ba2HoNbO6衬底上浸镀Bi(2223)厚膜,在77 K和零磁场条件下,tc(0)为109 K,电流密度约为4 × 103 A cm - 2。
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引用次数: 0
Dielectric properties of [(Pb1 - xSrx)O.TiO2)]-[2SiO2.B2O3]-[K2O] glass ceramics [(Pb1 - xSrx)O.TiO2)]-[2SiO2的介电性能B2O3 -[K2O]玻璃陶瓷
Pub Date : 2003-08-01 DOI: 10.1179/096797803225004990
A. Sahu, D. Kumar, O. Parkash, O. P. Thakur, C. Prakash
Abstract Dielectric properties of glass ceramics prepared in the [(Pb1 - xSrx)O.TiO2)]- [2SiO2.B2O3]-[K2O] system have been studied. The Curie temperature of crystalline phases has been found to decrease with decreasing Pb2+/Sr2+ ratio in the initial glass. This adds support to the authors' previous findings from XRD peak intensity studies suggesting that the crystallites are in solid solution in the system (Pb1 - xSrx)TiO3.
[(Pb1 - xSrx)O.TiO2)]- [2SiO2制备玻璃陶瓷的介电性能。研究了B2O3 -[K2O]体系。随着初始玻璃中Pb2+/Sr2+比例的降低,晶相的居里温度降低。这进一步支持了作者之前从XRD峰强度研究中得出的结论,即晶体在(Pb1 - xSrx)TiO3体系中处于固溶体状态。
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引用次数: 11
Crystallisation of lead strontium titanate perovskite phase in [(Pb1-xSrx)O.TiO2]- [2SiO2.B2O3]-[K2O] glass ceramics 钛酸铅锶钙钛矿相在[(Pb1-xSrx)O中的结晶。二氧化钛]-[2二氧化矽。B2O3 -[K2O]玻璃陶瓷
Pub Date : 2003-08-01 DOI: 10.1179/096797803225004981
A. Sahu, D. Kumar, O. Parkash
Abstract The crystallisation of lead strontium titanate solid solution phase in glass ceramics in the [(Pb1 - xSrx)O.TiO2] - [2SiO2.B2O3]-[K2O]system (x = 0, 0·1, 0·2, 0·3, 0·4) has been studied. Perovskite titanate was found to be the major phase in all samples investigated. The actual composition of the crystallites developed could not be confirmed on the basis of shifts in the XRD peak positions with changing Pb2+/Sr2+ ratio, because of similar effects due to solid solution and strain resulting from crystal clamping. Comparison of the observed intensities of the perovskite titanate phase with calculated intensities for (Pb1 - xSrx)TiO3 ceramics with the same lead/strontium ratios confirmed the formation of lead strontium titanate solid solution.
摘要研究了钛酸锶铅固溶相在[(Pb1 - xSrx)O中在玻璃陶瓷中的结晶。TiO2] - [2SiO2。研究了B2O3 -[K2O]体系(x = 0,0,1,0,2,0,3,0,4)。钛酸钙钛矿是所有样品的主要相。随着Pb2+/Sr2+比值的变化,XRD峰位的变化无法确定形成的晶体的实际组成,因为固溶体和晶体夹紧产生的应变的影响相似。将观察到的钛酸钙钛矿相强度与相同铅/锶比的(Pb1 - xSrx)TiO3陶瓷的计算强度进行比较,证实了钛酸铅锶固溶体的形成。
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引用次数: 19
Variability study of incinerated sewage sludge ash in relation to future use in ceramic brick manufacture 焚烧污泥灰分的变异性研究与未来在陶瓷砖制造中的应用
Pub Date : 2003-06-01 DOI: 10.1179/096797803225001614
M. Anderson, R. Skerratt
Abstract The prospective use of incinerated sewage sludge ash (ISSA) as a partial replacement for traditional brick-making materials has been previously reported. However, variability in the consistency of the raw materials used in commercial brick manufacture can cause serious production problems. Consequently, to gain market confidence for ISSA in this role, it is essential to establish that its quality is not detrimentally affected either by the nature of the sewage sludge being burned, or as a result of the performance of the incineration process itself. Ash sampling was conducted at a large modern commercial sewage sludge incinerator over a six week period, followed by property characterisation and ceramic evaluation. The results confirm that this source of ISSA is satisfactorily consistent in quality over time, thus verifying its potential for use in brick manufacture on a commercial basis. Recommendations for additional research to help ensure widespread acceptance are also discussed.
焚烧污水污泥灰(ISSA)作为传统制砖材料的部分替代品的前景已经有报道。然而,在商业砖生产中使用的原料稠度的变化会导致严重的生产问题。因此,为了获得市场对ISSA发挥这一作用的信心,必须确定其质量不会受到正在燃烧的污水污泥的性质或焚烧过程本身的性能的不利影响。在一个大型现代商业污水污泥焚烧炉进行了为期六周的灰采样,随后进行了特性表征和陶瓷评估。结果证实,这种ISSA来源的质量随时间的推移是令人满意的,从而验证了它在砖制造的商业基础上使用的潜力。本文还讨论了进一步研究以确保广泛接受的建议。
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引用次数: 48
Structural characterisation of organosiloxane membranes 有机硅氧烷膜的结构表征
Pub Date : 2003-06-01 DOI: 10.1179/096797803225004918
G. West, G. Diamond, N. Dajda, Mark E. Smith, M. Lewis
Abstract A sol-gel polymerisation/pyrolysis route has been used to produce hybrid organic-inorganic membranes. This route involved the copolymerisation of two organo-functional precursors, methyltrimethoxysilane and phenyltrimethoxysilane or diphenyldimethoxysilane. The thermal stability and structural evolution with temperature of the resulting xerogels were investigated using multinuclear solid state NMR (13C and 29Si), thermal analysis (TGA and DTA), and FTIR. It is shown that during pyrolysis the methyl ligand is replaced with hydroxyl groups, some of which condense into siloxane linkages. The retained hydroxyl groups are thought to provide adsorption sites throughout the material onto which polar gas molecules (such as CO2) can adsorb, and diffuse under a pressure gradient. This hypothesis is supported by the results of gas permeation trials on the membranes, and thus a direct link is established between membrane performance and material structure.
摘要采用溶胶-凝胶聚合/热解的方法制备了有机-无机杂化膜。这条路线涉及两种有机功能前体,甲基三甲氧基硅烷和苯基三甲氧基硅烷或二苯基二甲氧基硅烷的共聚。采用多核固体核磁共振(13C和29Si)、热分析(TGA和DTA)和红外光谱(FTIR)研究了所制干凝胶的热稳定性和结构随温度的变化。结果表明,在热解过程中,甲基配体被羟基取代,其中一些羟基凝聚成硅氧烷键。保留的羟基被认为在整个材料中提供了吸附点,极性气体分子(如CO2)可以吸附在上面,并在压力梯度下扩散。这一假设得到了膜上气体渗透试验结果的支持,从而建立了膜性能与材料结构之间的直接联系。
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引用次数: 7
1st Annual Biomaterials Workshop 第一届年度生物材料研讨会
Pub Date : 2003-06-01 DOI: 10.1179/096797803765763025
Delegates were welcomed to the workshop by the Head of the Department of Materials and Medical Sciences at Cranfield, Professor Cliff Friend, and by the founder and President of the ABW Council, Susan Essien Etok. The morning session began with a comprehensive description of conventional and new systems for dental restorative materials by Professor Peter Marquis (University of Birmingham). He argued convincingly that finding alternatives to metallic amalgams is a high technology challenge and described the potential benefits of newly developed nanoparticulates in providing the material quality and aesthetics required. Professor Andrew Lloyd (Universit y of Brighton) then presented an intriguing method for enhancing osseointegration through exploitation of part of the natural mineralisation process. In particular the role of calcium-binding phospholipids within matrix vesicles was described and Professor Lloyd showed how such lipids can, in vitro, selfassemble into three-dimensional gels that may provide a suitable environment for rapid calcification. Fabrication routes to produce apatite coatings were expertly discussed by Dr David Grant (Universit y of Nottingham). In particular, coatings formed by plasma spraying and laser ablation were compared with respect to their chemistry, surface topography and cell interaction. Dr Grant emphasised the need to apply absorption corrections in diffraction measurements of crystallinit y and pointed out the lack of any ASTM methodology in this respect. Subsequently, Dr Jonathon Knowles provided a persuasive description of the use of phosphate based glasses as biomaterials, and explained how the solubility of such materials can be significantly modified Hosted by Cranfield University (Shrivenham campus, UK) on 17 March 2003, this workshop was the inaugural event in what is intended to become a series of such meetings. The workshop, designed particularly to introduce new researchers to more established workers in the field and to present research in new and emerging areas, attracted more than 80 delegates from as far away as Spain and Belgium. 1st Annual Biomaterials Workshop
克兰菲尔德大学材料和医学科学系主任Cliff Friend教授和ABW理事会创始人兼主席Susan Essien Etok教授欢迎代表们参加讲习班。上午的会议以Peter Marquis教授(伯明翰大学)对牙科修复材料的传统和新系统的全面描述开始。他令人信服地指出,寻找金属汞合金的替代品是一项高科技挑战,并描述了新开发的纳米颗粒在提供所需的材料质量和美学方面的潜在好处。Andrew Lloyd教授(布莱顿大学)随后提出了一种有趣的方法,通过利用部分自然矿化过程来增强骨整合。特别是钙结合磷脂在基质囊泡中的作用,劳埃德教授展示了这些脂质如何在体外自组装成三维凝胶,这可能为快速钙化提供合适的环境。David Grant博士(诺丁汉大学)专门讨论了生产磷灰石涂层的制造路线。特别地,比较了等离子喷涂和激光烧蚀形成的涂层的化学性质、表面形貌和细胞相互作用。Grant博士强调了在结晶性的衍射测量中应用吸收校正的必要性,并指出在这方面缺乏任何ASTM方法。随后,Jonathon Knowles博士对磷酸盐基玻璃作为生物材料的使用进行了有说服力的描述,并解释了如何显著改变这些材料的溶解度。该研讨会于2003年3月17日由克兰菲尔德大学(英国Shrivenham校区)主办,是一系列此类会议的首次活动。该研讨会的目的是将新的研究人员介绍给该领域更成熟的工作人员,并展示新兴领域的研究成果,吸引了80多名来自远至西班牙和比利时的代表
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引用次数: 0
Effect of Cr2O3 on sinterability and properties of mullite-spinel composites Cr2O3对莫来石-尖晶石复合材料烧结性能的影响
Pub Date : 2003-06-01 DOI: 10.1179/096797803225004936
M. Zawrah
Abstract Seven mixes of mullite-spinel composites composed of 100:0, 80:20, 60:40, 50:50, 40:60, 20:80, and 0:100 wt-% of presynthesised mullite and magnesium aluminate (MA) spinel were prepared and fired up to 1550°C for 2 h. The phase compositions of the fired mixes were investigated using X-ray diffractometry. The physical, mechanical, and refractory properties of the fired composite batches were determined according to DIN standard specifications. The two mixes containing 40 and 20 wt-% mullite with 60 and 80 wt-% MA spinel were considered as optimum mixes, since they combined better physical, mechanical, and refractory properties than the other compositions. Additions of 2 wt-%Cr2O3 to both mixes resulted in further improvements in physical and mechanical properties after firing at 1550°C owing to its solid solution in mullite and spinel.
制备了重量为100:0、80:20、60:40、50:50、40:60、20:80和0:100 wt-%的莫来石-尖晶石复合材料,并在1550℃下烧制2 h,用x射线衍射仪研究了煅烧后混合物的物相组成。燃烧后的复合材料批次的物理、机械和耐火性能根据DIN标准规范进行测定。这两种混合物分别含有40%和20%重量%的莫来石和60%和80%重量%的MA尖晶石,被认为是最佳混合物,因为它们比其他组合物具有更好的物理、机械和耐火性能。在这两种混合物中添加2wt -%的Cr2O3,由于其在莫来石和尖晶石中的固溶体,在1550°C烧制后,其物理和机械性能得到进一步改善。
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引用次数: 5
Application of sodium alginate gelation to aqueous tape casting 海藻酸钠凝胶在水性铸带中的应用
Pub Date : 2003-06-01 DOI: 10.1179/096797803225004927
Z. Yu, Yi Huang, Caams Wang, X. Cui, S. Ouyang
Abstract A novel gel tape casting process has been developed by introducing sodium alginate into a conventional aqueous tape casting slurry. The process makes use of a binder system consisting of 1 wt-% sodium alginate and 20 vol.-% styrene acrylic latex to prepare the tape casting slurry. Sodium alginate can react with calcium iodate to form a three-dimensional network at room temperature, and with the ceramic particles held in this three-dimensional network, the slurry can be consolidated to form green tapes. This allows the need for the special drying procedure that is usually a critical step in tape casting to be avoided. Styrene acrylic latex was used to improve the flexibility of the green tapes. Compared with tapes obtained by conventional aqueous tape casting, more homogeneous microstructure was obtained by this process.
摘要:将海藻酸钠引入常规水性胶带浇注浆中,开发了一种新型的凝胶胶带浇注工艺。该工艺使用由1 wt %海藻酸钠和20 vol. %苯乙烯-丙烯酸胶乳组成的粘合剂系统来制备胶带浇注浆。海藻酸钠可以在室温下与碘酸钙反应形成三维网络,并且在这个三维网络中的陶瓷颗粒可以使浆液固结形成绿带。这允许需要特殊的干燥程序,通常是在胶带铸造的关键步骤,以避免。采用苯乙烯丙烯酸胶乳提高绿色胶带的柔韧性。与传统的水铸带工艺相比,该工艺获得了更加均匀的组织。
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引用次数: 0
Effect of pores on flexural strength of roofing tiles at low temperature 孔隙对屋面瓦低温抗弯强度的影响
Pub Date : 2003-06-01 DOI: 10.1179/096797803225001623
Hyungsun Kim, J. H. Kim, K. Ikeda
Abstract To understand freezing in roofing tiles at low temperature with the aim of preventing frost damage, the effects of microstructure, pore size, porosity, and pore distribution on flexural strength at low temperature were studied. Strength was determined by four point bending tests at room temperature and low temperatures of -10, -30, and -50°C. Porosity and pore size distribution affected low temperature strength, and freezing time and temperature showed a close correlation with strength. A relationship between porosity P and flexural strength S at low temperature ( -10, -30°C) was found, given by S = S0 exp (-bP), where S0 = 49-58 MPa and b = 4·7-7·4. With a decreasing frozen temperature in the range -10 to -50°C, flexural strength increased, and tiles with lower porosity showed higher strength.
摘要为了解屋面瓦在低温下的冻结情况,以防止冻损为目的,研究了屋面瓦的微观结构、孔隙大小、孔隙率和孔隙分布对屋面瓦低温抗弯强度的影响。通过室温和-10、-30和-50℃低温下的四点弯曲试验来确定强度。孔隙率和孔径分布影响低温强度,冻结时间和温度与强度密切相关。低温(-10℃、-30℃)下,孔隙率P与抗折强度S的关系为S = S0 exp (-bP),其中S0 = 49 ~ 58 MPa, b = 4.7 ~ 7.4。在-10 ~ -50℃范围内,冻结温度越低,抗折强度越高,孔隙率越低,抗折强度越高。
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引用次数: 3
Velocity of elastic waves in porous ceramic materials: influence of pore structure 多孔陶瓷材料中弹性波的速度:孔隙结构的影响
Pub Date : 2003-06-01 DOI: 10.1179/096797803225001641
B. O. Aduda, A. Boccaccini
Abstract A review has been undertaken of recently published data on ultrasonic velocity-porosity for a variety of porous ceramic materials, including information on pore structure. These experimental data have been compared with data calculated using a spheroidal pore model incorporating information on pore volume fraction, shape, and orientation. Good agreement is obtained between experimental and calculated values, especially when fractional porosity is less than about 0·25, even when a single 'effective' pore shape is employed in the calculation. The agreement improves if a different pore shape for each porosity level (point by point analysis) is used. The predictive ability of the spheroidal pore model is thus demonstrated.
摘要对近年来发表的各种多孔陶瓷材料的超声速度-孔隙率数据进行了综述,包括孔隙结构的信息。将这些实验数据与使用包含孔隙体积分数、形状和方向信息的球体孔隙模型计算的数据进行了比较。实验值与计算值吻合良好,特别是当分数孔隙率小于0.25时,即使在计算中采用单一的“有效”孔隙形状。如果对每个孔隙度级别使用不同的孔隙形状(逐点分析),则一致性会提高。从而证明了球形孔隙模型的预测能力。
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引用次数: 4
期刊
British Ceramic Transactions
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