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Effect of alumina addition on properties of glass/ceramic composite 氧化铝对玻璃/陶瓷复合材料性能的影响
Pub Date : 2003-10-01 DOI: 10.1179/174327613X13789817049900
A. El-Kheshen
Abstract A series of glass/ceramic composites were prepared from pyrex borosilicate glass with silica. The effects of 15 vol.-% alumina addition on cristobalite formation in this system have been studied. Cristobalite formation in the composites has been found to decrease with addition of alumina, which may be attributed to a strong coupling reaction between Al3+ from alumina and K+ from pyrex borosilicate glass. The resulting glass/ceramic composites containing alumina have low thermal expansion coefficient owing to the presence of a lower amount of cristobalite in the glass matrix. The formation of cristobalite limits the efficiency of the ceramic substrate when used in circuit boards.
摘要以热硼硅酸盐玻璃为原料,用二氧化硅制备了一系列玻璃/陶瓷复合材料。研究了在该体系中添加15%体积-%氧化铝对方石云石形成的影响。复合材料中方石石的形成随着氧化铝的加入而减少,这可能是由于氧化铝中的Al3+与热硼硅酸盐玻璃中的K+发生了强烈的偶联反应。所得到的含氧化铝的玻璃/陶瓷复合材料具有较低的热膨胀系数,这是由于在玻璃基体中存在较少量的方石英。方石英的形成限制了用于电路板的陶瓷基板的效率。
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引用次数: 9
Combustion synthesis, powder treatment, dispersion and tape casting of lanthanum strontium manganite 镧锶锰酸盐的燃烧合成、粉末处理、分散和带状铸造
Pub Date : 2003-10-01 DOI: 10.1179/174327613X13789817049865
M. Kakade, S. Ramanathan, P. De
Abstract Lanthanum strontium manganite La0·84Sr0·16MnO3 (LSM)powder was prepared by combustion synthesis, using a concentrated solution of nitrates of lanthanum, strontium, and manganese as oxidiser, and citric acid as fuel. The as formed powder was found to be crystalline LSM consisting of porous agglomerates of fine particles, and exhibited about 7% total weight loss on heating up to 1100 °C. Dispersion conditions for wet grinding of the powder agglomerates calcined at 1100 °C were evaluated from zeta potential and viscositystudies. A maximum zeta potential of - 35 mV was noted at a pH of 11, while pseudoplasticity of the slurry decreased with decreasing solid concentration. Powder with d50 of around 3 μm and free of agglomerates of size greater than 10 μm was formed by wet grinding. Further calci nation of this powder at 1350 °C improved the solids loading in the slurry. The tape cast slurry composition was optimised for minimum content of binder, plasticiser, and water with acceptable pseudoplasticity to form flexible and flat tapes. The dried tapes cut to required sizes were subjected to controlled binder burnout followed by sintering in the range 1350-1450 °C. The sintered flat specimens exhibited densities in the range 65-80% of theoretical, and open porosities in the range 35-20%, with a homogeneous distribution of pore phase in the matrix.
摘要以镧、锶、锰的浓硝酸盐溶液为氧化剂,柠檬酸为燃料,采用燃烧合成法制备了镧锶锰酸盐La0·84Sr0·16MnO3 (LSM)粉体。形成的粉末是由细颗粒的多孔团块组成的结晶LSM,加热到1100℃时,总重量损失约7%。从zeta电位和粘度研究中评估了1100°C煅烧的粉末团块湿法研磨的分散条件。pH = 11时zeta电位最大值为- 35 mV,浆料的假塑性随固体浓度的降低而降低。湿法磨成d50约为3 μm,不含粒径大于10 μm的团聚体的粉体。该粉末在1350℃下进一步煅烧,提高了浆料中的固体负荷。胶带浇铸浆的组成优化为最低含量的粘合剂,增塑剂和水,具有可接受的假塑性,以形成柔性和扁平的胶带。将干燥的胶带切割成所需的尺寸,然后在1350-1450°C范围内进行受控的粘结剂烧尽,然后烧结。烧结平面试样的密度为理论密度的65 ~ 80%,开孔率为35 ~ 20%,孔隙相在基体中分布均匀。
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引用次数: 10
Preparation of nanocrystalline gadolinia doped ceria powders by combustion synthesis process 燃烧合成法制备纳米晶钆掺杂二氧化铈粉末
Pub Date : 2003-10-01 DOI: 10.1179/096797803225005016
R. A. Rocha, E. Muccillo
Abstract Nanocrystalline gadolinia doped ceria powder was prepared by a combustion synthesis process using polyvinyl alcohol as fuel, with the aim of obtaining nanosized crystallites of this solid solution with high specific surface area. The structures of the polymer gel and the calcined materials were investigated by Fourier transform infrared spectroscopy. Residual carbon content and specific surface area determinations were carried out on calcined powders. Microstructural characterisation was done by X-ray diffractometry and scanning electron microscopy. The results demonstrate that nanocrystalline particles of the solid solution can be prepared with low carbon content and high specific surface area by this one step synthesis technique.
摘要以聚乙烯醇为燃料,采用燃烧合成工艺制备了纳米级钆掺杂二氧化铈粉末,目的是获得具有高比表面积的纳米级固溶体。利用傅里叶变换红外光谱研究了聚合物凝胶和煅烧材料的结构。对煅烧后的粉末进行了残余碳含量和比表面积的测定。通过x射线衍射和扫描电镜对其进行了显微结构表征。结果表明,该方法可制备出低碳、高比表面积的固溶体纳米晶颗粒。
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引用次数: 10
Structural and microwave dielectric properties of Sr1-xBaxNb2O6 ceramics at microwave frequencies Sr1-xBaxNb2O6陶瓷在微波频率下的结构和微波介电性能
Pub Date : 2003-10-01 DOI: 10.1179/096797803225005043
J. Yohannan, J. Jacob, A. Lonappan, K. T. Mathew
Abstract Microwave dielectric properties and crystal structure of Sr1-xBaxNb2O6 ceramics (x = 0·39, 0·45, 0·50, 0·55, 0·57, 0·60, 0·65) have been investigated. The microwave cavity perturbation technique was employed for the study of dielectric properties. Parameters such as complex permittivity and conductivity of strontium barium niobate ceramics were determined at the S band by measuring changes in the resonant frequencies and Q values of the cavity resulting from the introduction of the sample. The real part of the complex permittivity of all samples shows an increase with frequency, whereas the imaginary part of permittivity decreases as frequency increases. The effects of composition and sintering temperature on crystal structure and microstructure were studied by X-ray powder diffraction and scanning electron microscopy. Most compositions show preferred orientations along the c axis, as is evident from the relatively high intensity of (001) and (002) peaks. The microstructure contains ferroelectric domainlike structures with increasing barium content.
研究了Sr1-xBaxNb2O6陶瓷(x = 0.39、0.45、0.50、0.55、0.57、0.60、0.65)的微波介电性能和晶体结构。采用微波腔微扰技术对其介电特性进行了研究。通过测量样品引入后谐振腔的谐振频率和Q值的变化,在S波段测定了铌酸锶钡陶瓷的复介电常数和电导率等参数。复介电常数的实部随频率的增加而增大,虚部随频率的增加而减小。采用x射线粉末衍射和扫描电镜研究了成分和烧结温度对晶体结构和显微组织的影响。从(001)和(002)峰相对较高的强度可以明显看出,大多数成分沿c轴表现出优先取向。随着钡含量的增加,其微观结构为铁电畴状结构。
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引用次数: 2
Mechanical properties of short oxide fibre-kaolin clay matrix composites 短氧化纤维-高岭土基复合材料的力学性能
Pub Date : 2003-10-01 DOI: 10.1179/174327613X13789816719141
S. Papargyri, R. G. Cooke, D. Papargyris, A. Botis, G. Papapolymerou, A. D. Papargyris
Abstract A series of short fibre ceramic composites was produced by mixing, slip casting, and sintering kaolin clay with Al2O3 or mullite fibres at various volume contents. Sintering was conducted in air at various temperatures. The resulting composites were characterised with respect to chemical and mineralogical composition, microstructure, and mechanical properties. Sintering above 1200 °C changed the microstructure of kaolin from a weak point bonded structure to a strong dense glass ceramic structure, and changed δ-Al2O3 to α-Al2O3. The addition of oxide fibres to kaolin clay resulted in the formation of ceramic matrix composites, the properties of which depended on sintering temperature, matrix and fibre structures and relative volumes, the properties of the fibre/matrix interface, and fibre length. A relative increase in strength and toughness with incorporation of fibres is achieved with limited additions of fibres, and mainly in the weak point bonded structures. The application of linear elastic fracture mechanics to the examined ceramic matrix composites is also discussed.
摘要采用不同体积含量的Al2O3或莫来石纤维与高岭土混合、滑铸、烧结制备了一系列短纤维陶瓷复合材料。烧结在不同温度的空气中进行。所得到的复合材料在化学和矿物组成、微观结构和力学性能方面进行了表征。1200℃以上烧结使高岭土微观结构由弱点键合结构转变为强致密玻璃陶瓷结构,δ-Al2O3转变为α-Al2O3。将氧化纤维添加到高岭土中形成陶瓷基复合材料,其性能取决于烧结温度、基体和纤维的结构和相对体积、纤维/基体界面的性能和纤维长度。纤维掺入后强度和韧性的相对增加是在纤维添加量有限的情况下实现的,主要是在薄弱点粘合结构中。讨论了线弹性断裂力学在陶瓷基复合材料中的应用。
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引用次数: 4
Interparticle potentials of aqueous Al2O3 suspensions Al2O3悬浮液的粒子间电势
Pub Date : 2003-10-01 DOI: 10.1179/096797803225005034
C. A. Gutiérrez, R. Moreno
Abstract Optimum dispersing conditions for 43 vol.-% aqueous Al2O3 suspensions have been studied by assessing rheological behaviour as a function of dispersant concentration. A commercial polyelectrolyte was used as dispersant. The particle pair potentials have been calculated by considering the electrostatic and steric contributions. Variations in the steric potential produce significant changes in the shape and level of the potential energy curves and allow the prediction of the stability of suspensions that should coagulate according to the DLVO equation. Colloidal stability and rheological behaviour are correlated with the green and sintered densities of Al2O3 bodies produced by slip casting.
摘要通过评估分散剂浓度对43体积-% Al2O3水溶液悬浮液流变性能的影响,研究了其最佳分散条件。采用一种商用聚电解质作为分散剂。考虑静电和空间作用,计算了粒子对电势。位阻势的变化会使势能曲线的形状和水平发生显著变化,从而可以根据DLVO方程预测应凝固的悬浮液的稳定性。胶体稳定性和流变行为与滑移铸造Al2O3坯体的生坯密度和烧结密度有关。
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引用次数: 12
Effect of microsilica in MgO based castables on oxygen content of interstitial free steel MgO基浇注料中微二氧化硅对间隙游离钢氧含量的影响
Pub Date : 2003-08-01 DOI: 10.1179/096797803225004963
Huili Li, Y. Wei
Abstract Samples of interstitial free (IF) steel were heated at 1600 ° C for 90 min in graphite crucibles lined with MgO based castables bonded with microsilica. The total oxygen content (TOC) of the IF steel was determined for castables with various microsilica contents, and inclusions in the steel and refractory were characterised by SEM and EDS. As the microsilica content in the MgO castable increased from 3 to 7 wt-%, the TOC of the IF steel decreased. It is proposed that this is due to the formation of a viscous liquid layer between the molten steel and the refractory. This liquid layer prevents dissolution of oxides from the refractory into the molten steel and so decreases the TOC of IF steel. In addition, the liquid layer may act as an absorber for oxide inclusions in the molten steel.
摘要:在石墨坩埚中,用微二氧化硅粘结MgO基浇注料,在1600℃下加热90 min。对不同微二氧化硅含量的浇注料测定了IF钢的总氧含量(TOC),并用SEM和EDS对钢和耐火材料中的夹杂物进行了表征。当MgO浇注料中微二氧化硅含量从3%增加到7%时,IF钢的TOC降低。有人提出,这是由于钢水和耐火材料之间形成了粘性液体层。这种液体层防止氧化物从耐火材料溶解到钢液中,从而降低IF钢的TOC。此外,液体层可以作为钢液中氧化物夹杂物的吸收剂。
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引用次数: 9
Correlation between nitriding process and microstructure of reaction bonded aluminium nitride ceramics 氮化工艺与反应结合氮化铝陶瓷微观结构的关系
Pub Date : 2003-08-01 DOI: 10.1179/096797803225005007
E. Salahi, J. Heinrich
Abstract Aluminium nitride samples were produced by a reaction bonding process using AlN and Al powders with flake-like and equiaxed morphologies as starting materials. Changing the particle sizes and morphologies of the aluminium starting powders led to changes in degree of reaction and microstructure of the resulting reaction bonded aluminium nitride ceramics. At 25 wt-%Al, the degree of reaction showed a maximum, decreasing at higher aluminium concentrations. The degree of reaction was increased by increasing nitrogen gas flowrate or nitriding temperature. It was also found to be increased by reducing the average particle size of the Al starting powder, the green bulk density, or the sample thickness, and also by choosing flakelike morphology. SEM and optical micrographs of reaction bonded aluminium nitride samples revealed the pore structure and morphology of primary and secondary aluminium nitride.
摘要:以片状、等轴形貌的AlN和Al粉末为原料,采用反应键合法制备氮化铝样品。改变铝起始粉的粒度和形貌,可以改变反应的反应程度和反应所得氮化铝陶瓷的微观结构。当铝含量为25wt -%时,反应程度最大,铝浓度越高反应程度越低。提高氮气流量或氮化温度均可提高反应程度。通过降低铝起始粉的平均粒径、绿色堆积密度或样品厚度,以及选择片状形貌,也可以提高铝起始粉的平均粒径。反应结合氮化铝样品的SEM和光学显微照片显示了原生氮化铝和次生氮化铝的孔隙结构和形貌。
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引用次数: 7
Refractory castables based on barium aluminate cements 基于铝酸钡水泥的耐火浇注料
Pub Date : 2003-08-01 DOI: 10.1179/096797803225004954
S. El-Hemaly, N. Khalil, L. G. Girgis
Abstract Three aluminous cement compositions containing different proportions of barium aluminate were prepared from mixtures of calcined alumina, Egyptian barite, and limestone, by sintering briquettes at around 1600°C. The sintered bodies were ground to produce a cement powder of suitable fineness in which the predominant phases were found to be barium aluminate and calcium dialuminate. These cements were found to possess satisfactory cementitious behaviour and high refractoriness. Refractory castable compositions, based on the prepared cements and using sintered magnesia as aggregate, were formulated and evaluated for their physical, mechanical, and refractory properties. High strength and low shrinkage characterise the castable shapes in the cured, dried, and fired states. Such barium aluminate containing castables could be used effectively for lining structures subjected to very high temperatures.
摘要以煅烧的氧化铝、埃及重晶石和石灰石为原料,在1600℃左右烧结成块,制备了三种不同比例铝酸钡的铝质水泥组合物。将烧结体研磨成适当细度的水泥粉,其中主要相为铝酸钡和双铝酸钙。这些胶结物具有令人满意的胶结性能和高耐火度。耐火浇注料组合物以制备的水泥为基础,以烧结镁砂为骨料,配制并评估了其物理、机械和耐火性能。高强度和低收缩率是浇注料在固化、干燥和烧制状态下的特点。这种含有铝酸钡的浇注料可以有效地用于经受高温的衬里结构。
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引用次数: 9
Evidence for two stage mullite formation during thermal decomposition of kaolinite 高岭石热分解过程中两阶段莫来石形成的证据
Pub Date : 2003-08-01 DOI: 10.1179/096797803225004972
A. Chakraborty, Swagatika Das, Sonali Gupta
Abstract Structural changes on heat treatment of English kaolinite have been studied by a standard X-ray technique. Changes in the lattice parameters, strain values, and crystal sizes of mullite and cristobalite have been calculated using a computer based Rietveld program. The results show two separate stages of mullite formation during the reaction of kaolinite. Changes in the composition of mullite during the course of its formation are discussed.
用标准x射线技术研究了英国高岭石热处理后的结构变化。用Rietveld程序计算了莫来石和方石的晶格参数、应变值和晶体尺寸的变化。结果表明,在高岭石反应过程中,莫来石的形成分为两个阶段。讨论了莫来石在形成过程中成分的变化。
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引用次数: 11
期刊
British Ceramic Transactions
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