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Experimental investigation of humidification parameters using biomass-based charcoal as an alternative packing material 生物质炭替代填料增湿参数的实验研究
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.04.005
Sampath Suranjan Salins , S.V. Kota Reddy , Shiva Kumar , Clifton Stephen

Due to the increase in human population, there is an ever-increasing demand for energy in different sectors which leads to environmental problems like climate change, rise in temperature, and global catastrophes. Cooling systems have become a very essential element in recent decades for mankind. The present system focuses on the design and fabrication of a counter-flow humidification setup which uses biomass-based charcoal as the packing material. Air velocity and water flow rate have been varied along with the density of charcoal. Output parameters such as a change in pressure (ΔP), Coefficient of performance (COP), evaporation rate (ER), humidification efficiency (HE), specific cooling capacity (SCC), and energy consumption (EC) are evaluated. Performance parameters obtained for charcoal are compared with that of standard Celdek Packing. Through experiments, it is found that humidification efficiencies for Celdek and charcoal packing are 77.45% and 57.40% respectively. The overall coefficient of performance obtained is 1.41 for charcoal and 3.17 for Celdek packing. Among the three densities which were considered, charcoal packing with a density of 400 kg/m3 exhibited higher performance with respect to COP, HE, ER, and SCC. Similarly, a water flow rate of 0.4 lpm gave a maximum performance and 0.7 lpm gave the least. It is concluded that charcoal can be considered one of the highly efficient biomass-based materials contributing to sustainable energy related to cooling applications.

由于人类人口的增长,各行各业对能源的需求不断增加,这导致了气候变化、气温升高和全球灾难等环境问题。近几十年来,冷却系统已成为人类不可或缺的要素。本系统侧重于逆流加湿装置的设计和制造,该装置使用以生物质为基础的木炭作为填料。空气流速和水流量随木炭密度的变化而变化。对压力变化 (ΔP)、性能系数 (COP)、蒸发率 (ER)、加湿效率 (HE)、比冷量 (SCC) 和能耗 (EC) 等输出参数进行了评估。木炭的性能参数与标准 Celdek 填料的性能参数进行了比较。通过实验发现,Celdek 和木炭填料的加湿效率分别为 77.45% 和 57.40%。木炭和 Celdek 填料的总体性能系数分别为 1.41 和 3.17。在考虑的三种密度中,密度为 400 kg/m3 的木炭填料在 COP、HE、ER 和 SCC 方面表现出更高的性能。同样,水流量为 0.4 lpm 时性能最高,0.7 lpm 时性能最低。由此得出结论,木炭可被视为高效的生物质材料之一,有助于与冷却应用相关的可持续能源。
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引用次数: 0
Particle swarm optimization technique-based prediction of peak ground acceleration of Iraq’s tectonic regions 基于粒子群优化技术的伊拉克构造区地面加速度峰值预测
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.06.004
Mahir M. Hason , Ammar N. Hanoon , Ali A. Abdulhameed

Peak ground acceleration (PGA) is one of the critical factors that affect the determination of earthquake intensity. PGA is generally utilized to describe ground motion in a particular zone and is able to efficiently predict the parameters of site ground motion for the design of engineering structures. Therefore, novel models are developed to forecast PGA in the case of the Iraqi database, which utilizes the particle swarm optimization (PSO) approach. A data set of 187 historical ground-motion recordings in Iraq’s tectonic regions was used to build the explicit proposed models. The proposed PGA models relate to different seismic parameters, including the magnitude of the earthquake (Mw), average shear-wave velocity (VS30), focal depth (FD), and nearest epicenter distance (REPi) to a seismic station. The derived PGA models are remarkably simple and straightforward and can be used reliably for pre-design purposes. The proposed PGA models (i.e., models I and II) obtained via the explicit formula produced using the PSO method are highly correlated to the actual PGA records owing to low coefficients of variation (CoV) of approximately 2.12% and 2.06%, and mean values (i.e., close to 1.0) of approximately 1.005 and 1.004. Lastly, high-frequency, low absolute relative error (ARE), which is below 5%, is recorded for the proposed models, thereby showing an acceptable error distribution.

峰值地面加速度(PGA)是影响地震烈度确定的关键因素之一。峰值地面加速度通常用于描述特定区域的地面运动,并能有效预测现场地面运动参数,用于工程结构设计。因此,针对伊拉克数据库,利用粒子群优化(PSO)方法开发了预测 PGA 的新型模型。伊拉克构造地区 187 次历史地动记录的数据集被用于建立明确的拟议模型。提出的 PGA 模型与不同的地震参数有关,包括震级(Mw)、平均剪切波速度(VS30)、焦深(FD)和到地震台站的最近震中距离(REPi)。推导出的 PGA 模型非常简单直接,可以可靠地用于设计前工作。通过 PSO 方法产生的显式公式得到的 PGA 模型(即模型 I 和模型 II)与实际 PGA 记录高度相关,变异系数(CoV)分别约为 2.12% 和 2.06%,平均值(即接近 1.0)分别约为 1.005 和 1.004。最后,建议的模型记录了低于 5%的高频率、低绝对相对误差 (ARE),从而显示了可接受的误差分布。
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引用次数: 12
The scope of acoustic impedance matching of hybrid fiber metal laminates for shielding applications 用于屏蔽应用的混合纤维金属层压板的声阻抗匹配范围
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.07.002
Anand Pai, B. Satish Shenoy, R. Chandrakant Kini, Sriharsha Hegde

In a multi-layered shielding material, the sequence of the arrangement of the layers affects the extent of insulation to acoustic waves. In the current work, hybrid composite laminates have been taken up comprising 10 sequences, employing metallic faceplate (AA6061), paperboard, ballistic-grade aramid, and ultra-high molecular weight polyethylene (UHMWPE) fabrics with an epoxy binder. In the theoretical studies, an analytical model for the transmission loss function has been developed by incorporating the multiple wave reflection principle in combination with interface-wise acoustic impedance grading. The analytical model has been validated using the transmission loss functions from numerical and experimental studies on the different sequences. The numerical simulation has been carried out using the harmonic acoustic analysis module, on Ansys R19.0. The experimentation has been carried out on an impedance tube. The results from the analytical model are in good agreement with the experimental and numerical simulation results, the analytical model can be used for predicting the transmission losses of composite laminates.

在多层屏蔽材料中,层的排列顺序会影响隔绝声波的程度。在目前的工作中,混合复合层压材料包括 10 个序列,采用了金属面板(AA6061)、纸板、防弹级芳纶和超高分子量聚乙烯(UHMWPE)织物以及环氧树脂粘合剂。在理论研究中,结合多波反射原理和界面声阻抗分级,建立了传输损耗函数分析模型。利用对不同序列进行的数值和实验研究得出的传输损耗函数对该分析模型进行了验证。数值模拟是使用 Ansys R19.0 上的谐波声学分析模块进行的。实验是在阻抗管上进行的。分析模型得出的结果与实验和数值模拟结果十分吻合,该分析模型可用于预测复合材料层压板的传输损耗。
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引用次数: 3
Recyclability of low-density polyethylene water sachet film into powder and its suitability for polyethylene-wood composite 将低密度聚乙烯水袋薄膜制成粉末的可回收性及其对聚乙烯-木材复合材料的适用性
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2022.12.002
I.I. Ahmed, A.M. Akintola, O.E. Afolabi, J.A. Adebisi

Low density polyethylene (LDPE) based water sachet films were recycled into polymer powder by thermochemical treatment. Varying weights of sachet films were dissolved in automotive gas oil (AGO) at elevated temperature, followed by quenching in an ice-bath stainless steel container to determine optimum powder yield and particle size distribution. Sieve analysis of powder was carried out into different particle sizes and consequently to eliminate lumps. The polymer powder was subsequently mixed with maleic anhydride treated African mahogany wood dust (WD), in ratios 80:20, 70:30 and 60:40 wt%, and compacted by hot pressing to produce composite samples. Performance evaluation was carried out on the composite using tensile, flexural and impact energy testing techniques. Water absorption test was also carried out to determine hydrophilicity of the composite. The mass of powder yield from thermochemical treatment was about twice the amount of sachet films. Film dissolution of 100 mg/L of AGO gave optimal powder yield and size distribution with minimal lumps. Performance tests showed that, tensile and flexural strength, and impact energy of composites decreased with increase in the weight percent of wood dust. The water absorption test also revealed increased hydrophilicity of the composite with wood dust ratio.

通过热化学处理将以低密度聚乙烯(LDPE)为基础的水袋薄膜回收成聚合物粉末。在高温下将不同重量的水袋薄膜溶解在车用燃气油(AGO)中,然后在冰浴不锈钢容器中淬火,以确定最佳的粉末产量和粒度分布。对不同粒度的粉末进行筛分分析,从而消除块状物。随后将聚合物粉末与马来酸酐处理过的非洲桃花心木木屑(WD)按 80:20、70:30 和 60:40 wt% 的比例混合,并通过热压压制成复合材料样品。使用拉伸、弯曲和冲击能测试技术对复合材料进行了性能评估。此外,还进行了吸水测试,以确定复合材料的亲水性。热化学处理产生的粉末质量约为小袋薄膜的两倍。100 mg/L AGO 的薄膜溶解可获得最佳的粉末产量和粒度分布,且块状物极少。性能测试表明,复合材料的拉伸强度、弯曲强度和冲击能随着木粉重量百分比的增加而降低。吸水性测试也表明,随着木粉比例的增加,复合材料的亲水性也会增加。
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引用次数: 0
Adsorption capacity of the biochar obtained from Pinus patula wood micro-gasification for the treatment of polluted water containing malachite green dye 利用松柏木微气化获得的生物炭处理含孔雀石绿染料污染水的吸附能力
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.07.006
A. Rubio-Clemente , J. Gutiérrez , H. Henao , A.M. Melo , J.F. Pérez , E. Chica

In this work, the adsorption capacity of the biochar obtained from Pinus patula biomass micro-gasification was studied using malachite green (MG) as the probe pollutant. For this purpose, the biomass type (wood pellets and chips) was selected to produce two kinds of biochar (BC). Afterwards, the effects of the adsorbent dose (6, 9 and 12 g/L), the solution pH (4, 7 and 10) and the BC particle size distribution (150–300, 300–450 and 450–600 μm) for the maximization of the MG retention by the selected BC were evaluated using a faced-centered central composite design, as response surface methodology. The results indicated that the BC derived from wood chips (BWC) exhibited a higher MG dye adsorption capacity than the BC obtained from the wood pellets (BWP) gasification under the same operating conditions after having reached the equilibrium. A second-order regression model was built for describing the MG adsorption behaviour by BWC under the considered experimental domain. The model, which was validated, resulted to be statistically significant and suitable to represent the MG adsorption by the studied BC with a p-value of 0.00 and a correlation coefficient (R2) of 95.59%. Additionally, a three-dimensional response surface graph and a contour plot were utilized to analyze the interaction effects between the factors influencing the adsorption system and to discern the optimal operating conditions for the use of BWC. The maximal MG dye retention (99.70%) was found to be at an adsorbent dose, pH solution and a particle size distribution of 9.80 g/L, 10 and from 150 to 300 μm, respectively. Therefore, the BWC tested can be utilized for the treatment of water polluted with dyes, contributing to the establishment of a circular economy.

本研究以孔雀石绿(MG)为探针污染物,研究了从松柏生物质微气化中获得的生物炭的吸附能力。为此,选择了生物质类型(木粒和木片)来生产两种生物炭(BC)。随后,采用以面为中心的中心复合设计作为响应面方法,评估了吸附剂剂量(6、9 和 12 g/L)、溶液 pH 值(4、7 和 10)和生物炭粒度分布(150-300、300-450 和 450-600 μm)对所选生物炭最大限度截留 MG 的影响。结果表明,在达到平衡后的相同操作条件下,木屑(BWC)产生的 BC 比木粒(BWP)气化产生的 BC 具有更高的 MG 染料吸附能力。建立了一个二阶回归模型,用于描述 BWC 在所考虑的实验条件下对 MG 的吸附行为。经过验证,该模型具有统计学意义,适合表示所研究的 BC 对 MG 的吸附,P 值为 0.00,相关系数 (R2) 为 95.59%。此外,还利用三维响应面图和等值线图分析了吸附系统各影响因素之间的交互效应,并确定了使用 BWC 的最佳操作条件。结果发现,在吸附剂剂量、pH 值溶液和粒度分布分别为 9.80 g/L、10 和 150 至 300 μm 时,MG 染料的最大保留率(99.70%)为 99.70%。因此,所测试的 BWC 可用于处理受染料污染的水,为建立循环经济做出贡献。
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引用次数: 18
Novel one-pot microwave synthesis of maleic anhydride based mineral scale inhibitors and their application 马来酸酐基矿物阻垢剂的新型单锅微波合成及其应用
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.07.008
Yousef M. Al-Roomi, Kaneez F. Hussain

This paper presents our research efforts in the discovery of pioneering synthetic routes and designing low molecular-weight maleic-anhydride (MA) homopolymers and MA-n-octyl acrylamide (AAO) copolymers (YMR-series) and their application as scale inhibitors for mineral scales. Hence, the solvent-free, eco-friendly, rapid microwave-assisted method has been developed for the first time to synthesize these antiscalants with higher yield and better efficiency. The inhibition ability on the CaSO4 and CaCO3 scale is 100 % with a 3 ppm dosage level at pH 10.45 and temperature 70 °C.

Morphological changes of the CaCO3 and CaSO4 scales due to the strong inhibition action of YMR-series polymers have been studied by scanning electronic microscopy (SEM) and X-ray powder diffraction (XRD) analysis. It is also observed that the anti-scaling effect of the polymers greatly depends on the molecular weight, while MA copolymers show better inhibition efficiency compared to MA homopolymers.

本文介绍了我们在发现开创性合成路线、设计低分子量马来酸酐(MA)均聚物和马来酸酐-正辛基丙烯酰胺(AAO)共聚物(YMR-系列)以及将其用作矿物垢阻垢剂方面所做的研究工作。因此,我们首次开发了无溶剂、环保、快速的微波辅助方法来合成这些产率更高、效率更高的阻垢剂。通过扫描电子显微镜(SEM)和 X 射线粉末衍射(XRD)分析,研究了 YMR 系列聚合物的强抑制作用导致的 CaCO3 和 CaSO4 鳞片的形态变化。研究还发现,聚合物的防垢效果在很大程度上取决于分子量,而与 MA 均聚物相比,MA 共聚物显示出更好的抑制效率。
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引用次数: 0
Designing a pre-cooling model for air conditioning to avoid an electricity price spike for different building characteristics 设计空调预冷模型,避免不同建筑特征下的电价飙升
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.07.004
Marwan Marwan , Muhammad Dihyah Marwan

Air conditioning (AC) is a key driver to produce electricity consumption, particularly in residential buildings. In Indonesia, the electricity bill during pandemic covid-19 has increased to a high level on hot days. This is because during these periods many consumers applied their AC for a long time at the same time. It is therefore essential to develop an innovative model to control the electricity peak price and keep a comfortable room during hot days. Many previous studies have confirmed that applied evaporative cooling or other technologies can minimize the whole consumption and cost. This research aims to design a pre-cooling model (PM) for AC to avoid high electricity prices at midday during hot days. To achieve this goal a mathematical model was developed to define the energy cost (EC) and total cost (TC) for AC during the hot season. Under numerical optimization, the EC can be minimized when a spike may occur due to increased temperature at midday for a half hour (0.5 h) and one hour (1 h) spike cases. To justify this model, a PM was applied for two different building characteristics. As a result, the benefits of a PM if a spike occurs for 0.5 h and 1 h were achieved, such as IDR 10,061 (30.43 %) and IDR 10,693 (24.44 %) for building-1; IDR 12,071 (37.40 %) and IDR 14,844 (34.97 %) for building-2. In addition, the TC considering the probability of a spike of 0.5 h and 1 h if the spike occurs every five minutes were IDR 45,247 and IDR 38,287 for building-1 and building-2, respectively.

空调(AC)是产生电力消耗的主要驱动力,尤其是在住宅建筑中。在印度尼西亚,19 大流行病期间的电费在炎热的日子里增加到很高的水平。这是因为在这些时段,许多消费者同时长时间使用空调。因此,有必要开发一种创新模式来控制峰值电价,并在高温天保持舒适的室内环境。之前的许多研究已经证实,应用蒸发冷却或其他技术可以最大限度地减少整体消耗和成本。本研究旨在设计一种空调预冷模型(PM),以避免高温天中午的高电价。为实现这一目标,我们建立了一个数学模型,以确定高温季节空调的能源成本(EC)和总成本(TC)。在数值优化下,当半小时(0.5 小时)和一小时(1 小时)的峰值情况下,由于中午气温升高而可能出现峰值时,EC 可以最小化。为了证明该模型的合理性,针对两种不同的建筑特征采用了 PM 模型。结果是,如果在 0.5 小时和 1 小时内出现尖峰,则 PM 可带来收益,如 1 号楼的收益分别为 10,061 印尼盾(30.43%)和 10,693 印尼盾(24.44%);2 号楼的收益分别为 12,071 印尼盾(37.40%)和 14,844 印尼盾(34.97%)。此外,如果峰值每五分钟出现一次,则考虑到峰值出现 0.5 小时和 1 小时的概率,1 号楼和 2 号楼的 TC 分别为 45 247 印尼盾和 38 287 印尼盾。
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引用次数: 0
Study of Damietta branch meander suitability for inland first-class river cargo transportation 研究达米埃塔支流河曲是否适合内陆一流河道货物运输
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.06.003
W.A. Fahmy , Nasr Hekal

The current research aims to study the suitability of Damietta branch meanders for safe first-class cargo transportation. This branch is the River Nile eastern waterway bifurcated at the beginning of the Delta region, which is about 22.0 km downstream of El-Roda gauge in Cairo. It extends for 244 km to the Mediterranean Sea. The branch plan form was examined for meanders. Fifty-one meanders could be identified throughout. Their characteristics were analyzed. The results revealed the existence of eight sharp meanders and seven critical looping ones that would slow down and jeopardize the first-class navigation traffic. Also, it was found that about 68 % of the looping meander lengths could be saved if cut-offs were executed. Accordingly, examples of straightening the river at four meanders were proposed for clarification. It was found that their lengths could be reduced by 51.10 %. Finally, the study concluded that in order for the Damietta branch to be qualified and entitled to safe first-class cargo transportation, the sharp meanders and critical loops have to be subject to training works and re-channelized.

目前的研究旨在研究达米埃塔支流蜿蜒曲折是否适合安全的一流货物运输。该支流是尼罗河东部水道的分叉,位于三角洲地区的起点,在开罗罗达水尺下游约 22.0 公里处。它延伸 244 千米至地中海。我们对蜿蜒的支流平面进行了研究。在整个河道中发现了 51 条蜿蜒河道。对它们的特征进行了分析。结果显示,存在 8 个急弯和 7 个关键的环形弯道,这些弯道会减慢并危及一流的航运交通。此外,还发现如果实施截流,可以节省约 68% 的环形蜿蜒长度。因此,提出了在四个蜿蜒处拉直河道的例子,以供说明。结果发现,它们的长度可减少 51.10%。最后,研究得出的结论是,为了使达米埃塔支流具备一流的货物运输安全资格,必须对急剧的蜿蜒河道和关键的环形河道进行整治,并重新疏通河道。
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引用次数: 0
Assessing the influence of fly ash and polypropylene fiber on fresh, mechanical and durability properties of concrete 评估粉煤灰和聚丙烯纤维对混凝土新拌性能、力学性能和耐久性能的影响
Q1 Chemical Engineering Pub Date : 2023-11-01 DOI: 10.1016/j.jksues.2021.06.005
Abu Sayed Mohammad Akid , Saif Hossain , Md. Imtiaz Uddin Munshi , Md Manjur A Elahi , Md. Habibur Rahman Sobuz , Vivian W.Y. Tam , Md. Saiful Islam

This paper focuses on the investigation of fresh, mechanical, and durability properties of concrete with the influence of fly ash and polypropylene fiber. In this study, cement was partially replaced by 15 % and 30 % fly ash content in weight, whereas polypropylene fiber was incorporated in concrete mixes at 0.06 %, 0.12 %, and 0.18 % by volume. Twelve concrete mix proportions were developed, and slump, density, ball penetration, and compacting factor tests were conducted to examine the fresh concrete properties. Besides, mechanical characteristics, including the uniaxial compressive and splitting tensile strength of concrete, were evaluated at 7, 28, and 90 days. Further tests of concrete durability, including rapid chloride permeability test, sorptivity, and water penetration, were performed at 90 days. The results exhibited that the incorporation of fly ash developed fresh concrete properties, while polypropylene fiber decreased the fresh characteristics of concrete. Furthermore, the combination of fly ash and polypropylene fiber in concrete was substantially attained to improve the mechanical and durability characteristics compared to the control mix. Mix proportion of 15 % fly ash and 0.12 % polypropylene fiber exhibited a pronounced influence on compressive strength, chloride permeability, sorptivity, and water penetration compared to other concrete mixtures.

本文重点研究了受粉煤灰和聚丙烯纤维影响的混凝土的新拌性能、力学性能和耐久性能。在这项研究中,水泥部分被重量百分比为 15 % 和 30 % 的粉煤灰所取代,而聚丙烯纤维则以体积百分比为 0.06 %、0.12 % 和 0.18 % 加入混凝土拌合物中。开发了 12 种混凝土混合比例,并进行了坍落度、密度、球击穿和压实系数测试,以检验新拌混凝土的性能。此外,还评估了 7 天、28 天和 90 天的力学特性,包括混凝土的单轴抗压强度和劈裂拉伸强度。此外,还在 90 天时对混凝土的耐久性进行了测试,包括快速氯离子渗透性测试、吸水率和水渗透性。结果表明,掺入粉煤灰可改善混凝土的新拌特性,而聚丙烯纤维则会降低混凝土的新拌特性。此外,与对照组相比,粉煤灰和聚丙烯纤维在混凝土中的组合大大改善了力学和耐久性能。与其他混凝土混合物相比,混合比例为 15 % 的粉煤灰和 0.12 % 的聚丙烯纤维对抗压强度、氯离子渗透性、吸水率和透水性有明显的影响。
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引用次数: 39
Pretreatment and acid hydrolysis of Omani Prosopis Juliflora wood 阿曼藜木的预处理及酸水解研究
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.07.003
Mohammad Silwadi , Hasan Mousa , Ahlam Al Azkawi , Fatma Sulaiman Al Kumzary , Tahani Ali Al-Najadi

The objective of this research is to investigate different chemical pretreatment methods to reduce the lignin and hemicellulose content of Omani Prosopis Juliflora. The pretreated wood will then be acid hydrolyzed to convert the cellulose content to sugar. Four types of pretreatment methods were employed, namely: Alkaline pretreatment (Method I), Alkaline + Hydrogen peroxide pretreatment (Method II), Alkaline + Hydrogen peroxide + acid-chlorite pretreatment (Method III) and Alkaline + H2O2 + Acid-chlorite + bicarbonate pretreatment (Method IV). The effectiveness of each pretreatment method was assessed by measuring lignin, hemicellulose, and cellulose contents and the crystallinity index (CrI) using X-ray diffraction (XRD) analysis. The results were further assessed by taking images of the wood samples after each pretreatment step using Scanning Electron Microscope (SEM). The results showed that the CrI increased from 51% for the untreated samples to 61%, 65%, 68% and 73.2% after treating with Method I, II, III and IV, respectively. Measuring the cellulose, hemicellulose and lignin contents showed that the effectiveness of the methods in ascending order was Method I < Method II < Method III < Method IV.

The pretreated wood samples by method IV were acid hydrolyzed. The effect of acid type, namely: H2SO4, HNO3, HCl and H3PO4, concentration and hydrolysis time on the %conversion of cellulose to sugar was investigated. The results revealed that H2SO4 was the most effective acid, whereas H3PO4 was the weakest. The efficiency of the tested acids follows the following order: H2SO4 > HNO3 > HCL > H3PO4. For all acids tested, the %conversion of cellulose to reducing sugar as a function of time increases linearly till t = 90 min, after which no change in the %conversion was obtained. Investigating the effect of acid concentration showed that as the concentration increases, the %conversion increases too. Upon increasing acid concentration from 1% to 10%, the %conversion increases from 12% to 62% for H2SO4, from 5% to 43% for HNO3, from 0% to 47% for HCl, and from 5% to 34% for H3PO4.

本研究的目的是研究不同的化学预处理方法,以降低阿曼Prosopis Juliflora的木质素和半纤维素含量。然后将预处理过的木材进行酸水解,将纤维素含量转化为糖。采用了四种预处理方法,即:碱性预处理(方法I)、碱性预处理 + 过氧化氢预处理(方法二),碱性 + 过氧化氢 + 酸性亚氯酸盐预处理(方法III)和碱性 + H2O2 + 酸性亚氯酸盐 + 碳酸氢盐预处理(方法IV)。通过使用X射线衍射(XRD)分析测量木质素、半纤维素和纤维素含量以及结晶度指数(CrI)来评估每种预处理方法的有效性。通过使用扫描电子显微镜(SEM)在每个预处理步骤之后拍摄木材样品的图像来进一步评估结果。结果表明,用方法I、II、III和IV处理后,CrI从未处理样品的51%分别提高到61%、65%、68%和73.2%。纤维素、半纤维素和木质素含量的测定表明,这些方法的有效性按升序排列为方法I <; 方法二 <; 方法三 <; 方法四、对经方法四预处理的木材样品进行酸水解。研究了酸的种类,即:H2SO4、HNO3、HCl和H3PO4,浓度和水解时间对纤维素向糖转化率的影响。结果表明,H2SO4是最有效的酸,而H3PO4是最弱的酸。测试酸的效率遵循以下顺序:H2SO4 >; HNO3 >; HCL >; H3PO4.对于所有测试的酸,纤维素转化为还原糖的百分比随时间线性增加,直到t = 90 分钟,之后没有获得%转化率的变化。考察了酸浓度对转化率的影响,发现随着酸浓度的增加,转化率也随之增加。当酸浓度从1%增加到10%时,H2SO4的%转化率从12%增加到62%,HNO3的%转化度从5%增加到43%,HCl的转化率从0%增加到47%,H3PO4的转化率为5%增加到34%。
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引用次数: 1
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Journal of King Saud University, Engineering Sciences
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