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Pretreatment and acid hydrolysis of Omani Prosopis Juliflora wood 阿曼藜木的预处理及酸水解研究
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.07.003
Mohammad Silwadi , Hasan Mousa , Ahlam Al Azkawi , Fatma Sulaiman Al Kumzary , Tahani Ali Al-Najadi

The objective of this research is to investigate different chemical pretreatment methods to reduce the lignin and hemicellulose content of Omani Prosopis Juliflora. The pretreated wood will then be acid hydrolyzed to convert the cellulose content to sugar. Four types of pretreatment methods were employed, namely: Alkaline pretreatment (Method I), Alkaline + Hydrogen peroxide pretreatment (Method II), Alkaline + Hydrogen peroxide + acid-chlorite pretreatment (Method III) and Alkaline + H2O2 + Acid-chlorite + bicarbonate pretreatment (Method IV). The effectiveness of each pretreatment method was assessed by measuring lignin, hemicellulose, and cellulose contents and the crystallinity index (CrI) using X-ray diffraction (XRD) analysis. The results were further assessed by taking images of the wood samples after each pretreatment step using Scanning Electron Microscope (SEM). The results showed that the CrI increased from 51% for the untreated samples to 61%, 65%, 68% and 73.2% after treating with Method I, II, III and IV, respectively. Measuring the cellulose, hemicellulose and lignin contents showed that the effectiveness of the methods in ascending order was Method I < Method II < Method III < Method IV.

The pretreated wood samples by method IV were acid hydrolyzed. The effect of acid type, namely: H2SO4, HNO3, HCl and H3PO4, concentration and hydrolysis time on the %conversion of cellulose to sugar was investigated. The results revealed that H2SO4 was the most effective acid, whereas H3PO4 was the weakest. The efficiency of the tested acids follows the following order: H2SO4 > HNO3 > HCL > H3PO4. For all acids tested, the %conversion of cellulose to reducing sugar as a function of time increases linearly till t = 90 min, after which no change in the %conversion was obtained. Investigating the effect of acid concentration showed that as the concentration increases, the %conversion increases too. Upon increasing acid concentration from 1% to 10%, the %conversion increases from 12% to 62% for H2SO4, from 5% to 43% for HNO3, from 0% to 47% for HCl, and from 5% to 34% for H3PO4.

本研究的目的是研究不同的化学预处理方法,以降低阿曼Prosopis Juliflora的木质素和半纤维素含量。然后将预处理过的木材进行酸水解,将纤维素含量转化为糖。采用了四种预处理方法,即:碱性预处理(方法I)、碱性预处理 + 过氧化氢预处理(方法二),碱性 + 过氧化氢 + 酸性亚氯酸盐预处理(方法III)和碱性 + H2O2 + 酸性亚氯酸盐 + 碳酸氢盐预处理(方法IV)。通过使用X射线衍射(XRD)分析测量木质素、半纤维素和纤维素含量以及结晶度指数(CrI)来评估每种预处理方法的有效性。通过使用扫描电子显微镜(SEM)在每个预处理步骤之后拍摄木材样品的图像来进一步评估结果。结果表明,用方法I、II、III和IV处理后,CrI从未处理样品的51%分别提高到61%、65%、68%和73.2%。纤维素、半纤维素和木质素含量的测定表明,这些方法的有效性按升序排列为方法I <; 方法二 <; 方法三 <; 方法四、对经方法四预处理的木材样品进行酸水解。研究了酸的种类,即:H2SO4、HNO3、HCl和H3PO4,浓度和水解时间对纤维素向糖转化率的影响。结果表明,H2SO4是最有效的酸,而H3PO4是最弱的酸。测试酸的效率遵循以下顺序:H2SO4 >; HNO3 >; HCL >; H3PO4.对于所有测试的酸,纤维素转化为还原糖的百分比随时间线性增加,直到t = 90 分钟,之后没有获得%转化率的变化。考察了酸浓度对转化率的影响,发现随着酸浓度的增加,转化率也随之增加。当酸浓度从1%增加到10%时,H2SO4的%转化率从12%增加到62%,HNO3的%转化度从5%增加到43%,HCl的转化率从0%增加到47%,H3PO4的转化率为5%增加到34%。
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引用次数: 1
Evaluating two numerical methods for developing a local geoid model and a local digital elevation model for the Red Sea Coast, Egypt 评估埃及红海海岸开发局部大地水准面模型和局部数字高程模型的两种数值方法
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.04.004
Hamdy M. Ahmed , Elshewy A. Mohamed , Shaheen A. Bahaa

Global Navigation Satellite System (GNSS) provides ellipsoidal heights, whereas engineering projects need orthometric heights of points. Thus, to take advantage of GNSS in engineering work, the relation between orthometric and ellipsoid height must be determined as a function of position by geoid modeling. The Red Sea coastal cities have various natural potentials that render them economically promising cities that are attractive to numerous investors and visitors alike. Over the past years, there has been an increased governmental awareness of setting up large projects in these cities. With the increasing utilization of GNSS in a number of these projects, there is an imperative need to develop a local geoid model in this region. This study is an attempt to use a geometric method for the study area in order to develop a local geoid model and a local digital elevation model. In addition, the performance of EGM2008, SRTM, and ASTER is evaluated. In order to develop the local geoid model, the polynomial regression method and Artificial Neural network (ANN) technique are employed. Performance evaluation of the studied methods is based on a compilation of various statistical parameters and goodness-of-fit measures, followed by a comparison of methods outputs. The study indicates significant improvements in the local geoid model when using both methods. Additionally, the model resulting from the ANN appears more reliable compared to the calculated model using polynomial regression. In this study, the accuracy of EGM2008 is about ±0.466 m. Moreover, regarding the global digital elevation model, ASTER outperforms SRTM by about ±0.905 m.

全球卫星导航系统(GNSS)提供椭球体高度,而工程项目需要点的正交高度。因此,为了在工程工作中充分利用GNSS,必须通过大地水准面建模确定正交与椭球体高度之间的位置函数关系。红海沿岸城市具有各种自然潜力,使它们成为经济上有前景的城市,对众多投资者和游客都具有吸引力。在过去的几年里,政府越来越意识到在这些城市建立大型项目。随着GNSS在这些项目中的应用越来越多,迫切需要在该地区开发局部大地水准面模型。本研究尝试采用几何方法对研究区进行局部大地水准面模型和局部数字高程模型的建立。此外,还对EGM2008、SRTM和ASTER的性能进行了评价。为了建立局部大地水准面模型,采用多项式回归方法和人工神经网络(ANN)技术。所研究方法的性能评估是基于各种统计参数和拟合优度度量的汇编,然后是方法输出的比较。研究表明,两种方法均能显著改善局部大地水准面模型。此外,与使用多项式回归的计算模型相比,由人工神经网络得到的模型显得更加可靠。在本研究中,EGM2008的精度约为±0.466 m。此外,对于全球数字高程模型,ASTER优于SRTM约±0.905 m。
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引用次数: 2
Slurry erosion performance analysis and characterization of high-velocity oxy-fuel sprayed Ni and Co hardsurfacing alloy coatings 高速氧喷涂Ni和Co硬质堆焊合金涂层的浆液侵蚀性能分析与表征
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.06.009
Jashanpreet Singh

In this paper, the performance of hardsurfacing Cobalt alloy (Stellite 6) and Nickel alloy (Colmonoy 88) was tested in tribological slurry conditions by using a pot tester. Thermal spraying powders were deposited on AISI 316L substrates by using a high-velocity oxy-fuel (HVOF) technique. Wear experiments are carried out using a lab-scale pot tester at low velocities like 1.81, 2.71, 3.61, and 4.59 m/s. The high mass flux of ashes (ranging 30–60 wt%) is used to produce severe accelerated conditions. The effect of the size fraction of eroding particles was evaluated by preparing the multi-sized slurries of size fractions (ASTM: −200, −140 + 200, −100 + 140, and −60 + 100). Results show that the microhardness of AISI 316L was improved by the HVOF depositing of Cobalt alloy-6 and Nickel alloy-88. The average surface microhardness of Cobalt alloy-6 was found lower (439 ± 19 HV1000) than the Nickel alloy-88 coating (601 ± 11 HV1000). Erosion performance of coatings was found to be increased with an increase in the value of the velocity, time, mass flux, and weighted mean size of eroding particles. Results show that the Ni-alloy improved the wear resistance of AISI 316L by 2.03 ± 0.021 times in fly ash slurry conditions and 3.21 ± 0.035 times in bottom ash slurry conditions. However, the Co-alloy was beneficial in reducing the wear of AISI 316L by 1.48 ± 0.019 times in fly ash and 2.50 ± 0.032 times in bottom ash slurry conditions. Moreover, the maximum wear of AISI 316L steel was observed at an impingement angle of 30° whereas 60° and 45° for Ni-alloy and Co-alloy coatings respectively in fly ash conditions. Although, the AISI 316L and Ni-alloy coating show maximum wear at the same impingement conditions under the bottom ash slurry conditions. However, the Co-alloy coating showed maximum wear at 60° in bottom ash slurry conditions.

本文采用罐式试验机对钴合金(钨铬钴合金6号)和镍合金(Colmonoy 88号)在摩擦学浆料条件下的堆焊性能进行了测试。采用高速氧燃料(HVOF)技术在AISI 316L基体上沉积了热喷涂粉末。磨损实验是使用实验室规模的锅式测试仪在1.81、2.71、3.61和4.59 m/s等低速下进行的。灰烬的高质量流量(范围为30–60 wt%)用于产生严重的加速条件。通过制备粒度级分(ASTM:−200、−140+200、−100+140和−60+100)的多粒度浆料来评估侵蚀颗粒粒度级分的影响。结果表明,6号钴合金和88号镍合金的HVOF沉积提高了AISI 316L的显微硬度。钴合金-6涂层的平均表面显微硬度(439±19HV1000)低于镍合金88涂层(601±11HV1000)。涂层的侵蚀性能随着侵蚀颗粒的速度、时间、质量流量和加权平均尺寸的增加而增加。结果表明,在飞灰浆条件下,镍合金使AISI 316L的耐磨性提高了2.03±0.021倍,在底灰浆条件上提高了3.21±0.035倍。然而,在飞灰条件下,Co合金有利于将AISI 316L的磨损降低1.48±0.019倍,在底灰浆料条件下有利于将磨损降低2.50±0.032倍。此外,在飞灰条件下,在30°的冲击角下观察到AISI 316L钢的最大磨损,而Ni合金和Co合金涂层的最大磨损分别为60°和45°。尽管如此,AISI 316L和Ni合金涂层在底灰浆条件下的相同冲击条件下显示出最大磨损。然而,在底灰浆条件下,钴合金涂层在60°时显示出最大磨损。
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引用次数: 11
Analysis of risk factors affecting the main execution activities of roadways construction projects 影响公路建设项目主要执行活动的风险因素分析
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.05.004
Usama H. Issa , Khaled Gamal Marouf , Hamdy Faheem

In this study, the main execution activities associated with global roadways construction projects (RCPs) were identified and categorized into five main activities of RCPs as follows: (A) Preliminary Preparations; (B) Earthworks (cut/fill); (C) Implementing of sub-base and base layers; (D) Implementing of bituminous layers and (E) Traffic safety and road furniture. A field survey was conducted, and a comprehensive practical risk checklist consisting of 39 crucial risk factors affecting RCPs activities in Egypt was introduced as a case study. The probability of occurrence and the impacts on RCPs objectives (time, cost, and quality) and the risk severity were determined while the key risk factors were highlighted. The correlations between the risk factors indices were measured, and the strongest relationship was found between time and cost severities. The weights of time and cost percentages of each activity were identified, as well as the expected percentages of time and cost overruns. Activity (B) had the highest percentages of execution time and associated cost among the whole activities, i.e., 31% for time and 29% for cost. While the average overall time and cost overruns were found (at 15–20) % and (10–15) %, respectively. The effect on the quality of each activity and the overall effect on the project’s final quality were also evaluated. The results indicated a high effect on the quality of activities (A), (B), and (D) and a moderate effect on activities (C) and (E). Furthermore, the influence on the overall quality of the entire project was found with a high effect.

在本研究中,确定了与全球公路建设项目(RCPs)有关的主要执行活动,并将其分类为RCPs的五项主要活动如下:(A)初步筹备;(B)土方工程(切填);(C)实施分基层和基层;(D)实施沥青层和(E)交通安全和道路设施。进行了实地调查,并作为案例研究介绍了一份综合实际风险清单,其中包括影响埃及区域保护计划活动的39个关键风险因素。确定了发生的概率和对rcp目标(时间、成本和质量)的影响以及风险严重程度,同时突出了关键风险因素。结果表明,时间和成本严重程度之间的相关性最强。确定了每个活动的时间和成本百分比权重,以及预期的时间和成本超支百分比。在所有活动中,活动(B)的执行时间和相关成本占比最高,即时间占31%,成本占29%。而平均总时间和成本超支分别为(15 - 20%)%和(10 - 15%)%。对每项活动质量的影响以及对项目最终质量的总体影响也进行了评估。结果表明,对活动(a)、(B)和(D)的质量有很高的影响,对活动(C)和(E)的影响中等。此外,对整个项目的整体质量的影响也很高。
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引用次数: 11
Performance investigation of two-level reduced-switch D-STATCOM in grid-tied solar-PV array with stepped P&O MPPT algorithm and modified SRF strategy 基于步进P&O MPPT算法和改进SRF策略的并网太阳能光伏阵列两级减容开关D-STATCOM性能研究
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.06.008
Meenakshi Rastogi, Aijaz Ahmad, Abdul Hamid Bhat

In this paper, a Two-Level, Three-Phase, Reduced-Switch (2L3PRS) Voltage Source Converter (VSC) based Distribution Static Synchronous Compensator (DSTATCOM) integrated with a grid-tied solar photo-voltaic (PV) array has been discussed, and its performance investigation has been carried out. A versatile control strategy is proposed, which gives the system maximum power point tracking capability with a stepped perturbation and observation (P&O) algorithm and the grid current is maintained at unity power factor. The layout, in addition to the control technique, helps in supplying active power to the power grid and feeding active and reactive power demand of the 3-phase reactive unbalanced load. Modified Synchronous Reference Frame (MSRF) theory-based current control methodology is implemented to sustain DC-link voltage and to maintain the voltage balancing across split capacitors under all loading conditions. This modified algorithm generates switching pulses for three-phase VSI with only four IGBT switches for fulfilling the desired objectives like maintaining a constant DC link voltage, balancing split-capacitor voltages, balancing the power-sharing between the power grid and the solar-PV energy system, balancing the grid currents and voltages in case of unbalanced loading conditions and maintaining unity power factor operation of the grid by making the D-STATCOM compensate for load reactive power. The proposed system is replicated in MATLAB/Simulink using SimPowerSystems software-based environment. The experimental outcomes have been obtained with a digital real-time simulator to vindicate the simulation results. The experimental, as well as simulation results of the proposed real-time-based model, are demonstrated for three unbalanced single-phase inductive linear loads and with a load on one Phase kept open in the Power Factor Correction (PFC)mode of operation of D-STATCOM.

本文讨论了一种基于二电平、三相、降压开关(2L3PRS)电压源变换器(VSC)的分布式静态同步补偿器(DSTATCOM),该补偿器与并网太阳能光伏(PV)阵列集成,并对其性能进行了研究。提出了一种通用的控制策略,该策略通过步进扰动和观测(P&;O)算法赋予系统最大功率点跟踪能力,并将电网电流保持在单位功率因数。除了控制技术之外,该布局还有助于向电网提供有功功率,并为三相无功不平衡负载提供有功和无功功率需求。实现了基于改进的同步参考框架(MSRF)理论的电流控制方法,以在所有负载条件下维持DC链路电压并保持分裂电容器之间的电压平衡。这种改进的算法生成仅具有四个IGBT开关的三相VSI的开关脉冲,以实现所需的目标,如保持恒定的DC链路电压、平衡分压电容器电压、平衡电网和太阳能光伏能源系统之间的功率共享,在负载不平衡的情况下平衡电网电流和电压,并通过使D-STATCOM补偿负载无功功率来维持电网的单位功率因数操作。利用基于SimPowerSystems软件的环境,在MATLAB/Simulink中复制了所提出的系统。用数字实时模拟器对实验结果进行了验证。在D-STATCOM的功率因数校正(PFC)操作模式下,对三个不平衡单相电感线性负载和一相负载保持开路的情况下,演示了所提出的基于实时的模型的实验和仿真结果。
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引用次数: 16
Eggshell nanoparticle reinforced recycled low-density polyethylene: A new material for automobile application 蛋壳纳米颗粒增强再生低密度聚乙烯:一种汽车用新材料
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.04.008
Sefiu Adekunle Bello , Nasirudeen Kolawole Raji , Maruf Yinka Kolawole , Mohammed Kayode Adebayo , Jeleel Adekunle Adebisi , Kehinde Adekunle Okunola , Mustekeem Olanrewaju AbdulSalaam

Waste from low-density polyethylene products after lifespan accounts for 70% of solid waste in most dumpsites, contributing to environmental impacts. Eggshell foul smells are a threat to human and animal health. Before this study, there was no research documentation on transforming both wastes into green composites for engineering applications. This work developed composites using recycled low-density polyethylene (RLDPE) and eggshell Nanoparticles. They were evaluated structurally and mechanically. Straining, which affirms an improvement in the load-bearing capacity of the RLDPE due to the incorporation of eggshell Nanoparticles, was established by the composite XRD peak broadness. Structural integrities of the composites were confirmed with SEM. Maximum tensile strength was noted at 10% eggshell Nanoparticle additions to the RLDPE, equal to a 68% increase. About 52 and 19% enhancements in respective flexural strength and hardness value with a 0.85% reduction in impact energy were noted at 12% eggshell Nanoparticle additions. The probability value, 0.0481 <0.05 established the significance of the mono-variate regression model to estimate the tensile strength of RLDPE/eggshell Nanoparticle composites, and the model has 92.7% confidence. A bumper fascia prototype was fabricated from RLDPE/10% eggshell Nanoparticle composite possessing 10.64 Nmm−2 tensile strength, 21.964 Nmm−2 flexural strength, 21.69 J impact energy, and 59 VHN hardness value using sheet forming technique. Therefore, future usage of the developed RLDPE/10% eggshell Nanoparticle composite is established.

在大多数垃圾场,低密度聚乙烯产品在使用寿命后产生的废物占固体废物的70%,对环境造成影响。蛋壳的臭味对人类和动物的健康都是一种威胁。在本研究之前,没有将这两种废弃物转化为工程应用的绿色复合材料的研究文献。本研究利用回收低密度聚乙烯(RLDPE)和蛋壳纳米颗粒开发复合材料。对它们进行了结构和机械评价。复合XRD峰宽分析证实了蛋壳纳米粒子的加入对RLDPE的承载能力有一定的改善。用扫描电镜对复合材料的结构完整性进行了验证。在RLDPE中添加10%的蛋壳纳米颗粒时,最大拉伸强度增加了68%。当蛋壳纳米颗粒添加量为12%时,其抗弯强度和硬度值分别提高了52%和19%,冲击能量降低了0.85%。概率值为0.0481 <0.05,建立了单变量回归模型对RLDPE/蛋壳纳米颗粒复合材料抗拉强度的显著性,模型置信度为92.7%。以RLDPE/10%蛋壳纳米颗粒复合材料为材料,采用薄片成形技术制备了具有10.64 Nmm−2抗拉强度、21.964 Nmm−2抗折强度、21.69 J冲击能和59 VHN硬度值的保险杠筋膜原型。因此,开发的RLDPE/10%蛋壳纳米颗粒复合材料具有广阔的应用前景。
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引用次数: 7
Energy analysis of solar powered hydrogen production system with CuO/water nanofluids: An experimental investigation CuO/水纳米流体太阳能制氢系统的能量分析:实验研究
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2023.09.001
S. Senthilraja, R. Gangadevi, Hasan Köten, Sivasakthivel Thangavel, M. Baskaran, Mohamed M. Awad
Electrolysis is the process used to produce hydrogen using external electrical energy. Because of less initial and operating cost, less maintenance required, and simple construction, hydrogen production via water electrolysis has gained more attention among users globally. In this current attempt, a novel solar-powered hydrogen generation system was established and tested in different operating circumstances. Throughout the study, nanofluids with concentrations of 0.05%, 0.1%, and 0.2% were utilized, and their effect on electrical performance and hydrogen production rate was examined. Compared to conventional solar panels, the usage of nanofluids resulted in a significant improvement in electrical power productivity and hydrogen output rate. The highest electrical efficiency is with a 0.2% volume fraction of CuO/water nanofluids at 13.5% at Noon. During the same period, the lowest and highest hydrogen yield rates are found for the conventional PV module and 0.2% volume fraction CuO/water nanofluids-based system as 7.9 ml/min and 18.2 ml/min, respectively.
电解是利用外部电能生产氢气的过程。由于初始和运行成本低、维护成本低、结构简单,水电解制氢越来越受到全球用户的关注。在目前的尝试中,建立了一种新的太阳能制氢系统,并在不同的操作环境下进行了测试。在整个研究过程中,使用了浓度为0.05%、0.1%和0.2%的纳米流体,并研究了它们对电性能和产氢率的影响。与传统太阳能电池板相比,纳米流体的使用显著提高了电力生产率和氢气输出率。正午时,CuO/水纳米流体体积分数为0.2%,电效率最高,为13.5%。在同一时期,传统光伏组件和0.2%体积分数的CuO/水纳米流体系统的产氢率最低和最高,分别为7.9 ml/min和18.2 ml/min。
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引用次数: 0
Develop an artificial neural network (ANN) model to predict construction projects performance in Syria 开发一个人工神经网络(ANN)模型来预测叙利亚的建设项目绩效
Q1 Chemical Engineering Pub Date : 2023-09-01 DOI: 10.1016/j.jksues.2021.05.002
Rana Maya, Bassam Hassan, Ammar Hassan

The purpose of this paper is to enable members of the construction project team to understand the factors which they must closely monitor to complete the project with the required performance. Therefore, the research aimed to develop an artificial neural network (ANN) model to predict construction project performance based on the above factors.

A group of (34) factors that affect the performance of the project has been identified based on practitioners' opinions. ANN was designed to predict the project performance model using seven inputs that represent six factors that were prioritized as the most influencing factors. The model showed the factors that affect project performance as follows: Coordination and commitment of project parties (30.9%), Schedule estimate (25.4%), Project team experience and availability (24.5 %), and Support from senior management (14.3%).

We concluded to design a model that predicts project performance based on previous influencing factors, as this model has a prediction accuracy of 96.1 % and an error of 3.9 %.

本文的目的是使建设项目团队的成员了解他们必须密切监控的因素,以完成项目所需的性能。因此,本研究旨在建立基于上述因素的人工神经网络(ANN)模型来预测建设项目绩效。根据从业者的意见,确定了影响项目绩效的一组(34)因素。人工神经网络被设计用来使用七个输入来预测项目绩效模型,这些输入代表了六个被优先考虑为最具影响因素的因素。该模型显示影响项目绩效的因素如下:项目各方的协调和承诺(30.9%),进度估计(25.4%),项目团队的经验和可用性(24.5%),以及高级管理层的支持(14.3%)。由于该模型的预测精度为96.1%,误差为3.9%,因此我们设计了一个基于先前影响因素的项目绩效预测模型。
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引用次数: 11
Physico-mechanical performance of lightweight geopolymer foam aggregates developed by geopolymerization through microwave-oven irradiations 微波辐照地聚合物制备的轻质地聚合物泡沫聚集体的物理力学性能
Q1 Chemical Engineering Pub Date : 2023-07-01 DOI: 10.1016/j.jksues.2021.04.002
Sadia Hanif , Muhammad Akram Tahir , Khuram Rashid , Munib Ul Rehman , Nimra Saleem , Aamna Aslam , Ghinwa Naeem

Climatic change and global warming are pushing researchers to develop waste-based alternatives to cement and conventional concrete, which would have low embodied energy and operational energy due to better insulation properties. In this context, the current study presents the production of ultra-lightweight geopolymer foam aggregate utilizing coal fly ash. Fly ash was activated by two alkaline activators, sodium hydroxide (NaOH) and sodium silicate (Na2SiO3), and Na2SiO3 performed as foaming agents as well. Sodium bicarbonate (NaHCO3) was also used as an additive for geopolymer hardening and early strength gain. A novel curing method, microwave-oven curing, was practiced as an alternative to conventional energy and time-intensive curing techniques to promote rapid strength development and sustainability of materials and technology. The physicomechanical performance (morphology, expansion, density, specific gravity, water absorption, strength against compression, and impact loading) of manufactured aggregates was examined for pertinent use to formulate ultra-lightweight foam concrete, and the properties were also compared with natural as well as synthetic lightweight aggregate. Results indicated that manufactured aggregates experienced physicomechanical properties that would be suitable for designing lightweight concrete both for structural and insulation purposes. Satisfactory results of experimentation also confirmed the potential of microwave-oven curing to replace conventional curing techniques to realize economical, energy-efficient, and eco-efficient manufacturing of artificial aggregate.

气候变化和全球变暖促使研究人员开发以废物为基础的水泥和传统混凝土的替代品,这些替代品由于具有更好的绝缘性能,因此具有较低的隐含能量和运行能量。在此背景下,本研究提出了利用粉煤灰生产超轻质地聚合物泡沫骨料。粉煤灰采用氢氧化钠(NaOH)和硅酸钠(Na2SiO3)两种碱性活化剂进行活化,Na2SiO3作为发泡剂。碳酸氢钠(NaHCO3)也被用作地聚合物硬化和早期强度增加的添加剂。一种新的固化方法,微波固化,作为传统的能源和时间密集型固化技术的替代,促进了材料和技术的快速强度发展和可持续性。研究了人造骨料的物理力学性能(形态、膨胀、密度、比重、吸水率、抗压强度和冲击载荷),以便配制超轻量泡沫混凝土,并将其性能与天然和合成轻骨料进行了比较。结果表明,人造骨料的物理力学性能适合设计结构和保温目的的轻质混凝土。实验结果表明,微波固化技术有望取代传统的固化技术,实现经济、节能、环保的人工骨料生产。
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引用次数: 6
A study on the mechanical behaviour of three different fine-grained mine tailings 三种不同细粒尾矿的力学特性研究
Q1 Chemical Engineering Pub Date : 2023-07-01 DOI: 10.1016/j.jksues.2021.04.001
Shriful Islam

Mine tailings stored in the tailings storage facility (TSF) are normally loose and failure-prone for several reasons, such as liquefaction, erosion, overtopping, piping, and high excess pore water pressure (PWP). The investigation of the mechanical behavior of tailings material is essential for engineering design and safety evaluation of the TSF during mining operations, closure, and rehabilitation. As such, laboratory compaction, consolidation, and direct shear strength experiments are carried out on three different fine-grained mine tailings, named coal tailings (CT), red mud (RM), and gold tailings (GT). Compared to CT and RM, GT showed higher dry density at the optimum moisture content (OMC) and lower compressibility. The permeability of GT is similar to RM but much higher than that of CT. CT and GT showed the highest cohesion and angle of internal friction, respectively, among the tested materials. The direct shear test, among all the methods used, provided the highest dry density and lowest void ratio. The final state parameters obtained in compaction, consolidation, and direct shear tests are critically compared, which is the novelty of this study. This research explored useful information on the geotechnical properties of different tailings that can help mining operators and researchers effectively design and manage the tailings in the TSF.

由于液化、侵蚀、过顶、管道和超孔隙水压力过高等原因,尾矿储存库中的尾矿通常处于松散状态,容易发生破坏。尾矿材料力学特性研究是尾矿堆场工程设计和安全评价的重要内容。为此,对三种不同细粒尾矿(煤尾矿(CT)、赤泥尾矿(RM)和金尾矿(GT))进行室内压实、固结和直剪强度试验。与CT和RM相比,GT在最佳含水量(OMC)下表现出更高的干密度和更低的压缩率。GT的渗透率与RM相似,但远高于CT。CT和GT分别表现出最高的黏聚力和内摩擦角。在所有试验方法中,直接剪切试验的干密度最高,孔隙率最低。对压实、固结和直剪试验中获得的最终状态参数进行了严格比较,这是本研究的新颖之处。本研究探索了不同尾矿的岩土力学特性信息,可以帮助采矿经营者和研究人员有效地设计和管理TSF中的尾矿。
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引用次数: 8
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Journal of King Saud University, Engineering Sciences
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