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Exploring puffed rice as a novel ink for 3D food printing: Rheological characterization and printability analysis 探索将膨化大米作为新型墨水用于 3D 食品打印:流变表征和打印性能分析
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-09-07 DOI: 10.1016/j.jfoodeng.2024.112313

This study introduces a novel approach by using puffed rice (PR) as a sustainable and innovative ink for 3D food printing. Due to gelatinization and dextrinization, PR saw notable water absorption and solubility gains, with a modest viscosity uptick from 39.2 to 49.9 RVU, sharply contrasting Native rice (NR)'s jump from 128.9 to 167.8 RVU, emphasizing PR's minimal retrogradation. Gelatinized rice (GR) demonstrates similar stability in viscosity changes as PR, yet it requires more water and extended processing times for gelatinization. Conversely, PR's puffing process, which eliminates the need for water, offers quicker preparation and notable environmental benefits. Rheological analysis at 25% PR concentration reveals an optimal balance of viscosity (η, 897.4 Pa s), yield stress (τy, 2471.3 Pa), and flow stress (τf, 1509.2 Pa), demonstrating superior viscoelastic properties that facilitate enhanced printability and shape fidelity. Texture Profile Analysis outcomes reveals that PR significantly enhances key textural properties including hardness, adhesiveness, and springiness at this specific concentration. These findings highlight PR's potential as an eco-friendly and efficient ink choice for 3D-printed food products, providing enhanced performance and sustainability compared to GR and NR.

本研究介绍了一种新方法,即将膨化大米(PR)作为一种可持续的创新墨水用于三维食品打印。经过糊化和糊精化处理后,膨化大米的吸水性和溶解性显著提高,粘度从 39.2 RVU 小幅上升至 49.9 RVU,与原生大米(NR)从 128.9 RVU 上升至 167.8 RVU 形成鲜明对比,凸显了膨化大米的最小逆变性。糊化米 (GR) 的粘度变化稳定性与 PR 相似,但它需要更多的水和更长的加工时间来糊化。相反,PR 的膨化过程无需用水,制备速度更快,而且具有显著的环保优势。25% PR 浓度下的流变分析表明,粘度(η,897.4 Pa s)、屈服应力(τy,2471.3 Pa)和流动应力(τf,1509.2 Pa)达到了最佳平衡,显示出卓越的粘弹性能,有助于提高印刷适性和形状保真度。纹理轮廓分析结果表明,在此特定浓度下,PR 可显著增强关键纹理特性,包括硬度、粘合性和回弹性。这些研究结果凸显了 PR 作为 3D 打印食品的环保型高效油墨的潜力,与 GR 和 NR 相比,PR 的性能和可持续性更强。
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引用次数: 0
Preparation and characterization of pickering emulsions stabilized by zein/quercetin/quaternary ammonium chitosan composite nanoparticles with antibacterial effect 具有抗菌效果的玉米蛋白/槲皮素/季铵壳聚糖复合纳米粒子稳定的挑染乳剂的制备与表征
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-09-05 DOI: 10.1016/j.jfoodeng.2024.112305

The role of nanoparticles in the stabilizing interface is very important in the preparation of stable Pickering emulsions. In this study, ternary composite nanoparticles (ZQ-HC) were synthesized by complexing zein-quercetin covalent complex (ZQ) with quaternary ammonium chitosan (HTCC) and subsequently stabilized Pickering emulsions (ZQ-HC) with antibacterial activity. Results revealed that HTCC covers the surface of ZQ nanoparticles successfully, which designates an effective improvement in the surface wettability of ZQ effectively. Among them, ZQ-HC2:1 possesses the closest three-phase contact angle of 90° and the highest emulsification activity and emulsion stability. The results of ultra-high resolution microscopy showed that ZQ-HC nanoparticles were adsorbed at the oil-water interface to prevent droplet aggregation and improved the pH, ionic strength, and storage stability of the prepared Pickering emulsions. ZQ-HC nanoparticles construct an antioxidant barrier at the oil-water interface, improving the lipid oxidation stability of the emulsion. The ZQ-HC2:1 stabilized Pickering emulsion exhibits the most superior stability and strongest antibacterial activity against other emulsions. The ZQ-HC stabilized Pickering emulsions prepared in this study exhibit potential for use as carriers of bioactive ingredients in food applications.

纳米粒子在稳定界面中的作用对于制备稳定的皮克林乳剂非常重要。本研究通过将玉米素-槲皮素共价复合物(ZQ)与季铵壳聚糖(HTCC)复配,合成了三元复合纳米粒子(ZQ-HC),并随后稳定了具有抗菌活性的皮克林乳剂(ZQ-HC)。结果表明,HTCC 成功地覆盖了 ZQ 纳米粒子的表面,从而有效地改善了 ZQ 的表面润湿性。其中,ZQ-HC2:1 的三相接触角最接近 90°,乳化活性和乳化稳定性最高。超高分辨率显微镜的结果表明,ZQ-HC 纳米粒子吸附在油水界面上,防止了液滴的聚集,并改善了制备的皮克林乳液的 pH 值、离子强度和储存稳定性。ZQ-HC 纳米粒子在油水界面构建了抗氧化屏障,提高了乳液的脂质氧化稳定性。与其他乳液相比,ZQ-HC2:1 稳定型皮克林乳液具有最优异的稳定性和最强的抗菌活性。本研究制备的 ZQ-HC 稳定皮克林乳液具有在食品应用中用作生物活性成分载体的潜力。
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引用次数: 0
Fat crystallization, partial coalescence and melting resistance of ice cream with lauric diacylglycerol oil 含月桂二酰甘油的冰淇淋的脂肪结晶、部分凝聚和抗熔性
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-09-04 DOI: 10.1016/j.jfoodeng.2024.112304

Lauric acid-rich diacylglycerols (DAG) prepared from coconut oil (CO) and palm kernel stearin (PKST) were applied as lipid materials for ice cream. The influences of emulsifiers: glycerin monostearate (MSG), sucrose esters (S1170 and S1670) on the CO/PKST–DAG crystallization and properties of emulsions were evaluated. The CO/PKST–DAGs showed broad peaks with increased crystallization onsets, and the heterogeneous nucleation sites led to the formation of large crystals. DAG–emulsions presented higher partial coalescence degree but improved physical stability without guar gum addition. The emulsions showed strengthened network and good anti-melting properties with large droplet clusters around air bubbles. Lipophilic MSG promoted interfacial nucleation and increased the partial coalescence degree and emulsion rigidity, whereas S1670 reduced the partial coalescence and accelerated the melting process. CO/PKST-DAG formed fat crystallization network with >1.4 fold higher hardness than those of CO/PKST emulsion. Therefore, the CO/PKST-DAGs are promising lipid materials for fabricating melt-resistance ice creams. The rigidity and melting behavior can be further tailored by different emulsifiers.

由椰子油(CO)和棕榈仁硬脂(PKST)制备的富含月桂酸的二酰甘油(DAG)被用作冰淇淋的脂质材料。评估了乳化剂:单硬脂酸甘油酯(MSG)、蔗糖酯(S1170 和 S1670)对 CO/PKST-DAG 结晶和乳液特性的影响。CO/PKST-DAG 显示出宽阔的峰值,结晶起始点增加,异质成核点导致大晶体的形成。DAG 乳液的部分凝聚度较高,但在不添加瓜尔胶的情况下物理稳定性有所提高。乳液显示出强化的网络和良好的抗熔化性能,气泡周围有大液滴簇。亲脂性味精促进了界面成核,增加了部分凝聚度和乳液硬度,而 S1670 则减少了部分凝聚,加速了熔化过程。CO/PKST-DAG 形成的脂肪结晶网络的硬度比 CO/PKST 乳液的硬度高出 1.4 倍。因此,CO/PKST-DAG 是制造抗融化冰淇淋的理想脂质材料。不同的乳化剂可进一步调整其硬度和融化性能。
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引用次数: 0
Exploring the emulsifying properties of biopolymers from Ulva lactuca in stabilizing high internal phase emulsions 探索莼菜生物聚合物在稳定高内相乳液中的乳化特性
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-09-02 DOI: 10.1016/j.jfoodeng.2024.112303

Seaweed is a promising raw material for food emulsion stabilizers due to its abundance, low cost, and rich content of various natural biological macromolecules. This study explores the potential of using Ulva lactuca (UL) to stabilize emulsions by employing high-pressure homogenization (HPH) to release its interfacial active components. The results demonstrate that UL extract (ULE) with emulsifying activity was gradually extracted as the HPH pressure increased from 100 to 800 MPa. Concentrating the macromolecular components, specifically polysaccharides and proteins, in the ULE via membrane filtration resulted in a concentrated fraction, referred to as ULER, which exhibited enhanced emulsification performance. By optimizing the oil volume fraction (φ) and pH, it was found that high internal phase emulsions (φ = 0.7–0.8) showed superior viscoelasticity and stability at pH 3–7. In terms of stability, it was observed that the emulsions stabilized by ULER maintained their structure over extended periods without significant phase separation. The strong interaction between exogenous Ca2⁺ and ULER increased the apparent viscosity and viscoelasticity of the emulsion. However, the addition of Ca2⁺ did not significantly enhance the stability of the ULER-stabilized emulsions and, in some cases, even led to a decrease in emulsion stability. This effect may be probably due to the specific interactions between the Ca2⁺ ions and the polysaccharides and proteins in the ULER, which can affect the network structure of the emulsion. Overall, this study highlights the potential of HPH treatment in processing UL to transform it into an effective emulsion stabilizer for applications in the food industry.

海藻资源丰富、成本低廉,而且富含各种天然生物大分子,因此是一种很有前景的食品乳液稳定剂原料。本研究利用高压均质法(HPH)释放海藻的界面活性成分,探索利用海藻(UL)稳定乳剂的潜力。结果表明,随着高压均质压力从100兆帕增加到800兆帕,具有乳化活性的UL提取物(ULE)逐渐被提取出来。通过膜过滤浓缩 ULE 中的大分子成分,特别是多糖和蛋白质,可得到浓缩部分,称为 ULER,其乳化性能得到增强。通过优化油体积分数(φ)和 pH 值,发现高内相乳剂(φ = 0.7-0.8)在 pH 值为 3-7 时表现出优异的粘弹性和稳定性。就稳定性而言,经 ULER 稳定的乳液在较长时间内都能保持其结构,没有明显的相分离现象。外源 Ca2⁺与 ULER 之间的强烈相互作用增加了乳液的表观粘度和粘弹性。然而,添加 Ca2⁺ 并没有显著提高 ULER 稳定乳液的稳定性,在某些情况下甚至导致乳液稳定性下降。造成这种影响的原因可能是 Ca2⁺离子与 ULER 中的多糖和蛋白质之间存在特殊的相互作用,会影响乳剂的网络结构。总之,这项研究强调了在加工超低分子量聚合酶时采用 HPH 处理将其转化为有效的乳液稳定剂以应用于食品工业的潜力。
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引用次数: 0
Nucleation mechanism in the absence and presence of an electric field 无电场和有电场时的成核机制
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-30 DOI: 10.1016/j.jfoodeng.2024.112302

The objective of this article is to investigate the mechanism of the ice nucleation process theoretically by assaying the thermodynamics of the ice nucleus as a small system, and experimentally verified by studying the effect of the static electric field on the ice nucleation process. Using the thermodynamic of small system related to Hill, we predicted that the equilibrium temperature of water and ice nucleus decreases with the reduction of nucleus size. By applying an electrostatic field, the Gibbs free energy of nucleus formation decreases due to this fact that the electrostatic work on the ice nucleus is lower than that for bulk water which it causes a decrease in the critical size of the ice nucleus. The experimental results showed that the nucleation temperature of water increases by applying the electric field with the voltage of 4.5 kV (internal strength of 2.2 × 104 V/m) while the size of ice crystals decreases in the frozen agar gel at the presence of electric field.

本文旨在通过测定作为小系统的冰核的热力学,从理论上研究冰核形成过程的机理,并通过研究静电场对冰核形成过程的影响进行实验验证。利用与希尔有关的小系统热力学,我们预测水和冰核的平衡温度随着冰核尺寸的减小而降低。在静电场的作用下,冰核形成的吉布斯自由能会降低,这是因为冰核的静电功低于散装水的静电功,从而导致冰核的临界尺寸减小。实验结果表明,施加电压为 4.5 kV(内部强度为 2.2 × 104 V/m)的电场后,水的成核温度升高,而在电场作用下,冷冻琼脂凝胶中冰晶的尺寸减小。
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引用次数: 0
Monitor and classify dough based on color image with deep learning 利用深度学习,根据彩色图像监控面团并对其进行分类
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-28 DOI: 10.1016/j.jfoodeng.2024.112299

To address subjective, time-consuming, and labor-intensive manual methods for monitoring and classifying fermenting dough, an automated and non-destructive method is proposed. Deep learning model YOLOv8s and extracted features including dough surface area, contrast, and homogeneity from RGB color images were employed to monitor fermenting dough. The features were input to a stacked ensemble model (SEM) with base models SVM, AdaBoost, KNN, and RF, with AdaBoost as meta-learner to classify fermenting dough into under-fermented, fermented, and over-fermented. SEM demonstrated a high dough classification rate of 83%, with specific rates of 75% for under-fermented, 71% for fermented, and 90% for over-fermented dough. Results reviewed that combining dough surface area and texture features is effective for monitoring dough, and can be used in adjusting chamber conditions. Furthermore, SEM showed great ability in classifying fermenting dough. The proposed method offers a promising solution for improved bread quality and consistency in bread-making.

为了解决监测和分类发酵面团的主观、耗时和耗力的人工方法,提出了一种自动化和非破坏性的方法。利用深度学习模型 YOLOv8s 和从 RGB 彩色图像中提取的面团表面积、对比度和均匀性等特征来监测发酵面团。这些特征被输入到以 SVM、AdaBoost、KNN 和 RF 为基础模型,以 AdaBoost 为元学习器的堆叠集合模型(SEM)中,将发酵面团分为发酵不足、发酵和发酵过度。SEM 的面团分类率高达 83%,发酵不足的面团分类率为 75%,发酵的面团分类率为 71%,发酵过度的面团分类率为 90%。结果表明,结合面团表面积和质地特征可有效监测面团,并可用于调整腔室条件。此外,扫描电子显微镜在发酵面团的分类方面也显示出很强的能力。所提出的方法为提高面包质量和面包制作的一致性提供了一种很有前景的解决方案。
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引用次数: 0
Comparative analysis of twin-screw pressing and blending methods for walnut oleosome extraction: Yield, physical stability, and functionalities 双螺杆压榨法和混合法提取核桃油脂体的比较分析:产量、物理稳定性和功能性
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-24 DOI: 10.1016/j.jfoodeng.2024.112292

Walnuts are renowned for their rich oil content and nutritional value, imparting significant health benefits. Walnut oleosomes, naturally present in a pre-emulsified state, can be effectively extracted through aqueous methods. Mechanical processes, such as twin-crew pressing or blending, are commonly employed to disrupt cell walls and extract oleosomes. Our study focused on investigating these two methods under varying soaking pH for walnut oleosomes extraction to develop an efficient extraction process for large-scale production or specific applications. Results showed that the oil content of extracted oleosomes ranged from 84.5% to 89.5%, with no substantial differences noted. Twin-screw pressing significantly achieved higher extraction yields (53.3–57.8%) compared to blending (35.7–36.4%), while blending produced walnut oleosomes with higher zeta potential, viscosity, storage modulus, and smaller particle size, improving physical stability compared to blended samples. The soaking pH levels minimally impacted extraction efficiency and physicochemical attributes of the oleosomes. Overall, blending offered oleosomes with relatively better physical stability, while twin-screw pressing was more advantageous for higher yields, making it more commercially viable for large-scale production. This study underscored the efficiency of sustainable approach in harnessing walnut oleosomes for various industrial applications.

核桃以其丰富的油脂含量和营养价值而闻名,对健康大有裨益。核桃油质体以预乳化状态天然存在,可通过水性方法有效提取。通常采用双螺杆压榨或混合等机械工艺来破坏细胞壁并提取油脂体。我们的研究重点是研究这两种方法在不同浸泡酸碱度下提取核桃油质体的情况,以开发一种高效的提取工艺,用于大规模生产或特定应用。结果表明,提取的油脂体含油量从 84.5% 到 89.5%不等,没有明显差异。与混合(35.7-36.4%)相比,双螺杆压榨的提取率(53.3-57.8%)明显更高,而与混合样品相比,混合生产的核桃油质体具有更高的 zeta 电位、粘度、储存模量和更小的粒度,提高了物理稳定性。浸泡 pH 值对油脂体的提取效率和理化属性的影响最小。总体而言,混合样品能提供物理稳定性相对较好的油脂体,而双螺杆压榨在提高产量方面更具优势,使其在大规模生产中更具商业可行性。这项研究强调了利用核桃油质体进行各种工业应用的可持续方法的效率。
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引用次数: 0
Corrigendum (Authorship Correction) to “Designing and developing a programmable in vitro gastrointestinal model to assess the impact of pasteurization on the bioaccessibility of lycopene nanoparticles” [J. Food Eng. 382 (2024) 112211] 设计和开发可编程体外胃肠道模型以评估巴氏杀菌对番茄红素纳米粒子生物可及性的影响》[J. Food Eng. 382 (2024) 112211]的更正(作者更正]
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-24 DOI: 10.1016/j.jfoodeng.2024.112291
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引用次数: 0
Effect of temperature fluctuations on large yellow croaker fillets (Larimichthys crocea) in cold chain logistics: A microbiological and metabolomic analysis 温度波动对冷链物流中大黄鱼鱼片(Larimichthys crocea)的影响:微生物学和代谢组学分析
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-23 DOI: 10.1016/j.jfoodeng.2024.112290

Currently, aquatic products are mainly transported through cold chain logistics, which has been proven to significantly reduce the deterioration of quality and freshness. This study aimed to investigate the mechanisms of quality deterioration in large yellow croaker fillets under different cold chain conditions, specifically focusing on temperature fluctuations. Quality changes in the fillets were assessed through microbiological indicators and physicochemical properties. High-throughput sequencing was used to identify the microbial community structure, and LC-MS-based untargeted metabolomics identified the distinctive metabolites in the fillets under cold chain conditions. Notably, the group experiencing the greatest temperature fluctuations exhibited the highest pH value (7.15), trichloroacetic acid (TCA)-soluble peptides content (10.57 μmol tyrosine/g), total volatile basic nitrogen (TVB-N) content (34.91 mg N/100 g), and hypoxanthine (Hx) content (4.70 μmol/g), along with the lowest hypoxanthine ribonucleoside (HxR) content (1.67 μmol/g) and water holding capacity (WHC) value (79.22%). High-throughput sequencing results showed that the relative abundance of Aeromonas reached 54.01–56.95% in the temperature fluctuation groups on day 7.5. Additionally, the sharpest decrease in the relative abundance of Shewanella in temperature fluctuations groups was 70.16% lower than in the constant temperature group. Bioinformatics analyses further confirmed that amino acid metabolism was the most affected metabolic pathway due to temperature fluctuations in cold chain logistics. This study provides new insights that can improve the practical implementation of cold chain storage and preservation of fish.

目前,水产品主要通过冷链物流进行运输,事实证明,冷链物流可显著减少质量和新鲜度的下降。本研究旨在调查大黄鱼片在不同冷链条件下的质量劣变机制,特别关注温度波动。通过微生物指标和理化特性来评估鱼片的质量变化。利用高通量测序确定了微生物群落结构,基于 LC-MS 的非靶向代谢组学确定了冷链条件下鱼片中的独特代谢物。值得注意的是,温度波动最大的一组表现出最高的 pH 值(7.15)、三氯乙酸(TCA)-可溶性肽含量(10.57 μmol 酪氨酸/克)、总挥发性碱氮(TVB-N)含量(34.91 mg N/100 g)和次黄嘌呤(Hx)含量(4.70 μmol/g),以及最低的次黄嘌呤核糖核苷(HxR)含量(1.67 μmol/g)和持水量(WHC)值(79.22%)。高通量测序结果显示,温度波动组在第 7.5 天的气单胞菌相对丰度达到 54.01-56.95%。此外,温度波动组中的雪旺氏菌相对丰度下降幅度最大,比恒温组低 70.16%。生物信息学分析进一步证实,氨基酸代谢是冷链物流中受温度波动影响最大的代谢途径。这项研究提供了新的见解,有助于改进水产品冷链贮藏和保鲜的实际实施。
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引用次数: 0
Exploring the feasibility of biodegradable films for antimicrobial absorbent sachets and CO2 emitters as sustainable active packaging 探索将可生物降解薄膜用于抗菌吸收袋和二氧化碳排放器作为可持续活性包装的可行性
IF 5.3 2区 农林科学 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-22 DOI: 10.1016/j.jfoodeng.2024.112289

The use of biodegradable polymer films for packaging materials as eco-friendly alternatives to traditional plastics is limited by their water sensitivity and poor gas barrier properties. This study developed a multifunctional supplemental packaging system using poly(butylene adipate-co-terephthalate) (PBAT) and thermoplastic starch (TPS) blend film incorporated with 3% and 5% zinc oxide (ZnO) nanoparticles. The system targets the triple-active packaging displayed antimicrobial activity with water absorption and CO2 emission properties. ZnO incorporation effectively reduced water solubility of the PBAT/TPS film (from 16% to 7%), and exhibited excellent antimicrobial activity against Gram-positive and Gram-negative bacteria (>99% reduction). Well-dispersed ZnO, verified by scanning electron microscopy, decreased water vapor and CO2 gas permeation. A PBAT/TPS-ZnO sachet was fabricated, comprising carboxymethyl cellulose as the absorbent function and CO2 precursors (sodium bicarbonate and citric acid). The 3% ZnO loading achieved optimal performance, balancing water absorption (2.48 g weight gain after 144 h) and CO2 emission (35% in headspace at equilibrium). Kinetic studies suggested diffusion as the dominant mechanism for CO2 release, driven by concentration differences between the sachet and headspace. This system showed potential as active modified atmosphere packaging to extend product shelf life.

作为传统塑料的环保型替代品,生物可降解聚合物薄膜作为包装材料的使用受到了水敏感性和气体阻隔性差的限制。本研究利用掺入了 3% 和 5% 纳米氧化锌(ZnO)的聚己二酸丁二醇酯(PBAT)和热塑性淀粉(TPS)共混膜,开发了一种多功能补充包装系统。以三重活性包装为目标的系统显示出抗菌活性、吸水性和二氧化碳排放特性。氧化锌的加入有效降低了 PBAT/TPS 薄膜的水溶性(从 16% 降至 7%),并对革兰氏阳性和革兰氏阴性细菌表现出卓越的抗菌活性(减少 99%)。经扫描电子显微镜验证,分散良好的氧化锌可减少水蒸气和二氧化碳气体的渗透。我们制作了一种 PBAT/TPS-ZnO 小袋,其中包括具有吸收功能的羧甲基纤维素和二氧化碳前体(碳酸氢钠和柠檬酸)。3% 的 ZnO 负载实现了最佳性能,平衡了吸水(144 小时后重量增加 2.48 克)和二氧化碳排放(平衡时顶空 35%)。动力学研究表明,扩散是二氧化碳释放的主要机制,由小袋和顶空之间的浓度差驱动。该系统显示出作为活性改良气氛包装延长产品保质期的潜力。
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引用次数: 0
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Journal of Food Engineering
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