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Formation of gallium nanoparticles by thermal evaporation method 热蒸发法制备纳米镓
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2021-2-56-62
G. Kozhemyakin, Y. Belov, М. K. Trufanova, О. Е. Bryl
The conditions have been developed for obtaining of gallium (Ga) nanoparticles by thermal evaporation method in an argon atmosphere on glass carbon substrates. Ga particles research was carried out by the developed intelligent analysis method of the images of the micrographs obtained under a scanning electron microscope. It is shown, that temperature of glass carbon substrate and the condensation time of the melt determine number of the nanoparticles and microparticles. Ga nanoparticles with 10 – 100 nm sizes and microparticles with up to 500 nm sizes were formed on the substrates with the condensation time of 10 – 20 s. Ga nanoparticles had a shape close to spherical, and their amount increased with the increase of the condensation time. The increase of the substrate temperature from 118 to 124 °С provided the decrease of 20 % in the average sizes of most Ga nanoparticles and the increase of their number by a factor of 7 – 20.
研究了在氩气气氛下用热蒸发法制备纳米镓的条件。利用开发的智能分析方法对扫描电子显微镜下获得的显微图像进行了Ga颗粒的研究。结果表明,玻璃碳衬底温度和熔体凝结时间决定了纳米粒子和微粒子的数量。在10 ~ 20 s的缩聚时间内,在衬底上形成了10 ~ 100 nm尺寸的Ga纳米颗粒和500 nm尺寸的Ga微粒。Ga纳米颗粒的形状接近球形,且随着缩聚时间的增加,其数量增加。当衬底温度从118°升高到124°С时,大多数Ga纳米颗粒的平均尺寸减小了20%,其数量增加了7 - 20倍。
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引用次数: 0
Regularities of formation of the lattice structures produced by the method of selective laser melting of 316L steel powder 316L钢粉末选择性激光熔化法产生晶格结构的形成规律
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2019-6-52-61
M. Isaenkova, Y. Perlovich, A. Yudin, A. Rubanov, N. Zhuravlev, M. Saveliev, A. Dub
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引用次数: 0
Deposition of pseudo-alloy coating by electroarc metallization method 电弧金属化法沉积伪合金涂层
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2019-4-21-26
O. Elagina, V. Gusev, A. G. Buklakov, N. S. Nesterenko, K. O. Tomsky
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引用次数: 0
Mechanical effect of an electric field on nanostructure elements 电场对纳米结构元件的机械效应
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2021-3-79-82
V. P. Babaev, S. V. Zaitsev, K. A. Inshakova, A. N. Shaykin
A computational and experimental estimation of the magnitude of forces acting in a high-intensity electric field on elements of nanoconstructions with a high surface curvature is made. Depending on the magnitude of the electric potential and vacuum conditions, these forces can vary both in magnitude and direction over a wide range. They can cause structural damage, as well as provoke unwanted electrical discharges. The possibilities of useful application of these effects are analyzed.
对高强度电场作用在具有高表面曲率的纳米结构元件上的力的大小进行了计算和实验估计。根据电势和真空条件的大小,这些力在大小和方向上都可以在很大的范围内变化。它们会造成结构损坏,并引发不必要的放电。分析了这些效应有效应用的可能性。
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引用次数: 0
Directions of development of a non-waste plasma-electromagnetic technology for the reduction of d- and f-metals from refined volatile fluoride raw materials: Scientific and technical principles, technological evolution 从精制挥发性氟化物原料中还原d和f金属的非废等离子体电磁技术的发展方向:科学技术原理、技术演变
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2019-1-55-70
Y. Tumanov
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引用次数: 0
On the problems of creating shells of fuel rods from zirconium alloys for tolerant fuel 耐受性燃料用锆合金制燃料棒壳的若干问题
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2021-3-69-78
A. A. Yakushkin, As “Src Rf Triniti”
Three directions of the establishment of accident tolerant fuel cladding for light water reactors are actively exploring at present: 1) replacement zirconium alloy E110 for more corrosion-resistant material in accident operation conditions; 2) surface dispersion hardening or doping of the zirconium cladding of fuel element; 3) deposition a corrosion-resistant coating to the fuel cladding. The first direction requires significant and irreversible changes in fuel rod production technology and has long-term prospects. Conversely, the second direction suggest minimal changes in the fuel rod production technology, however, it has no significant effect on the high temperature oxidation kinetics of fuel claddings in steam. Using of a corrosion resistant coating results in a significant change in the high temperature oxidation kinetics of the zirconium alloy, (no transition to linear oxidation) that is related to maintaining the continuity of the oxide layer formed during oxidation. The issue provides a brief overview of the current state of research in the field of fuel, tolerant to the effects of coolant in emergency situations.
目前,轻水堆耐事故燃料包壳的建立有三个方向正在积极探索:1)在事故运行条件下,用更耐腐蚀的材料替代锆合金E110;2)燃料元件锆包层表面分散硬化或掺杂;3)在燃料包壳上沉积一层耐腐蚀涂层。第一个方向需要燃料棒生产技术发生重大且不可逆转的变化,并且具有长期前景。相反,第二个方向表明燃料棒生产技术的变化很小,但是,它对蒸汽中燃料包壳的高温氧化动力学没有显著影响。使用耐腐蚀涂层会导致锆合金的高温氧化动力学发生显著变化(不向线性氧化过渡),这与保持氧化过程中形成的氧化层的连续性有关。本刊简要概述了在紧急情况下可容忍冷却剂影响的燃料领域的研究现状。
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引用次数: 0
Structure and properties of rapidly solidified foils of triple Bi – In – Sn alloy and solder joint based on it 双银锡三元合金快速凝固箔片及其焊点的组织与性能
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2022-2-65-70
V. Shepelevich, O. Gusakova, S. V. Husakova
The alloy Bi32In41Sn27 was produced by fusing the components in quarts ampoules. A piece of alloy of 0.2 g was heated and injected onto the inner polished surface of rapidly rotating copper cylinder with a diameter 20 cm. The alloy was solidified in the form of a foil up10 cm long and up to10 mm wide. Foils with a thickness of 30 – 100 micrometers were used for the study. The chemical compositions of the foil in the layers in contact with surface of the mold and the atmosphere are coincided within the measurement error. A rapidly solidified alloy Bi32In41Sn27 consists of ε-phase (BiIn) and γ-phase (Sn4In) having a dispersed structure. The average value of the chords dγ of random secants located on the sections of γ-phase and average value of the specific surface area of the interphase boundary Sε – γ, formed by ε- and γ-phases, depend on the expose time t at room temperature; their properties are described by equations d = 0,58 + 0,29lnt and Sε – γ = 2,9 − 0,43lnt, correspondly. The alloy foils have a microcrystalline structure and well-defined texture (0001) of the γ-phase and poorly expressed double (211) + (112) of the ε-phase. Texture are persist during annealing 60 °С for 2 hours. The microhardness of the alloy Bi32In41Sn27 foils monotonically increases with increasing expose time at room temperature and reaches saturation. Subsequent isothermal annealing at 60 °С leads to a microhardness value equal to it of massive sample. The distribution of components in the solder joint between copper plates was investigated. Indium and tin diffuse into the copper plates. The depth of penetration of copper into the joint reaches 3 micrometers. When the soldered copper plates are strained, the breakdown on the junction occurs at 790  N and absolute value of the deformation is 0.8 mm. The conducted investigations of copper solder joints indicate the possible practical use of the alloy Bi32In41Sn27 foil as a solder.
在夸脱安瓿中熔合制备了Bi32In41Sn27合金。将0.2 g的合金加热后注入直径为20 cm的高速旋转铜筒内抛光表面。合金被固化成长10厘米、宽10毫米的箔状。研究中使用了厚度为30 - 100微米的铝箔。与模具表面和大气接触层中铝箔的化学成分在测量误差范围内是一致的。快速凝固合金Bi32In41Sn27由ε相(BiIn)和γ相(Sn4In)组成,具有分散结构。室温下,位于γ相截面上的随机割线弦dγ的平均值和ε相和γ相形成的相间边界的比表面积Sε - γ的平均值随暴露时间t的变化而变化;分别用方程d = 0,58 + 0,29lnt和se ε - γ = 2,9−0,43lnt来描述它们的性质。合金箔具有微晶组织和清晰的γ-相织构(0001)和表达较差的ε-相双晶(211)+(112)。60°С退火2小时后,织构仍然存在。Bi32In41Sn27合金箔在室温下的显微硬度随暴露时间的增加而单调增加,并达到饱和。随后在60°С下进行等温退火,得到的显微硬度值等于块状样品的显微硬度值。研究了铜板间焊点中元件的分布。铟和锡扩散到铜板中。铜在接头中的渗透深度达到3微米。在790 N处发生击穿,变形绝对值为0.8 mm。对铜焊点进行的研究表明,合金Bi32In41Sn27箔作为焊料可能具有实际用途。
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引用次数: 0
Effect of pulsed photon treatment on electrophysical and thermal properties of n-type solid solution on the base of Bi2Te3-Bi2Se3. I. Electrophysical characteristics 脉冲光子处理对Bi2Te3-Bi2Se3基n型固溶体电物理和热性能的影响一、电物理特性
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2019-5-14-20
A. Grebennikov, A. I. Bocharov, S. B. Kushchev, D. Serikov, A. B. Kostyuchenko, E. Fedorova, I. V. Izvekova, I. Safonov, Military Educational
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引用次数: 3
Influence of heat treatment on the properties of antibacterial corrosion resistant steel 热处理对抗菌耐蚀钢性能的影响
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2022-3-67-73
М. А. Kaplan, S. V. Konushkin, K. V. Sergienko, B. Kartabaeva, А. D. Gorbenko, А. G. Kolmakov, А. Y. Ivannikov, М. А. Sevostyanov
The field of application of corrosion-resistant austenitic steel is wide due to its resistance to corrosion and oxidation, durability, high strength and ductility. Austenitic corrosion-resistant steel is of particular importance for medicine. Medical instruments and products are made from it. However, the environment is very corrosive to metals and can lead to protein adsorption, biofilm formation (attachment of microorganisms/bacteria to the surface of the material), and corrosion or itself become a source of bacterial contamination. Recent studies have shown that the addition of Ag and Ti to corrosion-resistant steels can impart antibacterial properties to them without the need for surface modification. The article is devoted to the study of the structure and mechanical properties of a new antibacterial corrosion-resistant steel. The structure was studied by light optical microscopy and X-ray diffractometry. The mechanical properties were studied by stretching the samples on a tensile testing machine. The effect of homogenizing annealing and ingot rolling on the structure of corrosion-resistant steel is shown. According to the test results, it has been established that heat treatment of steel makes it possible to increase the ductility of steel. After rolling, the plates have a fine-grained structure. Normalization at 900 °C and 1000 °C relieves internal stresses and reduces the proportion of ferrite in the structure.
耐腐蚀奥氏体钢具有抗腐蚀、抗氧化、耐久性好、强度高、延展性好等优点,应用领域十分广泛。奥氏体耐腐蚀钢在医药领域具有特别重要的意义。医疗器械和产品都是由它制成的。然而,环境对金属具有很强的腐蚀性,可导致蛋白质吸附、生物膜形成(微生物/细菌附着在材料表面)、腐蚀或本身成为细菌污染的来源。最近的研究表明,在耐腐蚀钢中添加Ag和Ti可以使其具有抗菌性能,而无需对其表面进行改性。本文研究了一种新型抗菌耐蚀钢的结构和力学性能。用光学显微镜和x射线衍射仪对其结构进行了研究。在拉伸试验机上对试样进行拉伸,研究了试样的力学性能。研究了均匀化退火和铸锭轧制对耐蚀钢组织的影响。试验结果表明,对钢进行热处理可以提高钢的延展性。轧制后,板材具有细晶粒结构。900℃和1000℃正火可以消除内应力,降低组织中铁素体的比例。
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引用次数: 0
Factors and mechanisms of elongation of VVER-1000 fuel rods during thermal tests simulating dry storage modes 模拟干贮存模式的热试验中VVER-1000燃料棒伸长的因素和机理
Pub Date : 1900-01-01 DOI: 10.30791/0015-3214-2022-1-66-77
G. P. Kobylyanskij, A. Mazaev, E. A. Zvir, P. A. Il’in, P. I. Grin’, E. V. Chertopyatov, A. V. Obuhov
To prove safety of dry storage conditions, thermal tests of the VVER-1000 fuel rods were performed in electrically heated furnaces in helium gas environment under stationary conditions (they were held at Т = 380 °С for 468 days) and thermal cycling ones (48 temperature cycles in a temperature range of 20 to 380 °С) with duration of cycles varying from 1 to 10 days and the total time of thermal testing of 427 days). The effect of thermal testing on elongation of fuel rods, which were under operation in the VVER-1000 reactors for one year (burnup was ~ 20 (MW⋅days)/kgU) and for six years (burnup was ~ 70 (MW⋅days)/kgU), was studied. It was revealed that high-burnup fuel rods elongated less compared to low burnup fuel rods. The highest elongation values were obtained for the low-burnup fuel rods: it made up 6.0 mm under the stationary operating conditions and 9.5 mm under thermal cycling. Hoop strain of fuel rods increased insignificantly. As there was gas pressure under the cladding, it induced tensile stresses in it at a temperature of 380 °С and thus, stimulated thermal creep. Lower burnup fuel rods could preserve their fuel-cladding gap throughout the entire height of their fuel columns. A model of gas-filled tubular specimen with a textured cladding in which the effective axial stress is enhanced by additional tensile load due to the pressure from fuel column on the spring plunger and a greater recovery of yield strength in the longitudinal direction compared to the transverse one, is applicable to these fuel rods. For high-burnup fuel rods, this model is applicable to for that part of the cladding where it is not in contact with the fuel, i.e. for a shorter length compared to low-burnup fuel rods. Thus, the idea was proved according to which the main mechanism of fuel rod elongation is the thermal creep of the cladding induced by enhanced (due to anisotropic recovery of the yield strength) effective axial stresses resulted from the fuel gas and fuel column pressure on the spring plunger. Thermal cycling leads to greater elongation of fuel rods due to a higher creep rate of the cladding at the unsteady-state stage during short cycles.
为了证明干贮存条件的安全性,对VVER-1000燃料棒进行了固定条件下氦气环境下的电热炉热试验(在Т = 380°С温度下保持468天)和热循环试验(在20 ~ 380°С温度范围内进行48个温度循环),循环时间从1天到10天不等,热试验总时间为427天)。研究了在VVER-1000反应堆中运行1年(燃耗~ 20 (MW⋅days)/kgU)和6年(燃耗~ 70 (MW⋅days)/kgU)的热试验对燃料棒伸长率的影响。结果表明,与低燃耗燃料棒相比,高燃耗燃料棒的延长幅度较小。低燃耗燃料棒的伸长率最高:在固定工况下伸长率为6.0 mm,在热循环工况下伸长率为9.5 mm。燃料棒环向应变增加不显著。由于熔覆层下存在气体压力,在380°С的温度下产生拉应力,从而激发热蠕变。低燃耗燃料棒可以在燃料柱的整个高度保持燃料包层间隙。一种具有纹理包层的充气管状试样模型适用于这些燃料棒,其中有效轴向应力由于燃料柱对弹簧柱塞的压力而被额外的拉伸载荷所增强,并且在纵向上比在横向上有更大的屈服强度恢复。对于高燃耗燃料棒,该模型适用于包壳不与燃料接触的部分,即与低燃耗燃料棒相比,包壳长度较短。由此证明了燃料棒延伸的主要机理是由燃料气体和燃料柱压力对弹簧柱塞产生的有效轴向应力增强(由于屈服强度的各向异性恢复)引起的包层热蠕变。在短循环过程中,由于包层在非稳态阶段的蠕变速率较高,热循环导致燃料棒的伸长较大。
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Physics and Chemistry of Materials Treatment
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