首页 > 最新文献

Journal of Nuclear Fuel Cycle and Waste Technology最新文献

英文 中文
Feasibility Study on Power Ramp Test Under Atmospheric Pressure and Ordinary Temperature 常压常温下功率斜坡试验的可行性研究
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-93417
Xiangyu Wei, Wenhua Zhang, Yingchun Zhao
Pellet-to-cladding mechanical interaction is an important physical phenomenon during reactor power change as well as a multi-phenomenal fuel rod failure mechanism involving stress, strain and material irradiation properties. In order to avoid the failure caused by PCMI, a large number of power ramp tests have been carried out by international organizations over the past decades. The typical way of power ramp test in a high temperature and pressure loop requires stringent test capabilities and high test costs. The key parameters of the PCMI phenomena are stress and strain of cladding, which are generally chosen as the evaluation indicators of PCMI. If it is possible to simulate the pellet-to-cladding contact state, i.e. the gap between pellet and cladding under basic irradiation power level in atmospheric pressure and ordinary temperature environment, then the high stress and strain state of the cladding during the subsequent power ramp test could also be simulated in the same environment, which means lower test costs and test loop requirements. Therefore, a sensitivity analysis using the fuel rod performance analysis code RoPE, was carried out on factors such as initial pellet-to-cladding gap and fuel densification in the power ramp test rod design. By adapting the manufacturing parameters of the test rod and coolant conditions, the high stress and strain state of the cladding could be simulated in the test environment at normal temperature and pressure. The sensitivity analysis provides a theoretical basis for conducting power ramp tests in an atmospheric pressure and ordinary temperature loop.
球团-包壳力学相互作用是反应堆功率变化过程中重要的物理现象,是一种涉及应力、应变和材料辐照特性的多现象燃料棒失效机制。为了避免PCMI引起的故障,国际组织在过去几十年中进行了大量的功率斜坡试验。在高温高压回路中进行典型的功率斜坡测试需要严格的测试能力和较高的测试成本。熔覆层的应力和应变是影响熔覆现象的关键参数,通常作为熔覆层应力和应变的评价指标。如果能够模拟常压和常温环境下基本辐照功率水平下球团与包层的接触状态,即球团与包层之间的间隙,那么在相同的环境下也可以模拟后续功率斜坡试验中包层的高应力应变状态,从而降低试验成本和试验回路要求。因此,利用燃料棒性能分析程序RoPE,对动力斜坡试验棒设计中的初始球团与包壳间隙和燃料密度等因素进行敏感性分析。通过调整试验棒的制造参数和冷却剂条件,可以模拟常温常压试验环境下熔覆层的高应力应变状态。灵敏度分析为在常压和常温回路中进行功率斜坡试验提供了理论依据。
{"title":"Feasibility Study on Power Ramp Test Under Atmospheric Pressure and Ordinary Temperature","authors":"Xiangyu Wei, Wenhua Zhang, Yingchun Zhao","doi":"10.1115/icone29-93417","DOIUrl":"https://doi.org/10.1115/icone29-93417","url":null,"abstract":"\u0000 Pellet-to-cladding mechanical interaction is an important physical phenomenon during reactor power change as well as a multi-phenomenal fuel rod failure mechanism involving stress, strain and material irradiation properties. In order to avoid the failure caused by PCMI, a large number of power ramp tests have been carried out by international organizations over the past decades. The typical way of power ramp test in a high temperature and pressure loop requires stringent test capabilities and high test costs. The key parameters of the PCMI phenomena are stress and strain of cladding, which are generally chosen as the evaluation indicators of PCMI. If it is possible to simulate the pellet-to-cladding contact state, i.e. the gap between pellet and cladding under basic irradiation power level in atmospheric pressure and ordinary temperature environment, then the high stress and strain state of the cladding during the subsequent power ramp test could also be simulated in the same environment, which means lower test costs and test loop requirements. Therefore, a sensitivity analysis using the fuel rod performance analysis code RoPE, was carried out on factors such as initial pellet-to-cladding gap and fuel densification in the power ramp test rod design. By adapting the manufacturing parameters of the test rod and coolant conditions, the high stress and strain state of the cladding could be simulated in the test environment at normal temperature and pressure. The sensitivity analysis provides a theoretical basis for conducting power ramp tests in an atmospheric pressure and ordinary temperature loop.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"46 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83728750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on UC Phase Control of UC Ceramic Microspheres Prepared by Sol-Gel Method 溶胶-凝胶法制备UC陶瓷微球的UC相控制研究
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-92188
Feng Wen, Bolong Guo, Mingyang Li, Jiachen Wang, Fan Zhang, W. Liu, Wenkai Ma, Zhihua Liu
Since uranium carbide (UC) fuel has higher thermal conductivity and uranium density than UO2 fuel, good inherent safety and economy can be achieved by UC dispersion fuel. This paper focuses on the research of UC phase control during sol-gel preparation of UC ceramic microsphere. Using nano-carbon black powder as carbon source, UC ceramic microspheres were prepared by sol-gel process combined with carbothermal reaction process. Specific amount of carbon black was uniformly added into the glue solution, which was then dispersed to prepare carbon ADU gel spheres. With heat treatment of carbon ADU gel spheres subject to carbothermic reaction, ceramic microspheres containing UC phase were obtained. During the experiment, the effects of different carbon black addition ratio, thickener addition level and dispersion process on the chemical composition, sphericity and surface morphology on UC ceramic microspheres were investigated. The effects of heat treatment temperature, atmosphere and pressure on the preparation of UC microspheres were also studied during the carbothermic experiment. The process parameters for UC phase control were determined through the experiment and XRD, and the ceramic microsphere samples containing the UC phase were obtained as well. Analysis results show that crack-free UC microspheres with smooth surface can be obtained after drying when sol solution C/U is 2.5∼6.0 and thickener addition level is 1.2∼2.0 kg/kgU. By reaction treatment at high temperature, ceramic microspheres with good sphericity, compact structure and UC phase composition were obtained. A preparation method of UC ceramic microspheres was developed as a result.
由于碳化铀(UC)燃料具有比UO2燃料更高的导热系数和铀密度,因此使用UC分散燃料可以获得较好的固有安全性和经济性。本文主要研究了溶胶-凝胶法制备UC陶瓷微球过程中UC相控制问题。以纳米炭黑粉末为碳源,采用溶胶-凝胶法结合碳热反应法制备UC陶瓷微球。在胶液中均匀加入一定量的炭黑,分散制备碳ADU凝胶球。对碳ADU凝胶球进行碳热反应热处理,得到了含UC相的陶瓷微球。在实验中,考察了不同炭黑添加比、增稠剂添加量和分散工艺对UC陶瓷微球化学成分、球度和表面形貌的影响。在碳热实验中研究了热处理温度、气氛和压力对UC微球制备的影响。通过实验和XRD确定了UC相控制的工艺参数,获得了含UC相的陶瓷微球样品。分析结果表明,当溶胶溶液C/U为2.5 ~ 6.0,增稠剂添加量为1.2 ~ 2.0 kg/kgU时,干燥后可获得表面光滑的无裂纹UC微球。通过高温反应处理,制得球形度好、结构致密、相组成UC的陶瓷微球。研究了UC陶瓷微球的制备方法。
{"title":"Study on UC Phase Control of UC Ceramic Microspheres Prepared by Sol-Gel Method","authors":"Feng Wen, Bolong Guo, Mingyang Li, Jiachen Wang, Fan Zhang, W. Liu, Wenkai Ma, Zhihua Liu","doi":"10.1115/icone29-92188","DOIUrl":"https://doi.org/10.1115/icone29-92188","url":null,"abstract":"\u0000 Since uranium carbide (UC) fuel has higher thermal conductivity and uranium density than UO2 fuel, good inherent safety and economy can be achieved by UC dispersion fuel. This paper focuses on the research of UC phase control during sol-gel preparation of UC ceramic microsphere. Using nano-carbon black powder as carbon source, UC ceramic microspheres were prepared by sol-gel process combined with carbothermal reaction process. Specific amount of carbon black was uniformly added into the glue solution, which was then dispersed to prepare carbon ADU gel spheres. With heat treatment of carbon ADU gel spheres subject to carbothermic reaction, ceramic microspheres containing UC phase were obtained. During the experiment, the effects of different carbon black addition ratio, thickener addition level and dispersion process on the chemical composition, sphericity and surface morphology on UC ceramic microspheres were investigated. The effects of heat treatment temperature, atmosphere and pressure on the preparation of UC microspheres were also studied during the carbothermic experiment. The process parameters for UC phase control were determined through the experiment and XRD, and the ceramic microsphere samples containing the UC phase were obtained as well. Analysis results show that crack-free UC microspheres with smooth surface can be obtained after drying when sol solution C/U is 2.5∼6.0 and thickener addition level is 1.2∼2.0 kg/kgU. By reaction treatment at high temperature, ceramic microspheres with good sphericity, compact structure and UC phase composition were obtained. A preparation method of UC ceramic microspheres was developed as a result.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"5 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73094391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Summary of Geometric Parameters and Their Effects on Performance of U-10Mo Fuel Plates U-10Mo燃料板几何参数及其对性能影响综述
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-93700
H. Ozaltun, H. Roh, W. Mohamed
A monolithic plate-type fuel system has been under development to convert high-performance test reactors from highly enriched uranium to low-enrichment uranium fuels and is now moving into the qualification phase, a predecessor to the timely conversion of the target reactors. To qualify this fuel system, the plates must meet the safety standards and perform well in a reactor. The plates must maintain mechanical integrity, exhibit geometric stability, and have stable and predictable in-reactor behavior. The requirement to maintain mechanical integrity under normal operating conditions is primarily demonstrated by successful testing. However, each high-performance reactor employs distinct design, resulting in distinct plate geometries, with unique features, attributes, irregularities, and tolerances. Due to the abundance of such distinct geometric varieties, a single “generic” plate geometry capturing all the extremes is not achievable. It is also impractical to test each of these proposed designs in a reactor. This limitation necessitates cautious evaluations since the thermo-mechanical response of a plate with a certain geometry may not be representative for a plate with a significantly different geometry. To address concerns related to in-reactor performance of the plates, large set of sensitivity studies were performed. These parametric studies aimed to better understand irradiation performance, while evaluating the sensitivity of results to various modeling inputs, including geometric, operational, and material parameters. This work studied selected geometric parameters based on provided fuel specifications and performed a series of parametric simulations. The resulting temperature, displacement and stress-strains were comparatively evaluated to determine the effects of various geometric parameters. This draft provides a “high-level summary” of parametric sensitivity studies performed and summarizes the key findings from those studies.
目前正在开发一种整体板型燃料系统,用于将高性能试验反应堆从高浓缩铀转换为低浓缩铀燃料,目前正在进入鉴定阶段,这是目标反应堆及时转换的前身。为了使这种燃料系统合格,这些板必须符合安全标准,并在反应堆中表现良好。板必须保持机械完整性,表现出几何稳定性,并具有稳定和可预测的反应器内行为。在正常操作条件下保持机械完整性的要求主要通过成功的测试来证明。然而,每个高性能反应器都采用不同的设计,导致不同的板几何形状,具有独特的特征,属性,不规则性和公差。由于这种不同的几何品种的丰富,单一的“通用”板几何捕获所有极端是不可能实现的。在反应堆中测试每一种提议的设计也是不切实际的。这种限制需要谨慎评估,因为具有特定几何形状的板的热机械响应可能不能代表具有显著不同几何形状的板。为了解决与板的反应器内性能有关的问题,进行了大量的灵敏度研究。这些参数研究旨在更好地了解辐照性能,同时评估结果对各种建模输入的敏感性,包括几何、操作和材料参数。本文根据所提供的燃料规格,研究了选定的几何参数,并进行了一系列参数模拟。对比评价了温度、位移和应力-应变的影响,确定了不同几何参数的影响。本草案提供了所进行的参数敏感性研究的“高级摘要”,并总结了这些研究的主要发现。
{"title":"Summary of Geometric Parameters and Their Effects on Performance of U-10Mo Fuel Plates","authors":"H. Ozaltun, H. Roh, W. Mohamed","doi":"10.1115/icone29-93700","DOIUrl":"https://doi.org/10.1115/icone29-93700","url":null,"abstract":"\u0000 A monolithic plate-type fuel system has been under development to convert high-performance test reactors from highly enriched uranium to low-enrichment uranium fuels and is now moving into the qualification phase, a predecessor to the timely conversion of the target reactors. To qualify this fuel system, the plates must meet the safety standards and perform well in a reactor. The plates must maintain mechanical integrity, exhibit geometric stability, and have stable and predictable in-reactor behavior. The requirement to maintain mechanical integrity under normal operating conditions is primarily demonstrated by successful testing. However, each high-performance reactor employs distinct design, resulting in distinct plate geometries, with unique features, attributes, irregularities, and tolerances. Due to the abundance of such distinct geometric varieties, a single “generic” plate geometry capturing all the extremes is not achievable. It is also impractical to test each of these proposed designs in a reactor. This limitation necessitates cautious evaluations since the thermo-mechanical response of a plate with a certain geometry may not be representative for a plate with a significantly different geometry. To address concerns related to in-reactor performance of the plates, large set of sensitivity studies were performed. These parametric studies aimed to better understand irradiation performance, while evaluating the sensitivity of results to various modeling inputs, including geometric, operational, and material parameters. This work studied selected geometric parameters based on provided fuel specifications and performed a series of parametric simulations. The resulting temperature, displacement and stress-strains were comparatively evaluated to determine the effects of various geometric parameters. This draft provides a “high-level summary” of parametric sensitivity studies performed and summarizes the key findings from those studies.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"45 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73827670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preliminary Sensitivity and Uncertainty Analysis of Accident Tolerant Fuel in SMR SMR中容错燃料的敏感性和不确定性初步分析
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-92887
Yuxuan Liang, Xiang Wang
As the technology of small modular reactor (SMR) becomes mature, its safety is getting more attention. In recent research of accident tolerant fuel (ATF) such as the U3Si2 used in a large commercial pressurized water reactor can significantly improve the safety of the core due to its high thermal conductivity and good physicochemical properties. Therefore, applying the ATF in the SMR can also enhance its safety. The mPower with a thermal power output of 530 MW designed by B&W company is selected as one of the SMR. In the design and production process of fuel rods, the design and manufacturing parameters such as fuel pellet diameter, inner diameter of cladding, fuel pellet density and other parameters have uncertain factors. These factors affect the results of effective multiplication factor (keff). In this work, we carried out preliminary sensitivity and uncertainty analysis of the U3Si2 with accident tolerant cladding (FeCrAl, SiC) in mPower using SEPRENT and DAKOTA. Sensitivity analysis performed the relative importance of each input parameters for different ATF combination. Uncertainty analysis gave the tolerance range and uncertainty for different ATF combination.
随着小型模块化反应堆技术的日趋成熟,其安全性越来越受到人们的重视。近年来在大型商用压水堆中使用的事故容忍燃料(ATF) U3Si2由于其高导热性和良好的物理化学性质,可以显著提高堆芯的安全性。因此,在SMR中应用ATF也可以提高SMR的安全性。B&W公司设计的热电输出功率为530兆瓦的mPower被选为SMR之一。在燃料棒的设计生产过程中,燃料球团直径、包壳内径、燃料球团密度等设计制造参数存在不确定因素。这些因素都会影响有效乘法系数(keff)的计算结果。在这项工作中,我们使用sepret和DAKOTA对mPower中具有事故耐受包层(FeCrAl, SiC)的U3Si2进行了初步的灵敏度和不确定度分析。敏感性分析分析了不同ATF组合下各输入参数的相对重要性。不确定度分析给出了不同ATF组合的容差范围和不确定度。
{"title":"Preliminary Sensitivity and Uncertainty Analysis of Accident Tolerant Fuel in SMR","authors":"Yuxuan Liang, Xiang Wang","doi":"10.1115/icone29-92887","DOIUrl":"https://doi.org/10.1115/icone29-92887","url":null,"abstract":"\u0000 As the technology of small modular reactor (SMR) becomes mature, its safety is getting more attention. In recent research of accident tolerant fuel (ATF) such as the U3Si2 used in a large commercial pressurized water reactor can significantly improve the safety of the core due to its high thermal conductivity and good physicochemical properties. Therefore, applying the ATF in the SMR can also enhance its safety. The mPower with a thermal power output of 530 MW designed by B&W company is selected as one of the SMR. In the design and production process of fuel rods, the design and manufacturing parameters such as fuel pellet diameter, inner diameter of cladding, fuel pellet density and other parameters have uncertain factors. These factors affect the results of effective multiplication factor (keff). In this work, we carried out preliminary sensitivity and uncertainty analysis of the U3Si2 with accident tolerant cladding (FeCrAl, SiC) in mPower using SEPRENT and DAKOTA. Sensitivity analysis performed the relative importance of each input parameters for different ATF combination. Uncertainty analysis gave the tolerance range and uncertainty for different ATF combination.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"2 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74020643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Fuel Management Strategy of LBE-Cooled Fast Reactor BLESS-D lbe冷却快堆BLESS-D燃料管理策略
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-90443
Zhen Luo, Eing Yee Yeoh, Xiaosong Chen, Linsen Li, Mian Xing
As one of the six nuclear reactor candidates selected by the Generation IV International Forum (GIF), lead-cooled fast reactor (LFR) has become one of the most promising concepts and attracted more attention from the institutes. A lead-bismuth eutectic (LBE) cooled fast reactor called BLESS-D has been proposed by State Power Investment Corporation Research Institute of China. The fuel management is critical to reactor design because it affects reactor economics. Although the research on fuel management of PWR has matured, there are few studies on fuel management for LFR. Fuel management design includes the entire process from initial cycle to transition cycle, and to equilibrium cycle. To obtain a better refueling scheme and optimize the key parameters of equilibrium cycle, a new refueling scheme is first proposed, and then traditionally, the simulation covering the entire refueling operation is required cycle by cycle, resulting in consuming a massive computing resource. If the scheme fails to meet expectations, expenditure will multiply until the modified scheme meets the safety design criteria. Fuel management design using “pseudo-equilibrium cycle” instead of traditional method is carried out in this work. The “pseudo-equilibrium cycle” method can directly solve the core key parameters of equilibrium cycle by replacing fuel model with approximate nuclides densities estimated from initial core arrangement and refueling scheme. In this paper, a two-batch refueling scheme is proposed with “pseudo-equilibrium cycle” method and then transition cycle are designed to ensure the feasibility that the fresh core successfully transition to the “pseudo-equilibrium cycle” state. Afterwards, neutronics parameters are solved for each cycle from the fresh core and results show that when the burnup calculation comes to the 5th cycle, the reactor key parameters, including assembly peaking factor, linear power density, delayed neutron fraction, and prompt neutron lifetime are in good agreement with “pseudo-equilibrium cycle”, which proves that the “pseudo-equilibrium cycle” method can be used accurately and efficiently to design the refueling scheme.
作为第四代国际论坛(GIF)选定的六个候选核反应堆之一,铅冷快堆(LFR)已成为最具发展前景的概念之一,受到了各研究所的广泛关注。中国国家电力投资集团研究院提出了一种铅铋共晶(LBE)冷却快堆——bliss - d。燃料管理是反应堆设计的关键,因为它影响反应堆的经济性。尽管对压水堆燃料管理的研究已经成熟,但对轻堆燃料管理的研究还很少。燃料管理设计包括从初始循环到过渡循环,再到平衡循环的全过程。为了获得更好的加注方案和优化平衡循环的关键参数,首先提出了一种新的加注方案,而传统的加注模拟是逐周期进行的,需要消耗大量的计算资源。如果方案未能达到预期,则支出将成倍增加,直到修改后的方案达到安全设计标准。本文采用“拟平衡循环”方法代替传统方法进行燃料管理设计。“拟平衡循环”方法通过用初始堆芯布置和换料方案估计的近似核素密度代替燃料模型,直接求解堆芯平衡循环的关键参数。本文提出了一种采用“伪平衡循环”方法的两批换料方案,并设计了过渡循环,以保证新鲜堆芯顺利过渡到“伪平衡循环”状态的可行性。结果表明,当燃耗计算到第5个循环时,反应堆的装配峰值因子、线性功率密度、延迟中子分数、提示中子寿命等关键参数与“伪平衡循环”基本吻合,证明了“伪平衡循环”方法可以准确、高效地用于换料方案设计。
{"title":"Fuel Management Strategy of LBE-Cooled Fast Reactor BLESS-D","authors":"Zhen Luo, Eing Yee Yeoh, Xiaosong Chen, Linsen Li, Mian Xing","doi":"10.1115/icone29-90443","DOIUrl":"https://doi.org/10.1115/icone29-90443","url":null,"abstract":"\u0000 As one of the six nuclear reactor candidates selected by the Generation IV International Forum (GIF), lead-cooled fast reactor (LFR) has become one of the most promising concepts and attracted more attention from the institutes. A lead-bismuth eutectic (LBE) cooled fast reactor called BLESS-D has been proposed by State Power Investment Corporation Research Institute of China. The fuel management is critical to reactor design because it affects reactor economics. Although the research on fuel management of PWR has matured, there are few studies on fuel management for LFR. Fuel management design includes the entire process from initial cycle to transition cycle, and to equilibrium cycle. To obtain a better refueling scheme and optimize the key parameters of equilibrium cycle, a new refueling scheme is first proposed, and then traditionally, the simulation covering the entire refueling operation is required cycle by cycle, resulting in consuming a massive computing resource. If the scheme fails to meet expectations, expenditure will multiply until the modified scheme meets the safety design criteria. Fuel management design using “pseudo-equilibrium cycle” instead of traditional method is carried out in this work. The “pseudo-equilibrium cycle” method can directly solve the core key parameters of equilibrium cycle by replacing fuel model with approximate nuclides densities estimated from initial core arrangement and refueling scheme. In this paper, a two-batch refueling scheme is proposed with “pseudo-equilibrium cycle” method and then transition cycle are designed to ensure the feasibility that the fresh core successfully transition to the “pseudo-equilibrium cycle” state. Afterwards, neutronics parameters are solved for each cycle from the fresh core and results show that when the burnup calculation comes to the 5th cycle, the reactor key parameters, including assembly peaking factor, linear power density, delayed neutron fraction, and prompt neutron lifetime are in good agreement with “pseudo-equilibrium cycle”, which proves that the “pseudo-equilibrium cycle” method can be used accurately and efficiently to design the refueling scheme.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"98 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83589454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Creep Performance and Microstructure Evolution of IN617 at 950 °C for VHTR Applications 950°C下VHTR用IN617的蠕变性能和微观结构演变
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-88939
Yue Wang, Haitao Wang, Kejian Li
IN617 was considered the primary material candidate for the IHX in the VHTR. Researching microstructure evolution during high-temperature creep of IN617 helped understand its fracture laws and guide IHX operation under creep loading. Creep tests of IN617 were conducted under 19 MPa, 24 MPa, 27 MPa, and 38 MPa at 950 °C. Creep rupture mechanisms of IN617 were discussed by correlating creep performance, microstructure characteristics and fracture-surface morphology. The results indicated that DRX, creep voids and brittle-phase precipitation were found under different stresses during microstructure observation, which would cause the specimen ductile rupture, intergranular rupture and brittle rupture, respectively. Specifically, under the highest stress 38 MPa, DRX occurred and grain size was decreased greatly to 11.1 μm from 99.7 μm. Fine grains were easy to migrate, causing significant plastic deformation and ductile rupture of specimens. With stress decreased to 27 MPa, grain boundaries became vulnerable and intergranular rupture occurred because intergranular carbides dissolved and their pinning effect was weakened. As stresses were lowered to 24 MPa and 19 MPa, nitrogen was diffused into specimens and brittle nitrides precipitated into continuous networks along GBs. The internal cracking of nitride networks caused brittle rupture. Meanwhile, steady creep rates were increased, and creep rupture lives were shortened greatly, especially under 19 MPa.
IN617被认为是VHTR中IHX的主要候选材料。研究IN617高温蠕变过程中的微观组织演变,有助于了解其断裂规律,指导IHX在蠕变载荷下的运行。对IN617进行了950℃下19 MPa、24 MPa、27 MPa和38 MPa的蠕变试验。从蠕变性能、微观组织特征和断口形貌等方面探讨了IN617的蠕变断裂机理。结果表明:显微组织观察发现,在不同应力下存在DRX、蠕变空洞和脆性相析出,分别导致试样的韧性断裂、晶间断裂和脆性断裂。在最高应力38 MPa下,晶粒尺寸由99.7 μm大幅减小至11.1 μm。细小晶粒易迁移,导致试样发生明显的塑性变形和延性断裂。当应力降低到27 MPa时,晶界变得脆弱,晶间碳化物溶解,钉钉作用减弱,导致晶间破裂。当应力降低到24 MPa和19 MPa时,氮扩散到试样中,脆性氮化物沿gb沿连续网络析出。氮化网络的内部裂纹导致脆性断裂。同时,稳定蠕变速率增加,蠕变破裂寿命大大缩短,特别是在19 MPa下。
{"title":"Creep Performance and Microstructure Evolution of IN617 at 950 °C for VHTR Applications","authors":"Yue Wang, Haitao Wang, Kejian Li","doi":"10.1115/icone29-88939","DOIUrl":"https://doi.org/10.1115/icone29-88939","url":null,"abstract":"\u0000 IN617 was considered the primary material candidate for the IHX in the VHTR. Researching microstructure evolution during high-temperature creep of IN617 helped understand its fracture laws and guide IHX operation under creep loading. Creep tests of IN617 were conducted under 19 MPa, 24 MPa, 27 MPa, and 38 MPa at 950 °C. Creep rupture mechanisms of IN617 were discussed by correlating creep performance, microstructure characteristics and fracture-surface morphology. The results indicated that DRX, creep voids and brittle-phase precipitation were found under different stresses during microstructure observation, which would cause the specimen ductile rupture, intergranular rupture and brittle rupture, respectively. Specifically, under the highest stress 38 MPa, DRX occurred and grain size was decreased greatly to 11.1 μm from 99.7 μm. Fine grains were easy to migrate, causing significant plastic deformation and ductile rupture of specimens. With stress decreased to 27 MPa, grain boundaries became vulnerable and intergranular rupture occurred because intergranular carbides dissolved and their pinning effect was weakened. As stresses were lowered to 24 MPa and 19 MPa, nitrogen was diffused into specimens and brittle nitrides precipitated into continuous networks along GBs. The internal cracking of nitride networks caused brittle rupture. Meanwhile, steady creep rates were increased, and creep rupture lives were shortened greatly, especially under 19 MPa.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"15 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83645192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fission Gas Release Grain Boundary Network Percolation Mechanistic Studies in Oxide Fuels Based on COMSOL Multiphysics Framework 基于COMSOL多物理场框架的氧化物燃料裂变气体释放晶界网络渗流机理研究
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-92732
Jingyu Guo, Wenzhong Zhou
Fission gas release was modeled by COMSOL Multiphysics in oxide fuels, whose theory is based on the effect of grain boundary network percolation. The model is contributed to the conventional Booth model. In this model, the fuel pellet microstructure adopts 2D axisymmetric geometry. The effect of different bubble growth and coalescence rates on the independent grain boundaries are investigated, such as bubble contact angle, resolution rate, and radial position. The modeled physical phenomena are similar to the existing experiments and can be observed in the fission gas release process. The fission gas release is sensitive to the variations of these parameters. Therefore, the parameters are essential to the fission gas release on the microscopic or macroscopic scales. The long-range percolation on the networked grain boundaries is also considered in this work, but it is not considered in the Booth model. The gas resolution on the grain boundaries is also taken into account. At last, this model’s results will be compared with the outcomes of the Booth model as well as the other models.
利用COMSOL Multiphysics模拟氧化物燃料中的裂变气体释放,该模型的理论基础是晶界网络渗流效应。该模型是对传统的布斯模型的补充。在该模型中,燃料颗粒微观结构采用二维轴对称几何结构。研究了不同气泡生长速率和聚结速率对气泡接触角、分辨率和径向位置等独立晶界的影响。模拟的物理现象与现有实验相似,可以在裂变气体释放过程中观察到。裂变气体的释放对这些参数的变化很敏感。因此,无论在微观还是宏观尺度上,这些参数对裂变气体的释放都是至关重要的。本研究也考虑了网络晶界上的远程渗透,但在Booth模型中没有考虑。晶粒边界上的气体分辨率也被考虑在内。最后,将该模型的结果与Booth模型的结果以及其他模型的结果进行比较。
{"title":"Fission Gas Release Grain Boundary Network Percolation Mechanistic Studies in Oxide Fuels Based on COMSOL Multiphysics Framework","authors":"Jingyu Guo, Wenzhong Zhou","doi":"10.1115/icone29-92732","DOIUrl":"https://doi.org/10.1115/icone29-92732","url":null,"abstract":"\u0000 Fission gas release was modeled by COMSOL Multiphysics in oxide fuels, whose theory is based on the effect of grain boundary network percolation. The model is contributed to the conventional Booth model. In this model, the fuel pellet microstructure adopts 2D axisymmetric geometry. The effect of different bubble growth and coalescence rates on the independent grain boundaries are investigated, such as bubble contact angle, resolution rate, and radial position. The modeled physical phenomena are similar to the existing experiments and can be observed in the fission gas release process. The fission gas release is sensitive to the variations of these parameters. Therefore, the parameters are essential to the fission gas release on the microscopic or macroscopic scales. The long-range percolation on the networked grain boundaries is also considered in this work, but it is not considered in the Booth model. The gas resolution on the grain boundaries is also taken into account. At last, this model’s results will be compared with the outcomes of the Booth model as well as the other models.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"1 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75325094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on Risk of Nuclear Spent Fuel Marine Transportation 核废料海上运输风险研究
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-92870
Liu Yiqing, Wang Wei, Zhao Xiaodong, Gui Zhong, Chen Jiangtao
The safety of hazardous materials marine transportation is an important aspect of marine transportation safety. As the seventh category of hazardous materials, spent fuel has strong radioactivity and high decay heat, which makes the marine transportation of spent fuel concerned by the national competent department. Risk analysis is based on the identification of risk factors, through qualitative or quantitative analysis methods, to analyze the possible consequences of these risks and the possibility of these consequences, so as to determine the corresponding risk level and formulate targeted risk control measures. The safety of marine transportation depends not only on the safety of the cargo itself, but also on the navigation safety of the ship. On the basis of introducing the steps and methods of risk analysis, this paper selects various factors affecting the safety of spent fuel marine transportation from the aspects of cargo itself and ship navigation safety, and establishes a scientific and reasonable spent fuel marine transportation safety evaluation index system; The risk factors of maritime transportation are evaluated by risk evaluation methods such as expert scoring and risk coordinate diagram, some measures and suggestions are put forward according to the evaluation results.
危险物品海上运输安全是海上运输安全的一个重要方面。乏燃料作为第七类危险物质,放射性强,衰变热高,使乏燃料的海上运输受到国家主管部门的关注。风险分析是在识别风险因素的基础上,通过定性或定量的分析方法,分析这些风险可能产生的后果以及这些后果发生的可能性,从而确定相应的风险等级,制定有针对性的风险控制措施。海上运输的安全不仅取决于货物本身的安全,还取决于船舶的航行安全。在介绍风险分析步骤和方法的基础上,从货物本身和船舶航行安全两方面选取影响废燃料海上运输安全的各种因素,建立科学合理的废燃料海上运输安全评价指标体系;采用专家评分和风险坐标图等风险评价方法对海上运输的风险因素进行了评价,并根据评价结果提出了相应的措施和建议。
{"title":"Study on Risk of Nuclear Spent Fuel Marine Transportation","authors":"Liu Yiqing, Wang Wei, Zhao Xiaodong, Gui Zhong, Chen Jiangtao","doi":"10.1115/icone29-92870","DOIUrl":"https://doi.org/10.1115/icone29-92870","url":null,"abstract":"\u0000 The safety of hazardous materials marine transportation is an important aspect of marine transportation safety. As the seventh category of hazardous materials, spent fuel has strong radioactivity and high decay heat, which makes the marine transportation of spent fuel concerned by the national competent department. Risk analysis is based on the identification of risk factors, through qualitative or quantitative analysis methods, to analyze the possible consequences of these risks and the possibility of these consequences, so as to determine the corresponding risk level and formulate targeted risk control measures. The safety of marine transportation depends not only on the safety of the cargo itself, but also on the navigation safety of the ship. On the basis of introducing the steps and methods of risk analysis, this paper selects various factors affecting the safety of spent fuel marine transportation from the aspects of cargo itself and ship navigation safety, and establishes a scientific and reasonable spent fuel marine transportation safety evaluation index system; The risk factors of maritime transportation are evaluated by risk evaluation methods such as expert scoring and risk coordinate diagram, some measures and suggestions are put forward according to the evaluation results.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"32 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85005853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogenation of Zircaloy-4 in a Defective Fuel Pellet for Pressurized Water Reactors 锆-4在压水堆缺陷燃料球团中的加氢
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-90736
Doctor Enivweru, Qingyu Wang, A. Ayodeji, John Njoroge
The integrity of structural components is a major concern in reactor safety. Cladding materials can fail when hydrogen uptake is in excess of the terminal solid solubility (TSS). Previous studies on hydrogenation or secondary hydriding (SH) focused mainly on loss of coolant accident (LOCA) and fuel ballooning. Most of these studies are carried out in autoclave conditions and they preclude the contribution of ionizing radiations (neutrons and gamma) to hydrogen generation during normal reactor condition. This study is devoted to the hydrogenation of Zircaloy-4 (Zry-4) cladding material during normal reactor operation and during the early phase of core degradation in a LOCA event. Radiolysis and corrosion are considered as hydrogen sources during normal reactor operation while corrosion is considered in the early phase of core degradation. Using appropriate initial and boundary conditions peculiar to pressurized water reactors (PWRs), diffusion equation is solved in a defective Zry-4 fuel system using COMSOL Multiphysics 5.2. Results show that the average corrosive source term (1.279E−4 mol m−3 s−1) is higher than the radiolytic source term (3.6594E−7 mol m−3 s−1) by a factor of 350 during normal reactor operation. By integrating in two kinetics regimes and setting 6 years as the maximum lifetime of Zry-4, the amount of H dissolved in the cladding material at a temperature of 633 K are 6.54E−03 and 2.02 wt. ppm due to radiolysis and corrosion respectively. These values are safe compared to the TSS of dissolution (CTSSD) of Zry-4 which is 117 wt. ppm at the same referenced temperature. However, in the early phase of core degradation where the source term is 9.405E−01 mol m−3 s−1, SH is observed in 13 days. A comparison is made between hydrogenation by integration in two regimes and hydrogenation using Sievert’s law. The results obtained in this study are useful for the prediction of the onset of hydrogen embrittlement, and to determine the service time of Zry-4 cladding material.
结构部件的完整性是反应堆安全的一个主要问题。当吸氢量超过终端固溶度(TSS)时,包层材料就会失效。以往关于氢化或二次氢化的研究主要集中在冷却剂损失事故和燃料膨胀。这些研究大多是在高压釜条件下进行的,它们排除了在正常反应堆条件下电离辐射(中子和伽马)对氢生成的贡献。本研究致力于在正常反应堆运行期间和在LOCA事件中堆芯降解的早期阶段锆-4 (Zry-4)包层材料的氢化。在反应堆正常运行时,辐射分解和腐蚀被认为是氢源,而在堆芯降解的早期阶段,腐蚀被认为是氢源。采用合适的压水堆初始条件和边界条件,利用COMSOL Multiphysics 5.2软件求解了存在缺陷的Zry-4燃料系统的扩散方程。结果表明,反应器正常运行时,腐蚀源平均项(1.279E−4 mol m−3 s−1)比辐射源平均项(3.6594E−7 mol m−3 s−1)高350倍。通过对两种动力学体系进行积分,并将Zry-4的最大寿命设定为6年,在633 K温度下,由于辐射溶解和腐蚀,包层材料中的H溶解量分别为6.54E - 03和2.02 wt. ppm。与相同参考温度下Zry-4的溶解TSS (CTSSD)为117wt . ppm相比,这些值是安全的。然而,在核心降解的早期阶段,源项为9.405E−01 mol m−3 s−1,在13天内观察到SH。比较了两种体系积分加氢法和西弗特定律加氢法。研究结果可用于预测氢脆发生的时间和确定Zry-4包层材料的使用时间。
{"title":"Hydrogenation of Zircaloy-4 in a Defective Fuel Pellet for Pressurized Water Reactors","authors":"Doctor Enivweru, Qingyu Wang, A. Ayodeji, John Njoroge","doi":"10.1115/icone29-90736","DOIUrl":"https://doi.org/10.1115/icone29-90736","url":null,"abstract":"The integrity of structural components is a major concern in reactor safety. Cladding materials can fail when hydrogen uptake is in excess of the terminal solid solubility (TSS). Previous studies on hydrogenation or secondary hydriding (SH) focused mainly on loss of coolant accident (LOCA) and fuel ballooning. Most of these studies are carried out in autoclave conditions and they preclude the contribution of ionizing radiations (neutrons and gamma) to hydrogen generation during normal reactor condition. This study is devoted to the hydrogenation of Zircaloy-4 (Zry-4) cladding material during normal reactor operation and during the early phase of core degradation in a LOCA event. Radiolysis and corrosion are considered as hydrogen sources during normal reactor operation while corrosion is considered in the early phase of core degradation. Using appropriate initial and boundary conditions peculiar to pressurized water reactors (PWRs), diffusion equation is solved in a defective Zry-4 fuel system using COMSOL Multiphysics 5.2. Results show that the average corrosive source term (1.279E−4 mol m−3 s−1) is higher than the radiolytic source term (3.6594E−7 mol m−3 s−1) by a factor of 350 during normal reactor operation. By integrating in two kinetics regimes and setting 6 years as the maximum lifetime of Zry-4, the amount of H dissolved in the cladding material at a temperature of 633 K are 6.54E−03 and 2.02 wt. ppm due to radiolysis and corrosion respectively. These values are safe compared to the TSS of dissolution (CTSSD) of Zry-4 which is 117 wt. ppm at the same referenced temperature. However, in the early phase of core degradation where the source term is 9.405E−01 mol m−3 s−1, SH is observed in 13 days. A comparison is made between hydrogenation by integration in two regimes and hydrogenation using Sievert’s law. The results obtained in this study are useful for the prediction of the onset of hydrogen embrittlement, and to determine the service time of Zry-4 cladding material.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"1 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76397372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design of Radiation Damage Monitoring Scheme for Materials in China Experimental Fast Reactor 中国实验快堆材料辐射损伤监测方案设计
IF 0.4 Pub Date : 2022-08-08 DOI: 10.1115/icone29-90146
Hu Ziao, Chen Xiao-xian, Chen Xiao-liang
In order to monitor the radiation effects of advanced fuel element cladding materials, it is necessary to install irradiation supervision tanks in the reactor, which contain kinds of detector foils. And then the detector foils are used to determine the neutron energy spectrum and neutron flux, so as to evaluate the radiation damage of the material. Taking China Experimental Fast Reactor (CEFR) as the research object, seven neutron detector foils were selected and five supervision schemes were designed in 316 stainless steel. The size of the neutron detector, the irradiation time and the corresponding relationship with the radiation damage are calculated by the Monte Carlo code and SPECTER program, and finally the sound monitoring scheme is given. It has guiding significance for irradiation experiments of structural materials, and provides a basis for monitoring the irradiation damage of large commercial fast reactor structures.
为了对先进燃料元件包壳材料的辐射效应进行监测,需要在反应堆内安装辐照监测罐,该罐内装有各种检测箔。然后利用探测器箔片测定中子能谱和中子通量,从而评价材料的辐射损伤。以中国实验快堆(CEFR)为研究对象,选择了7种中子探测器箔,设计了5种316不锈钢的监督方案。利用Monte Carlo程序和SPECTER程序计算了中子探测器的尺寸、辐照时间以及与辐射损伤的对应关系,最后给出了合理的监测方案。对结构材料的辐照实验具有指导意义,为大型商用快堆结构的辐照损伤监测提供了依据。
{"title":"Design of Radiation Damage Monitoring Scheme for Materials in China Experimental Fast Reactor","authors":"Hu Ziao, Chen Xiao-xian, Chen Xiao-liang","doi":"10.1115/icone29-90146","DOIUrl":"https://doi.org/10.1115/icone29-90146","url":null,"abstract":"\u0000 In order to monitor the radiation effects of advanced fuel element cladding materials, it is necessary to install irradiation supervision tanks in the reactor, which contain kinds of detector foils. And then the detector foils are used to determine the neutron energy spectrum and neutron flux, so as to evaluate the radiation damage of the material. Taking China Experimental Fast Reactor (CEFR) as the research object, seven neutron detector foils were selected and five supervision schemes were designed in 316 stainless steel. The size of the neutron detector, the irradiation time and the corresponding relationship with the radiation damage are calculated by the Monte Carlo code and SPECTER program, and finally the sound monitoring scheme is given. It has guiding significance for irradiation experiments of structural materials, and provides a basis for monitoring the irradiation damage of large commercial fast reactor structures.","PeriodicalId":36762,"journal":{"name":"Journal of Nuclear Fuel Cycle and Waste Technology","volume":"17 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77492713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Nuclear Fuel Cycle and Waste Technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1