Pub Date : 2024-08-26DOI: 10.1016/j.molliq.2024.125848
Solubility data and regularity of 3-methyl-1,2-cyclopentanedione (MCP) in twelve pure organic solvents were investigated by static method under certain conditions. The results of experiments demonstrate that the solubility of MCP is proportional to the temperature. One of the most solubilizing solvents is dichloromethane. A preliminary assessment of the potential for chemical bond formation between the solute and the solvent was conducted by examining electrostatic potential energy surfaces of the solute. The dissolution behavior was explained by physicochemical properties (polarity, hydrogen bond donor–acceptor propensities and cohesive energy density (CED)) of solvent. The results demonstrate that polarity has a more pronounced impact on the dissolution process, but that other properties also effect the dissolution process to some extent. The Density Functional Theory (DFT) was applied to demonstrate interactions between solute and solvent during the dissolution process. Six thermodynamic models (van’t Hoff, Apelblat, Yaws, λh, Wilson, Jouyban) were utilized to fit solubility data. Wilson model exhibits the highest correlation. The thermodynamic properties indicate that the dissolution of the MCP can be described as an entropy-driven process, which is endothermic and spontaneous.
{"title":"Solubility, solvent effect, correlation and thermodynamic properties of 3-methyl-1,2-cyclopentanedione in twelve pure organic solvents from 278.15 K to 313.15 K","authors":"","doi":"10.1016/j.molliq.2024.125848","DOIUrl":"10.1016/j.molliq.2024.125848","url":null,"abstract":"<div><p>Solubility data and regularity of 3-methyl-1,2-cyclopentanedione (MCP) in twelve pure organic solvents were investigated by static method under certain conditions. The results of experiments demonstrate that the solubility of MCP is proportional to the temperature. One of the most solubilizing solvents is dichloromethane. A preliminary assessment of the potential for chemical bond formation between the solute and the solvent was conducted by examining electrostatic potential energy surfaces of the solute. The dissolution behavior was explained by physicochemical properties (polarity, hydrogen bond donor–acceptor propensities and cohesive energy density (CED)) of solvent. The results demonstrate that polarity has a more pronounced impact on the dissolution process, but that other properties also effect the dissolution process to some extent. The Density Functional Theory (DFT) was applied to demonstrate interactions between solute and solvent during the dissolution process. Six thermodynamic models (van’t Hoff, Apelblat, Yaws, <em>λh</em>, Wilson, Jouyban) were utilized to fit solubility data. Wilson model exhibits the highest correlation. The thermodynamic properties indicate that the dissolution of the MCP can be described as an entropy-driven process, which is endothermic and spontaneous.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142089644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-26DOI: 10.1016/j.molliq.2024.125840
To address the problems of slow crystallization and nucleation in two-phase miscibility in the application of refrigerant hydrates, adding surfactants can be taken as an effective way to promote hydrate formation. Three kinds of polyoxyethylene laurate (LAE) surfactant with different hydrophilic chain lengths (LAE-4, LAE-9 and LAE-24) were selected as accelerators to study their effects on hydrate formation. LAE series surfactants significantly reduce hydrate nucleation induction time. The hydrate induction time of the system with 4.0 wt% LAE-9 is shortest (98 min). The hydrate formation with 4.0 wt% LAE-9 has small randomness and is more stable. Micelles formed by LAE surfactants provide more nucleation sites and accelerate hydrate growth. The hydrate cold storage density is related to the hydrophilic chain length of surfactant. The system with 4.0 wt% LAE-9, which has a suitable hydrophilic chain length, achieves the largest hydrate cold storage density (246.10 kJ·kg−1). Hydrate has the fastest growth rate of 4.80 kJ·kg−1·min−1 in the system with 2.0 wt% LAE-24. There is a “memory” effect during hydrate formation and dissociation cycle, eliminating the need for induction time during hydrate re-formation. Hydrate can be re-formed quickly.
{"title":"Effect of polyoxyethylene laurate series surfactants on HCFC-141b hydrate formation","authors":"","doi":"10.1016/j.molliq.2024.125840","DOIUrl":"10.1016/j.molliq.2024.125840","url":null,"abstract":"<div><p>To address the problems of slow crystallization and nucleation in two-phase miscibility in the application of refrigerant hydrates, adding surfactants can be taken as an effective way to promote hydrate formation. Three kinds of polyoxyethylene laurate (LAE) surfactant with different hydrophilic chain lengths (LAE-4, LAE-9 and LAE-24) were selected as accelerators to study their effects on hydrate formation. LAE series surfactants significantly reduce hydrate nucleation induction time. The hydrate induction time of the system with 4.0 wt% LAE-9 is shortest (98 min). The hydrate formation with 4.0 wt% LAE-9 has small randomness and is more stable. Micelles formed by LAE surfactants provide more nucleation sites and accelerate hydrate growth. The hydrate cold storage density is related to the hydrophilic chain length of surfactant. The system with 4.0 wt% LAE-9, which has a suitable hydrophilic chain length, achieves the largest hydrate cold storage density (246.10 kJ·kg<sup>−1</sup>). Hydrate has the fastest growth rate of 4.80 kJ·kg<sup>−1</sup>·min<sup>−1</sup> in the system with 2.0 wt% LAE-24. There is a “memory” effect during hydrate formation and dissociation cycle, eliminating the need for induction time during hydrate re-formation. Hydrate can be re-formed quickly.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142097112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-26DOI: 10.1016/j.molliq.2024.125828
Composites are multiphasic materials that show improved characteristics compared to the consisting components. In nanocomposites, the sizes of components fall in the nano dimension due to which they exhibit extraordinary features compared to normal composites and are explored in numerous areas efficiently. Polyaniline (PANI) is a fascinating conducting polymer (CP) that is extensively utilized in various fields including water remediation and generation of composites of various semiconductor photocatalysts for improvement of photocatalytic efficiency, stability, recovery and recyclability, and reduction of agglomeration and photoinduced dissolution in solution due to extensive delocalized pi-electron system, effective mobility of electrons, lower band gap, and presence of aromatic amine functionalities in the polymer backbone. PANI forms binary and multi-component nanocomposites with photocatalysts such as metal-based (metal, metal oxide, metal sulfide, metal halide, metal ferrites, etc.), and carbon-based (GO, rGO, g-C3N4, CNT) which exhibit highly improve photocatalytic performance compared to pristine semiconductor photocatalysts against numerous water pollutants. Usually, PANI in the binary nanocomposites with the metal- and carbon-based semiconductor photocatalysts generates heterojunction structures of type-II, p-n, Z-scheme, and S-scheme and reduces band gap, enhances optical absorbance in visible light, increases separation of charge carriers, and their delocalization and via this prevent charge carriers recombination and their life span due to which photocatalytic performance is amplified. This review study is planned to present a review on PANI based binary nanocomposite photocatalysts, their synthesis, features, and photocatalytic applications for degradation of organic pollutants (dyes, phenolic pollutants, nitroaromatics, pesticide, pharmaceuticals pesticides, etc.) and inorganic pollutants under visible, UV, and solar light exposure at numerous reaction conditions. Moreover, this study highlighted various synthesis procedures of polyaniline and their merits, and demerits, synthesis routes of polyaniline nanocomposites.
复合材料是一种多相材料,与组成成分相比,具有更好的特性。在纳米复合材料中,各成分的尺寸均为纳米级,因此与普通复合材料相比,纳米复合材料具有非凡的特性,并在许多领域得到了有效的应用。聚苯胺 (PANI) 是一种迷人的导电聚合物 (CP),广泛应用于多个领域,包括水处理和各种半导体光催化剂的复合材料,以提高光催化效率、稳定性、回收性和可回收性,并减少聚结和溶液中的光诱导溶解,这归功于广泛的非局域π电子系统、有效的电子迁移率、较低的带隙以及聚合物骨架中芳香胺官能团的存在。PANI 与金属基(金属、金属氧化物、金属硫化物、金属卤化物、金属铁氧体等)和碳基(GO、rGO、g-C3N4、CNT)等光催化剂形成二元和多组分纳米复合材料,与原始半导体光催化剂相比,这些纳米复合材料对多种水污染物的光催化性能有很大提高。通常情况下,PANI 与金属和碳基半导体光催化剂的二元纳米复合材料会产生 II 型、p-n 型、Z 型和 S 型异质结结构,从而减小带隙,提高可见光的光吸收率,增加电荷载流子的分离和脱ocal,从而防止电荷载流子重组,延长其寿命,从而提高光催化性能。本综述研究计划综述基于 PANI 的二元纳米复合光催化剂、其合成、特性以及在多种反应条件下,在可见光、紫外线和太阳光照射下降解有机污染物(染料、酚类污染物、硝基芳烃、农药、药物杀虫剂等)和无机污染物的光催化应用。此外,本研究还强调了聚苯胺的各种合成程序及其优缺点,以及聚苯胺纳米复合材料的合成路线。
{"title":"Polyaniline based binary nanocomposite heterostructures with semiconductor photocatalysts for photocatalytic improvement","authors":"","doi":"10.1016/j.molliq.2024.125828","DOIUrl":"10.1016/j.molliq.2024.125828","url":null,"abstract":"<div><p>Composites are multiphasic materials that show improved characteristics compared to the consisting components. In nanocomposites, the sizes of components fall in the nano dimension due to which they exhibit extraordinary features compared to normal composites and are explored in numerous areas efficiently. Polyaniline (PANI) is a fascinating conducting polymer (CP) that is extensively utilized in various fields including water remediation and generation of composites of various semiconductor photocatalysts for improvement of photocatalytic efficiency, stability, recovery and recyclability, and reduction of agglomeration and photoinduced dissolution in solution due to extensive delocalized pi-electron system, effective mobility of electrons, lower band gap, and presence of aromatic amine functionalities in the polymer backbone. PANI forms binary and multi-component nanocomposites with photocatalysts such as metal-based (metal, metal oxide, metal sulfide, metal halide, metal ferrites, etc.), and carbon-based (GO, rGO, g-C<sub>3</sub>N<sub>4</sub>, CNT) which exhibit highly improve photocatalytic performance compared to pristine semiconductor photocatalysts against numerous water pollutants. Usually, PANI in the binary nanocomposites with the metal- and carbon-based semiconductor photocatalysts generates heterojunction structures of type-II, p-n, Z-scheme, and S-scheme and reduces band gap, enhances optical absorbance in visible light, increases separation of charge carriers, and their delocalization and via this prevent charge carriers recombination and their life span due to which photocatalytic performance is amplified. This review study is planned to present a review on PANI based binary nanocomposite photocatalysts, their synthesis, features, and photocatalytic applications for degradation of organic pollutants (dyes, phenolic pollutants, nitroaromatics, pesticide, pharmaceuticals pesticides, etc.) and inorganic pollutants under visible, UV, and solar light exposure at numerous reaction conditions. Moreover, this study highlighted various synthesis procedures of polyaniline and their merits, and demerits, synthesis routes of polyaniline nanocomposites.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142097115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-26DOI: 10.1016/j.molliq.2024.125850
The objective of this research was to investigate the healing characteristics of bitumen through the assessment of fatigue-healing performance of SARAs fractions and its characterization at the molecular level with SARAs fractions as the intermediate. Firstly, the flow behaviors and fatigue-healing performance of fractions were characterized by rheometer. Then, the diffusion systems were constructed and the diffusion with preset cracks was carried out, the evaluation of which was identified by density distribution, relative concentration in crack region, mean square displacement and interaction effect. The results indicate that aromatics exhibit the closest similarity to original bitumen in flowing behavior, which also reflected in the healing performance. The healing performance of resins and asphaltenes are extremely limited while that of saturates was comparable to fluid. Molecular simulation was further supporting to investigate the healing process. A platform period was found in the healing period when the molecules would move to seek the lowest energy state which was considered as healing in the alternative perspective. During the period, heavy components were more difficult to traverse while weak interaction between light components would shorten the period and identify the lowest energy state more easily, thereby greatly affecting the healing performance of fractions. Furthermore, heavy components are analogous to anchor points, among which resins were more readily aggregated and asphaltenes were relatively dispersed, while light components diffuse flexibly within them. The diffusion has the potential to drive the movement of heavy components which also kept the capture of other components, ultimately resulting in the formation of a stable healing state. The outcome with a discernible interaction effect would be important theoretical significance for the refinement of bitumen of better healing performance and the potential to influence the development of rejuvenators.
{"title":"Measurement on the fatigue-healing performance of SARAs fractions in bitumen and its characterization by molecular simulations","authors":"","doi":"10.1016/j.molliq.2024.125850","DOIUrl":"10.1016/j.molliq.2024.125850","url":null,"abstract":"<div><p>The objective of this research was to investigate the healing characteristics of bitumen through the assessment of fatigue-healing performance of SARAs fractions and its characterization at the molecular level with SARAs fractions as the intermediate. Firstly, the flow behaviors and fatigue-healing performance of fractions were characterized by rheometer. Then, the diffusion systems were constructed and the diffusion with preset cracks was carried out, the evaluation of which was identified by density distribution, relative concentration in crack region, mean square displacement and interaction effect. The results indicate that aromatics exhibit the closest similarity to original bitumen in flowing behavior, which also reflected in the healing performance. The healing performance of resins and asphaltenes are extremely limited while that of saturates was comparable to fluid. Molecular simulation was further supporting to investigate the healing process. A platform period was found in the healing period when the molecules would move to seek the lowest energy state which was considered as healing in the alternative perspective. During the period, heavy components were more difficult to traverse while weak interaction between light components would shorten the period and identify the lowest energy state more easily, thereby greatly affecting the healing performance of fractions. Furthermore, heavy components are analogous to anchor points, among which resins were more readily aggregated and asphaltenes were relatively dispersed, while light components diffuse flexibly within them. The diffusion has the potential to drive the movement of heavy components which also kept the capture of other components, ultimately resulting in the formation of a stable healing state. The outcome with a discernible interaction effect would be important theoretical significance for the refinement of bitumen of better healing performance and the potential to influence the development of rejuvenators.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142097310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-25DOI: 10.1016/j.molliq.2024.125849
Highly stable aqueous magnetic mono nanofluids of nickel ferrite (NiFe2O4), magnetite (Fe3O4), and hybrid magnetic nanofluids of NiFe2O4-Fe3O4 are synthesized through a two-step method. The structural analysis of the NiFe2O4 and Fe3O4 nanoparticles made through X-ray diffraction identifies their spinel cubic structure. The magnetic studies indicate their superparamagnetic nature, which is further confirmed through the Langevin fitting of the experimental data. The monodomain nature of nanoparticles is verified using the coupling constant, and a spherical morphology is observed using a transmission electron microscope. The surface charge of the nanoparticles is studied through zeta potential analysis. The electrical conductivity of the aqueous mono and hybrid magnetic nanofluids is measured for various concentrations and temperatures. The hybrid magnetic nanofluids show higher electrical conductivity values than those of both the mono nanofluids. For instance, NiFe2O4-Fe3O4 (1.2 vol%) hybrid nanofluid is found to have a conductivity value of 18.91 μS/cm that is 1.5 times enhanced than that of Fe3O4 mono nanofluid (12.87 μS/cm) and three times enhanced than that of NiFe2O4 (6.43 μS/cm) mono nanofluid of same volume percentage at 303 K. A Maximum enhancement of 136 % is obtained for 1.2 vol% hybrid nanofluid with respect to water at 303 K and this enhancement further increases to 196 % with the rise in temperature to 323 K. There is no theoretical model found in literature to explain the electrical conductivity of hybrid nanofluids. Maxwell, Bruggeman, Cruz, and Shen models are applied to explain the conductivity of hybrid magnetic nanofluids. Through a comparison of experimental values with theoretical values, it is found that the Shen model, if modified suitably, can explain the electrical conduction of hybrid magnetic nanofluids. Also, the electrical conduction mechanism in hybrid magnetic nanofluids is described in terms of electrophoretic charge transportation and the Brownian motion. In addition, the magneto-electrical conductivity study is performed by measuring the electrical conductivity by applying a magnetic field of various strengths. The electrical conductivity, magneto-electrical conductivity studies and an understanding of electrical conduction mechanism are highly significant for magnetically transportable electronic cooling and conducting applications of hybrid magnetic nanofluids.
{"title":"Synthesis of aqueous NiFe2O4-Fe3O4 hybrid magnetic nanofluids and investigation on electrical conducting behaviour","authors":"","doi":"10.1016/j.molliq.2024.125849","DOIUrl":"10.1016/j.molliq.2024.125849","url":null,"abstract":"<div><p>Highly stable aqueous magnetic mono nanofluids of nickel ferrite (NiFe<sub>2</sub>O<sub>4</sub>), magnetite (Fe<sub>3</sub>O<sub>4</sub>), and hybrid magnetic nanofluids of NiFe<sub>2</sub>O<sub>4</sub>-Fe<sub>3</sub>O<sub>4</sub> are synthesized through a two-step method. The structural analysis of the NiFe<sub>2</sub>O<sub>4</sub> and Fe<sub>3</sub>O<sub>4</sub> nanoparticles made through X-ray diffraction identifies their spinel cubic structure. The magnetic studies indicate their superparamagnetic nature, which is further confirmed through the Langevin fitting of the experimental data. The monodomain nature of nanoparticles is verified using the coupling constant, and a spherical morphology is observed using a transmission electron microscope. The surface charge of the nanoparticles is studied through zeta potential analysis. The electrical conductivity of the aqueous mono and hybrid magnetic nanofluids is measured for various concentrations and temperatures. The hybrid magnetic nanofluids show higher electrical conductivity values than those of both the mono nanofluids. For instance, NiFe<sub>2</sub>O<sub>4</sub>-Fe<sub>3</sub>O<sub>4</sub> (1.2 vol%) hybrid nanofluid is found to have a conductivity value of 18.91 μS/cm that is 1.5 times enhanced than that of Fe<sub>3</sub>O<sub>4</sub> mono nanofluid (12.87 μS/cm) and three times enhanced than that of NiFe<sub>2</sub>O<sub>4</sub> (6.43 μS/cm) mono nanofluid of same volume percentage at 303 K. A Maximum enhancement of 136 % is obtained for 1.2 vol% hybrid nanofluid with respect to water at 303 K and this enhancement further increases to 196 % with the rise in temperature to 323 K. There is no theoretical model found in literature to explain the electrical conductivity of hybrid nanofluids. Maxwell, Bruggeman, Cruz, and Shen models are applied to explain the conductivity of hybrid magnetic nanofluids. Through a comparison of experimental values with theoretical values, it is found that the Shen model, if modified suitably, can explain the electrical conduction of hybrid magnetic nanofluids. Also, the electrical conduction mechanism in hybrid magnetic nanofluids is described in terms of electrophoretic charge transportation and the Brownian motion. In addition, the magneto-electrical conductivity study is performed by measuring the electrical conductivity by applying a magnetic field of various strengths. The electrical conductivity, magneto-electrical conductivity studies and an understanding of electrical conduction mechanism are highly significant for magnetically transportable electronic cooling and conducting applications of hybrid magnetic nanofluids.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142096985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-25DOI: 10.1016/j.molliq.2024.125853
In this study, we developed a laboratory-based model to analyze wettability alteration in the oil–water-rock system. The selected Surface Complexation Model (SCM), based on experimental data, is refined through sensitivity analysis and comparison with experimental measurements, including zeta potential and contact angle. Our analysis indicates that, in addition to magnesium, calcium, and sulfate ions, the adsorption of sodium and chlorine on calcite surfaces, as well as sodium adsorption on oil surfaces, significantly affects electrostatic interactions and surface potential alterations. Consequently, the complexing reactions of these ions were incorporated into the model and adjusted based on sensitivity analysis. Moreover, surface complex reactions exhibit distinct behaviors in neutral, acidic, and alkaline environments. Therefore, different reactions were considered and sensitivity analyzed for oil and rock surfaces in neutral conditions. The model’s reliability was further validated by comparing predicted and experimental zeta potentials. Additionally, disjoining pressures were computed, and contact angles were simulated, demonstrating the model’s accuracy. Key findings include the successful modification of reaction parameters to achieve accurate results across different pH levels and ion concentrations. This confirms the applicability and reliability of the developed SCM for wettability alteration analysis, further supported by stability maps that consider varying ion concentrations and pH levels.
{"title":"Understanding the wettability alterations in carbonate reservoirs: Integrating experimental data and a surface complexation model for enhanced predictions","authors":"","doi":"10.1016/j.molliq.2024.125853","DOIUrl":"10.1016/j.molliq.2024.125853","url":null,"abstract":"<div><p>In this study, we developed a laboratory-based model to analyze wettability alteration in the oil–water-rock system. The selected Surface Complexation Model (SCM), based on experimental data, is refined through sensitivity analysis and comparison with experimental measurements, including zeta potential and contact angle. Our analysis indicates that, in addition to magnesium, calcium, and sulfate ions, the adsorption of sodium and chlorine on calcite surfaces, as well as sodium adsorption on oil surfaces, significantly affects electrostatic interactions and surface potential alterations. Consequently, the complexing reactions of these ions were incorporated into the model and adjusted based on sensitivity analysis. Moreover, surface complex reactions exhibit distinct behaviors in neutral, acidic, and alkaline environments. Therefore, different reactions were considered and sensitivity analyzed for oil and rock surfaces in neutral conditions. The model’s reliability was further validated by comparing predicted and experimental zeta potentials. Additionally, disjoining pressures were computed, and contact angles were simulated, demonstrating the model’s accuracy. Key findings include the successful modification of reaction parameters to achieve accurate results across different pH levels and ion concentrations. This confirms the applicability and reliability of the developed SCM for wettability alteration analysis, further supported by stability maps that consider varying ion concentrations and pH levels.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142097108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-25DOI: 10.1016/j.molliq.2024.125847
The injection of CO2 foam into the carbonate reservoir for enhanced oil recovery (EOR) has attracted special interest in the last decades; nevertheless, the understanding of the effect of liquid solution chemistry on foam stability at high temperatures and salinities is limited. Hence, this paper fully investigates the effect of chelating agents L-glutamic acid-N, N-diacetic acid (GLDA) pH, and hydrochloric acid (HCl) on the stability and viscosity of generated CO2 foam for heterogeneous carbonate formation under reservoir conditions. In this paper, Duomeen TTM and Armovis VES surfactants were utilized due to their capabilities to produce viscous CO2 foam under harsh conditions. The foamability, foam stability, and foam structure were studied at 100 °C and 1000 psi using a high-temperature and high-pressure (HPHT) foam analyzer. The measurement of CO2 foam viscosity was determined at 100 °C, 1000 psi, and 70 % foam quality using the HPHT foam rheometer. Rheology experiments and dynamic light scattering investigated the micelle’s size or aggregation behavior of surfactants. The obtained results showed that the Duomeen TTM generated unstable foam; however, foam stability and foamability improved with the decrease in GLDA pH. Armovis VES showed excellent CO2 foam performance, where the foam half-life time of Armovis VES systems was 240 min. The liquid drainage and bubble coarsening were delayed due to the formation of the viscoelastic liquid phase. The foamability of Armovis VES was improved as the GLDA pH decreased. Furthermore, the addition of HCl to Armovis VES solution presented the highest foamability. The outcomes of the HPHT foam analyzer and HPHT viscometer proved that as the pH of Armovis VES solution decreased, higher foamability was produced. The highest foam viscosity was obtained using the synergic effect of 0.5 wt% Duomeen TTM and 0.5 wt% Armovis VES (39 cp at 100/s). In comparison, 1 wt% Armovis VES presented the lowest foam viscosity (30 cp at 100/s). The outcomes of this research can provide insight into the effect of chemistry on CO2 foam and extend its application in oilfield development. This work broadens the design of novel CO2 foam formulation, leading to the improvement of sweep efficiency in CO2-EOR methods and enhance the gas trapping in carbon storage.
在过去几十年中,向碳酸盐岩储层注入二氧化碳泡沫以提高石油采收率(EOR)引起了人们的特别关注;然而,人们对液态溶液化学性质在高温和高盐度条件下对泡沫稳定性的影响了解有限。因此,本文全面研究了螯合剂 L-谷氨酸-N,N-二乙酸(GLDA)的 pH 值和盐酸(HCl)对储层条件下异质碳酸盐岩形成过程中生成的二氧化碳泡沫的稳定性和粘度的影响。本文采用了 Duomeen TTM 和 Armovis VES 表面活性剂,因为这两种表面活性剂能够在苛刻条件下产生粘性 CO2 泡沫。使用高温高压(HPHT)泡沫分析仪在 100 °C 和 1000 psi 条件下研究了泡沫的可发泡性、泡沫稳定性和泡沫结构。使用 HPHT 泡沫流变仪测量了二氧化碳在 100 °C、1000 psi 和 70 % 泡沫质量条件下的泡沫粘度。流变学实验和动态光散射研究了表面活性剂的胶束大小或聚集行为。结果表明,Duomeen TTM 产生的泡沫不稳定;然而,随着 GLDA pH 值的降低,泡沫稳定性和可发泡性得到改善。阿乐斯 VES 表现出优异的二氧化碳泡沫性能,阿乐斯 VES 系统的泡沫半衰期为 240 分钟。由于粘弹性液相的形成,液体排出和气泡变粗的时间被推迟。随着 GLDA pH 值的降低,Armovis VES 的发泡性也得到了改善。此外,在阿乐斯 VES 溶液中加入 HCl 时,泡沫性最高。HPHT 泡沫分析仪和 HPHT 粘度计的结果证明,随着阿乐斯 VES 溶液 pH 值的降低,可产生更高的泡沫。在 0.5 wt% Duomeen TTM 和 0.5 wt% Armovis VES 的协同作用下,泡沫粘度最高(100/s 时为 39 cp)。相比之下,1 wt% Armovis VES 的泡沫粘度最低(100/s 时为 30 cp)。这项研究成果有助于深入了解化学对二氧化碳泡沫的影响,并扩大其在油田开发中的应用。这项工作拓宽了新型 CO2 泡沫配方的设计范围,从而提高了 CO2-EOR 方法中的清扫效率,并增强了碳封存中的气体截留。
{"title":"The impact of chelating agent pH on the stability and viscosity of CO2 foam under harsh reservoir conditions","authors":"","doi":"10.1016/j.molliq.2024.125847","DOIUrl":"10.1016/j.molliq.2024.125847","url":null,"abstract":"<div><p>The injection of CO<sub>2</sub> foam into the carbonate reservoir for enhanced oil recovery (EOR) has attracted special interest in the last decades; nevertheless, the understanding of the effect of liquid solution chemistry on foam stability at high temperatures and salinities is limited. Hence, this paper fully investigates the effect of chelating agents L-glutamic acid-N, N-diacetic acid (GLDA) pH, and hydrochloric acid (HCl) on the stability and viscosity of generated CO<sub>2</sub> foam for heterogeneous carbonate formation under reservoir conditions. In this paper, Duomeen TTM and Armovis VES surfactants were utilized due to their capabilities to produce viscous CO<sub>2</sub> foam under harsh conditions. The foamability, foam stability, and foam structure were studied at 100 °C and 1000 psi using a high-temperature and high-pressure (HPHT) foam analyzer. The measurement of CO<sub>2</sub> foam viscosity was determined at 100 °C, 1000 psi, and 70 % foam quality using the HPHT foam rheometer. Rheology experiments and dynamic light scattering investigated the micelle’s size or aggregation behavior of surfactants. The obtained results showed that the Duomeen TTM generated unstable foam; however, foam stability and foamability improved with the decrease in GLDA pH. Armovis VES showed excellent CO<sub>2</sub> foam performance, where the foam half-life time of Armovis VES systems was 240 min. The liquid drainage and bubble coarsening were delayed due to the formation of the viscoelastic liquid phase. The foamability of Armovis VES was improved as the GLDA pH decreased. Furthermore, the addition of HCl to Armovis VES solution presented the highest foamability. The outcomes of the HPHT foam analyzer and HPHT viscometer proved that as the pH of Armovis VES solution decreased, higher foamability was produced. The highest foam viscosity was obtained using the synergic effect of 0.5 wt% Duomeen TTM and 0.5 wt% Armovis VES (39 cp at 100/s). In comparison, 1 wt% Armovis VES presented the lowest foam viscosity (30 cp at 100/s). The outcomes of this research can provide insight into the effect of chemistry on CO<sub>2</sub> foam and extend its application in oilfield development. This work broadens the design of novel CO<sub>2</sub> foam formulation, leading to the improvement of sweep efficiency in CO<sub>2</sub>-EOR methods and enhance the gas trapping in carbon storage.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142117646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-25DOI: 10.1016/j.molliq.2024.125839
The mechanical strength of conventional hydrogels is inadequate for preventing leakage in high-temperature and high-salinity reservoirs, primarily due to the increased mobility of polymer chains and the degradation of crosslinked networks. Herein, we employed the strategy of ’network nesting and layer reinforcement’ to design a hybrid multi-site crosslinked hydrogel. This approach enhances the interconnections between polymer chains and fortifies the crosslinked network. The shear rheological behavior and temperature sensitive characteristics of the profile control working fluids were evaluated based on rheological dynamics. In the high temperature (140 ℃) and high salinity (21.81 × 104 mg/L) preparation environment, the effects of different components to the mechanical strength of the hydrogel were investigated under dynamic shear and uniaxial compression conditions. The incorporation of N-(hydroxymethyl)acrylamide (NMA) in the copolymerization with acrylamide (AM) resulted in an increase in the covalent cross-linking density, leading to a rise in the shear elastic modulus from 105 Pa to 238 Pa. The use of pre-gelatinized cassava starch (PGCM) as the grafting framework enhanced the bonding between the polymer chains, as evidenced by the increase in uniaxial compressive strength from 0.018 MPa to 0.081 MPa and the rise in peak strain from 55.0 % to 72.9 %. Furthermore, the synergistic effect of fumed silica (AEROSIL), which exploits mechanical coupling between inorganic nano-fillers and organic polymers, increased the compressive strength from 0.081 MPa to 0.418 MPa and raised the peak strain from 72.9 % to 81.8 %. It provides an effective approach to enhance the plugging performance of hydrogels in high temperature and high salinity reservoirs.
{"title":"Design of hybrid multi-crosslinked hydrogel with a combination of high stiffness, elastic applied in high temperature and high salinity reservoirs","authors":"","doi":"10.1016/j.molliq.2024.125839","DOIUrl":"10.1016/j.molliq.2024.125839","url":null,"abstract":"<div><p>The mechanical strength of conventional hydrogels is inadequate for preventing leakage in high-temperature and high-salinity reservoirs, primarily due to the increased mobility of polymer chains and the degradation of crosslinked networks. Herein, we employed the strategy of ’network nesting and layer reinforcement’ to design a hybrid multi-site crosslinked hydrogel. This approach enhances the interconnections between polymer chains and fortifies the crosslinked network. The shear rheological behavior and temperature sensitive characteristics of the profile control working fluids were evaluated based on rheological dynamics. In the high temperature (140 ℃) and high salinity (21.81 × 10<sup>4</sup> mg/L) preparation environment, the effects of different components to the mechanical strength of the hydrogel were investigated under dynamic shear and uniaxial compression conditions. The incorporation of N-(hydroxymethyl)acrylamide (NMA) in the copolymerization with acrylamide (AM) resulted in an increase in the covalent cross-linking density, leading to a rise in the shear elastic modulus from 105 Pa to 238 Pa. The use of pre-gelatinized cassava starch (PGCM) as the grafting framework enhanced the bonding between the polymer chains, as evidenced by the increase in uniaxial compressive strength from 0.018 MPa to 0.081 MPa and the rise in peak strain from 55.0 % to 72.9 %. Furthermore, the synergistic effect of fumed silica (AEROSIL), which exploits mechanical coupling between inorganic nano-fillers and organic polymers, increased the compressive strength from 0.081 MPa to 0.418 MPa and raised the peak strain from 72.9 % to 81.8 %. It provides an effective approach to enhance the plugging performance of hydrogels in high temperature and high salinity reservoirs.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142089643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-25DOI: 10.1016/j.molliq.2024.125838
<div><p>Nanobubbles (NBs) which are gas filled cavities of nanometre dimensions present in liquids attracted increasing attention in the recent years due to their application in various fields such as chemistry, biology, medicine etc. An important aspect of NB research is the study of effect of additives on formation and evolution of these bubbles. The present study examined by applying molecular dynamics simulations, the formation and evolution of methane NBs in the CH<sub>4</sub>-H<sub>2</sub>O-Alcohol system, which is known to form during alcohol induced dissociation of CH<sub>4</sub> hydrates in the natural gas extraction process. The effect of alcohol type and concentration on NB formation and evolution was examined through simulations of CH<sub>4</sub>-H<sub>2</sub>O-CH<sub>3</sub>OH, CH<sub>4</sub>-H<sub>2</sub>O-C<sub>2</sub>H<sub>5</sub>OH and CH<sub>4</sub>-H<sub>2</sub>O-nC<sub>3</sub>H<sub>7</sub>OH systems. The study revealed that increase in both concentration and the alkyl chain length of alcohols promoted NB formation. Alcohol molecules are found to enhance NB nucleation through accumulation near the NB-liquid interface resulting in a decrease in the surface tension (γ) at the interface. These effects become more pronounced as the alkyl chain length increases which explains the enhanced NB formation in systems containing nC<sub>3</sub>H<sub>7</sub>OH and C<sub>2</sub>H<sub>5</sub>OH compared to those containing CH<sub>3</sub>OH. The mechanism of formation and evolution of NBs is found to significantly depend on the type of alcohol present. NBs are found to nucleate at multiple locations in the systems containing nC<sub>3</sub>H<sub>7</sub>OH and C<sub>2</sub>H<sub>5</sub>OH which eventually coalesce to form a single large stable NB. In the presence of NBs which vary significantly in size, bubble growth was also found to occur through Ostwald ripening which involves transfer of CH<sub>4</sub> from smaller NB to the larger one. In contrast, in the CH<sub>4</sub>-H<sub>2</sub>O-CH<sub>3</sub>OH system, primarily a single NB nucleated which grew in size through absorption of CH<sub>4</sub> molecules dissolved in the liquid, rather than through coalescence or Ostwald ripening. The observed influence of alcohol type on the process of NB evolution is explained by examining the influence of alkyl chain length on γ and diffusivity of CH<sub>4</sub> molecules. Due to the role of NBs on methane hydrate regeneration from the hydrate melt, we examined the influence of NB in the CH<sub>4</sub>-H<sub>2</sub>O-Alcohol system on the organization of water molecules (HSWs) present in the hydration shell of dissolved CH<sub>4</sub>. The value of F<sub>4</sub> order parameter of HSWs and the number of hydrogen bonded water rings in the hydration shell of CH<sub>4</sub> were analysed. The value of F<sub>4</sub> order parameter indicate that the hydrophobic alkyl chain of alcohol induced hydrate like arrangement of HSWs, which is more pronounced in the
纳米气泡(NBs)是存在于液体中的充满气体的纳米级空腔,近年来由于其在化学、生物、医学等多个领域的应用而日益受到关注。NB 研究的一个重要方面是研究添加剂对这些气泡的形成和演变的影响。本研究通过分子动力学模拟,研究了甲烷 NBs 在 CH4-H2O-Alcohol 体系中的形成和演化,众所周知,在天然气提取过程中,CH4 水合物在酒精诱导解离过程中会形成 NBs。通过模拟 CH4-H2O-CH3OH、CH4-H2O-C2H5OH 和 CH4-H2O-nC3H7OH 体系,研究了酒精类型和浓度对 NB 形成和演化的影响。研究发现,增加醇的浓度和烷基链长度都会促进 NB 的形成。研究发现,醇分子通过在 NB-液体界面附近聚集,导致界面表面张力(γ)降低,从而促进 NB 成核。这些效应随着烷基链长度的增加而变得更加明显,这也解释了为什么与含有 CH3OH 的体系相比,含有 nC3H7OH 和 C2H5OH 的体系中 NB 的形成更强。研究发现,NB 的形成和演化机制在很大程度上取决于存在的醇的类型。在含有 nC3H7OH 和 C2H5OH 的体系中,NB 在多个位置成核,最终凝聚成一个大的稳定 NB。在 NB 大小差异显著的情况下,气泡的增长也是通过奥斯特瓦尔德熟化作用发生的,这涉及到 CH4 从较小的 NB 转移到较大的 NB。与此相反,在 CH4-H2O-CH3OH 体系中,主要是单个 NB 成核,它通过吸收溶解在液体中的 CH4 分子而增大,而不是通过凝聚或奥斯特瓦尔德熟化。通过研究烷基链长度对 γ 和 CH4 分子扩散性的影响,可以解释观察到的醇类型对 NB 演化过程的影响。鉴于 NB 对甲烷水合物从水合物熔体中再生的作用,我们研究了 CH4-H2O-Alcohol 体系中 NB 对溶解 CH4 水合壳中水分子(HSW)组织的影响。分析了 HSWs 的 F4 阶参数值和 CH4 水合壳中氢键水环的数量。F4 有序参数值表明,酒精的疏水烷基链导致 HSW 呈水合物状排列,这在烷基链较长的酒精中更为明显。然而,醇分子也会使 CH4 周围的 HSW 脱落,导致溶解的 CH4 周围的水环数量减少,不利于水合物的形成。这些观察结果与所报道的酒精对水合物形成的双重影响一致,即酒精在低浓度时促进水合物形成,而在高浓度时抑制水合物形成。
{"title":"Formation and evolution of nanobubbles in CH4-H2O-Alcohol system: Insight into the effect of alcohol chain length from molecular dynamics simulations","authors":"","doi":"10.1016/j.molliq.2024.125838","DOIUrl":"10.1016/j.molliq.2024.125838","url":null,"abstract":"<div><p>Nanobubbles (NBs) which are gas filled cavities of nanometre dimensions present in liquids attracted increasing attention in the recent years due to their application in various fields such as chemistry, biology, medicine etc. An important aspect of NB research is the study of effect of additives on formation and evolution of these bubbles. The present study examined by applying molecular dynamics simulations, the formation and evolution of methane NBs in the CH<sub>4</sub>-H<sub>2</sub>O-Alcohol system, which is known to form during alcohol induced dissociation of CH<sub>4</sub> hydrates in the natural gas extraction process. The effect of alcohol type and concentration on NB formation and evolution was examined through simulations of CH<sub>4</sub>-H<sub>2</sub>O-CH<sub>3</sub>OH, CH<sub>4</sub>-H<sub>2</sub>O-C<sub>2</sub>H<sub>5</sub>OH and CH<sub>4</sub>-H<sub>2</sub>O-nC<sub>3</sub>H<sub>7</sub>OH systems. The study revealed that increase in both concentration and the alkyl chain length of alcohols promoted NB formation. Alcohol molecules are found to enhance NB nucleation through accumulation near the NB-liquid interface resulting in a decrease in the surface tension (γ) at the interface. These effects become more pronounced as the alkyl chain length increases which explains the enhanced NB formation in systems containing nC<sub>3</sub>H<sub>7</sub>OH and C<sub>2</sub>H<sub>5</sub>OH compared to those containing CH<sub>3</sub>OH. The mechanism of formation and evolution of NBs is found to significantly depend on the type of alcohol present. NBs are found to nucleate at multiple locations in the systems containing nC<sub>3</sub>H<sub>7</sub>OH and C<sub>2</sub>H<sub>5</sub>OH which eventually coalesce to form a single large stable NB. In the presence of NBs which vary significantly in size, bubble growth was also found to occur through Ostwald ripening which involves transfer of CH<sub>4</sub> from smaller NB to the larger one. In contrast, in the CH<sub>4</sub>-H<sub>2</sub>O-CH<sub>3</sub>OH system, primarily a single NB nucleated which grew in size through absorption of CH<sub>4</sub> molecules dissolved in the liquid, rather than through coalescence or Ostwald ripening. The observed influence of alcohol type on the process of NB evolution is explained by examining the influence of alkyl chain length on γ and diffusivity of CH<sub>4</sub> molecules. Due to the role of NBs on methane hydrate regeneration from the hydrate melt, we examined the influence of NB in the CH<sub>4</sub>-H<sub>2</sub>O-Alcohol system on the organization of water molecules (HSWs) present in the hydration shell of dissolved CH<sub>4</sub>. The value of F<sub>4</sub> order parameter of HSWs and the number of hydrogen bonded water rings in the hydration shell of CH<sub>4</sub> were analysed. The value of F<sub>4</sub> order parameter indicate that the hydrophobic alkyl chain of alcohol induced hydrate like arrangement of HSWs, which is more pronounced in the ","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142097110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-25DOI: 10.1016/j.molliq.2024.125855
The continuous reduction in feature size of integrated circuits has raised stricter material removal selectivity and surface quality requirements for the chemical mechanical polishing (CMP) process of shallow trench isolation (STI). To reduce surface defects, small-sized CeO2 abrasives are introduced into the CMP of STI. We investigated the impacts of three amino acids and their composites added to a 50 nm-sized CeO2 dispersion (pH maintained at 5) on the polishing of silicon dioxide and silicon nitride. The promoting or inhibitory effects of amino acids first increased and then decreased with increasing concentration. When 0.02 M lysine and 0.02 M glutamic acid were added to 0.5 wt% CeO2 dispersion, the best effect was achieved. At this time, the material removal rate (MRR) of SiO2 and Si3N4 were 2993.4 Å/min and 137.2 Å/min, respectively, with surface roughness of 0.108 nm and 0.142 nm in the 5 μm × 5 μm region. This study shows that amino acids promote the MRR of SiO2 primarily by enhancing the reactivity of Ce4+ by complexing with carboxyl groups. In contrast, amino acids inhibit the MRR of Si3N4 primarily by forming strong hydrogen bonds between the amino group and its surface, resulting in surface adsorption and suppressing the hydrolysis reaction. The CMP mechanisms of the three amino acids are similar, and the differences in their effects are mainly due to the varying numbers of amino and carboxyl groups they carry. The adsorption of three amino acids on SiO2 and Si3N4 surfaces was simulated by Materials Studio software, and the results were consistent with the experimental results. Finally, this paper explained the mechanism of action of amino acids at the microscopic level and provided some guidance on improving the performance of CeO2 slurry.
{"title":"The effect of amino acid addition in CeO2-based slurry on SiO2/Si3N4 CMP: Removal rate selectivity, morphology, and mechanism research","authors":"","doi":"10.1016/j.molliq.2024.125855","DOIUrl":"10.1016/j.molliq.2024.125855","url":null,"abstract":"<div><p>The continuous reduction in feature size of integrated circuits has raised stricter material removal selectivity and surface quality requirements for the chemical mechanical polishing (CMP) process of shallow trench isolation (STI). To reduce surface defects, small-sized CeO<sub>2</sub> abrasives are introduced into the CMP of STI. We investigated the impacts of three amino acids and their composites added to a 50 nm-sized CeO<sub>2</sub> dispersion (pH maintained at 5) on the polishing of silicon dioxide and silicon nitride. The promoting or inhibitory effects of amino acids first increased and then decreased with increasing concentration. When 0.02 M lysine and 0.02 M glutamic acid were added to 0.5 wt% CeO<sub>2</sub> dispersion, the best effect was achieved. At this time, the material removal rate (MRR) of SiO<sub>2</sub> and Si<sub>3</sub>N<sub>4</sub> were 2993.4 Å/min and 137.2 Å/min, respectively, with surface roughness of 0.108 nm and 0.142 nm in the 5 μm × 5 μm region. This study shows that amino acids promote the MRR of SiO<sub>2</sub> primarily by enhancing the reactivity of Ce<sup>4+</sup> by complexing with carboxyl groups. In contrast, amino acids inhibit the MRR of Si<sub>3</sub>N<sub>4</sub> primarily by forming strong hydrogen bonds between the amino group and its surface, resulting in surface adsorption and suppressing the hydrolysis reaction. The CMP mechanisms of the three amino acids are similar, and the differences in their effects are mainly due to the varying numbers of amino and carboxyl groups they carry. The adsorption of three amino acids on SiO<sub>2</sub> and Si<sub>3</sub>N<sub>4</sub> surfaces was simulated by Materials Studio software, and the results were consistent with the experimental results. Finally, this paper explained the mechanism of action of amino acids at the microscopic level and provided some guidance on improving the performance of CeO<sub>2</sub> slurry.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142097311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}