Journal of the Taiwan Institute of Chemical Engineers最新文献

{"title":"Machine learning-assisted optimization and evaluation of methylene blue adsorption kinetics on citrus aurantifolia leaves: Insights from isotherm and thermodynamic studies","authors":"","doi":"10.1016/j.jtice.2024.105696","DOIUrl":"10.1016/j.jtice.2024.105696","url":null,"abstract":"<div><h3>Background</h3><p>Methylene Blue (MB) is a cationic dye widely used in various industrial and pharmacological applications. However, its improper disposal poses significant environmental and health risks due to its toxicity, carcinogenicity, and resistance to biodegradation. Despite extensive efforts have been done to remove MB using green synthesis approaches, however; there remains a critical need to enhance the efficacy of these methods through proper optimization and the use of novel green sources. Addressing these challenges is essential to mitigate the environmental impact of MB.</p></div><div><h3>Methods</h3><p>Citrus aurantifolia leaves powder (CALP), a simple, environmentally friendly, adsorbent has been utilized to remove MB dye. The adsorption kinetic efficacy of CALP was studied under different experimental conditions, including pH (3–9), contact time (2–8 min), and MB dye concentrations (10–70 mg/L). Additionally, machine learning (ML) was employed to optimize experimental conditions, predict, and validate the adsorption kinetic efficacy. The machine learning (ML) optimized experimental dataset which included parameters of pH (9), contact time (2 min), CALP adsorbent (0.3 gm), and MB dye concentration (70 mg/L) has shown maximum adsorption efficacy. To enhance and assess the extraction efficiency of MB dye, a response surface methodology (RSM) was employed utilizing a central composite design (CCD).</p></div><div><h3>Significant findings</h3><p>The adsorption efficacy of CALP was verified by the Freundlich isotherm model, which demonstrated an adsorption capacity of 415.05 mg/g with a coefficient of determination R² of 0.999. The nonlinear pseudo-second-order kinetic model with an R² value of 0.998 further confirms MB dye adsorption. In addition, spontaneous nature of the process was determined by calculating thermodynamic parameters such as ΔG°, ΔH^°, and ΔS^°. The outcomes demonstrate that CALP is a highly effective, reliable, and easily available adsorbent for the removal of MB dyes from wastewater. To the best of the author's knowledge, there are substantial unmet research gaps in the fields of wastewater treatment and adsorption modeling optimization. In particular, research that combine cutting-edge machine learning methods with conventional adsorption models to enhance process efficiency and prediction accuracy are scarce. This study is the first to employ CALP, a cost-effective and environmentally sustainable natural adsorbent, for the adsorption of MB dye utilizing a machine learning-optimized approach.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141964197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption and decomposition of perfluorinated compounds using NiSBA-15 and CuSBA-15 catalysts for greenhouse gas reduction","authors":"","doi":"10.1016/j.jtice.2024.105694","DOIUrl":"10.1016/j.jtice.2024.105694","url":null,"abstract":"<div><h3>Background</h3><p>The persistence of the environmental effects of perfluorinated compounds (PFCs) and fluorinated compounds (FCs) has raised concerns due to their widespread use and long-term impact on ecosystems and human health.</p></div><div><h3>Methods</h3><p>In this study, we investigated the use of NiSBA-15 and CuSBA-15 catalysts for the adsorption and decomposition of PFCs/FCs (CF₄, SF₆, NF₃, C₃F₈, and C₄F₈) by varying parameters such as weight percentage and contact time. The catalysts were synthesized through an impregnation method with stirring at 300 rpm for 24 h, followed by calcination at 550 °C for 6 h. The catalytic decomposition of NF₃ was conducted using a glass reactor with precise flow rate control and FT-IR monitoring. Variations in acid concentration during synthesis led to structural changes, transitioning from elongated rods to doughnut-like shapes and eventually spherical structures. Impregnation with nickel and copper nitrates successfully modified SBA-15, forming NiSBA-15 and CuSBA-15, as confirmed by HR-TEM images displaying black spots. Catalytic PFC decomposition experiments using unmodified SBA-15 showed limited efficiency, achieving only 15 % NF₃ removal at 500 ppm and 500 °C over 1000 min. Subsequent modification with nickel and copper significantly improved NF₃ removal efficiency.</p></div><div><h3>Significant Results</h3><p>CuSBA-15 exhibited superior performance compared to NiSBA-15, reaching a remarkable 95 % removal efficiency of NF₃. Kinetic analysis using a pseudo-first-order reaction model demonstrated the enhanced catalytic efficiency of the modified SBA-15 catalysts, with increased reaction rate constants (K) for NF₃ decomposition. This study reveals the potential of NiSBA-15 and CuSBA-15 catalysts for the adsorption and decomposition of specific PFCs/FCs, offering valuable insights into the underlying mechanisms and practical applications of these catalysts.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Single-atom decorated hollow mesoporous carbon spheres composited with free-standing carbon cloth supported cobalt sulfide nanowire arrays as high-performance sulfur host for lithium-sulfur batteries","authors":"","doi":"10.1016/j.jtice.2024.105699","DOIUrl":"10.1016/j.jtice.2024.105699","url":null,"abstract":"<div><h3>Background</h3><p>Lithium-sulfur batteries (LSBs) are a promising next generation electrochemical energy storage device. Its commercialization however is hindered by several technical challenges, particularly shuttling of polysulfides.</p></div><div><h3>Methods</h3><p>A composite sulfur host, coupled with a porous current collector, was developed to mitigate the shuttling problem. Iron single atom (SAFe) decorated hollow mesoporous carbon spheres (HMCS), composited with cobalt sulfide nanowire arrays supported on free-standing carbon cloth (S-Co@CC), were fabricated as a high-performance sulfur host for LSBs. The sulfur host combines the high electrical conductivity and physical confinement capability of HMCS, the excellent polysulfides chemisorption capability of cobalt sulfide nanowire arrays, and the high catalytic efficiency of iron single atoms toward polysulfide conversion reactions, to achieve a high-performance LSB.</p></div><div><h3>Significant findings</h3><p>The S-Co@CC/SAFe-HMCS based LSB exhibited a high initial specific capacity of 1430 mAh <em>g</em>⁻¹ at 0.1 C. For cycling stability, a specific capacity of 578 mAh <em>g</em>⁻¹ was maintained after a 600-cycle operation at 1 C, achieving an ultralow average capacity decay rate of 0.029 % per cycle. The design of composite sulfur hosts, combining all functional components in one, proves to be an effective strategy to advance the development of high-performance LSBs.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydroxyapatite-based materials for adsorption, and adsorptive membrane process for heavy metal removal from wastewater: Recent progress, bottleneck and opportunities","authors":"","doi":"10.1016/j.jtice.2024.105668","DOIUrl":"10.1016/j.jtice.2024.105668","url":null,"abstract":"<div><h3>Background</h3><p>Heavy metals in water pose grave risks to human health and the environment, necessitating the development of cost-effective and sustainable materials to combat heavy metal pollution in water. Natural and waste-based materials have received exceptional attention among researchers in removing heavy metals.</p></div><div><h3>Methods</h3><p>The efficient hydroxyapatite (HAp) and its composites have been utilized as adsorbents and membrane materials for the efficient elimination of heavy metals from wastewater, capitalizing on their low cost, eco-friendliness, thermal stability, and efficiency.</p></div><div><h3>Significant findings</h3><p>The review commences with a brief highlight and comparison of methods of heavy metal removal. Then, it delves into HAp properties, synthesis methods, and the influence of preparation conditions on HAp characteristics. The paper evaluates heavy metal adsorption in terms of equilibrium conditions, isotherms, and kinetics. While adsorption is effective for heavy metal removal, it can be labor-intensive for regenerating adsorbents and costly for large-scale applications. Therefore, the paper discusses the potential of HAp-based membranes fabricated via electrospinning and phase inversion techniques. It explores the characteristics and heavy metal removal performance of HAp membranes. In conclusion, the review discusses limitations and future directions for HAp-based membranes. This article serves as a valuable resource for understanding the capabilities of HAp-based adsorbents and membranes for sustainable heavy metal removal.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient degradation of methylene blue by cobalt-lanthanum bimetallic MOFs with synergistic activation of peroxymonosulfate: Dominant role of singlet oxygen and hypervalent metal species","authors":"","doi":"10.1016/j.jtice.2024.105695","DOIUrl":"10.1016/j.jtice.2024.105695","url":null,"abstract":"<div><h3>Background</h3><p>The heterogeneous catalytic system of metal-organic frameworks (MOFs)-activated peroxymonosulfate (PMS) can effectively remove organic pollutants, and has become a research hotspot in the field of wastewater treatment.</p></div><div><h3>Methods</h3><p>In this work, novel bimetallic MOFs (CLB-2:1) were prepared from a one-step solvothermal method with the simultaneous introduction of transition metal cobalt and rare earth metal lanthanum.</p></div><div><h3>Significant findings</h3><p>With methylene blue (MB) as the target pollutant, the degradation rate of the CLB-2:1/PMS system can reach 97.54 % within 10 min, and the corresponding reaction rate constant (<em>k</em>_obs) is 0.7519 min⁻¹. This system maintains high stability and catalytic activity in a wide pH range and different water quality conditions. Notably, the CLB-2:1/PMS system can effectively treat various organic dyes, and is widely applicable to alleviating the pollution of printing and dyeing effluents. Mechanism studies have shown that non-radical pathways such as singlet oxygen (¹O₂) and high-valent metal species play a leading role in the reaction process. Based on LC-MS test analysis, combined with density functional theory (DFT) calculations, the MB possible degradation pathway was proposed. In general, the bimetallic MOFs/PMS system constructed here has great application prospects in the field of organic wastewater pollution treatment.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multiphase behaviors in a multistage vanadium leaching tank with mechanical-vapor combined stirring","authors":"","doi":"10.1016/j.jtice.2024.105683","DOIUrl":"10.1016/j.jtice.2024.105683","url":null,"abstract":"<div><h3>Background</h3><p>The improvement of conventional mixing methods on the problems of uneven solid phase distribution and bottom mineral deposition in multi-stage vanadium-bearing shale agitated leach tanks is limited, and more novel mixing methods need to be proposed and developed.</p></div><div><h3>Method</h3><p>In this study, vapor-liquid-solid flow, dead-zone buildup and bubble residence time in a multistage vanadium-bearing shale leaching tank with inlet and outlet were numerically investigated and compared. Three different stirring methods, namely mechanical stirring, vapor blowing stirring, and combined mechanical vapor blowing stirring, were used to stir the samples, and different inlet speeds were compared, and the numerical models were validated by water modeling tests.</p></div><div><h3>Significant Findings</h3><p>The results showed that the combination of mechanical mixing and vapor blowing could reduce the ratio of the \"dead zone\", in which the top low-concentration zone was reduced from 0.84% to 0.178%, and the bottom deposition zone was reduced from 0.32% to 0.026% compared with only mechanical mixing. Increasing the inlet vapor flow rate would enhance the stirring effect of vanadium shale leaching tank and reduce the residence time of bubble particles in the tank. The minimum residence time of bubble particles was shortened from 10.05 s to 5.95 s, and the peak residence time of bubble particles and the distribution of vapor residence time were improved significantly. The combination of mechanical stirring and vapor blowing was favorable for solid-liquid two-phase leaching reaction. Increasing the flow rate could effectively reduce the effect of bubbles on the mixing of solid-liquid phase.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Deep eutectic solvent-functionalized ZIF-67: A novel bifunctional heterogeneous catalyst for chemical fixation of CO2 into cyclic carbonates","authors":"","doi":"10.1016/j.jtice.2024.105687","DOIUrl":"10.1016/j.jtice.2024.105687","url":null,"abstract":"<div><h3>Background</h3><p>CO₂ is one of the dominant greenhouse gases that causes global warming and a series of serious environmental problems. The catalytic chemical conversion of CO₂ into value-added products is one of the attractive approaches.</p></div><div><h3>Methods</h3><p>A novel zeolitic imidazolate framework (ZIF-67) has been successfully synthesized by incorporating choline chloride and thiosemicarbazide-based deep eutectic solvent onto the surface of ZIF-67, denoted as ChTSC@ZIF-67. The material's textural and physical characteristics were analyzed using powder XRD, TGA, zeta potential, SEM, and BET surface area measurements.</p></div><div><h3>Significant Findings</h3><p>The utilization of ChTSC@ZIF-67 as a catalyst for the conversion of epoxides and carbon dioxide into cyclic carbonates, in the absence of a co-catalyst or solvent, was investigated under various experimental conditions. Optimum conditions (3 mg catalyst, 4.0 bar CO₂ pressure, 80 °C, and 3 h reaction time) led to the production of diverse cyclic carbonates with excellent yield and selectivity. The synergistic effect between the active site in ZIF-67 and the deep eutectic solvent may be the main reason for the high catalytic activity. Furthermore, the catalyst retains its heterogeneous nature for more than six cycles, exhibiting no substantial decline in yield.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Process design and muti-objective optimization of solid waste/biomass co-gasification considering tar formation","authors":"","doi":"10.1016/j.jtice.2024.105688","DOIUrl":"10.1016/j.jtice.2024.105688","url":null,"abstract":"<div><h3>Background</h3><p>The co-gasification of solid waste and biomass to produce syngas is an environmentally friendly technology. Unfortunately, the tar formation in the solid waste/biomass co-gasification process would degrade the product gas quality and the overall process efficiency.</p></div><div><h3>Methods</h3><p>In this study, the kinetics of the solid waste/biomass co-gasification is shown by the Aspen Plus simulation. Through the model validation and sensitivity analysis, it is validated that tar yield, syngas composition, and syngas yield are sensitive to gasifier temperature, steam-to-feed ratio (S/F), and blending weight ratio (B/W). It shows that the increase of the product gas yield (GY) increases CO₂ concentration in the product gas, but the tar yield is reduced. To address the sustainable solid waste/biomass co-gasifier, the multi-objective optimization (MOO) algorithm is implemented to maximize GY and minimize CO₂ concentration. For solving the MOO problem, the standard genetic algorithm (GA) coupled with response surface methodology (RSM) is performed to find the Pareto frontier plot, and the technique for order of preference by similarity to the ideal solution (TOPSIS) is used to determine optimal operating conditions.</p></div><div><h3>Significant Findings</h3><p>Under the Pareto frontier plot and TOPSIS, a GY of 2.672 Nm³/kg, CO₂ concentration of 8.045 vol.%, and tar yield of 17.0617 g/Nm³ can be achieved under the optimal conditions of T = 1099.95 °C, S/F ratio = 0.79, and B/W ratio = 10.02. In addition, the CO₂ absorption using CaO is added to purify CO₂ up to 99.999 % of purity.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Eulerian-Lagrangian numerical investigation of the fluid flow properties and heat transfer of a nanofluid-cooled micro pin-fin heat sink","authors":"","doi":"10.1016/j.jtice.2024.105674","DOIUrl":"10.1016/j.jtice.2024.105674","url":null,"abstract":"<div><h3>Background</h3><p>While the potential benefits of hybrid nanofluids for heat transfer applications have been recognized, a comprehensive understanding of their thermal behavior remains elusive due to limited modeling data.</p></div><div><h3>Methods</h3><p>This study addresses this knowledge gap by leveraging Ansys Fluent and the Lagrangian-Eulerian technique to simulate a micro pin fin heat sink containing a novel hybrid nanofluid, composed of MoS₂-Cu₃O₄ nanoparticles suspended in water. The validity of the simulations is established through meticulous comparison with established experimental data documented in the literature. The hybrid nanofluid employed in the simulations is formulated with a concentration ranging from 0.1 % to 0.5 %. Thermo-fluidic characteristics of the studied cases such as thermal performance, friction factor, and Nusselt number are presented and discussed.</p></div><div><h3>Significant Findings</h3><p>The findings indicate that the use of a hybrid nanofluid with a 5 % concentration increases the average Nusselt number by 7.6 %, 9.1 %, and 12.8 % in different sections of the heat sink compared to a 1 % concentration. The maximum thermal performance in this study is associated with case D, where using MoS₂-Cu₃O₄ at a 5 % concentration and Reynolds number of 2000 results in an 8 % increase compared to the simple case.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945428","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The effect of initial temperature on the mechanical strength of tricalcium phosphate/Chitosan/Silica aerogels nanocomposites using molecular dynamics simulation","authors":"","doi":"10.1016/j.jtice.2024.105682","DOIUrl":"10.1016/j.jtice.2024.105682","url":null,"abstract":"<div><h3>Background</h3><p>Chitosan is an organic polymer derived from chitin, showcasing commendable biocompatibility and biodegradability, while tricalcium phosphate emerges as an active ceramic with proven biocompatibility and superior compatibility with bone tissue. This composite material, endowed with a unique amalgamation of attributes including biocompatibility, porosity, and mechanical strength, proves highly applicable in diverse fields such as tissue engineering, drug delivery systems, wound repair, and as scaffolds for cell proliferation in regenerative medicine.</p></div><div><h3>Methods</h3><p>The focal point of this study is an exploration of the nuanced interplay between the mechanical properties of silica aerogel/chitosan tricalcium phosphate nanocomposites with increasing initial temperature. Employing molecular dynamics (MD) simulation, the research aims to unveil the temperature-induced variations in the critical properties.</p></div><div><h3>Significant Findings</h3><p>The results reveal that the ultimate strength and Young's modulus values are determined to converge to 772.28 MPa and 62.291 GPa, at 297 K. As the initial temperature escalates from 300 to 350 K, the US decreases from 72.28 to 714.47 MPa. The decrease in US could be due to higher temperatures, the increased thermal energy can lead to greater atomic vibrations within the material, which can promote easier dislocation movement and result in reduced resistance to deformation. The results reveal that as temperature increases to 320 K, YM increases to 67.134, and with further increase in temperature, YM decreases to 62.865 GPa</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}