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Construcción de un potenciostato de bajo costo para estudios de inhibición de corrosión de acero: determinación del potencial de corrosión y mediciones cronoamperométricas 钢抗腐蚀研究用低成本恒电位器的构造:腐蚀电位的测定和计时安培的测量
Q4 Social Sciences Pub Date : 2017-10-01 DOI: 10.1016/j.eq.2017.05.006
Marco Alfaro , Ignacio Alfaro

Knowledge integration is the central duty of chemistry education and is in this context where the investigation surrounding steel corrosion inhibition bring us the opportunity to integrate knowledge from electrochemical kinetics, Organic chemistry, Instrumental analytical chemistry and electronics via the construction of a low cost potentiostat and the use of this in studies of the anticorrosive properties of atropine sulphate with carbon steel in solution. Due that this experience is going to allow the student the determination of the corrosion potential and chronoamperometric behavior of carbon steel SAE 1010 in 0.9% NaCl solution in presence and absence of atropine sulphate in a standard electrochemistry cell of three electrodes.

知识整合是化学教育的核心任务,在这种背景下,围绕钢铁缓蚀的研究为我们提供了整合电化学动力学,有机化学,仪器分析化学和电子学知识的机会,通过构建低成本的定位器,并将其用于研究硫酸阿托品与碳钢溶液的防腐性能。由于这一经验将允许学生在三电极的标准电化学电池中,在存在和不存在硫酸阿托品的0.9% NaCl溶液中测定碳钢sae1010的腐蚀电位和计时安培行为。
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引用次数: 3
La cuarta revolución química (1945-1966). De las sustancias a las especies químicas
Q4 Social Sciences Pub Date : 2017-10-01 DOI: 10.1016/j.eq.2017.07.001
José Antonio Chamizo Guerrero

With educational purposes, a new chronology is introduced to address the history of chemistry around five revolutionary moments, analysing in this article only the fourth of them. Each revolution is considered in terms of the Kuhnian notion of ‘exemplar’ rather than ‘paradigm’. This approach enables the incorporation into the revolutionary process of the instruments that contributed to their establishment, as well as the concepts that were developed and the derived subdisciplines. It is recognized, beyond a dogma, the way in which several ‘hidden entities’ very important in the teaching of chemistry —such as atoms, molecules, electrons or, in this case, spin— are consolidated. It also traces the passage of the substances to the chemical species.

出于教育目的,本文引入了一个新的年表,以解决化学史上的五个革命时刻,本文仅分析其中的第四个。每一次革命都是根据库恩的“范例”而不是“范式”来考虑的。这种方法能够将有助于其建立的工具,以及开发的概念和派生的子学科纳入革命过程。人们认识到,在教条之外,几个在化学教学中非常重要的“隐藏实体”——如原子、分子、电子,或者在这种情况下的自旋——是如何被巩固起来的。它还追踪了物质到化学物种的通道。
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引用次数: 6
Ligações químicas em livros didáticos de química: uma análise dos elementos dos gêneros de discurso 化学教科书中的化学键:语篇体裁元素分析
Q4 Social Sciences Pub Date : 2017-10-01 DOI: 10.1016/j.eq.2017.05.001
João Rufino de Freitas Filho , Sírio Pereira da Silva , Cleiton Luiz da Silva Souza , Ladjane Pereira da Silva Rufino de Freitas , Juliano Carlo Rufino de Freitas , Jucleiton José Rufino de Freitas

Using the ideas of Bakhtin and inserting them in the broader frame of discursive studies, this paper analyzes the elements of discursive genres found in chemistry textbooks texts. Chemistry twelve books were analyzed, aimed at students of the first high school series of public and private schools. Three books have been recommended by the National Textbook Program ‐ PNLD/2012 and chosen by a large number of public school teachers. The object of the study was content Chemical Bonds. It was possible to identify recaps, calls and metaphors (the didactic genre elements); description, classification, explanation and definition (the scientific genre elements). The context element was just described in the analyzed books. The use of metaphor was predominant in the book H.

本文运用巴赫金的思想,并将其纳入话语研究的大框架,分析了化学教科书文本中话语体裁的构成要素。本研究分析了12本针对公立和私立学校第一高中系列学生的化学教科书。有3本入选2012年国家教科书计划(PNLD/2012),并被大量公立学校教师选择。研究的对象是内容化学键。它能够识别概述、召唤和隐喻(说教类型元素);描述、分类、解释和定义(科学类型元素)。上下文元素只是在分析的书籍中描述的。隐喻的运用在H。
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引用次数: 0
Teorias ácido‐base no século XX e uma análise reflexiva do trabalho científico 20世纪酸碱理论与科学工作的反思性分析
Q4 Social Sciences Pub Date : 2017-10-01 DOI: 10.1016/j.eq.2017.07.002
Felipe de Moura Souza , Eliana Maria Aricó

The paper presents a new reading on the construction of acid‐base theory in the twentieth century, more specifically the participation of S.A. Arrhenius, J.N. Bronsted, T.M. Lowry and G.N. Lewis. Along the historiographical review confronted naive views of the nature of science in order to achieve a better reflection on the scientist's role in science. The reading will provide a rethink about the importance of the history of chemistry in the classroom.

本文对20世纪酸碱理论的构建提出了一个新的解读,更具体地说,是a.a Arrhenius, J.N. Bronsted, T.M. Lowry和G.N. Lewis的参与。沿着史学的回顾,面对科学本质的幼稚观点,以便更好地反映科学家在科学中的作用。阅读材料将提供一个重新思考化学历史在课堂上的重要性。
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引用次数: 0
El laboratorio en Química Orgánica: una propuesta para la promoción de competencias científico-tecnológicas 有机化学实验室:促进科学技术能力的建议
Q4 Social Sciences Pub Date : 2017-10-01 DOI: 10.1016/j.eq.2017.04.002
Liliana I. Viera, Silvia S. Ramírez, Ana Fleisner

From different spaces it has been stated that the training in competences would seem to be the challenge of High Education. In this teaching model, not only is the understanding of the conceptual content of the disciplines important, but also the acquisition of the complex skills needed to develop competently.

This paper presents a proposal for the experimental part of a university course of Organic Chemistry based on the approach of teaching by competences. We believe that, through its implementation, competencies such as: organization and decision making, manual skills, investigative procedures and attitudes, conceptual understanding, social attitudes and information management, are promoted. Students must design a work plan whose objective is the isolation and purification of a natural product, using all the theoretical tools studied and the materials and reagents available. Subsequently they must present it in oral and written form, execute it and make a final report (written and oral) in which the results are communicated, analyzed and discussed.

The experiences showed a greater motivation of the students and an environment of great potentiality to favor the acquisition of scientific-technological competences. These kinds of experiences are transferable to other disciplines that require experimental work.

从不同的角度来看,能力的培训似乎是高等教育的挑战。在这种教学模式中,不仅理解学科的概念内容很重要,而且获得发展能力所需的复杂技能也很重要。本文提出了基于能力教学的大学有机化学课程实验部分教学方案。我们认为,通过它的实施,可以促进诸如组织和决策、手工技能、调查程序和态度、概念理解、社会态度和信息管理等能力。学生必须设计一个工作计划,其目标是分离和纯化天然产物,使用所有的理论工具和材料和试剂可用。随后,他们必须以口头和书面形式提交报告,执行报告并做出最终报告(书面和口头),在报告中沟通、分析和讨论结果。这些经验表明,学生的动机更大,环境有很大的潜力,有利于获得科学技术能力。这些经验可以转移到需要实验工作的其他学科。
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引用次数: 9
Fe de errores de «Van der Waals, más que una ecuación cúbica de estado» “范德华错误信念,而不是三次状态方程”
Q4 Social Sciences Pub Date : 2017-10-01 DOI: 10.1016/j.eq.2017.10.001
Paola R. Duque Vega, Jesus Gracia-Fadrique
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引用次数: 0
Investigación en Química Analítica aplicada a la Nutrición como una herramienta en docencia 分析化学作为教学工具应用于营养的研究
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.01.004
Rodrigo José Vargas, Dulce G. Saldaña, Lorena López-Donado

Research is one of the necessary elements to build up knowledge; for this reason, the career of nutrition at Mariano Galvez University has implemented research as an important component of the course of analytical chemistry. During this process, the impact of scientific involvement is evaluated as part of a regular course and it allows students to develop a research as a product of their imagination and curiosity.

研究是积累知识的必要因素之一;因此,马里亚诺·加尔韦兹大学的营养学专业将研究作为分析化学课程的重要组成部分。在这个过程中,科学参与的影响被评估为常规课程的一部分,它允许学生将研究作为他们想象力和好奇心的产物。
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引用次数: 0
Proposta de aula experimental utilizando a perlita expandida modificada com ortofenantrolina na remoção do negro de eriocromo T em resíduos de titulometria de complexação 用邻菲罗啉改性的膨胀珍珠岩去除络合滴定法残基中的红黑T的实验课程建议
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.01.001
Janiele Mayara Ferreira de Almeida, Sheila Pricila Marques Cabral de Souza, Isabel do Nascimento Silva, Nedja Suely Fernandes

In this paper, an approach to the removal of the eriochrome black T in an actual effluent (generated from the test to determine the water hardness by complexometric titration) using perlite modified with orthophenanthroline by the adsorption technique is proposed. A preliminary assessment of the removal of eriochrome black T in a synthetic effluent (aqueous solution of eriochrome black T) was executed for subsequent application of the optimized conditions in actual residual water (titration residue of complexation). The removal of dye at pH 10, the natural pH of the actual effluent, was not significant reaching 8.12% of color removal, on the other hand, the removal of dye at pH 3 achieved the maximum color removal (100%), indicating that the eriochrome black T interacts more effectively with the adsorbent at acidic pH (pH 5 or 3), and more efficiently at pH 3. Therefore, by the results obtained under conditions established in this present study were concluded that expanded perlite (an amorphous and naturally acidic aluminosilicate) modified with orthophenanthroline (a Bronsted base) is an easy to prepare, cheap and effective material for removal of acid dyes (eriochrome black T) applied to residues containing eriochrome T black generated during practical chemistry classes.

本文提出了一种利用正邻菲罗啉改性珍珠岩吸附技术去除实际出水(络合滴定法测定水硬度试验产生的出水)中铬黑T的方法。初步评估了合成出水(铬黑T水溶液)对铬黑T的去除率,并将优化条件应用于实际剩余水(络合滴定残渣)。在实际出水的自然pH值为pH 10时,染料去除率不显著,去除率仅为8.12%,而在pH 3时,染料去除率达到最大(100%),说明染色黑T在酸性pH (pH 5或3)下与吸附剂的相互作用更有效,在pH 3时更有效。因此,在本研究条件下得到的结果表明,用正邻菲罗啉(一种Bronsted碱)修饰的膨胀珍珠岩(一种无定形的天然酸性铝硅酸盐)是一种易于制备、廉价且有效的材料,可用于去除实际化学课上产生的含eriochrome T black残留的酸性染料(eriochrome T black)。
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引用次数: 2
¿Cómo podemos averiguar si Limpics es un fraude? Aprendiendo a diseñar investigaciones en educación secundaria 我们如何知道Limpics是否是一个骗局?学习设计中等教育研究
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.01.002
Beatriz Crujeiras , Fermín Cambeiro

This paper presents a task designed to introduce 9th grade students (14-15 years old) to planning investigations in the Chemistry laboratory. We used a context related to everyday life: an enterprise committee has just launched a campaign in schools in which they ask students to help them to unmask another who has announced a very efficient detergent called Limpics. To help students in planning the investigation, they were provided with coloured cards containing some questions. Their answers to these questions following a particular order will compose the planning. The analysis consists of examining students’ written designs (N = 20) depending on their content and adequacy to solve the investigation. The main results point to short and little precise designs.

本文提出了一项旨在介绍九年级学生(14-15岁)在化学实验室计划调查的任务。我们使用了一个与日常生活相关的语境:一个企业委员会刚刚在学校发起了一项活动,他们要求学生帮助他们揭开另一个人的面具,这个人宣布了一种非常高效的洗涤剂,名为Limpics。为协助学生策划调查,我们向他们派发了载有问题的彩色卡片。他们按照特定顺序对这些问题的回答将构成计划。分析包括检查学生的书面设计(N = 20),根据其内容和充分性来解决调查。主要的结果指向了短而不精确的设计。
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引用次数: 1
Aprendizaje basado en problemas como complemento de la enseñanza tradicional en Fisicoquímica 以问题为基础的学习是对传统物理化学教学的补充
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.03.001
Carina Lorena Fernández, María Inés Aguado

Physicochemistry's contents are considered as of little application in the future, and so a lot of the students direct their efforts towards a superficial learning. Problem-based learning (PBL) is a methodological strategy that seeks to stimulate the need of knowing in students and it is used as a mean to acquire knowledge and apply them to solve a real or fictitious problem. The purpose of this article is to describe the results of an experience in which PBL was used as a complement of traditional teaching in three student cohorts. Two instances of qualitative evaluation and three of quantitative evaluation were done. Results showed a high qualitative evaluation, emphasizing the studentś satisfaction with the close integration of theoretical and practical contents. At the same time, the group quantitative achievements were very encouraging, even though the individual performance of the group members did not reflect the same. In conclusion, the adoption of PBL as a complement to traditional teaching is an educational investment that is fruitful at least in the short and medium term, despite the initial resistance of the students and the time and effort demanded to teachers and students.

物理化学的内容被认为对将来没有什么用处,所以很多学生都把精力放在肤浅的学习上。基于问题的学习(PBL)是一种方法论策略,旨在激发学生对知识的需求,并将其作为获取知识并将其应用于解决实际或虚拟问题的手段。本文的目的是描述一个经验的结果,其中PBL被用作传统教学的补充,在三个学生队列。定性评价2例,定量评价3例。结果表明,学生对课程的定性评价较高,注重理论与实践内容的紧密结合。与此同时,小组的量化成绩非常令人鼓舞,尽管小组成员的个人表现并没有反映出同样的情况。总之,采用PBL作为传统教学的补充是一项教育投资,至少在短期和中期是富有成效的,尽管学生最初会抵制,教师和学生需要花费时间和精力。
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引用次数: 8
期刊
Educacion Quimica
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