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Modified Newman projections: A new representation of the Newman notations to convey conformational properties 改进的纽曼投影:纽曼符号的一种新的表示,以表达构象性质
Q4 Social Sciences Pub Date : 2016-10-01 DOI: 10.1016/j.eq.2016.02.003
M. Hossein Khalilian, Hormoz Khosravi, Saber Mirzaei

Conformational analysis is one of the significant subjects in the organic chemistry curriculum. Since this subject may be intricate for some beginner students, a concrete model (an activity) has been devised to explain the conformational concepts with an intriguing and simple method. This model is based on geometric shapes (particularly triangles) in which the revolution of each shape on its axis at the centroid (around its vertices and edges) simulates the rotation about a single bond in a molecule. If we take edges as lower energy (more stable) and vertices as higher energy (less stable), this revolution gives a graph almost identical to the actual conformational energy diagram of that molecule. These shapes can also incorporate into the Newman projections to form a tangible representation of these notations. Most of the participants, who got familiar with these newly modified Newman projections, found them beneficial in enhancing the students’ perception of the basic conformational properties of the molecules. Furthermore, searching for a relevant shape to match the right molecule serves as an activity that in addition to being enjoyable can encourage the students to get engaged with the topic. This model is applicable to a large variety of molecules such as the hydrocarbon, aldehyde and ketone molecules, which can also generalize to more functional groups and compounds.

构象分析是有机化学课程的重要内容之一。由于这个主题对一些初学者来说可能是复杂的,所以我们设计了一个具体的模型(一个活动),用一种有趣而简单的方法来解释构象概念。该模型基于几何形状(尤其是三角形),其中每个形状在质心轴上的旋转(围绕其顶点和边缘)模拟了分子中单个键的旋转。如果我们把边看成能量较低(更稳定),把顶点看成能量较高(更不稳定),这一转变给出的图形几乎与该分子的实际构象能图相同。这些形状也可以合并到纽曼投影中,形成这些符号的有形表示。大多数熟悉了这些新修改的纽曼投影的参与者发现,它们有助于增强学生对分子基本构象性质的感知。此外,寻找与正确分子相匹配的相关形状作为一种活动,除了令人愉快之外,还可以鼓励学生参与到主题中来。该模型适用于烃类、醛类、酮类分子等种类繁多的分子,也可以推广到更多的官能团和化合物。
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引用次数: 0
Experimentos integrados: utilización de sensores en plantas de la galvanotecnia
Q4 Social Sciences Pub Date : 2016-10-01 DOI: 10.1016/j.eq.2016.04.002
Ramón Lagos , Juan Camus

Trying to integrate knowledge sometimes is very difficult in the experimental sciences, however, the electroplating industry gives us a great opportunity because it allows integrating the knowledge of electrochemistry with the analytical chemistry and hence the use of instruments of varied sophistication in the determination of analytes. The colours of different electrolytes in the bath of electrolysis, in the cited plants, allow using the colorimetric sensor to help plant operator to quantify the degree of electrodeposition of metal of the colored electrolyte. The nickel baths are of extraordinary importance in a electroplating plant, or those requiring to deposit hard copper for the printing roller or small workshops of artisans or jewelers, because nickel coating allows deposit on it, other metals as gold or silver, of greater value, improving the aesthetics value of the obtained piece part and raising their resistance to corrosion and wear. The plant experienced operator, is capable of determining the degree of depletion of electrolyte observing the intensity of the colour to be sent to quantitative analysis, with the aim of adding exactly the amount of nickel salts that need the bath. Using the colorimetric sensor allows this operation efficiently enough, allowing solving quickly, in-situ, the analytical problem.

在实验科学中,试图整合知识有时是非常困难的,然而,电镀行业给了我们一个很好的机会,因为它允许将电化学知识与分析化学相结合,因此可以使用各种复杂的仪器来测定分析物。在所引用的工厂中,电解液中不同电解质的颜色允许使用比色传感器来帮助工厂操作员量化有色电解质的金属电沉积程度。镀镍槽在电镀厂,或那些需要为印刷滚筒或工匠或珠宝商的小作坊沉积硬铜的工厂中非常重要,因为镍涂层允许在其上沉积其他金属,如金或银,具有更高的价值,提高所获得的零件的美学价值,并提高其抗腐蚀和磨损能力。该工厂经验丰富的操作员,能够确定电解液的消耗程度,观察要发送定量分析的颜色的强度,目的是添加所需的镍盐的确切数量。使用比色传感器可以使该操作足够高效,可以快速地解决原位分析问题。
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引用次数: 5
Listado de autores 作者名单
Q4 Social Sciences Pub Date : 2016-10-01 DOI: 10.1016/j.eq.2016.09.008
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引用次数: 0
The phenomenon of brine rejection: a practical proposal for prospective primary teacher training 排斥盐水现象:未来小学教师培训的实用建议
Q4 Social Sciences Pub Date : 2016-07-01 DOI: 10.1016/j.eq.2016.03.001
José Domingo Villarroel, Daniel Zuazagoitia

The fact that sea ice may be a suitable source for fresh water is nothing new; in fact, sailors were aware of this long ago. Nevertheless, the issue that ice does reject the ions of a saline solution is not a well known topic by both novice learners and prospective teachers. This paper describes a practical activity carried out in the regular chemistry training course aimed at teachers-to-be with the objectives of, on the one hand, getting to know the phenomenon of brine rejection and, on the other hand, taking advantage of the utilized experimental design to gain insight into the colligative properties of solutions. This activity might also be adequate for secondary and high school levels.

海冰可能是淡水的合适来源,这并不是什么新鲜事;事实上,水手们很久以前就意识到了这一点。然而,冰确实排斥盐溶液中的离子,这一问题对于初学者和未来的教师来说都不是一个众所周知的话题。本文描述了在常规化学培训课程中针对准教师开展的一项实践活动,其目的一方面是了解排卤现象,另一方面是利用实验设计来了解溶液的依数性质。这种活动可能也适合中学和高中水平。
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引用次数: 1
Enseñanza de la estequiometría: uso de analogías y comprensión conceptual 化学计量学教学:使用类比和概念理解
Q4 Social Sciences Pub Date : 2016-07-01 DOI: 10.1016/j.eq.2016.04.003
Andrés Raviolo, Gabriela Lerzo

This work makes a connection between the teaching of stoichiometry, analogies and the conceptual resolution of chemistry problems. A didactic sequence on the topic is drawn up, progressive in difficulty. This sequence, based on analogies, is applied by first year university students. The experience is evaluated by means of a written questionnaire, where, amongst others, Nurrenbern and Pickering's (1987) 2 conceptual stoichiometry items figure (Nurrenbern y Pickering, 1987). The results show only partial understanding of the subject since some difficulties expressed in the bibliography were not overcome. To what extent and under which conditions analogies are helpful in the learning of this subject are discussed.

这项工作在化学计量学、类比和化学问题的概念解决之间建立了联系。关于这个话题的教学顺序已拟定,难度逐级递增。这个基于类比的顺序被大学一年级的学生应用。通过一份书面问卷来评估经验,其中包括Nurrenbern和Pickering(1987)的2个概念化学计量项目图(Nurrenbern y Pickering, 1987)。由于没有克服参考书目中表达的一些困难,结果表明对该主题只有部分理解。讨论了类比在多大程度上以及在什么条件下有助于本主题的学习。
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引用次数: 2
In memoriam 为纪念
Q4 Social Sciences Pub Date : 2016-07-01 DOI: 10.1016/j.eq.2016.05.002
Aureli Caamaño
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引用次数: 0
History and the teaching of chemistry. A tribute to Thomas Lowry's textbook “Historical Introduction to Chemistry” 历史和化学教学。致敬Thomas Lowry的教科书《化学历史导论》
Q4 Social Sciences Pub Date : 2016-07-01 DOI: 10.1016/j.eq.2016.05.001
William B. Jensen

Through Thomas Lowry's book written in 1915, Historical Introduction to Chemistry, this paper shows how chemistry can be taught from its own history.

通过Thomas Lowry在1915年写的《化学历史导论》,本文展示了如何从化学本身的历史中教授化学。
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引用次数: 3
Graphical representation of chemical periodicity of main elements through boxplot 用箱线图表示主要元素的化学周期
Q4 Social Sciences Pub Date : 2016-07-01 DOI: 10.1016/j.eq.2016.04.007
João Elias Vidueira Ferreira, Maria Tayane Silva Pinheiro, Wagner Roberto Santos dos Santos, Rodrigo da Silva Maia

Graphics play an important role in data analysis. Boxplots are powerful graphical representation of data that gives an overview and a numerical summary of a data set. In this paper boxplots are used to analyze the periodic trends of main elements. The properties considered are atomic radius, first ionization energy, electron affinity and electronegativity. Boxplots are constructed and metals, nonmetals and metalloids are compared. The results are presented in a manner not explored in chemistry textbooks, pointing out key chemical features visualized through median, quartiles, possible outliers and shape of the distribution. These pictorial representations can show similarities, differences, trends and irregularities among elements, groups and periods, which help better understand their characteristics.

图形在数据分析中起着重要的作用。箱线图是一种功能强大的数据图形表示形式,它提供了数据集的概览和数字摘要。本文采用箱线图来分析主要元素的周期变化趋势。考虑的性质是原子半径,第一电离能,电子亲和性和电负性。构建箱线图,并对金属、非金属和类金属进行比较。结果以化学教科书中未探索的方式呈现,指出通过中位数,四分位数,可能的异常值和分布形状可视化的关键化学特征。这些图形表示可以显示元素、类群和时期之间的相似性、差异性、趋势和不规则性,有助于更好地理解它们的特征。
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引用次数: 28
One hundred and one years after a milestone: Modern chemical weapons and World War I 在现代化学武器和第一次世界大战这一里程碑的101年后
Q4 Social Sciences Pub Date : 2016-07-01 DOI: 10.1016/j.eq.2016.04.004
Diego Vilches , Germán Alburquerque , Rodrigo Ramirez-Tagle

While chemical weapons have been used since the beginning of armed struggles, either for their flammable or toxic properties, it was only during World War I when what is known as “modern” chemical warfare began. July 28 marks the one hundred and one anniversary of the beginning of what is also known as “The Great War”. This conflict created enormous consequences for society at the time, marking a before and after in the history of mankind, as well as being the genesis of modern chemical warfare.

虽然化学武器从武装斗争开始就被使用,因为它们具有易燃或有毒的特性,但直到第一次世界大战期间才开始了所谓的“现代”化学战争。7月28日是“第一次世界大战”爆发101周年纪念日。这场冲突给当时的社会造成了巨大的影响,标志着人类历史的前后转折,也是现代化学战的起源。
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引用次数: 4
Desarrollo de tecnologías de la información y la comunicación para reforzar los procesos de enseñanza y aprendizaje en ciencias en el grado de maestro/a en educación infantil de la Universidad de Málaga 开发信息和通信技术,以加强马拉加大学幼儿教育硕士学位的科学教学和学习过程
Q4 Social Sciences Pub Date : 2016-07-01 DOI: 10.1016/j.eq.2016.04.006
Santiago Rojano Ramos , María del Mar López Guerrero , Gema López Guerrero

The use of a blog can improve learning of experimental sciences, so a study has been developed. The blog as a strategy allows us to encourage the learning of students and their participation in the course. The study developed contains information about the use of the blog and its positive influence to improve the perception of students towards Chemistry. In quantitative terms, it was found that this tool increases the studentś academic performance thanks to better assimilation of concepts. The sample has been divided into two groups, experimental and control group, the experimental group was involved in the development of the blog, and the control group did not have access to it. In both groups, the subject was developed in the same way, and the lecturer of the two groups was the same. The results showed that the experimental group improved their learning and raised their scores, compared to the control group. Furthermore, the experimental group completed a questionnaire in which they were asked for the usefulness of the blog. The results showed that the majority of students considered the use of blog in a positive way in order to improve the learning and understanding of the subject studied.

利用博客可以促进实验科学的学习,因此开展了一项研究。博客作为一种策略,可以鼓励学生学习和参与课程。这项研究包含了使用博客的信息及其对提高学生对化学的认知的积极影响。在定量方面,我们发现,由于更好地吸收概念,这个工具提高了学生的学习成绩。样本被分为两组,实验组和对照组,实验组参与了博客的开发,而对照组没有访问它。在两组中,主题的发展方式是一样的,两组的讲师也是一样的。结果显示,与对照组相比,实验组改善了他们的学习,提高了他们的分数。此外,实验组完成了一份调查问卷,询问他们对博客的有用性。结果显示,大多数学生认为使用博客是积极的,以提高学习和理解所研究的主题。
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引用次数: 7
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Educacion Quimica
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