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Temas de química cuántica: análisis de su presentación en libros de texto de química general 量子化学的主题:分析它们在普通化学教科书中的表现
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.03.002
Silvia Ramírez, Ana Fleisner, Liliana Viera

College students show serious difficulties in learning chemistry. From research in science teaching, this problem is considered to be multicausal. We will focus on one of the possible intrinsically disciplinary causes. Among the first issues addressed in basic chemistry courses of scientific/technological careers are those corresponding to quantum chemistry. When the student approaches for the first time these subjects only knows classic contents of physics and chemistry. While many of the terms used in both contexts are the same, the ‘world’ and ‘objects’ referred to in classical physics not seem to be the same that those that is cited in chemistry. The fact that it would seem that the quantum chemistry depends on physical models available of the world, it adds the complication of using classical physics concepts in a context in which they no longer seem to have the same meaning. In this paper we analyze the way in which general chemistry textbook introduced the contents of quantum chemistry. Four aspects are considered: epistemologic choice, perspective of approach, use of the history and philosophy of science, and contextualisation of relations between quantum and classical concepts. We conclude that the modes of presentation in the texts do not contribute to a better understanding of the concepts of the discipline, nor of the mode in which the scientific knowledge is developed.

大学生在学习化学方面表现出严重困难。从科学教学的研究来看,这个问题被认为是多因果的。我们将集中讨论一个可能的内在纪律原因。在科学/技术职业的基础化学课程中,首先要解决的问题是与量子化学相对应的问题。当学生第一次接触这些科目时,他们只知道物理和化学的经典内容。虽然在这两种情况下使用的许多术语是相同的,但经典物理学中提到的“世界”和“物体”似乎与化学中引用的不一样。事实上,量子化学似乎依赖于世界上可用的物理模型,这增加了在一个似乎不再具有相同意义的背景下使用经典物理概念的复杂性。本文分析了普通化学教材引入量子化学内容的方式。四个方面被考虑:认识论的选择,方法的角度,历史和科学哲学的使用,以及量子和经典概念之间关系的语境化。我们得出的结论是,文本中的呈现模式无助于更好地理解学科的概念,也无助于科学知识发展的模式。
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引用次数: 3
Learning from contrasting molecular animations with a metacognitive monitor activity 学习对比分子动画与元认知监测活动
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.02.003
Resa M. Kelly

A common problem associated with having General Chemistry students view animations is that students tend to accept the animations as “correct” explanations without question or consideration for their limitations. This study proposes a new strategy for presenting animations in chemistry instruction that requires students to critique contrasting animations to determine which animation is a best fit with video-recorded scientific evidence. The purpose of the study was to examine how undergraduate students, enrolled in their first semester of a General Chemistry course, responded to two contrasting animations, one that was scientifically accurate and one that was scientifically inaccurate, as molecular level explanations of a video of a redox reaction involving the reaction between solid copper and aqueous silver nitrate. An analysis of a metacognitive monitoring activity was performed to study how students saw similarities and differences between the animations, as well as, to their own molecular level explanations of the reaction event. The findings revealed that students picked up on the mechanistic differences between the animations, but they struggled with understanding why the reaction happened. Regardless of their background knowledge of chemistry, students voiced preference for animations that were simplistic in their appearance and obvious in what they conveyed while also having an explicit connection to the macroscopic level.

普通化学学生看待动画的一个常见问题是,学生倾向于接受动画作为“正确”的解释,而不去质疑或考虑它们的局限性。本研究提出了一种在化学教学中呈现动画的新策略,要求学生批判对比动画,以确定哪个动画最适合视频记录的科学证据。这项研究的目的是研究本科生在第一学期的普通化学课程中,如何对两种截然不同的动画做出反应,一种是科学上准确的,另一种是科学上不准确的,作为一段涉及固体铜和硝酸银水溶液之间反应的氧化还原反应视频的分子水平解释。对元认知监测活动进行了分析,以研究学生如何看待动画之间的异同,以及他们自己对反应事件的分子水平解释。研究结果显示,学生们发现了动画之间的机制差异,但他们很难理解为什么会发生这种反应。无论他们的化学背景知识如何,学生们都表示更喜欢那些外观简单,传达的内容明显,同时又与宏观层面有明确联系的动画。
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引用次数: 10
Historia de la ciencia para enseñar naturaleza de la ciencia: una estrategia para la formación inicial del profesorado de ciencia 从科学史到科学性质的教学:初级科学教师培训的策略
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2016.12.003
José Antonio Acevedo-Díaz , Antonio García-Carmona , María del Mar Aragón

This paper presents a didactic approach for initial science teacher education on the nature of science (NDC) using the history of science (HDC). This approach is developed through a reflective reading of stories about cases and controversies from HDC, which has been made by the authors of this work. A brief description of the stories and the methodological strategy for its implementation in the classroom are included. Also, the qualitative assessment of the participants’ reflections through a rubric with levels of progression is described.

本文提出了一种利用科学史对初级科学教师进行科学本质(NDC)教学的方法。这种方法是通过对HDC的案例和争议故事的反思性阅读而发展起来的,这些故事是由这项工作的作者制作的。故事的简要描述和在课堂上实施的方法策略包括在内。此外,定性的评估参与者的反思,通过一个标题与水平的进展描述。
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引用次数: 14
Una evaluación alternativa del tema titulación ácido-base a través de una simulación 通过模拟对酸碱滴定主题的另一种评价
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.01.003
Andrés Raviolo, Andrea Farré

This work shows the results of a learning experience on acid-base titrations, based on the projection of a simulation, in the context of an integrating and conceptual final evaluation. This activity was done after the first year university students attended theoretical, problem-solving and lab lessons and were subjected to traditional evaluation. Students were inquired about how they had identified the different materials and entities shown in the simulation and how they had established adequate conceptual links between them. In order to evaluate the results, the sample was divided in two groups depending on whether the participants had approved or not the General Chemistry mid-term evaluation. Interesting conclusions came up about what happens when students have to draw information from a simulation to solve traditional format problems.

这项工作显示了在综合和概念性最终评价的背景下,基于模拟的投影的酸碱滴定学习经验的结果。这项活动是在大学一年级学生参加了理论、问题解决和实验课程之后进行的,并接受了传统的评估。学生们被问及他们如何识别模拟中显示的不同材料和实体,以及他们如何在它们之间建立适当的概念联系。为了评估结果,根据参与者是否认可普通化学中期评估,将样本分为两组。当学生必须从模拟中提取信息来解决传统格式问题时,会发生什么情况,得出了一些有趣的结论。
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引用次数: 4
Photoprocesses in chemical education. Key experiments for core concepts 化学教育中的光处理。核心概念的关键实验
Q4 Social Sciences Pub Date : 2017-07-01 DOI: 10.1016/j.eq.2017.03.003
Michael Walter Tausch, Nico Meuter, Sebastian Spinnen

Due to the “big five” challenges in the 21st Century related to the terms of energy, food, water, mobility and climate, mankind has to replace energy from fossil fuels step by step by renewable energies. Between them, solar energy is definitely the most abundant and clean. This is a major, but not the only reason for the inclusion of photoprocesses into chemical education. In this article we present an experimental approach to the basic concept suitable for teaching all phenomena involving light in a reasonable approximation. Updated experiments demonstrating the down conversion of light by fluorescence and room-temperature phosphorescence as well as aggregation induced emission and rigidification induced luminescence are described. In order to use these experiments for teaching basic concepts in photochemistry, a simple version of an energy level model, and an extended version, containing vibrational states, are proposed.

由于21世纪能源、粮食、水、交通和气候等“五大”挑战,人类必须逐步用可再生能源取代化石燃料。在它们之间,太阳能绝对是最丰富和清洁的。这是将光过程纳入化学教育的主要原因,但不是唯一的原因。在这篇文章中,我们提出了一种实验方法来解释基本概念,这种基本概念适用于以合理的近似来教授所有涉及光的现象。更新的实验证明了光的荧光和室温磷光的下转换,以及聚集诱导发射和凝固诱导发光。为了将这些实验用于光化学基本概念的教学,我们提出了能级模型的一个简单版本,以及包含振动态的扩展版本。
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引用次数: 5
Whatever happened to Linnett double-quartet (LDQ) theory? Linnett双四重奏(LDQ)理论怎么了?
Q4 Social Sciences Pub Date : 2017-04-01 DOI: 10.1016/j.eq.2016.11.003
William B. Jensen

This paper discuss one recent episode in the history of chemistry which currently has received little attention in the scientific realism debate: the rise and “apparent” fall of an approximate model of the chemical bond known as Linnett double-quartet theory. In 1961 Linnett published a paper in the Journal of the American Chemical Society entitled “A Modification of the Lewis-Langmuir Octet Rule” in which he suggested certain changes in G. N. Lewis's original views on the role of the electron pair in covalent bond formation based on an explicit consideration of the effects of electron spin – a property of the electron unknown to Lewis in 1916. Although his theory produced outstanding predictions, it is now forgotten.

本文讨论了化学史上最近发生的一件事,这一事件目前在科学现实主义辩论中很少受到关注:一个被称为Linnett双四重奏理论的化学键近似模型的兴起和“明显”的衰落。1961年,Linnett在《美国化学学会杂志》上发表了一篇题为《Lewis- langmuir八元规则的修正》的论文,他在论文中提出了一些关于电子对在共价键形成中的作用的原始观点的改变,这些观点基于对电子自旋效应的明确考虑——这是1916年Lewis所不知道的电子性质。尽管他的理论做出了杰出的预言,但现在已经被遗忘了。
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引用次数: 3
El plateado: una actividad electroquímica para integrar diversas ciencias con el arte 镀银:一种将各种科学与艺术相结合的电化学活动
Q4 Social Sciences Pub Date : 2017-04-01 DOI: 10.1016/j.eq.2016.11.004
Ramón Lagos , Juan Camus

Electrochemical silver is an interesting activity of teaching for the integration of electrochemistry, chemistry, physics and art. Craftsman needs to produce a bright layer of silver on his works and so chooses to use electrolyte of diverse nature. The cost and the degree of toxicity are two important variables that have an impact on the determination of the choice of the electrolyte to be used. Silver usually is find in the complex state and the study of the different complexes represents an interesting activity in the chemistry of coordination compounds. It is important to establish a relation between the brightness of the coating and the stability of the complex compound of silver and therefore of its structure. This paper correlates characteristics of electrolyte with the silver brightness electrochemically deposited on copper and nickel. In order to quantify the silver brightness, the reflectivity measurements were made with the luxmeter.

《电化学银》是一项集电化学、化学、物理、美术为一体的有趣的教学活动。工匠需要在他的作品上产生一层明亮的银,因此选择使用多种性质的电解液。成本和毒性程度是影响电解液选择的两个重要变量。银通常以络合物的形式存在,对不同络合物的研究代表了配位化合物化学中一种有趣的活动。建立镀层的亮度与银络合物的稳定性及其结构之间的关系是十分重要的。本文将电解液的特性与电化学沉积在铜和镍上的银的亮度联系起来。为了量化银的亮度,用luxmeter进行了反射率测量。
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引用次数: 0
Identifying research foci to progress chemistry education as a field 确定研究重点,以推动化学教育作为一个领域
Q4 Social Sciences Pub Date : 2017-04-01 DOI: 10.1016/j.eq.2016.12.001
Keith S. Taber

Chemistry education is now increasingly seen as an academic field of scholarship in its own right. This article suggests two important principles to be taken into account when considering the question ‘What should be the key foci for chemistry education research (CER)?’. The first of these applies a typology that divides research into chemistry classrooms as inherent (‘essential’), embedded (‘entangled’) or collateral (‘incidental’), according to the extent to which the research is conceptualised in terms of issues that arise in teaching and learning the specific subject matter of chemistry. It is important for the development of the field that inherent CER is particularly encouraged. The second principle relates to what makes a field scientific. Here it is suggested that research needs to have a programmatic nature so that the field does not just accumulate more studies, but is seen to progress by allowing new researchers to effectively be inducted and then build upon existing work.

化学教育现在越来越被视为一个独立的学术领域。本文提出了在思考“化学教育研究的重点是什么”问题时应考虑的两个重要原则。其中第一个应用了一种类型学,将化学课堂研究分为固有的(“基本的”),嵌入的(“纠缠的”)或附带的(“偶然的”),根据研究在教学和学习化学特定主题中出现的问题的概念化程度。特别鼓励固有的CER对该领域的发展是重要的。第二个原则与什么使一个领域具有科学性有关。在这里,有人建议研究需要具有纲领性,这样该领域不仅可以积累更多的研究,而且可以通过允许有效地引入新的研究人员,然后在现有工作的基础上发展,从而看到进步。
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引用次数: 9
Implementación de Avogadro como visualizador y constructor de moléculas con alumnos de primer año de Odontología en la asignatura Química General y Orgánica 在普通化学和有机化学专业的牙科一年级学生中实现阿伏加德罗作为分子可视化和构建器
Q4 Social Sciences Pub Date : 2017-04-01 DOI: 10.1016/j.eq.2016.08.004
Celia Torres Quezada , Patricia Varela Gangas , María Verónica Frías , Patricio Flores-Morales

Today, molecular viewers are an undeniable reality in the classroom. This type of softwares allow students the three dimensional development. In this study, free access molecular viewer Avogadro was used. The using of the program was successful not only in the three dimensional training, but in the pointing out of carbons’ quilarity of optical isomers. In fact, the velocity was reduced to a half part in comparison to bidimensional molecules. On the other hand, students were prone to the usage of Avogadro in basic and advanced chemical courses.

今天,分子观众在课堂上是一个不可否认的现实。这种类型的软件可以让学生立体发展。在本研究中,使用了自由存取的分子观察器阿伏伽德罗。该程序的应用不仅在三维训练方面取得了成功,而且在光学同分异构体的碳质性的指出方面也取得了成功。事实上,与二维分子相比,速度减少了一半。另一方面,学生在基础和高级化学课程中倾向于使用阿伏伽德罗定理。
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引用次数: 0
¿Hacia dónde debe dirigirse la enseñanza de la Ciencia de Materiales? 材料科学的教学应该朝哪个方向发展?
Q4 Social Sciences Pub Date : 2017-04-01 DOI: 10.1016/j.eq.2016.10.002
José G. Carriazo , Martha J. Saavedra , Manuel F. Molina

Currently, it is evident the need of discussing the curricular orientation that Material Science should have as a key subject in undergraduate programs of science, engineering and related careers with technological and industrial design applications. In this work, some fundamental aspects for building of Materials Science curricula are discussed from scientific, technological and pedagogical perspectives. A scientific and technological view allows establishing conceptual contents intended from world modern knowledge on research and technological activities performed for Materials and Solid State fields. The pedagogical view shows that meaningful learning and STS (Science, Technology and Society) approach should be combined to yield a suitable educational strategy.

目前,材料科学作为科学、工程及与技术和工业设计相关的本科专业的一门重点学科,显然有必要讨论其课程定位。本文从科学、技术和教学的角度探讨了材料科学课程建设的一些基本问题。科学和技术的观点允许从世界现代知识中建立概念性内容,用于材料和固态领域的研究和技术活动。教育学观点表明,有意义的学习和STS(科学,技术和社会)方法应该结合起来,以产生一个合适的教育策略。
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引用次数: 2
期刊
Educacion Quimica
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