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2013 Annual Report Conference on Electrical Insulation and Dielectric Phenomena最新文献

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The Influence of Organic Acid on Thermal Aging of Power Transformer Oil-paper Insulation 有机酸对电力变压器油纸绝缘热老化的影响
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748119
Cui Yunguang, Wu Guangning, Wang Xiaojian, Peng Qian, Chen Ling, G. Bo
To research the influence of one of the aging product (organic acid) of cellulose on oil-paper insulation, low molecular weight of the carboxylic acid (formic, acetic) and high molecular weight of the carboxylic acid (stearic) have been added to new electric insulating oil to arrive at a neutralization value of 0.3mgKOH/g, the initial moisture content in insulation paper have been controlled at 0.5% and 2.75%. The distribution characters of organic acid in oil-paper insulation and the influence of organic acid on thermal aging of oil-paper insulation at 70°C, 90°C and 110°C have been investigated. Experimental results show that formic and acetic could be easily absorbed by insulation paper while stearic could easily dissolve in electric insulating oil. There is no significant influence of temperature and initial moisture content on the distribution characters of organic acid in oil-paper insulation. Low molecular acid would work together with moisture to accelerate the aging speed of insulation paper.
为研究纤维素老化产物之一(有机酸)对油纸绝缘性能的影响,在新型电绝缘油中加入低分子量羧酸(甲酸、乙酸)和高分子量羧酸(硬脂酸),达到中和值0.3mgKOH/g,将绝缘纸初始含水率控制在0.5%和2.75%。研究了有机酸在油纸绝缘材料中的分布特征,以及有机酸对油纸绝缘材料在70℃、90℃和110℃时热老化的影响。实验结果表明,甲酸和乙酸易被绝缘纸吸附,硬脂酸易溶于电绝缘油。温度和初始含水率对油纸绝缘材料中有机酸的分布特征无显著影响。低分子酸会与水分共同作用,加速绝缘纸的老化速度。
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引用次数: 8
Thermal in situ reduction of graphene oxide in epoxy-based nanodielectrics: Influence on dielectric properties 环氧基纳米电介质中氧化石墨烯的原位热还原:对介电性能的影响
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748226
P. Mancinelli, T. Heid, D. Fabiani, A. Saccani, M. Toselli, M. Frechette, S. Savoie, É. David
Graphene oxide (GO) water solution has been added and mixed to epoxy resin. Water has been evaporated at low pressure and the resulting mixture has been cured through an amine. Heating GO-epoxy samples at 130°C in situ chemical reduction of GO has been carried out. Dielectric constant of these graphene-based samples shows an increase of more than 50% compared to neat epoxy even for 0.3 wt% of GO dispersed into the matrix. This procedure may open a new way on tuning electrical properties of insulating materials.
将氧化石墨烯(GO)水溶液加入环氧树脂中进行混合。水在低压下蒸发,得到的混合物通过胺固化。在130℃下加热氧化石墨烯环氧树脂样品,进行了氧化石墨烯的原位化学还原。即使在基体中分散0.3 wt%的氧化石墨烯,与纯环氧树脂相比,这些石墨烯基样品的介电常数也增加了50%以上。该方法可为绝缘材料的电性能调整开辟一条新途径。
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引用次数: 9
The relationship between dielectric properties and nanoparticle dispersion of nano-SILICA/Epoxy composites 纳米二氧化硅/环氧复合材料介电性能与纳米颗粒分散的关系
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748293
Mingze Gao, Peihong Zhang, Feifeng Wang, Lin Li, Zhongyuan Li
The effect of nano-fillers on dielectric properties of Epoxy has been studied for years. However, with the same nano-particles component, there are some conflicting reports regarding the effect of nano-particles on the dielectric properties of composites. The different processing will result in different dispersion of nano-particles and different dielectric properties of composites as a result of the agglomerate and distribution of nano-particle. Here we investigate the relationship between dielectric properties and nano-particle dispersions of nano-Silica/Epoxy composites. The dielectric properties including permittivity, corona-resistance, breakdown strength and dispersion are quantitative analyzed by Image J and mathematical method. Some rules are discovered between dielectric properties and nano-particle dispersion.
纳米填料对环氧树脂介电性能的影响已被研究多年。然而,在相同的纳米颗粒成分下,关于纳米颗粒对复合材料介电性能的影响,有一些相互矛盾的报道。由于纳米颗粒的团聚和分布,不同的加工工艺会导致纳米颗粒的分散和复合材料的介电性能不同。本文研究了纳米二氧化硅/环氧复合材料的介电性能与纳米粒子分散度之间的关系。采用图像J和数学方法定量分析了介电常数、电晕电阻、击穿强度和色散等介电性能。发现了介电性能与纳米粒子色散之间的一些规律。
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引用次数: 4
DC field measurements around a cable end 电缆端头周围的直流磁场测量
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748310
M. Saltzer, B. Kallstrand, K. Johansson, D. Borg, J. Schiessling, C. Doiron
Even under corona-free conditions, insulating structures (materials) may be charged in DC fields. This is due to the fact that air has a finite ionic conductivity. The finite conductivity of air results from charges generated by background radio activity and cosmic radiation. Typical ion concentrations on ground are 107 to 1010 ions/m3 which leads to conductivities ranging from 10-16 to 10-13 S/m. An experiment has been conducted where the end of a terminated high voltage XLPE cable was used as an insulating structure. The field distribution around the stripped cable end was measured with an applied DC voltage of -140 kV using a rotating field probe. The measurements are compared to simulations, which do not specifically take into account space charge effects. A big discrepancy is observed, showing the relevance of taking into account space charge effects when modeling HVDC insulation components subjected to air.
即使在无电晕条件下,绝缘结构(材料)也可能在直流磁场中带电。这是因为空气的离子电导率是有限的。空气的有限导电性是由背景无线电活动和宇宙辐射产生的电荷造成的。地面上典型的离子浓度为107到1010个离子/立方米,这导致电导率在10-16到10-13 S/m之间。采用端接高压交联聚乙烯电缆的端部作为绝缘结构进行了实验研究。在-140 kV直流电压下,用旋转场探头测量剥离电缆端周围的场分布。测量结果与没有特别考虑空间电荷效应的模拟结果进行了比较。观察到一个很大的差异,表明在模拟受空气影响的高压直流绝缘元件时考虑空间电荷效应的相关性。
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引用次数: 2
Space charge accumulation and electric breakdown in XLPE under DC high electric field 直流强电场作用下交联聚乙烯的空间电荷积累与电击穿
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6747415
H. Suzuki, Ando Nozomu, H. Miyake, Y. Tanaka, T. Maeno
We have observed space charge profiles using the PEA (pulsed electro-acoustic) system in low density polyethylene (LDPE) and cross-linked polyethylene (XLPE) under high electric dc field to study a relationship between space charge behavior and dielectric breakdown. XLPE, which is used as an insulating material of ac power cable, is also expected to be applied as the insulating layer of DC long distance power cable. To apply the polymeric materials for the insulating layer of a dc power cable, it is necessary to understand the "space charge" effect under high dc stress. In our previous research works, we have found that a large amount of, so called, packet-like charge generates in LDPE under dc high electric field of more than 100 kV/mm and it enhances the electric field locally in balk of the sample, and finally it leads a breakdown. On the other hand, such breakdown process has not been reported for XLPE yet. Because it was difficult to get a thinner XLPE sample as LDPE was. However, since we need to understand the relationship between the space charge and the breakdown in XLPE, we tried to measure them using specially arranged PEA system for high voltage application. In this report, we investigate the space charge formation and electric breakdown characteristics in XLPE. As the results, it is found that the relationship between the space charge and the breakdown in XLPE is completely different from that in LDPE. Since the XLPE was chemically made from LDPE using cross-linked agent at high temperature. It is assumed that the breakdown strength in XLPE is strongly affected by both of the residues of the cross-linking by products and the heat history.
利用脉冲电声系统对低密度聚乙烯(LDPE)和交联聚乙烯(XLPE)在高直流电场作用下的空间电荷分布进行了观察,研究了空间电荷行为与介质击穿的关系。交联聚乙烯作为交流电力电缆的绝缘材料,也有望应用于直流长途电力电缆的绝缘层。为了将聚合物材料应用于直流电力电缆绝缘层,必须了解高直流应力下的“空间电荷”效应。在我们之前的研究工作中,我们发现在大于100 kV/mm的直流高电场作用下,LDPE中会产生大量的所谓包状电荷,并使样品的阻挡处局部电场增强,最终导致击穿。另一方面,这种分解过程在XLPE中还没有报道。因为很难得到像LDPE那样薄的XLPE样品。然而,由于我们需要了解XLPE中空间电荷与击穿之间的关系,我们尝试使用专门安排的高压应用PEA系统来测量它们。本文研究了XLPE的空间电荷形成和电击穿特性。结果表明,XLPE中空间电荷与击穿的关系与LDPE中完全不同。由于XLPE是由LDPE在高温下使用交联剂化学合成的。假定交联副产物的残余和热历史对交联聚乙烯的击穿强度有很大的影响。
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引用次数: 20
Research on interface modification and electrical tree of PE/MMT composites PE/MMT复合材料界面改性及电树研究
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6747428
X. Chi, Junguo Gao, Jiahui Guo, Guowei Zheng, Xiaohong Zhang
The phenomenon of electrical tree in polyethylene affects its service life and application in widely field. Our previous research works have showed that montmorillonite (MMT) introduced can improve electrical tree performance of polyethylene. In the present paper, organic processing methods by using intercalation agent and coupling agent are selected to modify spacing between laminar layers and surface characteristic of nano-montmorillonite. Polyethylene/nano-montmorillonite (PE/MMT) composites are prepared via melting intercalation method, the organic MMT content is 0.5%, 1%, 3%, and 5% in mass fraction respectively. It can be observed that infrared absorbance peaks of PE/MMT reduce by Fourier transform infrared spectrum (FTIR) due to hydrogen bonds formed between organic MMT and PE. The space charge characteristic and electrical tree properties of PE and PE/MMT are investigated. The test results reveal that the interfacial charge peak improved near cathode and internal space charge accumulation decreases obviously in PE/MMT composite. When content of organic montmorillonite is 0.5%, the PE/MMT composite has the minimum length and maximum density of electrical trees. Establish a model which can express the propagation of electrical tree in composite with layered inorganic filler simply, according to the testing results.
聚乙烯中的电气树现象影响了其使用寿命和在广泛领域的应用。我们之前的研究工作表明,蒙脱土(MMT)的引入可以改善聚乙烯的导电性能。本文选择了插层剂和偶联剂的有机处理方法来改变纳米蒙脱土的层间距和表面特性。采用熔融插层法制备聚乙烯/纳米蒙脱土(PE/MMT)复合材料,有机MMT的质量分数分别为0.5%、1%、3%和5%。通过傅里叶变换红外光谱(FTIR)可以观察到,由于有机MMT与PE之间形成氢键,PE/MMT的红外吸光度峰降低。研究了PE和PE/MMT的空间电荷特性和电树特性。测试结果表明,PE/MMT复合材料在阴极附近的界面电荷峰得到改善,内部空间电荷积累明显减少。当有机蒙脱土含量为0.5%时,PE/MMT复合材料的电树长度最小,密度最大。根据试验结果,建立了能简单表达层状无机填料复合材料中电树生长的模型。
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引用次数: 1
Influence of temperature on developing process of surface flashover in oil-paper insulation under combined AC-DC voltage 交直流复合电压下温度对油纸绝缘表面闪络发展过程的影响
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748251
Yuanxiang Zhou, F. Jin, Meng Huang, Y. Sha, Ling Zhang, Jianwen Huang
In order to study the influence of temperature on surface flashover behavior with oil-paper interface under combined AC-DC voltage, a discharge test assembly was established to investigate the influence of temperature on developing process of surface flashover of oil-paper interface from 25 °C to 90 °C. Based on impulse current method, the process of surface flashover of oil-paper interface under combined AC-DC voltage was studied by electrodes configurations that simulated the tangential electric field and radial electric field of surface of pressboard, in which the voltage was increased step-by-step. Meanwhile the partial discharge (PD) spectrums at whole flashover stages were studied. Moreover, high speed camera was used to record the whole process of surface flashover which was divided into 4 stages: (1)Inception stage, (2)Streamer stage, (3)Intermittent breakdown stage, (4) Surface flashover stage. The experiments results shown that flashover voltage and PD inception voltage at high temperature (HT) was lower than the voltage at low temperature (LT). The average amplitudes of PD at LT were lower than at HT. The growth rate and repetition rate of PD at HT was faster than at LT. It was easier to develop the flashover at oil-paper interface under combined AC and DC voltage at HT. So the flashover voltage was lower at HT. the surface of pressboard was destructed severely at HT, the track of surface discharge was obvious at HT.
为了研究交直流复合电压下温度对油纸界面表面闪络行为的影响,建立了一个放电试验装置,研究温度对油纸界面表面闪络发展过程的影响,试验温度范围为25℃~ 90℃。基于脉冲电流法,通过模拟压板表面切向电场和径向电场的电极配置,研究了交直流复合电压下油纸界面表面闪络的过程。同时对闪络全阶段局部放电谱进行了研究。采用高速摄像机对表面闪络的全过程进行记录,将闪络过程分为4个阶段:(1)初始阶段,(2)闪络阶段,(3)间歇击穿阶段,(4)表面闪络阶段。实验结果表明,高温条件下的闪络电压和PD起始电压均低于低温条件下的闪络电压。LT时PD的平均振幅低于HT时。高温下PD的生长速度和重复率比低温下快,交直流复合电压下油纸界面处更容易发生闪络。因此高温下的闪络电压较低。高温下压板表面破坏严重,表面放电轨迹明显。
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引用次数: 10
The frequency domain spectroscopy of natural ester and its impregnated paper insulation 天然酯及其浸渍纸绝缘的频域谱
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748338
Chen Ling, Liu Rui, Zhang Fu-zhou
With the advantages of high lighting temperature, easier degradation and renewable, the natural ester-paper insulation has been employed in distribution transformer, gradually. During the operation, the natural ester-paper insulation will deteriorate under the effect of hot, electrical field and moisture. So it is very important to assess the insulation status of ester-paper insulation in transformers. The Frequency Domain Spectroscopy (FDS) has been widely used to assess the insulation status of oil-paper insulation system. But there is little research about the FDS of natural ester and its impregnated paper insulation. This paper studies the influence of temperature and aging on the FDS of natural ester and its impregnated paper based on experiments. And the results show that, the temperature does not change the shape of FDS of natural ester and its impregnated paper, it just changes the position of FDS in the coordinate axis. The aging changes the shape of FDS of ester, obviously, but does not change the basic shape of FDS of ester-impregnated paper.
天然酯纸绝缘材料具有光照温度高、易降解、可再生等优点,已逐渐在配电变压器中得到应用。在使用过程中,天然酯纸绝缘层在高温、电场和湿气的作用下会劣化。因此,对变压器中酯-纸绝缘的绝缘状况进行评估具有十分重要的意义。频域谱法(FDS)已被广泛应用于油纸绝缘系统的绝缘状态评估。但对天然酯及其浸渍纸绝缘材料的FDS研究较少。通过实验研究了温度和老化对天然酯及其浸渍纸FDS的影响。结果表明,温度并不会改变天然酯及其浸渍纸的FDS的形状,而只会改变FDS在坐标轴上的位置。老化对酯浸渍纸FDS的形状有明显的改变,但对酯浸渍纸FDS的基本形状没有改变。
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引用次数: 1
Influence of proportion of vegetable insulating oil and mineral insulating oil on thermal aging of oil-paper insulation 植物绝缘油与矿物绝缘油配比对油纸绝缘热老化的影响
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748274
Baimei Wang, Jian Li, Junru Xiang, B. Du
Vegetable insulating oil shows good performance in electric, high anti-aging ability and environmental protection. Thus it is considered as a promising substitute for mineral insulating oil. In order to the wide spread application of vegetable oil in large power transformers, this paper presents accelerated aging experiments of oil-paper insulation involving insulating paper and the mixed oil. The mixed oil combined with different proportion of vegetable and mineral insulating oil. The experiments were performed at 130 °C to analyze the generation principle of aging products for different types of oil-paper insulation samples. Experimental results showed that the moisture content of insulating oil and paper increased with increasing of aging time and the different proportion of vegetable and mineral insulating oil during the aging process. Besides, acid value of insulation oil increased with aging time, and acid value was related to the different proportion of vegetable and mineral insulating oil. The degree of polymerization (DP) of the insulation paper decreased with the aging time. However, the DP declining rate decreased with increasing of different proportion of vegetable and mineral insulating oil.
植物绝缘油具有电气性能好、抗老化能力高、环保等特点。因此,它被认为是一种很有前途的矿物绝缘油的替代品。为了使植物油在大型电力变压器中的广泛应用,本文进行了以绝缘纸和混合油为对象的油纸绝缘加速老化试验。混合油由不同比例的植物和矿物绝缘油混合而成。实验在130℃下进行,分析了不同类型油纸绝缘试样老化产物的产生原理。实验结果表明,在老化过程中,绝缘油和纸的含水率随老化时间的延长以及植物绝缘油和矿物绝缘油比例的不同而增加。保温油的酸值随老化时间的延长而增大,酸值与植物和矿物保温油的不同配比有关。随着老化时间的延长,绝缘纸的聚合度(DP)降低。但随着植物绝缘油和矿物绝缘油配比的增加,其DP下降速率有所下降。
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引用次数: 3
Space charge accumulation on multilayer graphene/epoxy nanocomposites 多层石墨烯/环氧纳米复合材料的空间电荷积累
Pub Date : 2013-10-01 DOI: 10.1109/CEIDP.2013.6748270
J. Castellon, S. Agnel, S. Diaham, F. Saysouk, Z. Valdez-Nava, D. Fabiani, M. Frechette
Nanocomposite materials are nowadays widely studied. It is often desired, by the addition of nanoparticles in an insulating matrix, to improve electrical and thermal properties. However, few types of nanoparticles enable improvement of combined electrical and thermal properties. Here the influence of the presence of graphene nanoparticles in an epoxy matrix on space charge accumulation is studied. Thus, several percentages of graphene nanoparticles (0.05 wt.%, 0.1 wt.%, 0.5 wt.%), voluntarily chosen below the electrical percolation threshold and an epoxy resin as reference, are studied in order to evaluate the influence of the content of the nanoparticles in the epoxy matrix on space charge accumulation. Space charge measurements have been performed using the Thermal Step Method. The influence of the applied dc electric field and temperature during the poling has also been studied.
纳米复合材料目前得到了广泛的研究。通常需要在绝缘基质中加入纳米颗粒,以改善电学和热学性能。然而,很少有类型的纳米颗粒能够改善综合电学和热学性能。本文研究了石墨烯纳米颗粒在环氧基体中的存在对空间电荷积累的影响。因此,我们研究了石墨烯纳米颗粒的几个百分比(0.05 wt.%, 0.1 wt.%, 0.5 wt.%),自愿选择低于电渗透阈值,并以环氧树脂为参考,以评估环氧树脂基体中纳米颗粒含量对空间电荷积累的影响。空间电荷测量是用热步法进行的。研究了外加直流电场和温度对极化过程的影响。
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引用次数: 3
期刊
2013 Annual Report Conference on Electrical Insulation and Dielectric Phenomena
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