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Removal of Chromium from Aqueous Solution using Multilayer-Mixed (Reduction/Sorption) Bed from Iron Scrap and Nutshells 用多层混合(还原/吸附)床从铁屑和坚果壳中去除水溶液中的铬
Pub Date : 2019-06-30 DOI: 10.33261/JAARU.2019.26.2.006
N. Mahdi, H. Hameed
In this research removal of chromium from an aqueous solution by multilayer-mixed (reduction/sorption) bed via scrap iron as zero valent iron and charred nutshell (walnut shell) as adsorber were studied. Both batch and continuous system were conducted. The batch system reveals that the adsorption process was of favorable type. Three models were used to describe the adsorption process. Freundlich model is matching well to the data with (R2=0.975). In the continuous system , two  sets of experimental were considered, the first set (multilayer bed) conducted by fixing the characteristics of the scrap iron bed (bed height 0.2 cm, particle size 500 µm) and varying the walnut shell parameters, the optimum value of this set recorded as (bed height 2.5 cm, particle size250µm). While for the second set of experimental after fixing the optimum values of the walnut shell bed and varying the scrap iron bed characteristics, the optimum values were (height 1cm, particle size 500µm as filling). Also, the Mixed bed configuration were studied by conducting the optimum conditions for the previous experiment. it was found that at any certain time the mixed layer offers the maximum efficiency of removal rather than the multi-layer bed.
采用多层混合(还原/吸附)床,以废铁为零价铁,焦化核桃壳为吸附剂,对水溶液中铬的去除进行了研究。间歇系统和连续系统都进行了试验。间歇式吸附系统表明,吸附过程为有利型。用三种模型描述了吸附过程。Freundlich模型与数据匹配良好(R2=0.975)。在连续系统中,考虑了两组实验,第一组(多层床)通过固定废铁床的特性(床高0.2 cm,粒度500µm)和改变核桃壳参数进行实验,该组实验的最佳值为(床高2.5 cm,粒度250µm)。第二组实验在确定核桃壳床最佳值和改变废铁床特性后,最佳值为(高度1cm,充填粒度500µm)。并对混合床的构型进行了优化研究。研究发现,在任何特定时间,混合层比多层床具有最大的去除效率。
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引用次数: 0
Preparation of amino-functionalized mesoporous silica (MCM-41) for Nitrate anion adsorption from aqueous solution 氨基功能化介孔二氧化硅(MCM-41)的制备及其对硝酸盐阴离子的吸附
Pub Date : 2019-06-30 DOI: 10.33261/JAARU.2019.26.2.005
Anaam A. Sabri, Noor Abbood
In this study, mesoporous silica MCM-41 material was synthesized using simple method at room temperature, and then loaded it with amine group by grafting method. MCM-41 was characterized by means of atomic force microscopy (AFM), X-ray diffraction (XRD), BET surface area; Thermal Gravimetric Analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. Then the ability of MCM-41 as adsorbents to treat NO3 anion as inorganic pollutant from synthetic wastewater was investigated. Batch adsorption was employed to determine the effects of initial concentration (25-150 mg/L), pH (2-11), temperature (297,313,333 K), adsorbent dose (0.1-2g), and contact time (0–140 min). The results indicated that the kinetic data for nitrate anion adsorption with MCM-41 was fitted well with the pseudo-second-order kinetic model (R2=1). It was found that the Freundlich adsorption isotherm model for nitrate anion had the best fit with the experimental data. Various adsorbents (activated carbon, SBA-15, MCM-48) have been utilized to investigate their ability to remove nitrate anion and the results show that MCM-48 could be used to remove NO3 better than other adsorbents.
本研究采用简单的方法在室温下合成了介孔二氧化硅MCM-41材料,并通过接枝法负载胺基。采用原子力显微镜(AFM)、x射线衍射(XRD)、BET表面积等手段对MCM-41进行了表征;热重分析(TGA)和傅里叶变换红外光谱(FTIR)。然后考察了MCM-41作为吸附剂对合成废水中无机污染物NO3阴离子的处理能力。采用批量吸附法考察了初始浓度(25 ~ 150mg /L)、pH(2 ~ 11)、温度(297,313,333 K)、吸附剂剂量(0.1 2g)和接触时间(0 ~ 140 min)对吸附效果的影响。结果表明,MCM-41吸附硝酸盐阴离子的动力学数据符合拟二级动力学模型(R2=1)。结果表明,Freundlich吸附等温线模型与实验数据最吻合。利用活性炭、SBA-15、MCM-48等不同吸附剂对硝酸钠阴离子的去除效果进行了研究,结果表明MCM-48对硝酸钠阴离子的去除效果优于其他吸附剂。
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引用次数: 1
Al-Shanshul eventionality in the architecture of the first decade of the 21st century 21世纪头十年建筑的偶然性
Pub Date : 2019-06-30 DOI: 10.33261/JAARU.2019.26.2.014
Zainab Huseen Ra’ouf, R. Mahdi, Enas Salim Abdulahhad
The paper studies the concept of Shanshul as an architectural concept rooted in the Islamic world and the countries of the East with two functional and aesthetic dimensions of equal importance which contributed to its formulation as an event, But a new techniques have emerged to try to create a new image that Western architectural experiences have adopted and moved on to local Arab architectural experiences, Research Problem emerged as a lack of clarity of the role of contemporary technologies in the introduction of a new image of the Shanshul as a multidimensional event, , and the research defined its methodology to reach its goal and ending with its conclusions. It highlighted the depth of the global and Arab experience, which tried to maintain the approximate balance of the aesthetic and functional dimensions, the research concluded the ability of the Shanshul to find the balance of functional and aesthetic dimensions by reverting to their founding principles and pushing them forward through contemporary materials in a unified and coherent structure. 
本文将山书的概念作为一种植根于伊斯兰世界和东方国家的建筑概念进行了研究,并从功能和美学两个方面对其作为一个事件的形成做出了同等重要的贡献。但是,一种新的技术已经出现,试图创造一种西方建筑经验所采用的新形象,并将其转移到当地的阿拉伯建筑经验中。研究问题的出现是由于当代技术在将山书作为一个多维事件的新形象引入的过程中缺乏清晰的作用,研究定义了其方法以达到其目标并以其结论结束。它强调了全球和阿拉伯经验的深度,这些经验试图保持美学和功能维度的近似平衡,研究总结了Shanshul通过回归其创始原则并通过统一连贯的当代材料推动它们向前发展来找到功能和美学维度平衡的能力。
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引用次数: 0
Field Evaluating of Wetting Pattern from Surface Drip Irrigation System for Sand and Sandy Loam Soils 地表滴灌系统对沙质和砂质壤土湿润模式的田间评价
Pub Date : 2019-06-30 DOI: 10.33261/JAARU.2019.26.2.004
Ahmad Dnan Abbass, H. Al-thamiry
Water distribution through soils from trickle source is very important issue since it affects irrigation efficiency, wetted surface area and wetted soil profile. Many attempts to determine wetting pattern under drip irrigation using mathematical and numerical models were carried out. The verification of the validity of which model will be suitable for Iraqi soils need a detailed study. In this paper, the field work measurements of wetted pattern in two Iraqi soils (sand and sandy loam) were conducted to investigate the validity of the application of wetting pattern formulas predicted by Dawood (2016), Amin and Ekhmaj, (2006) and Schwartzman and Zur (1986). The work was divided into two parts: the first one was the laboratory work of soil texture, field capacity, permanent wilting point, and soil porosity. The second one includes field operations through landing, installation of trickle irrigation system, installation of equipment’s and sensors, adjustment of emitter discharge by the valve on the supply pipe. In each run, initial water content was measured and the system was operated for three continuous hours with three different discharges, discharges were selected as 1, 3 and 6 l/hr. the wetted diameter and depth were recorded hourly during each run test .The field measurements of wetted area were compared with that predicted by the previous studies. The obtained result indicate that the value of the wetted diameter and depth increase with increasing of water contents, the wetted diameter are inversely proportional was saturated hydraulic conductivity, and the wetted depth was directly proportional to the saturated hydraulic conductivity. Amin and Ekhmaj 2006 formula was suitable for wetted depth in sandy loam soil with average error 13.40% and Schwartzman and Zur, 1986 formulas gave a good prediction for wetted diameters with average error 12.79% for same soil. Finally Dawood (2016) formulas were more suitable than others for sand soil with average error for wetted diameter and depth 11.49%, 16.79% respectively.
细流源土壤水分分布是影响灌溉效率、湿表面积和湿土剖面的重要问题。利用数学和数值模型对滴灌条件下的湿润模式进行了多次尝试。验证哪种模型适合伊拉克土壤的有效性需要进行详细的研究。为了验证Dawood(2016)、Amin和Ekhmaj(2006)以及Schwartzman和Zur(1986)预测的湿润模式公式的有效性,本文对伊拉克两种土壤(砂土和砂质壤土)的湿润模式进行了实地测量。工作分为两部分:第一部分是土壤质地、田间容量、永久萎蔫点和土壤孔隙度的实验室工作。第二部分包括着陆的现场作业,安装滴灌系统,安装设备和传感器,通过供应管道上的阀门调节喷射器流量。在每次运行中,测量初始含水量,系统连续运行3小时,选择3种不同的流量,流量分别为1、3和6 l/hr。在每次运行试验中,每小时记录一次润湿直径和深度,并将现场测量的润湿面积与以往研究预测的润湿面积进行比较。研究结果表明:润湿直径和深度随含水率的增加而增大,润湿直径与饱和导水率成反比,润湿深度与饱和导水率成正比。Amin和Ekhmaj 2006公式适用于砂壤土的湿润深度,平均误差为13.40%;Schwartzman和Zur, 1986公式适用于相同土壤的湿润直径,平均误差为12.79%。最后,Dawood(2016)公式更适合于砂土,湿润直径和深度的平均误差分别为11.49%和16.79%。
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引用次数: 1
The Reservoir Applications of Formation Test Tool (Thayyem Rutbah Field - Syria) 地层测试工具在油藏中的应用(叙利亚Thayyem Rutbah油田)
Pub Date : 2019-06-30 DOI: 10.33261/JAARU.2019.26.2.009
Mayada Razouk
The Formation test tool is a very wide and useful application in reservoir studies. By analyzing the data in the exploratory wells, we can obtain some initial conditions for the reservoir such as heat and pressure of the reservoir as well as the determination of the initial depths of the fluid contacts. New wells in the field We can assess the movement of the fluid contacts over time and evaluate the vertical and horizontal hydrodynamic connection between the field wells. The data of this Formation test tool helps in assessing the quality of the profiles in terms of reservoir, particularly in terms of permeability. In order to clarify these applications and the mechanism of analysis of the Formation test tool test data, Thayyem Rutbah Field of the Al-Furat Oil Company in Syria was selected because of the availability of the data of this Formation test tool in a number of wells in the field. Thus, using the applications of this Formation test tool in the wells of this reservoir over time during the production period, Of the reservoir of the density of the fluid and the pressure and temperature of the reservoir and the initial depth of the oil-water contact level, in addition to the change in height over time, and the payment system that controls the reservoir as a water propulsion system, and identify the reservoir properties of the reservoir, And a good hydrodynamic connection between all field wells, making the Rutbah formation a good investment tank.
地层测试工具在储层研究中有着非常广泛和有用的应用。通过对探井资料的分析,得到了储层的温度、压力等初始条件,并确定了流体接触的初始深度。我们可以评估随着时间的推移流体接触的运动,并评估油田井之间的垂直和水平水动力连接。该地层测试工具的数据有助于评估储层剖面的质量,特别是渗透率。为了阐明这些应用和分析地层测试工具测试数据的机制,选择了叙利亚Al-Furat石油公司的Thayyem Rutbah油田,因为该油田的许多井都可以获得该地层测试工具的数据。因此,利用该地层测试工具在该油藏生产期间的井中随时间的应用,对储层的流体密度、储层的压力和温度以及油水接触层的初始深度,以及高度随时间的变化,以及作为水推进系统控制储层的支付系统,识别储层的储层性质。所有井之间良好的水动力连接,使Rutbah地层成为一个很好的投资储层。
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引用次数: 0
Design Experiments for Biosorption of Lead Ions from Wastewater by Box-Wilson’s Method Box-Wilson法生物吸附废水中铅离子的设计实验
Pub Date : 2019-06-30 DOI: 10.33261/JAARU.2019.26.2.007
Jaafar Zaki Yahya, H. Flayeh
Box-Wilson’s method of design of experiments was used to maximize heavy metal removal from synthetic wastewater. The process of optimization was based on four independent pertinent parameters: agitation speed (150-250) rpm, initial metal concentration (20-40) mg/l, pH (4-8), and biomass dose (2-4) g/l. Lead was chosen as heavy metal. A maximum biosorption was practically attained following thirty runs of different experiments, as given by 24 - Central Composite Design (CCD). The best conditions were initial metal concentration 25.29 mg/l, pH 5.78, biomass dose 3.36 g/l, agitation speed 209.21 rpm. The gained data of experiments were used to form a semiempirical model, based upon a quadratic polynomial, to foretell lead ions biosorption. The model was examined using a statistical software (Design Expert® 11.0) and found adequate. Biosorption response surfaces and contour plots were generated using the developed model, which exposed the existence of high biosorption plateaus whose specifications will be beneficial in monitoring industrial scale or pilot-scale units of future to confirm economic achievability.
Box-Wilson的实验设计方法被用来最大限度地去除合成废水中的重金属。优化过程基于四个独立的相关参数:搅拌速度(150-250)rpm,初始金属浓度(20-40)mg/l, pH(4-8)和生物质剂量(2-4)g/l。铅被选为重金属。根据24 -中心复合设计(CCD),经过30次不同的实验,实际达到了最大的生物吸收率。最佳条件为初始金属浓度25.29 mg/l、pH 5.78、生物质投加量3.36 g/l、搅拌转速209.21 rpm。利用实验所得数据,建立了基于二次多项式的半经验模型来预测铅离子的生物吸附。使用统计软件(Design Expert®11.0)对模型进行检验,发现模型是合适的。利用所开发的模型生成了生物吸收响应曲面和等高线图,揭示了高生物吸收高原的存在,其规格将有利于监测工业规模或中试规模的未来装置,以确认经济可行性。
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引用次数: 0
Removal of Reactive Green 12 Dye and COD from Simulated Wastewater Using Different Coagulants 不同混凝剂对模拟废水中活性绿12染料及COD的去除
Pub Date : 2019-06-30 DOI: 10.33261/JAARU.2019.26.2.002
T. Hussein, N. A. Jasim
The ability of using each of the following: aluminum sulphate (Al2(SO4)3.16H2O), ferric chloride (FeCl3), and ferrous sulphate (FeSO4) as chemical coagulants was investigated for removing of reactive green 12 (RG 12) dye and chemical oxygen demand (COD) from simulated wastewater. Best pH , coagulants dosages, and initial concentrations were obtained by jar test. The maximum efficiency for removing RG-12 and COD recorded by ferric chloride were 98% and 88 %,  by alum were 95% and 88%, and by ferrous sulphate were 70% and 50%. All these results obtained at the best pH 6, dosage 100 mg/l and initial concentrations for RG-12 and COD 50 mg/l and 600 mg/l respectively. The maximum volume of sludge was for alum coagulant 14 ml/l, 12 ml/l for ferric chloride and 0.5 ml/l for ferrous sulphate. The study improved that it is possible to use each of aluminum sulphate, ferric chloride and ferrous sulphate as an economical coagulant to treat the wastewater which it is polluted with RG 12 dye and COD.
研究了用硫酸铝(Al2(SO4)3.16H2O)、氯化铁(FeCl3)和硫酸亚铁(FeSO4)作为化学混凝剂去除模拟废水中的活性绿12 (rg12)染料和化学需氧量(COD)的能力。通过瓶试验获得最佳pH值、混凝剂用量和初始浓度。氯化铁对RG-12和COD的最大去除率分别为98%和88%,明矾为95%和88%,硫酸亚铁为70%和50%。结果表明,最佳pH值为6,投加量为100 mg/l, RG-12初始浓度为50 mg/l, COD初始浓度为600 mg/l。明矾混凝剂最大污泥量为14 ml/l,氯化铁最大污泥量为12 ml/l,硫酸亚铁最大污泥量为0.5 ml/l。研究表明,用硫酸铝、氯化铁和硫酸亚铁分别作为经济的混凝剂处理含rg12染料和COD的废水是可行的。
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引用次数: 1
Performance of Self-Compacted Reactive Powder Concrete Slab Under Harmonic Dynamic Loading 自密实活性粉混凝土板在谐波动荷载作用下的性能研究
Pub Date : 2019-03-31 DOI: 10.33261/JAARU.2019.26.1.012
Mohammad Bilal, S. Mohamad
Many types of loading the structure must sustain in addition to dead and live loads according to the function of structural element type that must be taken in analysis.  Dynamic resistance to loading of reinforced concrete slabs using self-compact reactive powder concrete, with different boundary conditions at the sides in addition of static loading was studied. The reinforced concrete slabs were designed under static load according to ACI-318R-2014 and then the adequacy was checked under harmonic dynamic loading. The static loading consists of dead load and residential live load considering according to ASCE-07-2010. Modeling analysis was performed to determine the eigenvalues and eigenvectors values and then frequency response analyses of the slab by finite elements method that adopted for analysis. The results indicated that in case of self-compacted reactive powder concrete rather than normal concrete gave deflection less and also there was a different result of deflection according the type of slab boundary condition supports.
根据分析中必须考虑的结构单元类型的作用,除了恒活荷载外,结构还必须承受多种荷载。研究了自密实活性粉混凝土混凝土板在外加静荷载作用下,在不同边界条件下的动力抗力。按照ACI-318R-2014标准对钢筋混凝土板进行静载设计,然后进行谐波动载充分性校核。根据ASCE-07-2010,静荷载包括恒载和住宅活载。首先进行建模分析,确定特征值和特征向量值,然后采用有限元法对楼板进行频响分析。结果表明,自密实活性粉混凝土的挠度比普通混凝土的挠度要小,而且根据板边界条件的不同,挠度的结果也不同。
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引用次数: 1
Motion Control of Non-Holonomic Wheeled Mobile Robot Based on Particle Swarm Optimization Method (PSO) 基于粒子群优化方法的非完整轮式移动机器人运动控制
Pub Date : 2019-03-31 DOI: 10.33261/JAARU.2019.26.1.008
M. Tawfik
Using (PID) controller to control the trajectory motion of non-holonomic wheeled mobile robot may not be efficient especially for non-linear systems. Hence this work introduces a combination of back stepping method with the (PID) controller to obtain an efficient controller for (WMR) to deal with the non-linear systems. Different common trajectories such as infinity, circle and straight line were applied to be tracked by (WMR) to examine the control system. The results of the simulation tests of the designated trajectories with the desired trajectories were achieved through the implementation of the mean square error for x, y and the orientation. Practical swam optimization method was used to find the control gain to investigate an optimized minimum error percentage. The results of simulation show a good tracking performance with the desired trajectories.
采用PID控制器对非完整轮式移动机器人的轨迹运动进行控制可能效果不佳,特别是对于非线性系统。因此,本文将反步法与PID控制器相结合,以获得一种有效的WMR控制器来处理非线性系统。采用无限大轨迹、圆轨迹和直线轨迹等不同的常用轨迹进行WMR跟踪,对控制系统进行检验。通过实现x、y和方向的均方误差,实现了指定轨迹与期望轨迹的仿真试验结果。采用实际游动优化方法求控制增益,寻求最优的最小误差百分比。仿真结果表明,该系统具有良好的跟踪性能。
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引用次数: 1
Optimization of Machining Parameters for MRR and Surface Roughness for 7024 AL-alloy in Pocket Milling Process 7024铝合金口袋铣削加工MRR和表面粗糙度参数的优化
Pub Date : 2019-03-31 DOI: 10.33261/JAARU.2019.26.1.002
M. Abdulrazaq, Adil Shabeeb Jaber, A. S. Hammood, Ahmed Ghazi Abdulameer
The objective of this work is the investigation of milling process variables which resulting in optimal values of the surface roughness and material removal rate during machining of 7024 Al-alloy. The machining operation implemented on C-TEK CNC milling machine. The effects of the selected parameters on the chosen characteristics have been accomplished using Taguchi’s parameter design approach; also ANOVA had been used to evaluate the contribution of each parameter on the process outputs. Different feed rates are used ranging from (60, 80 and 100) mm/min, found that high feed rates gives a high material removal rates and good surface roughness. On the other hand, using three levels of spindle speeds found that a higher spindle speeds gives better surface roughness with a little effect on MRR. The process results showed that maximum MRR achieved (2.40) mm3/min when machining feed rate (100) mm/min, spindle speed (1000) r.p.m, and depth of cut (0.6) mm while good surface roughness (0.41 µm) when machining feed rate (100) mm/min, spindle speed (1000) r.p.m, and depth of cut (0.2) mm. The level of importance of the machining parameters for material removal rate and surface roughness and is determined by using Taguchi designing experiments and the variance analysis (ANOVA).
本工作的目的是研究铣削过程中导致7024铝合金表面粗糙度和材料去除率最佳值的工艺变量。在C-TEK数控铣床上进行加工操作。采用田口的参数设计方法,完成了所选参数对所选特性的影响;还使用方差分析来评估每个参数对过程输出的贡献。不同进给量的使用范围为(60,80和100)mm/min,研究发现,高进给量可获得高材料去除率和良好的表面粗糙度。另一方面,使用三个水平的主轴转速发现,较高的主轴转速可以获得更好的表面粗糙度,而对MRR的影响很小。加工结果表明,当进给量为100 mm/min、主轴转速为1000 r.p.m.、切削深度为0.6 mm时,工件的MRR最大,达到2.40 mm3/min;当进给量为100 mm/min、主轴转速为1000 r.p.m.、切削深度为0.2 mm时,工件表面粗糙度较好,达到0.41µm。通过Taguchi设计实验和方差分析(ANOVA)确定了加工参数对材料去除率和表面粗糙度的重要程度。
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引用次数: 0
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Association of Arab Universities Journal of Engineering Sciences
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