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EXAMINATION AND ANALYSIS OF A PAINTED WOODEN FUNERARY STELA FROM THE LATE PERIOD AT THE EGYPTIAN MUSEUM IN CAIRO 对开罗埃及博物馆晚期的彩绘木制墓葬石碑的检查和分析
IF 0.2 Pub Date : 2022-12-31 DOI: 10.21608/ejars.2022.276152
A. M., Kalil, H., M. M.
: This study presents the results of various analytical techniques applied to a painted wooden stela in the Egyptian Museum in Cairo. The examined elements of the stela included the wooden support, the prepared layer, and the various colors overlaying it. The techniques applied were the analysis of a cross-section from the wooden support using a USB digital microscope, Scanning Electron Microscope (SEM), X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy with Attenuated Total Reflection (FTIR), and Visible-induced Infrared Luminescence (VIL). The study also focused on the most active fungi that grow on the wood. The analysis of the pigments revealed the presence of Egyptian green and blue, hematite, calcium carbonate, and orpiment. These were applied on an orpiment background. An organic binder in the form of gum Arabic was detected, indicating the application of the tempera technique. The wooden support was made of sycamore wood. The preparation layer consisted of calcium carbonate with silicon as the base layer, followed by a layer of calcite.
本研究展示了各种分析技术应用于开罗埃及博物馆的彩绘木碑的结果。检查了石碑的元素,包括木制支撑,准备层,以及覆盖它的各种颜色。采用USB数码显微镜、扫描电子显微镜(SEM)、x射线荧光(XRF)、x射线衍射(XRD)、衰减全反射傅里叶变换红外光谱(FTIR)和可见诱导红外发光(VIL)对木支架的横截面进行分析。该研究还关注了生长在木材上的最活跃的真菌。对颜料的分析揭示了埃及绿和蓝色、赤铁矿、碳酸钙和赭石的存在。这些都是应用在一个装饰背景。一种阿拉伯胶形式的有机粘合剂被检测到,这表明了蛋彩画技术的应用。木支架是用梧桐木做的。制备层由碳酸钙和硅为基层,外加一层方解石组成。
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引用次数: 0
EXPERIMENTAL STUDY TO PREAPARE A COMPATIBLE MORTAR FOR FILLING THE CRACKS IN ARCHAEOLOGICAL BASALTIC STONES AT ABU SIR, EGYPT 预配相容砂浆填充埃及阿布西尔考古玄武岩裂缝的试验研究
IF 0.2 Pub Date : 2022-12-31 DOI: 10.21608/ejars.2022.276150
H. Y.
: Basalt represents one of the most common stones used in the construction of our archaeological structures. However, basalt is a very dense, compact and hard igneous stone; it is highly deterior-ated by physicochemical deterioration factors especially in the open air environments. Cracks are among the dangerous deterioration aspects in basaltic stones. They significantly contribute to accelerate their deterioration rates. Consequently, the cracks in basaltic stones have to be filled with a suitable mortar to stop their harmful impacts. In the present work, four types of organic binder based mortars were prepared and comparatively evaluated to select the best one for filling the cracks occurring in the studied archaeological basaltic stones at Abu Sir area. Examinations and analytical study were performed using transmission electron microscope, polarizing microscope, x-ray diffraction, colourimetric measurement, static water contact angle, compressive strength and scanning electron microscope attached with EDS. The results declared that the mortar named M4 (Acryclirsil + basaltic powder) is the most suitable composite for filling the cracks in the studied basalt.
:玄武岩是我们考古建筑中最常见的石头之一。然而,玄武岩是一种非常致密、致密和坚硬的火成岩;它受到物理化学劣化因素的高度破坏,尤其是在露天环境中。裂缝是玄武岩中危险的退化方面之一。它们大大加快了它们的恶化速度。因此,玄武岩的裂缝必须用合适的砂浆填充,以阻止其有害影响。在本工作中,制备了四种类型的有机粘结剂基砂浆,并对其进行了比较评估,以选择最适合填充Abu Sir地区考古玄武岩中出现的裂缝的砂浆。使用透射电子显微镜、偏光显微镜、x射线衍射、色度测量、静态水接触角、抗压强度和附EDS的扫描电子显微镜进行检查和分析研究。研究结果表明,M4(Acrycyclirsil+玄武岩粉)砂浆是最适合填充玄武岩裂缝的复合材料。
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引用次数: 0
A STUDY OF THE DEGRADATION OF NATURAL ULTRAMARINE BLUE IN OIL PAINTINGS DUE TO THE INFLUENCE OF THE LOW SULFUR CONTENT CHROMOPHORE IN THE COMPOSITION BY RAMAN ANALYSIS 低含硫发色团对油画中天然群青蓝降解作用的拉曼光谱研究
IF 0.2 Pub Date : 2022-12-31 DOI: 10.21608/ejars.2022.276166
Abo-Taleb, Th.
: The discoloration of natural ultramarine is related to the change in the molecular structure and crystal arrangements of the minerals due to the release of sulfur in acidic conditions. The acid breaks the Al-O bands and causes the cage to open permanently to allow access to the chromophore responsible for the color, released from the crystal structure and the loss of aluminum. Thus, a color change allows the release of the color-bearing radical anions. Thus, it is due to the natural ultramarine that has a stimulating effect on the dissolution of the binder (linseed oil), which leads to the appearance of a white dotted surface or heterogeneous white lines on the surface of the blue color or darkening dark gray more homogeneous. The study aims to study the mechanism of color change to grey whiteness in one of the oil paintings dating back to the late nineteenth century from the Gezira Museum in Cairo. It was carried out several examinations using stereo microscopy, polarized microscopy, spectroscopy photo by (VIS-UV-IR-IRFC), and analyses by color photometer, Raman and XRD methods, and related techniques (such as FTIR ART and SEM-EDX).
:天然群青的变色与酸性条件下硫的释放导致矿物分子结构和晶体排列的变化有关。酸破坏了Al-O带,并导致笼状物永久打开,以接触负责颜色的发色团,从晶体结构中释放出来并损失铝。因此,颜色变化允许带颜色的自由基阴离子的释放。因此,这是由于天然群青对粘合剂(亚麻籽油)的溶解具有刺激作用,这导致出现白色点状表面或蓝色表面上的不均匀白线,或使深灰色变暗更均匀。这项研究旨在研究开罗盖齐拉博物馆的一幅19世纪末的油画中颜色变化为灰白色的机制。使用立体显微镜、偏光显微镜、VIS-UV-IR-IRFC光谱照片、彩色光度计、拉曼和XRD方法以及相关技术(如FTIR-ART和SEM-EDX)进行了几次检查。
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引用次数: 0
DAMAGE ASSESSMENT AND NANO TREATMENT OF THE SHARIA JUDGE TOMB AT THE FATIMID CEMETERY, ASWAN - EGYPT 埃及阿斯旺法蒂玛墓园伊斯兰教法法官墓的损伤评估和纳米处理
IF 0.2 Pub Date : 2022-12-31 DOI: 10.21608/ejars.2022.276167
Orabi, E., S. A.
: This paper focuses on the environmental hazards affecting the building materials at the Sharia Judge tomb in Aswan, abreast with finding out the appropriate Nano consolidant, to achieve the afore-mentioned purpose; the ambient environmental factors were studied and the deterioration products were noticed, building materials were studied using SEM-EDX, XRD and FTIR. Through SEM investigation; it was found that the plaster layers had a significant deterioration in addition to the spread of gaps, sepa-rations, cracks, and lack of interconnection between the grains. The analyses by EDX and XRD proved that the two layers of the plaster consist of calcium carbonate CaCO 3 and quartz SiO 2 with a percentage of halite NaCl, whitewash from gypsum CaSO 4 .2H 2 O with a percentage of halite. Through FTIR analytical results it was find out the type of organic media used. It turned out that the media was from animal glue. The study aims to consolidate the layers of plaster that suffer from complete or partial separation by applying the consolidation with calcium nano hydroxide mix with TiO 2 nanoparticles in different concentrations to consolidate the layers of the separated plaster on models similar i n composition to the composition of the original plaster layers. The results indicated that the mixture consisting of calcium nano hydroxide
:本文重点研究了影响阿斯旺Sharia Judge陵墓建筑材料的环境危害,同时寻找合适的纳米固结剂,以达到上述目的;利用SEM-EDX、XRD和FTIR对建筑材料进行了研究。通过SEM调查;研究发现,除了间隙、分离、裂纹和晶粒之间缺乏互连之外,石膏层还具有显著的劣化。EDX和XRD分析表明,两层石膏由碳酸钙CaCO3和石英SiO2组成,含一定比例的石盐NaCl,由石膏CaSO4·2H2 O洗白,含一定百分比的石盐。通过FTIR分析结果,找出了所使用的有机介质的类型。事实证明,媒体是由动物胶制成的。该研究旨在通过使用不同浓度的纳米氢氧化钙与TiO2纳米颗粒的混合物进行固结,将分离的石膏层固结在成分与原始石膏层成分相似的模型上,从而固结遭受完全或部分分离的灰泥层。结果表明,该混合物由纳米氢氧化钙组成
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引用次数: 1
COMPOSITIONAL STUDY OF SILVER COINS OF SHAMSUDDIN ILYAS SHAH, A SULTAN OF BENGAL (14TH CENTURY CE) USING EDXRF 孟加拉苏丹沙姆苏丁·伊利亚斯·沙(公元14世纪)银币成分的EDXRF研究
IF 0.2 Pub Date : 2022-12-31 DOI: 10.21608/ejars.2022.276165
N. A., A. M
: In numismatics, coins are considered as a reflection of the economy and culture of a nation or civilization. Relative proportion of major/minor elements in coins provides valuable information on changes in monetary theory, economic conditions, material technologies, political aspect, religion, cultural heritage and art of minting at the time. Ten silver coins issued by Shamsuddin Ilyas Shah, a ruler of the Bengal Sultanate, were selected from the collection of Bangladesh National Museum and analyzed using EDXRF for elemental composition and comparative study. Shamsuddin Iliyas Shah ascended the throne about the end of the year 1342 CE (743 Hijri) and had a reign of 16 years and some months. The main element, silver was estimated along with trace elements copper and gold. Silver was found in all coins and varied between 97% and 99% indicating the better economic condition of the regime of Shamsuddin Ilyas Shah. Moreover, copper was delib-erately added to silver during coin fabrication for hardening purposes.
在钱币学中,硬币被认为是一个国家或文明的经济和文化的反映。硬币中主要/次要元素的相对比例为当时货币理论、经济条件、物质技术、政治方面、宗教、文化遗产和铸造艺术的变化提供了宝贵的信息。孟加拉苏丹国统治者沙姆苏丁·伊利亚斯·沙阿发行的10枚银币是从孟加拉国国家博物馆的藏品中挑选出来的,并使用EDXRF进行元素组成分析和比较研究。沙姆苏丁·伊利亚斯·沙阿于公元1342年(743年)年底登基,在位16年零几个月。主要元素银与微量元素铜和金一起被估算。所有硬币中都发现了银,银的比例在97%到99%之间,这表明沙姆苏丁·伊利亚斯·沙阿政权的经济状况更好。此外,在硬币制造过程中,出于硬化目的,铜被故意添加到银中。
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引用次数: 0
THE STONE BLEEDING PHENOMENON AFFECTING SOME SANDSTONE INSCRIPTIONS IN THE KARNAK TEMPLES 影响卡纳克神庙砂岩铭文的渗石现象
IF 0.2 Pub Date : 2022-12-31 DOI: 10.21608/ejars.2022.276151
E. M., M. M., Redwan, M.
: Stone bleeding affecting the sandstone artifacts is considered one of the most deterioration forms that dominated the Karnak temples complex . This symptom is a serious deterioration form resulting essentially due to losing the binding material of the stone as a result of the synergistic deterioration factors and their related mechanisms (witting/drying & heating/cooling) cycles . This form is composed of an external hard crust with weak interior components that can be loosed by scratching, causing the bleeding of quartz grains. Some analytical techniques were used, such as SEM-EDX, XRD, and AAS, to define the main essence of this symptom and understand the chemical and mineralogical components. The main results of this study showed that stone bleeding is formed essentially by environmental deterioration factors, especially saline groundwater that causes the weakening of the interior components of the stone and dissolving the binding of its materials.
影响砂岩文物的石头出血被认为是卡纳克神庙建筑群中最严重的退化形式之一。这种症状是一种严重的变质形式,主要是由于协同变质因素及其相关机制(湿润/干燥和加热/冷却)循环导致石材的结合物质丢失。这种形式是由外部坚硬的外壳和脆弱的内部成分组成的,这些成分可以通过刮擦而松散,导致石英颗粒出血。利用SEM-EDX、XRD、AAS等分析技术确定了该症状的主要特征,并了解了其化学和矿物学成分。本研究的主要结果表明,结石出血本质上是由环境恶化因素造成的,特别是地下水盐碱化导致结石内部成分的弱化,溶解了其物质的结合。
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引用次数: 0
AN ANALYTICAL STUDY OF A LATE PERIOD MULTI-PIECE CARTONNAGE FROM THE EGYPTIAN MUSEUM IN CAIRO 开罗埃及博物馆一件晚期多件卡通的分析研究
IF 0.2 Pub Date : 2022-06-01 DOI: 10.21608/ejars.2022.246574
A. M., A. M., Abou Seif, N.
: The poor conditions of storage in the basement of the Egyptian Museum were the reason for severe damage to an unknown multi-piece mummy cartonnage dating back to the Late Period (780 BC-332 BC). This mummy consists of five separated pieces (a mask, a pectoral, an apron, a stomach , and a foot) on canvas support topped by a ground layer decorated with green, yellow, red, black, and white colors and a gilded layer . All the pieces of the mummy cartonnage have damage in the form of separations, cracks, discoloration, tears, and brit tleness in the layers of the canvas support. The research paper presents the result of an examination and analytical study for the layers' structure of the mummy cartonnage. Therefore, the Optical Microscope (LOM), visible light, Scanning Electronic Microscope (SEM), EDX, Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), and XRF Spectroscopy were used. The results showed that canvas support made of linen in the form of four layers of thin fiber was used in the mask, stomach, and apron pieces . In contrast, one layer of thick fiber canvas was used in other pieces (mask, foot, and pectoral). The ground layer consisted of calcium carbonate, traces of gypsum, and quartz. The painted layer included Egyptian green, malachite , hematite, goethite, goethite with orpiment, graphite, and under layer of Egyptian blue below the green, red, and yellow pigments in a unique technique, especially in the pectoral and foot pieces. It was also noted that animal glue was used in all pigments and colors as a binding medium.
:埃及博物馆地下室的储藏条件恶劣,这是一个可追溯到晚期(公元前780年至公元前332年)的未知多件木乃伊盒严重损坏的原因。这具木乃伊由五块分开的画布支撑物组成(一个面具、一个胸脯、一条围裙、一个胃和一只脚),顶部是一层用绿色、黄色、红色、黑色和白色装饰的底层和一层镀金层。木乃伊纸箱的所有碎片都有破损,表现为画布支撑层分离、开裂、变色、撕裂和脆性。本文介绍了对木乃伊盒各层结构的检验和分析研究结果。因此,使用了光学显微镜(LOM)、可见光、扫描电子显微镜(SEM)、EDX、傅立叶变换红外光谱(FTIR)、X射线衍射(XRD)和XRF光谱。结果表明,由四层薄纤维形式的亚麻制成的帆布支架用于口罩、胃部和围裙。相比之下,在其他作品(面具、脚和胸脯)中使用了一层厚纤维帆布。底层由碳酸钙、微量石膏和石英组成。绘画层包括埃及绿、孔雀石、赤铁矿、针铁矿、带雌黄的针铁矿、石墨,以及在绿色、红色和黄色颜料下方的埃及蓝底层,采用了独特的技术,尤其是胸脯和脚部。还注意到,动物胶在所有颜料和颜色中都被用作粘合介质。
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引用次数: 4
PREPARATION OF BLUE VITREOUS PAINT FROM CO3O4 NANOPARTICLES FOR APPLICATION ON STAINED GLASS AT LOW TEMPERATURES AN EXPERIMENTAL 低温彩色玻璃上用co304纳米颗粒制备蓝色玻璃涂料的实验研究
IF 0.2 Pub Date : 2022-06-01 DOI: 10.21608/ejars.2022.246579
A. N.
: One of the most important problems facing the restorer in stained glass restoration is the completion of missing glass pieces to which vitreous paints containing metal oxides were applied that require a high temperature for installation, starting from 550 °C and increasing according to the colored oxide nature and the smelter used. The present paper discusses the preparation of blue vitreous paint for nanoparticles Co 3 O 4 to improve its thermal and color properties. It compares the color prepared from the cobalt nano oxide Co 3 O 4 and cobalt oxide CoO mainly used to color the glass blue since the pharaonic periods. Examination and analysis methods , i.e., XRD, FTIR, SEM, EDX, and TEM, were used in characterizing the cobalt nano oxide. STEM, SEM, and stereo microscope were used to study the prepared color samples. Results showed that the particles size of the prepared Co 3 O 4 of 0.78 nm gave an excellent blue color when applied to the glass at a temperature of 620 °C compared to the color resulting from CoO, which was installed at a temperature of 700 °C according to mixing rates. That paved the way for reducing the proportion of the smelter in the color mixture to increase color resistance to weathering deterioration factors, especially moisture. of 620 °C; 80 °C lower than the color obtained from CoO , which allowed reducing the percentage of smelt in the color mixture. These properties help in facilitating the color completion of stained glass panels, which is an important problem facing the restorer during the restoration of archaeological glass panels. They also enhance the resistance of glass panels to weather deterioration factors, esp ecially humidity. Therefore, this study can con-tribute and pave the way in reserving stained glass panels considered a great part of the history of art.
:修复师在彩色玻璃修复中面临的最重要问题之一是完成缺失的玻璃片,这些玻璃片上涂有含有金属氧化物的玻璃漆,安装时需要高温,从550°C开始,并根据彩色氧化物的性质和使用的冶炼厂而增加。本文讨论了制备纳米Co3O4蓝色玻璃涂料,以改善其热性能和颜色性能。比较了从法老时期以来主要用于将玻璃染成蓝色的钴纳米氧化物Co3O4和钴氧化物CoO制备的颜色。采用XRD、FTIR、SEM、EDX和TEM等检测分析方法对钴纳米氧化物进行了表征。利用STEM、SEM和立体显微镜对制备的彩色样品进行了研究。结果表明,与根据混合速率在700°C温度下安装的CoO相比,在620°C的温度下应用于玻璃时,所制备的0.78nm的Co3O4的颗粒尺寸呈现出优异的蓝色。这为降低冶炼厂在颜色混合物中的比例铺平了道路,以提高颜色对风化变质因素的抵抗力,尤其是对水分的抵抗力。620°C;比从CoO获得的颜色低80°C,这允许降低颜色混合物中熔炼物的百分比。这些特性有助于彩色玻璃板的颜色完成,这是修复师在考古玻璃板修复过程中面临的一个重要问题。它们还增强了玻璃板对天气恶化因素的抵抗力,尤其是湿度。因此,这项研究可以为保留被认为是艺术史上重要组成部分的彩色玻璃板提供借鉴和铺平道路。
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引用次数: 0
CORROSION CHARACTERISTICS AND CONSERVATION OF ANCIENT EGYPTIAN BRONZE OSIRIS STATUETTE FROM AL-ARISH MUSEUM 阿尔阿里什博物馆古埃及青铜奥西里斯雕像的腐蚀特征与保护
IF 0.2 Pub Date : 2022-06-01 DOI: 10.21608/ejars.2022.246577
Mahmoud, G.
: A bronze statuette in the form of Osiris is dating back to the late period. It was manufactured by casting method. The statuette in the Osiris position shows the wand, the sceptre and the royal crown and has a cobra snake. The hooked chin and facial details reveal a calm smile. On the outside, the statuette suffered from deterioration phenomena, for example different layers of soil mixed with sand and corrosion products on the statuette's surface. Bronze disease appears in separ ate areas of the statuette. Various examinations and analyses were performed on the samples that represent the places of damage on the statuette. The layers on the statuette surface were studied using stereo microscope examination, polarizing microscope and scanning electron microscope with energy dispersive X-ray analysis (SEM-EDX). Examinations show that the surface layers consist of clay minerals, sand and corrosion products in various colors. The mineral composition of the samples was determined by X-ray diffraction analysis. The analysis revealed the presence of cuprite, ata c-amite as Corrosion products, in addition to quartz. Calcifications have been removed using appropriate tools such brushes and blunt scalpels. Treatment processes of the bronze statuette include mechanical and chemical cleaning in addition to apply benzotriazole inhibitor by 3%. A protective layer of paraloid B 82 by 3% was applied. Finally, the bronze statuette was displayed in Al- Arish museum.
:奥西里斯的青铜雕像可以追溯到晚期。它是用铸造法制造的。奥西里斯位置的小雕像展示了魔杖、权杖和皇家王冠,并有一条眼镜蛇。钩形下巴和面部细节流露出平静的微笑。从外观上看,小雕像出现了退化现象,例如不同的土壤层与沙子混合,小雕像表面出现了腐蚀产物。青铜病出现在小雕像的分离区。对代表小雕像损坏位置的样本进行了各种检查和分析。用立体显微镜、偏光显微镜和扫描电子显微镜结合能谱X射线分析(SEM-EDX)对雕像表面的层进行了研究。检查表明,表层由粘土矿物、沙子和各种颜色的腐蚀产物组成。通过X射线衍射分析测定了样品的矿物成分。分析显示,除了石英外,还存在作为腐蚀产物的亚铜矿、ata c-amite。使用合适的工具,如刷子和钝手术刀,清除钙化。青铜雕像的处理过程包括机械和化学清洗,以及3%的苯并三唑抑制剂。应用了视差B 82的3%的保护层。最后,青铜雕像在阿里什博物馆展出。
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引用次数: 0
PRE-CASTING AS AN ALTERNATIVE TECHNIQUE FOR COMPENSATION OF MISSING PARTS: APPLIED TO THE LID OF THE GRANITIC SARCOPHAGUS OF TJAY, TOMB -TT23 AT LUXOR-QURNA 预铸作为一种替代性的缺件补偿技术&应用于卢克索-库尔纳TT23墓TJAY花岗岩石棺盖
IF 0.2 Pub Date : 2022-06-01 DOI: 10.21608/ejars.2022.246576
O. A., Gad, A.
: This research deals with some defects resulting from the compensation of granite artifacts by direct casting including the leakage of a used liquid or plastic substance on the surface of the artifact causing its distortion. It also includes the subsequent treatment that is carried out to clean such leakage by using mechanical abrasive tools resulting in scratches, cracks, surface deformation, loss, etc. Additionally, the application of unsuitable materials such as white cement h as its defects. This work aims to make a blank of the missing area and then mould and cast it away from the object as an alternative gap-filling technique. That was applied on a granitic sarcophagus of Tjay tomb 23. An original sample was taken from the broken fractures of the sarcophagus and examined in terms of color, texture, and strength, then the same type of granite was brought from Aswan and crushed, then mixed with two types of Araldites, and white cement as binders. After evaluation of different mixtures, Araldite 1092 PY was chosen to be applied with coarse granite grains to be pre-casted and reinstalled. Compared to the traditional method of compensation, the authors' opinion described technique will provide a useful example of an alternative casting technique reducing the potential for any damage.
本研究针对花岗石人工制品在直接浇铸补偿过程中出现的一些缺陷,包括用过的液体或塑性物质在人工制品表面的泄漏导致其变形。还包括后续处理,使用机械磨具清理泄漏,造成划痕、裂纹、表面变形、损失等。此外,白水泥等不合适的材料的应用也是其缺陷。这个作品的目的是在缺失的区域制造一个空白,然后将其从物体上铸造和丢弃,作为一种替代的空白填充技术。这是用在第23号墓的花岗岩石棺上的。从石棺的断裂处提取了一个原始样本,并对其颜色、质地和强度进行了检查,然后从阿斯旺带来了相同类型的花岗岩并进行了粉碎,然后与两种阿拉尔石混合,并使用白水泥作为粘合剂。通过对不同混合物的评价,选择Araldite 1092 PY与粗粒花岗岩进行预浇筑和再浇筑。与传统的补偿方法相比,作者的观点描述的技术将提供一个有用的例子,一种替代铸造技术,减少潜在的任何损害。
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引用次数: 0
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Egyptian Journal of Archaeological and Restoration Studies
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